{"id":182235,"date":"2019-08-01T12:00:24","date_gmt":"2019-08-01T04:00:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=182235"},"modified":"2019-07-31T16:57:10","modified_gmt":"2019-07-31T08:57:10","slug":"%e9%a1%b6%e5%88%8a%e9%80%9f%e9%80%92%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8%e9%a2%86%e5%9f%9f%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=182235","title":{"rendered":"\u9876\u520a\u901f\u9012|\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u8d85\u7ea7\u7535\u5bb9\u5668\u4f5c\u4e3a\u4e00\u79cd\u50a8\u80fd\u5668\u4ef6\uff0c\u5177\u5907\u9ad8\u529f\u7387\u5bc6\u5ea6\uff0c\u5feb\u901f\u5145\u653e\u7535\uff0c\u957f\u5bff\u547d\uff0c\u5b89\u5168\u7b49\u7279\u70b9\u3002\u7136\u800c\uff0c\u76f8\u6bd4\u4e8e\u7535\u6c60\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u8f83\u4f4e\u7684\u80fd\u91cf\u5bc6\u5ea6\u9650\u5236\u5176\u5546\u4e1a\u5e94\u7528\u3002\u968f\u7740\u5927\u91cf\u7684\u7814\u7a76\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\u4e0d\u65ad\u6d8c\u73b0\u51fa\u7a81\u7834\u6027\u7684\u8fdb\u5c55\uff0c\u4e14\u65b0\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u5f15\u8d77\u5e7f\u6cdb\u7814\u7a76\uff0c\u5982\u53ef\u4fee\u590d\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u53ef\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u53ef\u7a7f\u6234\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u3002\u672c\u6587\u7b80\u5355\u68b3\u7406\u4e86\u8d85\u7535\u9886\u57df\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\uff0c\u671b\u5bf9\u5927\u5bb6\u6709\u6240\u5e2e\u52a9\u3002<\/span><\/p>\n

1,\u00a0\u57fa\u4e8e\u53cc\u4ea4\u8054\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u53ef\u62c9\u4f38\u53ef\u6108\u5408\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u540c\u6d4e\u5927\u5b66\u9648\u6d9b\u8bfe\u9898\u7ec4\u53d1\u8868\u5728\u9876\u520aNature\u00a0communications\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aUltrastretchable and superior healable supercapacitors based on a double cross-linked hydrogel electrolyte [1]<\/sup>.<\/span><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\u5982\u56fe\u6240\u793a\uff0c\u672c\u6587\u62a5\u9053\u4e00\u79cd\u7531poly(AMPS-co-DMAAm)\uff0cLaponite\uff08\u9502\u8499\u8131\u77f3\u578b\u7c98\u571f\uff09\u548cGO\uff08\u6c27\u5316\u77f3\u58a8\u70ef\uff09\u7ec4\u6210\u7684\u4ea4\u8054\u5171\u805a\u7269\u6c34\u51dd\u80f6\u4f5c\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u89e3\u8d28\uff0c\u8868\u73b0\u51fa\u9ad8\u673a\u68b0\u62c9\u4f38\u6027\uff0c\u4f18\u5f02\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u53ef\u6108\u5408\u6027\u80fd\u3002GO\u7684\u5b58\u5728\u8d4b\u4e88\u4e86\u6c34\u51dd\u80f6\u4f18\u5f02\u7684\u673a\u68b0\u548c\u7535\u5b50\u6027\u80fd\uff0c\u4f7f\u5f97\u5236\u5907\u7684\u6c34\u51dd\u80f6\u5177\u6709\u9ad8\u673a\u68b0\u6027\u80fd\uff08\u62c9\u4f38\u5ea6\u4e3a1173\uff05\uff09\u548c\u4f18\u5f02\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u3002\u5728\u6c34\u51dd\u80f6\u65ad\u88c2\u754c\u9762\u5904\uff0cLaponite\u548cGO\u4e2d\u4e30\u5bcc\u7684\u5b98\u80fd\u56e2\uff08-COOH\uff0c-OH\u548cMg2+<\/sup>\uff09\u80fd\u4e0e\u805a\u5408\u7269\u57fa\u56e2\uff08-CONH2<\/sub>\uff09\u4ea7\u751f\u4ea4\u8054\u53cd\u5e94\uff0c\u4fdd\u8bc1\u5176\u51fa\u8272\u7684\u6108\u5408\u80fd\u529b\u3002\u7531\u8fd9\u79cd\u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u548c\u8936\u76b1\u7ed3\u6784\u7684\u7535\u6781\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0d\u4ec5\u5177\u59071000\uff05\u7684\u8d85\u5f3a\u673a\u68b0\u62c9\u4f38\u6027\uff0c\u5728300%\u7684\u5e94\u53d8\u62c9\u4f382000\u6b21\u4e0b\u4ecd\u80fd\u4fdd\u630198%\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e14\u5728\u7ea2\u5916\u5149\u7167\u5c04\u548c\u52a0\u70ed\u7684\u60c5\u51b5\u4e0b\u4fdd\u6301\u91cd\u590d\u7684\u6108\u5408\u80fd\u529b\u3002\u65ad\u88c2\/\u6108\u5408\u7684\u8d85\u7535\u80fd\u591f\u8fbe\u5230900%\u7684\u8d85\u9ad8\u62c9\u4f38\u6027\uff0c\u6027\u80fd\u4ec5\u51fa\u73b0\u8f7b\u5fae\u7684\u8870\u51cf\u3002<\/p>\n

