{"id":187190,"date":"2019-10-12T06:30:24","date_gmt":"2019-10-11T22:30:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=187190"},"modified":"2019-10-11T19:44:48","modified_gmt":"2019-10-11T11:44:48","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6-adv-mater-%e7%bb%bc%e8%bf%b0-%e7%94%b5%e5%82%ac%e5%8c%96co2%e8%bf%98%e5%8e%9f%e7%9a%84%e7%94%b5%e6%9e%81%e6%9d%90%e6%96%99%e5%b7%a5%e7%a8%8b%ef%bc%9a%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=187190","title":{"rendered":"Adv. Mater.\u7efc\u8ff0: \u7535\u50ac\u5316CO2\u8fd8\u539f\u7684\u7535\u6781\u6750\u6599\u5de5\u7a0b\uff1a\u80fd\u91cf\u8f93\u5165\u548c\u8f6c\u5316\u6548\u7387"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u968f\u7740\u5168\u7403\u7ecf\u6d4e\u7684\u5feb\u901f\u589e\u957f\uff0c\u5bfc\u81f4\u4eba\u4eec\u5bf9\u80fd\u6e90\u7684\u9700\u6c42\u4e5f\u662f\u4e0d\u65ad\u589e\u957f\uff0c\u8fdb\u800c\u63a8\u52a8\u4e86\u6e05\u6d01\u80fd\u6e90\u548c\u53ef\u518d\u751f\u80fd\u6e90\u7684\u53d1\u5c55\u3002\u7136\u800c\uff0c\u5728\u5f53\u4eca\u80fd\u6e90\u7ed3\u6784\u4e2d\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u4ecd\u7136\u5360\u636e\u7740\u4e0d\u53ef\u52a8\u6447\u7684\u5730\u4f4d\u3002\u76ee\u524d\u5168\u7403\u5316\u77f3\u71c3\u6599\u71c3\u70e7\u6bcf\u5e74\u4ea7\u751f\u7684\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u6392\u653e\u91cf\u7ea6\u4e3a35.5\u4ebf\u5428\uff0c\u800c\u7eff\u8272\u690d\u7269\u548c\u81ea\u517b\u751f\u7269\u6bcf\u5e74\u6d88\u8017CO2<\/sub>\u7684\u603b\u91cf\uff08200 Mt\uff09\u8fd8\u4e0d\u5230\u4e0a\u8ff0\u6392\u653e\u603b\u91cf\u76846%\u3002\u6240\u4ee5\u521b\u9020\u53ef\u6301\u7eed\u7684\u89e3\u51b3\u65b9\u6848\u6765\u6d88\u8017\u5927\u6c14\u4e2d\u7684CO2<\/sub>\u6210\u4e3a\u5168\u4eba\u7c7b\u9762\u4e34\u7684\u6700\u7d27\u8feb\u7684\u4efb\u52a1\u4e4b\u4e00\u3002\u5176\u4e2d\uff0c\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u6280\u672f\uff08ECR\uff09\u662f\u4e00\u9879\u5f88\u6709\u524d\u9014\u7684\u6280\u672f\u3002\u5176\u5229\u7528\u5927\u6c14\u4e2d\u7684CO2<\/sub>\u4f5c\u4e3a\u5de5\u4e1a\u751f\u4ea7\u548c\u65e5\u5e38\u751f\u6d3b\u6240\u9700\u7684\u539f\u6599\uff0c\u540c\u65f6\u53ef\u4ee5\u7f13\u89e3CO2<\/sub>\u5f15\u8d77\u7684\u6e29\u5ba4\u6548\u5e94\u548c\u65e5\u76ca\u589e\u52a0\u7684\u80fd\u6e90\u9700\u6c42\u538b\u529b\u3002\u8fd1\u5e74\u6765\uff0c\u5404\u79cd\u65b0\u578b\u7535\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u5236\u5907\u4f7f\u7684ECR\u7cfb\u7edf\u7684\u5230\u957f\u8db3\u7684\u53d1\u5c55\u3002\u56e0\u6b64\uff0c\u975e\u5e38\u6709\u5fc5\u8981\u5bf9\u5176\u53d1\u5c55\u8fdb\u884c\u603b\u7ed3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5357\u4eac\u5927\u5b66\u6731\u4fca\u6770\u6559\u6388\u548c\u7f8e\u56fd\u534e\u76db\u987f\u5dde\u7acb\u5927\u5b66Yuehe Lin\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8054\u5408\u603b\u7ed3\u5e76\u62a5\u9053\u4e86\u5728ECR\u7cfb\u7edf\u4e2d\u9633\u6781\u6750\u6599\u548c\u9634\u6781\u6750\u6599\u7684\u50ac\u5316\u5242\u5728\u9ad8\u6548\u80fd\u91cf\u8f93\u5165\u548c\u6709\u6548\u7684\u591a\u76f8\u50ac\u5316\u8f6c\u5316\u9886\u57df\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u57fa\u4e8e\u80fd\u6e90\u6027\u8d28\u548c\u9633\u6781\u6750\u6599\u4f5c\u7528\u7684\u4e0d\u540c\uff0c\u4f5c\u8005\u8be6\u7ec6\u4ecb\u7ecd\u4e86ECR\u7cfb\u7edf\u7684\u57fa\u672c\u539f\u7406\uff0c\u5305\u62ec\u5149\u7535\u9633\u6781\u8f85\u52a9ECR\u7cfb\u7edf\u548c\u751f\u7269\u9633\u6781\u8f85\u52a9ECR\u7cfb\u7edf\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u4ecb\u7ecd\u4e86ECR\u7cfb\u7edf\u7684\u9634\u6781\u53cd\u5e94\u673a\u7406\u548c\u9014\u5f84\uff0c\u5e76\u4e14\u8ba8\u8bba\u4e86\u63d0\u9ad8ECR\u8f6c\u5316\u7387\u548c\u9009\u62e9\u6027\u7684\u4e0d\u540c\u9634\u6781\u50ac\u5316\u8bbe\u8ba1\u7b56\u7565\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u4e5f\u4ecb\u7ecd\u4e86\u9633\u6781\u6750\u6599\u548c\u9634\u6781\u50ac\u5316\u5242\u6240\u9762\u4e34\u7684\u65b0\u6311\u6218\u548c\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u3002\u603b\u4e4b\uff0c\u8be5\u6587\u7684\u603b\u7ed3\u6709\u5229\u4e8e\u4fc3\u8fdbECR\u7cfb\u7edf\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cElectrode Materials Engineering in Electrocatalytic CO2<\/sub> Reduction: Energy Input and Conversion Efficiency\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u4f7f\u7528\u4e0d\u540c\u9633\u6781\u7684\u5404\u79cdECR\u7cfb\u7edf\u793a\u610f\u56fe<\/strong>
\n \"\"
\n \uff08A\uff09\u666e\u901a\u9633\u6781\uff1b\uff08B\uff09\u5149\u7535\u9633\u6781\uff1b\uff08C\uff09\u751f\u7269\u9633\u6781\u3002<\/p>\n

