{"id":184036,"date":"2019-08-24T06:30:29","date_gmt":"2019-08-23T22:30:29","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=184036"},"modified":"2019-08-23T17:34:40","modified_gmt":"2019-08-23T09:34:40","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%a4%8d%e6%97%a6%e5%88%98%e6%99%ba%e6%94%80%e5%92%8c%e5%90%8c%e6%b5%8e%e9%9f%a6%e5%b9%bf%e4%b8%b0ees%ef%bc%9a%e8%b6%85%e8%b6%8a%e9%93%82%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=184036","title":{"rendered":"\u590d\u65e6\u5218\u667a\u6500\u548c\u540c\u6d4e\u97e6\u5e7f\u4e30EES\uff1a\u8d85\u8d8a\u94c2\u7684\u91d1\u5c5e\u787c\u5316\u7269\u2014\u2014\u8d85\u9ad8\u672c\u5f81\u6d3b\u6027Pd2B\u6790\u6c22\u53cd\u5e94\u50ac\u5316\u5242"},"content":{"rendered":"<p>\u3010\u524d\u8a00\u3011<\/p>\n<p>\u6c34\u88c2\u89e3\u8fc7\u7a0b\u4e2d\u7684\u4ece\u8d28\u5b50\u5230\u6c22\u6c14\u8f6c\u6362\u53cd\u5e94\uff08\u6790\u6c22\u53cd\u5e94\uff0cHER\uff0c2H<sup>+<\/sup>+2e<sup>&#8211;<\/sup>\u2192H<sub>2<\/sub>\uff09\uff0c\u662f\u83b7\u53d6\u6e05\u6d01\u6c22\u80fd\u7684\u91cd\u8981\u624b\u6bb5\uff0c\u56e0\u6b64\u8be5\u53cd\u5e94\u88ab\u8ba4\u4e3a\u662f\u5411\u6e05\u6d01\u80fd\u6e90\u793e\u4f1a\u53d1\u5c55\u7684\u91cd\u8981\u5316\u5b66\u53cd\u5e94\u3002\u7136\u800c\uff0c\u8be5\u53cd\u5e94\u901a\u5e38\u9700\u8981\u4ee5\u94c2\uff08Pt\uff09\u4e3a\u57fa\u7840\u7684\u6750\u6599\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u50ac\u5316\u5242\u6210\u672c\u9ad8\u3001\u957f\u671f\u7a33\u5b9a\u6027\u4e0d\u8db3\uff0c\u5f88\u5927\u7a0b\u5ea6\u4e0a\u9650\u5236\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002<\/p>\n<p>\u8fd1\u671f\uff0c\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u5218\u667a\u6500\u8bfe\u9898\u7ec4\u548c\u540c\u6d4e\u5927\u5b66\u5316\u5b66\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u97e6\u5e7f\u4e30\u8bfe\u9898\u7ec4\u57fa\u4e8e\u91cf\u5b50\u529b\u5b66\u7406\u8bba\u7814\u7a76\u9884\u6d4b\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u6eb6\u5242\u70ed\u6cd5\u5408\u6210\u7684\u78b3\u8d1f\u8f7dPd<sub>2<\/sub>B\u7eb3\u7c73\u7247\u3002\u5b9e\u9a8c\u8868\u660e\u8be5Pd<sub>2<\/sub>B\u7eb3\u7c73\u7247\u5177\u6709\u8d85\u4f4e\u7684HER\u8fc7\u7535\u4f4d\uff0c\u572810 mA\/cm<sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u4f4d\u4ec5\u4e3a15.3 mV\uff0cTafel\u659c\u7387\u4e3a22.5 mV\/Dec\uff0c\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\uff08j<sub>0<\/sub>\uff09\u8fbe\u52302.84 mA\/cm<sup>2<\/sup>\u3002\u5b9e\u9a8c\u8fd8\u8868\u660e\u8be5\u91d1\u5c5e\u787c\u5316\u7269\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u5177\u6709\u521b\u8bb0\u5f55\u7684\u9ad8\u672c\u5f81\u6d3b\u6027\uff0c\u6bd4\u5546\u4e1a\u5316\u7684Pt\/C\u50ac\u5316\u5242\u9ad8\u7ea62\u500d\uff0c\u5e76\u4e14\u5728\u53cd\u5e94\u6761\u4ef6\u4e0b\u5177\u6709\u5f88\u9ad8\u7684\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cMetal Boride Better Than Pt: HCP Pd<sub>2<\/sub>B as Superactive Hydrogen Evolution Reaction Catalyst\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u4e8e\u80fd\u6e90\u548c\u73af\u5883\u9886\u57df\u9876\u7ea7\u671f\u520a\u300aEnergy &amp; Environmental Science\u300b\uff08DOI: 10.1039\/C9EE01564G\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184037 size-large\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-22-1024x501.png\" alt=\"\" width=\"1024\" height=\"501\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-22-1024x501.png 1024w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-22-300x147.