{"id":188125,"date":"2019-10-30T06:30:17","date_gmt":"2019-10-29T22:30:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=188125"},"modified":"2019-10-29T19:28:27","modified_gmt":"2019-10-29T11:28:27","slug":"%e6%a2%b3%e7%90%86%ef%bc%81mofs%e5%9f%ba%e8%86%9c%e6%9d%90%e6%96%99%e7%9a%84%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=188125","title":{"rendered":"\u68b3\u7406\uff01MOFs\u57fa\u819c\u6750\u6599\u7684\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u7c07\u4e0e\u6709\u673a\u914d\u4f53\u901a\u8fc7\u914d\u4f4d\u952e\u94fe\u63a5\u800c\u5f62\u6210\u5468\u671f\u6027\u591a\u5b54\u7f51\u7edc\uff0c\u5176\u5177\u6709\u9ad8\u7684\u5b54\u9699\u7387\u548c\u529f\u80fd\u53ef\u8bbe\u8ba1\u6027\u4f7f\u5176\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u9886\u57df\u3002\u7136\u800c\uff0c\u5408\u6210\u5177\u6709\u826f\u597d\u52a0\u5de5\u6027\u7684MOFs\u6216\u8005\u9ad8MOFs\u8d1f\u8f7d\u91cf\u7684\u6df7\u57fa\u819c\u59cb\u7ec8\u662f\u6269\u5c55MOFs\u5e94\u7528\u7684\u6709\u6548\u9014\u5f84\u6216\u7ec8\u6781\u76ee\u6807\u3002\u8be5\u6587\u7b80\u5355\u5217\u8ff0\u4e86\u8fd1\u671fMOFs\u57fa\u819c\u6750\u6599\u5728\u591a\u79cd\u9886\u57df\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

1. \u7a33\u5b9a\u7684\u8d85\u758f\u6c34\/\u8d85\u4eb2\u6cb9\u8936\u76b1\u5fae\u7403MOF@rGO\u590d\u5408\u6750\u6599\u7528\u4e8e\u9ad8\u6548\u6cb9\u6c34\u5206\u79bb<\/b><\/strong>[<\/b><\/sup><\/strong>1<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u5408\u7406\u8bbe\u8ba1\u5177\u6709\u4f18\u5f02\u7684\u5438\u9644\u80fd\u529b\u3001\u9ad8\u6cb9\u6c34\u9009\u62e9\u6027\u548c\u4f4e\u5bc6\u5ea6\u7684\u4e09\u7ef4\u591a\u5b54\u6750\u6599\u662f\u5236\u5907\u6cb9\u6c34\u5206\u79bb\u6750\u6599\u7684\u6709\u6548\u65b9\u6cd5\u3002MOFs\u6750\u6599\u5177\u5907\u7a33\u5b9a\u3001\u53ef\u8bbe\u8ba1\u6027\u7684\u591a\u7ea7\u7eb3\u7c73\u5b54\u7ed3\u6784\uff0c\u65e2\u53ef\u4ee5\u589e\u52a0\u6750\u6599\u7684\u8868\u9762\u4eb2\u758f\u6c34\u6027\uff0c\u53c8\u53ef\u4ee5\u63d0\u9ad8\u5bf9\u