{"id":189450,"date":"2019-11-19T06:30:29","date_gmt":"2019-11-18T22:30:29","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=189450"},"modified":"2019-11-18T18:36:00","modified_gmt":"2019-11-18T10:36:00","slug":"%e5%b0%8f%e7%b2%92%e5%ad%90%ef%bc%8c%e5%a4%a7%e4%bd%9c%e4%b8%ba%e2%88%92poms%e5%9c%a8%e5%89%8d%e6%b2%bf%e6%9d%90%e6%96%99%e4%b8%ad%e7%9a%84%e8%ba%ab%e5%bd%b1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=189450","title":{"rendered":"\u5c0f\u7c92\u5b50\uff0c\u5927\u4f5c\u4e3a\u2212POMs\u5728\u524d\u6cbf\u6750\u6599\u4e2d\u7684\u8eab\u5f71"},"content":{"rendered":"

\u591a\u91d1\u5c5e\u6c27\u7c07\uff08POMs\uff09\u662f\u4e00\u7c7b\u6709\u8fc7\u6e21\u91d1\u5c5e\u4e0e\u6c27\u5f62\u6210\u7684\u4e00\u7c7b\u65e0\u673a\u7eb3\u7c73\u7c07\uff0c\u5176\u5c3a\u5bf8\u53ef\u8c03\uff0c\u7ed3\u6784\u660e\u786e\uff0c\u5177\u6709\u591a\u79cd\u591a\u6837\u7684\u62d3\u6251\u7ed3\u6784\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5149\u7535\u78c1\u7b49\u6027\u8d28\uff0c\u5728\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u3001\u80fd\u6e90\u50ac\u5316\u3001\u533b\u836f\u751f\u7269\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u8be5\u6587\u7b80\u5355\u8ffd\u8e2a\u4e86\u8fd1\u671fPOM\u57fa\u6750\u6599\u5728\u5404\u79cd\u524d\u6cbf\u9886\u57df\u7684\u8eab\u5f71\u3002<\/p>\n

1.\u00a0<\/b><\/strong>\u542bPOM\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7528\u4f5c\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong>[<\/b><\/sup><\/strong>1<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u9502\u91d1\u5c5e\u662f\u9502\u7535\u6c60\u4e2d\u6240\u6709\u6b63\u6781\u6750\u6599\u4e2d\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u6700\u9ad8\u7684\u3002\u7136\u800c\uff0c\u9502\u7684\u4e0d\u5747\u5300\u7535\u6c89\u79ef\u4f1a\u5bfc\u81f4\u6811\u679d\u72b6\u9502\u6676\u7684\u5f62\u6210\uff0c\u7a7f\u900f\u7535\u6c60\u7684\u9694\u819c\uff0c\u5bfc\u81f4\u77ed\u8def\u3002\u56fa\u6001\u7535\u89e3\u8d28\u4f5c\u4e3a\u7269\u7406\u5c4f\u969c\u662f\u963b\u6b62\u9502\u679d\u6676\u7684\u7a7f\u900f\u7684\u6709\u6548\u624b\u6bb5\u3002\u56e0\u6b64\uff0c\u9ad8\u7684\u5316\u5b66\u548c\u673a\u68b0\u7a33\u5b9a\u6027\u7684\u540c\u65f6\uff0c\u517c\u5177\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u6210\u4e3a\u8bbe\u8ba1\u6750\u6599\u91cd\u8981\u7684\u56e0\u7d20\u3002MOF\u3001COF\u7b49\u9aa8\u67b6\u7ed3\u6784\u5177\u6709\u7a33\u5b9a\u7684\u5b54\u7ed3\u6784\u548c\u7a33\u5b9a\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u4f7f\u5176\u5728\u5bb9\u7eb3\u6709\u673a\u7535\u89e3\u8d28\u7684\u540c\u65f6\u4fdd\u6301\u56fa\u6001\u7ed3\u6784\u3002\u901a\u5e38\u7531\u4e24\u79cd\u7b56\u7565\u6765\u63d0\u9ad8\u8be5\u7c7b\u6750\u6599\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\uff1a\u4e00\u79cd\u662f\u9634\u79bb\u5b50\u4e0e\u9aa8\u67b6\u7ed3\u6784\u4e2d\u7684\u91d1\u5c5e\u914d\u4f4d\uff0c\u4f7f\u9aa8\u67b6\u5e26\u6709\u8d1f\u7535\u8377\uff1b\u53e6\u4e00\u79cd\u662f\u8bbe\u8ba1\u9634\u79bb\u5b50\u914d\u4f53\uff0c\u76f4\u63a5\u5408\u6210\u5e26\u6709\u8d1f\u7535\u8377\u7684\u9aa8\u67b6\u7ed3\u6784\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684Yaghi, Omar M.\u56e2\u961f\u5c06\u5177\u6709\u8f83\u9ad8\u7684\u8d1f\u7535\u8377\u5bc6\u5ea6POM\uff0c\u901a\u8fc7\u6709\u673a\u5171\u4ef7\u4fee\u9970\uff0c\u5f15\u5165MOF\u7ed3\u6784\u4e2d\u3002\u901a\u8fc7\u79bb\u5b50\u66ff\u6362\u5c06POM\u7684\u6297\u8861\u79bb\u5b50\u6362\u6210\u9502\u79bb\u5b50\uff0c\u5728\u5ba4\u6e29\u4e0b\u5b9e\u73b0\u4e86\u8f83\u9ad8\u7684\u79bb\u5b50\u5bfc\u7535\u73873.4\u00d710\u2212<\/sup>4<\/sup>\u00a0cm\u2212<\/sup>1<\/sup>\u3001\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u8f6c\u6362\u6570tLi+<\/sub>=0.87\u548c\u8f83\u4f4e\u7684\u754c\u9762\u7535\u963b353\u00a0\u03a9\u3002\u8bbe\u8ba1\u786c\u5e01\u7535\u6c60\uff0c\u4ee5\u91d1\u5c5e\u9502\u4e3a\u5370\u8bb0\uff0cLiFePO4<\/sub>\u4e3a\u9633\u6781\uff0c\u5728\u4e0d\u989d\u5916\u6dfb\u52a0\u9502\u76d0\u7684\u60c5\u51b5\u4e0b\uff0c\u8be5\u56fa\u6001\u7535\u89e3\u8d28\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u5e93\u4f26\u6548\u7387\uff0899.6%\uff09\uff0c\u7a33\u5b9a\u7684\u7535\u538b\u548c\u6709\u9650\u7684\u7535\u5bb9\u8870\u51cf\uff0c\u8bf4\u660e\u5176\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe1. MOF-688\u7684\u5408\u6210\u7b56\u7565\u53ca\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

