{"id":188378,"date":"2019-10-29T06:30:23","date_gmt":"2019-10-28T22:30:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=188378"},"modified":"2019-10-28T15:23:40","modified_gmt":"2019-10-28T07:23:40","slug":"%e3%80%90%e9%80%9a%e8%ae%af%e4%bd%9c%e8%80%85%e4%b8%ba%e5%9b%bd%e5%a4%96%e6%9c%aa%e6%a0%a1%e7%a8%bf%e3%80%91adv-funct-mater-%ef%bc%9a%e4%b8%80%e8%88%ac%e6%ba%b6%e5%89%82%e7%83%ad%e5%90%88%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=188378","title":{"rendered":"Adv. Funct. Mater.\uff1a\u4e00\u822c\u6eb6\u5242\u70ed\u5408\u6210\u6cd5\u5236\u5907\u5168\u56fa\u6eb6\u8303\u56f4\u53cc\u91d1\u5c5e\u548c\u9ad8\u71b5\u5408\u91d1\u7eb3\u7c73\u50ac\u5316\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u53cc\u91d1\u5c5e\u7eb3\u7c73\u5408\u91d1\u51ed\u501f\u72ec\u7279\u7684\u7ed3\u6784\u548c\u7535\u5b66\u6027\u80fd\uff0c\u5e76\u7ed3\u5408\u7ec4\u6210\u91d1\u5c5e\u7ec4\u5143\u7684\u4f18\u52bf\u6027\u8d28\uff0c\u5728\u591a\u79cd\u53cd\u5e94\u548c\u8fc7\u7a0b\u4e2d\u90fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u591a\u79cd\u65b9\u6cd5\u53ef\u7528\u4e8e\u5408\u6210\u53cc\u91d1\u5c5e\u7eb3\u7c73\u5408\u91d1\uff0c\u4f46\u662f\u90fd\u76f8\u5bf9\u590d\u6742\uff0c\u4e14\u7f3a\u4e4f\u53ef\u6d4b\u91cf\u6027\uff0c\u4e14\u5bf9\u5316\u5b66\u548c\u7269\u7406\u6761\u4ef6\u90fd\u8981\u6c42\u4e25\u82db\u3002\u7eb3\u7c73\u5408\u91d1\u5408\u6210\u6280\u672f\u6781\u5bcc\u610f\u4e49\u7684\u8fdb\u5c55\u662f\u53ef\u4ee5\u4fdd\u8bc1\u81f3\u5c11\u4e94\u79cd\u4e0d\u540c\u7684\u91d1\u5c5e\u540c\u65f6\u5b58\u5728\uff0c\u8fd9\u4e9b\u6750\u6599\u53ef\u7528\u4e8e\u5236\u5907\u9ad8\u71b5\u7eb3\u7c73\u5408\u91d1\u3002\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u5242\u901a\u5e38\u4ee5\u8d35\u91d1\u5c5e\u4f5c\u4e3a\u4e3b\u8981\u6210\u5206\uff0c\u91cd\u8981\u7684\u5e38\u89c4\u5408\u6210\u6d41\u7a0b\u53d6\u51b3\u4e8e\u7eaf\u8d35\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u548c\u7eb3\u7c73\u5408\u91d1\u3002\u50ac\u5316\u6027\u80fd\u7531\u7eb3\u7c73\u9897\u7c92\u7684\u53c2\u91cf\u51b3\u5b9a\uff0c\u5982\u7ed3\u6676\u5ea6\u3001\u9897\u7c92\u5927\u5c0f\uff08\u8868\u9762\u79ef\uff09\u3001\u5f62\u8c8c\u3001\u6676\u4f53\u7ed3\u6784\u548c\u5316\u5b66\u7ec4\u6210\uff08\u5408\u91d1\u5316\u6216\u63ba\u6742\uff09\u3002\u6700\u5927\u50ac\u5316\u6d3b\u6027\u901a\u5e38\u51fa\u73b0\u5728\u7279\u5b9a\u7684\u6676\u9762\u4e0a\uff0c\u56e0\u6b64\u65e2\u8981\u63a7\u5236\u5c3a\u5bf8\uff0c\u4e5f\u8981\u5173\u6ce8\u7eb3\u7c73\u5408\u91d1\u7684\u5f62\u8c8c\u3002\u53ef\u4ee5\u5bf9\u6676\u4f53\u7ed3\u6784\u8c03\u5236\uff0c\u4ea7\u751