{"id":180496,"date":"2019-07-18T12:00:13","date_gmt":"2019-07-18T04:00:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=180496"},"modified":"2019-07-18T21:17:31","modified_gmt":"2019-07-18T13:17:31","slug":"%e7%94%b5%e6%b1%a0%e9%a2%86%e5%9f%9f%e5%8f%88%e6%9c%89%e6%96%b0%e8%bf%9b%e5%b1%95%ef%bc%8c%e5%bf%ab%e8%b7%9f%e4%b8%8a%e9%98%9f%e4%bc%8d%ef%bc%81%ef%bc%88amine%ef%bc%8c%e5%b4%94%e5%b1%b9%ef%bc%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=180496","title":{"rendered":"\u7535\u6c60\u9886\u57df\u53c8\u6709\u65b0\u8fdb\u5c55\uff0c\u5feb\u8ddf\u4e0a\u961f\u4f0d\uff01\uff08Amine\uff0c\u5d14\u5c79\uff0c\u80e1\u52c7\u80dc\u7b49\uff09"},"content":{"rendered":"

\u4e8c\u6b21\u7535\u6c60\u662f\u4e00\u79cd\u5c06\u7535\u80fd\u548c\u5316\u5b66\u80fd\u76f8\u4e92\u8f6c\u5316\u7684\u8bbe\u5907\u3002\u81ea\u4ece1800\u5e74\u4f0f\u6253(Volta)\u53d1\u660e\u4f0f\u6253\u7535\u5806\u4ee5\u6765\uff0c\u7535\u6c60\u5c31\u5f00\u542f\u4e86\u5b83\u5feb\u901f\u53d1\u5c55\u7684\u5386\u7a0b\u30021859\u5e74\uff0c\u666e\u5170\u7279(Plante)\u53d1\u660e\u4e86\u5177\u6709\u91cd\u8981\u610f\u4e49\u4e14\u4e00\u76f4\u4f7f\u7528\u81f3\u4eca\u7684\u94c5\u9178\u7535\u6c60\u30021991\u5e74\uff0c\u7d22\u5c3c(sony)\u6210\u529f\u5b9e\u73b0\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5546\u4e1a\u5316\uff0c\u5f00\u542f\u4e86\u4e8c\u6b21\u7535\u6c60\u7684\u4e00\u4e2a\u65b0\u7eaa\u5143\u3002\u5728\u4eca\u5929\uff0c\u4e8c\u6b21\u7535\u6c60\u5df2\u7ecf\u662f\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u4e2d\u6700\u5e7f\u6cdb\u4f7f\u7528\u7684\u50a8\u80fd\u8bbe\u5907\u3002\u800c\u968f\u7740\u8fd1\u4e9b\u5e74\u667a\u80fd\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u7206\u70b8\u5f0f\u7684\u53d1\u5c55\uff0c\u4e8c\u6b21\u7535\u6c60\u7684\u7814\u7a76\u4e5f\u8d70\u5411\u4e86\u9ad8\u6f6e\u3002\u4eba\u4eec\u4e0d\u4ec5\u81f4\u529b\u4e8e\u6539\u5584\u539f\u6709\u7684\u7535\u5316\u5b66\u50a8\u80fd\u4f53\u7cfb\uff0c\u8fd8\u7740\u91cd\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u65b0\u578b\u7535\u6c60\u4f53\u7cfb\u3002\u4e3a\u4e86\u4f7f\u5927\u5bb6\u66f4\u52a0\u5168\u9762\u548c\u5373\u65f6\u5730\u638c\u63e1\u4e8c\u6b21\u7535\u6c60\u7684\u6700\u65b0\u7814\u7a76\u52a8\u6001\uff0c\u6211\u4eec\u5bf9\u8fd1\u671f\u7684\u4e00\u4e9b\u91cd\u8981\u7684\u7535\u6c60\u6587\u732e\u8fdb\u884c\u4e86\u6c47\u603b\u68b3\u7406\uff0c\u5e0c\u671b\u80fd\u7ed9\u5927\u5bb6\u7684\u7814\u7a76\u5e26\u6765\u5e2e\u52a9\u3002<\/p>\n

