{"id":186244,"date":"2019-10-12T06:30:04","date_gmt":"2019-10-11T22:30:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=186244"},"modified":"2019-10-11T23:00:50","modified_gmt":"2019-10-11T15:00:50","slug":"%e5%82%a8%e8%83%bd%e9%a2%86%e5%9f%9f%e6%96%b0%e8%bf%9b%e5%b1%95%ef%bc%8c%e5%bf%ab%e6%9d%a5%e6%9f%a5%e6%94%b6%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=186244","title":{"rendered":"\u50a8\u80fd\u9886\u57df\u65b0\u8fdb\u5c55\uff0c\u5feb\u6765\u67e5\u6536\uff01"},"content":{"rendered":"

\u50a8\u80fd\u6280\u672f\u7684\u5feb\u901f\u8fdb\u6b65\u4fc3\u8fdb\u4e86\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u7206\u70b8\u5f0f\u53d1\u5c55\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4eba\u4eec\u4e5f\u4e00\u76f4\u5728\u8ffd\u6c42\u66f4\u597d\u7684\u50a8\u80fd\u7cfb\u7edf\u3002\u5728\u6b64\uff0c\u6211\u4eec\u5bf9\u8fd1\u671f\u50a8\u80fd\u7535\u6c60\u7684\u91cd\u5927\u8fdb\u5c55\u8fdb\u884c\u4e86\u6c47\u603b\u68b3\u7406\uff0c\u4ee5\u4fbf\u5927\u5bb6\u5168\u9762\u5feb\u901f\u5730\u638c\u63e1\u6700\u8fd1\u7684\u7814\u7a76\u52a8\u6001\uff0c\u5e76\u5e0c\u671b\u7ed9\u5927\u5bb6\u7684\u7814\u7a76\u5e26\u6765\u4e00\u4e9b\u542f\u53d1\u3002<\/p>\n

1<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/h3>\n

\u9502\u79bb\u5b50\u7535\u6c60\u662f\u73b0\u9636\u6bb5\u5177\u6709\u6700\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u5b9e\u7528\u5316\u50a8\u80fd\u5668\u4ef6\u3002\u4e0d\u8fc7\uff0c\u4eba\u4eec\u4ecd\u7136\u5728\u81f4\u529b\u4e8e\u5f00\u53d1\u5177\u6709\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5e76\u5e0c\u671b\u63a8\u52a8\u9502\u79bb\u5b50\u7535\u6c60\u56de\u6536\u6280\u672f\u7684\u53d1\u5c55\u3002<\/p>\n

Advanced<\/b><\/strong>\u00a0<\/b><\/strong>Materials\uff1a\u4e09\u7ef4\u8702\u5de2\u7ed3\u6784\u6784\u5efa\u9ad8\u500d\u7387\u957f\u5bff\u547dFeF<\/b><\/strong>3<\/b><\/sub><\/strong>-Li\u7535\u6c60<\/b><\/strong><\/p>\n

\u201c\u91d1\u5c5e\u6c1f\u5316\u7269-\u9502\u201d\u7535\u6c60\u5728\u7406\u8bba\u4e0a\u5177\u6709\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u751a\u81f3\u6bd4Li-S\u7535\u6c60\u8fd8\u8981\u9ad8\uff0c\u56e0\u6b64\u975e\u5e38\u6709\u5e0c\u671b\u6210\u4e3a\u4e0b\u4e00\u4ee3\u8f7b\u8d28\u4f4e\u6210\u672c\u7684\u53ef\u5145\u7535\u7535\u6c60\u3002FeF3<\/sub>\u662f\u4e00\u7c7b\u5178\u578b\u7684\u6c1f\u5316\u7269\u6b63\u6781\u6750\u6599\uff0c\u5b83\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\u9ad8\u8fbe712 mAh g-1<\/sup>\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u6c1f\u5316\u7269\u6b63\u6781\u6750\u6599\u5b58\u5728\u7740\u7535\u5b50\u5bfc\u7535\u7387\u5dee\uff0c\u53cd\u5e94\u52a8\u529b\u5b66\u6162\u548c\u526f\u53cd\u5e94\u7b49\u95ee\u9898\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5b58\u5728\u7740\u9ad8\u7684\u7535\u538b\u56de\u6ede\uff0c\u5dee\u7684\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u5feb\u901f\u7684\u5bb9\u91cf\u8870\u51cf\u3002\u5728\u6b64\uff0c\u4e2d\u5357\u5927\u5b66\u7684\u5434\u98de\u7fd4<\/b><\/strong>\u548c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u4f59\u5f66<\/b><\/strong>\u91c7\u7528\u4e00\u79cd\u7b80\u5355\u7684\u65b9\u6cd5\u5236\u5907\u51fa\u4e86\u5177\u6709\u4e09\u7ef4\u8702\u5de2\u7ed3\u6784\u7684FeF3<\/sub>@C\u590d\u5408\u6750\u6599\uff0c\u4ee5\u671f\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898[1]<\/sup>\u3002\u5728\u8be5\u590d\u5408\u6750\u6599\u4e2d\uff0c\u76f4\u5f8410-50 nm\u7684FeF3<\/sub>\u9897\u7c92\u88ab\u5747\u5300\u5730\u57cb\u8986\u5728\u4e86\u4e09\u7ef4\u7684\u8702\u5de2\u78b3\u9aa8\u67b6\u4e2d\uff08\u56fe1\uff09\u3002\u9aa8\u67b6\u4e2d\u8702\u5de2\u72b6\u7684\u78b3\u58c1\u4ee5\u53ca\u516d\u8fb9\u5f62\u7684\u901a\u9053\u53ef\u4ee5\u4fdd\u8bc1\u7535\u5b50\u548c\u79bb\u5b50\u7684\u5feb\u901f\u4f20\u8f93\u3002\u56e0\u6b64\uff0c\u5236\u5907\u51fa\u7684\u4e09\u7ef4\u8702\u5de2\u7ed3\u6784\u7684FeF3<\/sub>@C\u590d\u5408\u6b63\u6781\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff08\u56fe2\uff09\uff1a\uff081\uff09\u57282.2 mg cm-2<\/sup>\u7684\u8f7d\u91cf\uff0c100 C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u4ecd\u7136\u9ad8\u8fbe50 mAh g-1<\/sup>\uff1b\uff082\uff09\u57285.3 mg cm-2<\/sup>\u7684\u8f7d\u91cf\uff0c15 C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u6750\u6599\u7684\u6bd4\u5bb9\u91cf\u4ecd\u7136\u63a5\u8fd1120 mAh g-1<\/sup>\uff1b\uff083\uff09\u57282.2 mg cm-2<\/sup>\u7684\u8f7d\u91cf\uff0c2\u00a0C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5faa\u73af1000\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u7136\u63a5\u8fd185%\u3002\u8fd9\u4e2a\u7ed3\u679c\u8868\u660e\u4e09\u7ef4\u8702\u5de2\u7ed3\u6784\u5bf9\u4e8e\u6539\u5584\u91d1\u5c5e\u6c1f\u5316\u7269\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u975e\u5e38\u6709\u6548\u3002<\/p>\n

