{"id":180747,"date":"2019-07-17T18:05:58","date_gmt":"2019-07-17T10:05:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=180747"},"modified":"2019-07-17T18:05:58","modified_gmt":"2019-07-17T10:05:58","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e9%99%88%e5%86%9b%e9%99%a2%e5%a3%abchem%e5%9f%ba%e4%ba%8e%e8%81%9a%e8%92%bd%e9%86%8c%e9%98%b3%e6%9e%81%e7%9a%84%e5%8f%af%e5%85%85%e7%94%b5%e6%b0%b4%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=180747","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u9648\u519b\u9662\u58ebChem:\u57fa\u4e8e\u805a\u84bd\u918c\u9633\u6781\u7684\u53ef\u5145\u7535\u6c34\u6027\u805a\u5408\u7269-\u7a7a\u6c14\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u6c60\u5b89\u5168\u5728\u7535\u80fd\u5b58\u50a8\u7684\u5927\u89c4\u6a21\u5e94\u7528\u9886\u57df\u662f\u81f3\u5173\u91cd\u8981\u3002\u4e0e\u6709\u673a\u6eb6\u5242\u57fa\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u6c34\u6027\u7535\u6c60\u5177\u6709\u8bf8\u5982\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u4e0d\u53ef\u71c3\u6027\u3001\u5bf9\u73af\u5883\u7a7a\u6c14\u7684\u654f\u611f\u6027\u8f83\u4f4e\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7b49\u72ec\u7279\u7684\u4f18\u70b9\u3002\u6c34\u6027\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u662f\u4ee5\u7a7a\u6c14\u4e2d\u7684\u6c27\u6c14\u4f5c\u4e3a\u6d3b\u6027\u6750\u6599\u4e14\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u56e0\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u9633\u6781\u4fa7\u7684\u679d\u6676\u3001\u949d\u5316\u548c\u8150\u8680\u5bfc\u81f4\u91d1\u5c5e\u9633\u6781\u7684\u5229\u7528\u7387\u8f83\u4f4e\u4e14\u5faa\u73af\u7a33\u5b9a\u6027\u8f83\u5dee\u3002\u56e0\u6b64\uff0c\u7b5b\u9009\u5177\u6709\u826f\u597d\u53ef\u9006\u6027\u548c\u6df1\u5ea6\u5145\u653e\u7535\u80fd\u529b\u7684\u66ff\u4ee3\u9633\u6781\u6750\u6599\u5bf9\u4e8e\u83b7\u5f97\u5177\u6709\u957f\u5faa\u73af\u5bff\u547d\u7684\u6c34\u6027\u7a7a\u6c14\u7535\u6c60\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5171\u8f6d\u918c\u805a\u5408\u7269\u7531\u4e8e\u5177\u6709\u9ad8\u5bb9\u91cf\u3001\u542b\u91cf\u4e30\u5bcc\u3001\u4f4e\u6210\u672c\u548c\u7ed3\u6784\u53ef\u8bbe\u8ba1\u6027\u7684\u4f18\u70b9\u800c\u88ab\u5e7f\u6cdb\u4f5c\u4e3aLi\u6216Na\u79bb\u5b50\u7535\u6c60\u7684\u9634\u6781\u6750\u6599\u3002\u00a0\u918c\u805a\u5408\u7269\u901a\u5e38\u5728\u975e\u6c34\u7535\u89e3\u8d28\u4e2d\u53ef\u63d0\u4f9b2.1\u81f32.8 V\u7684\u53ef\u8c03\u6c27\u5316\u8fd8\u539f\u7535\u538b\u5e73\u53f0\u3002\u7136\u800c\uff0c\u805a\u5408\u7269\u7684\u4f4e\u5bfc\u7535\u6027\u5bfc\u81f4\u542b\u6c34\u7535\u6c60\u7684\u901f\u7387\u635f\u5931\uff0c\u7279\u522b\u662f\uff0c\u5408\u7406\u8bbe\u8ba1\u805a\u5408\u7269\u9633\u6781\u4ee5\u786e\u4fdd\u5176\u4e0e\u50ac\u5316\u7a7a\u6c14\u9634\u6781\u7684\u52a8\u529b\u5b66\u53ef\u6bd4\u6027\u5bf9\u4e8e\u9ad8\u6027\u80fd\u6c34\u6027\u805a\u5408\u7269-\u7a7a\u6c14\u7535\u6c60\u662f\u5fc5\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u9648\u519b\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u6c34\u6027\u805a\u5408\u7269-\u7a7a\u6c14\u7535\u6c60\uff0c\u5176\u4f7f\u7528\u5728\u78b3\u7eb3\u7c73\u7ba1\u4e0a\u539f\u4f4d\u805a\u5408\u7684\u5171\u8f6d\u6709\u673a\u805a\u5408\u7269\u805a\uff081,4-\u84bd\u918c\uff09\uff08P14AQ\uff09\u4f5c\u4e3a\u9633\u6781\u800c\u8d1f\u8f7d\u5728CNT\u4e0a\u7684\u5c16\u6676\u77f3\u94b4\u9530\u6c27\u5316\u7269\uff08CMO@CNT\uff09\u4f5c\u4e3a\u50ac\u5316\u9634\u6781\u3002\u7814\u7a76\u53d1\u73b0\uff0cP14AQ\/CNT-\u7a7a\u6c14\u7535\u6c60\u5177\u6709500\u6b21\u5faa\u73af\u7684\u957f\u5faa\u73af\u5bff\u547d\uff0892%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff09\u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff08147 mAh g-1<\/sup>P14AQ<\/sub>\uff0c38.5 \u00b0C\uff09\u3002\u800c\u4e14\u6240\u5236\u5907\u7684\u888b\u5f0fP14AQ\/CNT-\u7a7a\u6c14\u7535\u6c60\u663e\u793a\u51fa1025 mAh\u7684\u9ad8\u5bb9\u91cf\uff0c\u5728100\u6b21\u5faa\u73af\u540e\u5177\u670995%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff0c\u56e0\u800c\u5c55\u73b0\u51fa\u5927\u89c4\u6a21\u5e94\u7528\u7684\u6f5c\u529b\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Rechargeable Aqueous Polymer-Air Batteries Based on Polyanthraquinone Anode<\/strong>“\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aChem<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u6784\u5efa\u7684P14AQ \/ CNT-\u7a7a\u6c14\u7535\u6c60\u7684\u6784\u9020\u548c\u53cd\u5e94\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2 P14AQ\/CNT\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(A) P14AQ\/CNT\u7684SEM\u548c\u9ad8\u5206\u8fa8HRTEM\u56fe\u50cf\uff1b<\/p>\n