2,MoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\u7528\u4f5c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\uff0c\u5177\u6709\u8d85\u9ad8\u8d5d\u7535\u5bb9\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u540c\u6d4e\u5927\u5b66\u6768\u91d1\u864e\u8bfe\u9898\u7ec4\u53d1\u8868\u5728\u9876\u520aNature\u00a0communications\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aA polymer-direct-intercalation strategy for MoS2<\/sub>\/carbon-derived heteroaerogels with ultrahigh pseudocapacitance [2]<\/sup>\u3002<\/span><\/p>\n

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\u672c\u6587\u62a5\u9053\u4e00\u79cd\u805a\u5408\u7269\u5d4c\u5165\u65b9\u6cd5\u5408\u6210\u4e09\u7ef4MoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\u3002\u5982\u56fe\u6240\u793a\uff0c\u9996\u5148\uff0cPEI \u548cMoS2<\/sub>\u7eb3\u7c73\u7247\u6df7\u5408\u6eb6\u4e8e\u6c34\u4e2d\u3002MoS2<\/sub>\u7eb3\u7c73\u7247\u8868\u9762\u5e26\u8d1f\u7535\uff0cPEI\u5e26\u6b63\u7535\uff0c\u7531\u4e8e\u4e8c\u8005\u9759\u7535\u5438\u5f15\u4f5c\u7528\uff0cPEI\u5206\u5b50\u8f7b\u6613\u5730\u5438\u9644\u4e8eMoS2<\/sub>\u7eb3\u7c73\u7247\u8868\u9762\uff0c\u5e76\u5728\u8d85\u58f0\u4f5c\u7528\u4e0b\u5d4c\u5165MoS2<\/sub>\u5c42\u4e2d\u3002\u7531\u4e8ePEI\u5206\u5b50\u5728MoS2<\/sub>\u7eb3\u7c73\u7247\u4e4b\u95f4\u7684\u8fde\u63a5\u4f5c\u7528\uff0c\u6df7\u5408\u7269\u51b7\u51bb\u5e72\u71e5\u540e\u5f62\u6210\u6c14\u51dd\u80f6\u72b6\u7684\u4e09\u7ef4MoS2<\/sub>\/PEI\u590d\u5408\u7269\u3002\u6700\u540e\uff0c\u51b7\u51bb\u5e72\u71e5\u540e\u7684\u6df7\u5408\u7269\u5728800\u00b0C\u4e0b\u00a0\u7145\u70e76\u5c0f\u65f6\uff0c\u751f\u6210MoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\u3002\u7145\u70e7\u540e\uff0c\u548c\u7eafMoS2<\/sub>\u7eb3\u7c73\u7247\u76f8\u6bd4\uff0cMoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u6750\u6599\u663e\u793a\u51fa\u4e0d\u540c\u7684\u5c42\u95f4\u8ddd\u3002\u7ecf\u7145\u70e7\u540e\u7684\u7eafMoS2<\/sub>\u7eb3\u7c73\u7247\u7684\u5c42\u95f4\u8ddd\u4e3a0.62nm\uff0c\u800cMoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\u7684\u5c42\u95f4\u8ddd\u4e3a0.98nm\u3002\u8fd9\u4e2a\u6570\u503c\u4e0e\u77f3\u58