{"id":186281,"date":"2019-09-25T06:28:38","date_gmt":"2019-09-24T22:28:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=186281"},"modified":"2019-09-25T11:49:35","modified_gmt":"2019-09-25T03:49:35","slug":"%e7%bb%8f%e5%85%b8%e6%b0%b8%e6%b5%81%e4%bc%a0%ef%bc%81%e7%83%ad%e7%82%b9%e6%9d%90%e6%96%99%e9%a2%86%e5%9f%9f%e6%9c%80%e9%ab%98%e5%bc%95%e6%96%87%e7%ab%a0%e9%89%b4%e8%b5%8f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=186281","title":{"rendered":"\u7ecf\u5178\u6c38\u6d41\u4f20\uff01\u70ed\u70b9\u6750\u6599\u9886\u57df\u6700\u9ad8\u5f15\u6587\u7ae0\u9274\u8d4f"},"content":{"rendered":"

\u5386\u53f2\u4e0a\uff0c\u5bf9\u6750\u6599\u7684\u8ba4\u8bc6\u548c\u5229\u7528\u7684\u80fd\u529b\uff0c\u51b3\u5b9a\u7740\u793e\u4f1a\u7684\u5f62\u6001\u548c\u4eba\u7c7b\u751f\u6d3b\u7684\u8d28\u91cf\uff0c\u5386\u53f2\u5b66\u5bb6\u4e5f\u628a\u6750\u6599\u53ca\u5176\u5668\u5177\u4f5c\u4e3a\u5212\u5206\u65f6\u4ee3\u7684\u6807\u5fd7\uff1a\u5982\u4ece\u65e7\u77f3\u5668\u65f6\u4ee3\u5f00\u59cb\uff0c\u7ecf\u8fc7\u65b0\u77f3\u5668\u65f6\u4ee3\u3001\u9752\u94dc\u5668\u65f6\u4ee3\u3001\u94c1\u5668\u65f6\u4ee3\u3001\u94a2\u94c1\u65f6\u4ee3\u3001\u9ad8\u5206\u5b50\u65f6\u4ee3\u3001\u9ad8\u6027\u80fd\u9676\u74f7\u65f6\u4ee3\uff0c\u76f4\u5230\u590d\u5408\u6750\u6599\u65f6\u4ee3\u3002<\/p>\n

\u4ece\u4e00\u5f00\u59cb\u7684\u5bcc\u52d2\u70ef\u5230\u78b3\u7eb3\u7c73\u7ba1\uff0c\u5230\u77f3\u58a8\u70ef\uff0cMOFs\uff0c\u518d\u5230\u5982\u4eca\u5982\u706b\u5982\u837c\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6750\u6599\u7814\u7a76\uff0c\u5b83\u4eec\u6700\u53d7\u6b22\u8fce\u7684\u6587\u7ae0\u662f\u4ec0\u4e48\uff1f2017\u5e74\u4ee5\u6765\uff0c\u6750\u6599\u4eba\u63a8\u51fa\u7cfb\u5217\u520a\uff0c\u5982\u4eca\u6750\u6599\u4eba\u518d\u7eed\u524d\u7f18\uff0c\u4e3a\u60a8\u6574\u7406\u8fd1\u5e74\u6765\u70ed\u70b9\u6750\u6599\u7814\u7a76\u9886\u57df\u7684\u6700\u9ad8\u5f15\u6587\u7ae0\uff0c\u5176\u4e2d\u4e0d\u542b\u7efc\u8ff0\u7c7b\u6587\u7ae0\u3002<\/p>\n

\u3010\u5f15\u8bfb\u3011<\/b><\/strong><\/h3>\n

\"\"<\/b><\/strong><\/h4>\n

\uff08\u6392\u540d\u4e0d\u5206\u524d\u540e\uff09<\/p>\n

\"\"<\/p>\n

\u4ece\u671f\u520a\u5206\u5e03\u53ef\u4ee5\u770b\u51faNature\u3001Science\u4ee5\u538b\u5012\u6027\u7684\u4f18\u52bf\u5360\u636e\u4e86\u534a\u58c1\u6c5f\u5c71\uff0c\u9876\u520a\u5b9e\u81f3\u540d\u5f52\u3002<\/p>\n