6eb6\u5242\u7684\u6355\u83b7\u548c\u7a33\u5b9a\u80fd\u529b\u3002\u57fa\u4e8e\u6c34\u7a33\u5b9aMOFs\u548cMOFs\u57fa\u819c\u5236\u5907\u65b9\u6cd5\u7684\u62a5\u9053\u8d8a\u6765\u8d8a\u591a\uff0cMOFs\u5c06\u5728\u6db2\u4f53\u5206\u79bb\u9886\u57df\u53d1\u6325\u4e0d\u53ef\u66ff\u4ee3\u7684\u4f18\u52bf\u3002\u5317\u4eac\u5316\u5de5\u5927\u5b66Hongwei Fan\u548cHong Meng\u56e2\u961f\u5f00\u53d1\u4e86\u7531MOF@rGO\u7ec4\u6210\u7684\u65b0\u578b\u8d85\u758f\u6c34\/\u8d85\u4eb2\u6cb9\u6750\u6599\u590d\u5408\u6750\u6599\uff0c\u4e3a\u9ad8\u6548\u7684\u6cb9\u6c34\u5206\u79bb\u6216\u5176\u4ed6\u6297\u6c34\u6750\u6599\u63d0\u4f9b\u65b0\u7684\u8bbe\u8ba1\u601d\u8def\u3002\u57fa\u4e8e\u9ad8\u6e29\u8fd8\u539f\u81ea\u7ec4\u88c5\u7684\u65b9\u6cd5\uff0c\u5b9e\u9a8c\u56e2\u961f\u5c06MOF\u7eb3\u7c73\u9897\u7c92\u5305\u57cb\u5728\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u5c42\u4e2d\u95f4\uff0c\u5f97\u76ca\u4e8e\u8936\u76b1rGO\u5fae\u7403\u72ec\u7279\u7684\u5fae\/\u7eb3\u7c73\u5206\u7ea7\u7ed3\u6784\u548cMOF\u7eb3\u7c73\u9ad8\u5b54\u9699\u7387\uff0cMOF@rGO\u6750\u6599\u7684\u63a5\u89e6\u89d2\u53ef\u8fbe\u5230158\u00b0\uff0c\u8868\u73b0\u51fa\u8d85\u758f\u6c34\u6027\u8d28\u5e76\u4e14\u53ef\u4ee5\u9ad8\u6548\u5438\u9644\u6c34\u4e2d\u5b58\u5728\u7684\u6709\u673a\u6eb6\u5242\u548c\u6cb9\u3002\u8fdb\u4e00\u6b65\uff0c\u5b9e\u9a8c\u56e2\u961f\u5229\u7528\u6d78\u6ce1-\u70ed\u4ea4\u8054\u7684\u65b9\u6cd5\u5236\u5907\u4e86MOF@rGO@PU\u590d\u5408\u6d77\u7ef5\uff0c\u5176\u5bf9\u6cb9\u6027\u6db2\u4f53\u7684\u5438\u9644\u91cf\u53ef\u8fbe1400~2900 wt%\uff0c\u5e76\u80fd\u8fde\u7eed\u4f7f\u7528\u8d85\u8fc7100\u6b21\u3002\u8be5\u7814\u7a76\u4e0d\u4ec5\u4e3a\u6709\u673a\u6c61\u67d3\u7269\u7684\u6ea2\u6cb9\u6e05\u7406\u548c\u5e9f\u6c34\u5904\u7406\u63d0\u4f9b\u4e86\u6709\u524d\u666f\u7684\u6750\u6599\uff0c\u800c\u4e14\u4e3a\u77f3\u58a8\u70ef\/ MOF\u590d\u5408\u6750\u6599\u7684\u7ed3\u6784\u548c\u591a\u529f\u80fd\u5f00\u53d1\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u6982\u5ff5\u3002<\/p>\n