a8\u70ef\u5d4c\u5165MoS2<\/sub>\u7684\u5c42\u95f4\u8ddd\u4e00\u81f4\uff0c\u8bf4\u660e\u77f3\u58a8\u70ef\u6210\u529f\u5d4c\u5165MoS2<\/sub>\u5c42\u4e2d\uff0c\u8fd9\u662f\u7531\u4e8e\u5d4c\u5165MoS2<\/sub>\u5c42\u4e2d\u7684PEI\u539f\u4f4d\u78b3\u5316\u9020\u6210\u3002\u8fd9\u79cd\u7535\u6781\u6750\u6599\u7684\u4f18\u52bf\uff1a1\uff0c\u4e09\u7ef4\u6750\u6599\u7ed3\u6784\u6709\u5229\u4e8e\u7535\u5b50\u548c\u79bb\u5b50\u7684\u5feb\u901f\u4f20\u8f93\uff1b2\uff0c\u7531\u4e8eMoS2<\/sub>\u5c42\u4e4b\u95f4\u5d4c\u5165\u7c7b\u77f3\u58a8\u70ef\u5355\u5c42\u78b3\uff0c\u4f7f\u5176\u66b4\u9732\u51fa\u66f4\u591a\u6d3b\u6027\u4f4d\u70b9\uff0c\u521b\u9020\u51fa\u65b0\u7684\u79bb\u5b50\/\u7535\u5b50\u4f20\u8f93\u9014\u5f84\uff0c\u4f7f\u5f97\u5355\u5c42MoS2<\/sub>\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\uff1b3\uff0c\u7eafMoS2<\/sub>\u5bfc\u7535\u6027\u5dee\uff0c\u7535\u5b50\u53ea\u80fd\u6cbf\u7740\uff08002\uff09\u9762\u4f20\u8f93\uff0c\u800cMoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\uff0c\u7535\u5b50\u901a\u8fc7Mo-N\u952e\uff08\u7c7b\u91d1\u5c5e\u952e\uff09\u4f20\u8f93\u6bd4\u901a\u8fc7Mn-O\uff08\u7c7b\u5171\u4ef7\u952e\uff09\u4f20\u8f93\u6548\u7387\u9ad8\u3002\u56e0\u6b64\uff0cMoS2<\/sub>\/\u6c2e\u63ba\u6742\u78b3\u6750\u6599\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u53731\u00a0A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8d28\u91cf\u6bd4\u7535\u5bb9\u4e3a4144\u00a0F g–<\/sup>1<\/sup>\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\u523010\u00a0A g-1<\/sup>\uff0c\u8d28\u91cf\u6bd4\u7535\u5bb9\u4ecd\u80fd\u8fbe\u52302483 F g–<\/sup>1<\/sup>\u3002<\/p>\n

3,\u76b1\u6298\u5782\u76f4\u7684CNT\u9635\u5217\u7528\u4f5c\u9ad8\u5ea6\u53ef\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u5bc6\u6b47\u6839\u5dde\u7acb\u5927\u5b66Changyong Cao\u6559\u6388\u548c\u675c\u514b\u5927\u5b66Jeffrey T. Glass\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u4f5c\u53d1\u8868\u5728\u9876\u520aAdvanced Energy Materials\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aHighly Stretchable Supercapacitors via Crumpled Vertically Aligned Carbon Nanotube Forests[3]<\/sup>.<\/span><\/p>\n