\u3010\u6b63\u6587\u3011<\/b><\/strong><\/h3>\n

1<\/b><\/strong>\u00a0<\/b><\/strong>Science<\/b><\/strong>: \u7cfb\u7edf\u5730\u8bbe\u8ba1<\/b><\/strong>\u591a\u5b54<\/b><\/strong>\u7684\u529f\u80fd<\/b><\/strong>\u6027M<\/b><\/strong>OF<\/b><\/strong>\u7528\u4e8e<\/b><\/strong>\u7532\u70f7\u50a8\u5b58<\/b><\/strong><\/p>\n

\u56fe1 MOFs\u7cfb\u5217\u6a21\u578b<\/p>\n

\"\"<\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF-5)\u662f\u4e00\u7c7b\u65b0\u578b\u591a\u5b54\u6750\u6599\u7684\u539f\u578b\uff0c\u7531\u516b\u9762\u4f53Zn-O-C\u56e2\u7c07\u548c\u82ef\u73af\u6784\u6210\u3002\u7814\u7a76\u8868\u660e\uff0c\u8be5\u4f53\u7cfb\u7684\u4e09\u7ef4\u591a\u5b54\u4f53\u7cfb\u53ef\u4ee5\u4e0e-Br\u3001-NH2<\/sub>\u3001-OC3<\/sub>H7<\/sub>\u7b49\u6709\u673a\u57fa\u56e2\u529f\u80fd\u5316\uff0c\u5176\u5b54\u5f84\u53ef\u7531\u957f\u5206\u5b50\u91cf\u7684\u8054\u82ef\u3001\u8298\u7b49\u6269\u5927\u3002\u4e9a\u5229\u6851\u90a3\u5dde\u7acb\u5927\u5b66\u7684Yaghi\u6559\u6388\u56e2\u961f\u5408\u6210\u4e86\u7531\u76f8\u540c\u6846\u67b6\u62d3\u6251\u7ed3\u6784\u768416\u79cd\u9ad8\u6676\u4f53\u6750\u6599\uff0c\u8fd9\u4e9b\u6750\u6599\u7684\u5b54\u9699\u7387\u5360\u6676\u4f53\u4f53\u79ef\u768491.1%\uff0c\u4ee5\u53ca\u5747\u5300\u7684\u5468\u671f\u5b54\u9699\uff0c\u8fd9\u4e9b\u5b54\u9699\u7684\u957f\u5ea6\u53ef\u4ee5\u4ece3.8\u523028.8 \u00c5\u4e0d\u7b49\uff0c\u7cfb\u5217\u4e2d\u7684IRMOF-6\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u7532\u70f7\u50a8\u5b58\u80fd\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aEddaoudi, M. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage. Science, 2002, 295(5554):469-472.<\/p>\n

2 N<\/b><\/strong>ature: \u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1<\/b><\/strong><\/p>\n

\u56fe2 \u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7535\u5b50\u663e\u5fae\u955c\u7ed3\u6784<\/p>\n