\u56fe1. MOF@rGO\u548cMOF@rGO@PU\u7684\u5236\u5907\u65b9\u6cd5\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

2. \u5177\u6709\u8d85\u9ad8\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u8d1f\u8f7d\u91cf\u7684\u6df7\u57fa\u819c\u7528\u4e8e\u9ad8\u901a\u91cf\u5206\u79bb<\/b><\/strong>[<\/b><\/sup><\/strong>2<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u6c34\u4e2d\u67d3\u6599\u5206\u5b50\u7684\u53bb\u9664\u5bf9\u4e8e\u89e3\u51b3\u5168\u7403\u65e5\u76ca\u5173\u6ce8\u7684\u7f3a\u6c34\u548c\u6c34\u8d28\u95ee\u9898\u81f3\u5173\u91cd\u8981\u3002\u800c\u5728\u5236\u836f\u548c\u751f\u7269\u5de5\u4e1a\u4e2d\uff0c\u9ad8\u6548\u7684\u624b\u6027\u548c\u86cb\u767d\u8d28\u5206\u79bb\u5728\u5149\u5b66\u6d3b\u6027\u836f\u7269\u7684\u751f\u4ea7\u548c\u751f\u7269\u6d3b\u6027\u7814\u7a76\u4e2d\u4e5f\u662f\u5fc5\u4e0d\u53ef\u5c11\u3002MOFs\u5177\u6709\u6709\u5e8f\u7684\u5f00\u653e\u901a\u9053\u3001\u5927\u7684\u5b54\u9699\u5ea6\u3001\u53ef\u9884\u6d4b\u7684\u5b54\u5f84\u548c\u53ef\u8c03\u8282\u7684\u5316\u5b66\u73af\u5883\uff0c\u4e3a\u5206\u5b50\u5206\u79bb\u5e94\u7528\u63d0\u4f9b\u4e86\u5de8\u5927\u7684\u673a\u4f1a\u3002\u5c3d\u7ba1MOF\u7ed3\u6676\u7c89\u672b\u5177\u6709\u5438\u9644\u5206\u79bb\u5206\u5b50\u7684\u80fd\u529b\uff0c\u4f46\u5b83\u4eec\u6613\u788e\u4e14\u5bb9\u6613\u5206\u89e3\u6210\u7ec6\u7c89\u672b\uff0c\u96be\u4ee5\u5236\u5907\u5927\u9762\u79ef\u65e0\u7f3a\u9677\u7684\u819c\u6750\u6599\u3002\u5bf9\u4e8e\u6df7\u57fa\u819c\u6750\u6599\uff0c\u9ad8\u7684MOF\u542b\u91cf\u4f1a\u5bfc\u81f4\u6750\u6599\u8106\u6027\u589e\u52a0\uff0c\u7ed9\u5927\u9762\u79ef\u65e0\u88c2\u7eb9\u819c\u7684\u751f\u4ea7\u5e26\u6765\u56f0\u96be\uff0c\u800c\u4f4e\u7684MOF\u8d1f\u8f7d\u91cf\u901a\u5e38\u4f1a\u5bfc\u81f4\u9009\u62e9\u6027\u4f4e\u3002\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u56e2\u961f\u5f00\u53d1\u4e86\u70ed\u8bf1\u5bfc\u76f8\u5206\u79bb-\u70ed\u538b\uff08TIPS-HoP\uff09\u7684\u7b56\u7565\uff0c\u5236\u5907\u4e86\u8d85\u9ad8MOF\u542b\u91cf\u7684\u67d4\u6027\u6df7\u57fa\u819c\uff0cMOF\u8d1f\u8f7d\u91cf\u9ad8\u8fbe86%\uff0c\u5206\u79bb\u819c\u4f9d\u7136\u4fdd\u6301\u8f83\u597d\u7684\u673a\u68b0\u6027\u80fd\u3002\u5f97\u76ca\u4e8eMOF\u6750\u6599\u7684\u9ad8\u5b54\u9699\u7387\u548c\u53ef\u8c03\u5b54\u73af\u5883\uff0c\u8be5\u6df7\u57fa\u819c\u5b9e\u73b0\u4e86\u5728\u9519\u6d41\u65b9\u5f0f\u4e0b\u9ad8\u901a\u91cf\u3001\u9ad8\u622a\u7559\u6548\u7387\u5730\u6c34\u5904\u7406\u5c0f\u5206\u5b50\u67d3\u6599\u3002\u901a\u8fc7\u66ff\u6362\u4e0d\u540c\u8868\u9762\u7535\u8377\u7684MOF\uff0c\u8be5\u6df7\u57fa\u819c\u53ef\u7528\u4e8e\u6c34\u4e2d\u53bb\u9664\u4e0d\u540c\u7535\u8377\u7684\u67d3\u6599\u5206\u5b50\u3002\u8fdb\u4e00\u6b65\u5730\u5b9e\u9a8c\u8bc1\u660e\uff0c\u66ff\u6362\u4e0d\u540c\u6027\u8d28\u7684MOFs\uff0c\u5728\u6b7b\u7aef\u8fc7\u6ee4\u6a21\u5f0f\u4e0b\uff0c\u8be5\u5206\u79bb\u819c\u8fd8\u53ef\u4ee5\u9ad8\u9009\u62e9\u6027\u5206\u79bb\u86cb\u767d\u8d28\u548c\u624b\u6027\u5bf9\u6620\u4f53\u3002TIPS-HoP\u7684\u7b56\u7565\u4e0d\u4ec5\u9002\u7528\u4e8eMOF\u57faPE\u6750\u6599\uff0c\u540c\u6837\u9002\u7528\u4e8e\u6cb8\u77f3\u3001COF\u548c\u5176\u5b83\u591a\u5b54\u7c89\u672b\u6750\u6599\u7684\u9ad8\u542b\u91cf\u5438\u9644\u819c\u7684\u5236\u5907\u548c\u529f\u80fd\u6027\u3002\u8be5\u5de5\u4f5c\u4e3a\u5927\u89c4\u6a21\u5377\u5f0fMOF\u819c\u5438\u9644\u5242\u7684\u751f\u4ea7\u548c\u73b0\u6709\u5de5\u4e1a\u8fc7\u7a0b\u7684\u6539\u9020\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5149\u660e\u7684\u524d\u666f\u3002<\/p>\n

\u56fe2. MOF\u57faPE\u819c\u7684TIPS-HoP\u5236\u5907\u65b9\u6cd5\u53ca\u5176\u5206\u79bb\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