\"\"<\/p>\n

\u53ef\u62c9\u4f38\u7684\u7535\u5b50\u8bbe\u5907\u5728\u627f\u53d7\u8f83\u5927\u5f62\u53d8\u7684\u60c5\u51b5\u4e0b\u4ecd\u80fd\u4fdd\u6301\u6b63\u5e38\u529f\u80fd\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u53ef\u7a7f\u6234\u5668\u4ef6\uff0c\u751f\u7269\u533b\u5b66\u5668\u4ef6\u7b49\u9886\u57df\u3002\u8d85\u7ea7\u7535\u5bb9\u5668\u4f5c\u4e3a\u50a8\u80fd\u5668\u4ef6\uff0c\u5177\u6709\u9ad8\u5145\u653e\u7535\u901f\u7387\uff0c\u9ad8\u529f\u7387\u5bc6\u5ea6\uff0c\u9ad8\u5bff\u547d\u7b49\u7279\u70b9\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u7136\u800c\uff0c\u76ee\u524d\u7814\u7a76\u51fa\u7684\u53ef\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\u53ea\u80fd\u5b9e\u73b0\u5728\u4e00\u4e2a\u65b9\u5411\u62c9\u4f38\uff1b\u4e14\u5f53\u610f\u5916\u62c9\u4f38\u5927\u4e8e\u8bbe\u5907\u7684\u9884\u5b9a\u62c9\u4f38\u6027\u65f6\uff0c\u8bbe\u5907\u5f88\u5bb9\u6613\u88ab\u635f\u574f\u3002\u56e0\u6b64\uff0c\u5236\u5907\u53ef\u591a\u65b9\u5411\u62c9\u4f38\u4e14\u80fd\u4fdd\u6301\u6027\u80fd\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u5c24\u5176\u91cd\u8981\u3002\u672c\u6587\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u9ad8\u62c9\u4f38\u5ea6\uff0c\u9ad8\u53ef\u9760\u6027\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u7535\u6781\u6750\u6599\u662f\u7531\u57fa\u4e8e\u5f39\u6027\u4f53\u57fa\u677f\u4e0a\u76b1\u6298\u5782\u76f4\u7684CNT\u9635\u5217\u7ec4\u6210\u3002\u8fd9\u79cdCNT\u9635\u5217\u7535\u6781\u5728\u5355\u8f74300%\u6216\u53cc\u8f74300%\u00d7300%\u5e94\u53d8\u60c5\u51b5\u4e0b\u4ecd\u80fd\u663e\u793a\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u7531\u4e24\u7247CNT\u9635\u5217\u7535\u6781\u7ec4\u6210\u7684\u8d85\u7535\u80fd\u591f\u627f\u53d7800%\u7684\u62c9\u4f38\uff0c\u5177\u67095mF\u00a0cm-2<\/sup>\u7684\u6bd4\u7535\u5bb9\u3002\u8fd9\u79cdCNT\u9635\u5217\u53ef\u4f38\u7f29\u8d85\u7535\u7535\u6781\u7684\u4f18\u52bf\u53ef\u5f52\u7eb3\u4e3a\uff1a1\uff0cCNT\u7ed3\u6784\u7a33\u5b9a\uff0c\u7145\u70e7\u540e\u5f88\u5bb9\u6613\u8f6c\u79fb\u5230\u7845\u57fa\u5e95\uff1b2\uff0c\u76f8\u6bd4\u4f20\u7edf\u7684\u5e73\u9762\u8584\u819c\uff0c\u5782\u76f4\u7684CNT\u9635\u5217\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff1b3\uff0c\u5f53\u610f\u5916\u62c9\u4f38\u5927\u4e8e\u6750\u6599\u5236\u5907\u8fc7\u7a0b\u4e2d\u7684\u9884\u5b9a\u62c9\u4f38\u6027\u65f6\uff0cCNT\u9635\u5217\u7535\u6781\u4ecd\u80fd\u4fdd\u6301\u9ad8\u5bfc\u7535\u6027\u3002<\/p>\n

\u5236\u5907\u8fc7\u7a0b\u5982\u56fe\u6240\u793a:<\/span><\/strong><\/p>\n

1\uff1a\u901a\u8fc7\u7b49\u79bb\u5b50\u4f53\u589e\u5f3a\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\uff08PECVD\uff09\u5728\u7845\u57fa\u5e95\u957f\u51faCNT\u9635\u5217\u3002<\/span><\/p>\n

2\uff1a\u7ecf\u8fc7\u7145\u70e7\uff0cCNT\u9635\u5217\u5f88\u5bb9\u6613\u88ab\u8f6c\u79fb\u5230\u5df2\u53cc\u5411\u62c9\u4f38\u7684\u5f39\u6027\u4f53\u57fa\u5e95\u4e0a\u3002<\/span><\/p>\n