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-22-768x376.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-22.png 1326w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/p>\n<p>\u6700\u65b0\u7684\u91cf\u5b50\u5316\u5b66\u6a21\u62df\u7814\u7a76\u8868\u660e\uff0c\u94c2\u50ac\u5316\u5242\u7684\u9ad8\u6d3b\u6027\u539f\u5b50\u5f88\u5927\u7a0b\u5ea6\u4e0a\u6765\u6e90\u4e8e\u4f4d\u4e8e\u50ac\u5316\u5242\u8d85\u5c0f\u7eb3\u7c73\u9897\u7c92\u7684\u9876\u70b9\u7684\u9ad8\u6d3b\u6027\u4f4d\uff0c\u800c\u8fd9\u4e9b\u9876\u70b9\u7684\u6d3b\u6027\u4f4d\u5bb9\u6613\u5728\u5b9e\u9645\u53cd\u5e94\u6761\u4ef6\u4e0b\u968f\u7740\u7eb3\u7c73\u7c92\u5b50\u56e2\u805a\u800c\u4e22\u5931\u3002\u8be5\u5de5\u4f5c\u7684\u7814\u7a76\u91cd\u70b9\u5219\u662f\u5e0c\u671b\u5bfb\u627e\u5230\u4e00\u79cd\u80fd\u591f\u5728\u539f\u5b50\u7d27\u5bc6\u5806\u79ef\u7684\u8868\u9762\u4e0a\u5c55\u73b0\u51fa\u9ad8\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\u7684\u6676\u4f53\u6750\u6599\u3002\u5229\u7528\u57fa\u4e8e\u7b2c\u4e00\u6027\u539f\u7406\u7684\u52bf\u80fd\u9762\u968f\u673a\u884c\u8d70\u5168\u5c40\u4f18\u5316\u6280\u672f\uff0c\u7814\u7a76\u56e2\u961f\u6700\u8fd1\u7684\u7814\u7a76(Wei et.al., Phys. Chem. Chem. Phys., 2018, 20, 27752\uff0c\u5165\u90092018 PCCP \u70ed\u70b9\u8bba\u6587)\u53d1\u73b0\uff0cPd-B\u80fd\u591f\u590d\u5408\u5f62\u6210\u7a33\u5b9a\u7684\u5177\u6709\u91d1\u5c5e\u6027\u7684\u5757\u4f53\u787c\u5316\u7269\uff0c\u800c\u70ed\u529b\u5b66\u4e0a\u6700\u7a33\u5b9a\u7684Pd\u787c\u5316\u7269\u76f8\u5219\u662f\u5177\u6709\u516d\u65b9\u5bc6\u5806\uff08hcp\uff09\u7ed3\u6784\u7684Pd<sub>2<\/sub>B\u76f8\u3002\u7406\u8bba\u7814\u7a76\u8fdb\u4e00\u6b65\u9884\u6d4b\uff0cPd<sub>2<\/sub>B\u80fd\u591f\u5177\u6709\u6bd4\u7eaf\u94c2\u66f4\u9ad8\u7684\u672c\u5f81\u6d3b\u6027\uff0c\u56e0\u6b64Pd<sub>2<\/sub>B\u88ab\u786e\u5b9a\u4e3a\u5408\u9002\u7684\u5019\u9009\u6750\u6599\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184041 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-19.png\" alt=\"\" width=\"1142\" height=\"520\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-19.png 1142w, 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184040 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-20.png\" alt=\"\" width=\"878\" height=\"471\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-20.png 878w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-20-300x161.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-20-768x412.png 768w\" sizes=\"(max-width: 878px) 100vw, 878px\" \/><\/p>\n<p>\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u7a76\u5f00\u53d1\u8ba1\u5212\uff082018YFA0208600\uff09\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0821533001, 91745201, 21603165\u300121573149\uff09\u3001\u4e0a\u6d77\u5e02\u9752\u5e74\u79d1\u6280\u82f1\u624d\u626c\u5e06\u8ba1\u5212\uff0816YF1412300\uff09\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u590d\u65e6\u5927\u5b66\u9648\u6797\uff0c\u5408\u8457\u8005\u5305\u62ec\u540c\u6d4e\u5927\u5b6616\u7ea7\u7855\u58eb\u751f\u7ae0\u73b2\u7136\u3001\u4e0a\u6d77\u5e02\u5e94\u7528\u6280\u672f\u5927\u5b6617\u7ea7\u7855\u58eb\u751f\u59da\u51cc\u71d5\u3001\u4e0a\u6d77\u5e02\u5e94\u7528\u6280\u672f\u5927\u5b66\u65b9\u4e9a\u8f89\u526f\u6559\u6388\u3001