{"id":180936,"date":"2019-07-22T06:30:58","date_gmt":"2019-07-21T22:30:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=180936"},"modified":"2019-07-21T21:07:33","modified_gmt":"2019-07-21T13:07:33","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%b1%aa%e5%9b%bd%e9%9b%84%e7%a0%94%e7%a9%b6%e5%91%98%e5%92%8c%e5%8c%85%e4%bf%a1%e5%92%8c%e9%99%a2%e5%a3%abam%e7%bb%bc%e8%bf%b0%e5%9b%ba%e4%bd%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=180936","title":{"rendered":"\u6c6a\u56fd\u96c4\u7814\u7a76\u5458\u548c\u5305\u4fe1\u548c\u9662\u58ebAM\u7efc\u8ff0:\u56fa\u4f53\u6c27\u5316\u7269\u7535\u89e3\u6c60\u4e2d\u9ad8\u6e29CO2\u7535\u89e3\u7684\u53d1\u5c55\u3001\u6311\u6218\u4e0e\u5c55\u671b"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5316\u77f3\u71c3\u6599\u7684\u5927\u91cf\u6d88\u8017\uff0c\u5927\u6c14\u4e2d\u7684CO2<\/sub>\u6d53\u5ea6\u4ece1750\u5e74\u7684280 ppm\u8fc5\u901f\u589e\u52a0\u81f32018\u5e74\u7684410 ppm\u3002CO2<\/sub>\u6d53\u5ea6\u7684\u5347\u9ad8\u4f1a\u5bfc\u81f4\u6e29\u5ba4\u6548\u5e94\uff0c\u5e76\u5e26\u6765\u4e25\u91cd\u7684\u73af\u5883\u548c\u751f\u6001\u95ee\u9898\uff0c\u5982\u6d77\u6d0b\u9178\u5316\u3001\u6d77\u5e73\u9762\u4e0a\u5347\u548c\u7269\u79cd\u706d\u7edd\u7b49\u3002\u56e0\u6b64\uff0c\u76ee\u524d\u8feb\u5207\u9700\u8981\u964d\u4f4e\u5927\u6c14\u4e2dCO2<\/sub>\u7684\u6d53\u5ea6\u3002\u9664\u4e86\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u66ff\u4ee3\u5316\u77f3\u71c3\u6599\u5916\uff0c\u4eba\u4eec\u8fd8\u5f00\u53d1\u4e86CO2<\/sub>\u6355\u83b7\u4e0e\u50a8\u5b58(CCS)\u5de5\u827a\u4ee5\u53caCO2<\/sub>\u6355\u83b7\u4e0e\u5229\u7528(CCU)\u5de5\u827a\uff0c\u4ee5\u6709\u6548\u51cf\u5c11\u73b0\u6709\u5927\u6c14\u4e2dCO2<\/sub>\u7684\u6d53\u5ea6\u3002CCS\u5de5\u827a\u901a\u5e38\u6602\u8d35\u4e14\u590d\u6742\uff0c\u540c\u65f6\u9762\u4e34CO2<\/sub>\u6cc4\u6f0f\u7684\u98ce\u9669\uff0c\u800cCCU\u5de5\u827a\u80fd\u591f\u5c06\u6355\u83b7\u7684CO2<\/sub>\u8f6c\u5316\u4e3a\u542b\u78b3\u7684\u589e\u503c\u5316\u5b66\u54c1\u3002\u7136\u800cCO2<\/sub>\u4e2dC=O\u952e\u6bd4\u8f83\u7a33\u5b9a\uff0c\u5c06CO2<\/sub>\u8f6c\u5316\u4e3a\u76ee\u6807\u4ea7\u7269\u56f0\u96be\u3002\u5e38\u89c1\u7684CO2<\/sub>\u8f6c\u5316\u65b9\u6cd5\u6709\u5149\u5408\u4f5c\u7528\u3001\u70ed\u50ac\u5316\u8fd8\u539f\u3001\u7535\u5316\u5b66\u8fd8\u539f\u548c\u5149\u5316\u5b66\u8f6c\u5316\u7b49\u3002\u4e0e\u5176\u4ed6\u65b9\u6cd5\u76f8\u6bd4\uff0c\u7535\u5316\u5b66\u8fd8\u539f\u5177\u6709\u4e00\u4e9b\u7279\u70b9\uff1a1\uff09\u901a\u8fc7\u8c03\u8282\u65bd\u52a0\u7535\u538b\u548c\u53cd\u5e94\u6e29\u5ea6\u53ef\u63a7\u5236\u7535\u5316\u5b66\u8fd8\u539f\u8fc7\u7a0b\u30022\uff09\u8be5\u8fc7\u7a0b\u53ef\u4ee5\u4e0e\u98ce\u80fd\u3001\u592a\u9633\u80fd\u3001\u6c34\u529b\u53d1\u7535\u548c\u5730\u70ed\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u7ed3\u5408\uff0c\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\u63d0\u4f9b\u6709\u6548\u7684\u50a8\u5b58\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662<\/b><\/strong>\u5927\u8fde\u5316\u7269\u6240\u6c6a\u56fd\u96c4\u7814\u7a76\u5458\u548c<\/b><\/strong>\u5305\u4fe1\u548c\u9662\u58eb<\/b><\/strong>\u5728Advanced