\u56fe1<\/b><\/strong>\u00a0<\/b><\/strong>Fe<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>@C<\/b><\/strong>\u548cFeF<\/b><\/strong>3<\/b><\/sub><\/strong>@C<\/b><\/strong>\u7684\u5f62\u8c8c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>FeF<\/b><\/strong>3<\/b><\/sub><\/strong>@C<\/b><\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u00a0Energy & Environmental Science<\/b><\/strong>\uff1a\u57fa\u4e8e\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u5e9f\u65e7\u9502\u79bb\u5b50\u7535\u6c60\u9ad8\u6548\u7eff\u8272\u56de\u6536\u7b56\u7565<\/b><\/strong><\/p>\n

\u8fd130\u5e74\u6765\uff0c\u4f34\u968f\u7740\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5546\u4e1a\u5316\u548c\u5927\u91cf\u751f\u4ea7\uff0c\u65e0\u6570\u7684\u5e9f\u65e7\u9502\u79bb\u5b50\u7535\u6c60\u4e5f\u56e0\u6b64\u4ea7\u751f\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u9002\u5f53\u5730\u5904\u7406\u6709\u5bb3\u7684\u5e9f\u5f03\u7535\u6c60\u4ee5\u53ca\u4f4e\u6210\u672c\u5229\u7528\u6709\u4ef7\u503c\u7684\u6750\u6599\u5c31\u663e\u5f97\u5341\u5206\u91cd\u8981\u3002\u73b0\u6709\u7684\u6750\u6599\u56de\u6536\u7b56\u7565\u901a\u5e38\u662f\u57fa\u4e8e\u5316\u5b66\u6d78\u51fa\u548c\u6c89\u6dc0\u7684\u65b9\u6cd5\uff0c\u4f46\u662f\u5b83\u4eec\u4e5f\u5b58\u5728\u7740\u4e00\u4e9b\u4e25\u91cd\u7684\u95ee\u9898\uff0c\u6bd4\u5982\u6d88\u8017\u5927\u91cf\u5316\u5b66\u539f\u6599\u3001\u5b58\u5728\u4e8c\u6b21\u6c61\u67d3\u4ee5\u53ca\u6b65\u9aa4\u7e41\u591a\u3002\u5728\u6b64\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u7684\u738b\u5e86<\/b><\/strong>\u7b49\u4eba\u57fa\u4e8e\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u9502\u7535\u6750\u6599\u56de\u6536\u7b56\u7565\u5e76\u4ee5\u56de\u6536\u5e9f\u65e7\u7684LiFePO4<\/sub>\u4e3a\u4f8b\u505a\u4e86\u5c55\u793a[2]<\/sup>\u3002\u5982\u56fe3\u6240\u793a\uff0c\u4f5c\u8005\u91c7\u75280.20 M\u7684[Fe(CN)6<\/sub>]3-<\/sup>\u6eb6\u6db2\u4f5c\u4e3a\u53ef\u518d\u751f\u7684\u6c27\u5316\u8fd8\u539f\u4e2d\u4ecb\uff0c\u901a\u8fc7\u4e0eLiFePO4<\/sub>\u53d1\u751f\u53cd\u5e94\u4f7f\u5176\u53d8\u4e3aFePO4<\/sub>\u548cLi+<\/sup>\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u57fa\u4e8e\u9502\u7684\u53bb\u9664\u7387\u8ba1\u7b97\u5f97\u5230\u7684\u56de\u6536\u6548\u7387\u9ad8\u8fbe99.8%\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8be5\u6c27\u5316\u8fd8\u539f\u4e2d\u4ecb\u4f1a\u5728\u7535\u6781\u5904\u91cd\u751f\u4ee5\u4fbf\u7528\u4e8e\u4e0b\u4e00\u8f6e\u53cd\u5e94\uff0c\u4f46Li+<\/sup>\u5219\u4f1a\u5728\u53e6\u4e00\u4e2a\u7535\u6781\u5904\u8fdb\u884c\u56de\u6536\u3002\u56e0\u6b64\uff0c\u5316\u5b66\u539f\u6599\u7684\u6d88\u8017\u5f97\u4ee5\u6781\u5927\u5730\u964d\u4f4e\u800c\u4e14\u4e0d\u5b58\u5728\u4e8c\u6b21\u6c61\u67d3\u3002\u57fa\u4e8e\u8be5\u65b0\u578b\u8fc7\u7a0b\uff0c\u4f5c\u8005\u5236\u5907\u51fa\u4e86\u9ad8\u7eaf\u7684LiOH(99.90%)\u548cFePO4<\/sub>(99.97%)\uff08\u56fe4\uff09\u3002\u56e0\u6b64\uff0c\u8be5\u65b9\u6cd5\u975e\u5e38\u6709\u5e0c\u671b\u4fc3\u8fdb\u9502\u79bb\u5b50\u4ea7\u4e1a\u7684\u957f\u4e45\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n

\u56fe3<\/b><\/strong>\u00a0<\/b><\/strong>\u5e9f\u65e7LiFePO<\/b><\/strong>4<\/b><\/sub><\/strong>\u56de\u6536\u7684\u5de5\u4f5c\u539f\u7406\u53ca\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4<\/b><\/strong>\u00a0<\/b><\/strong>LiFePO<\/b><\/strong>4<\/b><\/sub><\/strong>\u56de\u6536\u8fc7\u7a0b\u4e2d\u7684\u8868\u5f81\u53ca\u5176\u56de\u6536\u4ea7\u7269<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/h3>\n