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\u4e3a\u4e86\u7814\u7a76\u7ed3\u6784\u7684\u6027\u8d28\uff0c\u9700\u8981\u5177\u6709\u660e\u786e\u7684\u5f62\u8c8c\u3001\u957f\u5ea6\u3001\u539a\u5ea6\u548c\u8bb8\u591a\u540c\u5fc3\u58f3\u4f53\u7684\u7eb3\u7c73\u7ba1\uff1b\u7136\u800c\uff0c\u6b63\u5e38\u7684\u78b3\u5f27\u5408\u6210\u4f1a\u4ea7\u751f\u4e00\u7cfb\u5217\u7684\u7ba1\u578b\u3002\u7279\u522b\u662f\uff0c\u5927\u591a\u6570\u8ba1\u7b97\u90fd\u662f\u5173\u4e8e\u5355\u58f3\u7ba1\uff0c\u800c\u78b3\u5f27\u5408\u6210\u51e0\u4e4e\u5b8c\u5168\u4ea7\u751f\u591a\u58f3\u7ba1\u3002Sumio Iijima\u7b49\u5728Nature\u62a5\u9053\u4e86\u91c7\u7528\u7535\u5f27\u6cd5\uff0c\u5728\u77f3\u58a8\u7535\u6781\u4e2d\u6dfb\u52a0\u4e00\u5b9a\u7684\u50ac\u5316\u5242\uff0c\u591a\u58f3\u5c42\u7eb3\u7c73\u7ba1\u662f\u5728\u78b3\u9634\u6781\u4e0a\u5f62\u6210\u7684\uff0c\u800c\u5355\u58f3\u5c42\u7eb3\u7c73\u7ba1\u662f\u5728\u6c14\u76f8\u4e2d\u751f\u957f\uff0c\u5f97\u5230\u4ec5\u4ec5\u5177\u6709\u4e00\u5c42\u7ba1\u58c1\u7684\u78b3\u7eb3\u7c73\u7ba1\uff0c\u5373\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u4ea7\u7269\u3002\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7684\u51fa\u73b0\u610f\u5473\u7740\u78b3\u6750\u6599\u88ab\u7684\u7ef4\u5ea6\u6269\u5c55\u5230\u4e86\u4e00\u7ef4\u7a7a\u95f4\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aIijima S, Ichihashi T. Single-shell carbon nanotubes of 1-nm diameter. Nature, 1993, 363(6430):603-605.<\/p>\n

3 Nature<\/b><\/strong>: \u7eb3\u7c73\u5c3a\u5bf8\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599<\/b><\/strong><\/p>\n

\u56fe3\u00a0MO\/Li\u7535\u6c60\u7684\u6027\u80fd<\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5: Poizot P, Laruelle S, Grugeon S, et al. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature, 2010, 32(3):496-499.<\/p>\n

4 N<\/b><\/strong>ature Materials<\/b><\/strong>:<\/b><\/strong>\u00a03D<\/b><\/strong>\u6253\u5370<\/b><\/strong>\u6a21\u5f0f\u8840\u7ba1\u7f51\u7edc<\/b><\/strong><\/p>\n

\u56fe4 \u78b3\u6c34\u5316\u5408\u7269\u73bb\u7483\u6750\u6599\u6027\u80fd\u548c\u4e1d\u72b6\u7ed3\u6784\u7684\u5f62\u6210<\/p>\n