1<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

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Nature<\/b><\/strong>\u00a0<\/b><\/strong>energy\uff1a\u6784\u5efa\u8d85\u5171\u5f62\u5305\u8986\u5c42\uff0c\u540c\u65f6\u4fdd\u62a4\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u4e00\u6b21\u9897\u7c92\u548c\u4e8c\u6b21\u9897\u7c92\uff0c\u63d0\u9ad8\u6750\u6599\u5728\u9ad8\u7535\u538b\u4e0b\u7684\u5bb9\u91cf\u548c\u7a33\u5b9a\u6027\u3002<\/b><\/strong><\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff08(LiNix<\/i><\/sub><\/em>Coy<\/i><\/sub><\/em>Mn1\u2212 <\/sub>x<\/i><\/sub><\/em>\u2212 <\/sub>y<\/i><\/sub><\/em>O2<\/sub>\uff0cNCM\uff09\u6b63\u6781\u6750\u6599\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5728\u9ad8\u7535\u538b\u7a97\u53e3\u4e0b\u6216\u8005\u5728\u8f83\u9ad8\u6e29\u5ea6\u4e0b\u8fdb\u884c\u5faa\u73af\u65f6\uff0c\u5176\u5c42\u72b6\u7ed3\u6784\u4f1a\u8f6c\u53d8\u4e3a\u5c16\u6676\u77f3\/\u5ca9\u76d0\u76f8\uff0c\u800c\u5b83\u4e0e\u7535\u89e3\u6db2\u7684\u754c\u9762\u4e5f\u4e0d\u7a33\u5b9a\uff0c\u8fd9\u4f1a\u5f15\u8d77\u6027\u80fd\u7684\u8870\u51cf\u548c\u4e25\u91cd\u7684\u5b89\u5168\u95ee\u9898\u3002\u9274\u4e8e\u6b64\uff0c\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684Khalil Amine<\/b><\/strong>\u548c\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u7684\u9648\u56fd\u534e<\/b><\/strong>\u91c7\u7528\u6c27\u5316\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08Oxidative chemical vapour deposition technique\uff09\u7684\u65b9\u6cd5\u5bf9\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u8fdb\u884c\u8d85\u5171\u5f62\u5305\u8986PEDOT\uff08poly(3,4-ethylenedioxythiophene\uff09\u4ee5\u671f\u6539\u5584\u5b83\u4eec\u7684\u6027\u80fd[1]<\/sup>\u3002\u8be5\u6280\u672f\u53ef\u4ee5\u540c\u65f6\u5bf9\u4e00\u6b21\/\u4e8c\u6b21\u9897\u7c92\u8fdb\u884c\u8d85\u5171\u5f62\u5305\u8986\uff0c\u800c\u4e14\u5177\u6709\u53ef\u79fb\u690d\u6027\u3002\u76f8\u6bd4\u4e8e\u53ea\u8fdb\u884c\u4e8c\u6b21\u9897\u7c92\u5305\u8986\uff0c\u540c\u65f6\u5bf9\u4e00\u6b21\/\u4e8c\u6b21\u9897\u7c92\u8fdb\u884c\u5305\u8986\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u5e76\u6784\u5efa\u7a33\u5b9a\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08\u56fe1\uff09\u3002\u6b64\u5916\uff0c\u8d85\u5171\u5f62\u5305\u8986\u7684PEDOT\u8fd8\u5177\u6709\u597d\u7684\u7535\u5b50\u548c\u79bb\u5b50\u4f20\u5230\u7279\u6027\uff0c\u4ece\u800c\u6709\u5229\u4e8e\u6750\u6599\u6027\u80fd\u7684\u53d1\u6325\u3002\u7814\u7a76\u8868\u660e\uff0c\u8d85\u5171\u5f62PEDOT\u5305\u8986\u7684NCM\u6750\u6599\u8868\u73b0\u51fa\u4e86\u6781\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u6781\u5c0f\u7684\u7535\u538b\u8870\u51cf\uff08\u56fe2\uff09\u3002\u56e0\u6b64\uff0c\u8be5\u6280\u672f\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9ad8Ni\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u4e2d\u3002<\/p>\n

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\"\" \u00a0\u00a0\u00a0<\/p>\n

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\"\"<\/p>\n

Nature<\/b><\/strong>\u00a0<\/b><\/strong>energy\uff1a\u591a\u79cd\u7ef4\u751f\u7d20\uff08Ti\uff0cMg\u548cAl\uff09\u52a9\u529bLi<\/b><\/strong>CoO<\/b><\/strong>2<\/b><\/sub><\/strong>\u6750\u6599\u5b9e\u73b0\u9ad8\u538b4<\/b><\/strong>.6 <\/b><\/strong>V\u7a33\u5b9a\u5faa\u73af\u3002<\/b><\/strong><\/p>\n