Materials<\/b><\/strong>\u53d1\u8868\u9898\u4e3a\u201cHigh-Temperature CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects<\/b><\/strong>\u201d\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u56fa\u4f53\u6c27\u5316\u7269\u7535\u89e3\u6c60(Solid Oxide Electrolysis Cell, SOEC)\u5c06CO2<\/sub>\u548cH2<\/sub>O\u8f6c\u5316\u4e3a\u5408\u6210\u6c14\u3001\u70c3\u7c7b\u71c3\u6599\u5e76\u8054\u4ea7\u9ad8\u7eafO2<\/sub>\uff0c\u5177\u6709\u5168\u56fa\u6001\u548c\u6a21\u5757\u5316\u7ed3\u6784\u3001\u53cd\u5e94\u901f\u7387\u5feb\u3001\u80fd\u91cf\u6548\u7387\u9ad8\u4ee5\u53ca\u6210\u672c\u4f4e\u7b49\u4f18\u70b9\uff0c\u5728CO2<\/sub>\u8f6c\u5316\u548c\u53ef\u518d\u751f\u6e05\u6d01\u7535\u80fd\u5b58\u50a8\u65b9\u9762\u8868\u73b0\u51fa\u6781\u5177\u6f5c\u529b\u7684\u5e94\u7528\u524d\u666f\u3002\u8be5\u8fdb\u5c55\u62a5\u544a\u4ecb\u7ecd\u4e86SOEC\u7684\u53d1\u5c55\u5386\u7a0b\u3001CO2<\/sub>\u7535\u89e3\u673a\u7406\u3001SOEC\u7535\u6781\u548c\u7535\u89e3\u8d28\u6750\u6599\uff0c\u63a2\u8ba8\u4e86\u7535\u6781\u7ec4\u6210\u548c\u5fae\u89c2\u7ed3\u6784\u5bf9CO2<\/sub>\u7535\u89e3\u6027\u80fd\u7684\u5f71\u54cd\uff1b\u603b\u7ed3\u4e86SOEC\u7684\u8870\u51cf\u673a\u5236\uff0c\u4ee5\u53ca\u71c3\u6599\u534f\u52a9\u578bSOEC\u548c\u9ad8\u538bSOEC\u7684\u53d1\u5c55\u72b6\u51b5\uff1b\u6700\u540e\u5c55\u671b\u5229\u7528\u539f\u4f4d\u52a8\u6001\u8868\u5f81\u6280\u672f\u7814\u7a76\u7535\u6781\u53cd\u5e94\u673a\u7406\uff0c\u4e3a\u7814\u5236\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u63d0\u4f9b\u6307\u5bfc\uff0c\u540c\u65f6\u901a\u8fc7\u9633\u6781\u8026\u5408\u70f7\u70c3\u8f6c\u5316\u6765\u5b9e\u73b0SOEC\u9ad8\u6548\u751f\u4ea7\u71c3\u6599\u548c\u5316\u5b66\u54c1\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u8868\u4e00\u4e0d\u540c<\/b><\/strong>CO2<\/sub>\u7535\u89e3<\/b><\/strong>\u6c60<\/b><\/strong>\u7684\u5bf9\u6bd4<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u56fe\u4e00<\/b><\/strong>\u9ad8\u6e29<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535<\/b><\/strong>\u89e3<\/b><\/strong>\u7684\u78b3\u4e2d<\/b><\/strong>\u5faa\u73af\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c<\/b><\/strong>\u9ad8\u6e29CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535<\/b><\/strong>\u89e3<\/b><\/strong>\u548cCO<\/b><\/strong>2<\/b><\/sub><\/strong>\/H<\/b><\/strong>2<\/b><\/sub><\/strong>O\u5171<\/b><\/strong>\u7535\u89e3<\/b><\/strong>\u7684\u80fd\u91cf\u9700\u6c42\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09CO2<\/sub>\u7535\u89e3<\/p>\n