\"\"<\/p>\n

\u5728\u7f3a\u4e4f\u53ef\u704c\u6ce8\u8840\u7ba1\u7f51\u7edc\u7684\u60c5\u51b5\u4e0b\uff0c\u7ec6\u80de\u5bc6\u96c6\u76843D\u5de5\u7a0b\u7ec4\u7ec7\u4f1a\u8fc5\u901f\u5f62\u6210\u574f\u6b7b\u7684\u6838\u5fc3\uff0c\u7f3a\u4e4f\u4e00\u79cd\u901a\u7528\u7684\u65b9\u6cd5\u6765\u5feb\u901f\u6784\u5efa\u8fd9\u6837\u7684\u7f51\u7edc\u4ecd\u7136\u662f3D\u7ec4\u7ec7\u57f9\u517b\u7684\u4e3b\u8981\u6311\u6218\u3002\u5728\u6b64\uff0c\u5bbe\u5915\u6cd5\u5c3c\u4e9a\u5927\u5b66\u7684Christopher S. Chen\u6559\u6388\u7b49\u4eba\u6253\u5370\u4e86\u78b3\u6c34\u5316\u5408\u7269\u73bb\u7483\u7684\u521a\u6027\u4e09\u7ef4\u4e1d\u7f51\u7edc\uff0c\u5e76\u5c06\u5176\u4f5c\u4e3a\u542b\u6709\u6d3b\u7ec6\u80de\u7684\u5de5\u7a0b\u7ec4\u7ec7\u7684\u7ec6\u80de\u76f8\u5bb9\u6027\u6a21\u677f\uff0c\u751f\u6210\u4e86\u53ef\u4ee5\u5185\u886c\u7ec6\u80de\u5e76\u5728\u9ad8\u538b\u8109\u52a8\u6d41\u52a8\u4e0b\u5145\u8840\u7684\u5706\u67f1\u5f62\u7f51\u7edc\u3002\u7531\u4e8e\u8fd9\u79cd\u7b80\u5355\u7684\u8840\u7ba1\u94f8\u578b\u65b9\u6cd5\u5141\u8bb8\u72ec\u7acb\u63a7\u5236\u7f51\u7edc\u51e0\u4f55\u7ed3\u6784\u3001\u5185\u76ae\u5316\u548c\u8840\u7ba1\u5916\u7ec4\u7ec7\uff0c\u56e0\u6b64\u5b83\u9002\u7528\u4e8e\u591a\u79cd\u7ec6\u80de\u7c7b\u578b\u3001\u5408\u6210\u548c\u5929\u7136\u7ec6\u80de\u5916\u57fa\u8d28\u4ee5\u53ca\u4ea4\u8054\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMiller J S, Stevens K R, Yang M T , et al. Rapid casting of patterned vascular networks for perfusable engineered three-dimensional tissues. Nature Materials, 2012, 11(9):768-774.<\/p>\n

5 A<\/b><\/strong>CS NANO: \u6c34\u70ed\u81ea\u7ec4\u88c5<\/b><\/strong>\u5408\u6210<\/b><\/strong>\u77f3\u58a8\u70ef\u6c34\u51dd\u80f6<\/b><\/strong><\/p>\n

\u56fe5 \u6c34\u51dd\u80f6\u7269\u7406\u6027\u80fd\u53ca\u7535\u955c\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aXu Y, Sheng K, Li C, et al.\u00a0Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process. ACS Nano, 2010, 4(7):4324-4330.<\/p>\n

6 Science<\/b><\/strong>: \u539f\u5b50\u8584\u819c\u4e2d\u7684\u7535\u573a\u6548\u5e94<\/b><\/strong><\/p>\n

\u56fe6 \u77f3\u58a8\u70ef\u8584\u819c\u53ca\u5355\u5c42\u7684\u573a\u6548\u5e94<\/p>\n

\"\"<\/p>\n

\u8bfa\u8d1d\u5c14\u7269\u7406\u5b66\u5956\u83b7\u5f97\u8005K.S. Novoselov1, A.K. Geim\u63cf\u8ff0\u4e86\u5355\u6676\u77f3\u58a8\u8584\u819c\uff0c\u5b83\u53ea\u6709\u51e0\u4e2a\u539f\u5b50\u539a\uff0c\u4f46\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u4ecd\u7136\u7a33\u5b9a\uff0c\u91d1\u5c5e\u548c\u975e\u5e38\u9ad8\u7684\u8d28\u91cf\u3002\u5236\u5907\u4e86\u53ea\u6709\u51e0\u4e2a\u539f\u5b50\u539a\u5ea6\u7684\u5355\u6676\u77f3\u58a8\u8584\u819c\uff0c\u5b83\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u4ecd\u7136\u662f\u7a33\u5b9a\u7684\uff0c\u91d1\u5c5e\u7684\uff0c\u5e76\u4e14\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u6027\u80fd\u3002\u8fd9\u4e9b\u8584\u819c\u662f\u4e8c\u7ef4\u534a\u91d1\u5c5e\uff0c\u5728\u4ef7\u5e26\u548c\u7535\u5bfc\u5e26\u4e4b\u95f4\u6709\u5fae\u5c0f\u7684\u91cd\u53e0\uff0c\u5e76\u4e14\u5b83\u4eec\u8868\u73b0\u51fa\u5f3a\u70c8\u7684\u53cc\u6781\u7535\u573a\u6548\u5e94\uff0c\u901a\u8fc7\u65bd\u52a0\u6805\u6781\u7535\u538b\uff0c\u53ef\u4ee5\u8bf1\u5bfc\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u6d53\u5ea6\u8fbe\u52301013<\/sup>cm-2<\/sup>\uff0c\u5ba4\u6e29\u79fb\u52a8\u8303\u56f4\u4e3a10000 cm2<\/sup>\/V\u00b7s\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aNovoselov, K. S. Electric Field Effect in Atomically Thin Carbon Films. Science, 2004, 306(5696):666-669.<\/p>\n