3. \u5408\u7406\u4f18\u5316\u542b\u9506\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u819c\u7528\u4e8e\u6c22\u6c14\u7eaf\u5316<\/b><\/strong>[<\/b><\/sup><\/strong>3<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u5341\u5e74\u4e2d\uff0c\u652f\u6301\u6c22\u4f5c\u4e3a\u672a\u6765\u6e05\u6d01\u80fd\u6e90\u7684\u547c\u58f0\u8d8a\u6765\u8d8a\u9ad8\u3002\u4ece\u6df7\u5408\u6c14\u4f53\u4e2d(\u4f8b\u5982\uff0cCO2<\/sub>\u3001N2<\/sub>\u3001CH4<\/sub>\u548cH2<\/sub>O)\u7eaf\u5316\u662f\u6c22\u71c3\u6599\u7535\u6c60\u7b49\u5b9e\u9645\u5e94\u7528\u7684\u5fc5\u8981\u6761\u4ef6\u3002\u4f9d\u636e\u5c3a\u5bf8\u9009\u62e9\u7b5b\u5206\u6548\u5e94\uff0c\u8c03\u6574MOFs\u7684\u5b54\u5f84\u548c\u5f62\u72b6\u662f\u63d0\u9ad8MOFs\u819c\u6750\u6599\u9009\u62e9\u6027\u7684\u4e00\u79cd\u5b9e\u7528\u65b9\u6cd5\u3002\u65e5\u672c\u4eac\u90fd\u5927\u5b66Easan Sivaniah\u56e2\u961f\u9009\u7528\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\u9ad8\u7684\u542bZr\u7684MOF\u6750\u6599UiO-66\u4f5c\u4e3a\u6a21\u677f\uff0c\u5728\u6c27\u5316\u94dd\u57fa\u5e95\u4e0a\u5236\u5907\u4e86\u591a\u6676\u819c\uff0c\u5176\u5728\u5c0f\u4e8e350 \u00b0C\u65f6\u662f\u7a33\u5b9a\u7684\u3002\u8be5\u56e2\u961f\u7cfb\u7edf\u7684\u7814\u7a76\u4e86\u6709\u673a\u914d\u4f53\u7684\u4f53\u79ef\u6548\u5e94\u548c\u5b98\u80fd\u56e2\u53d8\u5316\u5bf9\u6c22\u6c14\u6e17\u900f\u7387\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5f15\u5165\u4f53\u79ef\u8f83\u5927\u7684\u6709\u673a\u914d\u4f53\uff0c\u5373H2<\/sub>NDC\u548cH2<\/sub>ADC\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u6c22\u6c14\u7684\u9009\u62e9\u6027\u3002\u5206\u5b50\u6a21\u62df\u7ed3\u679c\u8868\u660e\uff0c\u589e\u52a0\u7684\u82ef\u73af\u4f7f\u8fd9\u4e9bMOFs\u7684\u5b54\u5b54\u5f84\u7f29\u5c0f\uff0c\u5bfc\u81f4\u8f83\u5927\u5c3a\u5bf8\u7684\u6c14\u4f53\u5206\u5b50\u7684\u901a\u8fc7\u6027\u964d\u4f4e\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u8fde\u63a5\u914d\u4f53\u82ef\u73af\u4e0a\u6807\u8bb0\u7684\u6c28\u57fa\u548c\u6eb4\u5bf9H2<\/sub>\u7684\u5206\u79bb\u6027\u80fd\u5f71\u54cd\u4e0d\u5927\u3002\u8be5\u7814\u7a76\u6d89\u53ca\u7684\u5206\u79bb\u819c\u5236\u5907\u65b9\u6cd5\u53ca\u5176\u5bf9\u6709\u673a\u8fde\u914d\u4f53\u7684\u7cfb\u7edf\u6027\u7814\u7a76\u4e3aZr-MOFs\u57fa\u819c\u6750\u6599\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n

\u56fe3. \u900f\u8fc7\u7387\u4e0e\u5206\u5b50\u76f4\u5f84\u7684\u5173\u7cfb\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09UiO-66, (b) Naph, (c) Anth. (d) \u4e0e\u6587\u732e\u62a5\u9053\u7ed3\u679c\u5bf9\u6bd4\u3002<\/p>\n