2.\u00a0<\/b><\/strong>\u542bPOM\u7684\u78c1\u6027\u79bb\u5b50\u6db2\u4f53\u7528\u4e8e\u6c34\u5904\u7406\u53ca\u5fae\u5851\u6599\u53bb\u9664<\/b><\/strong>[<\/b><\/sup><\/strong>2<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u53d1\u5c55\u4e2d\u56fd\u5bb6\u7684\u8bb8\u591a\u6c34\u8d44\u6e90\u542b\u6709\u9ad8\u6d53\u5ea6\u7684\u6709\u673a\u6c61\u67d3\u7269\u3001\u91cd\u91d1\u5c5e\u6216\u5fae\u751f\u7269\u6c61\u67d3\u7269\u3002\u6b64\u5916\uff0c\u5fae\u5851\u6599\u9897\u7c92\u6700\u8fd1\u88ab\u786e\u5b9a\u4e3a\u65b0\u51fa\u73b0\u7684\u6c61\u67d3\u7269\uff0c\u5b83\u4eec\u53ef\u4ee5\u7ed3\u5408\u548c\u6d53\u7f29\u6301\u4e45\u6027\u6709\u673a\u6c61\u67d3\u7269\uff0c\u5728\u88ab\u6d77\u6d0b\u751f\u7269\u5438\u6536\u540e\u53ef\u8fdb\u5165\u98df\u7269\u94fe\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u6c34\u5904\u7406\u65b0\u6750\u6599\uff0c\u83b7\u5f97\u6e05\u6d01\u6c34\u4ecd\u7136\u662f\u4e00\u9879\u91cd\u5927\u6311\u6218\u3002\u4e4c\u5c14\u59c6\u5927\u5b66Streb, Carsten\u7814\u7a76\u56e2\u961f\uff0c\u4ee5\u5177\u6709\u6297\u83cc\u6d3b\u6027\u7684\u56db\u5e9a\u57fa\u6eb4\u5316\u94f5\u5305\u8986\u7f3a\u4f4dKeggin POM \u5236\u5907\u5f97\u5230\u542bPOM\u7684\u805a\u79bb\u5b50\u6db2\u4f53\uff08POM-IL\uff09\u4e0eSiO2<\/sub>@Fe2<\/sub>O3<\/sub>\u590d\u5408\uff0c\u5176\u4e2dPOM-IL\u542b\u91cf\u4e3a20%\u00a0wt.%\u3002\u8be5\u590d\u5408\u6750\u6599\u53ef\u4ee5\u6709\u6548\u7684\u5438\u9644\u6c34\u4e2d\u7684\u91d1\u5c5e\u79bb\u5b50\u6c61\u67d3\u7269\uff0c\u5982\uff1aPb2+<\/sup>\uff0cNi2+<\/sup>\uff0cCo2+<\/sup>\u548cMnMO4-<\/sup>\uff0c\u540c\u65f6\uff0c\u8be5\u590d\u5408\u6750\u6599\u53ef\u4ee5\u6709\u6548\u5730\u53bb\u9664\u6c34\u4e2d\u7684\u6709\u673a\u6c61\u67d3\u7269\u3001\u5fae\u5851\u6599\u4ee5\u7ec6\u83cc\uff0c\u4e14\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u53bb\u9664\u6548\u7387\u3002\u7531\u4e8e\u7531\u78c1\u6027\u7eb3\u7c73\u7c92\u5b50Fe2<\/sub>O3<\/sub>\u7684\u5b58\u5728\uff0c\u8be5\u590d\u5408\u6750\u6599\u53ef\u4ee5\u901a\u8fc7\u78c1\u94c1\u56de\u6536\uff0c\u4e14\u8be5\u65b9\u6cd5\u9002\u7528\u4e8e\u5927\u91cf\u6c61\u67d3\u6c34\u6e90\u7684\u6c34\u5904\u7406\u64cd\u4f5c\u3002<\/p>\n