\u7531\u4e8e\u5177\u6709\u6700\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u88ab\u8a89\u4e3a\u8d1f\u6781\u6750\u6599\u754c\u7684\u201c\u5723\u676f\u201d\u3002\u4e0d\u8fc7\u4e0d\u5747\u5300\u7684\u9502\u6c89\u79ef\u95ee\u9898\u5374\u4e00\u76f4\u56f0\u6270\u7740\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u9502\u91d1\u5c5e\u7814\u7a76\u7684\u4e00\u5927\u91cd\u70b9\u5c31\u662f\u89e3\u51b3\u9502\u679d\u6676\u7684\u95ee\u9898\u3002<\/p>\n

Joule\uff1a\u65b0\u578b\u6db2\u5316\u6c14\u7535\u89e3\u6db2\u4fc3\u6210\u9ad8\u6548\u9502\u91d1\u5c5e\u8d1f\u6781<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u6700\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff083860 mAh g-1<\/sup>\uff09\u4ee5\u53ca\u6700\u4f4e\u7684\u7535\u5316\u5b66\u7535\u52bf\uff08-3.04 V vs. SHE\uff09\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u9502\u57fa\u7535\u6c60\u7684\u201c\u5723\u676f\u201d\u3002\u7136\u800c\uff0c\u9502\u679d\u6676\u7684\u751f\u957f\u548c\u4f4e\u7684\u5e93\u4f26\u6548\u7387\u5374\u4e00\u76f4\u963b\u788d\u7740\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5728\u6b64\uff0c\u6765\u81ea\u52a0\u5dde\u5927\u5b66\u5723\u5730\u4e9a\u54e5\u5206\u6821\u7684Y<\/b><\/strong>ang Yangyuchen<\/b><\/strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u7535\u89e3\u6db2\u6765\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898[3]<\/sup>\u3002\u8be5\u7535\u89e3\u6db2\u662f\u901a\u8fc7\u5728\u6c1f\u4ee3\u7532\u70f7\u57fa\u6db2\u5316\u6c14\u7535\u89e3\u6db2\u4e2d\u5f15\u5165\u56db\u6c22\u544b\u5583\u6dfb\u52a0\u5242\u6784\u6210\u7684\uff0c\u5b83\u53ef\u4ee5\u4e0eLi+<\/sup>\u5b8c\u5168\u914d\u4f4d\uff0c\u4ece\u800c\u6781\u5927\u5730\u63d0\u9ad8\u9502\u76d0\u7684\u6eb6\u89e3\u548c\u4f20\u8f93\u901f\u5ea6\uff08\u56fe5\uff09\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u8be5\u7535\u89e3\u6db2\u5177\u6709\u9ad8\u7684\u79bb\u5b50\u5bfc\u7535\u7387\uff083.9 mS cm-1<\/sup>\uff09\u548c\u8fc1\u79fb\u6570\uff08t+<\/sub>>0.79\uff09\uff0c\u8fd9\u4f7f\u5176\u53ef\u4ee5\u663e\u8457\u5730\u6539\u5584\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5faa\u73af\u6027\u80fd\u3002\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c\u91c7\u7528\u8be5\u6db2\u5316\u6c14\u7535\u89e3\u6db2\u5728\u5b9a\u5bb90.5\uff0c1\uff0c\u548c3\u00a0mAh cm-2<\/sup>\u5faa\u73af\u65f6\uff0c\u7535\u6c60\u7cfb\u7edf\u7684\u5e93\u4f26\u6548\u7387\u5206\u522b\u9ad8\u8fbe99.6%\uff0c99.4%\u548c98.1%\u3002\u6b64\u5916\uff0c\u7535\u6c60\u7cfb\u7edf\u4e5f\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u65e0\u679d\u6676\u7684\u5f62\u8c8c\u3002\u4f4e\u6e29\u8bd5\u9a8c\u4e5f\u8868\u660e\uff0c\u5373\u4f7f\u5728\u8f83\u4f4e\u7684\u6e29\u5ea6\u4e0b\uff080\uff0c-20\uff0c-40\uff0c-60\u2103\uff09\uff0c\u8be5\u7535\u89e3\u6db2\u4e5f\u53ef\u8d4b\u4e88\u9502\u91d1\u5c5e\u7535\u6c60\u4f18\u5f02\u7684\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe5<\/b><\/strong>\u00a0<\/b><\/strong>\u65b0\u578b\u6db2\u5316\u6c14\u7535\u89e3\u6db2\u7684\u7ed3\u6784\u53ca\u5176\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>dvanced Energy Materials<\/b><\/strong>\uff1a\u5c04\u9891\u6e85\u5c04\u201c\u77f3\u58a8\/<\/b><\/strong>SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u201d\u5c42\u590d\u5174\u9502\u91d1\u5c5e\u8d1f\u6781<\/b><\/strong><\/p>\n

