{"id":187410,"date":"2019-10-13T06:30:35","date_gmt":"2019-10-12T22:30:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=187410"},"modified":"2019-10-12T18:40:23","modified_gmt":"2019-10-12T10:40:23","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e9%a1%b6%e5%88%8aees%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%b0%b4%e7%b3%bb%e9%94%8c%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e9%9d%a2%e4%b8%b4%e7%9a%84%e9%97%ae%e9%a2%98","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=187410","title":{"rendered":"\u9876\u520aEES\u7efc\u8ff0\uff1a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u9762\u4e34\u7684\u95ee\u9898\u4e0e\u673a\u9047"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/h3>\n

\u76f8\u6bd4\u4e8e\u4f7f\u7528\u6613\u71c3\u3001\u6709\u6bd2\u7684\u6709\u673a\u7535\u89e3\u8d28\u7684\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u57fa\u4e8e\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u662f\u4e00\u79cd\u4f4e\u6210\u672c\u3001\u73af\u4fdd\u3001\u5b89\u5168\u7684\u65b0\u578b\u50a8\u80fd\u7cfb\u7edf\uff0c\u5e76\u4e14\u5176\u5728\u5c06\u6765\u53ef\u80fd\u4f1a\u88ab\u5e94\u7528\u4e8e\u7535\u7f51\u50a8\u80fd\u7cfb\u7edf\u548c\u53ef\u7a7f\u6234\u8bbe\u5907\u3002\u8fd1\u5e74\u6765\u5bf9\u6c34\u7cfbZIBs\u7684\u6b63\u6781\u3001\u950c\u8d1f\u6781\u548c\u7535\u89e3\u6db2\u7684\u7814\u7a76\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u8fdb\u5c55\uff0c\u4f46\u6c34\u7cfbZIBs\u5728\u6b63\u6781\u548c\u8d1f\u6781\u65b9\u9762\u4ecd\u7136\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u6b63\u6781\u6eb6\u89e3\u3001\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u4ea7\u751f\u7684\u4e0d\u826f\u5f71\u54cd\u3001\u950c\u679d\u6676\u3001\u8150\u8680\u3001\u949d\u5316\u548c\u526f\u4ea7\u7269\u7b49\u95ee\u9898\u90fd\u53ef\u80fd\u4f1a\u5bfc\u81f4\u6c34\u7cfbZIBs\u5bb9\u91cf\u8870\u51cf\u3001\u5e93\u4ed1\u6548\u7387\u4f4e\u548c\u77ed\u8def\u7b49\uff0c\u8fd9\u4e25\u91cd\u5236\u7ea6\u4e86\u6c34\u7cfbZIBs\u7684\u53d1\u5c55\u548c\u5546\u4e1a\u5316\u3002\u56e0\u6b64\uff0c\u603b\u7ed3\u6c34\u7cfbZIBs\u9762\u4e34\u7684\u6311\u6218\u53ca\u63d0\u51fa\u76f8\u5173\u7684\u89e3\u51b3\u65b9\u6848\u662f\u975e\u5e38\u6709\u5fc5\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/h3>\n

\u8fd1\u65e5\uff0c\u4e2d\u5357\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u5468\u6c5f\u6559\u6388\u3001\u6881\u53d4\u5168\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u7855\u58eb\u7814\u7a76\u751f\u5510\u535a\u96c5\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aEnergy & Environmental Science\uff08IF=33.25\uff09\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cIssues and Opportunities Facing Aqueous Zinc-ion Batteries<\/b><\/strong>\u201d\u7684\u7efc\u8ff0\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u5206\u6790\u4e86\u6c34\u7cfbZIBs\u7535\u6781\u6750\u6599\u548c\u7535\u89e3\u8d28\u4f18\u5316\u4e2d\u5b58\u5728\u7684\u95ee\u9898\uff08\u6b63\u6781\u6eb6\u89e3\u3001\u7531\u4e8e\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u4ea7\u751f\u7684\u4e0d\u826f\u5f71\u54cd\u3001\u950c\u679d\u6676\u3001\u8150\u8680\u3001\u949d\u5316\u548c\u526f\u4ea7\u7269\u7b49\uff09\uff0c\u603b\u7ed3\u4e86\u76ee\u524d\u63d0\u5347\u6c34\u7cfbZIBs\u6027\u80fd\u7684\u7b56\u7565\u3002\u6587\u7ae0\u63d0\u51fa\u4ec5\u4ec5\u6539\u8fdb\u6c34\u7cfbZIBs\u7535\u6781\u6750\u6599\u662f\u4e0d\u591f\u7684\uff0c\u91cd\u8981\u7684\u662f\u5bf9\u6574\u4e2a\u7535\u6c60\u7cfb\u7edf\u7684\u534f\u540c\u4f18\u5316\u3002\u6700\u540e\uff0c\u6587\u7ae0\u5bf9\u540e\u7eed\u6c34\u7cfbZIBs\u7684\u4f18\u5316\u8bbe\u8ba1\u8fdb\u884c\u4e86\u5c55\u671b\uff0c\u4ee5\u671f\u4e3a\u6c34\u7cfbZIBs\u9886\u57df\u8fdb\u4e00\u6b65\u7814\u7a76\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/h3>\n