7 Nature Materials\uff1a<\/b><\/strong>\u805a\u5408\u5149\u50ac\u5316\u5242\u7528\u4e8e\u53ef\u89c1\u5149\u4ea7\u6c22<\/b><\/strong><\/p>\n

\u56fe7 \u77f3\u58a8\u5316\u6c2e\u5316\u78b3\u7684\u6676\u4f53\u7ed3\u6784\u548c\u5149\u5b66\u6027\u8d28<\/p>\n

\"\"<\/p>\n

\u5229\u7528\u50ac\u5316\u5242\u548c\u592a\u9633\u80fd\u4ece\u6c34\u4e2d\u751f\u4ea7\u6c22\u662f\u4e00\u79cd\u7406\u60f3\u7684\u672a\u6765\u80fd\u6e90\uff0c\u4e0d\u4f9d\u8d56\u4e8e\u5316\u77f3\u50a8\u91cf\u3002\u9a6c\u514b\u65af-\u666e\u6717\u514b\u80f6\u4f53\u4e0e\u754c\u9762\u7814\u7a76\u6240\u3001\u798f\u5dde\u5927\u5b66\u7684Xinchen Wang\u6559\u6388\uff0c\u4e1c\u4eac\u5927\u5b66\u7684Kazunari Domen\u6559\u6388\u5c55\u793a\u4e86\u4e00\u79cd\u4e30\u5bcc\u7684\u805a\u5408\u7269\u6c2e\u5316\u78b3\uff0c\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u5728\u727a\u7272\u4f9b\u4f53\u7684\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u53ef\u4ee5\u4ece\u6c34\u4e2d\u4ea7\u751f\u6c22\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u3002\u4e0e\u5176\u4ed6\u5bfc\u7535\u805a\u5408\u7269\u534a\u5bfc\u4f53\u4e0d\u540c\uff0c\u6c2e\u5316\u78b3\u5728\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\u65b9\u9762\u90fd\u5f88\u7a33\u5b9a\uff0c\u4e0d\u4f9d\u8d56\u590d\u6742\u7684\u5668\u4ef6\u5236\u9020\u3002\u8fd9\u4e9b\u7ed3\u679c\u4ee3\u8868\u4e86\u5149\u5408\u4f5c\u7528\u7684\u91cd\u8981\u7684\u7b2c\u4e00\u6b65\uff0c\u5728\u4e00\u822c\u60c5\u51b5\u4e0b\uff0c\u4eba\u5de5\u5171\u8f6d\u805a\u5408\u7269\u534a\u5bfc\u4f53\u53ef\u4ee5\u7528\u4f5c\u80fd\u91cf\u4f20\u611f\u5668\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aWang X, Maeda K, Thomas A, et al. A metal-free polymeric photocatalyst for hydrogen production from water under visible\u00a0light. Nature Materials, 2008, 8(1):76-80.<\/p>\n

8<\/b><\/strong>\u00a0<\/b><\/strong>Science: <\/b><\/strong>\u591a\u5b54\u6676\u4f53<\/b><\/strong>\uff1a<\/b><\/strong>\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n