LiCoO2<\/sub>\u662f\u6700\u65e9\u5b9e\u73b0\u5546\u4e1a\u5316\u5e94\u7528\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u7531\u4e8e\u5176\u9ad8\u5bc6\u5ea6\u5e26\u6765\u7684\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\uff0c\u8fc4\u4eca\u4e3a\u6b62\u4ecd\u7136\u7262\u7262\u5360\u636e\u6d88\u8d39\u7535\u5b50\u9886\u57df\u3002LiCoO2<\/sub>\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\u9ad8\u8fbe274 mAh g-1<\/sup>\uff0c\u7136\u800c\u5b9e\u9645\u5e94\u7528\u65f6\u4e3a\u4e86\u4fdd\u8bc1\u8f83\u597d\u7684\u5faa\u73af\u6027\u80fd\uff0c\u5b83\u53ea\u80fd\u653e\u51fa173 mAh g-1<\/sup>\u7684\u5bb9\u91cf\uff08\u5bf9\u5e94\u622a\u6b62\u7535\u538b4.45 V\uff09\u3002\u901a\u8fc7\u63d0\u9ad8\u5145\u7535\u622a\u6b62\u7535\u538b\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8LiCoO2<\/sub>\u7684\u5bb9\u91cf\uff084.5 V\uff0c~185 mAh g-1<\/sup>\uff1b4.6\u00a0V\uff0c~220 mAh g-1<\/sup>\uff09\uff0c\u4f46\u662f\u8fd9\u4f1a\u9020\u6210\u5176\u7ed3\u6784\u4e0d\u7a33\u5b9a\u4ee5\u53ca\u4e25\u91cd\u7684\u5b89\u5168\u95ee\u9898\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u7269\u7406\u6240\u7684\u79b9\u4e60\u8c26<\/b><\/strong>\u548c\u674e\u6cd3<\/b><\/strong>\u7814\u7a76\u5458\u8054\u5408\u7f8e\u56fdSALC\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684Yijin<\/b><\/strong>\u00a0<\/b><\/strong>Liu<\/b><\/strong>\u91c7\u7528Ti\u3001Mg\u3001Al\u4e09\u79cd\u5143\u7d20\u5bf9LiCoO2<\/sub>\u6750\u6599\u8fdb\u884c\u75d5\u91cf\u5171\u63ba\u6742\uff08\u56fe3\uff0c\u63ba\u6742\u6bd4\u4f8b <0.1 wt%\uff09\uff0c\u5b9e\u73b0\u4e86LiCoO2<\/sub>\u57284.6 V\u9ad8\u7535\u538b\u7684\u7a33\u5b9a\u5faa\u73af\u53ca\u9ad8\u500d\u7387\u7279\u6027[2]<\/sup>\u3002\u7ed3\u5408\u540c\u6b65\u8f90\u5c04X\u5c04\u7ebf\u6210\u50cf\u6280\u672f\u548c\u5176\u4ed6\u5148\u8fdb\u7684\u5149\u8c31\u6280\u672f\uff0c\u7814\u7a76\u8005\u4eec\u8bc1\u5b9eMg\u548cAl\u8fdb\u5165\u4e86LiCoO2<\/sub>\u7684\u6676\u683c\u5185\u90e8\uff0c\u8fd9\u53ef\u4ee5\u6291\u5236LiCoO2<\/sub>\u5728\u5145\u7535\u81f34.5 V\u4ee5\u4e0a\u65f6\u53d1\u751f\u7684\u76f8\u8f6c\u53d8\u3002\u6b64\u5916\u8fd8\u53d1\u73b0\uff0cTi\u5143\u7d20\u4e0d\u4ec5\u5bcc\u96c6\u4e8eLiCoO2<\/sub>\u9897\u7c92\u8868\u9762\uff0c\u8fd8\u4f1a\u5728\u9897\u7c92\u5185\u90e8\u7684\u6676\u754c\u5904\u5bcc\u96c6\uff0c\u8fd9\u80fd\u591f\u4e3aLiCoO2<\/sub>\u9897\u7c92\u5185\u90e8\u4e00\u6b21\u9897\u7c92\u4e4b\u95f4\u63d0\u4f9b\u826f\u597d\u7684\u754c\u9762\u63a5\u89e6\uff0c\u4ece\u800c\u63d0\u5347\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\uff0c\u800c\u4e14\u5b83\u8fd8\u80fd\u591f\u5bf9\u5176\u5468\u8fb9\u7684\u6c27\u539f\u5b50\u5728\u8131\u9502\u6001\u4e0b\u7684\u7535\u8377\u5206\u5e03\u8fdb\u884c\u8c03\u8282\uff0c\u6709\u6548\u964d\u4f4e\u5176\u6c27\u5316\u6d3b\u6027\u3002\u8fd9\u4e9b\u63ba\u6742\u7684\u5143\u7d20\u901a\u8fc7\u4e0d\u540c\u7684\u673a\u7406\u534f\u540c\u6027\u5730\u6539\u5584\u4e86LiCoO2<\/sub>\u57284.6 V\u9ad8\u7535\u538b\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe4\uff09\u3002<\/p>\n