\u56fe\u4e00\u3001\u6c34\u7cfbZIBs\u9762\u4e34\u7684\u6311\u6218\u53ca\u4f18\u5316\u7b56\u7565<\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe\u4e8c\u3001\u5e38\u89c1\u6c34\u7cfbZIBs\u9530\u57fa\u6b63\u6781\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u00a0\u03b1<\/i><\/em>-MnO2<\/sub>; (b) \u03b2<\/i><\/em>-MnO2<\/sub>; (c)\u00a0\u03bb<\/i><\/em>-MnO2<\/sub>; (d) todorokite MnO2<\/sub>; (e) \u03b4<\/i><\/em>-MnO2<\/sub>; (f) \u03b3<\/i><\/em>-MnO2<\/sub>; (g) R-MnO2<\/sub>; (h) ZnMn2<\/sub>O4<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e09\u3001\u6c34\u7cfbZIBs\u9530\u57fa\u3001\u9492\u57fa\u6b63\u6781\u7684\u6027\u80fd\u4f18\u5316<\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a, b) \u5728ZnMn2<\/sub>O4<\/sub>\u4e2d\u8bbe\u8ba1Mn\u7a7a\u4f4d\u4ee5\u51cf\u5f31\u9759\u7535\u5c4f\u969c\u5e76\u4fc3\u8fdb\u950c\u79bb\u5b50\u6269\u6563\uff1b<\/p>\n

(c)\u00a0\u5408\u6210SSWM@Mn3<\/sub>O4<\/sub>\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(d-g) V2<\/sub>O5<\/sub>, VO2<\/sub>\u00a0\u548cV6<\/sub>O13<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u53ca\u6027\u80fd\u3002<\/p>\n

\u56fe\u56db\u3001<\/b>\u6c34\u7cfbZIBs\u9492\u57fa\u6b63\u6781\u4e2d\u7684Zn2+<\/sup>\u548cH2<\/sub>O\u5171\u5d4c\u5165\u673a\u5236<\/strong><\/p>\n

\"\"<\/p>\n

(a-c)\u00a0Zn0.25<\/sub>V2<\/sub>O5<\/sub>\u00b7nH2<\/sub>O\u3001V2<\/sub>O5<\/sub>\u3001NH4<\/sub>V4<\/sub>O10<\/sub>\u4e2d\u7684Zn2+<\/sup>\u548cH2<\/sub>O\u5171\u5d4c\u5165\u673a\u5236\u3002<\/p>\n

\u56fe\u4e94\u3001<\/b>\u950c\u679d\u6676\u751f\u957f\u8fc7\u7a0b\u539f\u4f4d\u7814\u7a76\u53ca\u6c34\u7cfbZIBs\u950c\u8d1f\u6781\u8150\u8680\u3001\u679d\u6676\u3001\u949d\u5316\u5f62\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a-c) \u5728\u542b5m KOH\u548c0.15 m ZnO\u7684\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u950c\u679d\u6676\u751f\u957f\u3001\u6eb6\u89e3\u548c\u518d\u751f\u957f\u7684\u539f\u4f4d\u5b9e\u9a8c\u7814\u7a76\uff1b<\/p>\n

(d) \u6c34\u7cfbZIBs\u950c\u8d1f\u6781\u8150\u8680\u3001\u679d\u6676\u3001\u949d\u5316\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u516d\u3001<\/b>\u6c34\u7cfbZIBs\u950c\u8d1f\u6781\u4f18\u5316\u7b56\u7565<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7eb3\u7c73CaCO3<\/sub>\u5305\u8986Zn\u7b94\u4fc3\u8fdbZn\u5f62\u6838\u5747\u5300\uff1b<\/p>\n

(b, c) \u7528TiO2<\/sub>\u5305\u8986\u7a33\u5b9aZn\u8d1f\u6781\u7684\u793a\u610f\u56fe\u548cSTEM\u56fe\uff1b<\/p>\n

(d) \u5236\u5907Zn@\u77f3\u58a8\u6be1\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

(e) \u6c89\u79ef\u5728\u78b3\u7eb3\u7c73\u7ba1\u548c\u78b3\u5e03\u4e0a\u7684Zn\u8d1f\u6781\u793a\u610f\u56fe\uff1b<\/p>\n