\uff08B\uff09CO2<\/sub>\/H2<\/sub>O\u5171\u7535\u89e3<\/p>\n

\uff08C\uff09CO2<\/sub>\/H2<\/sub>O\u5171\u7535\u89e3\u5236CH4<\/sub><\/p>\n

\uff08D\uff09CO2<\/sub>\/H2<\/sub>O\u5171\u7535\u89e3\u5236C2<\/sub>H4<\/sub><\/p>\n

\uff08E\uff09CH4<\/sub>\u8f85\u52a9CO2<\/sub>\/H2<\/sub>O\u5171\u7535\u89e3<\/p>\n

\uff08F\uff09C\u8f85\u52a9CO2<\/sub>\/H2<\/sub>O\u5171\u7535\u89e3<\/p>\n

\u56fe\u4e09\u9499\u949b\u77ff\u76f8\u5173\u6c27\u5316\u7269\u7684\u6676\u4f53\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u56db<\/b><\/strong>\u63d0\u9ad8\u7535\u6781\u50ac\u5316\u6d3b\u6027\u7684\u4e09\u79cd\u65b9\u6cd5<\/b><\/strong><\/p>\n

\"\"\u00a0<\/b><\/strong><\/p>\n

\uff08A\uff09\u6d78\u6e0dCeO2<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684La0.3<\/sub>Sr0.7<\/sub>Ti0.3<\/sub>Fe0.7<\/sub>O3-\u03b4<\/sub>\u9634\u6781SEM\u56fe\u3002<\/p>\n

\uff08B\uff09\u63ba\u6742V\u7684La0.5<\/sub>Sr0.5<\/sub>FeO3-\u03b4<\/sub>\u9634\u6781SEM\u56fe\u3002<\/p>\n

\uff08C\uff09La0.52<\/sub>Sr0.28<\/sub>Ti0.94<\/sub>Ni0.06<\/sub>O3-\u03b4<\/sub>\u539f\u4f4d\u6790\u51faNi\u7eb3\u7c73\u9897\u7c92SEM\u56fe\u3002<\/p>\n

\uff08D\uff09\u6d78\u6e0dCe0.9<\/sub>Mn0.1<\/sub>O2-\u03b4<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684LSCM-GDC\u9634\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\uff08E\uff09\u63ba\u6742V\u7684La0.5<\/sub>Sr0.5<\/sub>FeO3-\u03b4<\/sub>\u9634\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\uff08F\uff09La0.2<\/sub>Sr0.8<\/sub>TiO3\u00b1\u03b4<\/sub>\u539f\u4f4d\u6eb6\u51fa\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e94\u7535\u6781\u9000\u5316\u7684\u4e3b\u8981\u95ee\u9898\u662f\u56e2\u805a\u3001<\/b><\/strong>\u6325\u53d1<\/b><\/strong>\u3001<\/b><\/strong>\u79ef\u78b3<\/b><\/strong>\u3001<\/b><\/strong>\u6bd2\u5316<\/b><\/strong>\u548c<\/b><\/strong>\u7ed3\u6784<\/b><\/strong>\u5206\u89e3<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09Ni\u56e2\u805a<\/p>\n