\u56fe2. \u5229\u7528\u542b\u78c1\u6027\u7c92\u5b50\u7684\u591a\u91d1\u5c5e\u6c27\u7c07\u57fa\u79bb\u5b50\u6db2\u4f53\u6750\u6599\u53bb\u9664\u6c34\u4e2d\u591a\u79cd\u6c61\u67d3\u7269\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

3. POM\u63ba\u6742\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7528\u4e8e\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u548c\u957f\u671f\u7a33\u5b9a\u6027<\/b><\/strong>[<\/b><\/sup><\/strong>3<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u6709\u673a-\u65e0\u673a\u5364\u5316\u94c5\u9499\u949b\u77ff\uff0c\u5177\u6709\u53ef\u8c03\u7684\u80fd\u5e26\u95f4\u9699\u3001\u5f3a\u7684\u5149\u5b66\u5438\u6536\u4ee5\u53ca\u4f4e\u6210\u672c\u7684\u6eb6\u6db2\u5236\u9020\u5de5\u827a\uff0c\u6210\u4e3a\u4e00\u7c7b\u6781\u6709\u524d\u9014\u7684\u5149\u4f0f\u6750\u6599\u3002spiro-OMeTAD\u7684\u53ef\u63a7\u6c27\u5316\u548c\u63d0\u9ad8\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u7a33\u5b9a\u6027\u5bf9\u6539\u5584\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u548c\u826f\u597d\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002\u901a\u8fc7\u589e\u5f3a\u56fa\u6709\u7a33\u5b9a\u6027\u3001\u91c7\u7528\u8868\u9762\u949d\u5316\u548c\u4f7f\u7528\u9002\u5f53\u7684\u4e2d\u95f4\u5c42\u53ef\u4ee5\u63d0\u9ad8\u9499\u949b\u77ff\u5c42\u7684\u7a33\u5b9a\u6027\uff0c\u800c\u5bf9\u7a7a\u7a74\u4f20\u8d28\u5c42\u7684\u7814\u7a76\u8f83\u5c11\u3002\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66Fan Ruiqing\u56e2\u961f\u8bbe\u8ba1\u5408\u6210POM\u4e0e\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6742\u5316\u7684\u590d\u5408\u6750\u6599POM@Cu-BTC\uff0c\u5229\u7528\u9aa8\u67b6\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u548c\u591a\u5b54\u6027\uff0cPOM\u8f83\u5f3a\u7684\u7535\u5b50\u63a5\u53d7\u548c\u6c27\u5316\u80fd\u529b\uff0c\u8be5\u6750\u6599\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u5bfc\u7535\u6027\uff0c\u8f7d\u6d41\u5b50\u7684\u63d0\u53d6\u6548\u7387\uff0c\u800c\u4e14\u51cf\u5c11\u4e86\u9499\u949b\u77ff\u5c42\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u7535\u8377\u7684\u590d\u5408\uff0c\u5e76\u4e14\u8010\u6e7f\u5ea6\u63d0\u9ad8\u4e8690%\u3002<\/p>\n

