{"id":182256,"date":"2019-08-07T06:30:04","date_gmt":"2019-08-06T22:30:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=182256"},"modified":"2019-08-06T15:13:43","modified_gmt":"2019-08-06T07:13:43","slug":"%e8%bf%9b%e5%b1%95%e6%a2%b3%e7%90%86%e4%b8%a8cof%e6%9d%90%e6%96%99%e5%9c%a8%e5%85%89%e5%82%ac%e5%8c%96%e9%a2%86%e5%9f%9f%e7%9a%84%e7%a0%94%e7%a9%b6%ef%bc%8c%e5%bf%ab%e6%9d%a5%e4%b8%80%e7%9d%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=182256","title":{"rendered":"\u8fdb\u5c55\u68b3\u7406\u4e28COF\u6750\u6599\u5728\u5149\u50ac\u5316\u9886\u57df\u7684\u7814\u7a76\uff0c\u5feb\u6765\u4e00\u7779\u4e3a\u5feb\uff01"},"content":{"rendered":"

\u4e00\uff1aCOF\u7b80\u4ecb<\/b><\/strong><\/h3>\n

COFs\uff08Covalent Organic Frameworks\uff0cCOFs\uff09\u662f\u4e00\u7c7b\u65b0\u578b\u7684\u57fa\u4e8e\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u6676\u6001\u6709\u673a\u591a\u5b54\u805a\u5408\u7269\uff0c\u5b83\u662f\u5229\u7528\u5171\u4ef7\u5316\u5b66\u53cd\u5e94\u5728\u5206\u5b50\u5c3a\u5ea6\u4e0a\u5c06\u7ed3\u6784\u5355\u5143\u8fdb\u884c\u6709\u5e8f\u6392\u5217\uff0c\u8fdb\u800c\u5f62\u6210\u6709\u5e8f\u7684\u6846\u67b6\u7ed3\u6784\u3002\u7ecf\u8fc7\u79d1\u5b66\u5de5\u4f5c\u8005\u5341\u591a\u5e74\u7684\u4e0d\u61c8\u52aa\u529b\uff0cCOFs\u7684\u7814\u7a76\u5df2\u7ecf\u53d6\u5f97\u5341\u5206\u5de8\u5927\u7684\u8fdb\u5c55\uff0c\u5728\u4f17\u591a\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002COFs\u6750\u6599\u662f\u4e00\u7c7b\u57fa\u4e8eC, H, O, N,\u7b49\u8f7b\u8d28\u5143\u7d20\uff0c\u8fde\u63a5\u800c\u6210\u7684\u4e00\u7c7b\u6676\u6001\u6709\u673a\u591a\u5b54\u6750\u6599\uff0c\u5176\u5177\u6709\u5bc6\u5ea6\u5c0f\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u597d\u3001\u5b54\u9053\u7ed3\u6784\u6613\u4e8e\u8c03\u63a7\u548c\u529f\u80fd\u5316\u7b49\u7279\u70b9\uff0c\u56e0\u6b64\u5728\u591a\u76f8\u50ac\u5316\u3001\u6c14\u4f53\u50a8\u5b58\u4e0e\u5206\u79bb\u3001\u50a8\u80fd\u6750\u6599\u4ee5\u53ca\u5149\u7535\u6750\u6599\u7b49\u9886\u57df\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u5149\u50ac\u5316\u53cd\u5e94\u662f\u6307\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u5728\u5149\u7167\u6761\u4ef6\u4e0b\u4fc3\u8fdb\u5316\u5408\u7269\u8f6c\u5316\u7684\u8fc7\u7a0b\u3002\u5149\u50ac\u5316\u5242\u7684\u53d1\u5c55\u4e3a\u4eba\u7c7b\u5f00\u53d1\u548c\u5229\u7528\u592a\u9633\u80fd\u6765\u521b\u9020\u65b0\u7684\u7269\u8d28\u63d0\u4f9b\u4e00\u79cd\u53ef\u80fd\u3002\u4e00\u65b9\u9762\uff0c\u5149\u50ac\u5316\u6709\u673a\u6c61\u67d3\u7269\u7684\u964d\u89e3\uff0c\u5149\u50ac\u5316CO2<\/sub>\u7684\u8fd8\u539f\u4e0e\u8f6c\u5316\u6709\u52a9\u4e8e\u89e3\u51b3\u73af\u5883\u95ee\u9898\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5149\u89e3\u6c34\u4ea7\u6c22\u6c14\u4e0e\u6c27\u6c14\u80fd\u4e3a\u4eba\u7c7b\u5f00\u53d1\u65b0\u7684\u80fd\u6e90\uff1b\u800c\u5149\u50ac\u5316\u6761\u4ef6\u4e0b\u7684\u5316\u5b66\u8f6c\u5316\u5219\u53ef\u4ee5\u6709\u6548\u7684\u5c06\u5149\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\u3002COFs\u6750\u6599\u6709\u5e8f\u7684\u5171\u8f6d\u7ed3\u6784\u4e0d\u4ec5\u6709\u5229\u4e8e\u5149\u80fd\u7684\u5438\u6536\uff0c\u4e5f\u6709\u52a9\u4e8e\u6fc0\u53d1\u6001\u7535\u5b50\u7684\u4f20\u8f93\u3002\u5176\u591a\u5b54\u7ed3\u6784\u6709\u5229\u4e8e\u5e95\u7269\u7684\u5438\u9644\uff0c\u4ee5\u53ca\u4ea7\u7269\u7684\u4f20\u8f93\u3002\u53ef\u4ee5\u8bf4\uff0cCOFs\u6750\u6599\u5177\u5907\u4f5c\u4e3a\u591a\u76f8\u5149\u50ac\u5316\u5242\u8bb8\u591a\u4f18\u70b9\u3002\u6587\u672c\u5c06\u4e3e\u4f8b\u8bf4\u660e\u76ee\u524d\u7eafCOFs\u6750\u6599\u5728\u5149\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\uff0c\u76ee\u524d\u4e5f\u6709\u4e00\u4e9b\u57fa\u4e8eCOFs\u548c\u5176\u4ed6\u6750\u6599\u590d\u5408\u7684\u624b\u6bb5\u5e94\u7528\u4e8e\u5149\u50ac\u5316\uff0c\u4e0d\u5305\u542b\u5728\u6b64\u6587\u4e2d\u3002<\/p>\n