4. \u94b4\u809f\u57fa\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u8584\u819c\u7528\u4e8e\u7535\u50ac\u5316\u6790\u6c22<\/b><\/strong>[<\/b><\/sup><\/strong>4<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u5206\u5b50\u6790\u6c22\u50ac\u5316\u5242(HECs)\u5177\u6709\u5408\u6210\u4e0a\u7684\u53ef\u8c03\u6027\uff0c\u901a\u5e38\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u6d3b\u6027\uff0c\u4f46\u5176\u7a33\u5b9a\u6027\u548c\u5728\u5747\u76f8\u4e2d\u4f7f\u7528\u7684\u5b9e\u9645\u9650\u5236\u7684\u963b\u788d\u3002\u5c06\u5176\u4f5c\u4e3a\u8fde\u63a5\u57fa\u5143\u5d4c\u5165\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u53ef\u4ee5\u5f25\u8865\u8fd9\u4e9b\u7f3a\u9677\u3002MOFs\u7684\u5ef6\u7eed\u6027\u4e09\u7ef4\u9aa8\u67b6\u7ed3\u6784\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684\u8d1f\u8f7d\u91cf\/\u51e0\u4f55\u8868\u9762\u79ef\u3002\u745e\u5178\u4e4c\u666e\u8428\u62c9\u5927\u5b66\u7684Sascha Ott\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u53ef\u63a7\u4e8c\u7ea7\u6784\u7b51\u57fa\u5143\u7684\u65b9\u6cd5\u5c06\u88ab\u5e7f\u6cdb\u7814\u7a76\u7684HEC\u50ac\u5316\u5242\u94b4\u809f\u5f15\u5165UU-100\u4e2d\uff0c\u5e76\u7528\u8fde\u7eed\u7535\u5b50\u884d\u5c04\uff08cRED\uff09\u9a8c\u8bc1\u5176\u5f97\u5230\u7684UU-100(Co)\u5177\u6709\u5e26\u6709\u692d\u5706\u72b6\u5b54\u7684\u77e9\u5f62\u901a\u9053\u3002UU-100(Co)\u8584\u819c\u53ef\u4ee5\u76f4\u63a5\u5728FTO\u7535\u6781\u4e0a\u7535\u5316\u5b66\u5408\u6210\uff0c\u65b9\u4fbf\u7814\u7a76\u56e2\u961f\u5bf9\u5176\u7535\u5316\u5b66\u548c\u7535\u8377\u4f20\u8f93\u7279\u6027\u8fdb\u884c\u7cfb\u7edf\u7814\u7a76\u3002\u5176\u8868\u89c2\u6269\u6563\u7cfb\u6570\u4e3a4.1(\u00b10.8)\u00d710\u2212<\/sup>8<\/sup>\u00a0cm2<\/sup>\u00a0s\u2212<\/sup>1<\/sup>\uff0c\u6bd4\u76f8\u5173\u7684\u535f\u5549\u57faMOF\u8584\u819c\u7684\u9ad8\u51e0\u4e2a\u6570\u91cf\u7ea7\u3002\u5c06\u94b4\u809f\u5f15\u5165MOF\u4e2d\u6781\u5927\u7684\u63d0\u9ad8\u4e86\u5176\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002UU-100(Co)\u751f\u957f\u5728\u73bb\u78b3\u7535\u6781\u8868\u9762\uff0c\u57281.7 mA cm-2<\/sup>\u7684\u6052\u5b9a\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5728pH = 4\u7684\u6c34\u4e2d\u53ef\u6301\u7eed\u5de5\u4f5c\u81f3\u5c1118\u5c0f\u65f6\u3002\u8be5\u5de5\u4f5c\u9a8c\u8bc1\u4e86\u7ed3\u6784\u8106\u5f31\u7684\u5206\u5b50\u50ac\u5316\u5242\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165MOF\u9aa8\u67b6\u4e2d\u4e0d\u4ec5\u589e\u5f3a\u5176\u5728\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\uff0c\u5e76\u4e14TON\u503c\u662f\u5176\u5b83\u7c7b\u4f3c\u4f53\u7cfb\u768450~200\u500d\uff0c\u8fd9\u5f97\u4ee5\u4e0eMOF\u9aa8\u67b6\u7ed3\u6784\u7684\u7a33\u5b9a\u5b54\u901a\u9053\u548c\u9650\u57df\u6548\u5e94\u3002\u7814\u7a76\u56e2\u961f\u9884\u6d4b\u8fd9\u4e9b\u8fdb\u5c55\u5c06\u8fdb\u4e00\u6b65\u7f29\u5c0f\u5206\u5b50\u50ac\u5316\u548c\u6750\u6599\u50ac\u5316\u4e4b\u95f4\u7684\u5dee\u8ddd\u3002<\/p>\n

\u56fe4.<\/p>\n

\"\"<\/p>\n

\uff08a\uff09MOF UU-100(Co)\u7ed3\u6784\u793a\u610f\u56fe\u3002\uff08b\uff09\u7c89\u672bXRD\u3002\uff08c\uff09\u6301\u7eed\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