f\u65b0\u7684\u4e9a\u7a33\u7eb3\u7c73\u6676\u76f8\uff0c\u4ece\u800c\u63a7\u5236\u5f62\u8c8c\u3002\u5bf9\u7535\u5b50\u7ed3\u6784\u7684\u7cbe\u7ec6\u8c03\u63a7\uff0c\u53ef\u901a\u8fc7\u8d35\u91d1\u5c5e\u5728\u56fa\u6eb6\u4f53\u4e2d\u5408\u91d1\u5316\u5b9e\u73b0\uff0c\u4f46\u4f1a\u53d7\u5230\u56fa\u6eb6\u5ea6\u95f4\u9699\u7684\u9650\u5236\u3002\u5bf9\u4e8e\u7eb3\u7c73\u5c3a\u5ea6\u5408\u91d1\uff0c\u6bd4\u8868\u9762\u79ef\u589e\u52a0\u4f7f\u6676\u4f53\u7ed3\u6784\u66f4\u52a0\u7a33\u5b9a\uff0c\u53ef\u4ee5\u5728\u5757\u4f53\u4e2d\u6781\u96be\u5408\u6210\u7684\u6210\u5206\u8303\u56f4\u5b9e\u73b0\u56fa\u6eb6\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u65b9\u6cd5\u4ec5\u9002\u7528\u4e8e\u548c\u5757\u4f53\u6750\u6599\u6676\u4f53\u7ed3\u6784\u76f8\u540c\u7684\u91d1\u5c5e\uff0c\u5426\u5219\u4f1a\u53d1\u751f\u76f8\u5206\u79bb\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e39\u9ea6\u5965\u80e1\u65af\u5927\u5b66<\/strong>\u7684Bo Brummerstedt Iversen<\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Advanced Functional Materials<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cGeneral Solvothermal Synthesis Method for Complete Solubility Range Bimetallic and High<\/strong>\u2010Entropy Alloy Nanocatalysts<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u5de5\u4f5c\u62a5\u9053\u4e86\u4e00\u4e2a\u5e38\u89c4\u7684\u4f4e\u6e29\u6eb6\u5242\u70ed\u5408\u6210\u65b9\u6cd5\uff0c\u6e29\u5ea6\u4e3a200\u2103\u6761\u4ef6\u4e0b\u5728\u9ad8\u538b\u91dc\u4e2d\u8fdb\u884c4-24h\u7684\u6301\u7eed\u53cd\u5e94\uff0c\u5c06\u4e00\u7cfb\u5217\u8d35\u91d1\u5c5e\u4e59\u9170\u4e19\u916e\u524d\u9a71\u4f53\u6eb6\u89e3\u5230\u4e59\u9187-\u4e19\u916e\u6df7\u5408\u7269\u4e2d\uff0c\u5bf9\u8fd8\u539f\u52a8\u7406\u5b66\u8fdb\u884c\u7cbe\u786e\u63a7\u5236\u3002\u8be5\u65b9\u6cd5\u662f\u8d35\u91d1\u5c5e\u548c\u4e0d\u540c\u7684\u5757\u4f53\u7ed3\u6784\u5b9e\u73b0\u5408\u91d1\u5316\uff0c\u540c\u65f6\u5728\u5168\u6210\u5206\u8303\u56f4\u63a7\u5236\u76f8\u7ec4\u6210\uff0c\u5e76\u6269\u5c55\u5230\u4e94\u5143\u9ad8\u71b5\u5408\u91d1\u4f53\u7cfb\u3002\u73b0\u6709\u7ed3\u679c\u8bf4\u660e\u8d35\u91d1\u5c5e\u50ac\u5316\u6750\u6599\u7684\u6210\u5206\u548c\u6676\u4f53\u7ed3\u6784\u53ef\u5b9e\u73b0\u7cbe\u786e\u8c03\u63a7\uff0c\u4e3a\u4e00\u7cfb\u5217\u6709\u6f5c\u5728\u4f18\u5f02\u6027\u80fd\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u9047\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1\uff1a\u4e8c\u5143\u7eb3\u7c73\u5408\u91d1\u4f53\u7cfb\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u6570\u636e\u3002<\/p>\n