(B) CNT\u3001P14AQ\u548cP14AQ\/CNT C1s\u7684XPS\u5149\u8c31\uff1b<\/p>\n

(C) P14AQ\u548cP14AQ\/CNT\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

(D) CNT\u7684\u4f18\u5316\u6784\u8c61\uff1b<\/p>\n

(E, F) P14AQ\u548cCNT\u6784\u8c61\u7684\u9876(E)\u548c\u524d(F)\u89c6\u56fe\uff1b<\/p>\n

(G, H) P14AQ\u548cCNT\u4e4b\u95f4\u7684\u6a21\u62df\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u7684\u9876(G)\u548c\u524d(H)\u89c6\u56fe\uff1b<\/p>\n

(I) P14AQ\u548cP14AQ\/CNT\u7684DOS\u8ba1\u7b97\u3002<\/p>\n

\u56fe3 P14AQ\u548cCMO@CNT\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(A) P14AQ\u548cP14AQ\/CNT\u57285mV s-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(B) P14AQ\u548cP14AQ\/CNT\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

(C) P14AQ\/CNT\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(D) P14AQ\/CNT\u5bf9\u5e94\u7684log ip<\/sub><\/em>\u4e0elog v\u7684\u5173\u7cfb\uff1b<\/p>\n

(E) P14AQ\/CNT\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

(F) CMO@ CNT\u548cPt\/C\u57286M KOH\u6eb6\u6db2\u4e2d\uff0c10mV s-1<\/sup>\u6761\u4ef6\u4e0b\u7684ORR\u548cOER\u6d3b\u6027\u3002<\/p>\n