5. \u5206\u522b\u91cf\u5316\u8302\u91d1\u5c5e\u63ba\u6742\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u8584\u819c\u7684\u7535\u5b50\u548c\u79bb\u5b50\u6269\u6563<\/b><\/strong>[<\/b><\/sup><\/strong>5<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u5728\u5bfc\u7535\u57fa\u5e95\u4e0a\u5236\u5907MOF\u8584\u819c\u4e0d\u4ec5\u6709\u5229\u4e8e\u5b83\u4eec\u7684\u7535\u5316\u5b66\u8868\u5f81\uff0c\u800c\u4e14\u4fc3\u8fdb\u4e86\u5bfc\u7535MOFs\u819c\u6750\u6599\u7684\u5e94\u7528\u3002\u7136\u800c\uff0c\u591a\u79cd\u5bfc\u7535MOFs\u6750\u6599\u88ab\u5f00\u53d1\uff0c\u5176\u4e2d\u7684\u7535\u5b50\u4f20\u9012\u673a\u7406\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\u3002\u57fa\u4e8e\u6c27\u5316\u8fd8\u539f\u8df3\u8dc3\u673a\u7406\uff0c\u7535\u5316\u5b66\u7535\u8377\u8f6c\u79fb\u4f9d\u8d56\u4e8e\u7535\u5b50\u6269\u6563\u901f\u7387(De<\/sub>)\u548c\u79bb\u5b50\u6269\u6563\u901f\u7387(Di<\/sub>)\u3002De<\/sub>\u4e0e\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\u7684\u540c\u8d28\u81ea\u4ea4\u6362\u76f8\u5173\uff0c\u800cDi<\/sub>\u4f9d\u8d56\u4e8e\u79bb\u5b50\u5c3a\u5bf8\u3001MOF\u5b54\u5f84\u548c\u79bb\u5b50\u914d\u5bf9\u80fd\u529b\u3002\u7406\u89e3\u5b83\u4eec\u7684\u76f8\u5bf9\u8d21\u732e\u5bf9\u4e8e\u5efa\u7acb\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u81f3\u5173\u91cd\u8981\uff0c\u65b9\u4fbf\u8bbe\u8ba1\u5bfc\u7535MOFs\u6750\u6599\u3002\u7f8e\u56fd\u5f17\u5409\u5c3c\u4e9a\u7406\u5de5\u5927\u5b66Amanda J. Morris\u56e2\u961f\u5c06\u56fa\u4f53\u4f0f\u5b89\u6cd5\u7406\u8bba\u6a21\u578b\u5e94\u7528\u5230MOF\u57fa\u8584\u819c\u6750\u6599\u4e2d\uff0c\u901a\u8fc7\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u542b\u6709\u8302\u91d1\u5c5e\u63ba\u6742\u7684M-NU-1000\u8584\u819c\uff0c\u5728PF6<\/sub>1-<\/sup>\u548cTFAB1-<\/sup>\u7535\u89e3\u8d28\u4e2d\u8fdb\u884c\u8ba1\u65f6\u5b89\u57f9\u5206\u6790\u6d4b\u8bd5\uff0c\u4e3a\u9610\u660e\u63ba\u6742\u8302\u91d1\u5c5e\u7684\u8584\u819c\u4e2d\u7535\u5b50\u548c\u79bb\u5b50\u6269\u6563\u7684\u76f8\u5bf9\u8d21\u732e\u63d0\u4f9b\u4e86\u4f9d\u636e\u3002\u8be5\u56e2\u961f\u5728\u5206\u6790\u8ba1\u65f6\u5b89\u57f9\u5b9e\u9a8c\u6570\u636e\u65f6\uff0c\u660e\u786e\u4e86\u7535\u5316\u5b66\u8f6c\u6362\u8fc7\u7a0b\u4e2d\u7684\u4e09\u4e2a\u5173\u952e\u72b6\u6001\uff0c\u5e76\u5206\u6790\u603b\u7ed3\u5bf9\u5e94\u72b6\u6001\u4e2d\u7684De\u548cDi\u7684\u8d21\u732e\u548c\u53d7\u6750\u6599\u548c\u7535\u89e3\u8d28\u7684\u5f71\u54cd\u3002\u8be5\u5de5\u4f5c\u5bf9\u7406\u89e3\u7535\u5316\u5b66\u5b9e\u9a8c\u4e2d\u7684\u7535\u5b50\u548c\u79bb\u5b50\u8fc1\u79fb\u610f\u4e49\u91cd\u5927\uff0c\u5e76\u53ef\u7528\u4e8e\u6307\u5bfc\u5176\u5b83\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684MOF\u6750\u6599\u3002<\/p>\n

\u56fe5.\u8ba1\u65f6\u5b89\u57f9\u66f2\u7ebf\u53cd\u6620\u4e86\u7535\u5316\u5b66\u8f6c\u6362\u7684\u4e09\u4e2a\u72b6\u6001\u3002<\/p>\n

\"\"<\/p>\n

6. \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u8584\u819c\u7528\u4e8eMg<\/b><\/strong>2+<\/b><\/sup><\/strong>\u9009\u62e9\u6027\u4f20\u8f93<\/b><\/strong>[<\/b><\/sup><\/strong>6<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

