{"id":181940,"date":"2019-07-30T06:30:06","date_gmt":"2019-07-29T22:30:06","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=181940"},"modified":"2019-07-29T11:44:15","modified_gmt":"2019-07-29T03:44:15","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6adv-energy-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e4%bb%8b%e8%b4%a8%e6%9d%90%e6%96%99%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=181940","title":{"rendered":"\u82cf\u5dde\u5927\u5b66&\u6e05\u534e\u5927\u5b66Adv. Energy Mater.\u7efc\u8ff0\uff1a\u4ecb\u8d28\u6750\u6599\u7684\u8bbe\u8ba1\u5bf9\u9502\u786b\u5316\u5b66\u7684\u7535\u50ac\u5316\u4f5c\u7528\uff1a\u8fdb\u5c55\u548c\u524d\u666f"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff082600 Wh\u00b7kg-1<\/sup>\uff09\u548c\u7406\u8bba\u6bd4\u5bb9\u91cf(1672 mAh\u00b7g-1<\/sup>)\uff0c\u9502\u786b\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u5148\u8fdb\u7684\u50a8\u80fd\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u4e0e\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0c\u9502\u786b\u7535\u6c60\u7684\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e0d\u4ec5\u6d89\u53ca\u4e86\u9502\u79bb\u5b50\u7684\u8131\u5d4c\uff0c\u800c\u4e14\u8fd8\u5177\u6709\u591a\u6b65\u590d\u6742\u7684\u7269\u76f8\u6f14\u53d8\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u5316\u8fdb\u7a0b\u53d7\u5230\u4e86\u8bf8\u591a\u65b9\u9762\u7684\u6311\u6218\uff0c\u4e3b\u8981\u5305\u62ec\u4e86\u591a\u786b\u5316\u9502\u7684\u7a7f\u68ad\u6548\u5e94\u548c\u7f13\u6162\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u8fd9\u4e9b\u6311\u6218\u9020\u6210\u6d3b\u6027\u6750\u6599\u786b\u7684\u4e0d\u53ef\u9006\u635f\u5931\uff0c\u786b\u7684\u5229\u7528\u6548\u7387\u964d\u4f4e\uff0c\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u4e0b\u964d\u3002\u57fa\u4e8e\u4e0a\u8ff0\u79d1\u5b66\u548c\u5e94\u7528\u95ee\u9898\uff0c\u6709\u6548\u6291\u5236\u591a\u786b\u5316\u9502\u7a7f\u68ad\uff0c\u5408\u7406\u5316\u9502\u786b\u4f53\u7cfb\u7684\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u5bf9\u6539\u5584\u7535\u6c60\u7684\u5bb9\u91cf\u548c\u5faa\u73af\u5bff\u547d\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u5b59\u9756\u5b87\u6559\u6388\u548c\u6e05\u534e\u5927\u5b66\u5f20\u5f3a\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u56e2\u961f\u603b\u7ed3\u4e86\u8fd1\u671f\u9502\u786b\u5316\u5b66\u4e2d\u50ac\u5316\u4ecb\u8d28\u6750\u6599\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u65e8\u5728\u6df1\u5165\u7406\u89e3\u591a\u786b\u5316\u9502\u7684\u6f14\u53d8\u673a\u7406\uff0c\u6307\u5bfc\u5408\u7406\u7684\u4f53\u7cfb\u8bbe\u8ba1\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u80fd\u91cf\u957f\u5bff\u547d\u7684\u9502\u786b\u7535\u6c60\u3002\u7efc\u8ff0\u5bf9\u9502\u786b\u5316\u5b66\u4e2d\u7684\u7535\u50ac\u5316\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u8ba8\u8bba\uff0c\u4ece\u201c\u754c\u9762\u5de5\u7a0b\u8bbe\u8ba1\u201d\u3001\u201c\u6d3b\u6027\u6750\u6599\u5f15\u5165\u201d\u548c\u201c\u53cc\u50ac\u5316\u673a\u5236\u6784\u5efa\u201d\u4e09\u4e2a\u65b9\u9762\u603b\u7ed3\u4e86\u8fd1\u671f\u50ac\u5316\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u540c\u65f6\u8fd8\u5bf9\u4ecb\u8d28\u6750\u6599\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\u8fdb\u884c\u4e86\u5c55\u671b\u3002\u8be5\u7efc\u8ff0\u4e0d\u4ec5\u52a0\u6df1\u4e86\u5bf9\u591a\u786b\u5316\u9502\u6f14\u53d8\u548c\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u7684\u6df1\u5165\u7406\u89e3\uff0c\u800c\u4e14\u8fd8\u4e3a\u8bbe\u8ba1\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u6750\u6599\uff0c\u5b9e\u73b0\u591a\u786b\u5316\u9502\u7684\u6709\u6548\u7ba1\u7406\uff0c\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u7684\u5408\u7406\u5316\u63d0\u4f9b\u4e86\u8fdb\u4e00\u6b65\u7684\u6307\u5bfc\u3002\u76f8\u5173\u7efc\u8ff0\u4ee5\u201cRationalizing Electrocatalysis of Li\u2013S Chemistry by Mediator Design: Progress and Prospects\u201d\u4e3a\u9898\u53d1\u8868\u5728Adv. Energy Mater.\u4e0a\u3002\u8bba\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5b8b\u82f1\u6cfd\u535a\u58eb\u3001\u8521\u6587\u9f99\u535a\u58eb\u548c\u5b54\u9f99\u535a\u58eb\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 \u00a0<\/strong>\u9502\u786b\u5316\u5b66\u4e2d\u591a\u786b\u5316\u9502\u7684\u6f14\u53d8\u673a\u5236<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2\u00a0 <\/strong>\u6a21\u677f\u6cd5\u5408\u6210\u4ecb\u8d28\u6750\u6599\u5e76\u7528\u4e8e\u9502\u786b\u4f53\u7cfb\u6027\u80fd\u6269\u5c55<\/strong><\/p>\n

