{"id":187732,"date":"2019-10-21T06:30:18","date_gmt":"2019-10-20T22:30:18","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=187732"},"modified":"2019-10-20T16:58:57","modified_gmt":"2019-10-20T08:58:57","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e7%8e%8b%e6%96%8c%e9%99%86%e4%bf%8aaem%ef%bc%9a%e5%bc%80%e5%8f%91%e8%83%bd%e5%9c%a8%e6%b0%b4%e5%92%8c%e7%a9%ba%e6%b0%94%e4%b8%ad%e9%95%bf%e6%97%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=187732","title":{"rendered":"\u738b\u658c&\u9646\u4fcaAEM\uff1a\u5f00\u53d1\u80fd\u5728\u6c34\u548c\u7a7a\u6c14\u4e2d\u957f\u65f6\u95f4\u5faa\u73af\u7684\u65e0\u679d\u6676\u67d4\u6027\u7ea4\u7ef4\u950c\u7535\u6c60"},"content":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n

\u53ef\u7a7f\u6234\u7535\u5b50\u8bbe\u5907\u7684\u84ec\u52c3\u53d1\u5c55\u9700\u8981\u7075\u6d3b\u3001\u9ad8\u6027\u80fd\u548c\u53ef\u7a7f\u6234\u7684\u50a8\u80fd\u88c5\u7f6e\u3002\u5728\u5404\u79cd\u5668\u4ef6\u4e2d\uff0c\u7ea4\u7ef4\u72b6\u6c34\u6027\u53ef\u5145\u950c\u7535\u6c60\uff08FARZBs\uff09\u56e0\u5176\u9ad8\u950c\u4e30\u5ea6\u3001\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u8f93\u51fa\u6f5c\u529b\u548c\u73af\u5883\u53cb\u597d\u6027\u800c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4f46\u662f\uff0cFARZBs\u7684\u53d1\u5c55\u53d7\u5230\u5faa\u73af\u5bff\u547d\u5dee\u548c\u5145\u653e\u7535\u6027\u80fd\u5dee\u7684\u9650\u5236\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8e\u950c\u679d\u6676\u7684\u751f\u957f\u4ee5\u53ca\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u4e0d\u53ef\u9006\u6027\u589e\u52a0\u3002\u76ee\u524d\u5df2\u7ecf\u4f7f\u7528\u8bb8\u591a\u7b56\u7565\u6765\u6539\u5584\u950c\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u548c\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4e14\u53d6\u5f97\u4e86\u4e0d\u9519\u7684\u8fdb\u5c55\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u7f3a\u4e4f\u5408\u9002\u7684\u5177\u6709\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u548c\u67d4\u97e7\u6027\u7684\u7ea4\u7ef4\u72b6\u7535\u6781\uff0cFARZB\u7684\u7814\u7a76\u4ecd\u5904\u4e8e\u65e9\u671f\u9636\u6bb5\u3002\u6b64\u5916\uff0c\u5728\u7279\u6b8a\u7684\u60c5\u51b5\u4e0b\uff0c\u4f8b\u5982\u4e0b\u96e8\u548c\u51fa\u6c57\uff0c\u6c34\u5206\u5b50\u53ef\u80fd\u4f1a\u5728\u9ad8\u6e7f\u5ea6\u4e0b\u6e17\u900f\u5230\u7535\u6c60\u4e2d\uff0c\u5e76\u5bfc\u81f4\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u53d8\u5316\u4ee5\u53ca\u4e0e\u7535\u6c60\u5185\u90e8\u6c34\u7684\u5bc4\u751f\u53cd\u5e94\uff0c\u4ece\u800c\u52a0\u901f\u7535\u6c60\u6545\u969c\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5728\u7a7a\u6c14\u4e2d\u6d4b\u8bd5\u7684FARZBs\u7684\u7075\u6d3b\u6027\u548c\u5faa\u73af\u5bff\u547d\u8fd8\u8fdc\u8fdc\u4e0d\u80fd\u4ee4\u4eba\u6ee1\u610f\uff0c\u66f4\u4e0d\u7528\u8bf4\u5728\u6c34\u4e2d\u4f7f\u7528\u4e86\u3002\u540c\u65f6\uff0cFARZBs\u7684\u4e00\u7ef4\uff081D\uff09\u7ea4\u7ef4\u7535\u6781\u4e2d\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u4ecd\u672a\u5f97\u5230\u5145\u5206\u7814\u7a76\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u6297\u5f2f\u548c\u9632\u6c34\u6027\u80fd\u7684\u957f\u5faa\u73af\u5bff\u547dFARZBs\u662f\u975e\u5e38\u7406\u60f3\u7684\uff0c\u4f46\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u4e2d\u7269\u9662\u5316\u5de5\u6750\u6599\u7814\u7a76\u6240\u7a0b\u5efa\u4e3d\u526f\u7814\u7a76\u5458\u3001\u738b\u658c\u7814\u7a76\u5458<\/strong>\u548c\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u9646\u4fca\u7814\u7a76\u5458<\/strong>\u901a\u8fc7\u5728\u954d\u4e1d\u4e0a\u751f\u957f\u7684\u4e09\u7ef4\uff083D\