{"id":189899,"date":"2019-11-15T06:30:45","date_gmt":"2019-11-14T22:30:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=189899"},"modified":"2019-11-14T15:16:24","modified_gmt":"2019-11-14T07:16:24","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91acs-applied-materials-interfaces%ef%bc%9a%e6%b0%ae%e3%80%81%e7%a1%ab%e5%85%b1%e6%8e%ba%e6%9d%82%e7%9f%b3%e5%a2%a8%e7%83%af%e9%99%90%e5%9f%9f%e7%94%9f%e9%95%bfsns","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=189899","title":{"rendered":"ACS Applied Materials & Interfaces\uff1a\u6c2e\u3001\u786b\u5171\u63ba\u6742\u77f3\u58a8\u70ef\u9650\u57df\u751f\u957fSnS\u7eb3\u7c73\u7247\u589e\u5f3a\u8d5d\u7535\u5bb9\u884c\u4e3a\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u5bb9\u5668"},"content":{"rendered":"

\u5f15\u8a00<\/strong><\/p>\n

\u94a0\u79bb\u5b50\u7535\u5bb9\u5668(SIC)\u662f\u4e00\u79cd\u65b0\u578b\u7684\u6df7\u5408\u578b\u7535\u5bb9\u5668\uff0c\u81ea2012\u5e74\u9996\u6b21\u7814\u7a76\u4ee5\u6765\uff0c\u5176\u5de5\u4f5c\u539f\u7406\u662f\u4ee5\u7535\u6c60\u578b\u6750\u6599\u4e3a\u8d1f\u6781\uff0c\u4ee5\u7535\u5bb9\u578b\u6750\u6599(\u5982\u6d3b\u6027\u70ad)\u4e3a\u6b63\u6781\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9634\u79bb\u5b50(\u5982ClO4<\/sub>–<\/sup>)\u5411\u6b63\u6781\u79fb\u52a8\u5f62\u6210\u7535\u53cc\u5c42\uff0c\u94a0\u79bb\u5b50\u5411\u8d1f\u6781\u79fb\u52a8\u4ea7\u751f\u6cd5\u62c9\u7b2c\u53cd\u5e94\uff1b\u5728\u5916\u90e8\u7535\u8def\u4e2d\uff0c\u7535\u5b50\u4ece\u6b63\u6781\u8f6c\u79fb\u5230\u8d1f\u6781\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u6df7\u5408\u88c5\u7f6e\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574\u5b83\u4eec\u5404\u81ea\u7684\u50a8\u80fd\u65b9\u5f0f\uff0c\u5c06\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4f18\u70b9\u7ed3\u5408\u8d77\u6765\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u4e24\u4e2a\u7535\u6781\u53ef\u4ee5\u5728\u4e0d\u540c\u7684\u7535\u4f4d\u8303\u56f4\u5185\u5de5\u4f5c\uff0c\u56e0\u6b64\u6df7\u5408\u88c5\u7f6e\u53ef\u4ee5\u5728\u8f83\u5927\u7684\u7535\u4f4d\u7a97\u53e3\u4e0b\u5de5\u4f5c\u3002\u7136\u800c\u4e0e\u9502\u79bb\u5b50\u4e0d\u540c\u7684\u662f\uff0c\u94a0\u79bb\u5b50\u5177\u6709\u6bd4\u9502\u79bb\u5b50\u66f4\u5927\u7684\u79bb\u5b50\u534a\u5f84\uff081.02\u00c5\uff1aNa+<\/sup>\u00a0vs. 0.76 \u00c5\uff1aLi+<\/sup>\uff09\uff0c\u5bf9\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u8d1f\u6781\u6750\u6599\u800c\u8a00\uff0c\u94a0\u79bb\u5b50\u66f4\u96be\u5d4c\u5165\u7535\u6781\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u4e2d\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u5176\u79bb\u5b50\u6269\u6563\u548c\u8fc1\u79fb\u7684\u96be\u5ea6\u66f4\u5927\u3002\u9020\u6210\u8f83\u5927\u7684\u6b63\u8d1f\u6781\u7535\u6781\u53cd\u5e94\u901f\u7387\u5931\u8861\uff