{"id":188062,"date":"2019-10-27T06:30:28","date_gmt":"2019-10-26T22:30:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=188062"},"modified":"2019-10-26T21:13:12","modified_gmt":"2019-10-26T13:13:12","slug":"%e5%b7%b2%e5%9b%9e%e5%a4%8d%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80%e5%90%b4%e5%bf%a0%e5%b8%85adv-funct-mater-%ef%bc%9a%e4%b8%80%e6%ad%a5%e5%88%b6%e5%a4%87%e7%9f%b3%e5%a2%a8%e7%83%af%e9%9b%86","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=188062","title":{"rendered":"\u5927\u8fde\u5316\u7269\u6240\u5434\u5fe0\u5e05Adv. Funct. Mater.\uff1a\u4e00\u6b65\u5236\u5907\u77f3\u58a8\u70ef\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\uff08MSCs\uff09\u7531\u4e8e\u5177\u6709\u5145\u653e\u7535\u901f\u7387\u5feb\uff0c\u529f\u7387\u5bc6\u5ea6\u9ad8\uff0c\u5faa\u73af\u5bff\u547d\u597d\u7b49\u4f18\u70b9\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6781\u6709\u7ade\u4e89\u529b\u7684\u5fae\u578b\u529f\u7387\u6e90\u3002\u7136\u800c\uff0c\u5355\u4e2a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8f93\u51fa\u7535\u538b\u548c\u7535\u6d41\u6709\u9650\uff0c\u96be\u4ee5\u6ee1\u8db3\u7535\u5b50\u5668\u4ef6\u7684\u5e94\u7528\u9700\u6c42\uff0c\u56e0\u6b64\u5728\u5b9e\u9645\u4e2d\u901a\u5e38\u9700\u8981\u5c06\u591a\u4e2a\u8d85\u7ea7\u7535\u5bb9\u5668\u8fdb\u884c\u4e32\u8054\u548c\uff08\u6216\uff09\u5e76\u8054\u96c6\u6210\u6765\u63d0\u9ad8\u7535\u538b\u548c\uff08\u6216\uff09\u7535\u6d41\u3002\u8fd1\u5e74\u6765\u7eb3\u7c73\u6750\u6599\uff08\u77f3\u58a8\u70ef\u3001MXene\u3001\u78b3\u7eb3\u7c73\u7ba1\u7b49\uff09\u7684\u53d1\u5c55\u548c\u5fae\u52a0\u5de5\u6280\u672f\uff08\u5149\u523b\u3001\u5370\u5237\u3001\u6fc0\u5149\u523b\u5199\u3001\u5149\u5316\u5b66\u8fd8\u539f\u7b49\uff09\u7684\u8fdb\u6b65\u663e\u8457\u63d0\u9ad8\u4e86\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6027\u80fd\uff0c\u5e76\u8d4b\u4e88\u4e86\u5176\u4e30\u5bcc\u7684\u529f\u80fd\u6027\u3002\u4f46\u662f\uff0c\u76ee\u524d\u62a5\u9053\u7684\u5927\u90e8\u5206\u96c6\u6210\u5316\u5fae\u578b\u50a8\u80fd\u5668\u4ef6\u4e2d\uff0c\u5176\u7535\u6781\u6750\u6599\u5408\u6210\uff0c\u56fe\u6848\u5316\u5fae\u7535\u6781\u5355\u4f53\u5236\u5907\u548c\u591a\u4e2a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u96c6\u6210\u4e00\u822c\u7531\u591a\u4e2a\u5206\u79bb\u7684\u6b65\u9aa4\u6784\u6210\uff0c\u5927\u5927\u589e\u52a0\u4e86\u5236\u4f5c\u8fc7\u7a0b\u7684\u590d\u6742\u5ea6\u3002\u56e0\u6b64\uff0c\u9700\u8981\u5f00\u53d1\u7b80\u5355\u9ad8\u6548\u7684\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u5236\u5907\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240<\/strong>\u7684\u5434\u5fe0\u5e05\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u91c7\u7528\u6fc0\u5149\u70ed\u89e3\u805a\u9170\u4e9a\u80fa\u7684\u65b9\u6cd5\uff0c\u4e00\u6b65\u5b9e\u73b0\u4e86\u77f3\u58a8\u70ef\u7535\u6781\u6750\u6599\uff08LIG\uff09\u7684\u5236\u5907\u3001\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\uff08LIG-MSCs\uff09\u5355\u4f53\u7684\u6784\u5efa\u548c\u591a\u4e2a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4e00\u4f53\u5316\u96c6\u6210\u3002\u6839\u636e\u4e0d\u540c\u7684\u5b9e\u9645\u5e94\u7528\u9700\u6c42\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u5bf9\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5f62\u72b6\u548c\u5927\u5c0f\u8fdb\u884c\u6709\u6548\u8c03\u63a7\uff0c\u800c\u4e14\u80fd\u591f\u5b9e\u73b0\u4efb\u610f\u6570\u91cf\u5e73\u9762\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4e32\u5e76\u8054\u96c6\u6210\uff0c\u6709\u6548\u5b9a\u5236\u5de5\u4f5c\u7535\u538b\u548c\u7535\u6d41\u3002\u7531\u4e8e\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u96c6\u6d41\u4f53\u3001\u7535\u6781\u548c\u5bfc\u7535\u8fde\u63a5\u4f53\u7ec4\u6210\u76f8\u540c\u4e14\u4e00\u6b65\u5236\u5f97\uff0c\u6240\u5f97\u5668\u4ef6\u5177\u6709\u826f\u597d\u7684\u4e00\u4f53\u6027\u3001\u67d4\u97e7\u6027\u548c\u6027\u80fd\u4e00\u81f4\u6027\u3002\u6b64\u5916\uff0c\u5728\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u6db2\u4e2d\u8be5\u5668\u4ef6\u8868\u73b0\u51fa\u51fa\u8272\u7684\u9ad8\u6e29\u7a33\u5b9a\u6027\uff0c\u53ef\u5728100 o<\/sup>C\u6761\u4ef6\u4e0b\u7a33\u5b9a\u5de5\u4f5c\u3002\u56e0\u6b64\uff0c\u8be5\u5de5\u4f5c\u4e3a\u7b80\u5355\u9ad8\u6548\u5236\u5907\u9ad8\u5ea6\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\uff0c\u5e76\u62d3\u5bbd\u4e86\u5176\u6f5c\u5728\u5e94\u7528\u573a\u666f\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>One-Step Scalable Fabrication of Graphene-Integrated Micro-Supercapacitors with Remarkable Flexibility and Exceptional Performance Uniformity<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Functional Materials<\/em><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 LIG<\/strong>\u8584\u819c\u7684\u5236\u5907\u548c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u6784\u578b\u7684\u5e73\u9762LIG-MSCs\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b-e\uff09\u4ea4\u53c9\u6307\u3001\u540c\u5fc3\u5706\u3001\u7ebf\u5f62\u548c\u6298\u53e0\u5f62\u7684LIG-MSCs\u7684\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08f\uff0cg\uff09LIG\u8584\u819c\u7684SEM\u56fe\uff1b<\/p>\n