3\uff1a\u6700\u540e\uff0c\u5c06\u9884\u62c9\u4f38\u7684\u5f39\u6027\u4f53\u6cbf\u4e00\u4e2a\u65b9\u5411\u6216\u4e24\u4e2a\u6b63\u4ea4\u65b9\u5411\u677e\u5f1b\uff0c\u5f62\u6210\u5355\u8f74\u6216\u53cc\u8f74\u76b1\u6298\u7684CNT\u9635\u5217\u7535\u6781\u3002<\/span><\/p>\n

\u00a0\"\"<\/b><\/strong><\/span><\/p>\n

\"\"<\/p>\n

SEM\u56fe\uff1a<\/strong>\uff08b\uff09\u751f\u957f\u5728\u7845\u57fa\u5e95\u4e0a\u7684CNT\u9635\u5217\uff1b\uff08c\uff09\u76b1\u6298CNT\u9635\u5217\u4f4d\u4e8e\u6cbf\u4e00\u4e2a\u65b9\u5411\u677e\u5f1b\u7684\u5f39\u6027\u57fa\u5730\uff1b\uff08d\uff09\u76b1\u6298CNT\u9635\u5217\u4f4d\u4e8e\u6cbf\u4e24\u4e2a\u6b63\u4ea4\u65b9\u5411\u677e\u5f1b\u7684\u5f39\u6027\u57fa\u5730\u3002<\/span><\/p>\n

\u5728\u53cc\u8f74\u5f62\u53d8\u4e0b\u76b1\u6298CNT\u9635\u5217\u7535\u6781\u7535\u5316\u5b66\u6027\u80fd\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u56fe\uff1b\uff08b\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u56fe\uff1b\uff08c\uff09\u7535\u6781\u57280\uff05\u00d70\uff05\uff0c150\uff05\u00d7150\uff05\u548c300\uff05\u00d7300\uff05\u7684\u53cc\u8f74\u5e94\u53d8\u4e0b\u7684CV\u56fe\uff0c\u626b\u901f\u4e3a100mV s-1<\/sup>\uff1b\uff08d\uff09\u7535\u6781\u57280\uff05\u00d70\uff05\uff0c150\uff05\u00d7150\uff05\u548c300\uff05\u00d7300\uff05\u7684\u53cc\u8f74\u5e94\u53d8\u4e0b\u7684\u5145\u653e\u7535\u56fe\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5mA cm-2<\/sup>;\u00a0\uff08e\uff09\u4e0d\u540c\u53cc\u8f74\u5e94\u53d8\u4e0b\u7535\u6781\u7684Nyquist\u963b\u6297\u56fe; \uff08f\uff09\u4e0d\u540c\u53cc\u8f74\u5e94\u53d8\u4e0b\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u9762\u79ef\u6bd4\u7535\u5bb9\u3002<\/p>\n

4,\u7403\u78e8\u6cd5\u589e\u52a0\u77f3\u58a8\u70ef\u53cc\u7535\u5c42\u7535\u5bb9\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5b8b\u6000\u6cb3\u8bfe\u9898\u7ec4\u53d1\u8868\u5728Advanced Functional Materials\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aBoosting the Electrical Double\u2010Layer Capacitance of Graphene by Self\u2010Doped Defects through Ball\u2010Milling\u00a0[4]<\/sup>.<\/span><\/p>\n

\"\"<\/p>\n

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\u00a0\u00a0\"\"<\/p>\n

5, \u4f7f\u7528\u6742\u539f\u5b50\u63ba\u6742\u548c\u9020\u5b54\u5de5\u7a0b\u63d0\u9ad8\u8d85\u7535\u78b3\u6750\u6599\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u52a0\u5dde\u5927\u5b66\u674e\u8f76\u6559\u6388\u548c\u91cd\u5e86\u5927\u5b66\u5f20\u4e91\u6000\u6559\u6388\u8bfe\u9898\u7ec4\u53d1\u8868\u5728Advanced Energy Materials\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aPore and Heteroatom Engineered Carbon Foams for Supercapacitors [5]<\/sup>.<\/span><\/p>\n

