{"id":188587,"date":"2019-11-04T06:30:21","date_gmt":"2019-11-03T22:30:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=188587"},"modified":"2019-11-03T19:59:43","modified_gmt":"2019-11-03T11:59:43","slug":"%e3%80%90%e5%ae%a1%e7%a8%bf%e5%b7%b2%e5%9b%9e%e5%a4%8d%e3%80%91%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e7%8e%8b%e7%85%a7%e5%a5%8e%e6%95%99%e6%8e%88adv-ener-mater-%e5%8d%a4%e5%8c%96%e9%94%a1%e9%92%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=188587","title":{"rendered":"\u82cf\u5dde\u5927\u5b66\u738b\u7167\u594e\u6559\u6388Adv. Ener. Mater.:\u5364\u5316\u9521\u9499\u949b\u77ff\u7684\u7814\u7a76\u8fdb\u5c55\u4e0e\u6311\u6218"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u738b\u7167\u594e\u6559\u6388<\/strong>\u5728\u8fd9\u7bc7\u7814\u7a76\u8fdb\u5c55\u7efc\u8ff0\u4e2d\uff0c\u7cfb\u7edf\u5730\u603b\u7ed3\u4e86\u5364\u5316\u9499\u949b\u77ff\u6750\u6599\u548c\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u6587\u7ae0\u4ece\u6676\u4f53\u5b66\uff0c\u5236\u5907\uff0c\u5149\u7269\u7406\u6027\u8d28\uff0c\u5c3a\u5bf8\uff0c\u7535\u8377\u4f20\u8f93\u5c42\u548c\u6dfb\u52a0\u5242\u7684\u5f71\u54cd\u7b49\u65b9\u9762\u8fdb\u884c\u7814\u7a76\u3002\u8fd8\u8ba8\u8bba\u4e86\u901a\u8fc7\u7528Sn\u90e8\u5206\u6216\u5b8c\u5168\u53d6\u4ee3Pb\u6765\u51cf\u8f7bPb\u5364\u5316\u7269\u9499\u949b\u77ff\u4e2d\u6bd2\u6027\u7684\u53ef\u80fd\u6027\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8ba8\u8bba\u4e86\u9499\u949b\u77ff\u578b\u5364\u5316\u9521\u6750\u6599\u548c\u5668\u4ef6\u7684\u4f18\u7f3a\u70b9\uff0c\u5e76\u5bf9\u5b83\u4eec\u7684\u524d\u666f\u8fdb\u884c\u4e86\u5c55\u671b\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/strong>Tin Halide Perovskites: Progress and Challenges<\/strong>\u201d\u6700\u8fd1\u53d1\u8868\u5728<\/strong>Adv. Ener. Mater.<\/strong>\u4e0a<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

Figure 1.<\/strong>\u9521\u9499\u949b\u77ff\u7684\u6676\u4f53\u5b66\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

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Figure 2.<\/strong>\u70ed\u84b8\u53d1\u6cd5\u5236\u5907\u5668\u4ef6<\/strong><\/p>\n

\"\"<\/p>\n

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c\uff09\u57fa\u4e8eSn\u7684PSC\u7684\u5178\u578b\u8bbe\u5907\u67b6\u6784<\/p>\n

Figure 3.<\/strong>\u9521\u9499\u949b\u77ff\u7684\u5668\u4ef6\u8868\u5f81<\/strong>\"\"<\/strong><\/p>\n

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Figure 4.<\/strong>\u5168\u65e0\u673a\u5364\u5316\u9521\u9499\u949b\u77ff<\/strong><\/p>\n

\"\"<\/p>\n

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d\uff09\u4e0d\u540c\u751f\u957f\u6761\u4ef6\u4e0bCsI\u7aef\u63a5\u4e2dVCs<\/sub>\u548cVI<\/sub>\u7684\u7f3a\u9677\u5f62\u6210\u80fd\u7684\u8ba1\u7b97\u503c<\/p>\n

Figure 5.<\/strong>\u57fa\u4e8e\u9521\u6bd4\u7684MA3<\/sub>Sn1-x<\/sub>Pbx<\/sub>I3<\/sub>\u9499\u949b\u77ff\u8868\u5f81<\/p>\n