0c\u8fd9\u79cd\u4e0d\u5e73\u8861\u7684\u53cd\u5e94\u52a8\u529b\u963b\u788d\u4e86\u8d1f\u6781\u6750\u6599\u5145\u5206\u53d1\u6325\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u4f18\u52bf\uff0c\u540c\u65f6\u5f15\u8d77\u7535\u5bb9\u578b\u6b63\u6781\u4ea7\u751f\u8f83\u5927\u7684\u6781\u5316\u8fc7\u7535\u4f4d\uff0c\u56e0\u6b64\u663e\u8457\u5f71\u54cd\u4e86\u6df7\u5408\u5668\u4ef6\u7684\u6548\u7387\u3002\u4e3a\u4e86\u5339\u914d\u7535\u5bb9\u578b\u6b63\u6781\u6750\u6599\u7684\u5feb\u901f\u975e\u6cd5\u62c9\u7b2c\u53cd\u5e94\u8fc7\u7a0b\uff0c\u9700\u8981\u94a0\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7684\u8d1f\u6781\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u94a0\u79bb\u5b50\u7535\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u3002\u4e8c\u7ef4\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u662f\u4e00\u7c7b\u7ed3\u6784\u548c\u6027\u8d28\u90fd\u975e\u5e38\u4e30\u5bcc\u7684\u5316\u5408\u7269\uff0c\u5177\u6709\u7c7b\u4f3c\u4e8e\u77f3\u58a8\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u5176\u8f83\u5927\u7684\u5c42\u95f4\u8ddd\uff085.7-6.5 \u00c5\uff09\uff0c\u4f7f\u94a0\u79bb\u5b50\u66f4\u5bb9\u6613\u5728\u5c42\u95f4\u53d1\u751f\u53ef\u9006\u7684\u8131\u5d4c\uff0c\u4e0e\u5bf9\u5e94\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u76f8\u6bd4\uff0cM-S\u952e\u6bd4M-O\u952e\u7535\u8d1f\u6027\u66f4\u5f3a\uff0c\u4f7f\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5316\u7269\u5177\u6709\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u4e14\u5b83\u4eec\u7684\u5bfc\u7535\u6027\u90fd\u4f18\u4e8e\u5bf9\u5e94\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u5e94\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u5c06\u83b7\u5f97\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u3002\u4e0e\u5757\u4f53\u6750\u6599\u76f8\u6bd4\uff0c\u5c11\u5c42\u6216\u5355\u5c42\u7684\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u5177\u6709\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u66f4\u4e30\u5bcc\u7684\u8fb9\u7f18\u7ed3\u6784\uff0c\u80fd\u4e3a\u94a0\u79bb\u5b50\u63d0\u4f9b\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u5341\u5206\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u7684\u5feb\u901f\u6e17\u900f\u548c\u79bb\u5b50\u7684\u5feb\u901f\u6269\u6563\uff0c\u56e0\u6b64\u5177\u6709\u660e\u663e\u7684\u8d5d\u7535\u5bb9\u6548\u5e94\u3002\u6b64\u5916\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u4e5f\u8bc1\u5b9e\u4e86\u91d1\u5c5e\u786b\u5316\u7269\u6750\u6599\u7684\u8d5d\u7535\u5bb9\u8d21\u732e\u5728\u603b\u4f53\u4e2d\u5360\u636e\u5f88\u5927\u6bd4\u4f8b\u3002\u8fd9\u4e9b\u91d1\u5c5e\u786b\u5316\u7269\u72ec\u7279\u7684\u4f18\u70b9\u4f7f\u5176\u80fd\u6210\u4e3a\u4f18\u826f\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u7684\u6f5c\u5728\u6750\u6599\u3002<\/p>\n