\u56fe8 COF-1\u53caCOF-5\u5408\u6210\u8def\u7ebf<\/p>\n

\"\"<\/p>\n

\u4ee5\u82ef\u57fa\u4e8c\u787c\u9178{C6<\/sub>H4<\/sub>[B(OH)2<\/sub>]2<\/sub>}\u548c\u516d\u7f9f\u57fa\u4e09\u82ef[C18<\/sub>H6<\/sub>(OH)6<\/sub>]\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u7f29\u5408\u53cd\u5e94\u6210\u529f\u5730\u5408\u6210\u4e86\u5171\u4ef7\u6709\u673a\u9aa8\u67b6(COFs)\u3002\u9ad8\u7ed3\u6676\u4ea7\u7269COF-1\u5230COF-5\u7684\u7c89\u672bx\u5c04\u7ebf\u884d\u5c04\u7814\u7a76\u663e\u793a\u51fa\u81a8\u80c0\u591a\u5b54\u77f3\u58a8\u5c42\uff0c\u5b83\u4eec\u662f\u4ea4\u9519\u6392\u5217\u7684\u6216\u91cd\u53e0\u7684\u3002\u6676\u4f53\u7ed3\u6784\u5b8c\u5168\u7531B\u3001C\u548cO\u539f\u5b50\u4e4b\u95f4\u7684\u5f3a\u952e\u6240\u4fdd\u6301\uff0c\u5f62\u6210\u5b54\u5f84\u4ece7\u00c5\u523027\u00c5\u4e0d\u7b49\u7684\u521a\u6027\u591a\u5b54\u7ed3\u6784\u3002COF-1\u548cCOF-5\u5177\u6709\u5f88\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027(\u6e29\u5ea6\u53ef\u8fbe500- 600\u2103)\u3001\u6c38\u4e45\u5b54\u9699\u5ea6\u548c\u9ad8\u8868\u9762\u79ef(\u5206\u522b\u4e3a711m2<\/sup>\/g\u548c1590m2<\/sup>\/g)\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPorous, Crystalline, Covalent Organic Frameworks. Science, 2005, 310(5751):1166-1170.<\/p>\n

9<\/b><\/strong>\u00a0<\/b><\/strong>Angew.\uff1a<\/b><\/strong>\u9ad8\u5149\u81f4\u53d1\u5149\u78b3\u70b9\u7528\u4e8e\u591a\u8272\u56fe\u6848\uff0c\u4f20\u611f\u5668\u548c\u751f\u7269\u6210\u50cf<\/b><\/strong><\/p>\n

\u56fe9 \u78b3\u91cf\u5b50\u70b9\u7684\u5408\u6210\u53ca\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u5409\u6797\u5927\u5b66\u7684\u6768\u67cf\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u7b80\u4fbf\u3001\u9ad8\u4ea7\u91cf\u3001QY\u53ef\u8fbe80%\u7684CDs\u5236\u5907\u65b9\u6cd5\u3002\u5bf9\u5176\u5316\u5b66\u7ed3\u6784\u548c\u53d1\u5149\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\uff0c\u901a\u8fc7\u4f4e\u6e29\u81f3\u9ad8\u6e29\u5408\u6210\uff0c\u5c06\u805a\u5408\u7269\u8f6c\u5316\u4e3a\u78b3\u6e90CDs\u3002\u8868\u9762\/\u5206\u5b50\u72b6\u6001\u5728\u7c7b\u805a\u5408\u7269CDs\u4e2d\u8d77\u4e3b\u5bfc\u4f5c\u7528\uff0c\u800c\u78b3\u6838\u4e0e\u8868\u9762\/\u5206\u5b50\u72b6\u6001\u7684\u534f\u540c\u4f5c\u7528\u5219\u5bf9\u5176\u78b3\u6e90CDs\u7684PL\u8d77\u4fc3\u8fdb\u4f5c\u7528\uff0c\u6b64\u5916\uff0cCDs\u65e2\u88ab\u7528\u4f5c\u5370\u5237\u6cb9\u58a8\uff0c\u80fd\u591f\u5728\u5fae\u5c3a\u5ea6\u4e0a\u4ea7\u751f\u591a\u8272\u56fe\u6848\uff0c\u4e5f\u88ab\u7528\u4f5c\u529f\u80fd\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff0c\u6709\u671b\u7528\u4e8e\u9632\u4f2a\u5e94\u7528\uff0c\u6b64\u5916\uff0cCDs\u8fd8\u53ef\u4f5c\u4e3a\u4e00\u79cd\u751f\u7269\u4f20\u611f\u5668\u8bd5\u5242\u7528\u4e8e\u68c0\u6d4b\u751f\u7269\u7cfb\u7edf\u4e2d\u7684\u94c1\u79bb\u5b50\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aShoujun Zhu, Qingnan Meng, Lei Wang\u00a0et al. Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging. Angew. Chem. Int. Ed. 2013, 52, 3953\u20133957.<\/p>\n