\u4e8c\uff1a\u5177\u4f53\u5e94\u7528\u8303\u56f4\uff1a<\/b><\/strong><\/h3>\n

1<\/b><\/strong>\u00a0\u5149\u89e3\u6c34\u4ea7\u6c22\uff08\u76ee\u524d<\/b><\/strong>\u7814\u7a76\u6700\u591a<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

2014\u5e74\uff0cLotsch\u8bfe\u9898\u7ec4[1,11]<\/sup>\u5229\u7528\u9170\u8159\u952e\u6784\u7b51\u4e86\u4e00\u4f8b2D COFs\u6750\u6599—TFPT-COF\uff0c\u5e76\u5c06\u6750\u6599\u5e94\u7528\u4e8e\u50ac\u5316\u5149\u89e3\u6c34\u4ea7\u6c22\u6c14\u3002TFPT-COF\u5c5e\u4e8e\u4ecb\u5b54\u6750\u6599\uff0c\u5176\u5b54\u5f84\u4e3a3.8 \uff4e\uff4d\uff0c\u6bd4\u8868\u9762\u79ef\u4e3a1603 m2<\/sup>\uff0c\u5b54\u4f53\u79ef\u4e3a1.03 cm3<\/sup>\/g\u3002\u4e0e\u5355\u4f53\u76f8\u6bd4\uff0c\u6750\u6599\u5177\u6709\u66f4\u597d\u7684\u53ef\u89c1\u5149\u5438\u6536\u6027\u80fd\uff0c\u5176\u5438\u6536\u8fb9\u754c\u53ef\u8fbe\u5230600 nm\u4ee5\u4e0a\uff0c\u5e26\u9699\u5bbd\u5ea6\u7ea6\u4e3a2.8 eV\u3002\u4f5c\u4e3a\u5149\u89e3\u6c34\u50ac\u5316\u5242\uff0c\u5176\u4ea7\u6c22\u901f\u7387\u4e3a1970 \u03bcmol\/g-1<\/sup>h-1<\/sup>,\u5728\u76f8\u540c\u6761\u4ef6\u4e0b\uff0cTFPT-COF\/Pt\u7684\u4ea7\u6c22\u6548\u7387\u6bd4\u65e0\u5b9a\u578b\u6750\u6599\uff0cg-C3<\/sub>N4<\/sub>\u4ee5\u53ca\u6676\u578b\u805a\u9170\u4e9a\u80fa\u7684\u4ea7\u6c22\u6548\u7387\u90fd\u9ad8\uff0c\u5982\u56fe1\u3002<\/p>\n