\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5f00\u53d1\u5c06\u4f1a\u63a8\u52a8\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5b58\u5728\u4e0d\u7a33\u5b9a\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\uff08SEI\uff09\u548c\u9502\u679d\u6676\u7684\u751f\u957f\u95ee\u9898\uff0c\u76f4\u63a5\u4f7f\u7528\u91d1\u5c5e\u9502\u8d1f\u6781\u4f1a\u5f15\u8d77\u4e25\u91cd\u7684\u5b89\u5168\u95ee\u9898\uff0c\u4f4e\u7684\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u5dee\u7684\u5faa\u73af\u6027\u80fd\u3002\u4e3a\u4e86\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\uff0c\u5357\u8fbe\u79d1\u4ed6\u5dde\u7acb\u5927\u5b66\u7684Rajesh Pathak<\/b><\/strong>\u91c7\u7528\u5c04\u9891\u6e85\u5c04\u7684\u65b9\u6cd5\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u6d82\u8986\u4e86\u201c\u77f3\u58a8-SiO2<\/sub>\u201d\u8d85\u8584\u53cc\u6d82\u5c42\uff0c\u5c06\u5176\u4f5c\u4e3a\u6709\u6548\u7684SEI\u5c42\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u8fdb\u884c\u4fdd\u62a4\uff08\u56fe6\uff09[4]<\/sup>\u3002\u76f8\u6bd4\u4e8e\u7eafLi\u8d1f\u6781\uff0c\u201c\u77f3\u58a8-SiO2<\/sub>\u201d\u53cc\u5c42\u4fee\u9970\u7684Li\u91d1\u5c5e\u8d1f\u6781\u53ef\u4ee5\u5b9e\u73b0\u5747\u5300\u65e0\u679d\u6676\u7684Li\u6c89\u79ef\uff0c\u56e0\u6b64\u8868\u73b0\u51fa\u4e86\u7a33\u5b9a\u7684\u5145\u653e\u7535\u66f2\u7ebf\u548c\u4f18\u5f02\u7684\u957f\u65f6\u9502\u7684\u6c89\u79ef\/\u8131\u51fa\uff08\u56fe7\uff09\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u76f8\u6bd4\u4e8e\u7eafLi\u8d1f\u6781\uff0c\u91c7\u7528\u8be5\u4fee\u9970\u7684Li\u91d1\u5c5e\u8d1f\u6781\u4e0e\u954d\u94b4\u9530\u9178\u9502\u6b63\u6781\u6216\u8005\u949b\u9178\u9502\u76f8\u5339\u914d\u7684\u7535\u6c60\u4e5f\u8868\u73b0\u51fa\u4e86\u6539\u5584\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff0c\u66f4\u9ad8\u7684\u500d\u7387\u6027\u80fd\uff0c\u66f4\u957f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u66f4\u4f4e\u7684\u7535\u538b\u56de\u6ede\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u77f3\u58a8\u53ef\u4ee5\u4f5c\u4e3a\u9502\u7535\u6781\u4e0e\u6c89\u79ef\u7684\u9502\u4e4b\u95f4\u7684\u7535\u5b50\u8fde\u63a5\u6865\uff0c\u4ece\u800c\u964d\u4f4e\u963b\u6297\u5e76\u7f13\u51b2Li\u6c89\u79ef\/\u8131\u51fa\u65f6\u7684\u4f53\u79ef\u81a8\u80c0\u3002\u8d85\u8584\u7684SiO2<\/sub>\u5c42\u5219\u53ef\u4ee5\u4fc3\u8fdb\u9502\u79bb\u5b50\u7684\u4f20\u8f93\uff0c\u4fdd\u8bc1\u9ad8\u7684\u7535\u89e3\u6db2\u4eb2\u548c\u6027\uff0c\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u9ad8\u7684\u6768\u6c0f\u6a21\u91cf\uff0c\u4ece\u800c\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\u3002<\/p>\n

\u56fe6<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u6c89\u79ef\u5728\u7eaf\u9502\u8d1f\u6781\u548c\u77f3\u58a8\/<\/b><\/strong>SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u53cc\u5c42\u4fee\u9970\u7684\u9502\u8d1f\u6781\u7684\u8fc7\u7a0b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe7<\/b><\/strong>\u00a0<\/b><\/strong>\u7eaf\u9502\u8d1f\u6781\u548c\u77f3\u58a8\/<\/b><\/strong>SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u4fee\u9970\u7684\u9502\u8d1f\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u786b\u7535\u6c60<\/b><\/strong><\/h3>\n

\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u786b\u6b63\u6781\u56e0\u4e3a\u8f6c\u5316\u673a\u7406\u800c\u6709\u7740\u975e\u5e38\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff0c\u56e0\u6b64\u4e5f\u662f\u7814\u7a76\u7684\u4e00\u5927\u70ed\u70b9\u3002\u5176\u4e2d\uff0c\u7814\u7a76\u7684\u91cd\u70b9\u662f\u5982\u4f55\u89e3\u51b3\u786b\u6b63\u6781\u7684\u7a7f\u68ad\u6548\u5e94\u4ee5\u53ca\u63d0\u9ad8\u7535\u6781\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

A<\/b><\/strong>dvanced Materials<\/b><\/strong>\uff1a\u539f\u5b50Co\u63ba\u6742\u7684\u4ecb\u5b54\u78b3\u9694\u5c42\u52a9\u529b\u7a33\u5b9a\u7684\u9502\u786b\u7535\u6c60<\/b><\/strong><\/p>\n

\u9502\u786b\u7535\u6c60\u662f\u975e\u5e38\u6709\u5e0c\u671b\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u5668\u4ef6\u3002\u7136\u800c\uff0c\u786b\u6b63\u6781\u5b58\u5728\u7684\u95ee\u9898\uff08\u4f4e\u7684\u7535\u5b50\u5bfc\u7535\u7387\uff0c\u5927\u7684\u4f53\u79ef\u53d8\u5316\u548c\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\uff09\u4e25\u91cd\u5730\u9650\u5236\u4e86\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u6027\u80fd\u3002\u901a\u8fc7\u5f15\u5165\u4ecb\u5b54\u78b3\u6765\u8d1f\u8f7d\u786b\u6b63\u6781\u53ef\u4ee5\u8f83\u597d\u5730\u89e3\u51b3\u786b\u6b63\u6781\u7684\u524d\u4e24\u4e2a\u95ee\u9898\u3002\u4e0d\u8fc7\uff0c\u78b3\u6750\u6599\u7684\u975e\u6781\u6027\u7279\u70b9\u4f7f\u5176\u5bf9\u6781\u6027\u7684\u591a\u786b\u5316\u7269\u7684\u4eb2\u548c\u6027\u5f88\u5dee\uff0c\u56e0\u6b64\u65e0\u6cd5\u89e3\u51b3\u786b\u6b63\u6781\u5b58\u5728\u7684\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u3002\u5728\u672c\u6587\u91cc\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7684\u9ec4\u4f73\u7426<\/b><\/strong>\u56e2\u961f\u91c7\u7528\u8d85\u5206\u5b50\u81ea\u6a21\u677f\u7684\u65b9\u6cd5\u5236\u5907\u4e86\u539f\u5b50\u94b4\u63ba\u6742\u7684\u4ecb\u5b54\u78b3\uff0c\u5b83\u53ef\u4ee5\u5728\u4fdd\u6301\u591a\u5b54\u78b3\u7ed3\u6784\u7684\u524d\u63d0\u4e0b\u6539\u5584\u4e0e\u591a\u786b\u5316\u7269\u7684\u4ea4\u4e92\u4f5c\u7528\uff08\u56fe8\uff09[5]<\/sup>\u3002\u6b64\u5916\uff0c\u63ba\u6742\u7684\u539f\u5b50\u94b4\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u6539\u5584\u786b\u6b63\u6781\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u91c7\u7528\u539f\u5b50\u94b4\u63ba\u6742\u7684\u4ecb\u5b54\u78b3\u4f5c\u4e3a\u9694\u5c42\u5236\u5907\u5904\u7684\u9502\u786b\u7535\u6c60\u53ef\u4ee5\u57280.5 C\u4e0b\u83b7\u5f971130 mAh\u00a0g–<\/sup>1<\/sup>\u7684\u6bd4\u5bb9\u91cf\uff0c\u800c\u4e14\u6709\u7740\u5f88\u9ad8\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u5faa\u73af300\u5708\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a74.1%\uff09\uff08\u56fe9\uff09\u3002<\/p>\n