\uff08B\uff09Ni\u6325\u53d1<\/p>\n

\uff08C\uff09\u79ef\u78b3<\/p>\n

\uff08D\uff09LSC\u9633\u6781\u4e2d\u6bd2<\/p>\n

\uff08E\uff09LSCF\u9633\u6781\u7684\u7ed3\u6784\u5206\u89e3<\/p>\n

\u56fe\u516d\u7535\u89e3\u8d28\u7684<\/b><\/strong>\u5931\u6d3b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e03\u71c3\u6599\u8f85\u52a9SOEC<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A\uff09CH4<\/sub>\u8f85\u52a9SOEC\u7684\u793a\u610f\u56fe<\/p>\n

B\uff09CH4<\/sub>\u767e\u5206\u6bd4\u5bf9CH4<\/sub>\u8f85\u52a9\u7684SOEC\u7684\u7535\u5316\u5b66\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n

C\uff09\u6e29\u5ea6\u5bf9SOEC\u548cCH4<\/sub>\u8f85\u52a9SOEC\u7684\u7535\u5316\u5b66\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n

D\uff09C\u8f85\u52a9SOEC\u7684\u793a\u610f\u56fe<\/p>\n

E\uff09J-V\u66f2\u7ebf\u548cF\uff09\u4f20\u7edfSOEC\u548cC\u8f85\u52a9SOEC\u7684\u80fd\u91cf\u6548\u7387<\/p>\n