\u56fe1. \u57fa\u4e8e\u9170\u8159\u952e\u8fde\u63a5\u7684COFs\u4e0e\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

2014\u5e74\uff0cBanerjee\u7ec4[2,11]<\/sup>\u5c06CdS\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u5230COFs\u4e2d\uff0c\u5f97\u5230\u4e86CdS\u6742\u5316COFs\u6750\u6599\uff0c\u5e76\u8003\u5bdf\u4e86\u5176\u5149\u89e3\u6c34\u4ea7\u6c22\u7684\u80fd\u529b\u3002\u6742\u5316\u6750\u6599\u4e2dCOF\u542b\u91cf\u7684\u4e0d\u540c\uff0c\u5176\u50ac\u5316\u6548\u679c\u4e5f\u6709\u5dee\u5f02\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u5f53COFs\u7684\u542b\u91cf\u4e3a10 %\u65f6\uff0c\u5176\u4ea7\u6c22\u901f\u7387\u4e3a3678 \u03bcmol\/g-1<\/sup>h-1<\/sup>, \u662f\u5757\u4f53CdS\u768430\u500d\u3002\u8fd9\u79cd\u6742\u5316\u6750\u6599\u4e2d\u542b\u6709\u5171\u8f6d\u9aa8\u67b6\u7ed3\u6784\uff0c\u6bd4\u8868\u9762\u79ef\u8f83\u5927\uff0c\u5e76\u4e14\u5b58\u5728\u4e30\u5bcc\u76842D\u5f02\u8d28\u7ed3\u3002\u8fd9\u79cd\u7279\u6b8a\u7684\u7ed3\u6784\u6709\u52a9\u4e8e\u5149\u751f\u7535\u5b50\u7684\u7a33\u5b9a\u5b58\u5728\uff0c\u4ece\u800c\u4ea7\u751f\u4f18\u5f02\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3002\u4f46\u662f\uff0c\u8d1f\u8f7dCdS\u540eCOFs\u6750\u6599\u7684\u6676\u578b\u53d7\u5230\u7834\u574f\uff0c\u5e76\u4e14\u50ac\u5316\u8fc7\u7a0b\u4ecd\u9700\u8981Pt\u8fd9\u79cd\u8d35\u91d1\u5c5e\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u3002\u56e0\u6b64\uff0c\u4ecd\u7136\u9700\u8981\u53d1\u5c55\u65b0\u7684\u65e0\u91d1\u5c5e\u7684\u534a\u5bfc\u4f53COFs\u5149\u50ac\u5316\u5242\u3002<\/p>\n

\u56fe2. CdS\u4e0eCOFs\u7684\u590d\u5408\u4ee5\u53ca\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u4e3a\u4e86\u907f\u514d\u4f7f\u7528\u8d35\u91cd\u91d1\u5c5ePt\uff0cLotsch\u8bfe\u9898\u7ec4\u5206\u522b\u4e8e2017[3]<\/sup>\u548c2019\u5e74[4]<\/sup>\u62a5\u9053\u4e86\u5229\u7528Co\u548cNi\u505a\u4e3a\u5171\u50ac\u5316\u5242\u7ed3\u5408COFs\u6750\u6599\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u4ea7\u6c22\u7684\u7814\u7a76\u4e2d\u3002\u5982\u56fe3\uff0c\u5229\u7528\u80bc\u952e\u505a\u4e3a\u8fde\u63a5\u65b9\u5f0f\u548c\u4e8c\u55ea\u5355\u4f53\u7ec4\u5408\uff0c\u5f97\u52302D COFs\uff0c\u5206\u522b\u5229\u7528\u4e09\u4e2aCo\u914d\u5408\u7269\u505a\u5171\u50ac\u5316\u5242\uff0c\u4e09\u4e59\u9187\u80faTEOA\u505a\u7535\u5b50\u7ed9\u4f53,\u5176\u4ea7\u6c22\u901f\u7387\u4e3a782 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\uff0cTON\u4e3a54.4\u3002\u5728\u56fe4\u4e2d\uff0c\u8be5\u8bfe\u9898\u7ec4\u5408\u6210\u4e86\u57fa\u4e8e\u567b\u5511\u5355\u4f53\u76842D COFs,\u800c\u505a\u4e3a\u5171\u50ac\u5316\u5242\u7684Ni\u7c07\u4e0d\u9700\u8981\u989d\u5916\u5236\u5907\uff0c\u5728\u5149\u50ac\u5316\u4e2d\u76f4\u63a5\u5728\u6c34\u4e2d\u73b0\u5236\u73b0\u7528\uff0c70\u5c0f\u65f6\u5185\u5176\u4ea7\u6c22\u6548\u7387\u4e3a941 \u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\uff0cTON\u4e3a103\u3002\u867d\u7136\u4e0e\u4f7f\u7528Pt\u505a\u5171\u50ac\u5316\u5242\u7684\u8bb0\u5f55\u6709\u70b9\u5dee\u8ddd\uff0c\u8be5\u5de5\u4f5c\u62d3\u5bbd\u4e86COFs\u4ea7\u6c22\u7684\u6750\u6599\u9009\u62e9\uff0c\u7ecf\u8fc7\u4f18\u5316\uff0c\u6709\u671b\u5c06\u6570\u503c\u63d0\u9ad8\u5230\u53ef\u5b9e\u9645\u4f7f\u7528\u7684\u8303\u56f4\u3002<\/p>\n