\u56fe<\/b><\/strong>8 <\/b><\/strong>Co\u63ba\u6742\u7684\u4ecb\u5b54\u78b3\uff08SC-Co\uff09\u7684\u793a\u610f\u56fe\u53ca\u5176\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u7167\u7247<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>9 <\/b><\/strong>\u91c7\u7528\u4ecb\u5b54\u78b3\u548cCo\u63ba\u6742\u7684\u4ecb\u5b54\u78b3\u4e3a\u9694\u5c42\u7684\u9502\u786b\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>dvanced <\/b><\/strong>Energy<\/b><\/strong>\u00a0Materials<\/b><\/strong>\uff1a\u65e0\u591a\u786b\u5316\u7269\u7a7f\u68ad\u7684Fe-S\u7535\u6c60<\/b><\/strong><\/p>\n

\u786b\u662f\u4e0b\u4e00\u4ee3\u50a8\u80fd\u7535\u6c60\u4e2d\u6700\u6709\u5e0c\u671b\u7684\u6b63\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u91d1\u5c5e-\u786b\u7535\u6c60\u4e2d\u5e7f\u6cdb\u5b58\u5728\u7684\u591a\u786b\u5316\u7269\u7684\u6eb6\u89e3\u548c\u7a7f\u68ad\u73b0\u8c61\u4e25\u91cd\u5730\u9650\u5236\u4e86\u4ed6\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5728\u672c\u6587\u91cc\uff0c\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66\u7eaa\u79c0\u78ca<\/b><\/strong>\u56e2\u961f\u521b\u65b0\u6027\u5730\u63d0\u51fa\u5c06\u786b\u6b63\u6781\u4e0e\u94c1\u91d1\u5c5e\u8d1f\u6781\u76f8\u5339\u914d\u7ec4\u88c5\u4e3aFe-S\u7535\u6c60\uff0c\u7531\u4e8e\u786b\u5316\u94c1\u672c\u5f81\u4e0d\u53ef\u6eb6\uff08\u56fe10b\uff09\uff0c\u56e0\u6b64Fe-S\u7535\u5316\u5b66\u53cd\u5e94\u4f53\u7cfb\u4e0d\u5b58\u5728\u7a7f\u68ad\u6548\u5e94\uff08\u56fe10a\uff09[6]<\/sup>\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u786b\u6b63\u6781\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50a8Fe2<\/sup>+<\/sup>\u6027\u80fd\uff1a\u786b\u6b63\u6781\u7684\u6bd4\u5bb9\u91cf\u9ad8\u8fbe1050 mAh g-1<\/sup>\uff0c\u6781\u5316\u4ec5\u4e3a~0.16 V\uff0c\u800c\u4e14\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af150\u6b21\uff08\u56fe11\uff09\u3002\u7814\u7a76\u53d1\u73b0\uff0cFe-S\u7535\u6c60\u4f53\u7cfb\u7684\u6c27\u5316\u8fd8\u539f\u673a\u7406\u662f\u4e00\u79cd\u591a\u6b65\u7684\u8f6c\u5316\u53cd\u5e94\uff08S8<\/sub>\u2194FeS2<\/sub>\u2194Fe3<\/sub>S4<\/sub>\u2194FeS\uff09\uff0c\u8fd9\u79cd\u5168\u56fa\u6001\u7684\u76f8\u8f6c\u53d8\u6709\u5229\u4e8e\u63d0\u9ad8\u53cd\u5e94\u7684\u53ef\u9006\u6027\u4e14\u6574\u4e2a\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u53d8\u5316\u7387\u4ec5\u670932.6%\uff08\u56fe10c\uff0cd\uff09\u3002\u8be5\u7814\u7a76\u4e5f\u4e3a\u5229\u7528\u786b\u6b63\u6781\u5236\u5907\u53ef\u5145\u7535\u7684\u8fc7\u6e21\u91d1\u5c5e-\u786b\u7535\u6c60\u6307\u660e\u4e86\u4e00\u4e2a\u65b0\u65b9\u5411\u3002<\/p>\n

\u56fe<\/b><\/strong>10 <\/b><\/strong>Fe-S\u7535\u6c60\u7684\u57fa\u672c\u539f\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>11 <\/b><\/strong>Fe-S\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4<\/b><\/strong>\u00a0<\/b><\/strong>\u94a0<\/b><\/strong>\/\u94be\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/h3>\n

\u76f8\u6bd4\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u94a0\u548c\u94be\u5177\u6709\u66f4\u9ad8\u7684\u8d44\u6e90\u50a8\u91cf\uff0c\u4e14\u6709\u7740\u4e0e\u9502\u76f8\u4f3c\u7684\u6027\u8d28\u3002\u56e0\u6b64\uff0c\u4eba\u4eec\u4e5f\u5728\u7740\u91cd\u5f00\u53d1\u65b0\u578b\u94a0\/\u94be\u79bb\u5b50\u7535\u6c60\uff0c\u4ee5\u4fbf\u5c06\u5176\u5e94\u7528\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u3002<\/p>\n

A<\/b><\/strong>dvanced <\/b><\/strong>Energy<\/b><\/strong>\u00a0Materials<\/b><\/strong>\uff1aTi\uff0cCu\u53cc\u53d6\u4ee3\u63a8\u52a8\u5c42\u72b6<\/b><\/strong>O3<\/sub>-NaNi<\/b><\/strong>0.5<\/b><\/sub><\/strong>Mn<\/b><\/strong>0.5<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6781\u8fbe\u5230\u80fd\u91cf\u5bc6\u5ea6\u6781\u9650<\/b><\/strong><\/p>\n