10<\/b><\/strong>\u00a0<\/b><\/strong>JACS\uff1a<\/b><\/strong>\u6709\u673a\u91d1\u5c5e\u5364\u5316\u9499\u949b\u77ff\u4f5c\u4e3a\u5149\u4f0f\u7535\u6c60\u7684\u53ef\u89c1\u5149\u654f\u5316\u5242<\/b><\/strong><\/p>\n

\u56fe10 \u00a0\u6709\u673a\u91d1\u5c5e\u5364\u5316\u9499\u949b\u77ff\u7684\u5149\u654f\u7279\u6027<\/p>\n

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\u4e1c\u4eac\u5927\u5b66\u7684Tsutomu Miyasaka\u6559\u6388\u7b49\u7814\u7a76\u53d1\u73b0\uff0cCH3<\/sub>NH3<\/sub>PbBr3<\/sub>\u548cCH3<\/sub>NH3<\/sub>PbI3<\/sub>\u4e24\u79cd\u6709\u673a\u5364\u4ee3\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u80fd\u6709\u6548\u5730\u654f\u5316TiO2<\/sub>\uff0c\u4f7f\u5176\u5728\u5149\u7ed3\u6784\u5316\u5b66\u5355\u5143\u4e2d\u53d1\u751f\u53ef\u89c1\u5149\u8f6c\u5316\u3002\u5728\u4ecb\u5b54TiO2<\/sub>\u8584\u819c\u4e0a\u81ea\u7ec4\u88c5\u65f6\uff0c\u7eb3\u7c73\u6676\u4f53\u9499\u949b\u77ff\u5177\u6709\u5f88\u5f3a\u7684\u5e26\u9699\u5438\u6536\u534a\u5bfc\u4f53\u6027\u8d28\u3002\u5149\u8c31\u7075\u654f\u5ea6\u9ad8\u8fbe800nm\u7684CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u5149\u7535\u6c60\u7684\u592a\u9633\u80fd\u8f6c\u6362\u6548\u7387\u4e3a3.8%\u3002\u57fa\u4e8eCH3<\/sub>NH3<\/sub>PbBr3<\/sub>\u7684\u7535\u6c60\u663e\u793a\u51fa0.96 V\u7684\u9ad8\u5149\u7535\u538b\u548c65%\u7684\u5916\u90e8\u91cf\u5b50\u8f6c\u6362\u6548\u7387\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aKojima A, Teshima K, Shirai Y, et al. Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells. JACS, 2009, 131(17):6050-6051.<\/p>\n

\u770b\u5b8c10\u7bc7\u70ed\u95e8\u9886\u57df\u7684\u6700\u9ad8\u5f15\u6587\u7ae0\uff0c\u8fc7\u763e\u5417\uff1f\u4e0d\u77e5\u9053\u60a8\u5fc3\u4e2d\u7684\u70ed\u70b9\u6750\u6599\u662f\u5426\u51fa\u73b0\u5728\u68b3\u7406\u4e2d\uff0c\u66f4\u591a\u7684\u9ad8\u5f15\u8bba\u6587\u6b22\u8fce\u5927\u5bb6\u7559\u8a00\u8ba8\u8bba\u3002<\/p>\n

\u672c\u6587\u7531Junas<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

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