\u56fe\u4e8c\u3001\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u5f97\u5230\u7684\u4e3b\u8981\u4ea7\u7269\u53cd\u5e94\u9014\u5f84<\/strong>
\n \"\"
\n \uff08A\uff09C1\u4ea7\u54c1\uff1b\uff08B\uff09C2\u4ea7\u54c1\u3002<\/p>\n

\u56fe\u4e09\u3001TiO2<\/sub>\u53ca\u5176\u590d\u5408\u6750\u6599\u4f5c\u4e3aPA-ECR\u7cfb\u7edf\u7684\u9633\u6781\u6750\u6599<\/strong>
\n \"\"\uff08A\uff09TiO2<\/sub>\u7eb3\u7c73\u68d2\u5149\u9633\u6781\u548c\u9540\u9521GDE\u9634\u6781\u7684\u7535\u5316\u5b66\u6d41\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08B\uff095\uff05Pt\u6539\u6027\u7684TiO2<\/sub>\u7eb3\u7c73\u7ba1\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff09PA-ECR\u7cfb\u7edf\u7684\u7535\u6d41-\u65f6\u95f4\u66f2\u7ebf\uff0c\u5176\u4e2d\u4f7f\u75285\uff05Pt\u6539\u6027\u7684TiO2<\/sub>\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u5149\u9633\u6781\uff0cGO\/Ni\u6ce1\u6cab\u4f5c\u4e3a\u9634\u6781\u3002<\/p>\n

\u56fe\u56db\u3001BiVO4<\/sub>\u53ca\u5176\u590d\u5408\u6750\u6599\u4f5c\u4e3aPA-ECR\u7cfb\u7edf\u7684\u9633\u6781\u6750\u6599<\/strong>
\n \"\"\uff08A\uff09Co-Pi\/BiVO4<\/sub>\u5149\u7535\u9633\u6781\u548cEC-PDA\u751f\u7269\u9634\u6781\u7ec4\u5efa\u7684PA-ECR\u7cfb\u7edf\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08B\uff09\u7eafBiVO4<\/sub>\u548cCoPi\/BiVO4<\/sub>\u7535\u6781\u5728\u5149\u7167\u4e0b\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08C\uff09\u5149\u9a71CO2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08D\uff09Co-Ci\/BiVO4<\/sub>\/WO3<\/sub>\u5149\u9633\u6781\u548cCu\u9634\u6781\u7684PA-ECR\u7cfb\u7edf\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08E-F\uff09\u4e0d\u540c\u5149\u7535\u9633\u6781\u7684\u5149\u7535\u6d41\u548c\u7535\u6d41\u8f6c\u6362\u6548\u7387\uff1b<\/p>\n