Mg\u7535\u6c60\u56e0\u5176\u6210\u672c\u4f4e\u3001\u9540\u5c42\u65e0\u6811\u679d\u72b6\u751f\u957f\uff0c\u8fd1\u5e74\u6765\u5f15\u8d77\u7814\u7a76\u8005\u7684\u5e7f\u6cdb\u9752\u7750\u3002\u9633\u6781\u548c\u9634\u6781\u7684\u5316\u5b66\u4e0d\u76f8\u5bb9\u662f\u963b\u788d\u5176\u53d1\u5c55\u7684\u4e00\u4e2a\u91cd\u8981\u6280\u672f\u5c4f\u969c\u3002\u5176\u4e2d\u4e00\u4e2a\u65b9\u6cd5\u662f\u8bbe\u8ba1\u5206\u79bb\u819c\u963b\u9694\u9634\u6781\u6db2\u548c\u9633\u6781\u6db2\u7684\u540c\u65f6\uff0c\u786e\u4fddMg2+<\/sup>\u7684\u9009\u62e9\u6027\u4f20\u8f93\uff0c\u8fd9\u6837\u53ef\u4ee5\u62d3\u5bbd\u9634\u9633\u6781\u7684\u5316\u5b66\u53cd\u5e94\u7684\u9009\u62e9\u8303\u56f4\u3002\u7f8e\u56fd\u6ce2\u58eb\u987f\u5b66\u9662Dunwei Wang\u7814\u7a76\u56e2\u961f\u91c7\u7528\u6e7f\u5316\u5b66\u6cd5\u5728\u9540\u91d1\u7684\u7845\u7247\u8868\u9762\u751f\u957f\u4e00\u5c42Mg-MOF-74\u8584\u819c\uff0c\u5176\u7535\u5bfc\u7387\u4e3a3.17\u00d710\u2212<\/sup>6<\/sup>\u00a0S cm\u2212<\/sup>1<\/sup>\uff0c\u5ba4\u6e29\u963b\u6297\u4e3a 6.4 \u03a9 cm2<\/sup>\uff0c\u6d3b\u5316\u80fd\u4e3a0.53 eV\u3002\u5229\u7528Mg-MOF-74\u9aa8\u67b6\u7ed3\u6784\u4e2d\u5f00\u653e\u7684\u91d1\u5c5e\u4f4d\u70b9\u4e0e\u591a\u9f7f\u9634\u79bb\u5b50\u548c\u6eb6\u5242\u5206\u5b50\u4e4b\u95f4\u7684\u914d\u4f4d\u4f5c\u7528\u4fc3\u8fdbMg2+<\/sup>\u7684\u4f20\u8f93\u3002\u5229\u7528\u540c\u6837\u7684\u6e7f\u5316\u5b66\u65b9\u6cd5\u5728\u9633\u6781\u6c27\u5316\u7684\u6c27\u5316\u94dd\u591a\u5b54\u57fa\u5e95\u4e0a\u751f\u957fMg-MOF-74\u53ef\u5f97\u5230\u72ec\u7acb\u7684\u819c\u6750\u6599\uff0c\u5b9e\u9a8c\u8bc1\u660e\u8be5\u819c\u6750\u6599\u5728 0.05 mA cm\u2212<\/sup>2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5faa\u73af100\u6b21\u4f9d\u7136\u4fdd\u6301\u8f83\u4f4e\u7684\u8fc7\u7535\u538b\uff08<0.3 V\uff09\uff0c\u540c\u65f6\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u963b\u6321\u78b3\u9178\u4e19\u70ef\u916f\u548c\u9634\u79bb\u5b50TFSI\u2212<\/sup>\u7684\u8de8\u819c\u4ea4\u6362\uff0c\u56e0\u6b64\u8be5\u6750\u6599\u53ef\u4ee5\u7528\u4f5cMg\u7535\u6c60\u9634\u9633\u7535\u89e3\u6db2\u5206\u79bb\u819c\u7684\u4e00\u79cd\u6f5c\u5728\u9009\u62e9\u3002\u4ee5\u5f80\u62a5\u9053\u7684\u538b\u7247\u6750\u6599\u5b58\u5728\u4e0d\u53ef\u907f\u514d\u7684\u7f1d\u9699\uff0c\u8be5\u5206\u79bb\u819c\u662f\u8fde\u7eed\u819c\uff0c\u65e0\u610f\u4e2d\u901a\u8fc7\u7f1d\u9699\u7684\u8f93\u8fd0\u53ef\u4ee5\u88ab\u6709\u6548\u7684\u907f\u514d\u3002\u540c\u65f6\u8be5\u5de5\u4f5c\u6709\u52a9\u4e8e\u7406\u89e3MOFs\u6750\u6599\u4f5c\u4e3a\u9009\u62e9\u6027\u79bb\u5b50\u5bfc\u4f53\u7684\u771f\u5b9e\u884c\u4e3a\u3002<\/p>\n

\u56fe 6. MOF\u819c\u53ef\u7528\u4e8e\u6df7\u5408\u7535\u6c60\u4e2d\u9009\u62e9\u6027\u8fd0\u8f93Mg2+<\/sup>\u7684\u793a\u610f\u56fe\uff0cMg\u91d1\u5c5e\u4f5c\u4e3a\u9633\u6781\uff0c\u50a8Mg\u6750\u6599\u4f5c\u4e3a\u9634\u6781\uff0c\u4e0d\u76f8\u5bb9\u7684\u7535\u89e3\u6db2\u88ab\u5206\u79bb\u819c\u9694\u5f00\u3002<\/p>\n