\u3010\u6311\u6218\u4e0e\u524d\u666f\u3011<\/b><\/strong><\/p>\n

\u8fc4\u4eca\u4e3a\u6b62\uff0cSOEC\u9762\u4e34\u7684\u6700\u5927\u6311\u6218\u662f\u6027\u80fd\u8870\u51cf\u548c\u6210\u672c\u9ad8\u3002SOEC\u7684\u4f7f\u7528\u5bff\u547d\u5e94\u8fbe\u52305\u4e07\u5c0f\u65f6\uff0c\u624d\u80fd\u4fdd\u6301\u5176\u5728\u5e02\u573a\u4e0a\u7684\u7ade\u4e89\u529b\uff0c\u4f46\u5927\u591a\u6570\u62a5\u9053\u7684SOEC\u7684\u5bff\u547d\u4e0d\u52301\u4e07\u5c0f\u65f6\uff0c\u4e14\u5177\u6709\u660e\u663e\u7684\u8870\u51cf\u901f\u7387\u3002SOEC\u7535\u89e3CO2<\/sub>\u7684\u6210\u672c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u8017\u7535\u91cf\u548c\u7535\u529b\u4ef7\u683c\uff0c\u7535\u529b\u6210\u672c\u5360SOEC\u7535\u89e3CO2<\/sub>\u603b\u6210\u672c\u768480\uff05\u4ee5\u4e0a\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9ad8\u6027\u80fd\u548c\u7a33\u5b9a\u7684SOEC\u964d\u4f4e\u7535\u529b\u6d88\u8017\u5bf9\u63d0\u9ad8\u5176\u7ecf\u6d4e\u7ade\u4e89\u529b\u81f3\u5173\u91cd\u8981\u3002\u4e3a\u4e86\u83b7\u5f97\u5177\u6709\u9ad8\u6027\u80fd\u548c\u4f18\u5f02\u7a33\u5b9a\u6027\u7684SOEC\uff0c\u672a\u6765\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u5229\u7528DFT\u8ba1\u7b97\uff0c\u539f\u4f4d\u7269\u7406\u5316\u5b66\u8868\u5f81\u6280\u672f\u548c\u7535\u5316\u5b66\u8868\u5f81\u76d1\u6d4b\u7535\u6781\u53cd\u5e94\u7684\u57fa\u672c\u8fc7\u7a0b\u548c\u5bff\u547d\u6d4b\u8bd5\u671f\u95f4SOEC\u7684\u8870\u51cf\u8fc7\u7a0b\uff0c\u4e3a\u8fdb\u4e00\u6b65\u63a2\u7d22\u9ad8\u6d3b\u6027\u7535\u6781\u6750\u6599\u63d0\u4f9b\u6307\u5bfc\u3002\uff082\uff09\u901a\u8fc7\u8c03\u8282\u53cc\u9499\u949b\u77ff\u6c27\u5316\u7269\uff0cRuddlesden-Popper\u76f8\u548c\u5176\u4ed6\u7ed3\u6784\u4ee5\u53ca\u5229\u7528\u975e\u5316\u5b66\u8ba1\u91cf\u6765\u5f15\u5165\u6d3b\u6027\u754c\u9762\uff0c\u4ee5\u589e\u5f3a\u6750\u6599\u6027\u80fd\u8fdb\u800c\u4fc3\u8fdb\u7535\u5316\u5b66\u53cd\u5e94\u3002\uff083\uff09\u901a\u8fc7\u5c06\u7532\u70f7\u6c27\u5316\u5076\u8054\u3001\u4f4e\u78b3\u70f7\u70c3\u6c27\u5316\u8131\u6c22\u3001\u7532\u70f7\u82b3\u6784\u5316\u6216\u5176\u4ed6\u6709\u4ef7\u503c\u7684\u5316\u5b66\u53cd\u5e94\u8026\u5408\u5230SOEC\u9633\u6781\uff0c\u5b9e\u73b0SOEC\u591a\u529f\u80fd\u5316\uff0c\u8fd9\u4e0d\u4ec5\u53ef\u4ee5\u4fc3\u8fdb\u9634\u6781CO2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\uff0c\u800c\u4e14\u80fd\u591f\u5145\u5206\u5229\u7528\u9633\u6781\u4ea7\u751f\u7684\u6c27\u7269\u79cd\u5b9e\u73b0\u70f7\u70c3\u9ad8\u6548\u8f6c\u5316\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>High-Temperature CO<\/b><\/u><\/strong>2<\/b><\/sub><\/u><\/strong>\u00a0Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects<\/b><\/u><\/strong><\/a>\u201d(<\/b><\/strong>Adv. Mater. 