\u6210\u679c\u4ecb\u7ecd<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u5357\u77f3\u6cb9\u5927\u5b66\u674e\u661f\u6559\u6388\u548c\u738b\u660e\u73ca\u526f\u6559\u6388\u56e2\u961f\u4e0e<\/b><\/strong>University of Washington <\/i><\/b><\/em><\/strong>\u7684<\/b><\/strong>Guozhong Cao\u6559\u6388<\/b><\/strong>\u5408\u4f5c\u5f00\u5c55\u4e86\u6c2e\uff0c\u786b\u5171\u63ba\u6742\u77f3\u58a8\u70ef\u9650\u57df\u751f\u957f\u786b\u5316\u4e9a\u9521\u7eb3\u7c73\u7247\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u8d1f\u6781\u6750\u6599\u7684\u7814\u7a76\u3002\u786b\u5316\u4e9a\u9521\uff08SnS\uff09\u5b58\u5728\u8f83\u5927\u7684\u5c42\u95f4\u95f4\u8ddd\uff080.56 nm\uff09\uff0c\u5177\u67091020 mA h g-1<\/sup>\u7684\u9ad8\u7406\u8bba\u6bd4\u5bb9\u91cf\uff0c\u662f\u5178\u578b\u7684\u9ad8\u6bd4\u5bb9\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u7136\u800c\u8be5\u6750\u6599\u5728\u94a0\u5316\u8fc7\u7a0b\u4e2d\u4f34\u968f\u8f83\u5927\u7684\u4f53\u79ef\u53d8\u5316\u4ee5\u53ca\u672c\u5f81\u7535\u5bfc\u7387\u4f4e\u7684\u95ee\u9898\uff0c\u5757\u4f53SnS\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u5f88\u5dee\u3002\u9488\u5bf9\u4e0a\u8ff0\u95ee\u9898\uff0c\u6784\u7b51\u4e8c\u7ef4\u7eb3\u7c73\u7ed3\u6784\uff0c\u4f7f\u5176\u5c55\u73b0\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u66b4\u9732\u8fb9\u7f18\u7ed3\u6784\uff0c\u53ef\u4ee5\u83b7\u5f97\u66f4\u591a\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u94a0\u79bb\u5b50\u5177\u6709\u66f4\u5feb\u901f\u7684\u5d4c\u5165\/\u8131\u51fa\u53cd\u5e94\u52a8\u529b\u3002\u57fa\u4e8e\u6b64\uff0c\u672c\u5de5\u4f5c\u901a\u8fc7\u6c34\u70ed\u9759\u7535\u81ea\u7ec4\u88c5\u7684\u65b9\u6cd5\uff0c\u5f15\u5165\u77f3\u58a8\u70ef\u548cPDDA\uff0c\u901a\u8fc7\u81ea\u7ec4\u88c5\u7ed3\u5408\u6c34\u70ed\u8fd8\u539f\uff0c\u539f\u4f4d\u751f\u957fSnS\u7eb3\u7c73\u7247\u5728\u77f3\u58a8\u70ef\u7ed3\u6784\u4e2d\uff0c\u7814\u7a76\u53d1\u73b0\uff0cSnS\u7684\u751f\u957f\u503e\u5411\u4e8e\u6cbf(l00)<\/i><\/em>\u548c(0l0)<\/i><\/em>\u65b9\u5411\uff0c\u56e0\u6b64\u7eafSnS\u5448\u73b0\u539a\u7684\u7247\u72b6\u7ed3\u6784\u3002\u5728\u77f3\u58a8\u70ef\u7684\u963b\u9694\u4f5c\u7528\u4e0b\uff0cSnS\u6cbf(l00)<\/i><\/em>\u548c(0l0)<\/i><\/em>\u65b9\u5411\u88ab\u9650\u5236\uff0c\u4e0e\u7eafSnS\u76f8\u6bd4\u5177\u6709\u660e\u663e\u51cf\u5c0f\u7684\u539a\u5ea6\u548c\u7c92\u5f84\uff0c\u8fd9\u79cd\u7eb3\u7c73\u7ed3\u6784\u66b4\u9732\u51fa\u4e30\u5bcc\u7684\u5f00\u653e\u8fb9\u7f18\uff0c\u7531\u4e8e\u8fb9\u7f18Sn2+<\/sup>\u7684\u4e0d\u7a33\u5b9a\u540c\u65f6\u5f15\u5165\u4e86\u6c27\u7a7a\u4f4d\u5f62\u6210Sn4+<\/sup>-O\u7684\u8fb9\u7f18\u7ed3\u6784\uff0c\u4e3aNa+<\/sup>\u8131\u5d4c\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u4fbf\u5229\u7684\u6269\u6563\u8def\u5f84\u3002\u540c\u65f6\u5728\u6c34\u70ed\u8fc7\u7a0b\u4e2d\uff0cL-\u534a\u80f1\u6c28\u9178\u7684\u5f15\u5165\u4f7f\u786b\uff0c\u6c2e\u63ba\u6742\u5728\u77f3\u58a8\u70ef\u7ed3\u6784\u4e2d\uff0c\u63d0\u9ad8\u4e86\u77f3\u58a8\u70ef\u7684\u5bfc\u7535\u6027\u3002\u8fd9\u79cd\u9650\u57df\u751f\u957f\u7684SnS\u7eb3\u7c73\u7247\/N\u3001S\u5171\u63ba\u6742\u77f3\u58a8\u70ef\u534f\u540c\u589e\u5f3a\u4e86Na+<\/sup>\u7684\u8d5d\u7535\u5bb9\u5b58\u50a8\u80fd\u529b\uff0c\u4f5c\u4e3a\u94a0\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u8d1f\u6781\u6750\u6599\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5728\u529f\u7387\u5bc6\u5ea6\u5206\u522b\u4e3a101\u548c11100 W kg -1<\/sup>\u65f6\uff0c\u8be5\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u6240\u63d0\u4f9b\u7684\u80fd\u91cf\u5bc6\u5ea6\u5206\u522b\u4e3a113\u548c54 W h kg -1<\/sup>\uff0c\u4e14\u57281 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b2000\u6b21\u5faa\u73af\u540e\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u4fdd\u6301\u7387\u4e3a76%\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n