\u4e2d\u79d1\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u4f55\u6797\u7814\u7a76\u5458\uff0c\u97e6\u5e7f\u4e30\u8001\u5e08\u4e0e\u5218\u667a\u6500\u6559\u6388\u4e3a\u8be5\u8bba\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p>\u901a\u8fc7\u7406\u8bba\u9884\u6d4bPd-B\u590d\u5408\u4f53\u7cfb\u7684\u76f8\u5bf9\u751f\u6210\u80fd\u56fe\uff08\u56fe1a\uff09\uff0c\u53ef\u4ee5\u770b\u5230\u968f\u7740B\u542b\u91cf\u7684\u589e\u52a0\uff0cPd<sub>x<\/sub>B\u7684\u6700\u7a33\u5b9a\u76f8\u7ed3\u6784\u9010\u6e10\u4ecefcc\u7ed3\u6784\u5411hcp\u7ed3\u6784\u8f6c\u53d8\uff0c\u800cPd<sub>2<\/sub>B\u5728\u6240\u6709\u7ec4\u5206\u4e2d\u5177\u6709\u6700\u8d1f\u7684\u76f8\u5bf9\u751f\u6210\u80fd\uff0c\u56e0\u800c\u88ab\u786e\u5b9a\u4e3aPd-B\u590d\u5408\u4f53\u7cfb\u5404\u7ec4\u5206\u4e2d\u70ed\u529b\u5b66\u6700\u7a33\u5b9a\u7684\u4f53\u76f8\u7ed3\u6784\u3002\u5b9e\u9a8c\u5219\u901a\u8fc7\u4e24\u6b65\u6cd5\u5148\u5728100<sup>o<\/sup>C\u53cd\u5e943\u5c0f\u65f6\u5408\u6210\u5230Pd\u7684\u7eb3\u7c73\u7247\uff0c\u518d\u52a0\u5165B\u6e90\uff08Me<sub>2<\/sub>NH-BH<sub>3<\/sub>\uff09\u5728THF\u6eb6\u5242\u4e2d\uff0c\u4e0d\u540c\u6e29\u5ea6\u4e0b\u6eb6\u5242\u70ed\u53cd\u5e942\u5c0f\u65f6\u5408\u6210\u5f97\u5230Pd<sub>x<\/sub>B NS\/C\u3002HRTEM\u8868\u5f81\u663e\u793aPd<sub>2<\/sub>B NS\u5177\u6709\u4e0e\u7406\u8bba\u9884\u6d4b\u4e00\u81f4\u7684\u7ed3\u6784\uff0c\u4eceXRD\u7ed3\u679c\u4e2d\u4e5f\u53ef\u4ee5\u8bc1\u5b9e\u968f\u7740\u6c34\u70ed\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u5408\u6210\u5f97\u5230\u7684Pd<sub>x<\/sub>B NS\/C\u9010\u6e10\u7531fcc\u7ed3\u6784\u5411hcp\u7ed3\u6784\u8f6c\u53d8\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184136 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-23.png\" alt=\"\" width=\"675\" height=\"553\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-23.png 675w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/1-23-300x246.png 300w\" sizes=\"(max-width: 675px) 100vw, 675px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong> (a) \u7406\u8bba\u8ba1\u7b97\u83b7\u5f97\u7684Pd-B\u590d\u5408\u4f53\u7cfb\u7684\u76f8\u5bf9\u751f\u6210\u80fd\u56fe\u3002(b) hcp Pd<sub>2<\/sub>B\u6676\u4f53\u7684\u7406\u8bba\u8ba1\u7b97\u7ed3\u6784\u3002(c) Pd<sub>2<\/sub>B NS\/C\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe\u3002(d-e) Pd<sub>2<\/sub>B NS\u7684HRTEM\u56fe\u50cf\u548cEDS \u5143\u7d20\u5206\u5e03\u56fe\u3002\u5185\u90e8\u662f(d)\u4e2d\u77e9\u5f62\u533a\u57df\u7684\u653e\u5927\u56fe\u50cf\u3002(f)\u4e0d\u540c\u53cd\u5e94\u6e29\u5ea6\u4e0bPd (fcc)\u9010\u6e10\u5411Pd<sub>2<\/sub>B (hcp)\u8f6c\u53d8\u7684XRD\u56fe\u8c31\u3002<\/p>\n<p>\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u68c0\u9a8c\u4e86\u4e0d\u540cPd<sub>x<\/sub>B NS\/C\u7684\u7535\u50ac\u5316HER\u6027\u80fd\u3002\u56fe2\u4e2d\u7684\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\u968f\u7740B\u542b\u91cf\u7684\u589e\u52a0\u4e0ePd<sub>2<\/sub>B\u7684\u5f62\u6210\uff0c\u6750\u6599\u7684HER\u6d3b\u6027\u5f97\u5230\u4e86\u663e\u8457\u63d0\u5347\u3002Pd<sub>2<\/sub>B NS\/C\u5355\u4f4d\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef(ECSA)\u7684\u6d3b\u6027(specific activity, SA) \u6bd4\u5546\u4e1a\u5316Pt\/C\u50ac\u5316\u5242\u63d0\u9ad8\u4e861\u500d\u591a\uff0c\u4e14\u53cd\u5e94\u7684\u8fc7\u7535\u4f4d\u572810 mA cm<sup>-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u65f6\u4ec5\u4e3a15.3 