\u5c3d\u7ba1\u94a0\u79bb\u5b50\u7535\u6c60\u65e0\u6cd5\u5728\u80fd\u91cf\u5bc6\u5ea6\u65b9\u9762\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u5339\u654c\uff0c\u4f46\u5728\u5bf9\u6210\u672c\u53ca\u53ef\u6301\u7eed\u6027\u7684\u6709\u8f83\u9ad8\u8981\u6c42\u7684\u5e94\u7528\u9886\u57df\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u5219\u6781\u6709\u53ef\u80fd\u53d6\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u3002O3\u578b\u5c42\u72b6\u6c27\u5316\u7269\u53ef\u4ee5\u5728\u67d0\u79cd\u7a0b\u5ea6\u4e0a\u514b\u670d\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u7684\u5c40\u9650\uff0c\u4f46\u662f\u5b83\u4eec\u7684\u5b9e\u9645\u5e94\u7528\u5374\u53d7\u5230\u53cd\u5e94\u8fc7\u7a0b\u7684\u56f0\u6270\uff08\u5927\u91cf\u7684\u76f8\u8f6c\u53d8\u548c\u4f53\u79ef\u53d8\u5316\uff09\u4ee5\u53ca\u5bf9\u6c34\u5206\u654f\u611f\u3002\u4e3a\u4e86\u514b\u670d\u4e0a\u8ff0\u95ee\u9898\uff0c\u6cd5\u5170\u897f\u5b66\u9662\u548c\u7d22\u90a6\u5927\u5b66\u7684Jean-Marie Tarascon<\/b><\/strong>\u56e2\u961f\u5bf9O3-NaNi0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u6750\u6599\u8fdb\u884c\u4e86Ti\uff08\u53d6\u4ee3Mn\uff09\u548cCu\uff08\u53d6\u4ee3Ni\uff09\u7684\u53cc\u53d6\u4ee3[7]<\/sup>\uff08\u56fe12\uff09\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u901a\u8fc7Ti\u548cCu\u7684\u53d6\u4ee3\uff0c\u6bcf\u6469\u5c14\u7684O3-NaNi0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u6700\u591a\u53ef\u4ee5\u53ef\u9006\u5730\u91ca\u653e\/\u5b58\u50a80.9\u6469\u5c14Na\uff0c\u4e14\u6750\u6599\u5728\u5faa\u73af\u65f6\u5177\u6709\u8f83\u5c0f\u7684\u6676\u683c\u4f53\u79ef\u7684\u53d8\u5316\uff08<\/b><\/strong>\u0394V\/V \u2248 23%\uff09\u3002<\/b><\/strong>\u4e0e\u6b64\u540c\u65f6\uff0c\u6750\u6599\u4e5f\u5bf9\u6c34\u5206\u7a33\u5b9a\uff08\u56fe13a\uff0cb\uff09\u3002\u4f5c\u8005\u8fd8\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u5bf9\u5176\u7ed3\u6784\u8fdb\u884c\u4e86\u8ba1\u7b97\uff0c\u4ece\u800c\u63ed\u793a\u4e86\u53d6\u4ee3\u7684\u4f18\u52bf\u3002\u4f5c\u8005\u8fd8\u5236\u5907\u4e8618650\u578b\u94a0\u79bb\u5b50\u7535\u6c60\u5bf9\u6750\u6599\u8fdb\u884c\u4e86\u68c0\u9a8c\uff0c\u8be5\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5730\u653e\u51fa180 mAh g-1<\/sup>\u7684\u5bb9\u91cf\uff0c\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe250 Wh L-1<\/sup>\uff0c\u6bd4\u73b0\u5728\u7684Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\/HC\u7535\u6c60\u5177\u6709\u66f4\u52a0\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff08\u56fe13c\uff09\u3002\u8fd9\u662f\u94a0\u79bb\u5b50\u7535\u6c60\u6280\u672f\u8d70\u5411\u5b9e\u9645\u5e94\u7528\u7684\u53c8\u4e00\u6b65\uff0c\u5b83\u5c06\u6709\u5e0c\u671b\u5e94\u7528\u5728\u5bf9\u80fd\u91cf\u5bc6\u5ea6\u8981\u6c42\u80dc\u8fc7\u529f\u7387\u5bc6\u5ea6\u7684\u9886\u57df\u91cc\u3002<\/p>\n

\u56fe<\/b><\/strong>12 <\/b><\/strong>\u4e00\u7cfb\u5217Ti\u548cCu\u53d6\u4ee3\u7684<\/b><\/strong>O3-NaNi<\/b><\/strong>0.5<\/b><\/sub><\/strong>Mn<\/b><\/strong>0.5<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>3 Cu<\/b><\/strong>\u63ba\u6742\u5bf9\u6750\u6599\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\u53ca<\/b><\/strong>NaNi<\/b><\/strong>0.4<\/b><\/sub><\/strong>Cu<\/b><\/strong>0.1<\/b><\/sub><\/strong>Mn<\/b><\/strong>0.4<\/b><\/sub><\/strong>Ti<\/b><\/strong>0.1<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6750\u6599\u5236\u5907\u76841<\/b><\/strong>8650<\/b><\/strong>\u578b\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Energy & Environmental Science: <\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Mxene<\/b><\/strong>\/<\/b><\/strong>NiCoP<\/b><\/strong>\u590d\u5408\u6750\u6599\u7528\u4f5c\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4f4e\u7684\u6210\u672c\u548c\u4e30\u5bcc\u7684\u8d44\u6e90\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u5927\u89c4\u6a21\u50a8\u80fd\u5668\u4ef6\u4e0a\u3002\u7136\u800c\uff0c\u94a0\u79bb\u5b50\u5177\u6709\u8f83\u5927\u7684\u79bb\u5b50\u76f4\u5f84\uff081.02 \u00c5\uff09\uff0c\u8fd9\u4f1a\u9020\u6210\u7535\u6781\u6750\u6599\u5728\u8fdb\u884c\u7535\u5316\u5b66\u53cd\u5e94\u65f6\u53d1\u751f\u4e25\u91cd\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u4ece\u800c\u4f7f\u5f97\u7535\u6c60\u5177\u6709\u5f88\u5dee\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u4e3a\u4e86\u6539\u5584\u7535\u6781\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u5e76\u63d0\u9ad8\u5176\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5c71\u4e1c\u5927\u5b66\u7684Danyang Zhao<\/b><\/strong>\u7b49\u4eba\u5c06\u53cc\u91d1\u5c5e\u78f7\u5316\u7269NiCoP\u4e0e\u78b1\u5f15\u5bfc\u76843D\u4ea4\u8054\u8936\u76b1\u591a\u5b54Ti3<\/sub>C2<\/sub>\u00a0Mxene\u76f8\u7ed3\u5408\u5236\u5907\u4e86\u4e00\u79cd\u590d\u5408\u6750\u6599\uff08\u56fe14\uff09[8]<\/sup>\u3002\u5728\u6b64\u590d\u5408\u6750\u6599\u4e2d\uff0c\u4ea4\u8054\u76843D Ti3<\/sub>C2<\/sub>\u8936\u76b1\u7ed3\u6784\u53ef\u4ee5\u63d0\u4f9b3D\u7684\u5bfc\u7535\u7f51\u7edc\uff0c\u4e30\u5bcc\u7684\u5b54\u548c\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u4ece\u800c\u786e\u4fdd3D\u9ad8\u901f\u7684\u7535\u8377\u8f6c\u79fb\u3002\u6b64\u5916\uff0cMxene\u72ec\u7279\u7684\u7ed3\u6784\u4e5f\u53ef\u4ee5\u6709\u6548\u5730\u7f13\u89e3NiCoP\u7eb3\u7c73\u9897\u7c92\u5728Na+<\/sup>\u79bb\u5b50\u63d2\u5165\/\u8131\u51fa\u65f6\u5f15\u8d77\u7684\u4f53\u79ef\u81a8\u80c0\u5e76\u963b\u6b62\u9897\u7c92\u7684\u7c89\u5316\u548c\u805a\u96c6\u3002\u53cc\u91d1\u5c5e\u78f7\u5316\u7269NiCoP\u5219\u6709\u7740\u4e30\u5bcc\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4f4d\u70b9\uff0c\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u7387\u548c\u4f4e\u7684\u7535\u8377\u8f6c\u79fb\u963b\u6297\u3002\u8fd9\u4e24\u4e2a\u7ec4\u5206\u4e4b\u95f4\u7684\u6709\u673a\u7ed3\u5408\u8d4b\u4e88\u4e86\u7535\u6781\u6750\u6599\u4f18\u5f02\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u56e0\u6b64\u6750\u6599\u8868\u73b0\u51fa\u4e86\u6781\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a\u57281\u00a0A\u00a0g-1<\/sup>\u4e0b\u5faa\u73af2000\u6b21\u540e\uff0c\u6bd4\u5bb9\u91cf\u4ecd\u7136\u9ad8\u8fbe261.7 mAh g-1<\/sup>\uff08\u56fe15\uff09\u3002\u8be5\u7b56\u7565\uff08\u539f\u4f4d\u78f7\u5316\u548c\u4e0e\u8936\u76b1\u76843D Ti3<\/sub>C2<\/sub>\u76f8\u590d\u5408\uff09\u4e5f\u53ef\u7528\u4e8e\u5236\u5907\u5176\u4ed6\u65b0\u578b\u7535\u6781\u4ee5\u7528\u5728\u9ad8\u6027\u80fd\u50a8\u80fd\u5668\u4ef6\u4e2d\u3002<\/p>\n