\u56fe3.<\/p>\n

\"\"<\/p>\n

a) POM@Cu-BTC\u793a\u610f\u56fe\u3002b)\u00a0\u589e\u5f3a\u6e7f\u5ea6\u7a33\u5b9a\u6027\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

4. Mo<\/b><\/strong>2<\/b><\/sub><\/strong>C\u884d\u751f\u7684POM\u7528\u4e8eNIR-II\u5149\u58f0\u6210\u50cf\u3001\u5316\u5b66\u52a8\u529b\u5b66\/\u5149\u70ed\u534f\u540c\u6cbb\u7597<\/b><\/strong>[<\/b><\/sup><\/strong>4<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u5316\u5b66\u52a8\u529b\u6cbb\u7597(CDT)\u57fa\u4e8eFenton\u53cd\u5e94\u589e\u52a0\u7ec6\u80de\u5185\u6d3b\u6027\u6c27(ROS)\u6740\u6b7b\u80bf\u7624\u7ec6\u80de\uff0c\u7136\u800c\u4ea7\u751f\u7684\u6d3b\u6027\u6c27\u4f1a\u88ab\u80bf\u7624\u90e8\u4f4d\u7684\u7528\u4e8e\u81ea\u8c03\u8282\u7684\u8fd8\u539f\u5242\uff08\u5982\u8c37\u80f1\u7518\u80bd\uff09\u4e2d\u548c\uff0c\u63d0\u9ad8\u6d3b\u6027\u6c27\u662f\u5316\u5b66\u52a8\u529b\u6cbb\u7597\u7684\u6709\u6548\u624b\u6bb5\u3002\u5149\u70ed\u7597\u6cd5(PTT)\u662f\u4e00\u79cd\u5229\u7528\u5149\u70ed\u4ecb\u8d28\u5728\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\u4e0b\u4ea7\u751f\u70ed\u7597\u7684\u6709\u6548\u6cbb\u7597\u65b9\u6cd5\u3002\u70ed\u7597\u4e0d\u4ec5\u4f1a\u5bf9\u764c\u7ec6\u80de\u9020\u6210\u76f4\u63a5\u635f\u4f24\uff0c\u8fd8\u4f1a\u901a\u8fc7\u52a0\u901fFenton\u8fc7\u7a0b\u4fc3\u8fdbROS\u7684\u4ea7\u751f\uff0c\u4ece\u800c\u534f\u540cCDT\u3002\u5357\u4eac\u5de5\u4e1a\u5927\u5b66Dong Xiaochen\u56e2\u961f\u4ee5Mo2C\u4e3a\u539f\u6599\u5408\u6210\u542bMo\u7684POM\u5b9e\u73b0PTT\/CDT\u53cc\u91cd\u6cbb\u7597\u3002\u9178\u6027\u8bf1\u5bfcPOM\u7684\u51dd\u805a\u8fdb\u800c\u5728\u80bf\u7624\u7ec6\u80de\u7279\u5f02\u6027\u5bcc\u96c6\u548c\u6ede\u7559\uff0c\u4e14\u589e\u5f3a\u7684\u8fd1\u7ea2\u5916\u4e8c\u533a\uff08NIR-II\uff09\u5438\u6536\u3002\u8be5\u56e2\u961f\u8fd8\u53d1\u73b0Mo5+<\/sup>\u5230Mo6+<\/sup>\u4ea7\u751f\u5927\u91cf1<\/sup>O2<\/sub>\u662f\u57fa\u4e8eRussell\u673a\u7406\u800c\u975eFenton\u53cd\u5e94\u3002CDT\u8fc7\u7a0b\u88ab\u5149\u70ed\u8fc7\u7a0b\u589e\u5e45\uff0c\u5373\u4f7f\u5728\u8c37\u80f1\u7518\u80bd\u7684\u6301\u7eed\u635f\u8017\u4e0b\uff0c\u5176\u6cbb\u7597\u6548\u679c\u4f9d\u7136\u4fdd\u6301\u7a33\u5b9a\u3002\u5149\u58f0\u548c\u5149\u70ed\u6210\u50cf\u4e0d\u4ec5\u63ed\u793a\u4e86\u7eb3\u7c73\u9897\u7c92\u7684\u52a8\u6001\u5206\u5e03\uff0c\u800c\u4e14\u6709\u52a9\u4e8e\u89c2\u5bdf\u6700\u4f73\u534f\u540c\u6cbb\u7597\u5904\u7406\u7684\u65f6\u95f4\u70b9\u3002<\/p>\n