mV\uff0c\u5c0f\u4e8e\u7edd\u5927\u90e8\u5206\u6587\u732e\u4e2d\u62a5\u9053\u7684\u4e3b\u6d41\u6790\u6c22\u53cd\u5e94\u50ac\u5316\u6750\u6599\u3002\u540c\u65f6Pd<sub>2<\/sub>B NS\/C\u7684Tafel\u659c\u7387\u4ec5\u4e3a22.5 mV\/Dec\uff0c\u8ba1\u7b97\u5f97\u5230\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6(j<sub>0<\/sub>)\u8fbe\u52302.84 mA cm<sup>-2<\/sup>\uff0c\u663e\u8457\u9ad8\u4e8e\u662f\u5546\u4e1a\u5316Pt\/C\u76840.92 mA cm<sup>-2<\/sup>\u3002\u8fd9\u4e9b\u7ed3\u679c\u5747\u8868\u660e\u5177Pd<sub>2<\/sub>B NS\/C\u5177\u6709\u66f4\u4e3a\u4f18\u8d8a\u7684\u672c\u5f81\u7535\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184137 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-23.png\" alt=\"\" width=\"803\" height=\"420\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-23.png 803w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-23-300x157.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/2-23-768x402.png 768w\" sizes=\"(max-width: 803px) 100vw, 803px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong> (a) Pd NS\/C\u3001Pd<sub>x<\/sub>B NS\/C\u548c\u5546\u7528Pt\/C\u57280.5 M H<sub>2<\/sub>SO<sub>4<\/sub>\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u7387\u4e3a1mV s<sup>-1<\/sup>\u3002(b) ECSA\u5f52\u4e00\u5316\u540e\u7684\u6781\u5316\u66f2\u7ebf\u3002(c) \u572850 mV\u8fc7\u7535\u4f4d\u4e0b\u4e0d\u540c\u6750\u6599\u7684\u8868\u9762\u6bd4\u6d3b\u6027\u3002(d) Pd<sub>2<\/sub>B NS\/C\u548c\u6587\u732e\u4e2d\u5178\u578b\u7684\u9178\u6027\u6eb6\u6db2HER\u50ac\u5316\u5242\u7684\u8fc7\u7535\u4f4d\u5bf9\u6bd4\u3002(e) Tafel \u659c\u7387\u3002(f) \u521d\u59cb\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm<sup>-2<\/sup>\u6761\u4ef6\u4e0b\uff0cPd\u3001Pt\u3001Pd<sub>2<\/sub>B\u50ac\u5316\u5242\u7684\u6052\u7535\u4f4di-t\u66f2\u7ebf\u3002<\/p>\n<p>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86B\u539f\u5b50\u5728Pd\u548cPd<sub>2<\/sub>B\u6676\u683c\u4e2d\u7684\u8fc1\u79fb\u548c\u8868\u9762B\u539f\u5b50\u7684\u5d4c\u5165\u673a\u5236\uff08\u56fe3\uff09\u3002\u7814\u7a76\u53d1\u73b0\u4e0d\u8bba\u5728\u7eafPd\u8fd8\u662f\u5728Pd<sub>2<\/sub>B\u6676\u683c\u4e2d\uff0cB\u539f\u5b50\u603b\u662f\u503e\u5411\u4e8e\u4f4d\u4e8ePd\u5b50\u6676\u683c\u7684\u516b\u9762\u4f53\u7a7a\u9699\u5f53\u4e2d\u5f62\u6210B-Pd<sub>6<\/sub>\u7684\u7ed3\u6784\u5355\u5143\uff0c\u800c\u5f53B\u4f4d\u4e8ePd\u5b50\u6676\u683c\u7684\u56db\u9762\u4f53\u7a7a\u9699\u4e2d\u65f6\u5219\u663e\u5f97\u5f88\u4e0d\u7a33\u5b9a\u3002\u4e00\u65b9\u9762\u5728Pd<sub>2<\/sub>B\u7684hcp\u6676\u683c\u4e2d\uff0cB\u539f\u5b50\u53ef\u4ee5\u4ece\u4e00\u4e2a\u516b\u9762\u4f53\u7a7a\u9699\u76f4\u63a5\u6269\u6563\u5230\u76f8\u90bb\u7684\u53e6\u4e00\u4e2a\u516b\u9762\u4f53\u7a7a\u9699\uff0c\u800c\u5728\u7eafPd\u7684fcc\u6676\u683c\u4e2d\uff0cB\u539f\u5b50\u5fc5\u987b\u7a7f\u8fc7fcc\u6676\u683c\u4e2d\u7684\u56db\u9762\u4f53\u7a7a\u9699\u624d\u80fd\u8fdb\u5165\u53e6\u4e00\u4e2a\u516b\u9762\u4f53\u7a7a\u9699\uff1b\u53e6\u4e00\u65b9\u9762\u4e0e\u7eafpd\u76f8\u6bd4\uff0cPd<sub>2<\/sub>B\u7684\u6676\u683c\u81a8\u80c0\u4e86\u7ea69%\uff0c\u6709\u52a9\u4e8e\u7a33\u5b9a\u6269\u6563\u8fc7\u7a0b\u4e2d\u7684\u8fc7\u6e21\u6001\u3002\u7531\u4e8e\u8fd9\u4e24\u65b9\u9762\u539f\u56e0\u4f7f\u5f97Pd<sub>2<\/sub>B\u6676\u683c\u4e2dB\u6269\u6563\u7684\u52bf\u5792(0.55 