\"\"(a) Pdx<\/sub>Ru1-x<\/sub><\/p>\n

(b) Ptx<\/sub>Ru1-x<\/sub><\/p>\n

(c) Irx<\/sub>Ru1-x<\/sub><\/p>\n

(d) Rhx<\/sub>Ru1-x<\/sub><\/p>\n

(e) Irx<\/sub>Pt1-x<\/sub><\/p>\n

(f) Rh1-x<\/sub>Ptx<\/sub><\/p>\n

\u56fe2\uff1a\u901a\u8fc7\u4e0d\u540c\u7eb3\u7c73\u5408\u91d1\u4f53\u7cfb\u7684\u7ed3\u6784\u7cbe\u4fee\u83b7\u5f97\u7684\u4e8c\u5143\u7eb3\u7c73\u5408\u91d1\u4f53\u7cfb\u5355\u80de\u53c2\u6570\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\uff1aPdx<\/sub>Ru1-x<\/sub>\u4f53\u7cfb\u7684\u5143\u7d20\u8868\u5f81\u3002<\/p>\n

\"\"(a) Pd0.5<\/sub>Ru0.5<\/sub>\u7684STEM\u56fe\u50cf\uff1b<\/p>\n

(b-d) Pd0.5<\/sub>Ru0.5<\/sub>\u7684STEM-EDS\u56fe\u50cf\uff1b<\/p>\n

(e) Pd0.5<\/sub>Ru0.5<\/sub>\u7684\u8fd1\u6444STEM\u56fe\u50cf\uff0c\u7eff\u7ebf\u8868\u793aEDS\u626b\u63cf\u65b9\u5411\uff1b<\/p>\n

(f) Pd0.5<\/sub>Ru0.5<\/sub>\u5355\u4e2a\u9897\u7c92\u7684EDS\u7ebf\u626b\u63cf\u7ed3\u679c\uff1b<\/p>\n

(g) Pdx<\/sub>Ru1-x<\/sub>\u4f53\u7cfb\u5168\u90e8\u6837\u54c1\u57282-4keV\u8303\u56f4\u5185\u7684EDS\u8c31\uff1b<\/p>\n

(h) EDS\u6d4b\u5b9a\u7684\u91d1\u5c5e\u542b\u91cf\u4e0ePdx<\/sub>Ru1-x<\/sub>\u4f53\u7cfb\u540d\u4e49\u91d1\u5c5e\u542b\u91cf\u7684\u6bd4\u503c\u3002<\/p>\n

\u56fe4\uff1a\u4e8c\u5143\u7eb3\u7c73\u5408\u91d1\u6837\u54c1\u7684\u5143\u7d20\u8868\u5f81\u3002<\/p>\n

\"\"(a) Rh0.5<\/sub>Pt0.5<\/sub>\u7684STEM\u56fe\u50cf\uff0c\u767d\u8272\u7bad\u5934\u8868\u793a\u626b\u63cf\u65b9\u5411\uff1b<\/p>\n

(b-d) Rh0.5<\/sub>Pt0.5<\/sub>\u7684STEM-EDS\u56fe\u50cf\uff1b<\/p>\n

(e) \u56fe(a)\u4e2d\u6807\u8bb0\u5904\u7ebf\u626b\u63cf\u7684EDS\u4fe1\u53f7\u5f3a\u5ea6\uff1b<\/p>\n

(f) \u5de6\u4fa7\u653e\u5927\u7684HRTEM\u56fe\u50cf\u662f\u5206\u6790\u5f97\u5230\u7684d\u7a7a\u95f4\u56fe\u793a\uff1b<\/p>\n

(g) Rh0.5<\/sub>Ru0.5<\/sub>\u7684STEM\u56fe\u50cf\uff0c\u767d\u8272\u7bad\u5934\u8868\u793a\u626b\u63cf\u65b9\u5411\uff1b<\/p>\n

(h-j) Rh0.5<\/sub>Ru0.5<\/sub>\u7684HRTEM\u56fe\u50cf;<\/p>\n

(k) \u56fe(g) \u4e2d\u6807\u8bb0\u5904\u7ebf\u626b\u63cf\u7684EDS\u4fe1\u53f7\u5f3a\u5ea6\uff1b<\/p>\n

(l)\u00a0 \u5de6\u4fa7\u653e\u5927\u7684HRTEM\u56fe\u50cf\u662f\u5206\u6790\u5f97\u5230\u7684d\u7a7a\u95f4\u56fe\u793a\u3002<\/p>\n

\u56fe5\uff1a\u4e2d\u71b5\u548c\u9ad8\u71b5\u7eb3\u7c73\u5408\u91d1\u6750\u6599\u7684\u8868\u5f81\u3002<\/p>\n

\"\"(a)\u9ad8\u71b5\u91d1\u5c5e\u7eb3\u7c73\u5408\u91d1\u7684\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u6570\u636e\uff1b<\/p>\n

(b)Pt0.33<\/sub>Pd0.33<\/sub>Rh0.33<\/sub>\u7684STEM-EDS\u56fe\u50cf\uff1b<\/p>\n

(c)Pt0.33<\/sub>Rh0.33<\/sub>Ru0.33<\/sub>\u7684STEM-EDS\u56fe\u50cf\uff1b<\/p>\n

(d)Pt0.25<\/sub>Pd0.25<\/sub>Rh0.25<\/sub>Ru0.25<\/sub>\u7684STEM-EDS\u56fe\u50cf\uff1b<\/p>\n

(e)Pt0.20<\/sub>Pd0.20<\/sub>Ir0.20<\/sub>Rh0.20<\/sub>Ru0.20<\/sub>\u7684STEM-EDS\u56fe\u50cf\u3002<\/p>\n

\u56fe6\uff1a\u4e8c\u5143\u7eb3\u7c73\u5408\u91d1\u7684\u6676\u7c92\u5c3a\u5bf8\u6570\u636e\u3002<\/p>\n