\u56fe3<\/p>\n

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\u56fe4\u00a0TMA-LCO\u548cLCO\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

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\u00a0\"\"<\/b><\/strong><\/p>\n

ACS<\/b><\/strong>\u00a0<\/b><\/strong>energy<\/b><\/strong>\u00a0<\/b><\/strong>letters\uff1a\u5316\u5b66\u9884\u9502\u5316\u5b9e\u73b0\u9ad8\u5e93\u4f26\u6548\u7387Si<\/b><\/strong>\/<\/b><\/strong>S\u9502\u79bb\u5b50\u7535\u6c60\u3002<\/b><\/strong><\/p>\n

\u9884\u9502\u5316\u6280\u672f\u6709\u7740\u91cd\u8981\u7684\u5e94\u7528\uff0c\u5b83\u53ef\u4ee5\u5c06\u975e\u9502\u5316\u7684\u6b63\/\u8d1f\u6781\u6750\u6599\u8f6c\u5316\u4e3a\u53ef\u63a7\u9502\u5316\u72b6\u6001\u7684\u6750\u6599\uff0c\u8fd9\u5bf9\u4e8e\u5f00\u53d1\u5148\u8fdb\u7684\u9502\u79bb\u5b50\u7535\u6c60\u975e\u5e38\u91cd\u8981\u3002\u4f46\u662f\uff0c\u8fc4\u4eca\u4e3a\u6b62\u5f00\u53d1\u7684\u5927\u90e8\u5206\u9884\u9502\u5316\u53cd\u5e94\u5242\u90fd\u5177\u6709\u5f88\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\u800c\u4e14\u5bf9\u6c34\u548c\u6c27\u5f88\u654f\u611f\uff0c\u8fd9\u4f7f\u5176\u96be\u4ee5\u5e94\u7528\u5728\u5b9e\u9645\u7684\u7535\u6c60\u91cc\u9762\u3002\u57fa\u4e8e\u6b64\uff0c\u6b66\u6c49\u5927\u5b66\u7684\u827e\u65b0\u5e73<\/b><\/strong>\uff0c\u94b1\u6c5f\u950b<\/b><\/strong>\u548c\u6e56\u5357\u56fd\u5bb6\u5148\u8fdb\u50a8\u80fd\u6750\u6599\u5de5\u7a0b\u7814\u7a76\u4e2d\u5fc3\u949f\u53d1\u5e73<\/b><\/strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u9884\u9502\u5316\u7b56\u7565\uff1a\u91c7\u7528\u8418\u57fa\u786b\uff08lithium naphtalenide\uff09\u5c06S-PAN\uff08Sulfur-poly(acrylonitrile)\uff09\u590d\u5408\u6750\u6599\u5b8c\u5168\u9884\u9502\u5316\u4e3aLi2<\/sub>S-PAN\u6b63\u6781\u5e76\u5c06\u7eb3\u7c73Si\u90e8\u5206\u9502\u5316\u4e3aLix<\/i><\/sub><\/em>Si\u8d1f\u6781\uff08\u56fe13\uff09[6]<\/sup>\u3002\u968f\u540e\uff0c\u5c06Li2<\/sub>S-PAN\u6b63\u6781\u4e0eLix<\/i><\/sub><\/em>Si\u8d1f\u6781\u76f8\u7ec4\u5408\u6784\u5efa\u4e86\u65b0\u578bSi\/S\u9502\u79bb\u5b50\u7535\u6c60\u3002\u8be5\u65b0\u578bLix<\/i><\/sub><\/em>Si\/Li2<\/sub>S-PAN\u7535\u6c60\u53ef\u4ee5\u8868\u73b0\u51fa710 Wh kg-1<\/sup>\u7684\u6bd4\u80fd\u91cf\uff0c\u9996\u6b21\u5e93\u4f26\u6548\u7387\u9ad8\u8fbe93.5%\uff0c\u800c\u4e14\u5177\u6709\u4e0d\u9519\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe14\uff09\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8be5\u5316\u5b66\u9884\u9502\u5316\u6280\u672f\u5177\u6709\u6e29\u548c\uff0c\u9ad8\u6548\u7684\u7279\u70b9\uff0c\u53ef\u4ee5\u5e7f\u6cdb\u5e94\u7528\u5728\u7f3c\u9502\u7684\u7535\u6781\u6750\u6599\u91cc\u3002\u56e0\u6b64\uff0c\u8be5\u6280\u672f\u4e5f\u4e3a\u5f00\u53d1\u4f4e\u6210\u672c\uff0c\u73af\u5883\u53cb\u597d\u548c\u9ad8\u5bb9\u91cf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5f00\u8f9f\u4e86\u65b0\u7684\u9053\u8def\u3002<\/p>\n