eV)\u8981\u663e\u8457\u4f4e\u4e8e\u5176\u5728\u7eafPd\u4e2d\u7684\u6269\u6563\u52bf\u5792(1.69 eV)\u3002\u8fd9\u610f\u5473\u7740\u5728\u4f53\u76f8\u7ed3\u6784\u4ecefcc\u5230hcp\u76f8\u53d8\u5c06\u4f1a\u663e\u8457\u4fc3\u8fdbB\u539f\u5b50\u7684\u6269\u6563\u3002<\/p>\n<p>\u56fe3b\u7ed9\u51fa\u4e86B\u539f\u5b50\u4ece\u8868\u9762\u9010\u6b65\u5d4c\u5165Pd\u6676\u683c\u6700\u7ec8\u5f62\u6210\u8868\u9762Pd<sub>2<\/sub>B\u7684\u8be6\u7ec6\u673a\u5236\u3002\u9996\u5148\u5728Pd\u8868\u9762\u7684B\u539f\u5b50(\u56fe\u4e2d\u72b6\u60011)\u80fd\u591f\u4ee5\u5f88\u4f4e\u7684\u52bf\u5792(0.32 eV)\u6269\u6563\u8fdb\u5165\u8868\u9762\u4e0b\u516b\u9762\u4f53\u7a7a\u9699\u4ece\u800c\u5f62\u6210\u6b21\u8868\u5c42B\u539f\u5b50(\u56fe\u4e2d\u72b6\u60012)\uff0c\u5e76\u663e\u8457\u653e\u70ed\u3002\u968f\u7740B\u539f\u5b50\u7684\u9010\u6e10\u5d4c\u5165\uff0c\u5728Pd\u6b21\u8868\u5c42\u7684B\u539f\u5b50\u6d53\u5ea6\u9010\u6e10\u5347\u9ad8\u81f30.5\u4e2a\u5355\u539f\u5b50\u5c42(monolayer, ML) (\u56fe\u4e2d\u72b6\u60013)\uff0c\u6574\u4e2a\u8fc7\u7a0b\u7684\u603b\u653e\u70ed\u8fbe\u52304.33 eV\u3002\u6b64\u65f6\uff0cB\u539f\u5b50\u8fdb\u4e00\u6b65\u6269\u6563\u5230fcc\u6676\u683c\u7684\u66f4\u6df1\u5c42(\u4ece\u72b6\u60013\u5230\u72b6\u60015)\uff0c\u7531\u4e8e\u9700\u8981\u8de8\u8d8a\u8f83\u9ad8\u7684\u4f53\u76f8\u6269\u6563\u52bf\u5792(1.56 eV)\u800c\u53d7\u963b\u3002\u5982\u679cB\u539f\u5b50\u8981\u8fdb\u5165\u6b21\u8868\u5c42\u4ee5\u4e0b\u7684\u66f4\u6df1\u5c42\uff0c\u5219\u5fc5\u987b\u5148\u53d1\u751f\u4ecefcc\u7ed3\u6784\u5230hcp\u7ed3\u6784\u7684\u8868\u5c42\u76f8\u53d8\u3002\u8fd9\u4e00\u8868\u5c42\u7684\u76f8\u53d8\u8fc7\u7a0b\u4e2dPd\u8868\u9762\u7684\u4e24\u5c42Pd\u539f\u5b50\u53d1\u751f\u6ed1\u79fb\uff0c\u5f62\u6210\u5177\u6709hcp\u7ed3\u6784\u7684Pd<sub>2<\/sub>B\u8986\u76d6\u5c42(\u56fe\u4e2d\u72b6\u60014)\u5e76\u6700\u7ec8\u5bfc\u81f4\u8868\u9762\u5c42\u7684\u6676\u683c\u81a8\u80c0\u3002\u968f\u540e\u6b21\u8868\u5c42\u7684B\u539f\u5b50\u5f97\u4ee5\u4ece\u65b0\u5f62\u6210\u7684hcp\u6676\u683c\u4e2d\u6269\u6563\u8fdb\u5165\u66f4\u6df1\u5c42(\u56fe\u4e2d\u72b6\u60016)\u3002\u6700\u7ec8\uff0c\u989d\u5916\u7684B\u539f\u5b50\u91cd\u65b0\u586b\u5145\u5165\u6b21\u8868\u5c42\u7a7a\u51fa\u7684\u516b\u9762\u4f53\u7a7a\u9699\u5e76\u5c06\u6b21\u8868\u5c42\u7684B\u539f\u5b50\u6d53\u5ea6\u91cd\u65b0\u6062\u590d\u52300.5 ML(\u56fe\u4e2d\u72b6\u60017)\u3002\u4f34\u968f\u7740fcc\u5230hcp\u9010\u5c42\u76f8\u53d8B\u539f\u5b50\u5d4c\u5165\u901a\u9053\u7684\u603b\u52bf\u5792\u4e3a0.88 eV\uff0c\u8fdc\u4f4e\u4e8e\u4e0d\u542b\u76f8\u53d8\u901a\u9053\u7684\u52bf\u5792(1.56 eV)\u3002\u53ef\u89c1\u9010\u5c42\u76f8\u53d8\u5bf9B\u7684\u63d2\u5165\u52a8\u529b\u5b66\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u8fd9\u70b9\u4e5f\u53cd\u6620\u5728\u5b9e\u9a8c\u83b7\u5f97\u7684XRD\u4e0a\uff0c\u5373\u65e9\u572890<sup>o<\/sup>C\u6eb6\u5242\u70ed\u5408\u6210\u5f97\u5230\u7684\u6837\u54c1\u4e2d\u5c31\u5df2\u7ecf\u80fd\u591f\u89c2\u5bdf\u5230\u90e8\u5206hcp\u76f8\u7684\u5f62\u6210\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184138 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-21.png\" alt=\"\" width=\"426\" height=\"368\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-21.png 426w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/3-21-300x259.png 300w\" sizes=\"(max-width: 426px) 100vw, 