\"\"a) \u4ee5\u78b3\u7403\u4e3a\u6a21\u677f\u5408\u6210\u591a\u5b54VN\u5e76\u7528\u4e8e\u786b\u6b63\u6781\u8bbe\u8ba1\uff1b<\/p>\n

b) \u4ee5\u7845\u85fb\u571f\u4e3a\u6a21\u677f\u5408\u6210\u591a\u7ea7\u5b54\u9053\u6c2e\u63ba\u77f3\u58a8\u70ef\u5e76\u7528\u4e8e\u529f\u80fd\u9694\u5c42\u8bbe\u8ba1\u3002<\/p>\n

\u56fe<\/strong>3 \u00a0\u201cGoldilocks\u201d<\/strong>\u51c6\u5219\u7528\u4e8e\u63cf\u8ff0\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e0e\u591a\u786b\u5316\u9502\u7684\u53cd\u5e94\u673a\u5236<\/strong><\/p>\n

\"\"a) \u9002\u7528\u4e8e\u201cGoldilocks\u201d\u51c6\u5219\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e0e\u591a\u786b\u5316\u9502\u7684\u4f5c\u7528\u673a\u5236\uff1b<\/p>\n

b) \u9002\u7528\u4e8e\u201cGoldilocks\u201d\u51c6\u5219\u7684VO2<\/sub>\u5bf9\u591a\u786b\u5316\u9502\u7684\u8d85\u5feb\u5438\u9644\u884c\u4e3a\u3002<\/strong><\/p>\n

\u56fe<\/strong>4 \u00a0Li2<\/sub>S<\/strong>\u7684\u6210\u6838\u673a\u5236<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5\u00a0 \u201cVO2<\/sub>-VN\u201d<\/strong>\u754c\u9762\u5bf9\u591a\u786b\u5316\u9502\u7684\u7ba1\u7406\u53ca\u7535\u5316\u5b66\u53cd\u5e94\u7684\u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6\u00a0 \u201cGraphene-V2<\/sub>O3<\/sub>\u201d<\/strong>\u754c\u9762\u5bf9\u591a\u786b\u5316\u9502\u7684\u7ba1\u7406\u53ca\u7535\u5316\u5b66\u53cd\u5e94\u7684\u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7\u00a0 <\/strong>\u6d3b\u6027\u6750\u6599\u5f15\u5165\u5bf9\u591a\u786b\u5316\u9502\u7684\u7ba1\u7406\u53ca\u7535\u5316\u5b66\u53cd\u5e94\u7684\u8c03\u63a7\u4f5c\u7528<\/strong><\/p>\n