\"\"(a) \u7cbe\u4fee\u5f97\u5230\u7684\u4e0d\u540c\u5408\u91d1\u4f53\u7cfb\u7ed3\u6784\u5e73\u5747\u6676\u7c92\u5927\u5c0f\uff0cPdx<\/sub>Ru1-x<\/sub>\u4f53\u7cfb\u7684\u4f53\u79ef\u52a0\u6743\u7c92\u5b50\u5927\u5c0f\uff1b<\/p>\n

(b) \u672c\u5de5\u4f5c\u53ca\u5176\u4ed6\u5de5\u4f5c\u4e2d\u7eaf\u5143\u7d20\u7684\u5e73\u5747\u6676\u7c92\u4ee3\u9500\u4e0e\u7194\u5316\u7113\u7684\u6bd4\u503c\uff1b<\/p>\n

(c) Pdx<\/sub>Ru1-x<\/sub>, Ptx<\/sub>Ru1-x<\/sub>, Rhx<\/sub>Ru1-x<\/sub>\u548cRh1-x<\/sub>Ptx<\/sub>\u4f53\u7cfb\u5408\u91d1\u6837\u54c1\u7684\u5e73\u5747\u6676\u7c92\u5927\u5c0f\u4e0e\u9884\u4f30\u7194\u5316\u7113\u7684\u6bd4\u503c\uff1b<\/p>\n

(d) Irx<\/sub>Ru1-x<\/sub>\u548cIr1-x<\/sub>Ptx<\/sub>\u4f53\u7cfb\u5408\u91d1\u6837\u54c1\u7684\u5e73\u5747\u6676\u7c92\u5927\u5c0f\u4e0e\u9884\u4f30\u7194\u5316\u7113\u7684\u6bd4\u503c\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u901a\u8fc7\u8c03\u63a7\u6eb6\u5242\u6027\u8d28\u548c\u91d1\u5c5e\u524d\u9a71\u4f53\u7c7b\u578b\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u5355\u901a\u7528\u7684\u6eb6\u5242\u70ed\u5408\u6210\u65b9\u6cd5\uff0c\u5bf9\u516d\u79cd\u4e0d\u540c\u7684\u4e8c\u5143\u8d35\u91d1\u5c5e\u4f53\u7cfb\u5b9e\u73b0\u5168\u5316\u5b66\u8ba1\u91cf\u8303\u56f4\u7684\u76f8\u63a7\u5236\u548c\u5747\u5300\u5408\u91d1\u5316\u3002\u6b64\u5916\uff0c\u8be5\u65b9\u6cd5\u53ef\u4ee5\u6269\u5c55\u5230\u5305\u542b\u56db\u6216\u4e94\u79cd\u4e0d\u540c\u91d1\u5c5e\u5143\u7d20\u7684\u4e2d\u71b5\u548c\u9ad8\u71b5\u7eb3\u7c73\u5408\u91d1\u4f53\u7cfb\uff0c\u8fd9\u5728\u4ee5\u5f80\u88ab\u8ba4\u4e3a\u662f\u65e0\u6cd5\u7528\u57fa\u4e8e\u6eb6\u89e3\u7684\u5316\u5b66\u5408\u6210\u65b9\u6cd5\u5b9e\u73b0\u7684\u3002\u5408\u6210\u7684\u7eb3\u7c73\u5408\u91d1\u7684\u5e73\u5747\u6676\u7c92\u5c3a\u5bf8\u53d6\u51b3\u4e8e\u91d1\u5c5e\u5143\u7d20\u7ec4\u5143\u7684\u7194\u5316\u7113\u6216\u7194\u70b9\uff0c\u4ece\u800c\u53ef\u4ee5\u901a\u8fc7\u4e0d\u540c\u7684\u5316\u5b66\u8ba1\u91cf\u6bd4\u6765\u9884\u6d4b\u6676\u7c92\u5927\u5c0f\u3002\u8be5\u65b9\u6cd5\u53ef\u7528\u4e8e\u4e00\u7cfb\u5217\u542b\u6709\u8d35\u91d1\u5c5e\u7684\u65b0\u578b\u7eb3\u7c73\u5408\u91d1\u7684\u5236\u5907\uff0c\u6709\u52a9\u4e8e\u5f00\u53d1\u8fd9\u7c7b\u6750\u6599\u5728\u50ac\u5316\u9886\u57df\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aGeneral Solvothermal Synthesis Method for Complete Solubility Range Bimetallic and High\u2010Entropy Alloy Nanocatalysts<\/a>\uff08Adv. Funct. Mater.\uff0c2019\uff0cDOI\uff1a10.1002\/adfm.201905933\uff09<\/p>\n

 <\/p>\n

\u672c\u6587\u7531Isobel\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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