{"id":182918,"date":"2019-08-12T09:50:01","date_gmt":"2019-08-12T01:50:01","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=182918"},"modified":"2019-08-12T09:52:40","modified_gmt":"2019-08-12T01:52:40","slug":"%e3%80%90%e5%ae%a1%e7%a8%bf%e6%9c%aa%e9%80%9a%e8%bf%87%e3%80%91nano-energy%ef%bc%9a%e5%a3%b3%e7%bb%93%e6%9e%84%e9%94%8c%e9%92%b4%e5%8f%8c%e9%87%91%e5%b1%9e%e7%a1%ab%e5%8c%96%e7%89%a9%e6%b0%ae","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=182918","title":{"rendered":"Nano Energy\uff1a\u58f3\u7ed3\u6784\u950c\u94b4\u53cc\u91d1\u5c5e\u786b\u5316\u7269@\u6c2e\u63ba\u6742\u78b3\u7528\u4e8e\u589e\u5f3a\u9502\u79bb\u5b50\u5b58\u50a8"},"content":{"rendered":"<p>\u3010\u80cc\u666f\u3011<\/p>\n<p>\u7531\u4e8e\u9ad8\u5bb9\u91cf\uff0c\u4f4e\u6210\u672c\u548c\u73af\u5883\u53cb\u597d\u6027\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09\u7684\u6f5c\u5728\u9633\u6781\u6750\u6599\u5df2\u5f15\u8d77\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5927\u7684\u4f53\u79ef\u53d8\u5316\u548c\u7f13\u6162\u7684\u52a8\u529b\u5b66\uff0c\u5b83\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u53d7\u5230\u8f83\u5dee\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u901f\u7387\u80fd\u529b\u7684\u963b\u788d\u3002\u8fd9\u91cc\uff0c\u62a5\u9053\u4e86\u5177\u6709\u589e\u5f3a\u7684\u9502\u50a8\u5b58\u7684\u86cb\u9ec4-\u58f3\u7ed3\u6784\u7684\u950c- \u94b4\u4e8c\u5143\u91d1\u5c5e\u786b\u5316\u7269@N-\u63ba\u6742\u7684\u78b3\u590d\u5408\u7269\uff08Zn-Co-S@NC\uff09\u3002\u5728\u8fd9\u79cd\u590d\u5408\u6750\u6599\u4e2d\uff0c\u72ec\u7279\u7684\u591a\u5b54\u58f3\u7ed3\u6784\u7f29\u77ed\u4e86Li\u00a0<sup>+<\/sup>\/e\u00a0<sup>&#8211;<\/sup>\u6269\u6563\u8ddd\u79bb\uff0c\u5e76\u63d0\u4f9b\u8db3\u591f\u7684\u7a7a\u9699\u7a7a\u95f4\u4ee5\u9002\u5e94Li\u00a0<sup>+<\/sup>\u63d2\u5165\/\u63d0\u53d6\u8fc7\u7a0b\u7684\u4f53\u79ef\u53d8\u5316\u3002N\u63ba\u6742\u78b3\u7684\u5b58\u5728\u4e0d\u4ec5\u589e\u5f3a\u4e86\u7535\u5b50\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u800c\u4e14\u8fd8\u6539\u5584\u4e86\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u53cc\u91d1\u5c5e\u786b\u5316\u7269\u589e\u5f3a\u4e86\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u4f18\u5f02\u7684\u9502\u50a8\u5b58\u5e76\u51cf\u5c11\u4e86\u526f\u4ea7\u7269\u7684\u5f62\u6210\u3002\u5c06\u6240\u5f97\u7684Zn-Co-S@NC\u9633\u6781\u5c55\u73b0\u663e\u8457\u589e\u5f3a\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff081000mA\u202fg<sup>\u22121 <\/sup>300\u6b21\u5faa\u73af\u4e4b\u540e\u4e3a667.7 mAh g<sup>\u22121<\/sup>\uff09\u548c\u500d\u7387\u6027\u80fd\uff085000 mA\u202fg<sup>\u22121<\/sup>\u65f6\u4e3a332.2 mAh g<sup>\u22121<\/sup>\uff09\u3002<\/p>\n<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n<p>\u8fd1\u671f\uff0c\u5e7f\u4e1c\u5de5\u4e1a\u5927\u5b66\u9b4f\u79c0\u5a1f\uff0c\u6797\u5c55\u548c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u5171\u540c\u901a\u8baf\u5728<strong>Nano Energy<\/strong>\u671f\u520a\u4e0a\u53d1\u8868\u9898\u4e3a<strong>\u201cYolk-shell-structured zinc-cobalt binary metal sulfide @ N-doped carbon for<br \/>\n enhanced lithium-ion storage\u201d<\/strong>\u7684\u7814\u7a76\u8bba\u6587\u3002\u7814\u7a76\u8005\u91c7\u7528MOFs\u53c2\u4e0e\u7b56\u7565\u8bbe\u8ba1\u5e76\u5236\u9020\u4e86\u5177\u6709\u86cb\u9ec4\u58f3\u7ed3\u6784\u7684CoS\/Zn<sub>0.754<\/sub>Co<sub>0.246<\/sub>S @ N-\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599(Zn-Co-S@NC)\u3002\u8fd9\u4e9b\u72ec\u7279\u7684\u86cb\u9ec4\u58f3\u7ed3\u6784\u7684Zn-Co-S@N-C\u591a\u9762\u4f53\u7531\u5e73\u5747\u5c3a\u5bf8\u4e3a90nm\u7684Zn-Co-S\u6838\u548c\u539a\u5ea6\u4e3a15nm\u7684N-\u63ba\u6742\u78b3\u58f3\u7ec4\u6210\u3002\u5728\u7eb3\u7c73\u7ed3\u6784\u4e2d\uff0cZn-Co-S\u6838\u5177\u6709\u9ad8\u7684\u8f7d\u6d41\u5b50\u80fd\u529b\uff0c\u6240\u5236\u5907\u7684\u5b54\u9699\u7a7a\u95f4\u53ef\u4ee5\u7f13\u89e3\u8f83\u5927\u7684\u4f53\u79ef\u53d8\u5316\u3002\u6b64\u5916\uff0cN\u63ba\u6742\u7684\u78b3\u58f3\u5c42\u53ef\u4ee5\u63d0\u9ad8\u6574\u4f53\u7535\u5bfc\u7387\u3002\u5229\u7528\u4e0a\u8ff0\u4f18\u70b9\uff0c\u5236\u5907\u7684\u86cb\u9ec4\u58f3\u7ed3\u6784Zn-Co-S@N-C\u591a\u9762\u4f53\u5177\u6709\u8f83\u9ad8\u7684\u9502\u5b58\u50a8\u5bb9\u91cf\u3001\u4f18\u5f02\u7684\u901f\u7387\u6027\u80fd\u548c\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p><a href=\"mailto:\u56fe1.Zn-Co-S@N-C\">\u56fe1. Zn-Co-S@N-C<\/a>\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-182919\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-5.png\" alt=\"\" width=\"600\" height=\"313\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-5.png 1038w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-5-300x156.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-5-768x400.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-5-1024x534.png 1024w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) Zn\/Co-ZIF-67 \u548c Co-ZIF-67 \u524d\u9a71\u4f53\u7684XRD\u56fe\uff1b<\/p>\n<p>(b) Zn\/Co-ZIF-67@P\u548cCo-ZIF-67@PDA\u7684XRD\u56fe\uff1b<\/p>\n<p>(c) Zn-Co-S@N-C\u548cCoS@N-C \u7684XRD\u56fe\uff1b<\/p>\n<p>(d) Zn-Co-S@N-C\u548cCoS@N-C\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n<p>(e\uff0cf) Zn-Co-S@N-C\u548cCoS@N-C\u7684N<sub>2<\/sub>\u5438\u9644\u8131\u5438\u9644\u66f2\u7ebf\u3002<\/p>\n<p>\u56fe3. Zn-Co-S@N-C \u7684XPS\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-182920\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-4.png\" alt=\"\" width=\"600\" height=\"322\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-4.png 1029w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-4-300x161.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-4-768x413.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-4-1024x550.png 1024w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5168\u8c31; (b) Co 2p\u8c31\u56fe; (c) Zn 2p\u8c31\u56fe, (d) S 2p\u8c31\u56fe, (e) N 1s\u8c31\u56fe, and (f) C 1s\u8c31\u56fe\u3002<\/p>\n<p>\u56fe4. \u7535\u955c\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-182921 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-5.png\" alt=\"\" width=\"635\" height=\"455\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-5.png 635w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-5-300x215.png 300w\" sizes=\"(max-width: 635px) 100vw, 635px\" \/><\/p>\n<p>(a-c) Zn\/Co-ZIF-67, Zn\/Co-ZIF-67@PDA, Zn-Co-S@N-C\u7684SEM\u56fe;<\/p>\n<p>(d\uff0ce) Zn-Co-S@N-C \u7684TEM\u56fe\uff1b<\/p>\n<p>(f) Zn-Co-S@N-C \u7684HRTEM\u6676\u683c\u56fe\uff1b<\/p>\n<p>(g) Zn-Co-S@N-C \u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n<p>\u56fe5. \u5236\u5907\u7684Zn-Co-S@N-C\u3001CoS@N-C\u548cCoS\/N-C\u4e09\u79cd\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-182922\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-4.png\" alt=\"\" width=\"600\" height=\"311\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-4.png 1039w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-4-300x156.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-4-768x398.