uff09\u7247\u72b6\u950c\u8d1f\u6781\u548c\u5728\u954d\u4e1d\u4e0a\u751f\u957f\u7684Co3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\uff08CNWA\uff09\u4f5c\u4e3a\u6b63\u6781\uff0c\u83b7\u5f97\u4e86\u5728\u6c34\u548c\u7a7a\u6c14\u4e2d\u5faa\u73af\u5bff\u547d\u957f\u7684\u53ef\u5145\u7535\u7ea4\u7ef4\u72b6Zn\/\/Co3<\/sub>O4<\/sub>\u7535\u6c60\u3002\u8d1f\u6781\u6750\u6599\u5219\u8bbe\u8ba1\u4e86\u951a\u56fa\u5728N\u3001O\u529f\u80fd\u5316\u78b3\u7ea4\u7ef4\uff08ZFCF\uff09\u4e0a\u76843D\u950c\u8584\u7247\uff0c\u901a\u8fc7\u591a\u79cd\u8868\u5f81\u65b9\u6cd5\uff0c\u5e76\u4e0e\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u7814\u7a76\u76f8\u7ed3\u5408\uff0c\u4ee5\u786e\u8ba4\u950c\u53ef\u4ee5\u5747\u5300\u5730\u5728\u8d1f\u6781\u4e0a\u751f\u957f\u5e76\u6291\u5236\u950c\u679d\u6676\u7684\u751f\u957f\uff0c\u8fd9\u662f\u7531\u4e8e\u950c\u5728N\u548cO\u8868\u9762\u4eb2\u950c\u529f\u80fd\u6027\u4f4d\u70b9\u548c\u591a\u5b54\u7ed3\u6784\u4e0a\u7684\u66f4\u5f3a\u5438\u9644\u5728\u78b3\u7ea4\u7ef4\u675f\u4e4b\u95f4\u3002\u5bf9\u4e8e\u6b63\u6781\u800c\u8a00\uff0cCo3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\u5728\u954d\u4e1d\u96c6\u7535\u5668\u4e0a\u7684\u76f4\u63a5\u751f\u957f\u6709\u76ca\u4e8e\u7535\u5b50\u4f20\u5bfc\u6027\uff0c\u5feb\u901f\u7684\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u56e0\u6b64\u6709\u5229\u4e8e\u5feb\u901f\u7684\u5145\u653e\u7535\u80fd\u529b\u548c\u826f\u597d\u7684\u53ef\u9006\u6027\u3002\u7ea4\u7ef4\u72b6ZFCF\/\/CNWA\u5168\u7535\u6c60\u5c55\u793a\u4e86\u5353\u8d8a\u7684\u7535\u6c60\u6027\u80fd\uff0c\u57282000\u6b21\u5faa\u73af\u540e\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a90\uff05\uff0c\u4ece\u800c\u5bfc\u81f4\u4e865.63 mWh cm-3<\/sup>\u7684\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u548c72.5 \u00b5Wh cm-2<\/sup>\u7684\u9762\u80fd\u91cf\u5bc6\u5ea6\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u8bbe\u5907\u57280\u00b0\u81f3180\u00b0\u7684\u5f2f\u66f2\u8303\u56f4\u5185\u663e\u793a\u51fa\u51fa\u8272\u7684\u67d4\u97e7\u6027\uff0c\u57283000\u6b21\u5faa\u73af\u4e2d\u5b8c\u5168\u6d78\u5165\u6c34\u4e2d\u8d85\u8fc733\u5c0f\u65f6\u5177\u6709\u51fa\u8272\u7684\u957f\u5faa\u73af\u5bff\u547d\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u7ea6\u4e3a80\uff05\u3002\u8be5\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u7ea4\u7ef4\u72b6Zn\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u8010\u7528\u6027\u548c\u9632\u6c34\u6027\uff0c\u8fd9\u5bf9\u4e8e\u53ef\u7a7f\u6234\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002\u8be5\u6210\u679c\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201cDendrite<\/strong>\u2010<\/strong>Free Flexible Fiber<\/strong>\u2010<\/strong>Shaped Zn Battery with Long Cycle Life in Water and Air<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdv. Energy Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>\u7ea4\u7ef4\u72b6<\/strong>ZFCF\/\/CNWA<\/strong>\u5168\u7535\u6c60\u7684\u5236\u9020\u8fc7\u7a0b\u6781\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Zn\/\/Co3<\/sub>O4<\/sub>\u7535\u6c60\u5236\u4f5c\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b-c\uff09\u751f\u957f\u5728\u954d\u4e1d\u4e0aCo3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\uff08CNWA\uff09\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08d\uff09\u751f\u957f\u5728\u954d\u4e1d\u4e0aCo3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\uff08e\uff09\u751f\u957f\u5728\u954d\u4e1d\u4e0a\u7684Co3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\u7684HRTEM\u56fe\u50cf\uff0c\u63d2\u56fe\u662fSAED\u56fe\u50cf\u3002<\/p>\n