\u56fe4. POM\u7684\u5408\u6210\u53ca\u5176\u4f5c\u7528\u673a\u7406\u3002<\/p>\n

\"\"<\/p>\n

5. POM\u7a33\u5b9a\u8d64\u94c1\u77ff\u7528\u4e8e\u53ef\u89c1\u5149\u50ac\u5316\u5149\u6c27\u5316<\/b><\/strong>[<\/b><\/sup><\/strong>5<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u867d\u7136\u5404\u79cd\u5404\u6837\u7684\u7269\u7406\u624b\u6bb5\u5df2\u7ecf\u63d0\u4f9b\u4e86\u56fa\u6001\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u8584\u819c\u8868\u9762\u8fdb\u884c\u6c34\u6c27\u5316\u53cd\u5e94\u7684\u8be6\u7ec6\u7684\u673a\u7406\u4fe1\u606f\uff0c\u4f46\u662f\u5bf9\u6c34\u6eb6\u6027\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u6676\u53ca\u5176\u7c7b\u4f3c\u7269\u5728\u6c34\u4e2d\u8fdb\u884c\u6c34\u6c27\u5316\u7684\u7406\u89e3\u4f9d\u65e7\u8f83\u5c11\u3002\u4e3b\u8981\u662f\u56e0\u4e3a\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u6676\u5728\u6eb6\u6db2\u4e2d\uff0c\u5c24\u5176\u662f\u6c34\u4e2d\u503e\u5411\u4e8e\u5feb\u901f\u805a\u96c6\uff0c\u59a8\u788d\u5bf9\u5176\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u8ddf\u8e2a\u7814\u7a76\u3002\u672c-\u53e4\u91cc\u5b89\u5927\u5b66Weinstock, Ira A.\u7814\u7a76\u56e2\u961f\u8bbe\u8ba1\u5408\u6210\u7f3a\u4f4dPOM\u7a33\u5b9a\u7684\u8d64\u94c1\u77ffFe2<\/sub>O3<\/sub>\u7eb3\u7c73\u6676\uff0c\u5f97\u5230\u590d\u5408\u7269\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u4e0d\u4ec5\u6eb6\u4e8e\u6c34\uff0c\u800c\u4e14\u5177\u6709\u826f\u597d\u7684\u6297\u6c27\u5316\u548c\u6297\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u5728\u8fdb\u884c\u53ef\u89c1\u5149\u50ac\u5316\u6c34\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u5176\u6d3b\u6027\u53ef\u4fdd\u6301\u4e00\u4e2a\u661f\u671f\u3002\u8be5\u50ac\u5316\u5242\u72ec\u7279\u7684\u6eb6\u89e3\u6027\u548c\u7a33\u5b9a\u6027\u4e3a\u7814\u7a76\u6eb6\u6db2\u4e2d\u53ef\u89c1\u5149\u50ac\u5316\u6c34\u6c27\u5316\u673a\u7406\u63d0\u4f9b\u4e86\u53ef\u80fd\uff0c\u5b9e\u9a8c\u8bc1\u660e\uff0c\u4e0e\u5149\u7535\u6781\u53cd\u5e94\u673a\u7406\uff08\u53cd\u5e94\u6d3b\u6027\u7a7a\u7a74\u4f34\u968f\u7740O-O\u952e\u7684\u751f\u6210\u800c\u79ef\u7d2f\uff09\u4e0d\u540c\u7684\u662f\uff0c\u5176\u6c27\u5316\u673a\u5236\u4e3achain\u6a21\u5f0f\uff0c\u53cd\u5e94\u6d3b\u6027\u7a7a\u7a74\u7531\u5149\u6fc0\u53d1\u7535\u5b50\u7684\u9650\u901f\u6355\u83b7\u6fc0\u53d1\u5e76\u79ef\u7d2f\u3002<\/p>\n

\u56fe5.<\/p>\n

\"\"<\/p>\n

a) \u6c34\u6eb6\u6027\u91d1\u5c5e\u6c27\u5316\u7269\u50ac\u5316\u5242\u793a\u610f\u56fe\u3002b) \u53ef\u89c1\u5149\u6c27\u5316\u6c34\u7684chain\u673a\u7406\u3002<\/p>\n

6. \u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u8d1f\u8f7dPOMs\u5236\u5907\u7a33\u5b9a\u6c27\u5316\u8fd8\u539f\u6750\u6599<\/b><\/strong>[<\/b><\/sup><\/strong>6<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

