{"id":180224,"date":"2019-07-12T08:16:56","date_gmt":"2019-07-12T00:16:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=180224"},"modified":"2019-07-12T15:26:21","modified_gmt":"2019-07-12T07:26:21","slug":"%e4%bb%8a%e6%97%a5%e6%9c%80%e6%96%b0science%e8%b6%85%e5%88%86%e5%ad%90%e7%ac%bc%e6%8d%95%e6%8d%89%e9%98%b4%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=180224","title":{"rendered":"\u4eca\u65e5\u6700\u65b0Science:\u8d85\u5206\u5b50\u7b3c\u6355\u6349\u9634\u79bb\u5b50"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u76d0\u7c7b\u5316\u5408\u7269\u5728\u6c34\u4e2d\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\u662f\u4e00\u4e2a\u5f88\u5e38\u89c1\u7684\u81ea\u7136\u73b0\u8c61\u3002\u8fd9\u5176\u4e2d\u7684\u90e8\u5206\u539f\u56e0\u662f\u6781\u5316\u7684O-H\u952e\u53ef\u4ee5\u5438\u5f15\u5e26\u8d1f\u7535\u7684\u6c2f\u79bb\u5b50\u3002\u53d7\u6b64\u542f\u53d1\uff0c\u5f53\u9700\u8981\u51cf\u7f13\u6216\u8005\u6d88\u9664\u79bb\u5b50\u8fc7\u5269\u5e26\u6765\u7684\u6c61\u67d3\u65f6\uff0c\u53ef\u4ee5\u8bbe\u8ba1\u542b\u6709O-H\u952e\u6216\u8005N-H\u952e\u7684\u5206\u5b50\u53d7\u4f53\u6765\u5bcc\u96c6\u6355\u6349\u76ee\u6807\u79bb\u5b50\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u5c3a\u5bf8\u8f83\u5c0f\u7684\u9634\u79bb\u5b50\u6765\u8bf4\uff0c\u5176\u5177\u6709\u66f4\u52a0\u7d27\u5b9e\u7684\u6c34\u5316\u5c42\u548c\u66f4\u9ad8\u7684\u6c34\u5408\u81ea\u7531\u80fd\uff0c\u9700\u8981\u66f4\u591a\u7684\u80fd\u91cf\u6765\u9776\u5411\u8bc6\u522b\u4e0e\u6355\u6349\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5bf9\u5c0f\u5c3a\u5bf8\u9634\u79bb\u5b50\u5982\u6c2f\u79bb\u5b50\u5177\u6709\u9ad8\u5ea6\u4eb2\u548c\u6027\u548c\u7279\u5f02\u6027\u6355\u6349\u80fd\u529b\u7684\u5206\u5b50\u53d7\u4f53\u76ee\u524d\u4ecd\u662f\u4e00\u9879\u6781\u5177\u6311\u6218\u7684\u7814\u7a76<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u7f8e\u56fd\u5370\u7b2c\u5b89\u7eb3\u5927\u5b66\u7684<\/strong><strong>A. H. Flood<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u62a5\u9053\u53d1\u73b0\uff0c\u4e0eO-H\u952e\u76f8\u6bd4\uff0c\u5145\u5206\u6781\u5316\u7684C-H\u952e\u5bf9\u6c2f\u79bb\u5b50\u5177\u6709\u66f4\u52a0\u4f18\u5f02\u7684\u6355\u6349\u80fd\u529b\u3002\u5728\u8be5\u9879\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528CH\u7ed9\u4f53\u8bbe\u8ba1\u4e86\u7c7b\u7a74\u72b6\u914d\u4f53\uff08cryptand\uff09\u7684triazolo\u8d85\u5206\u5b50\u7b3c\u3002\u8fd9\u4e00\u5206\u5b50\u7b3c\u7684\u7a7a\u8154\u5927\u5c0f\u4e0eBowman-James\u7684NH\u6c22\u952e\u7ed3\u5408\u7684\u7a74\u72b6\u914d\u4f53\u76f8\u540c\uff0c\u800c\u5229\u7528\u4e09\u5511\u53d6\u4ee3\u9170\u80fa\u53c8\u80fd\u7ea6\u675f\u5316\u5b66\u952e\u7684\u65cb\u8f6c\u4ece\u800c\u63d0\u9ad8\u5206\u5b50\u7b3c\u7684\u521a\u6027\u3002\u8fd9\u4e00triazolo\u8d85\u5206\u5b50\u7b3c\u5c55\u73b0\u51fa\u82