(f) \u5728\u94dc\u9aa8\u67b6\u4e0a\u5236\u59073D Zn\u8d1f\u6781\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e03\u3001\u6c34\u7cfbZIBs\u7535\u89e3\u6db2\u4f18\u5316\u7b56\u7565<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7535\u89e3\u6db2\u4e2d\u52a0\u5165Na2<\/sub>SO4<\/sub>\u6dfb\u52a0\u5242\u80fd\u591f\u6291\u5236NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u7684\u6eb6\u89e3\u548cZn\u679d\u6676\u7684\u5f62\u6210\uff1b<\/p>\n

(b) Zn\u8d1f\u6781\u57285 M\u548c30 M ZnCl2<\/sub>\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u524d\u540e\u7684\u975e\u539f\u4f4dXRD\u56fe\uff1b<\/p>\n

(c) \u5728\u6c34\u7cfbZIBs\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0\u5341\u4e8c\u70f7\u57fa\u786b\u9178\u94a0\uff08SDS\uff09\u524d\u540e\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u3002<\/p>\n

\u56fe\u516b\u3001\u7528\u4e8e\u6c34\u7cfbZIBs\u7684\u51dd\u80f6\u7535\u89e3\u8d28\u548c\u950c\u8d1f\u6781\u8868\u9762\u6539\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7528\u660e\u80f6\u548c\u805a\u4e19\u70ef\u9170\u80fa\u5236\u5907\u5206\u5c42\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u6297\u51bb\u6c34\u51dd\u80f6\u7684\u7167\u7247\u548c\u6a21\u62df\u7684\u5206\u5b50\u6a21\u578b\uff1b<\/p>\n

(c) \u6297\u51bb\u7535\u6c60\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff08\u7535\u6d41\u5bc6\u5ea6 2.4A g-1<\/sup>\uff09\uff1b<\/p>\n

(d, e)\u00a0\u805a\u9170\u80fa\u5305\u8986\u7684\u950c\u8d1f\u6781\u4e0e\u672a\u5305\u8986\u7684\u950c\u8d1f\u6781\u5728\u5faa\u73af\u4e2d\u6c89\u79ef\u950c\u79bb\u5b50\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/h3>\n

\u6c34\u7cfbZIBs\u7535\u6c60\u5177\u6709\u5b89\u5168\u6027\u9ad8\u3001\u6210\u672c\u4f4e\u3001\u73af\u4fdd\u7b49\u4f18\u70b9\uff0c\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u672c\u6587\u56de\u987e\u4e86\u8fd1\u5e74\u6765\u6c34\u7cfbZIBs\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u5e76\u5bf9\u7535\u6c60\u7ed3\u6784\u7684\u4f18\u5316\u7b56\u7565\uff08\u5305\u62ec\u6b63\u6781\u3001\u8d1f\u6781\u548c\u7535\u89e3\u6db2\uff09\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u63a2\u8ba8\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u4ecd\u6709\u4e00\u4e9b\u95ee\u9898\u6709\u5f85\u89e3\u51b3\u3002\u4ece\u8fd9\u4e2a\u89d2\u5ea6\uff0c\u6211\u4eec\u5bf9\u9ad8\u6027\u80fd\u6c34\u6027ZIB\u63d0\u51fa\u4e86\u4e00\u4e9b\u5c55\u671b\u3002<\/p>\n

1. \u5236\u5907\u56fa\u6001\u6216\u51dd\u80f6\u7535\u89e3\u8d28<\/p>\n

\u6c34\u7cfbZIBs\u5e38\u7528\u7684\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u5b58\u5728\u5927\u91cf\u5177\u6709\u9ad8\u53cd\u5e94\u6d3b\u6027\u7684\u6c34\uff0c\u8fd9\u4f1a\u5f15\u8d77\u7684\u7535\u5316\u5b66\u526f\u53cd\u5e94\u548c\u4e0d\u53ef\u63a7\u5236\u7684\u56fa\u6db2\u754c\u9762\u53cd\u5e94\u3002\u56fa\u4f53\/\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u6d3b\u6027\u6c34\u542b\u91cf\u5c11\u3001\u5f39\u6027\u6a21\u91cf\u9ad8\uff0c\u53ef\u4ee5\u89e3\u51b3\u6c34\u7cfbZIBs\u7684\u8fd9\u4e00\u95ee\u9898\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u56fa\u4f53\/\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u5177\u6709\u673a\u68b0\u5f3a\u5ea6\u9ad8\u3001\u5ef6\u5c55\u6027\u597d\u3001\u53ef\u52a0\u5de5\u6027\u597d\u7b49\u7279\u70b9\uff0c\u672a\u6765\u5728\u667a\u80fd\u3001\u67d4\u6027\u3001\u8010\u78e8\u7b49\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\uff0c\u56e0\u6b64\u53d1\u5c55\u56fa\u4f53\/\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u662f\u975e\u5e38\u6709\u5fc5\u8981\u7684\u3002<\/p>\n