\"\"a) 3D\u6c2e\u63ba\u77f3\u58a8\u70ef\/TiN\u5bf9\u9502\u786b\u4f53\u7cfb\u7535\u5316\u5b66\u53cd\u5e94\u7684\u8c03\u63a7\u4f5c\u7528<\/p>\n

b) MoN-VN\u5bf9\u9502\u786b\u4f53\u7cfb\u7535\u5316\u5b66\u53cd\u5e94\u7684\u8c03\u63a7\u4f5c\u7528<\/p>\n

\u56fe<\/strong>8 \u00a0\u201c<\/strong>\u53cc\u50ac\u5316<\/strong>\u201d<\/strong>\u673a\u5236\u7528\u4e8e\u5408\u7406\u5316\u9502\u786b\u4f53\u7cfb\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b<\/strong><\/p>\n

\"\"a) Co-N-GC\u5bf9\u9502\u786b\u5316\u5b66\u7684\u50ac\u5316\u4f5c\u7528\uff1b<\/p>\n

b) HPTCF\u5bf9\u9502\u786b\u5316\u5b66\u7684\u50ac\u5316\u4f5c\u7528\uff1b<\/p>\n

c) \u6c27\u7f3a\u9677WO3-x<\/sub>\u5bf9\u9502\u786b\u5316\u5b66\u7684\u50ac\u5316\u4f5c\u7528\uff1b<\/p>\n

d) Co-N\/G\u5bf9\u9502\u786b\u5316\u5b66\u7684\u50ac\u5316\u4f5c\u7528\uff1b<\/p>\n

e) Tandem-RM\u5bf9\u9502\u786b\u5316\u5b66\u7684\u50ac\u5316\u4f5c\u7528\u3002<\/p>\n

\u56fe<\/strong>9\u00a0 <\/strong>\u9ad8\u6d3b\u6027\u50ac\u5316\u6750\u6599\u5bf9\u9502\u786b\u4f53\u7cfb\u7535\u5316\u5b66\u53cd\u5e94\u7684\u4f5c\u7528\u673a\u5236<\/strong><\/p>\n

\"\"\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u6ede\u7f13\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u9650\u5236\u4e86\u9502\u786b\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u53d1\u6325\uff0c\u963b\u788d\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u8fdb\u7a0b\u3002\u5728\u8fd9\u65b9\u9762\uff0c\u50ac\u5316\u6750\u6599\u8bbe\u8ba1\u6709\u5229\u4e8e\u5408\u7406\u5316\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\uff0c\u63d0\u5347\u7535\u6c60\u7684\u6027\u80fd\uff0c\u662f\u4e00\u79cd\u5408\u7406\u548c\u6709\u6f5c\u529b\u7684\u7814\u7a76\u7b56\u7565\u3002\u7136\u800c\uff0c\u4e3a\u4e86\u66f4\u597d\u5730\u5e94\u5bf9\u9502\u786b\u4f53\u7cfb\u7684\u79d1\u5b66\u548c\u5e94\u7528\u95ee\u9898\uff0c\u66f4\u591a\u6709\u6548\u7684\u7b56\u7565\u7684\u63d0\u51fa\u548c\u53d1\u5c55\u9700\u8981\u7ecf\u8fc7\u957f\u671f\u7684\u673a\u7406\u7406\u89e3\u548c\u73b0\u5b9e\u5e94\u7528\u63a2\u7d22\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Rationalizing Electrocatalysis of Li\u2013S Chemistry by Mediator Design: Progress and Prospects (Adv. Energy Mater.<\/em><\/strong> 2019, DOI: 10.1002\/aenm.201901075)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8bd1\u6574\u7406\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u5b59\u9756\u5b87\u6559\u6388\u4fee\u6b63\u7a3f\u4ef6\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>cailiaokefu<\/strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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