\u00a0\u00a0\u56fe3. \u57fa\u4e8e\u80bc\u952e\u8fde\u63a5\u7684COFs\u4e0e\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4. \u57fa\u4e8e\u567b\u5511\u8fde\u63a5\u7684COFs\u4e0e\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

2018\u5e74Andrew I. Cooper\u56e2\u961f[5]<\/sup>\u62a5\u9053\u4e86\u4e00\u79cd\u5177\u6709\u9ad8\u6548\u5149\u89e3\u6c34\u4ea7\u6c22\u6027\u80fd\u7684\u542b\u781c\u5355\u5143\u7684COFs\u6750\u6599\u3002\u8be5COFs\u5177\u6709\u4f18\u5f02\u7684\u91cf\u5b50\u6548\u7387\u548c\u4ea7\u6c22\u6027\u80fd\uff0c\u7cfb\u7edf\u7684\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u5f97\u76ca\u4e8eCOFs\u7684\u9ad8\u7ed3\u6676\u5ea6\u6846\u67b6\u3001\u5bbd\u7684\u53ef\u89c1\u5149\u5438\u6536\u8303\u56f4\u4ee5\u53ca\u4eb2\u6c34\u4ecb\u5b54\u7684\u534f\u540c\u4f5c\u7528\u3002\u7ecf\u8fc7\u67d3\u6599\u654f\u5316\u540e\uff0c\u4ea7\u6c22\u901f\u7387\u53ef\u4ee5\u63d0\u9ad861%\uff0c\u8fbe\u523016.3 mmol g-1<\/sup>h-1<\/sup>\u3002<\/p>\n

\u56fe5. \u542b\u781c\u5355\u4f53\u7684COFs\u4e0e\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

2019\u5e74\u5f20\u5e06\u548c\u738b\u5fc3\u6668\u8bfe\u9898\u7ec4[6]<\/sup>\u4ee5\u591a\u53d6\u4ee3\u82b3\u919b\u548c\u4e8c\u6c30\u57fa\u53d6\u4ee3\u5421\u5576\u884d\u751f\u82b3\u70c3\u4e3a\u5355\u4f53\uff0c\u901a\u8fc7Knoevenagel\u7f29\u805a\uff0c\u751f\u6210\u78b3\u78b3\u53cc\u952e\u8fde\u63a5\u7684\u9ad8\u6676\u6001COFs\u3002\u4e0d\u540c\u4e8e\u4e4b\u524d\u62a5\u9053\u7684\u6c30\u57fa\u53d6\u4ee3\u78b3\u78b3\u53cc\u952eCOFs\uff0c\u8be5\u53cc\u952e\u5355\u5143\u6781\u6027\u7684\u964d\u4f4e\u6709\u5229\u4e8e\u03c0\u7535\u5b50\u7684\u9ad8\u5ea6\u79bb\u57df\u548c\u6709\u6548\u4f20\u8f93\uff0c\u4ece\u800c\u63d0\u9ad8COFs\u6750\u6599\u7684\u534a\u5bfc\u4f53\u6d3b\u6027\u3002\u5bf9\u6240\u5236\u5907\u6750\u6599\u7684\u5149\u89e3\u6c34\u6d3b\u6027\u8fdb\u884c\u4e86\u7cfb\u7edf\u63a2\u7a76\uff0c\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u5176\u4ea7\u6c22\u91cf\u53ef\u8fbe4120 \u00b5mol g-1<\/sup>\u00a0h-1<\/sup>\uff0c\u5728420 nm \u5904\u7684\u5916\u91cf\u5b50\u6548\u7387\u8fbe\u52304.84%\uff0c\u8fd9\u4e5f\u662f\u5f53\u524dCOFs\u6750\u6599\u5149\u89e3\u6c34\u4ea7\u6c22\u6548\u7387\u7684\u6700\u9ad8\u503c\u3002<\/p>\n