2.\u6784\u5efa3D\u950c\u8d1f\u6781\u4e0e\u950c\u8d1f\u6781\u8868\u9762\u4f18\u5316<\/p>\n

\u4e09\u7ef4\u7ed3\u6784\u7684\u7eb3\u7c73\u950c\u8d1f\u6781\u7684\u7535\u6d3b\u6027\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u80fd\u4ea7\u751f\u5747\u5300\u7684\u7535\u573a\u6d41\u7ebf\uff0c\u6709\u6548\u5730\u51cf\u5c0f\u950c\u6210\u6838\u5c3a\u5bf8\uff0c\u4fdd\u8bc1\u950c\u79bb\u5b50\u7684\u5747\u5300\u6c89\u79ef\uff0c\u4ece\u800c\u51cf\u5c11\u679d\u6676\u7684\u5f62\u6210\u3002\u6b64\u5916\uff0c\u5206\u5c42\u591a\u5b54\u7684\u5f62\u8c8c\u6709\u52a9\u4e8e\u51cf\u5c0f\u4f53\u79ef\u53d8\u5316\u548c\u4fdd\u6301\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u3002\u4e09\u7ef4\u7ed3\u6784\u7684\u950c\u8d1f\u6781\u5728\u7ed3\u6784\u548c\u7535\u5316\u5b66\u4f20\u8f93\u673a\u7406\u4e0a\u4e0e\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u5177\u6709\u5f88\u5f3a\u7684\u4e92\u8865\u6027\u3002\u80fd\u591f\u6709\u6548\u63d0\u9ad8\u7535\u6781\/\u7535\u89e3\u6db2\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u6d3b\u6027\u3002<\/p>\n

\u8868\u9762\u6539\u6027\u662f\u63d0\u9ad8\u950c\u8d1f\u6781\u6027\u80fd\u7684\u6709\u6548\u624b\u6bb5\u3002\u901a\u8fc7\u5efa\u7acb\u7f13\u51b2\u5c42\uff0c\u9632\u6b62\u950c\u8d1f\u6781\u8868\u9762\u76f4\u63a5\u66b4\u9732\u5728\u7535\u89e3\u6db2\u4e2d\uff0c\u53ef\u4ee5\u663e\u8457\u6291\u5236\u950c\u8150\u8680\u548c\u6790\u6c22\u3002<\/p>\n

3. \u539f\u4f4d\u63d0\u5347\u8d1f\u6781\u6027\u80fd\uff0c\u5bfb\u627e\u65b0\u7684\u8d1f\u6781\u6750\u6599<\/p>\n

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\u7531\u4e8eV\u5143\u7d20\u548cMn\u5143\u7d20\u7684\u4ef7\u6001\u4e30\u5bcc\uff0c\u91c7\u7528\u53cc\u7535\u5b50\u6216\u591a\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4ee3\u66ff\u4f20\u7edf\u7684\u5355\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u662f\u4e00\u79cd\u63d0\u9ad8\u6b63\u6781\u6027\u80fd\u7684\u53ef\u884c\u65b9\u6cd5\uff08\u5982\u5728MnO2<\/sub>\u4e2d\u5b9e\u73b0Mn4+<\/sup>\/Mn2+<\/sup>\u4ee3\u66ffMn4+<\/sup>\/Mn3+<\/sup>\uff09\uff0c\u5b83\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8\u5bb9\u91cf\uff0c\u800c\u4e14\u53ef\u4ee5\u62d3\u5bbd\u7535\u538b\u7a97\u53e3\u3002\u53e6\u5916\uff0c\u901a\u8fc7\u91c7\u7528\u4e0d\u540c\u7684\u7535\u89e3\u6db2\u5206\u522b\u6291\u5236\u6b63\u6781\u548c\u8d1f\u6781\u6790\u6c22\u6790\u6c27\u8fc7\u7a0b\uff0c\u4e5f\u80fd\u591f\u6709\u6548\u62d3\u5bbd\u7535\u538b\u7a97\u53e3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Issues and Opportunities Facing Aqueous Zinc-ion Batteries <\/b><\/strong>(Energy Environ.\u00a0Sci. 2019, DOI: 10.1039\/c9ee02526j.\u00a0https:\/\/pubs_rsc.gg363.site\/en\/content\/articlehtml\/2019\/ee\/c9ee02526j)<\/p>\n

\u672c\u6587\u7531\u7f16\u8f91\u90e8\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

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