\u56fe1<\/b><\/strong>4 Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\/NiCoP<\/b><\/strong>\u6df7\u5408\u7269\u7684\u5236\u5907\u8fc7\u7a0b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>5 Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\/NiCoP<\/b><\/strong>\u6df7\u5408\u7269\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5<\/b><\/strong>\u00a0<\/b><\/strong>\u5176\u4ed6\u65b0\u578b\u50a8\u80fd\u7535\u6c60<\/b><\/strong><\/h3>\n

\u9664\u4e86\u4e0a\u8ff0\u4f53\u7cfb\uff0c\u4eba\u4eec\u8fd8\u81f4\u529b\u4e8e\u5f00\u53d1\u65b0\u578b\u4e0b\u4e00\u4ee3\u50a8\u80fd\u7cfb\u7edf\uff0c\u5982Al\u79bb\u5b50\u7535\u6c60\uff0cCa\u79bb\u5b50\u7535\u6c60\u7b49\uff0c\u4ee5\u671f\u5e94\u7528\u5728\u4f4e\u6210\u672c\u9886\u57df\u3002<\/p>\n

A<\/b><\/strong>dvanced <\/b><\/strong>Energy<\/b><\/strong>\u00a0Materials<\/b><\/strong>\uff1aMOF\u884d\u751f\u7684<\/b><\/strong>Co<\/b><\/strong>3<\/b><\/sub><\/strong>(PO<\/b><\/strong>4<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>@C<\/b><\/strong>\u7528\u4f5c\u9ad8\u6027\u80fdAl\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599<\/b><\/strong><\/p>\n