\u78b3\u6750\u6599\uff0c\u5982\u6d3b\u6027\u78b3\uff0c\u77f3\u58a8\u70ef\uff0c\u78b3\u7eb3\u7c73\u7ba1\uff0c\u78b3\u7ea4\u7ef4\u7b49\uff0c\u4f5c\u4e3a\u8d85\u7535\u7535\u6781\u6750\u6599\u5177\u6709\u9ad8\u5bfc\u7535\u6027\uff0c\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u4e0d\u540c\u7684\u5f62\u8c8c\u7b49\u7279\u70b9\u3002\u4f46\u662f\uff0c\u78b3\u6750\u6599\u7684\u8d28\u91cf\u6bd4\u7535\u5bb9\u901a\u5e38\u5c0f\u4e8e100\u00a0F g–<\/sup>1<\/sup>\u3002\u5728\u78b3\u6750\u6599\u4e2d\u63ba\u6742N, O, S\u7b49\u6742\u539f\u5b50\u80fd\u6709\u6548\u589e\u52a0\u6d3b\u6027\u4f4d\u70b9\uff0c\u63d0\u9ad8\u8868\u9762\u6da6\u6e7f\u5ea6\uff0c\u8d21\u732e\u8d5d\u7535\u5bb9\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u4f20\u8f93\uff0c\u4ece\u800c\u63d0\u5347\u78b3\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0c\u9020\u5b54\u5de5\u7a0b\uff08pore engineering\uff09\u4e5f\u662f\u63d0\u9ad8\u78b3\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u53e6\u4e00\u91cd\u8981\u9014\u5f84\u3002\u591a\u7ea7\u5b54\u7ed3\u6784\uff08micro\/meso\/macropores\uff09\u80fd\u591f\u63d0\u9ad8\u6750\u6599\u6bd4\u8868\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u7535\u5b50\u548c\u79bb\u5b50\u7684\u4f20\u8f93\u3002\u672c\u6587\u7ed3\u5408\u4ee5\u4e0a\u4e24\u79cd\u65b9\u6cd5\u5236\u5907\u65b0\u578b\u7684N, O, S\u63ba\u6742\u7684\u591a\u5b54\u78b3\u6750\u6599\uff0c\u5e94\u7528\u4e8e\u8d85\u7535\u7535\u6781\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5373\u57281\u00a0A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8d28\u91cf\u6bd4\u7535\u5bb9\u4e3a402.5 F g–<\/sup>1<\/sup>\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\u5230100\u00a0A g-1<\/sup>\uff0c\u8d28\u91cf\u6bd4\u7535\u5bb9\u4ecd\u80fd\u8fbe\u5230308.5\u00a0F g–<\/sup>1<\/sup>\u3002\u5236\u5907\u8fc7\u7a0b\u5982\u4e0b\u56fe\u6240\u793a\u3002<\/p>\n

\"\"<\/p>\n

\u6c27\u5316\u77f3\u58a8\u70ef\uff08GO\uff09\uff0c\u00a0F127\uff0c1,3,5-\u4e09\u7532\u57fa\u82ef\uff08TMB\uff09\uff0c\u591a\u5df4\u80fa\uff08DA\uff09\uff0c\u534a\u80f1\u6c28\u9178\u6df7\u5408\u5f62\u6210\u6cb9\/\u6c34\u4e73\u6db2\u7cfb\u7edf\u3002\u52a0\u5165\u805a\u5408\u5f15\u53d1\u5242\u540e\uff0c\u591a\u5df4\u80fa\u5206\u5b50\u81ea\u805a\u5408\u6210\u805a\u591a\u5df4\u80fa\uff08PDA\uff09\u5e76\u6d82\u8986\u5728\u7403\u5f62\u80f6\u675f\u7684\u8868\u9762\u3002PDA\u58f3\u548c\u80f6\u675f\u6838\u901a\u8fc7\u975e\u5171\u4ef7\u81ea\u7ec4\u88c5\u548c\u5171\u4ef7\u952e\u5076\u8054\u5728\u4e00\u8d77\u3002\u5728\u526a\u5207\u529b\u7684\u4f5c\u7528\u4e0b\uff0cPDA\u5438\u9644\u7684\u5355\u5206\u6563\u7403\u5f62\u80f6\u675f\u8fdb\u4e00\u6b65\u5728GO\u8868\u9762\u7ec4\u88c5\u6210\u5782\u76f4\u7684\u4ecb\u5b54\u901a\u9053\u9635\u5217\u3002\u7ecf\u8fc7\u51b7\u51bb\u5e72\u71e5\uff0c\u7145\u70e7\uff0cKOH\u6d3b\u5316\uff0cN, O, S\u63ba\u6742\u7684\u591a\u5b54\u78b3\u6750\u6599\u5236\u5907\u5b8c\u6bd5\u3002KOH\u7684\u6d3b\u5316\u6709\u5229\u4e8e\u589e\u52a0\u78b3\u6750\u6599\u5fae\u5b54\u6570\u91cf\uff0c\u63d0\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u53cc\u7535\u5c42\u7535\u5bb9\u3002<\/span><\/p>\n

