{"id":182111,"date":"2019-08-29T06:30:14","date_gmt":"2019-08-28T22:30:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=182111"},"modified":"2019-08-28T10:41:30","modified_gmt":"2019-08-28T02:41:30","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%a5%bc%e9%9b%84%e6%96%87%e6%95%99%e6%8e%88%e8%83%a1%e5%8b%87%e6%95%99%e6%8e%88angew-chem-int-ed-%ef%bc%9a%e6%9e%84%e5%bb%bacoo-co-cu-s%e5%a4%9a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=182111","title":{"rendered":"\u697c\u96c4\u6587\u6559\u6388&\u80e1\u52c7\u6559\u6388Angew. Chem. Int. Ed.\uff1a\u6784\u5efaCoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7528\u4e8e\u6df7\u5408\u578b\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u591a\u7ea7\u4e2d\u7a7a\u7ed3\u6784\u80fd\u589e\u5927\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u52a0\u5feb\u79bb\u5b50\u548c\u7535\u5b50\u7684\u4f20\u8f93\uff0c\u5bb9\u7eb3\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u6b64\u5916\uff0c\u5f02\u8d28\u7ed3\u6784\u7684\u6784\u5efa\u4f1a\u589e\u5f3a\u5185\u90e8\u7535\u573a\uff0c\u8c03\u8282\u7535\u5b50\u7ed3\u6784\u3002\u591a\u7ea7\u4e2d\u7a7a\u5f02\u8d28\u7ed3\u6784\u7684\u8fd9\u4e9b\u7279\u5f81\u6709\u5229\u4e8e\u6539\u5584\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u7684\u697c\u96c4\u6587\u6559\u6388\u548c\u6d59\u6c5f\u5e08\u8303\u5927\u5b66\u7684\u80e1\u52c7\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5728Angew. Chem. Int. Ed.<\/em>\u4e0a\u62a5\u9053\u4e86\u901a\u8fc7\u591a\u6b65\u6cd5\u5236\u5907\u4e86\u591a\u5b54\u7684CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3002\u6b64CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7531\u4e8e\u5177\u6709\u72ec\u7279\u4e2d\u7a7a\u7ed3\u6784\u548c\u534f\u540c\u6548\u5e94\uff0c\u8868\u73b0\u51fa\u51fa\u8272\u7684\u7535\u5316\u5b66\u50a8\u80fd\u6027\u80fd\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2.0 A g-1<\/sup>\u65f6\u6bd4\u5bb9\u91cf\u9ad8\u8fbe320 mAh g-1<\/sup>\uff0c\u6b64\u6750\u6599\u5177\u6709\u7a81\u51fa\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u7531CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7535\u6781\u548c\u6d3b\u6027\u78b3\u7535\u6781\u7ec4\u6210\u7684\u6df7\u5408\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a800 W kg-1<\/sup>\u65f6\u5177\u670990.7 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u5e76\u8868\u73b0\u51fa\u957f\u671f\u7a33\u5b9a\u6027\u3002\u8fd9\u4e9b\u51fa\u8272\u7684\u6027\u80fd\u4f7f\u5f97CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u5728\u50a8\u80fd\u5e94\u7528\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u5e7f\u9614\u524d\u666f\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1. CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe2. FESEM\u56fe<\/p>\n

\"\"<\/p>\n

(a) PAN-Co(Ac)2<\/sub>\/Cu(NO3<\/sub>)2<\/sub>\u7eb3\u7c73\u7ea4\u7ef4<\/p>\n

(b) PAN@MOF-74\u6838-\u58f3\u7eb3\u7c73\u7ea4\u7ef4\uff08\u63d2\u56fe\u4e3a\u9ad8\u5206\u8fa8\u7387FESEM\u56fe\uff09<\/p>\n

(c) Co-Cu-O\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\uff08\u63d2\u56fe\u4e3a\u9ad8\u5206\u8fa8\u7387FESEM\u56fe\uff09<\/p>\n

(d) CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784<\/p>\n

\u56fe3. CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(a) TEM\u56fe<\/p>\n

(b) HRTEM\u56fe<\/p>\n

(c) Cu\u3001Co\u3001S\u548cO\u5143\u7d20\u7684\u5143\u7d20\u5206\u5e03\u56fe<\/p>\n