\u4f5c\u4e3a\u4e00\u79cd\u540e\u9502\u79bb\u5b50\u7535\u6c60\u6280\u672f\uff0c\u94dd\u79bb\u5b50\u7535\u6c60\uff08AIBs\uff09\u7531\u4e8e\u5177\u6709\u4e30\u5bcc\u7684\u94dd\u8d44\u6e90\uff0c\u4e09\u7535\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4ee5\u53ca\u9ad8\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5c3d\u7ba1AIBs\u5df2\u7ecf\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u662fAlCl4<\/sub>–<\/sup>\u9634\u79bb\u5b50\u8f83\u5927\u7684\u5c3a\u5bf8\u6240\u5f15\u8d77\u7684\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u5374\u963b\u788d\u7740\u78b3\u6b63\u6781\u7684\u6027\u80fd\u6539\u5584\u548c\u5546\u4e1a\u5316\u5e94\u7528\u3002\u5177\u6709\u96a7\u9053\u7ed3\u6784\u7684\u78f7\u9178\u76d0\u6750\u6599\u6709\u7740\u6bd4Al3<\/sup>+<\/sup>\u5927\u5f97\u591a\u7684\u5c42\u95f4\u8ddd\uff0c\u56e0\u6b64\u5f88\u6709\u5e0c\u671b\u4f5c\u4e3a\u9ad8\u6027\u80fdAIBs\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u3002\u9274\u4e8e\u6b64\uff0c\u5c71\u4e1c\u5927\u5b66\u7684\u5c39\u9f99\u536b<\/b><\/strong>\u56e2\u961f\u5236\u5907\u4e86\u7531ZIF-67\u884d\u751f\u7684\u591a\u7a7a\u96a7\u9053\u7ed3\u6784\u7684Co3<\/sub>(PO4<\/sub>)2<\/sub>@C\uff0c\u5e76\u5c06\u5176\u7528\u4f5cAIBs\u7684\u6b63\u6781\u6750\u6599\uff08\u56fe16\uff09[9]<\/sup>\u3002\u8be5\u6750\u6599\u5c55\u73b0\u51fa\u4e86\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u9ad8\u7684\u79bb\u5b50\u6d41\u52a8\u6027\uff0c\u548c\u9ad8\u7684Al3<\/sup>+<\/sup>\u6269\u6563\u7cfb\u6570\uff0c\u56e0\u6b64\u5177\u6709\u975e\u5e38\u9ad8\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u6b64\u5916\uff0c\u78b3\u58f3\u548c\u591a\u7a7a\u7ed3\u6784\u5c31\u50cf\u94e0\u7532\u4e00\u6837\u53ef\u4ee5\u7f13\u89e3\u6b63\u6781\u6750\u6599\u7684\u4f53\u79ef\u53d8\u5316\u5e76\u4fdd\u6301\u5176\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u6b63\u5982\u9884\u8ba1\u7684\u90a3\u6837\uff0c\u8be5\u8bbe\u8ba1\u5408\u7406\u7684\u590d\u5408\u6750\u6599\u663e\u51fa\u4e86\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff08\u57286\u00a0A g-1<\/sup>\u4e0b\u6bd4\u5bb9\u91cf\u9ad8\u8fbe111 mAh g-1<\/sup>\uff09\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u57282 A g-1<\/sup>\u4e0b\u5faa\u73af500\u6b21\u5bb9\u91cf\u540e\u4fdd\u6301\u7387\u9ad8\u8fbe90%\uff09\uff08\u56fe17\uff09\u3002\u8be5\u521b\u65b0\u7684\u8bbe\u8ba1\u53ef\u80fd\u662f\u957f\u5faa\u73af\u7a33\u5b9a\u6027AIBs\u7684\u4e00\u5927\u8fdb\u6b65\u3002\u8fd9\u9879\u7814\u7a76\u4e5f\u63ed\u793a\u4e86\u57fa\u4e8eAl3<\/sup>+<\/sup>\u800c\u4e0d\u662fAlCl4<\/sub>–<\/sup>\u7684AIBs\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u56fe1<\/b><\/strong>6 MOFs-Co<\/b><\/strong>3<\/b><\/sub><\/strong>(PO<\/b><\/strong>4<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>@C<\/b><\/strong>\u7684\u5408\u6210\u8fc7\u7a0b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>7 MOFs-Co<\/b><\/strong>3<\/b><\/sub><\/strong>(PO<\/b><\/strong>4<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>@C<\/b><\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Energy & Environmental Science: <\/b><\/strong>\u5ba4\u6e29C<\/b><\/strong>a<\/b><\/strong>\u79bb\u5b50\u7535\u6c60\u7528\u9ad8\u6548\u7a33\u5b9a\u7535\u89e3\u6db2<\/b><\/strong><\/p>\n

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\u56fe1<\/b><\/strong>8 Ca[B(hfip)<\/b><\/strong>4<\/b><\/strong>]<\/b><\/strong>2<\/b><\/sub>\u00b7<\/b><\/strong>4DME<\/b><\/strong>\u7535\u89e3\u8d28\u7684\u5408\u6210\u8fc7\u7a0b\u548c\u5355\u6676\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>9 Ca[B(hfip)<\/b><\/strong>4<\/b><\/sub><\/strong>]<\/b><\/strong>2<\/b><\/sub>\u00b7<\/b><\/strong>4DME\/DME<\/b><\/strong>\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/h3>\n

[1] F. Wu, V. Srot, S. Chen, S. Lorger, P.A. Aken, J. Maier, Y. Yu, 3D Honeycomb Architecture Enables a High\u2010Rate and Long\u2010Life Iron (III) Fluoride\u2013Lithium Battery, Advanced Materials, (2019) 1905146.<\/p>\n

[2] J. Yu, X. Wang, M. Zhou, Q. Wang, A redox targeting-based material recycling strategy for spent lithium ion batteries, Energy & Environmental Science, 12 (2019) 2672-2677.<\/p>\n

[3] Y. Yang, D.M. Davies, Y. Yin, O. Borodin, J.Z. Lee, C. Fang, M. Olguin, Y. Zhang, E.S. Sablina, X. Wang, C.S. Rustomji, Y.S. Meng, High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes, Joule, 3 (2019) 1986-2000.<\/p>\n

[4] R. Pathak, K. Chen, A. Gurung, K.M. Reza, B. Bahrami, F. Wu, A. Chaudhary, N. Ghimire, B. Zhou, W.H. Zhang, Y. Zhou, Q. Qiao, Ultrathin Bilayer of Graphite\/SiO2<\/sub>\u00a0as Solid Interface for Reviving Li Metal Anode, Advanced Energy Materials, (2019) 1901486.<\/p>\n

[5] J. Xie, B.Q. Li, H.J. Peng, Y.W. Song, M. Zhao, X. Chen, Q. Zhang, J.Q. Huang, Implanting Atomic Cobalt within Mesoporous Carbon toward Highly Stable Lithium-Sulfur Batteries, Adv Mater, (2019) 1903813.<\/p>\n

[6] X. Wu, A. Markir, Y. Xu, E.C. Hu, K.T. Dai, C. Zhang, W. Shin, D.P. Leonard, K.i. Kim, X. Ji, Rechargeable Iron\u2013Sulfur Battery without Polysulfide Shuttling, Advanced Energy Materials, (2019) 1902422.<\/p>\n

[7] Q. Wang, S. Mariyappan, J. Vergnet, A.M. Abakumov, G. Rousse, F. Rabuel, M. Chakir, J.M. Tarascon, Reaching the Energy Density Limit of Layered O3\u2010NaNi0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u00a0Electrodes via Dual Cu and Ti Substitution, Advanced Energy Materials, (2019) 1901785.<\/p>\n

[8] D. Zhao, R. Zhao, S. Dong, X. Miao, Z. Zhang, C. Wang, L. Yin, Alkali-induced 3D crinkled porous Ti3<\/sub>C2<\/sub>\u00a0MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries, Energy & Environmental Science, 12 (2019) 2422-2432.<\/p>\n

[9] C. Li, S. Dong, P. Wang, C. Wang, L. Yin, Metal\u2013Organic Frameworks\u2010Derived Tunnel Structured Co3<\/sub>(PO4<\/sub>)2<\/sub>@C as Cathode for New Generation High\u2010Performance Al\u2010Ion Batteries, Advanced Energy Materials, (2019) 1902352.<\/p>\n

[10] Z. Li, O. Fuhr, M. Fichtner, Z. Zhao-Karger, Towards stable and efficient electrolytes for room-temperature rechargeable calcium batteries, Energy & Environmental Science, (2019).<\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

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