\"\"<\/p>\n

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Figure 6.<\/strong>\u6750\u6599\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

abc\uff09\u5177\u67093D\u6676\u683c\uff0c2D\/3D\u6676\u683c\uff0c2D\u6676\u683c\u7684Sn\u57fa\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

d\uff09(PEA)2<\/sub>Ge1-x<\/sub>SnI4<\/sub>\u9499\u949b\u77ff\u7cfb\u5217\u7684\u5e26\u9699\u503c\uff0c\u5176\u4e2dx=0\u30010.125\u30010.25\u30010.5<\/p>\n

e\uff09\u4ecei\uff09DMSO\uff0cii\uff09MAAc\u548ciii\uff09DMSO+MAAc\u4e2d\u7684\u524d\u4f53\u6eb6\u6db2\u6c89\u79ef\u7684\u4f4e\u7ef4Ruddlesden-Popper\uff08LDRP\uff09BA2<\/sub>MA3<\/sub>Sn4<\/sub>I13<\/sub>\u9499\u949b\u77ff\u8584\u819c\u7684SEM\u56fe\u50cf\u548c\u793a\u610f\u56fe<\/p>\n

Figure 7.<\/strong>\u5364\u5316\u9521<\/strong>PSC<\/strong>\u4e2d\u7684\u7535\u8377\u4f20\u8f93\u5c42<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u901a\u8fc7p\u578bPEG-PEDOT\uff1aPSS\u7f13\u51b2\u5c42\u5bf9PEDOT\uff1aPSS\u7a7a\u7a74\u4f20\u8f93\u5c42\u548cFASnI3<\/sub>\u5438\u6536\u5c42\u4e4b\u95f4\u7684\u80fd\u7ea7\u5bf9\u51c6\u8fdb\u884c\u8c03\u5236\u7684\u5668\u4ef6\u80fd\u7ea7\u56fe<\/p>\n

b\uff09\u901a\u8fc7n\u578bPCBM\u5f62\u6210C60\u7535\u5b50\u4f20\u8f93\u5c42\u548cFA0.5<\/sub>MA0.5<\/sub>Sn0.5<\/sub>Pb0.5<\/sub>I3<\/sub>\uff08FAMA\uff09\u5438\u6536\u5c42<\/p>\n

c\uff09\u6bd4\u8f83\u57fa\u4e8ePEDOT\uff1aPSS\u548cPCP-Na\u7a7a\u7a74\u63d0\u53d6\u5c42\u7684\u5668\u4ef6\u4e2d\u7535\u8377\u91cd\u7ec4\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

d\uff09\u4e0d\u5e26PCBM\u5c42\u548c\u5e26PCBM\u5c42\u7684\u7535\u8377\u63d0\u53d6\u548c\u91cd\u7ec4\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

Figure 8.<\/strong>\u9521\u5364\u5316\u7269\u9499\u949b\u77ff\u8584\u819c\u7684\u6dfb\u52a0\u5242<\/strong>\"\"<\/strong><\/p>\n

a\uff09\u65f6\u95f4\u4f9d\u8d56\u6027\u7684\u5916\u89c2\u53d8\u5316<\/p>\n

b\uff09\u542b\u9521\u7c89\u6dfb\u52a0\u5242\u7684DMSO\u4e2d\u7684FASnI3<\/sub>\u524d\u4f53\u6eb6\u6db2<\/p>\n

c\uff09\u4ece\u5de6\u5230\u53f3\u6bd4\u4f8b\u4e3a0\uff05\uff0c40\uff05\u548c80\uff05HEAI\u6dfb\u52a0\u5242\u7684\u9499\u949b\u77ff\u7ed3\u6784<\/p>\n

d\uff09\u7528100\uff05HEAI\u6dfb\u52a0\u5242\u83b7\u5f97\u7684\u70ed\u529b\u5b66\u4e0a\u4f18\u9009\u7684\u6676\u4f53\u7ed3\u6784<\/p>\n

e\uff09\u57fa\u4e8e\u9499\u949b\u77ff\u7684MASnI3<\/sub>\u5149\u4f0f\u5668\u4ef6\u7684J-V\u66f2\u7ebf<\/p>\n

f\uff09\u540c\u65f6\u6dfb\u52a0SnF2<\/sub>\u548c\u5421\u55ea\u53ef\u6539\u5584\u5438\u6536\u5c42\u7684\u5f62\u8c8c\u548cPV\u53c2\u6570<\/p>\n

Figure 9.<\/strong>\u751f\u7269\u6bd2\u6027\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5e7c\u866b\u4e2d\u6bd2\u540e\u7684\u5f62\u6001\u7f3a\u9677<\/p>\n

bd\uff09SnI2<\/sub>\u548cPbI2<\/sub>\u5904\u7406\u7684\u5e7c\u866b\u7684\u6807\u79f0\u6d53\u5ea6-\u5b58\u6d3b\u66f2\u7ebf\uff0c\u6d53\u5ea6\u7578\u5f62\u66f2\u7ebf<\/p>\n