POM\u53ef\u7ecf\u5386\u591a\u91cd\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u8f6c\u6362\u800c\u4fdd\u6301\u7ed3\u6784\u7684\u7a33\u5b9a\uff0c\u4f7f\u5176\u6709\u671b\u6210\u4e3a\u5206\u5b50\u95ea\u5b58\u5668\u4ef6\u7684\u8282\u70b9\uff0c\u4e5f\u53ef\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u7ec4\u5206\u7528\u4e8e\u7535\u5316\u5b66\u80fd\u6e90\u5b58\u50a8\u5668\u4ef6\u3002\u4e0b\u4e00\u4ee3\u5206\u5b50\u7535\u5b50\u3001\u7535\u50ac\u5316\u548c\u80fd\u91cf\u5b58\u50a8\u7cfb\u7edf\u7684\u53d1\u5c55\u53d6\u51b3\u4e8e\u83b7\u5f97\u7a33\u5b9a\u7684\u6750\u6599\uff0c\u5176\u5177\u6709\u5206\u5b50\u7ea7\u7535\u8377\u5b58\u50a8\u4f4d\u70b9\uff0c\u5e76\u4e14\u4f20\u5bfc\u4e3b\u4f53\u4e4b\u95f4\u7d27\u5bc6\u8054\u7cfb\u3002\u7136\u800c\uff0c\u5b8c\u5168\u6c27\u5316\u7684POMs\u662f\u7535\u7edd\u7f18\u7684\uff0c\u9650\u5236\u4e86\u7535\u8377\u7684\u6d41\u52a8\uff0c\u800c\u4e14POMs\u901a\u5e38\u5728\u5316\u5b66\u548c\u7535\u5316\u5b66\u4e0a\u4e0d\u7a33\u5b9a\uff0c\u7279\u522b\u662f\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u3002\u8bfa\u4e01\u6c49\u5927\u5b66\u7684Khlobystov, A. N.\u56e2\u961f\u62a5\u9053\u4e86\u7b80\u5355\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u5c06POMs\u5305\u8f7d\u4e8e\u9633\u79bb\u5b50\u5355\u58c1\u78b3\u7ba1\u4e2d\uff0c\u5f97\u5230\u4e86\u7a33\u5b9a\u7684\u590d\u5408\u6750\u6599\u3002\u8be5\u8fc7\u7a0b\u5728\u5e93\u4ed1\u529b\u7684\u9a71\u52a8\u4e0b\uff0c\u65e0\u989d\u5916\u6dfb\u52a0\u7269\uff0c\u5e76\u4e14\u8be5\u8fc7\u7a0b\u5728\u5ba4\u6e29\u4e0b\u662f\u81ea\u53d1\u5730\u3001\u4e0d\u53ef\u9006\u5730\u3002\u8be5\u6750\u6599\u5373\u4f7f\u5728\u78b1\u6027\u7535\u89e3\u8d28(pH=13)\u4e2d\u4f9d\u7136\u7a33\u5b9a\u3002\u8be5\u6750\u6599\u4e3a\u53ef\u4f38\u7f29\u548c\u53ef\u6301\u7eed\u7684\u5408\u6210\u6742\u5316\u529f\u80fd\u6750\u6599\u5f00\u8f9f\u4e86\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n

\u56fe 6.<\/p>\n

\"\"<\/p>\n

i) \u7535\u5b50\u4eceSWNTs (\u7c89\u8272\u4e2d\u6027\uff0c\u84dd\u8272\u9633\u79bb\u5b50) \u8f6c\u79fb\u5230POMs (\u9ec4\u8272\u539f\u751f\u6001\uff0c\u6df1\u84dd\u8272\u8fd8\u539f\u6001); ii) \u5e93\u4ed1\u529b\u9a71\u52a8POMs\u5c01\u88c5\u4e8e\u9633\u79bb\u5b50SWNTs\u4e2d; iii) \u672a\u5c01\u88c5\u7684POMs\u548c\u6240\u6709\u7684\u94be\u79bb\u5b50\u88ab\u6c34\u51b2\u8d70\u3002<\/p>\n

7. POM<\/b><\/strong>s<\/b><\/strong>\u5355\u7c07\u67d4\u6027\u7ec4\u88c5\u53ca\u5176\u4e09\u7ef4\u8d85\u7ed3\u6784<\/b><\/strong>[<\/b><\/sup><\/strong>7<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/h3>\n