\u56fe6. \u78b3\u78b3\u53cc\u952eCOFs\u5408\u6210\u4e0e\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u00a0\u5149\u50ac\u5316\u6709\u673a\u53cd\u5e94<\/b><\/strong><\/h3>\n

2018\u5e74\u738b\u4e3a\u7ec4[7]<\/sup>\u62a5\u9053\u4e86\u4e09\u4e2a\u4ee5\u73af\u72b6\u7684\u82ef\u5e76\u6076\u5511\u505a\u4e3a\u952e\u5408\u7c7b\u578b\u7684COF-LZU-190 ~ LZU-192\uff0c\u8be5\u7cfb\u5217COFs\u5728\u5f3a\u9178\u78b1\uff089 M NaOH, 9 M HCl\uff09\uff0c\u4e09\u6c1f\u4e59\u9178\uff0c\u6cb8\u6c34\u548c\u5149\u7167\u6761\u4ef6\u4e0b\uff08\u5747\u4e3a3\u5929\u65f6\u95f4\uff09\u5747\u7a33\u5b9a\u5b58\u5728\u3002\u968f\u540e\u5c06\u5176\u5e94\u7528\u5728\u82ef\u787c\u9178\u5149\u50ac\u5316\u6c27\u5316\u4e3a\u82ef\u915a\u7684\u5b9e\u9a8c\u4e2d\uff0c\u53d1\u73b0\u4e09\u4e2aCOFs\u5747\u53ef\u4ee5\u5229\u7528\u7a7a\u6c14\u505a\u4e3a\u6c27\u6e90\uff0c\u53ef\u89c1\u5149\u6761\u4ef6\u4e0b\uff0c\u987a\u5229\u5c06\u5bf9\u7fa7\u57fa\u82ef\u787c\u9178\u6c27\u5316\u6210\u5bf9\u7fa7\u57fa\u82ef\u915a\u3002\u968f\u540e\u4ee5LZU-190\u4e3a\u4f8b\u8fdb\u884c\u4e86\u5e95\u7269\u62d3\u5c55\u548c\u673a\u7406\u65b9\u9762\u7684\u7814\u7a76\uff0c\u5229\u7528ESR\u548c\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u673a\u7406\u3002<\/p>\n

\u56fe7. \u542b\u82ef\u5e76\u6076\u5511\u5355\u4f53\u7684COFs\u4e0e\u5149\u50ac\u5316\u6c27\u5316\u82ef\u787c\u9178\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

2019\u5e74Banerjee\u7ec4[8]<\/sup>\u57fa\u4e8e\u4e09\u55ea\u5355\u5143\u5408\u6210\u4e86\u4e00\u79cd\u7528\u4e8e\u5f02\u76f8\u5149\u50ac\u5316\u7684COFs\uff0c\u5c06\u5176\u547d\u540d\u4e3aTpTt\u3002\u8be5COFs\u5bf9\u53ef\u89c1\u5149\u6709\u660e\u663e\u7684\u5438\u6536\uff0c\u5728\u84dd\u5149\u4e8c\u6781\u7ba1\u7167\u5c04\u4e0b\uff0c\u901a\u8fc7\u5149\u50ac\u5316\u9014\u5f84\u53ef\u4ee5\u5c06\u53cd\u5f0f\u4e8c\u82ef\u4e59\u70ef\u8f6c\u5316\u4e3a\u987a\u5f0f\u4e8c\u82ef\u4e59\u70ef\u3002\u8be5\u5de5\u4f5c\u8fd8\u7814\u7a76\u4e86\u53ef\u89c1\u5149\u5bf9\u8fd9\u79cd\u8f6c\u6362\u7684\u91cd\u8981\u6027\uff0c\u5f53\u5149\u7167\u65f6\u53cd\u5e94\u5f00\u59cb\uff0c\u5f53\u95ed\u5149\u65f6\u8f6c\u6362\u505c\u6b62\uff0c\u8fd9\u8868\u660e\u53cd\u5e94\u662f\u901a\u8fc7\u5149\u50ac\u5316\u9014\u5f84\u53d1\u751f\u7684\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63a2\u7d22\u5149\u50ac\u5316\u7684\u673a\u7406\uff0c\u4f5c\u8005\u4f7f\u7528\u81ea\u7531\u57fa\u6dec\u706d\u5242TEMPO\u8fdb\u884c\u4e86\u53ef\u63a7\u5149\u50ac\u5316\u53cd\u5e94\uff0c\u5f53\u4f7f\u75284\u5f53\u91cf\u7684TEMPO\u65f6\uff0c\u987a\u5f0f\u4ea7\u7269\u7684\u4ea7\u7387\u663e\u8457\u964d\u4f4e\u52303%\uff0c\u8bc1\u5b9e\u81ea\u7531\u57fa\u7684\u5b58\u5728\u4ee5\u53ca\u5bf9\u4e8e\u5149\u50ac\u5316\u53cd\u5e94\u7684\u91cd\u8981\u6027\u3002\u5bf9\u4e8e\u4e0d\u540c\u53cd\u5f0f\u70ef\u70c3\u5e95\u7269\uff0cTpTt\u90fd\u663e\u793a\u51fa\u4e86\u826f\u597d\u7684\u5149\u5f02\u6784\u5316\u6536\u7387\u3002<\/p>\n