\u56fe4. CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3001CoO\/CoSx<\/sub>\u7eb3\u7c73\u7ea4\u7ef4\u548cCu1.81<\/sub>S\u7eb3\u7c73\u7ea4\u7ef4\u7684 (a) Co 2p\u3001(b) Cu 2p\u3001(c) O 1s\u548c (d) S 2p\u7684XPS\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe5. CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3001CoO\/Co-Cu-S-1\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3001CoO\/Co-Cu-S-0.5\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3001CoO\/Co-Cu-S-2\u7eb3\u7c73\u9488\u3001CoO\/CoSx<\/sub>\u7eb3\u7c73\u7ea4\u7ef4\u548cCu1.81<\/sub>S\u7eb3\u7c73\u7ea4\u7ef4\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) CV\u66f2\u7ebf<\/p>\n

(b) GCD\u66f2\u7ebf<\/p>\n

(c) \u6bd4\u5bb9\u91cf<\/p>\n

(d) EIS\u66f2\u7ebf<\/p>\n

(e) \u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n

\u56fe6. CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684\u7535\u5316\u5b66\u8868\u5f81\"\"<\/p>\n

(a) \u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684CV\u66f2\u7ebf<\/p>\n

(b) CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684\u5cf0\u503c\u7535\u6d41\u548c\u626b\u63cf\u901f\u7387\u4e4b\u95f4\u7684\u5173\u7cfb<\/p>\n

(c) 5 mV s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0bCoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7684CV\u66f2\u7ebf<\/p>\n

(d) \u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7535\u5bb9\u63a7\u5236\u548c\u6269\u6563\u63a7\u5236\u8fc7\u7a0b\u6240\u5360\u7684\u6bd4\u4f8b<\/p>\n

\u56fe7. \u6df7\u5408\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) CV\u66f2\u7ebf<\/p>\n

(b) GCD\u66f2\u7ebf<\/p>\n

(c) \u6bd4\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387<\/p>\n

(d) \u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u7684\u5173\u7cfb<\/p>\n

(e) \u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7814\u7a76\u56e2\u961f\u5236\u5907\u4e86CoO\/Co-Cu-S\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u3002\u5176\u4e2d\uff0cCoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2.0 A g-1<\/sup>\u65f6\u6bd4\u5bb9\u91cf\u9ad8\u8fbe320 mAh g-1<\/sup>\uff0c\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\u523030 A g-1<\/sup>\u65f6\u4fdd\u7559\u4e8674%\u7684\u6bd4\u5bb9\u91cf\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a10 A g-1<\/sup>\u65f6\u8fd0\u884c\u4e865000\u6b21\u5faa\u73af\u540e\u4fdd\u7559\u4e8696.5%\u7684\u521d\u59cb\u5bb9\u91cf\u3002\u800c\u4e14\uff0c\u7531CoO\/Co-Cu-S-2\u591a\u7ea7\u7ba1\u72b6\u5f02\u8d28\u7ed3\u6784\u7535\u6781\u548c\u6d3b\u6027\u78b3\u7535\u6781\u7ec4\u6210\u7684\u6df7\u5408\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a800 W kg-1<\/sup>\u65f6\u5177\u670990.7 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u5e76\u8868\u73b0\u51fa\u957f\u671f\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u50a8\u80fd\u5e94\u7528\u4e2d\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aConstruction of CoO\/Co-Cu-S Hierarchical Tubular Heterostructures for Hybrid Supercapacitors<\/a>\uff08Angew. Chem. Int. Ed., 2019, DOI: 10.1002\/anie.201907516<\/em>\uff09<\/p>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002\u611f\u8c22\u5f20\u9e4f\u535a\u58eb\u5728\u767e\u5fd9\u4e2d\u5bf9\u672c\u6587\u8fdb\u884c\u6821\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u591a\u7ea7\u4e2d\u7a7a\u7ed3\u6784\u80fd\u589e\u5927\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u52a0\u5feb\u79bb\u5b50\u548c\u7535\u5b50\u7684\u4f20\u8f93\uff0c\u5bb9\u7eb3\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u6b64\u5916\uff0c\u5f02\u8d28\u7ed3\u6784\u7684\u6784\u5efa\u4f1a\u589e\u5f3a\u5185\u90e8\u7535\u573a\uff0c\u8c03\u8282\u7535\u5b50\u7ed3\u6784…<\/p>\n","protected":false},"author":1592,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-182111","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182111"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1592"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=182111"}],"version-history":[{"count":9,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182111\/revisions"}],"predecessor-version":[{"id":184626,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182111\/revisions\/184626"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=182111"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=182111"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=182111"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}