\uff08h\uff0ci\uff09LIG\u7684TEM\u548cHRTEM\u56fe\uff1b<\/p>\n

\uff08j\uff0ck\uff09LIG\u548cPI\u8584\u819c\u7684FTIR\u56fe\u548c\u62c9\u66fc\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08l\uff0cm\uff09LIG\u7684XRD\u56fe\u548cXPS\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2 PVA\/H3<\/sub>PO4<\/sub><\/strong>\u7535\u89e3\u8d28\u4e2d\uff0c\u4ea4\u53c9\u6307\u6784\u578b\u7684<\/strong>LIG-MSC<\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u673a\u68b0\u67d4\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4ea4\u53c9\u6307\u6784\u578b\u7684LIG-MSC\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff0cc\uff09\u57285-2000 mV s-1<\/sup>\u4e0b\uff0cLIG-MSC\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u57280.01-0.1 mA cm-2<\/sup>\u4e0b\uff0cLIG-MSC\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u57280.11 mA cm-2<\/sup>\u4e0b\uff0cLIG-MSC\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08f\uff09LIG-MSC\u7684\u4ea4\u6d41\u963b\u6297\u56fe\uff08\u63d2\u56fe\u4e3a\u9ad8\u9891\u533a\u7684\u653e\u5927\u56fe\uff09\uff1b<\/p>\n