426px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong> (a) B\u539f\u5b50\u5728Pd\u548cPd<sub>2<\/sub>B\u4f53\u76f8\u4e2d\u6269\u6563\u80fd\u5792\u548c\u5bf9\u5e94\u7684\u5173\u952e\u7ed3\u6784\u3002(b) B\u539f\u5b50\u4ecePd\u8868\u9762\u5d4c\u5165\u5e76\u5f62\u6210\u8868\u9762Pd<sub>2<\/sub>B\u7684\u53cd\u5e94\u673a\u7406\u3002\u56fe\u4e2d\u7528\u6a59\u8272\u7403\u9ad8\u4eae\u6807\u793a\u51fa\u4e86\u6b63\u5728\u8fc1\u79fb\u7684B\u539f\u5b50\u3002<\/p>\n<p>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 \u7814\u7a76\u4eba\u5458\u8fdb\u4e00\u6b65\u8ba1\u7b97\u4e86\u5b9e\u9a8c\u8fc7\u7a0b\u53ef\u80fd\u51fa\u73b0\u7684\u5404\u79cd\u8868\u9762\u4e0a\u7684H-H\u8026\u5408\u53cd\u5e94(\u50ac\u5316\u5242\u8868\u9762HER\u7684\u51b3\u901f\u6b65\u9aa4)\u7684\u52bf\u5792\u6765\u8bc4\u4f30\u5bf9\u4e8e\u6750\u6599\u6d3b\u6027\u8d77\u5173\u952e\u4f5c\u7528\u7684\u8868\u9762\u7ed3\u6784\u3002\u7814\u7a76\u53d1\u73b0B\u539f\u5b50\u5d4c\u5165Pd\u7684\u6b21\u8868\u9762\u80fd\u591f\u4f7f\u53cd\u5e94\u7684\u52bf\u5792\u4ece0.95 eV\u964d\u4f4e\u52300.64 eV\uff0c\u968f\u7740\u76f8\u53d8\u548cB\u539f\u5b50\u7684\u8fdb\u4e00\u6b65\u5d4c\u5165\u53cd\u5e94\u7684\u52bf\u5792\u6700\u7ec8\u80fd\u591f\u964d\u4f4e\u81f30.49 eV\u3002\u6709\u8da3\u7684\u662f\u5728\u5f62\u6210Pd<sub>2<\/sub>B\u7684hcp\u7ed3\u6784\u4e4b\u540e\u79fb\u9664\u534a\u6570\u7684B\u539f\u5b50\uff0c\u53cd\u5e94\u7684\u52bf\u5792\u4f9d\u7136\u4e5f\u4ec5\u67090.52 eV\u3002\u4ece\u8fd9\u4e9b\u7ed3\u679c\u4e2d\uff0c\u6211\u4eec\u53ef\u4ee5\u5f52\u7eb3\u51faB\u5728\u6d3b\u6027\u589e\u5f3a\u4e2d\u7684\u53cc\u91cd\u4f5c\u7528\uff1a(i)\u6b21\u8868\u9762\u5b58\u5728B\u7684\u80fd\u524a\u5f31\u8868\u9762\u7684H-Pd\u952e\u5e76\u4ece\u800c\u4fc3\u8fdbH-H\u8026\u5408\uff1b(ii) hcp\u6676\u683c\u5f62\u6210\u540e\u7684\u6676\u683c\u81a8\u80c0\u5f31\u5316\u4e86\u539f\u5b50\u6001H\u7684\u5438\u9644\uff0c\u800c\u5bf9\u4e8e\u8fc7\u6e21\u6001\u7684[H\u2013H]\u590d\u5408\u7269\u5219\u5f71\u54cd\u8f83\u5c0f\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86H-H\u8026\u5408\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-184139 \" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-20.png\" alt=\"\" width=\"1244\" height=\"357\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-20.png 1960w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-20-300x86.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-20-768x220.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/08\/4-20-1024x294.png 1024w\" sizes=\"(max-width: 1244px) 100vw, 1244px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4.<\/strong> (a)\u4e0d\u540c\u8868\u9762\u4e0aH-H\u8026\u5408\u7684\u53cd\u5e94\u52bf\u80fd\u9762\u3002(b)\u5bf9\u5e94\u7684\u8fc7\u6e21\u6001\u7684\u7ed3\u6784\u3002Pb:\u9752\u8272\u7403;B:\u7c89\u8272\u7403;H:\u767d\u8272\u7684\u7403\uff0c\u53cd\u5e94\u4e2d\u7684H\u539f\u5b50\u4ee5\u6de1\u9752\u8272\u7684\u7403\u88ab\u7a81\u51fa\u663e\u793a\u3002<\/p>\n<p>\u3010\u7ed3\u8bba\u3011<\/p>\n<p>\u8be5\u5de5\u4f5c\u901a\u8fc7\u7406\u6027\u8bbe\u8ba1\u5f00\u53d1\u4e86\u4e00\u79cd\u5408\u6210Pd<sub>2<\/sub>B\u7eb3\u7c73\u7247\u7684\u65b0\u65b9\u6cd5\uff0c\u5e76\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u5176\u5728\u5f3a\u9178\u6027\u6761\u4ef6\u4e0b\u7684\u8d85\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\u3002\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\uff0c\u7814\u7a76\u4eba\u5458\u8be6\u7ec6\u5206\u6790\u4e86\u4ece