\uff08G\uff09CNTsZnO-Co3<\/sub>O4<\/sub> NW\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08H\uff09CNTs-ZnO-Co3<\/sub>O4<\/sub> NW\uff08T-ZnO\uff09\u548c\u539f\u59cbZnO\uff08P-ZnO\uff09\u5149\u9633\u6781\u5206\u522b\u7ec4\u5efa\u7684PA-ECR\u7cfb\u7edf\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94\u3001BA-ECR\u7cfb\u7edf\u7684\u9633\u6781\u6750\u6599<\/strong>
\n \"\"\uff08A\uff09\u4f7f\u7528\u5fae\u751f\u7269\u63a5\u79cd\u7684\u78b3\u7ea4\u7ef4\u9633\u6781\u548cMWCNT\/CoTPc\u9634\u6781\u7684MFC\u9a71\u52a8\u7684BA-ECR\u7cfb\u7edf\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08B\uff09\u4e0d\u540c\u9633\u6781\u7684\u7535\u4f4d-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u516d\u3001\u4e0d\u540c\u6df7\u5408\u751f\u7269\u819c\u7684EET\u8fc7\u7a0b<\/strong>
\n \"\"\uff08A\uff09rGO\/\u5e0c\u74e6\u6c0f\u83cc\u6742\u4ea4\u751f\u7269\u819c\uff1b<\/p>\n

\uff08B\uff09PPy\u5305\u88f9\u7684\u5e0c\u74e6\u6c0f\u83cc\u6784\u5efa\u7684\u6742\u4ea4\u751f\u7269\u819c\u3002<\/p>\n

\u56fe\u4e03\u3001BA-ECR\u7cfb\u7edf\u9633\u6781\u6750\u6599\u4e2d\u7684\u5355\u91d1\u5c5ePd\u7eb3\u7c73\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08A-B\uff09\u5404\u79cd\u7535\u52bf\u4e0b\uff0c\u4e0d\u540c\u5c3a\u5bf8\u7684Pd NPs\u4e0a\u751f\u6210CO\u7684FEs\u548cTOFs\u503c\uff1b<\/p>\n

\uff08C\uff09\u5728Pd\uff08111\uff09\u3001Pd\uff08211\uff09\uff0cPd55\u548cPd38\u4e0a\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u4e3aCO\u7684\u81ea\u7531\u80fd\u8c31\uff1b<\/p>\n

\uff08D\uff09\u5404\u79cd\u7535\u52bf\u4e0b,\u57283.7 nm Pd NPs\u4e0a\u5f62\u6210\u7532\u9178\u3001H2<\/sub>\u548cCO\u7684FEs\u503c\uff1b<\/p>\n

\uff08E\uff098 nm Au NPs\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08F\uff09\u5404\u79cd\u7535\u52bf\u4e0b\uff0c\u5177\u6709\u4e0d\u540c\u5c3a\u5bf8\u7684Au NPs\u4e0aCO\u5f62\u6210\u7684FEs\u503c\uff1b<\/p>\n

\uff08G\uff09\u5177\u6709\u4e0d\u540c\u76f4\u5f84\u7684\u5c01\u95ed\u58f3\u7acb\u65b9\u516b\u9762\u4f53Au\u7c07\u4e0aAu\uff08111\uff09\u3001Au\uff08100\uff09\u8fb9\u7f18\u548c\u62d0\u89d2\u9876\u90e8\u4f4d\u7f6e\u7684\u5bc6\u5ea6\u3002<\/p>\n

\u56fe\u516b\u3001BA-ECR\u7cfb\u7edf\u9633\u6781\u6750\u6599\u4e2d\u7684\u5355\u91d1\u5c5eCu\u7eb3\u7c73\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08A\uff09Cu RDs\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09\u5728Cu NCs\u548cCu RDs\u4e0aCO2\u8fd8\u539f\u4e3a\u5404\u79cd\u4ea7\u54c1\u7684FEs\u503c\uff1b<\/p>\n