6,\u78b3\u70b9\/\u591a\u5b54\u78b3\u590d\u5408\u6750\u6599\u7528\u4e8e\u9ad8\u6027\u80fd\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8d1f\u6781\u6750\u6599\u3002<\/span><\/h3>\n

\u672c\u6587\u7531\u590d\u65e6\u5927\u5b66\u718a\u7115\u660e\u3001\u738b\u6c38\u521a\u8bfe\u9898\u7ec4\u53d1\u8868\u5728\u9876\u520aAdvanced Materials\u4e0a\u3002\u9898\u76ee\u4e3a\uff1aRobust Negative Electrode Materials Derived from Carbon Dots and Porous Hydrogels for High-Performance Hybrid Supercapacitors [6]<\/sup>.<\/span><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\u63d0\u5347\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u5bc6\u5ea6\u5bf9\u4e8e\u5546\u4e1a\u5e94\u7528\u5c24\u4e3a\u91cd\u8981\uff0c\u4e00\u822c\u901a\u8fc7\u6539\u5584\u78b3\u6750\u6599\u7684\u5b54\u7ed3\u6784\u6216\u8d1f\u8f7d\u8d5d\u7535\u5bb9\u6750\u6599\u63d0\u9ad8\u7535\u6781\u6750\u6599\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u672c\u6587\u62a5\u9053\u4e00\u79cd\u5728\u7535\u6781\u6750\u6599\u8868\u9762\u6784\u5efa\u5bcc\u7535\u5b50\u533a\u57df\u7684\u65b9\u6cd5\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u5bcc\u7535\u5b50\u533a\u57df\u80fd\u591f\u5c3d\u53ef\u80fd\u591a\u5730\u5438\u9644\u9633\u79bb\u5b50\uff0c\u52a0\u901f\u7535\u5b50\u8f6c\u79fb\uff0c\u663e\u8457\u63d0\u5347\u7535\u6781\u6750\u6599\u7535\u5bb9\u503c\u3002\u4f5c\u8005\u4f7f\u7528\u805a\u4e19\u70ef\u9170\u80fa\uff08PAM\uff09\u6c34\u51dd\u80f6\u4f5c\u4e3a\u4e3b\u4f53\uff0c\u5c0f\u4e8e10nm\u7684\u78b3\u70b9\u4f5c\u4e3a\u5ba2\u4f53\uff0c\u5408\u6210\u4e00\u79cd\u65b0\u578b\u7684\u78b3\u70b9\/\u591a\u5b54\u78b3\u590d\u5408\u6750\u6599\u3002\u7531\u4e8e\u78b3\u70b9\u5bcc\u542b\u78f7\u9178\u76d0\/\u6c2e\u57fa\u56e2\uff0c\u80fd\u591f\u8c03\u8282\u6750\u6599\u7535\u5b50\u7ed3\u6784\uff0c\u5f62\u6210\u5bcc\u7535\u5b50\u533a\u57df\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u8fd9\u79cd\u78b3\u6750\u6599\u5177\u6709\u5927\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u79bb\u5b50\u548c\u7535\u5b50\u7684\u4f20\u8f93\u3002\u56e0\u6b64\uff0c\u5982\u4e0b\u56fe\u6240\u793a\uff0c\u6b64\u6750\u6599\u7528\u4f5c\u8d85\u7535\u7535\u6781\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5728\u78b1\u6027\uff0c\u9178\u6027\u548c\u4e2d\u6027\u7535\u89e3\u8d28\u4e2d\uff0c\u8d28\u91cf\u6bd4\u7535\u5bb9\u5206\u522b\u4e3a468\uff0c510\uff0c438\u00a0F g-1<\/sup>\uff1b\u4e0eNi(OH)2<\/sub>\/CNTs\u7ec4\u5408\u6210\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u65f6\uff0c\u80fd\u91cf\u5bc6\u5ea6\u4e3a90\u00a0Wh\u00a0kg-1<\/sup>\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u57fa\u4e8e\u5bf9\u6700\u8fd1\u8d85\u7535\u6587\u732e\u7684\u5206\u6790\uff0c\u7528\u4e8e\u6700\u8fd1\u5bf9\u7528\u4e8e\u53ef\u4fee\u590d\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u53ef\u62c9\u4f38\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u53ef\u7a7f\u6234\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\u6216\u65b0\u578b\u7535\u89e3\u8d28\u7684\u7814\u7a76\u5c42\u51fa\u4e0d\u7a77\u3002\u5bf9\u4e8e\u78b3\u6750\u6599\u800c\u8a00\uff0c\u63d0\u9ad8\u5176\u7535\u5bb9\u503c\u7684\u65b9\u6cd5\u6709\u8c03\u63a7\u5b54\u7ed3\u6784\u548c\u6bd4\u8868\u9762\u79ef\uff0c\u6742\u539f\u5b50\u63ba\u6742\uff0c\u63d0\u9ad8\u6da6\u6e7f\u5ea6\u7b49\uff1b\u5bf9\u4e8e\u8d5d\u7535\u5bb9\u6750\u6599\uff0c\u63d0\u9ad8\u5176\u7535\u5bb9\u503c\u7684\u65b9\u6cd5\u6709\u5c06\u5176\u4e0e\u5bfc\u7535\u6027\u5927\u7684\u78b3\u6750\u6599\u7ed3\u5408\u6216\u8005\u6539\u53d8\u5176\u672c\u8eab\u7279\u6027\u3002\u603b\u4e4b\uff0c\u5982\u4f55\u4fdd\u6301\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u60c5\u51b5\u4e0b\u63d0\u5347\u80fd\u91cf\u5bc6\u5ea6\u4ecd\u7136\u662f\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/span><\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/span><\/strong><\/p>\n