\uff08g\uff09\u5728\u4e0d\u540c\u5f2f\u66f2\u72b6\u6001\u4e0b\uff0c\u4ea4\u53c9\u6307\u6784\u578b\u7684LIG-MSC\u7684\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08h\uff09\u4e0d\u540c\u5f2f\u66f2\u72b6\u6001\u4e0b\uff0cLIG-MSC\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff08\u63d2\u56fe\uff1a100 mV s-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff09\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u4e0d\u540c\u5f62\u72b6<\/strong>LIG-MSC<\/strong>\u7684\u8bbe\u8ba1\u6784\u5efa\u53ca\u6027\u80fd\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0920 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u5e73\u9762\u6784\u578b\u7684LIG-MSC\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff0920 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u5e73\u9762\u6784\u578b\u7684LIG-MSC\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u5e73\u9762\u6784\u578b\u7684LIG-MSC\u7684\u9762\u7535\u5bb9\u968f\u626b\u63cf\u901f\u7387\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08d\uff09\u540c\u5fc3\u5706\u5f62LIG-MSCs\u7684\u4e32\u8054\u793a\u610f\u56fe\u548c\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08e\uff09100 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\u540c\u5fc3\u5706\u5f62LIG-MSCs\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08f\uff0964 \u00b5A\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\u540c\u5fc3\u5706\u5f62LIG-MSCs\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08g\uff09\u6298\u53e0\u5f62LIG-MSCs\u7684\u4e32\u8054\u793a\u610f\u56fe\u548c\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08h\uff09100 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\u6298\u53e0\u5f62LIG-MSCs\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08i\uff0944 \u00b5A\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\u6298\u53e0\u5f62LIG-MSCs\u7684GCD\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong> 4 LIG-MSCs<\/strong>\u7684\u96c6\u6210\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff0910S\u00d71P\uff0c1S\u00d74P\u548c4S\u00d74P\u8fde\u63a5\u7684\u7ebf\u5f62\u5e73\u9762\u96c6\u6210\u5316LIG-MSCs\u7684\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08d\uff09\u4e09\u4e2a\u4ea4\u53c9\u6307\u5f62LIG-MSCs\u4e32\u8054\u4e3aLCD\u4f9b\u7535\u7684\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08e\uff09200 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\uff081\u30012\u30013\uff0c\u2026\uff0c10S\u00d71P\uff09\u7684\u96c6\u6210LIG-MSCs\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08f\uff09LIG-MSCs\u7684\u5bb9\u91cf\u548c\u7535\u538b\u7a97\u53e3\u968f\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\uff081\u30012\u30013\uff0c\u2026\uff0c10S\u00d71P\uff09\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08g\uff0910 \u00b5A\u4e0b\uff0c\u4e0d\u540c\u4e32\u8054\u4e2a\u6570\uff081\u30012\u30013\uff0c\u2026\uff0c10S\u00d71P\uff09LIG-MSCs\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08h\uff09100 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u5e76\u8054\u7ec4\u6570\uff084S\u00d71P\u52304S\u00d74P\uff09\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08i\uff09100 mV s-1<\/sup>\u4e0b\uff0c\u4e0d\u540c\u5e76\u8054\u7ec4\u6570\uff084S\u00d71P\u52304S\u00d74P\uff09\u7684\u5bb9\u91cf\uff1b<\/p>\n

\uff08j\uff095 \u00b5A\u4e0b\uff0c\u4e0d\u540c\u5e76\u8054\u7ec4\u6570\uff084S\u00d71P\u52304S\u00d74P\uff09\u7684GCD\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong> 5 <\/strong>\u5728<\/strong>BMIMPF6<\/sub>-PVDF-HFP<\/strong>\u7684\u79bb\u5b50\u51dd\u80f6\u7535\u89e3\u8d28\u4e2d\uff0c\u7ebf\u5f62<\/strong>LIG-MSC<\/strong>\u7684\u9ad8\u6e29\uff08<\/strong>100\u2103<\/strong>\uff09\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff095-500 mV s-1<\/sup>\u4e0b\uff0cLIG-MSC\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09LIG-MSC\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08d\uff090.1-1 mA cm-2<\/sup>\u4e0b\uff0cLIG-MSC\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u57280.4 mA cm-2<\/sup>\u4e0b\uff0cLIG-MSC\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08f\uff09LIG-MSCs-AE\uff0cLIG-MSCs-IL-25\uff0cLIG-MSCs-IL-100\u548c\u5df2\u62a5\u9053MSCs\u7684Ragone\u56fe\u5bf9\u6bd4\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u91c7\u7528\u6fc0\u5149\u523b\u5199\u4e00\u6b65\u5b9e\u73b0\u4e86\u4ece\u7535\u6781\u6750\u6599\u5236\u5907\u3001\u5355\u4e2a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u6784\u5efa\u5230\u591a\u4e2a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u4e00\u4f53\u5316\u96c6\u6210\u7684\u6280\u672f\u8fc7\u7a0b\uff0c\u5927\u5927\u7b80\u5316\u4e86\u96c6\u6210\u5316\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5236\u4f5c\u6d41\u7a0b\uff0c\u5e76\u62d3\u5bbd\u4e86\u5176\u6f5c\u5728\u5e94\u7528\u573a\u666f\uff0c\u672a\u6765\u6709\u671b\u88ab\u7528\u4f5c\u53ef\u7a7f\u6234\u7535\u5b50\u3001\u8d34\u7247\u5f0f\u5065\u5eb7\u76d1\u6d4b\u5668\u4ef6\u7b49\u591a\u7c7b\u5fae\u7535\u5b50\u4ea7\u54c1\u7684\u529f\u7387\u6e90\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>One-Step Scalable Fabrication of Graphene-Integrated Micro-Supercapacitors with Remarkable Flexibility and Exceptional Performance Uniformity<\/strong><\/a>\uff08Advanced Functional Materials<\/em>, 2019, DOI: 10.1002\/adfm.201902860\uff09\u3002<\/p>\n

\u3010\u56e2\u961f\u7b80\u4ecb<\/strong>\u3011\uff1a<\/p>\n

\"\"<\/p>\n

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