\u56fe4 P14AQ\/CNT-\u7a7a\u6c14\u7535\u6c60\u7684\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

(A) 400mA g-1<\/sup>\u6761\u4ef6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(B) \u7528\u4e8e\u539f\u4f4dFTIR\u6d4b\u8bd5\u7684\u888b\u7535\u6c60\u7684\u6a2a\u622a\u9762\u793a\u610f\u56fe\uff1b<\/p>\n

(C) P14AQ\u9633\u6781\u7684\u539f\u4f4d\u76d1\u6d4b\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

(D) P14AQ \/ CNT\u5728\u4e0d\u540c\u72b6\u6001\u4e0b\u7684XPS\u5149\u8c31\u3002<\/p>\n

\u56fe5 \u53ef\u5145\u7535P14AQ\/CNT-\u7a7a\u6c14\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4e0d\u540c\u901f\u7387\u4e0b\u7684\u5178\u578b\u653e\u7535\u548c\u5145\u7535\u66f2\u7ebf\uff1b<\/p>\n

(B) \u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(C) 1 A g-1<\/sup>\u6761\u4ef6\u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

(D) \u888b\u5f0f\u7535\u6c60\u7684GCD\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u6784\u5efa\u4e86\u5177\u6709P14AQ\/CNT\u9633\u6781\u548cCMO@ CNT\u9634\u6781\u7684\u805a\u5408\u7269-\u7a7a\u6c14\u7535\u6c60\u3002\u7814\u7a76\u8868\u660e\uff0c\u5171\u8f6dP14AQ\u805a\u5408\u7269\u4e0e\u4e09\u7ef4\u5bfc\u7535CNT\u4e4b\u95f4\u5b58\u5728\u5f3a\u76f8\u4e92\u4f5c\u7528\u8fdb\u800c\u4fc3\u8fdb\u4e86\u7535\u8377\u4eceP14AQ\u8f6c\u79fb\u81f3CNT\uff0c\u5bfc\u81f4\u7a33\u5b9a\u7684\u5145\u653e\u7535\u72b6\u6001\u548c\u8f83\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u3002\u7531\u4e8eP14AQ\/CNT\u5177\u6709\u826f\u597d\u7684\u53ef\u9006\u6027\u548c\u7a33\u5b9a\u6027\u4ee5\u53caCMO@CNT\u7684\u50ac\u5316\u6027\u80fd\uff0cP14AQ\/CNT-\u7a7a\u6c14\u7535\u6c60\u572838.5 \u00b0C\u65f6\u5c55\u73b0\u51fa147 mAh g-1<\/sup> P14AQ\u7684\u4f18\u5f02\u500d\u7387\u6027\u80fd\u548c\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002\u5bb9\u91cf\u4e3a1025 mAh\u7684\u888b\u5f0f\u7535\u6c60\u53ef\u63d0\u4f9b165 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u800c\u4e14100\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a95%\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aRechargeab Aqueous Polymer-Air Batteries Based on Polyanthraquinone Anode<\/a>\u00a0(Chem, 2019, DOI: 10.1016\/j.chempr.2019.06.001)<\/strong><\/p>\n

 <\/p>\n

\u672c\u6587\u7531biotech\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenkefu\u3002<\/strong>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u6c60\u5b89\u5168\u5728\u7535\u80fd\u5b58\u50a8\u7684\u5927\u89c4\u6a21\u5e94\u7528\u9886\u57df\u662f\u81f3\u5173\u91cd\u8981\u3002\u4e0e\u6709\u673a\u6eb6\u5242\u57fa\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u6c34\u6027\u7535\u6c60\u5177\u6709\u8bf8\u5982\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u4e0d\u53ef\u71c3\u6027\u3001\u5bf9\u73af\u5883\u7a7a\u6c14\u7684\u654f\u611f\u6027\u8f83\u4f4e\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7b49\u72ec\u7279…<\/p>\n","protected":false},"author":7746,"featured_media":180748,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2476,4023],"class_list":["post-180747","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2476","tag-4023"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180747"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7746"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=180747"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180747\/revisions"}],"predecessor-version":[{"id":180767,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180747\/revisions\/180767"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/180748"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=180747"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=180747"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=180747"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}