201<\/b><\/strong>9<\/b><\/strong>,<\/b><\/strong>DOI: 10.1002\/adma.201902033<\/b><\/strong>)<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu \u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7eb3\u7c73\u4e0e\u754c\u9762\u50ac\u5316\u7814\u7a76\u56e2\u961f\uff0c\u957f\u671f\u81f4\u529b\u4e8e\u80fd\u6e90\u548c\u50ac\u5316\u76f8\u5173\u7684\u57fa\u7840\u548c\u5e94\u7528\u57fa\u7840\u7814\u7a76\u3002\u5728\u5305\u4fe1\u548c\u9662\u58eb\u7684\u5e26\u9886\u4e0b\uff0c\u56e2\u961f\u4ece\u7eb3\u7c73\u4f53\u7cfb\u7684\u57fa\u672c\u539f\u7406\u548c\u7eb3\u7c73\u6750\u6599\u7684\u57fa\u672c\u7279\u6027\u51fa\u53d1\uff0c\u7cfb\u7edf\u7814\u7a76\u4e86\u7eb3\u7c73\u9650\u57df\u4f53\u7cfb\u4e2d\u50ac\u5316\u5242\u6d3b\u6027\u4e2d\u5fc3\u7684\u7ed3\u6784\u3001\u7535\u5b50\u7279\u6027\u548c\u50ac\u5316\u6027\u80fd\u7684\u63a7\u5236\u89c4\u5f8b\uff0c\u5728\u56fd\u9645\u4e0a\u7387\u5148\u63d0\u51fa\u4e86\u201c\u7eb3\u7c73\u9650\u57df\u50ac\u5316\u201d\u7684\u6982\u5ff5\uff0c\u5e76\u62d3\u5c55\u5230\u4e8c\u7ef4\u754c\u9762\u9650\u57df\u548c\u4e09\u7ef4\u6676\u683c\u9650\u57df\u50ac\u5316\u4f53\u7cfb\u3002\u4ee5\u6b64\u6982\u5ff5\u4e3a\u6307\u5bfc\uff0c\u521b\u5236\u4e86\u7164\u57fa\u5408\u6210\u6c14\u76f4\u63a5\u8f6c\u5316\u5236\u70ef\u70c3\u548c\u5929\u7136\u6c14\u76f4\u63a5\u9ad8\u503c\u5316\u5229\u7528\u7b49\u65b0\u50ac\u5316\u4f53\u7cfb\u548c\u65b0\u50ac\u5316\u8fc7\u7a0b\uff0c\u4e3a\u6211\u56fd\u5316\u77f3\u8d44\u6e90\u7684\u6e05\u6d01\u3001\u9ad8\u6548\u5229\u7528\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002\u56e2\u961f\u5728\u300a\u79d1\u5b66\u300b\uff08Science\uff09\u548c\u300a\u81ea\u7136\u300b\uff08Nature\uff09\u7cfb\u5217\u7b49\u672c\u9886\u57df\u7684\u91cd\u8981\u5b66\u672f\u671f\u520a\u53d1\u8868\u7814\u7a76\u8bba\u6587600\u591a\u7bc7\uff0c\u7533\u62a5\u53d1\u660e\u4e13\u5229140\u591a\u4ef6\uff0c\u5176\u4e2d\u56fd\u5916\u4e13\u522920\u4ef6\uff0c\u4e2d\u56fd\u4e13\u5229\u53d6\u5f97\u6388\u674360\u4f59\u4ef6\uff1b\u91cd\u8981\u6210\u679c\u5148\u540e\u5165\u90092014\u5e74\u5ea6\u548c2016\u5e74\u5ea6\u4e2d\u56fd\u79d1\u5b66\u5341\u5927\u8fdb\u5c55\u3002\u5305\u4fe1\u548c\u9662\u58eb\u5148\u540e\u83b7\u5f97\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3001\u4e2d\u79d1\u9662\u6770\u51fa\u6210\u5c31\u5956\u3001\u4e2d\u56fd\u5316\u5b66\u4f1a-\u4e2d\u56fd\u77f3\u6cb9\u5316\u5de5\u80a1\u4efd\u6709\u9650\u516c\u53f8\u5316\u5b66\u8d21\u732e\u5956\u3001\u56fd\u9645\u5929\u7136\u6c14\u8f6c\u5316\u6770\u51fa\u6210\u5c31\u5956\u3001\u5fb7\u56fdAlwin Mittasch\u50ac\u5316\u6210\u5c31\u5956\u7b49\u5956\u52b1\uff0c\u6240\u5e26\u9886\u7684\u7814\u7a76\u56e2\u961f\u83b7\u5f97\u9996\u5c4a\u5168\u56fd\u201c\u521b\u65b0\u4e89\u5148\u5956\u724c\u201d\u3002\u56e2\u961f\u6ce8\u91cd\u6559\u7814\u76f8\u7ed3\u5408\uff0c\u4e3a\u6211\u56fd\u57f9\u517b\u3001\u8f93\u9001\u4e86\u5927\u6279\u4f18\u79c0\u5316\u5b66\u4eba\u624d\u3002<\/p>\n