\u65e0\u673a\u7eb3\u7c73\u6676\u4f53\u7531\u4e8e\u5176\u6676\u683c\u7ed3\u6784\uff0c\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u521a\u6027\u5355\u5143\uff0c\u7eb3\u7c73\u6676\u4f53\u7684\u8f7b\u5fae\u53d8\u5f62\u4f1a\u5bfc\u81f4\u9ad8\u6676\u683c\u5e94\u529b\uff0c\u4ece\u800c\u9650\u5236\u5176\u7ec4\u88c5\u6210\u590d\u6742\u7684\u8d85\u7ed3\u6784\u3002\u4e0e\u65e0\u673a\u7eb3\u7c73\u6676\u4f53\u76f8\u6bd4\uff0cSub-1 nm\u7684\u65e0\u673a\u7eb3\u7c73\u7c07\u7ec4\u88c5\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u7684\u5b9a\u5411\u6216\u975e\u5b9a\u5411\u7531\u975e\u5171\u4ef7\u952e\u51b3\u5b9a\uff0c\u5b83\u4eec\u53ef\u80fd\u4e0d\u9075\u5faa\u786c\u7403\u6a21\u578b\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7f3a\u4e4f\u5408\u9002\u7684\u8fde\u63a5\u4ecb\u8d28\u548c\u56e2\u7c07\u7684\u805a\u96c6\u8d8b\u52bf\uff0c\u4ece\u5355\u4e2a\u56e2\u7c07\u5230\u8d85\u7ed3\u6784\u7684\u7ec4\u88c5\u4ecd\u7136\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u6e05\u534e\u5927\u5b66Wang\u00a0Xun\u7814\u7a76\u56e2\u961f\u91c7\u7528\u4e00\u6b65\u6c34\u70ed\u5408\u6210\u6cd5\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5355\u7c07\u7eb3\u7c73\u7ebf\u7ed3\u6784\u3001\u67d4\u6027\u7eb3\u7c73\u73af\u7ed3\u6784\u4ee5\u53ca\u4e09\u7ef4\u8d85\u7ed3\u6784\u3002\u5176\u4e2d\uff0c\u6eb6\u5242\u73af\u5883\u7684pH\u51b3\u5b9a\u4e86\u5176\u7ed3\u6784\u4e3a\u7eb3\u7c73\u7ebf\u8fd8\u662f\u7eb3\u7c73\u73af\uff1bPOM\u7684\u6297\u8861\u79bb\u5b50\u7684\u94fe\u957f\u5f71\u54cd\u5176\u53ef\u884c\u53d8\u5f62\u53ca\u7ec4\u88c5\u65f6\u95f4\uff1b\u9178\u76d0\u7684\u5c3a\u5bf8\u5f71\u54cd\u7c07\u95f4\u95f4\u8ddd\u3002\u8be5\u5de5\u4f5c\u4e3a\u5236\u5907\u591a\u529f\u80fd\u6027\u7684\u67d4\u6027\u7eb3\u7c73\u7ed3\u6784\u548c\u8d85\u7ed3\u6784\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u5e76\u53ef\u80fd\u4ece\u5206\u5b50\u6c34\u5e73\u4e0a\u542f\u53d1\u65e0\u673a\u8d85\u6750\u6599\u7684\u8bbe\u8ba1\u3002<\/p>\n

\u56fe 7. POMs\u7eb3\u7c73\u7ed3\u6784\u7684\u5408\u6210\u548c\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/h3>\n

POM\u672c\u8eab\u7684\u7ed3\u6784\u7279\u70b9\u53ca\u529f\u80fd\u6027\u8d28\u591a\u79cd\u591a\u6837\uff0c\u4f46\u9650\u4e8e\u5176\u672c\u8eab\u7684\u7a33\u5b9a\u6027\u53ca\u53ef\u52a0\u5de5\u6027\u5dee\uff0c\u4f7f\u5176\u5e94\u7528\u6269\u5c55\u53d7\u9650\u3002\u800c\u4eca\u5176\u5408\u6210\u7684\u591a\u6837\u6027\uff0c\u4fee\u9970\u7684\u4fbf\u5229\u6027\uff0c\u4f7f\u5176\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u586b\u6599\u6269\u5c55\u5e94\u7528\u9886\u57df\uff0c\u800c\u4e14\u4fbf\u4e8e\u53d1\u6325\u5176\u7ed3\u6784\u548c\u591a\u529f\u80fd\u6027\u7684\u4f18\u52bf\u3002\u5c0f\u7c92\u5b50\uff0c\u5927\u4f5c\u4e3a\u3002POM\u4e0e\u5404\u79cd\u660e\u661f\u5206\u5b50\u3001\u70ed\u70b9\u6750\u6599\u7684\u76f8\u4e92\u63ba\u6742\uff0c\u4f7f\u5176\u5728\u5404\u79cd\u524d\u6cbf\u9886\u57df\u4e2d\u9891\u7e41\u51fa\u73b0\uff0c\u5e76\u4e14\u8d77\u5230\u5173\u952e\u4f5c\u7528\uff0c\u4e3aPOM\u5316\u5b66\u7684\u53d1\u5c55\u5e26\u6765\u4e86\u673a\u9047\u548c\u6311\u6218\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/h3>\n