b3\u9999\u57fa\u5355\u5143\u4e0e\u4e09\u5511\u5355\u5143\u7684\u4ea4\u9519\u5e8f\u5217\uff0c\u5176\u7a7a\u8154\u5927\u5c0f\u80fd\u591f\u7279\u5f02\u6027\u7684\u6355\u6349\u6c2f\u79bb\u5b50\uff0c\u901a\u8fc7CH\u4e0e\u6c2f\u79bb\u5b50\u4e4b\u95f4\u7684\u6c22\u952e\u7ed3\u5408\u8fd8\u80fd\u8fdb\u4e00\u6b65\u7a33\u5b9a\u6c2f\u79bb\u5b50\u3002\u5229\u7528\u8fd9\u4e00\u8d85\u5206\u5b50\u7b3c\uff0c\u901a\u8fc7\u6db2\u6db2\u63d0\u53d6\u7684\u65b9\u5f0f\uff0c\u6c34\u4e2d\u7684\u6c2f\u5316\u7269\u53ef\u4ee5\u88ab\u9ad8\u6548\u63d0\u53d6\u5230\u975e\u6781\u6027\u7684\u4e8c\u6c2f\u7532\u70f7\u6eb6\u5242\u4e2d\uff0c\u5176\u4eb2\u548c\u80fd\u529b\u53ef\u4ee5\u8fbe\u523010<sup>17<\/sup>\/M\u3002\u8be5\u7814\u7a76\u8ba4\u4e3a\uff0c\u8bbe\u8ba1\u8fd9\u4e00\u5177\u6709\u9ad8\u4eb2\u548c\u529b\u7684\u5206\u5b50\u53d7\u4f53\u80fd\u591f\u4e3a\u9ad8\u6548\u63d0\u53d6\u6c34\u4e2d\u6c2f\u5316\u7269\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u548c\u7b56\u7565\u30022019\u5e7407\u670812\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Chloride capture using a C\u2013H hydrogen-bonding cage<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong>Science<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 <\/strong><strong>\u53ef\u7ed3\u5408\u6c2f\u5316\u7269\u5206\u5b50\u7b3c\u7684\u5408\u6210\u548c\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-180225\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/1-17.jpg\" alt=\"\" width=\"600\" height=\"370\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/1-17.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/1-17-300x185.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2 \u6c2f\u5316\u7269\u4eb2\u548c\u529b\u548c\u9009\u62e9\u6027\u7684\u5b9a\u91cf\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-180226\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2-16.jpg\" alt=\"\" width=\"535\" height=\"541\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2-16.jpg 535w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2-16-297x300.jpg 297w\" sizes=\"(max-width: 535px) 100vw, 535px\" \/><\/p>\n<p><strong>\u56fe3 \u76d0\u7684\u63d0\u53d6\u548c\u9632\u8150\u8680<\/strong> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-180227\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/3-16.jpg\" alt=\"\" width=\"600\" height=\"189\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/3-16.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/3-16-300x95.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/science.sciencemag.org\/content\/365\/6449\/159\" target=\"_blank\" rel=\"noopener\">Chloride capture using a C\u2013H hydrogen-bonding cage<\/a>\uff08Science, 2019, DOI: 10.1126\/science.aaw5145\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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