\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/p>\n

\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u56e2\u961f\u4ece\u50ac\u5316\u57fa\u7840\u89d2\u5ea6\u5f00\u5c55\u4e86\u6709\u7279\u8272\u548c\u6df1\u5165\u7cfb\u7edf\u7684CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u7814\u7a76\uff0c\u53d1\u5c55\u4e86\u65b0\u578b\u9ad8\u6548\u7eb3\u7c73\u7535\u50ac\u5316\u6750\u6599\uff0c\u663e\u8457\u63d0\u9ad8\u4e86CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u7684\u9009\u62e9\u6027\u3001\u6d3b\u6027\u548c\u7a33\u5b9a\u6027[<\/sup>1<\/sup>-6]<\/sup>\u3002\u6211\u4eec\u7cfb\u7edf\u7814\u7a76\u4e86CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u4e2d\u7eb3\u7c73Pd\u7684\u6d3b\u6027\u4f4d\u3001\u6d3b\u6027\u76f8\u53ca\u7535\u5316\u5b66\u589e\u5f3a\u50ac\u5316\u6548\u5e94[<\/sup>1<\/sup>-5]<\/sup>\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u6211\u4eec\u7ed3\u5408\u6a21\u578b\u8868\u9762\u7814\u7a76\u548c\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86Au-CeOx<\/sub>\u754c\u9762\u4fc3\u8fdbCO2<\/sub>\u5438\u9644\u548c\u7a33\u5b9a\u53cd\u5e94\u4e2d\u95f4\u4f53\uff0c\u663e\u8457\u63d0\u9ad8\u4e86CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u6d3b\u6027\u548c\u9009\u62e9\u6027[6]<\/sup>\u3002\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3\u50ac\u5316\u5242[7-10]<\/sup>\uff0cFe-N\u6d3b\u6027\u4f4d\u80fd\u591f\u5728\u8f83\u4f4e\u7535\u52bf\u4e0b\u5c06CO2<\/sub>\u7535\u8fd8\u539f\u4e3aCO\uff0c\u6700\u9ad8\u6cd5\u62c9\u7b2c\u6548\u7387\u8fbe\u523093.0%\uff0c\u4f46\u968f\u8fc7\u7535\u52bf\u5347\u9ad8CO\u6cd5\u62c9\u7b2c\u6548\u7387\u8fc5\u901f\u964d\u4f4e[9]<\/sup>\u3002Ni-N\u6d3b\u6027\u4f4d\u5728-0.53 V~-1.03 V\u4e4b\u95f4\u8868\u73b0\u51fa92.0%~98.0%\u7684CO\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\u751f\u6210CO\u7684\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523071.5 \u00b1 2.9 mA cm-2<\/sup>\uff0c\u6253\u7834\u4e86\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3\u50ac\u5316\u5242\u4e0aCO2<\/sub>\u7535\u8fd8\u539f\u9009\u62e9\u6027\u548c\u53cd\u5e94\u901f\u7387\u7684\u201c\u8df7\u8df7\u677f\u201d\u6548\u5e94\u9650\u5236[10]<\/sup>\u3002<\/p>\n

\u56e2\u961f\u8fd1\u671f\u81f4\u529b\u4e8e\u9ad8\u6e29CO2<\/sub>\u7535\u89e3\u7814\u7a76[11, 12]<\/sup>\u3002\u901a\u8fc7\u6d78\u6e0d\u548c\u539f\u4f4d\u8fd8\u539f\u624b\u6bb5\u6784\u5efa\u4e86\u4e00\u7cfb\u5217\u91d1\u5c5e-\u6c27\u5316\u7269\u754c\u9762\u7ed3\u6784\uff0c\u540c\u65f6\u5f62\u6210\u5927\u91cf\u6c27\u7a7a\u4f4d\uff0c\u6709\u6548\u589e\u5f3a\u4e86\u9634\u6781CO2<\/sub>\u5728\u9ad8\u6e29\u4e0b\u7684\u5438\u9644\u6d3b\u5316\u548c\u9633\u6781\u6c27\u6790\u51fa\u53cd\u5e94\uff0c\u663e\u8457\u63d0\u9ad8\u4e86CO2<\/sub>\u7535\u89e3\u6027\u80fd\u3002\u7ed3\u5408\u7535\u5316\u5b66\u4ea4\u6d41\u963b\u6297\u8c31\u3001\u7535\u5316\u5b66\u539f\u4f4d\u8fd1\u5e38\u538bXPS\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u63ed\u793a\u4e86\u5728SOEC\u9634\u6781\uff0c\u754c\u9762\u7ed3\u6784\u4e3b\u8981\u4fc3\u8fdbCO2<\/sub>\u7684\u5438\u9644\u548c\u89e3\u79bb\uff1b\u5728SOEC\u9633\u6781\uff0c\u754c\u9762\u7ed3\u6784\u4fc3\u8fdb\u6c27\u7269\u79cd\u4ece\u6c27\u5316\u7269\u5411\u91d1\u5c5e\u8868\u9762\u6ea2\u6d41\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/p>\n