c\uff09pH\u548c\u81f4\u6b7b\u7387\u968f\u6d53\u5ea6\u7684\u53d8\u5316<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7531\u4e8e\u9521\u7684\u79bb\u5b50\u534a\u5f84\u5408\u9002\uff0c\u5e76\u4e14\u5b58\u5728\u4ee5+2\u6001\u5b58\u5728\u7684\u53ef\u80fd\u6027\uff0c\u901a\u8fc7\u7528\u9521\u90e8\u5206\u6216\u5b8c\u5168\u66ff\u4ee3\u6709\u6bd2Pb\u7684\u5364\u5316\u9499\u949b\u77ff\u5df2\u88ab\u5e7f\u6cdb\u62a5\u9053\u3002\u6709\u8da3\u7684\u662f\uff0c\u5b8c\u5168\u66ff\u4ee3\u4f1a\u7f29\u5c0f\u5e26\u9699\uff0c\u800c\u90e8\u5206\u66ff\u4ee3\u4f1a\u51fa\u73b0\u5f02\u5e38\u73b0\u8c61\uff0c\u8fd9\u76f8\u5bf9\u4e8e\u7eafPb\u548cSn\u5364\u5316\u7269\u9499\u949b\u77ff\u5316\u5408\u7269\u800c\u8a00\uff0c\u5e26\u9699\u8fdb\u4e00\u6b65\u7f29\u5c0f\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u8fd9\u79cd\u5f02\u5e38\u884c\u4e3a\u7684\u4f18\u70b9\u5c1a\u672a\u5f97\u5230\u9002\u5f53\u5229\u7528\u3002\u5c3d\u7ba1\u5728\u63d0\u9ad8Sn\u57fa\u9499\u949b\u77ff\u4f53\u7cfb\u7684\u6027\u80fd\u65b9\u9762\u5df2\u53d6\u5f97\u4e86\u53ef\u559c\u7684\u8fdb\u5c55\uff0c\u4f46\u5176\u5149\u4f0f\uff08PV\uff09\u53c2\u6570\u4ecd\u7136\u660e\u663e\u4f4e\u4e8e\u57fa\u4e8ePb\u7684\u7c7b\u4f3c\u7269\u3002\u8fd9\u7bc7\u7efc\u8ff0\u603b\u7ed3\u4e86\u57fa\u4e8e\u9521\u7684\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u5236\u5907\uff0c\u5f62\u6001\u548c\u5149\u7269\u7406\u6027\u8d28\u65b9\u9762\u7684\u8fdb\u5c55\u548c\u6311\u6218\uff0c\u4ee5\u53ca\u8fd9\u4e9b\u56e0\u7d20\u5982\u4f55\u5f71\u54cd\u5176\u5149\u4f0f\u6027\u80fd\u3002\u5c3d\u7ba1\u53ef\u4ee5\u8ba4\u4e3aPb\u5364\u5316\u7269\u9499\u949b\u77ff\u4f53\u7cfb\u53ef\u80fd\u4ecd\u7136\u662f\u8584\u819c\u9499\u949b\u77ffPV\u9886\u57df\u4e2d\u6700\u53d7\u8ffd\u6367\u7684\u6280\u672f\uff0c\u4f46\u63d0\u9ad8Sn\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u7684\u6027\u80fd\u4ee5\u6539\u5584\u5668\u4ef6\u6027\u80fd\u4ecd\u6709\u5f88\u5927\u7684\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aTin Halide Perovskites: Progress and Challenges<\/a>. Adv.Ener. Mater.<\/em>, 2019<\/strong>, DOI: 10.1002\/aenm.201902584.<\/p>\n