\uff08C-D\uff09SD-Cu NPs\u7684\u4f4e\u548c\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08E\uff09\u5177\u6709\u4e0d\u540c\u8986\u76d6\u7387\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u7684DFT\u76f8\u5bf9\u80fd\u91cf\uff1b<\/p>\n

\uff08F\uff09\u5728Pd\uff08111\uff09\u3001Pd\uff08100\uff09\u3001\u6c22\u5316\u94af\uff08111\uff09\u548c\u6c22\u5316\u94af\uff08100\uff09\u4e0a\u8fd8\u539fCO2\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

\u56fe\u4e5d\u3001BA-ECR\u7cfb\u7edf\u9633\u6781\u6750\u6599\u4e2d\u7684\u5355\u91d1\u5c5eAu\u6216Bi\u7eb3\u7c73\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08A\uff09\u4e0d\u540c\u91d1\u539f\u5b50\u6570\u4e0b\uff0c2 nm\u5bbd\u7684Au NW\u548cAu NP\u4e2d\u5904\u4e8e\u8fb9\u7f18\u4f4d\u70b9\u7684\u91d1\u539f\u5b50\u91cd\u91cf\u767e\u5206\u6bd4<\/p>\n

\uff08B\uff092nm\u5bbd\u3001500nm\u957f\u7684Au NW\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff09\u5404\u79cd\u7535\u52bf\u4e0b\uff0c\u4e0d\u540c\u957f\u5ea6\u76842 nm\u5bbd\u7684Au NW\u4e0aCO2<\/sub>\u8fd8\u539f\u7684FEs\u503c\uff1b<\/p>\n

\uff08D-E\uff09Bi NW\u7684\u4f4e\u548c\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08F\uff09\u5728\u9971\u548cCO2<\/sub>\uff08\u5b9e\u7ebf\uff09\u548cN2<\/sub>\uff08\u865a\u7ebf\uff09\u7684NaHCO3<\/sub>\u6eb6\u6db2\u4e2d\uff0c\u4e0d\u540c\u7535\u6781\u7684\u5085\u7acb\u53f6\u53d8\u6362\u4ea4\u6d41\u4f0f\u5b89\u56fe\u7684\u56db\u6b21\u8c10\u6ce2\u5206\u91cf\uff1b<\/p>\n

\uff08G\uff09Pd\u7eb3\u7c73\u7247\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08H-I\uff09Bi\u7eb3\u7c73\u7247\u7684SEM\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u5341\u3001BA-ECR\u7cfb\u7edf\u9633\u6781\u6750\u6599\u4e2d\u7684Pd\u6216Te\u6742\u5316\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08A\uff09\u5404\u79cd\u94dc\u57fa\u50ac\u5316\u5242\u5bf9CO2<\/sub>\u8fd8\u539f\u7684\u50ac\u5316\u6d3b\u6027\uff1b<\/p>\n

\uff08B-C\uff09Pd10<\/sub>Te3<\/sub> NWs\u652f\u6491\u7684Cu\u539f\u5b50\u5bf9\uff080.1 wt\uff05\uff09\u7684SEM\u548c\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08D\uff09Pd10<\/sub>Te3<\/sub> NWs\u652f\u6491\u7684Cu\u539f\u5b50\u5bf9\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08E\uff09\u5728-0.78 V\uff08vs RHE\uff09\u4e0b\uff0c\u4e0d\u540cCu\u6837\u54c1\u4e0a\u5f62\u6210CO\u548cH2<\/sub>\u7684FE\u503c\uff1b<\/p>\n

\uff08F\uff09\u5728\u4e0d\u540cCu\u6837\u54c1\u4e0aCO2\u6d3b\u5316\u7684\u81ea\u7531\u80fd\u8c31\u4ee5\u53caCu-APC\u4e0a\u7269\u7406\u5438\u9644\u548c\u5316\u5b66\u5438\u9644CO2<\/sub>\u7684\u6a21\u578b\u3002<\/p>\n

\u56fe\u5341\u4e00\u3001BA-ECR\u7cfb\u7edf\u9633\u6781\u6750\u6599\u4e2d\u7684Pd\u6216Au\u6742\u5316\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08A-F\uff09\u5728\u4e0d\u540c\u653e\u5927\u500d\u6570\u4e0b\u7684Pd@Pd7<\/sub>Au3<\/sub>\u3001Pd@Pd3<\/sub>Au7<\/sub>\u548cPd@Pd1<\/sub>Au9<\/sub> NCs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aElectrode Materials Engineering in Electrocatalytic CO2 Reduction: Energy Input and Conversion Efficiency<\/a><\/strong>\uff08Adv. Mater.<\/em>, 2019<\/strong>, DOI: 10.1002\/adma.201903796\uff09<\/p>\n

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