[1] D. F. Gao, H. Zhou, G. X. Wang, J. G. Wang, X. H. Bao, et al., J. Am. Chem. Soc.<\/i><\/em>, 2015, 137, 4288.<\/p>\n

[2] Z. Yin, D. F. Gao, G. X. Wang, D. Ma, X. H. Bao, et al., Nano Energy<\/i><\/em>, 2016, 27, 35.<\/p>\n

[3] D. F. Gao, H. Zhou, F. Cai, J. G. Wang, G. X. Wang, X. H. Bao, et al., Nano Research<\/i><\/em>, 2017, 10, 2181.<\/p>\n

[4] F. Cai, D. F. Gao, G. X. Wang, X. H. Bao, et al., Chem. Sci.<\/i><\/em>, 2017, 8, 2569.<\/p>\n

[5] D. F. Gao, G. X. Wang, X. H. Bao, ACS <\/i><\/em>Catal<\/i><\/em>.<\/i><\/em>, 2018, 8, 1510.<\/p>\n

[6] D. F. Gao, Y. Zhang, Z. W. Zhou, F. Yang, G. X. Wang, X. H. Bao, et al., J. Am. Chem. Soc.<\/i><\/em>, 2017, 139, 5652.<\/p>\n

[7] H. H. Wu, H. B. Li, G. X. Wang, X. H. Bao, et al., Energy Environ. Sci.<\/i><\/em>, 2016, 9, 3736.<\/p>\n

[8] Y. F. Ye, H. B. Li, G. X. Wang, X. H. Bao, et al.,\u00a0ACS <\/i><\/em>Catal<\/i><\/em>.<\/i><\/em>, 2017, 7, 7638.<\/p>\n

[9] Y. F. Ye, F. Cai, G. X. Wang, Y. S. Li, X. H. Bao, et al., Nano Energy<\/i><\/em>, 2017, 38, 281.<\/p>\n

[10] C. C. Yan, H. B. Li, G. X. Wang, X. H. Bao, et al.<\/i><\/em>,\u00a0Energy Environ. <\/i><\/em>Sci.<\/i><\/em>, 2018, 11,\u00a01204.<\/p>\n

[11] Y. F. Song, S. Zhou, Q. Dong, G. X. Wang, X. H. Bao, et al.,<\/i><\/em>\u00a0Angew<\/i><\/em>. <\/i><\/em>Chem. Int. Ed.<\/i><\/em>, 2019, 58,\u00a04617.<\/p>\n

[12] Y. F. Song, X. M. Zhang, K. Xie, G. X. Wang,\u00a0X. H. Bao, Adv. Mater.<\/i><\/em>, 2019, 1902033.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u5316\u77f3\u71c3\u6599\u7684\u5927\u91cf\u6d88\u8017\uff0c\u5927\u6c14\u4e2d\u7684CO2\u6d53\u5ea6\u4ece1750\u5e74\u7684280 ppm\u8fc5\u901f\u589e\u52a0\u81f32018\u5e74\u7684410 ppm\u3002CO2\u6d53\u5ea6\u7684\u5347\u9ad8\u4f1a\u5bfc\u81f4\u6e29\u5ba4\u6548\u5e94\uff0c\u5e76\u5e26\u6765\u4e25\u91cd…<\/p>\n","protected":false},"author":7084,"featured_media":180947,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[18],"class_list":["post-180936","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-xinnengyuan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180936"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=180936"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180936\/revisions"}],"predecessor-version":[{"id":181115,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/180936\/revisions\/181115"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/180947"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=180936"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=180936"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=180936"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}