\"\"<\/p>\n

\u5c0f\u7ed3\uff1a<\/b><\/strong><\/p>\n

\u819c\u5668\u4ef6\u6216\u819c\u5206\u79bb\u6280\u672f\u5177\u6709\u5236\u5907\u548c\u64cd\u4f5c\u7b80\u5355\uff0c\u8282\u80fd\u51cf\u6392\u7684\u7279\u70b9\uff0c\u800cMOFs\u57fa\u591a\u5b54\u819c\u6750\u6599\u7531\u4e8e\u5176\u72ec\u7279\u7684\u5b54\u9053\u7ed3\u6784\u548c\u529f\u80fd\u591a\u6837\u6027\u5df2\u7ecf\u6210\u4e3a\u6700\u53d7\u6b22\u8fce\u7684\u4e0b\u4e00\u4ee3\u5206\u79bb\u819c\u4e4b\u4e00\uff0c\u5e94\u7528\u4e8e\u5404\u79cd\u73af\u5883\u548c\u80fd\u6e90\u9886\u57df\u3002\u5c3d\u7ba1\u65e0\u7f3a\u9677\u8fde\u7eedMOF\u819c\/\u6df7\u57fa\u819c\u7684\u5408\u6210\u548c\u5e94\u7528\u5df2\u7ecf\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u5927\u89c4\u6a21\u5730\u5236\u5907\u673a\u68b0\u6027\u80fd\u826f\u597d\u7684\u819c\u6750\u6599\u4f9d\u7136\u5177\u6709\u6311\u6218\uff0c\u8fd9\u4e5f\u4e3a\u672a\u6765\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u673a\u9047\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

(1) Gu, J.; Fan, H.; Li, C.; Caro, J.; Meng, H. Robust Superhydrophobic\/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil-Water Separation. Angew. Chem. Int. Ed. <\/i><\/em>2019,<\/b><\/strong>\u00a058<\/i><\/em>, 5297.<\/p>\n

(2) Wang, H.; Zhao, S.; Liu, Y.; Yao, R.; Wang, X.; Cao, Y.; Ma, D.; Zou, M.; Cao, A.; Feng, X.et al. Membrane Adsorbers with Ultrahigh Metal-Organic Framework Loading for High Flux Separations. Nat. Commun. <\/i><\/em>2019,<\/b><\/strong>\u00a010<\/i><\/em>, 4204.<\/p>\n

(3) Ghalei, B.; Wakimoto, K.; Wu, C. Y.; Isfahani, P. A.; Yamamoto, T.; Sakurai, K.; Higuchi, M.; Chang, B. K.; Kitagawa, S.; Sivaniah, E. Rational Tuning of Zirconium Metal-Organic Framework Membranes for Hydrogen Purification. Angew. Chem. Int. Ed. <\/i><\/em>2019<\/b><\/strong>, DOI:10.1002\/anie.201911359.<\/p>\n

(4) Roy, S.; Huang, Z.; Bhunia, A.; Castner, A.; Gupta, A. K.; Zou, X.; Ott, S. Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film. J. Am. Chem. Soc. <\/i><\/em>2019,<\/b><\/strong>\u00a0141<\/i><\/em>, 15942.<\/p>\n

(5) Celis-Salazar, P. J.; Cai, M.; Cucinell, C. A.; Ahrenholtz, S. R.; Epley, C. C.; Usov, P. M.; Morris, A. J. Independent Quantification of Electron and Ion Diffusion in Metallocene-Doped Metal-Organic Frameworks Thin Films. J. Am. Chem. Soc. <\/i><\/em>2019,<\/b><\/strong>\u00a0141<\/i><\/em>, 11947.<\/p>\n

(6) Luo, J.; Li, Y.; Zhang, H.; Wang, A.; Lo, W. S.; Dong, Q.; Wong, N.; Povinelli, C.; Shao, Y.; Chereddy, S.et al. A Metal-Organic Framework Thin Film for Selective Mg2+<\/sup>\u00a0Transport. Angew. Chem. Int. Ed. <\/i><\/em>2019,<\/b><\/strong>\u00a058<\/i><\/em>, 15313.<\/p>\n

\u672c\u6587\u7531Netlep<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u7c07\u4e0e\u6709\u673a\u914d\u4f53\u901a\u8fc7\u914d\u4f4d\u952e\u94fe\u63a5\u800c\u5f62\u6210\u5468\u671f\u6027\u591a\u5b54\u7f51\u7edc\uff0c\u5176\u5177\u6709\u9ad8\u7684\u5b54\u9699\u7387\u548c\u529f\u80fd\u53ef\u8bbe\u8ba1\u6027\u4f7f\u5176\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u9886\u57df\u3002\u7136\u800c\uff0c\u5408\u6210…<\/p>\n","protected":false},"author":10213,"featured_media":188126,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-188125","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/188125"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=188125"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/188125\/revisions"}],"predecessor-version":[{"id":188158,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/188125\/revisions\/188158"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/188126"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=188125"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=188125"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=188125"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}