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-4-1024x531.png 1024w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5728200 mA g<sup>-1<\/sup>\u4e0bZn-Co-S@N-C\u7535\u6781\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>(b) \u5728200 mA g<sup>-1<\/sup>\u4e0bZn-Co-S@N-C,CoS@N-C\u548cCoS\/N-C\u7535\u6781\u5faa\u73af\u6027\u80fd\u8ddf\uff1b<\/p>\n<p>(c) \u57281000 mA g<sup>-1<\/sup>\u4e0bZn-Co-S@N-C\u7535\u6781\u7684\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n<p>(d) \u5728\u4e0d\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0bZn-Co-S@N-C\u7535\u6781\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>(e) \u7535\u6d41\u5bc6\u5ea6\u4ece200 mA g<sup>-1<\/sup>\u52301000 mA g<sup>-1<\/sup>\uff0cZn-Co-S@N-C,CoS@N-C\u548cCoS\/N-C\u7535\u6781\u4e94\u4e2a\u5faa\u73af\u4e4b\u540e\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n<p>(f) Zn-Co-S@N-C, CoS@N-C and CoS\/N-C\u7535\u6781\u7684\u963b\u6297\u8c31\u56fe\u3002<\/p>\n<p>\u56fe6. \u53cd\u5e94\u80fd\u8bc4\u4f30<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-182923\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/5-3.png\" alt=\"\" width=\"600\" height=\"257\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/5-3.png 777w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/5-3-300x129.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/5-3-768x329.png 768w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a\uff0cb) ZnS\u548cCoS\u9633\u6781\u7684\u9502\u5316\u548c\u8131\u786b\u53cd\u5e94\u7684\u53cd\u5e94\u80fd(Er)\u3002\u5b9e\u7ebf\u8868\u793a\u4e3b\u8981\u53cd\u5e94\uff0c\u77ed\u865a\u7ebf\u8868\u793a\u653e\u7535\u548c\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u526f\u53cd\u5e94\u6216\u526f\u4ea7\u54c1\u3002<\/p>\n<p>\u3010\u7ed3\u8bba\u3011<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u91c7\u7528\u7b80\u5355\u7684MOF\u53c2\u4e0e\u7b56\u7565\u6210\u529f\u5236\u5907\u4e86\u5177\u6709\u86cb\u9ec4\u58f3\u7ed3\u6784\u7684CoS\/Zn<sub>0.754<\/sub>Co<sub>0.246<\/sub>S@N\u63ba\u6742\u78b3\u590d\u5408\u6750\u6599\u3002\u4f5c\u4e3a\u9502\u7535\u6c60\u7684\u9633\u6781\u6750\u6599\uff0c\u5b83\u5177\u6709\u826f\u597d\u7684\u901f\u7387\u5bb9\u91cf\u3001\u9ad8\u5e93\u4ed1\u6548\u7387\u548c\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7279\u522b\u662fZn-Co-S@N-C\u590d\u5408\u6750\u6599\u5728\u7ecf\u8fc7300\u6b21\u5faa\u73af\u540e\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1000 mA g<sup>-1<\/sup>\u7684\u60c5\u51b5\u4e0b\uff0c\u5176\u53ef\u9006\u5bb9\u91cf\u4e3a667.7 mAh g<sup>-1<\/sup>\uff0c\u5177\u6709\u826f\u597d\u7684\u9502\u5b58\u50a8\u6027\u80fd\uff0c\u5728\u9ad8\u6027\u80fd\u50a8\u80fd\u5668\u4ef6\u4e2d\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002Zn-CoS@N-C\u590d\u5408\u6750\u6599\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u5f52\u529f\u4e8e\u5176\u72ec\u7279\u7684\u591a\u5b54\u86cb\u9ec4\u58f3\u7ed3\u6784\u3001N\u63ba\u6742\u78b3\u57fa\u4f53\u4ee5\u53ca\u591a\u79cd\u91d1\u5c5e\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5b9e\u9a8c\u548c\u7406\u8bba\u5206\u6790\u5747\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\u3002\u6211\u4eec\u7684\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u9502\u9502\u7535\u6c60\u5f00\u53d1\u4e86\u4e00\u79cd\u6781\u5177\u53d1\u5c55\u524d\u666f\u7684\u9633\u6781\u6750\u6599\uff0c\u800c\u4e14\u4e3a\u8bbe\u8ba1\u5176\u4ed6\u7528\u4e8e\u9ad8\u6548\u50a8\u80fd\u7684\u591a\u7ec4\u5206\u91d1\u5c5e\u786b\u7cfb\u9633\u6781\u6750\u6599\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5<\/p>\n<p><strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285519306068#appsec1\">Yolk-shell-structured zinc-cobalt binary metal sulfide @ N-doped carbon for enhanced lithium-ion storage<\/a><\/strong><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91luna\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u5fae\u4fe1cailiaorenvip<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u3011 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