(1) Xu, W.; Pei, X.; Diercks, C. S.; Lyu, H.; Ji, Z.; Yaghi, O. M. A Metal-Organic Framework of Organic Vertices and Polyoxometalate Linkers as a Solid-State Electrolyte. J. Am. Chem. Soc. <\/i><\/em>2019,<\/b><\/strong>\u00a0141<\/i><\/em>, 17522.<\/p>\n

(2) Misra, A.; Zambrzycki, C.; Kloker, G.; Kotyrba, A.; Anjass, M. H.; Castillo, I. F.; Mitchell, S. G.; Guttel, R.; Streb, C. Water Purification and Microplastics Removal Using Magnetic Polyoxometalate Supported-Ionic Liquid Phases (Magpom-Silps). Angew. Chem. Int. Ed. <\/i><\/em>2019<\/b><\/strong>, DOI:10.1002\/anie.201912111.<\/p>\n

(3) Dong, Y.; Zhang, J.; Yang, Y.; Qiu, L.; Xia, D.; Lin, K.; Wang, J.; Fan, X.; Fan, R. Self-Assembly of Hybrid Oxidant Pom@Cu-Btc for Enhanced Efficiency and Long-Term Stability of Perovskite Solar Cells. Angew. Chem. Int. Ed. <\/i><\/em>2019<\/b><\/strong>, DOI:10.1002\/anie.201909291.<\/p>\n

(4) Liu, G.; Zhu, J.; Guo, H.; Sun, A.; Chen, P.; Xi, L.; Huang, W.; Song, X.; Dong, X. Mo2<\/sub> C-Derived Polyoxometalate for Nir-Ii Photoacoustic Imaging-Guided Chemodynamic\/Photothermal Synergistic Therapy. Angew. Chem. Int. Ed. <\/i><\/em>2019<\/b><\/strong>, DOI:10.1002\/anie.201910815.<\/p>\n

(5) Chakraborty, B.; Gan-Or, G.; Duan, Y.; Raula, M.; Weinstock, I. A. Visible-Light-Driven Water Oxidation with a Polyoxometalate-Complexed Hematite Core of 275 Iron Atoms. Angew. Chem. Int. Ed. <\/i><\/em>2019,<\/b><\/strong>\u00a058<\/i><\/em>, 6584.<\/p>\n

(6) Jordan, J. W.; Lowe, G. A.; McSweeney, R. L.; Stoppiello, C. T.; Lodge, R. W.; Skowron, S. T.; Biskupek, J.; Rance, G. A.; Kaiser, U.; Walsh, D. A.et al. Host-Guest Hybrid Redox Materials Self-Assembled from Polyoxometalates and Single-Walled Carbon Nanotubes. Adv. Mater. <\/i><\/em>2019,<\/b><\/strong>\u00a031<\/i><\/em>, 1904182.<\/p>\n

(7) Liu, Q.; He, P.; Yu, H.; Gu, L.; Ni, B.; Wang, D.; Wang, X. Single Molecule\u2013Mediated Assembly of Polyoxometalate Single-Cluster Rings and Their Three-Dimensional Superstructures. Sci. Adv. <\/i><\/em>2019,<\/b><\/strong>\u00a05<\/i><\/em>, eaax1081.<\/p>\n

\u672c\u6587\u7531Netlep<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u591a\u91d1\u5c5e\u6c27\u7c07\uff08POMs\uff09\u662f\u4e00\u7c7b\u6709\u8fc7\u6e21\u91d1\u5c5e\u4e0e\u6c27\u5f62\u6210\u7684\u4e00\u7c7b\u65e0\u673a\u7eb3\u7c73\u7c07\uff0c\u5176\u5c3a\u5bf8\u53ef\u8c03\uff0c\u7ed3\u6784\u660e\u786e\uff0c\u5177\u6709\u591a\u79cd\u591a\u6837\u7684\u62d3\u6251\u7ed3\u6784\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5149\u7535\u78c1\u7b49\u6027\u8d28\uff0c\u5728\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u3001\u80fd\u6e90…<\/p>\n","protected":false},"author":10213,"featured_media":179054,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-189450","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189450"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=189450"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189450\/revisions"}],"predecessor-version":[{"id":190381,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189450\/revisions\/190381"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/179054"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=189450"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=189450"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=189450"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}