\u56fe8.\u70ef\u9187\u4e92\u53d8COFs\u4e0e\u5149\u50ac\u5316\u5f02\u6784\u5316\u6027\u80fd\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>\u00a0\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f<\/b><\/strong><\/h3>\n

2018\u5e74Jian Zhang\u548cJier Huang\u7b49[9]<\/sup>\u5408\u6210\u4e86\u542b\u6709\u4e09\u55ea\u6838\u7684\u4e09\u80fa\u5355\u4f53\u548c\u8054\u5421\u5576\u7684\u7ebf\u6027\u4e8c\u919b\u57fa\u5143\u7ec4\u5408\u7684COFs\uff0c\u901a\u8fc7\u540e\u4fee\u9970\u624b\u6bb5\u5c06Re\u7edc\u5408\u7269\u901a\u8fc7\u4e0e\u8054\u5421\u5576\u914d\u4f4d\u5c06\u5176\u56fa\u8f7d\u5230COFs\u6846\u67b6\u91cc\uff0c\u5e76\u6210\u529f\u5e94\u7528\u4e8eCO2<\/sub>\u7684\u8fd8\u539f\uff0c\u8f6c\u5316\u7387\u9ad8\u8fbe98%\uff08420 nm\u5149\u6e90\uff09\uff0cTON\u4e3a48\uff0c\u662f\u5176\u5747\u76f8\u50ac\u5316\u768422\u500d\u3002\u5229\u7528\u539f\u4f4d\u53cd\u5c04UV\u5149\u8c31\uff0c\u8bc1\u5b9e\u4e86\u5f71\u54cd\u7535\u8377\u5206\u79bb\u7684\u5173\u952e\u4e2d\u95f4\u4ea7\u7269\uff1aTEOA+<\/sup>-(COF-Re)–<\/sup>\u548cTEOA+<\/sup>-(COF-Re[CO2])–<\/sup>\u3002<\/p>\n

\u56fe9 \u8054\u5421\u5576COFs\u5408\u6210\u4e0e\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f<\/strong><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

2019\u5e74\u4e8e\u5ca9\u7b49[10]<\/sup>\u62a5\u9053\u4e86\u5355\u70b9Ni\u50ac\u5316\u4e2d\u5fc3\/COFs\u534f\u540c\u589e\u5f3a\u5149\u50ac\u5316\u9009\u62e9\u6027\u8fd8\u539fCO2<\/sub>\u5236CO\u7814\u7a76\u7684\u91cd\u8981\u8fdb\u5c55\u3002\u4e8e\u4e0a\u6587[9]<\/sup>\u7c7b\u4f3c\uff0c\u4f5c\u8005\u9996\u5148\u5408\u6210\u4e86\u8054\u5421\u5576\u7684COFs\uff0c\u901a\u8fc7\u5c06Ni\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u8f7d\u5165\u8054\u5421\u5576\u529f\u80fd\u5316\u7684COFs\u4e2d\uff0c\u5728\u542b\u6c34\u4f53\u7cfb\u548c\u53ef\u89c1\u5149\u7167\u5c04\u6761\u4ef6\u4e0b\uff0c\u5b9e\u73b0\u4e86\u5149\u50ac\u5316\u9009\u62e9\u6027\u8fd8\u539fCO2<\/sub>\u5236CO\u6027\u80fd\u7684\u5927\u5927\u589e\u5f3a\u3002\u5bf9\u6bd4\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0cCO2<\/sub>\u5206\u5b50\u53ef\u4ee5\u88ab\u7a33\u5b9a\u5728COFs\u5b54\u9053\u5185\u7684\u5355\u70b9Ni\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\uff0c\u8fdb\u800c\u88ab\u6709\u6548\u914d\u4f4d\u6d3b\u5316\u3002COFs\u4e2d\u7684\u916e\u70ef\u80fa\u8282\u70b9\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u663e\u8457\u964d\u4f4e\u4e86\u751f\u6210Ni-CO2<\/sub>\u4e2d\u95f4\u4f53\u7684Gibbs\u81ea\u7531\u80fd\uff0c\u5bf9\u4e8e\u63d0\u9ad8\u50ac\u5316\u53cd\u5e94\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u8d77\u91cd\u8981\u4f5c\u7528\u3002\u8be5\u5de5\u4f5c\u4e3a\u6784\u7b51\u57fa\u4e8eCOFs\u6750\u6599\u7684\u5355\u539f\u5b50\u4f4d\u70b9\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u6761\u65b0\u601d\u8def\u3002<\/p>\n