[1] H. Li, T. Lv, H. Sun, G. Qian, N. Li, Y. Yao, T. Chen, Ultrastretchable and superior healable supercapacitors based on a double cross-linked hydrogel electrolyte, Nat. Commun. 10 (2019) doi.org\/10.1038\/s41467-019-08320-z. doi:10.1038\/s41467-019-08320-z.<\/span><\/p>\n

[2] N. Feng, R. Meng, L. Zu, Y. Feng, C. Peng, J. Huang, G. Liu, B. Chen, J. Yang, A polymer-direct-intercalation strategy for MoS 2 \/carbon-derived heteroaerogels with ultrahigh pseudocapacitance, Nat. Commun. 10 (2019) doi.org\/10.1038\/s41467-019-09384-7. doi:10.1038\/s41467-019-09384-7.<\/span><\/p>\n

[3] C. Cao, Y. Zhou, S. Ubnoske, J. Zang, Y. Cao, P. Henry, C.B. Parker, J.T. Glass, Highly Stretchable Supercapacitors via Crumpled Vertically Aligned Carbon Nanotube Forests, Adv. Energy Mater. 9 (2019) 1900618. doi:10.1002\/aenm.201900618.<\/span><\/p>\n

[4] Y. Dong, S. Zhang, X. Du, S. Hong, S. Zhao, Y. Chen, X. Chen, H. Song, Boosting the Electrical Double-Layer Capacitance of Graphene by Self-Doped Defects through Ball-Milling, Adv. Funct. Mater. 29 (2019) 1901127. doi:10.1002\/adfm.201901127.<\/span><\/p>\n

[5] H. Peng, B. Yao, X. Wei, T. Liu, T. Kou, P. Xiao, Y. Zhang, Y. Li, Pore and Heteroatom Engineered Carbon Foams for Supercapacitors, Adv. Energy Mater. 9 (2019) 1803665. doi:10.1002\/aenm.201803665.<\/span><\/p>\n

[6] J.S. Wei, C. Ding, P. Zhang, H. Ding, X.Q. Niu, Y.Y. Ma, C. Li, Y.G. Wang, H.M. Xiong, Robust Negative Electrode Materials Derived from Carbon Dots and Porous Hydrogels for High-Performance Hybrid Supercapacitors, Adv. Mater. 31 (2019) 1806197. doi:10.1002\/adma.201806197.<\/span><\/p>\n

\u672c\u6587\u7531Nolan<\/strong>\u4f9b\u7a3f\u3002<\/span><\/p>\n

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