\uff08f-g\uff09\u6c89\u79ef\u5728\u78b3\u7ea4\u7ef4\uff08ZFCF\uff09\u4e0a\u7684\u950c\u7247\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c\uff1a<\/strong>\u6b63\u8d1f\u6781\u7535\u5316\u5b66\u6d4b\u91cf<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09ZFCF\u8d1f\u6781\u57280.1 mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\uff08b\uff09CNWA\u6b63\u6781\u57285 mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff09CNWA\u6b63\u6781\u57280.25\u81f33.75A cm-3<\/sup>\u7684\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u6027\u80fd\u3002<\/p>\n

\uff08d\uff09CNWA\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\uff08e\uff09CNWA\u7535\u6781\u57281 A cm-3<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/strong>Zn\/\/Co3<\/sub>O4<\/sub>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09ZFCF\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u548c\u5e02\u552eZW\uff08Zn\u7ebf\uff09\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u6027\u80fd\u3002<\/p>\n

\uff08b\uff09ZFCF\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u548c\u5546\u7528ZW\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u57281 A cm-3<\/sup>\uff084 A g-1<\/sup>\uff09\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\uff08c\uff09ZFCF\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\uff08d\uff09ZFCF\/\/CNWA\u7ea4\u7ef4\u5168\u7535\u6c60\u5728\u4e0d\u540c\u7535\u52bf\u4e0b\u7684i<\/em>\/\u03bd1\/2<\/sup>\u4e0e\u03bd1\/2<\/sup>\u66f2\u7ebf\u56fe\u3002<\/p>\n

\uff08e\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u548c\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u8868\u9762\u7535\u5bb9\u8d21\u732e\u3002<\/p>\n

\uff08f\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u8868\u9762\u7535\u5bb9\u5bb9\u91cf\u548c\u6269\u6563\u53d7\u9650\u5bb9\u91cf\u7684\u8d21\u732e\u7387\u3002<\/p>\n

\uff08g\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.02 A cm-3<\/sup>\uff080.4 mAh g-1<\/sup>\uff09\u7684\u6761\u4ef6\u4e0b\uff0c\u5bb9\u91cf\u4e3a0.02 Ah cm-3<\/sup>\uff080.4 mAh g-1<\/sup>\uff09\u7684ZFCF\u548c\u5e02\u552eZW\u9633\u6781\u7684Zn\/Zn\u5bf9\u79f0\u7535\u6c60\u4e2dZn\u5265\u79bb\/\u7535\u9540\u7684\u6f5c\u5728\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

\uff08h\uff09\u57280.02 A cm-3<\/sup>\uff080.4 mA g-1<\/sup>\uff09\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5bb9\u91cf\u4e3a0.02 Ah cm-3<\/sup>\uff080.4 mAh g-1<\/sup>\uff09\u7684ZFCF\u548c\u5e02\u552eZW\u7535\u6781\u5728\u7b2c1\u300110\u300150\u548c200\u5c0f\u65f6\u7684\u7535\u4f4d-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

\uff08i\uff09\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5546\u7528ZW\u548cZFCF\u7684Zn\u6210\u6838\u7535\u4f4d\u3002<\/p>\n

\u56fe\u56db\uff1a<\/strong>\u4e0d\u540c\u6761\u4ef6\u4e0b\u7535\u6781\u5f62\u8c8c\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\u4e0d\u540c\u5faa\u73af\u7535\u6d41\u5bc6\u5ea6\u4e0b\u950c\u7535\u6781\u7684\u626b\u63cf\u7535\u955c\u5f62\u8c8c\u7814\u7a76\uff1a\uff08a-d\uff09\u5546\u7528ZW\u9633\u6781\uff1b\uff08e-h\uff09ZFCF\u9633\u6781\uff1b\uff08i-l\uff09ZCFN\u9633\u6781\u3002<\/p>\n

\u56fe\u4e94\uff1a\u5168\u7535\u6c60\u5b58\u50a8\u673a\u5236\u7684\u63a2\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09CNWA\u7535\u6781\u7684\u539f\u4f4dXRD\u56fe\u8c31\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff0c\u5bf9\u5e94\u4e8e1 A cm-3<\/sup>\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff09CNWA\u9634\u6781\u7ea4\u7ef4\u7535\u6781\u5728\u5faa\u73af2000\u6b21\u524d\u540e\u7684TEM\u548cSAED\u56fe\u50cf\u3002\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A cm-3<\/sup>\u3002<\/p>\n

\uff08d\uff09ZFCF\/\/CNWA\u7ea4\u7ef4\u72b6\u7535\u6c60\u5728\u4e0d\u540c\u5f2f\u66f2\u89d2\u5ea6\u4e0b\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n

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