\u91d1\u5c5ePd\u5230\u91d1\u5c5e\u787c\u5316\u7269Pd<sub>2<\/sub>B\u7684\u9010\u7ea7\u7ed3\u6784\u6f14\u53d8\u8fc7\u7a0b\uff0c\u8868\u660e\u4ecePd\u7684fc\u7ed3\u6784\u5230hcp\u7ed3\u6784\u7684\u9010\u5c42\u76f8\u53d8\u5bf9B\u5d4c\u5165\u52a8\u529b\u5b66\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002Pd<sub>2<\/sub>B\u50ac\u5316\u5242\u7684\u9ad8\u6d3b\u6027\u4e3b\u8981\u662f\u7531\u4e8e\u8868\u9762B\u7684\u5b58\u5728\u548cPb\u6676\u683c\u7684\u81a8\u80c0\u3002\u7531\u4e8e\u6839\u636e\u7406\u8bba\u9884\u6d4bPd<sub>2<\/sub>B\u6676\u4f53\u662fPd-B\u590d\u5408\u7269\u5404\u7ec4\u5206\u4e2d\u70ed\u529b\u5b66\u6700\u7a33\u5b9a\u7684\u4f53\u76f8\u7ed3\u6784\uff0c\u5b9e\u9a8c\u5408\u6210\u7684\u6210\u529f\u5f00\u542f\u4e86\u8be5\u7a33\u5b9a\u76f8\u4f5c\u4e3a\u6d3b\u6027\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u52a0\u6c22\u50ac\u5316\u53cd\u5e94\u7684\u53ef\u80fd\u6027\u3002\u8003\u8651\u5230Pd<sub>2<\/sub>B\u7684\u8fc7\u7535\u4f4d\u6bd4Pt\u66f4\u4f4e\uff0c\u56e0\u6b64\u5728\u82db\u523b\uff08\u5982\u8fd8\u539f\u6027\u3001\u9178\u6027\uff09\u6761\u4ef6\u4e0b\uff0c\u9ad8\u5408\u91d1\u5316\u7684\u8fc7\u6e21\u91d1\u5c5e\u787c\u5316\u7269\u6709\u671b\u6210\u4e3a\u4e00\u7c7b\u9ad8\u8010\u4e45\u6027\u3001\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u5242\u3002\u8be5\u5de5\u4f5c\u4f53\u73b0\u4e86\u901a\u8fc7\u7406\u8bba\u9884\u6d4b\u5230\u5b9e\u9a8c\u8bc1\u5b9e\u7684\u7406\u6027\u8bbe\u8ba1\u5f00\u53d1\u65b0\u50ac\u5316\u6750\u6599\u7684\u7814\u7a76\u6846\u67b6\uff0c\u7814\u7a76\u7ed3\u679c\u4e3a\u8fdb\u4e00\u6b65\u63a2\u7d22\u7a33\u5b9a\u91d1\u5c5e\u787c\u5316\u7269\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5<\/p>\n<p><strong><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/ee\/c9ee01564g#!divAbstract\">Metal Boride Better Than Pt: HCP Pd<sub>2<\/sub>B as Superactive Hydrogen Evolution Reaction Catalyst<\/a><\/strong><\/p>\n<p>\u3010\u76f8\u5173\u6587\u732e\u63a8\u8350\u3011<\/p>\n<p>1\u3001Guang-Feng Wei, Ling-Ran Zhang and Zhi-Pan Liu, \u201cGroup-VIII transition metal boride as promising hydrogen evolution reaction catalysts\u201d, <strong><em>Physical Chemistry Chemical Physics<\/em><\/strong>, <strong>2018<\/strong>, 20, 27752-27757 (2018 PCCP HOT Articles)<\/p>\n<p>2\u3001Guang-Feng Wei, Ling-Ran Zhang and Zhi-Pan Liu, \u201cRestructuring and Hydrogen Evolution on Pt Nanoparticle\u201d, <strong><em>Chemical Science<\/em><\/strong>, <strong>2015<\/strong>, 6, 1485-1490.<\/p>\n<p>3\u3001Si-Cong Ma, Si-Da Huang, Zhi-Pan Liu , \u201cDynamic Coordination of Cations and Catalytic Selectivity on Zn-Cr oxide Alloy during Syngas Conversion\u201d, <strong><em>Nature Catalysis<\/em><\/strong>, <strong>2019<\/strong>, 2, 671-677.<\/p>\n<p>\u3010\u901a\u8baf\u4f5c\u8005\u4ecb\u7ecd\u3011<\/p>\n<p>\u97e6\u5e7f\u4e30\uff0c\u73b0\u4efb\u540c\u6d4e\u5927\u5b66\u5316\u5b66\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u52a9\u7406\u6559\u6388\u30022012\u5e74\u6bd5\u4e1a\u4e8e\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\uff0c2012-2015\u5e74\u671f\u95f4\u4e3a\u590d\u65e6\u5927\u5b66\u7269\u7406\u7cfb\u535a\u58eb\u540e\u30022015\u5e74\u52a0\u5165\u540c\u6d4e\u5927\u5b66\u5316\u5b66\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u30022016\u5e74\u5165\u9009\u4e0a\u6d77\u5e02\u9752\u5e74\u79d1\u6280\u82f1\u624d\u626c\u5e06\u8ba1\u5212\u3002\u76ee\u524d\u4e3b\u8981\u4ece\u4e8b\u8868\u754c\u9762\u50ac\u5316\u53cd\u5e94\u673a\u7406\u4e0e\u65b0\u50ac\u5316\u6750\u6599\u7406\u6027\u8bbe\u8ba1\u7814\u7a76\u3002\u5728Nature Chemistry, Energy Environ. Sci., Chem. Sci., Chem. Mater., J. Chem. Theory Comput., J. Phys. Chem. C, Phys. Chem. Chem. Phys.