\u56fe13 \u91c7\u7528\u5316\u5b66\u9884\u9502\u5316\u6280\u672f\u5236\u5907\u7684Lix<\/i><\/sub><\/em>Si\/Li2<\/sub>S-PAN\u7535\u6c60<\/p>\n

\"\"<\/p>\n

\u56fe14<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7eb3\u7c73Si\u548c\u9884\u9502\u5316\u7684Si\u7684\u7535\u6027\u80fd\uff1b\uff08b-e\uff09Lix<\/i><\/sub><\/em>Si\/Li2<\/sub>S-PAN\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

4 \u94a0\/\u94be\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\u94a0\u548c\u94be\u5f52\u5c5e\u540c\u4e00\u65cf\uff0c\u5177\u6709\u7c7b\u4f3c\u7684\u5316\u5b66\u6027\u8d28\uff0c\u800c\u4e14\u76f8\u6bd4\u4e8e\u8d44\u6e90\u6709\u9650\u7684\u9502\uff0c\u5b83\u4eec\u7684\u50a8\u91cf\u6781\u5176\u4e30\u5bcc\u3002\u56e0\u6b64\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u5b66\u8005\u5f00\u59cb\u7814\u7a76\u94a0\u79bb\u5b50\u7535\u6c60\u548c\u94be\u79bb\u5b50\u7535\u6c60\uff0c\u4ee5\u671f\u80fd\u591f\u5c06\u5b83\u4eec\u5e94\u7528\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u4e0a\u3002<\/p>\n

ACS<\/b><\/strong>\u00a0<\/b><\/strong>energy<\/b><\/strong>\u00a0<\/b><\/strong>letters\uff1a\u9ad8\u6027\u80fdN<\/b><\/strong>a<\/b><\/strong>3<\/b><\/sub><\/strong>V<\/b><\/strong>2<\/b><\/sub><\/strong>(PO<\/b><\/strong>4<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>F<\/b><\/strong>3<\/b><\/sub><\/strong>\u7684\u5927\u89c4\u6a21\u7ecf\u6d4e\u5316\u751f\u4ea7\u4e4b\u8def\u3002<\/b><\/strong><\/p>\n

Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u56e0\u4e3a\u6709\u7740\u7a33\u5b9a\u7684NASICON\u7ed3\u6784\uff0c\u5feb\u901f\u7684Na+<\/sup>\u79bb\u5b50\u4f20\u8f93\u901f\u5ea6\uff0c\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff08128 mAh g-1<\/sup>\uff09\u548c\u9ad8\u7684\u5e73\u5747\u5de5\u4f5c\u7535\u538b\uff083.85 V\uff09\u800c\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u5e0c\u671b\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u73b0\u5728\u5236\u5907Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u7684\u65b9\u6cd5\u5b58\u5728\u7740\u4e24\u5927\u95ee\u9898\uff0c\u4e00\u4e2a\u662f\u80fd\u8017\u9ad8\uff0c\u53e6\u4e00\u4e2a\u662f\u5236\u5907\u7684\u6750\u6599\u500d\u7387\u6027\u80fd\u8f83\u5dee\u3002\u57fa\u4e8e\u6b64\uff0c\u4e2d\u79d1\u9662\u5927\u8fde\u7269\u5316\u6240\u7684\u90d1\u743c<\/b><\/strong>\u548c\u674e\u5148\u950b<\/b><\/strong>\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u6761\u7ecf\u6d4e\u9ad8\u6548\u7684\u201c\u6eb6\u5242\u70ed-\u7403\u78e8\u201d\u65b9\u6cd5\u6765\u89e3\u51b3\u4e0a\u8ff0\u7684\u95ee\u9898\uff08\u56fe15\uff09[7]<\/sup>\u3002\u5728\u6eb6\u5242\u70ed\u7684\u8fc7\u7a0b\u4e2d\uff0cNa3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u7684\u5f62\u8c8c\u4f1a\u968f\u7740pH\u7684\u53d8\u5316\u4ece0D\u53d8\u4e3a3D\u3002\u5f53pH=3\u7684\u65f6\u5019\uff0c\u7531\u4e8e\u6750\u6599\u5177\u6709\u6700\u5feb\u7684\u751f\u957f\u901f\u5ea6\uff0cNa3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u5448\u73b03D\u7ed3\u6784\u800c\u4e14\u5177\u6709\u6700\u4f73\u7684\u7eaf\u5ea6\u3002\u968f\u540e\uff0c\u5c06\u5f97\u5230\u7684Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u4e0e\u79d1\u7434\u9ed1\uff08KF\uff09\u4e00\u8d77\u8fdb\u884c\u77ed\u65f6\u95f4\u7684\u7403\u78e8\uff0c\u8be5\u8fc7\u7a0b\u4e0d\u4ec5\u53ef\u4ee5\u5c06Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u8fdb\u884c\u7eb3\u7c73\u5316\uff0c\u8fd8\u53ef\u4ee5\u5728\u5b83\u8868\u9762\u5305\u8986\u4e00\u5c42\u9ad8\u5ea6\u77f3\u58a8\u5316\u7684\u78b3\u3002\u6700\u4f18\u7684Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\/KF\u590d\u5408\u6750\u6599\u53ef\u4ee5\u57280.5 C\u7684\u65f6\u5019\u653e\u51fa138 mAh g-1<\/sup>\u7684\u521d\u59cb\u5bb9\u91cf\uff0c\u5b83\u572840 C\u7684\u65f6\u5019\u5bb9\u91cf\u4ecd\u7136\u6709122 mAh g-1<\/sup>\uff08\u56fe16\uff09\u3002\u6b64\u5916\uff0c\u5728\u4f7f\u7528100 ml\u805a\u56db\u6c1f\u4e59\u70ef\u5185\u886c\u8fdb\u884c\u6eb6\u5242\u70ed\u53cd\u5e94\u65f6\uff0cV\u6e90\u7684\u52a0\u5165\u91cf\u53ef\u4ee5\u9ad8\u8fbe80 mmol\uff0c\u8fd9\u4e48\u9ad8\u7684\u5242\u91cf\u8fd8\u662f\u9996\u6b21\u5b9e\u73b0\u3002\u8003\u8651\u5230\u539f\u6599\u548c\u80fd\u8017\u7684\u7ecf\u6d4e\u6027\uff0c\u9ad8\u7684\u5242\u91cf\u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0c\u8be5\u201c\u6eb6\u5242\u70ed-\u7403\u78e8\u201d\u65b9\u6cd5\u975e\u5e38\u6709\u5e0c\u671b\u5b9e\u73b0Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u7684\u5927\u89c4\u6a21\u751f\u4ea7\u548c\u5de5\u4e1a\u5316\u5e94\u7528\u3002<\/p>\n

\u56fe15 Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u4e0d\u540c\u5236\u5907\u65b9\u6cd5\u7684\u6bd4\u8f83<\/p>\n

\"\"<\/p>\n

\u56fe16 Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\/KF\u7684\u7535\u5316\u5b66\u6027\u80fd\u53ca\u5236\u5907\u65b9\u6cd5\u6bd4\u8f83<\/p>\n