\u56fe10.\u5355\u539f\u5b50\u50ac\u5316\u4f4d\u70b9COFs\u5149\u50ac\u5316\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u4e09\uff1a\u603b\u7ed3<\/b><\/strong><\/h3>\n

\u7efc\u4e0a\uff0c\u76ee\u524dCOFs\u7528\u4e8e\u5149\u50ac\u5316\u9886\u57df\u8fd8\u5904\u4e8e\u521d\u7ea7\u9636\u6bb5\uff0c\u4e3b\u8981\u5de5\u4f5c\u96c6\u4e2d\u5728\u5149\u50ac\u5316\u4ea7\u6c22\u9886\u57df\u3002\u800c\u5728\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u548c\u5176\u4ed6\u6709\u673a\u53cd\u5e94\u7684\u5e94\u7528\u5f88\u5c11\u3002\u5728\u5149\u50ac\u5316\u4ea7\u6c22\u9886\u57df\uff0c\u76ee\u524d\u8fd8\u5b58\u5728\u6548\u7387\u4e0d\u9ad8\uff0c\u5927\u90e8\u5206\u9700\u8981\u8d35\u91cd\u91d1\u5c5ePt\u505a\u4e3a\u5149\u50ac\u5316\u5242\uff0c\u4ee5\u53ca\u9700\u8981\u727a\u7272\u5242\u7b49\u7269\u8d28\uff0c\u4e0d\u591f\u7ecf\u6d4e\u73af\u4fdd\u3002\u672a\u6765\u7684\u5de5\u4f5c\u9664\u4e86\u63d0\u9ad8\u4ea7\u6c22\u6548\u7387\u5916\uff0c\u5f00\u53d1\u66f4\u52a0\u7eff\u8272\u7ecf\u6d4e\u73af\u4fdd\u7684\u50ac\u5316\u5242\u4e5f\u662f\u91cd\u8981\u7684\u52aa\u529b\u65b9\u5411\u4e4b\u4e00\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong>\uff1a<\/b><\/strong><\/h3>\n

[1] Linus Stegbauer, Katharina Schwinghammer, Bettina V. Lotsch, A Hydrazone-Based Covalent Organic Framework for Photocatalytic Hydrogen Production. Chemical Science<\/i><\/em>, 2014<\/b><\/strong>, 5<\/i><\/em>, 2789-2793.<\/p>\n

[2] Jayshri Thote, Harshitha Barike Aiyappa, Aparna Deshpande, David D\u00edaz\u2005D\u00edaz, Sreekumar Kurungot, Rahul Banerjee, A Covalent Organic Framework\u2013Cadmium Sulfide Hybrid as a Prototype Photocatalyst for Visible-Light-Driven Hydrogen Production. Chemistry \u2013 A European Journal<\/i><\/em>, 2014<\/b><\/strong>, 20<\/i><\/em>, 15961-15965.<\/p>\n

[3] Tanmay Banerjee, Frederik Haase, G\u00f6kcen Savasci, Kerstin Gottschling, Christian Ochsenfeld, Bettina V. Lotsch, Single-Site Photocatalytic H2<\/sub>\u00a0Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts. Journal of the American Chemical Society<\/i><\/em>, 2017<\/b><\/strong>, 139<\/i><\/em>, 16228-16234.<\/p>\n