\u7b49\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\uff0c\u8bba\u6587\u4ed6\u5f151000\u4f59\u6b21\uff0cH\u6307\u6570\u4e3a15\u3002<\/p>\n<p>\u5218\u667a\u6500\uff0c\u73b0\u4efb\u590d\u65e6\u5927\u5b66\u6559\u6388\u3001\u535a\u5bfc\u30022000-2003 \u5e74\u5728\u82f1\u56fd\u5973\u7687\u5927\u5b66\u653b\u8bfb\u7406\u8bba\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c2003-2005 \u5728\u82f1\u56fd\u5251\u6865\u5927\u5b66\u4ece\u4e8b\u5173\u4e8e\u8868\u9762\u79d1\u5b66\u7406\u8bba\u7684\u535a\u58eb\u540e\u7814\u7a76\u3002\u76ee\u524d\u4e3b\u8981\u4ece\u4e8b\u7406\u8bba\u8ba1\u7b97\u5316\u5b66\u65b9\u6cd5\u53d1\u5c55\u548c\u8868\u754c\u9762\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u7684\u6a21\u62df\u8ba1\u7b97\u3002\u8fd1\u5e74\u6765\u5728\u590d\u6742\u52bf\u80fd\u9762\u641c\u5bfb\u65b9\u6cd5\u53d1\u5c55\uff0c\u5168\u5c40\u795e\u7ecf\u7f51\u7edc\u52bf\u51fd\u6570\u6784\u5efa\uff0c\u591a\u7ec4\u5206\u590d\u76f8\u50ac\u5316\u57fa\u7840\u7406\u8bba\u7b49\u9886\u57df\uff0c\u53d6\u5f97\u4e86\u7cfb\u5217\u91cd\u8981\u6210\u679c\uff0c\u5efa\u7acb\u4e86\u4e00\u5957\u8f83\u5b8c\u5584\u7684\u7406\u8bba\u50ac\u5316\u7814\u7a76\u6846\u67b6\uff0c\u63a8\u8fdb\u4e86\u7406\u8bba\u50ac\u5316\u5316\u5b66\u53d1\u5c55\u3002\u53d1\u5c55\u4e86\u65b0\u578b\u56fa\u6db2\u754c\u9762\u6eb6\u5242\u5316\u6a21\u578b\u7406\u8bba\u65b9\u6cd5\uff0c\u9610\u660e\u4e86\u88c2\u89e3\u6c34\u7b49\u7cfb\u5217\u91cd\u8981\u56fa\u6db2\u754c\u9762\u5149\/\u7535\u5316\u5b66\u50ac\u5316\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\uff1b\u53d1\u5c55\u4e86\u65b0\u578b\u5168\u5c40\u8def\u5f84\u641c\u7d22\u65b9\u6cd5\uff0c\u968f\u673a\u8868\u9762\u884c\u8d70\u65b9\u6cd5\uff0c\u7528\u4e8e\u81ea\u52a8\u5316\u5bfb\u627e\u590d\u6742\u53cd\u5e94\u7f51\u7edc\uff0c\u5728\u56fa\u4f53\u76f8\u53d8\u7406\u8bba\u65b9\u9762\u53d6\u5f97\u91cd\u8981\u7a81\u7834\u3002\u4e3b\u6301\u79d1\u6280\u90e8\u91cd\u70b9\u7814\u53d1\u7eb3\u7c73\u79d1\u6280\u9879\u76ee\uff0c973 \u8bfe\u9898,\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u8bfe\u9898\u7b49\u591a\u9879\u56fd\u5bb6\u7ea7\u9879\u76ee\u8bfe\u9898\u3002\u5df2\u7ecf\u53d1\u8868 SCI \u6536\u5f55\u8bba\u6587 130 \u4f59\u7bc7\uff0c\u5176\u4e2d J. Am. Chem. Soc 24 \u7bc7\uff0c\u8bba\u6587\u603b\u5f15\u7528\u6570 7000 \u591a\u6b21\u3002\u83b7\u5f97\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u548c\u57fa\u91d1\u59d4\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u8d44\u52a9\uff0c2004 \u5e74\u56fd\u9645\u5316\u5b66\u4e0e\u5e94\u7528\u5316\u5b66\u5b66\u4f1a\uff08IUPAC\uff09\u9752\u5e74\u5316\u5b66\u5bb6\u5956\uff0c2007 \u5e74\u4e2d\u56fd\u5316\u5b66\u4f1a\u9752\u5e74\u5316\u5b66\u5956\uff0c2008 \u5e74\u7b2c\u56db\u5c4a\u4e0a\u6d77\u5e02\u9752\u5e74\u79d1\u6280\u82f1\u624d\uff0c2008 \u5e74\u4e0a\u6d77\u5e02\u9ad8\u6821\u7279\u8058\u6559\u6388(\u4e1c\u65b9\u5b66\u8005)\u79f0\u53f7\u7b49\u3002\u62c5\u4efb\u79d1\u5b66\u901a\u62a5\uff0c\u4e2d\u56fd\u79d1\u5b66\u5316\u5b66\uff0cJ. Chem. Phys.\uff0cChem. Phys. Lett.\u7f16 \u59d4\uff0cJ. Phys. Chem. 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