\"\" \u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n

Nature<\/b><\/strong>\u00a0<\/b><\/strong>energy\uff1a\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u9996\u6b21\u5c55\u9732\u771f\u5bb9\u3002<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u672c\u5f81\u7684\u5b89\u5168\u6027\u548c\u4f4e\u7684\u6210\u672c\uff0c\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\uff08AKIBs\uff09\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7f3a\u4e4f\u5408\u9002\u7684\u7535\u6781\u548c\u7535\u89e3\u6db2\uff0c\u73b0\u5728\u8fd8\u6ca1\u6709\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u7684\u62a5\u9053\u3002\u5728\u672c\u6587\u4e2d\uff0c\u5317\u4eac\u4e2d\u79d1\u9662\u7269\u7406\u6240\u7684\u80e1\u52c7\u80dc<\/b><\/strong>\u56e2\u961f\u9996\u6b21\u6784\u5efa\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60[8]<\/sup>\u3002\u5b83\u7684\u6b63\u6781\u662fFe\u90e8\u5206\u53d6\u4ee3\u7684\u5bccMn\u666e\u9c81\u58eb\u84dd\uff08Kx<\/i><\/sub><\/em>Fey<\/i><\/sub><\/em>Mn1-<\/sub>y<\/i><\/sub><\/em>[Fe(CN)6<\/sub>]w<\/i><\/sub><\/em>\u00b7z<\/i><\/em>H2<\/sub>O\uff0c\u56fe17\uff09\uff0c\u8d1f\u6781\u662f\u6709\u673a3,4,9,10-\u805a\u56db\u7532\u6c27\u57fa\u4e8c\u4e9a\u80fa\uff083,4,9,10-perylenetetracarboxylic diimide\uff09\uff0c\u7535\u89e3\u6db2\u662f22 M\u7684KCF3<\/sub>SO3<\/sub>\u3002\u7531\u4e8eFe\u53ef\u4ee5\u51cf\u7f13\u76f8\u8f6c\u53d8\u7684\u53d1\u751f\uff0cKx<\/i><\/sub><\/em>Fey<\/i><\/sub><\/em>Mn1-<\/sub>y<\/i><\/sub><\/em>[Fe(CN)6<\/sub>]w<\/i><\/sub><\/em>\u00b7z<\/i><\/em>H2<\/sub>O\u6b63\u6781\u5177\u6709\u6781\u597d\u7684\u5faa\u73af\u6027\u80fd\uff0c\u5b83\u5728100 C\u4e0b\u5faa\u73af10000\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u7136\u9ad8\u8fbe70%\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u7531\u4e8e\u4e0d\u5b58\u5728\u81ea\u7531\u6c34\uff0c\u6d53\u7684KCF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u65e2\u5177\u6709\u9ad8\u7684\u7535\u538b\u7a97\u53e3\u53c8\u53ef\u4ee5\u964d\u4f4e\u6b63\u8d1f\u6781\u7684\u6eb6\u89e3\u3002\u8be5\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u53ef\u4ee5\u8868\u73b0\u51fa80 Wh\u00a0kg–<\/sup>1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u800c\u4e14\u53ef\u4ee5\u5728\u4e0d\u540c\u7684\u500d\u7387\uff080.1-20 C\uff09\u548c\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\uff08-20\u523060\u2103\uff09\u8fd0\u884c\u826f\u597d\uff08\u56fe18\uff09\u3002\u8be5\u8bbe\u8ba1\u4e3a\u6c34\u7cfb\u94be\u79bb\u5b50\u5728\u5927\u89c4\u6a21\u7535\u7f51\u50a8\u80fd\u4e2d\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n

\u56fe17 Kx<\/i><\/sub><\/em>Fey<\/i><\/sub><\/em>Mn1-<\/sub>y<\/i><\/sub><\/em>[Fe(CN)6<\/sub>]w<\/i><\/sub><\/em>\u00b7z<\/i><\/em>H2<\/sub>O\u7684XRD\u56fe\u8c31\u548c\u6676\u4f53\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u56fe18 \u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

5 \u5176\u4ed6\u65b0\u578b\u50a8\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

\u5f00\u53d1\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u957f\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u5b89\u5168\u6027\u80fd\u7684\u7535\u6c60\u662f\u4eba\u4eec\u4e00\u76f4\u4ee5\u6765\u7684\u8ffd\u6c42\u3002\u9664\u4e86\u4e0a\u8ff0\u7684\u4f53\u7cfb\uff0c\u4eba\u4eec\u8fd8\u81f4\u529b\u4e8e\u63a2\u7d22\u65b0\u578b\u7535\u6c60\u7cfb\u7edf\uff0c\u6bd4\u5982Li-Te\u7535\u6c60\uff0cCa\u79bb\u5b50\u7535\u6c60\u548cZn\u79bb\u5b50\u7535\u6c60\u7b49<\/p>\n

E<\/b><\/strong>nergy storage materials<\/b><\/strong>\uff1aS\u63ba\u6742\u7684Te\u6784\u5efa\u9ad8\u4f53\u79ef\u6bd4\u5bb9\u91cf\u7684Li-Te\u7535\u6c60\u3002<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

Advanced energy materials<\/b><\/strong>\uff1a\u5ba4\u6e29\u9ad8\u500d\u7387\u957f\u5faa\u73af\u9499\u57fa\u591a\u79bb\u5b50\u7535\u6c60\u3002<\/b><\/strong><\/p>\n