[4] Bishnu P. Biswal, Hugo A. Vignolo-Gonz\u00e1lez, Tanmay Banerjee, Lars Grunenberg, G\u00f6kcen Savasci, Kerstin Gottschling, J\u00fcrgen Nuss, Christian Ochsenfeld, Bettina V. Lotsch, Sustained Solar H2<\/sub>\u00a0Evolution from a Thiazolo[5,4-D]Thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water. Journal of the American Chemical Society<\/i><\/em>, 2019<\/b><\/strong>, 141<\/i><\/em>, 11082-11092.<\/p>\n

[5] Xiaoyan Wang, Linjiang Chen, Samantha Y. Chong, Marc A. Little, Yongzhen Wu, Wei-Hong Zhu, Rob Clowes, Yong Yan, Martijn A. Zwijnenburg, Reiner Sebastian Sprick, Andrew I. Cooper, Sulfone-Containing Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution from Water. Nature Chemistry<\/i><\/em>, 2018<\/b><\/strong>, 10<\/i><\/em>, 1180-1189.<\/p>\n

[6] Shuai Bi, Can Yang, Wenbei Zhang, Junsong Xu, Lingmei Liu, Dongqing Wu, Xinchen Wang, Yu Han, Qifeng Liang, Fan Zhang, Two-Dimensional Semiconducting Covalent Organic Frameworks Via Condensation at Arylmethyl Carbon Atoms. Nature Communications<\/i><\/em>, 2019<\/b><\/strong>, 10<\/i><\/em>, 2467.<\/p>\n

[7] Pi-Feng Wei, Ming-Zhu Qi, Zhi-Peng Wang, San-Yuan Ding, Wei Yu, Qiang Liu, Li-Ke Wang, Huai-Zhen Wang, Wan-Kai An, Wei Wang, Benzoxazole-Linked Ultrastable Covalent Organic Frameworks for Photocatalysis. Journal of the American Chemical Society<\/i><\/em>, 2018<\/b><\/strong>, 140<\/i><\/em>, 4623-4631.<\/p>\n

[8] Mohitosh Bhadra, Sharath Kandambeth, Manoj K. Sahoo, Matthew Addicoat, Ekambaram Balaraman, Rahul Banerjee, Triazine Functionalized Porous Covalent Organic Framework for Photo-Organocatalytic E\u2013Z Isomerization of Olefins. Journal of the American Chemical Society<\/i><\/em>, 2019<\/b><\/strong>, 141<\/i><\/em>, 6152-6156.<\/p>\n

[9] Sizhuo Yang, Wenhui Hu, Xin Zhang, Peilei He, Brian Pattengale, Cunming Liu, Melissa Cendejas, Ive Hermans, Xiaoyi Zhang, Jian Zhang, Jier Huang, 2D\u00a0Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO2<\/sub>\u00a0Reduction. Journal of the American Chemical Society<\/i><\/em>, 2018<\/b><\/strong>, 140<\/i><\/em>, 14614-14618.<\/p>\n

[10] Wanfu Zhong, Rongjian Sa, Liuyi Li, Yajun He, Lingyun Li, Jinhong Bi, Zanyong Zhuang, Yan Yu, Zhigang Zou, A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2<\/sub>\u00a0to CO. Journal of the American Chemical Society<\/i><\/em>, 2019<\/b><\/strong>, 141<\/i><\/em>, 7615-7621.<\/p>\n

[11]\u00a0\u5171\u4ef7\u6709\u673a\u6846\u67b6\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u3001\u8868\u5f81\u53ca\u5e94\u7528.\u738b\u6000\u9707; \u5170\u5dde\u5927\u5b66\u7855\u58eb\u8bba\u6587; 2015<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u77f3\u6960\u82b1\u843dSay-goodbye<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\uff1aCOF\u7b80\u4ecb COFs\uff08Covalent Organic Frameworks\uff0cCOFs\uff09\u662f\u4e00\u7c7b\u65b0\u578b\u7684\u57fa\u4e8e\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u6676\u6001\u6709\u673a\u591a\u5b54\u805a\u5408\u7269\uff0c\u5b83\u662f\u5229\u7528\u5171\u4ef7\u5316\u5b66\u53cd\u5e94…<\/p>\n","protected":false},"author":10213,"featured_media":182269,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-182256","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182256"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=182256"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182256\/revisions"}],"predecessor-version":[{"id":182677,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/182256\/revisions\/182677"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/182269"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=182256"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=182256"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=182256"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}