\u7814\u7a76\u56e2\u961f\u7b80\u4ecb<\/strong><\/p>\n

\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u548c\u9499\u949b\u77ff\u53d1\u5149\u4e8c\u6781\u7ba1\u662f\u82cf\u5dde\u5927\u5b66\u5ed6\u826f\u751f\u6559\u6388\u3001\u738b\u7167\u594e\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u7814\u7a76\u65b9\u5411\u4e4b\u4e00\u3002\u8fd1\u51e0\u5e74\u6765\u8be5\u8bfe\u9898\u7ec4\u57fa\u4e8e\u4ee5\u5f80\u4ece\u4e8b\u6709\u673a\u5149\u7535\u5668\u4ef6\u548c\u6750\u6599\u7814\u7a76\u7684\u7ecf\u9a8c\uff0c\u56f4\u7ed5\u6709\u673a\/\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u754c\u9762\u3001\u9499\u949b\u77ff\u8584\u819c\u6676\u5316\u3001\u94c5\u7684\u6bd2\u6027\u7b49\u5173\u952e\u95ee\u9898\uff0c\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u7a7a\u7a74\u548c\u7535\u5b50\u4f20\u8f93\u6750\u6599\uff0c\u5728\u754c\u9762\u4fee\u9970\u7684\u57fa\u7840\u4e0a\uff0c\u53d1\u5c55\u4e86\u591a\u79cd\u9499\u949b\u77ff\u8584\u819c\u6676\u5316\u63a7\u5236\u7684\u65b0\u65b9\u6cd5\uff0c\u901a\u8fc7\u63ba\u6742\u975e\u94c5\u91d1\u5c5e\u5143\u7d20\u8c03\u63a7\u9499\u949b\u77ff\u8584\u819c\u7684\u6676\u5316\u53d6\u5e76\u5b9e\u73b0\u964d\u4f4e\u94c5\u4f7f\u7528\u91cf\u7b49\u591a\u91cd\u76ee\u7684\uff0c\u5e76\u5f00\u5c55\u4e86\u9499\u949b\u77ff\u6750\u6599\u5728\u5ba4\u5185\u5149\u4f0f\u5668\u4ef6\u65b9\u9762\u7684\u7814\u7a76\u3002\u5728\u9499\u949b\u77ff\u53d1\u5149\u4e8c\u6781\u7ba1\u65b9\u9762\uff0c\u5b9e\u73b0\u4e86\u5185\u90e8\u91cf\u5b50\u6548\u73872.6%\u7684\u6df1\u84dd\uff08465 nm\uff09\u9499\u949b\u77ffLED\u5668\u4ef6\u3002\u76f8\u5173\u8bba\u6587\u8bf7\u53c2\u8003\uff1a<\/p>\n

Joule<\/em><\/strong> 3, 1464 (2019);<\/p>\n

Adv. Mater.<\/em><\/strong>\u00a031, 1901519 (2019)<\/p>\n

Adv. Mater.<\/em><\/strong>\u00a031, 1904319 (2019) ;<\/p>\n

Adv. Mater. <\/em><\/strong>31, 1902222 (2019);<\/p>\n

    \n
  1. Am. Chem. Soc<\/u><\/em><\/strong>. 141, 13948 (2019)<\/li>\n
  2. Am. Chem. Soc<\/u><\/em><\/strong>. DOI:\u00a010.1021\/jacs.9b06796 (2019)<\/li>\n<\/ol>\n

    Nano Lett. <\/em><\/strong>19, 2066 (2019);<\/p>\n

    Nano Lett. <\/em><\/strong>19, 5176 (2019);<\/p>\n

    Adv. Energy Mater<\/em><\/strong>. 9, 1803150 (2019);<\/p>\n

    Adv. Energy Mater<\/em><\/strong>. 9, 1902584 (2019);<\/p>\n

    Adv. Energy Mater<\/em><\/strong>. 9, 1902653 (2019)<\/p>\n

    Adv. Funct. Mater<\/em><\/strong>. 29, 1807094 (2019)<\/p>\n

    Nano Energy<\/em><\/strong> 63, 103865<\/strong> (2019)<\/a><\/p>\n

    Adv. Mater.<\/em><\/strong>\u00a030, 1800258 (2018)<\/a>;<\/p>\n

    Adv. Energy Mater.<\/em><\/strong>, 8, 1701688<\/strong> (2018)<\/a>;<\/p>\n

    Adv. Funct. Mater<\/em><\/strong>. 28, 1705875 (2018);<\/p>\n

    Nano Energy<\/em><\/strong>, 43, 47 (2018)<\/a>;<\/p>\n

    Adv. Mater.<\/em><\/strong>\u00a028, 6695 (2016)<\/a>;<\/p>\n

    Adv. Energy Mater.<\/em><\/strong> 6, 1601156 (2016);<\/p>\n

    Adv. Funct. Mater<\/em><\/strong>. 25, 6671 (2015);<\/p>\n

    ACS Nano<\/em><\/strong> 10, 5479 (2016);<\/p>\n

    ACS Energy Lett<\/em><\/strong>. 3, 875 (2018);<\/p>\n

      \n
    1. Mater. Chem. A<\/em><\/strong>, 7, 3655 (2019)<\/li>\n
    2. Mater. Chem. A<\/em><\/strong> 7, 145559 (2019);<\/li>\n
    3. Mater. Chem. A<\/em><\/strong> 7, 1161 (2018);<\/li>\n
    4. Mater. Chem. A<\/em><\/strong> 6, 1161 (2018);<\/li>\n
    5. Mater. Chem. A<\/em><\/strong> 5, 2572 (2017)<\/a>;<\/li>\n
    6. Mater. Chem. A<\/em><\/strong> 4, 15088 (2016);<\/li>\n
    7. Mater. Chem. A<\/em><\/strong> 4, 1326 (2016);<\/li>\n
    8. Mater. Chem. A<\/em><\/strong> 3, 13533 (2015);<\/li>\n<\/ol>\n

      \u672c\u6587\u7531tt\u4f9b\u7a3f\u3002\u00a0<\/p>\n

      \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead\u3002\u00a0<\/p>\n

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