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\u56fe21 \u9499\u57fa\u591a\u79bb\u5b50\u7535\u6c60\u7684\u5145\u653e\u7535\u673a\u7406\u53ca\u5bf9Li+<\/sup>\u52a0\u5165\u91cf\u7684\u4f18\u5316<\/p>\n

\"\"<\/p>\n

\u56fe22 \u9499\u57fa\u591a\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

[1] G.-L. Xu, Q. Liu, K.K.S. Lau, Y. Liu, X. Liu, H. Gao, X. Zhou, M. Zhuang, Y. Ren, J. Li, M. Shao, M. Ouyang, F. Pan, Z. Chen, K. Amine, G. Chen, Building ultraconformal protective layers on both secondary and primary particles of layered lithium transition metal oxide cathodes, Nature Energy, 4 (2019) 484-494.<\/p>\n

[2] J.-N. Zhang, Q. Li, C. Ouyang, X. Yu, M. Ge, X. Huang, E. Hu, C. Ma, S. Li, R. Xiao, W. Yang, Y. Chu, Y. Liu, H. Yu, X.-Q. Yang, X. Huang, L. Chen, H. Li, Trace doping of multiple elements enables stable battery cycling of LiCoO2<\/sub>\u00a0at 4.6\u2009V, Nature Energy, (2019).<\/p>\n

[3] S. Li, H. Wang, J. Cuthbert, T. Liu, J.F. Whitacre, K. Matyjaszewski, A Semiliquid Lithium Metal Anode, Joule, (2019) 1-10.<\/p>\n

[4] J. Wang, W. Huang, A. Pei, Y. Li, F. Shi, X. Yu, Y. Cui, Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy, Nature Energy, (2019).<\/p>\n

[5] W. Xue, Z. Shi, L. Suo, C. Wang, Z. Wang, H. Wang, K.P. So, A. Maurano, D. Yu, Y. Chen, L. Qie, Z. Zhu, G. Xu, J. Kong, J. Li, Intercalation-conversion hybrid cathodes enabling Li\u2013S full-cell architectures with jointly superior gravimetric and volumetric energy densities, Nature Energy, 4 (2019) 374-382.<\/p>\n

[6] Y. Shen, J. Zhang, Y. Pu, H. Wang, B. Wang, J. Qian, Y. Cao, F. Zhong, X. Ai, H. Yang, Effective Chemical Prelithiation Strategy for Building a Silicon\/Sulfur Li-Ion Battery, ACS Energy Letters, (2019) 1717-1724.<\/p>\n

[7] H. Yi, L. Lin, M. Ling, Z. Lv, R. Li, Q. Fu, H. Zhang, Q. Zheng, X. Li, Scalable and Economic Synthesis of High-Performance Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u00a0by a Solvothermal\u2013Ball-Milling Method, ACS Energy Letters, (2019) 1565-1571.<\/p>\n

[8] L. Jiang, Y. Lu, C. Zhao, L. Liu, J. Zhang, Q. Zhang, X. Shen, J. Zhao, X. Yu, H. Li, X. Huang, L. Chen, Y.-S. Hu, Building aqueous K-ion batteries for energy storage, Nature Energy, 4 (2019) 495-503.<\/p>\n

[9] X. Ge, L. Yin, S-doping induced boosted electrochemical redox kinetics in Te1-xSx nanorod cathodes for high volumetric capacity Li-Te batteries, Energy Storage Materials, 20 (2019) 89-97.<\/p>\n

[10] J. Lang, C. Jiang, Y. Fang, L. Shi, S. Miao, Y. Tang, Room-Temperature Rechargeable Ca-Ion Based Hybrid Batteries with High Rate Capability and Long-Term Cycling Life, Advanced Energy Materials, (2019).<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

\u62d2\u7edd\u5e73\u5eb8\uff01\u63d0\u9ad8\u8bba\u6587\u6863\u6b21\u79bb\u4e0d\u5f00\u7684\u7535\u6c60\u539f\u4f4d\uff08in situ\uff09\u7814\u7a76\u6280\u672f<\/a><\/p>\n

\u8fd13\u5e74nature&Science\u4e0a\u5341\u5927\u7535\u6c60\u7814\u7a76\u8bba\u6587\uff1a\u5d14\u5c79\u3001\u738b\u6625\u751f\u7b49\u8bfe\u9898\u7ec4<\/a><\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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