\"\"\u00a0 \u00a0\u00a0\u56fe1\u00a0SnS\/rGO\u6750\u6599\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe2 (a) SnS2<\/sub>\u9ad8\u6e29\u5904\u7406\u524d\u7684XRD\u56fe; (b) SnS\/rGO \u548cSnS \u7684XRD\u56fe; (c) SnS\/rGO\u7684\u62c9\u66fc\u56fe\u8c31; (d) SnS\/rGO\u7684\u70ed\u91cd\u66f2\u7ebf<\/p>\n

\u88681\u00a0SnS\/rGO\u548cSnS\u5728(040) \u548c\u00a0(002) \u884d\u5c04\u9762\u4e0a\u7684\u6676\u7c92\u5c3a\u5bf8\u5206\u6790\"\"<\/p>\n

XRD\u8ba1\u7b97\u663e\u793aSnS\/rGO\u4e2d\u7684SnS\u7247\u5c3a\u5bf8\u76f8\u6bd4\u4e8e\u7eafSnS\u7684\u66f4\u5c0f\u66f4\u8584\u3002\u8bf4\u660e\u77f3\u58a8\u70ef\u7684\u52a0\u5165\u6291\u5236\u4e86SnS\u7684\u957f\u5927\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u00a0(a) SnS \u548c\u00a0SnS\/rGO\u7684XPS\u5168\u8c31\u56fe; (b) SnS\/rGO \u7684N1s\u5206\u8c31\u56fe; (c) SnS\/rGO \u7684C1s \u5206\u8c31\u56fe; (d) \uff0c(e)\u662fSnS \u548c SnS\/rGO \u7684S2p \u4e0eSn3d\u5206\u8c31\u56fe<\/p>\n

XPS\u663e\u793a\u5728\u77f3\u58a8\u70ef\u4e2d\u5f15\u5165\u4e86N,S\u5143\u7d20\u3002\u63d0\u9ad8\u77f3\u58a8\u70ef\u7684\u5bfc\u7535\u6027\u5e76\u589e\u52a0\u6d3b\u6027\u4f4d\u70b9\u3002\u540c\u65f6S2p\u4e0eSn3d\u5b58\u5728\u4e00\u4e2a\u5c0f\u7684\u4f4d\u79fb\u3002\u8bc1\u5b9eSnS\u4e0e\u77f3\u58a8\u70ef\u4e4b\u95f4\u5b58\u5728\u9759\u7535\u5438\u5f15\u3002\u589e\u52a0SnS\/rGO\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027, \u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"\u56fe4\u00a0\u00a0(a) \u548c\u00a0(e) \u5206\u522b\u662fSnS \u4e0e\u00a0SnS\/rGO\u7684SEM\u56fe\u3002(b) \u548c\u00a0(c) \u662f SnS\u7684TEM\u56fe\uff1b(d) \u00a0FFT\u8f6c\u53d8\u56fe\uff1b(f), (g) \u548c\u00a0(h) \u4e3a SnS\/rGO \u7684TEM\u56fe\u3002(i) SnS\/rGO\u7684\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe\uff1b(j) \u00a0(040)\u6676\u4f53\u5e73\u9762\u95f4\u8ddd\u6d4b\u8bd5\uff1b(k)\u548c(l) \u6cbf(l00)<\/i><\/em>\u548c(00l)<\/i><\/em>\u8f74\u63d2\u5165(002)(\u7ea2\u8272\u5e73\u9762)\u548c(040)(\u84dd\u8272\u5e73\u9762)\u7684\u4e8c\u7ef4SnS\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\u7ed3\u679c\u663e\u793a\uff0c\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u77f3\u58a8\u70ef\u7684\u7ea6\u675f\uff0cSnS\u7eb3\u7c73\u7247\u6cbf(l00)<\/i><\/em>\u548c(00l)<\/i><\/em>\u65b9\u5411\u66b4\u9732\u4e86\u8bb8\u591a\u5f00\u653e\u8fb9\u7f18\uff0c\u5982\u56fe4i\u6240\u793a\u3002\u4eceSnS\u8584\u7247\u7684[100]\u548c[001]\u8f74 (\u56fe4k,l)\u4e2d\uff0c\u8fd9\u4e9b\u66b4\u9732\u7684\u8fb9\u7f18\u53ef\u4ee5\u4fc3\u8fdbNa+<\/sup>\u8f6c\u79fb\u5230(0l0)<\/i><\/em>\u5e73\u9762\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 (a) SnS\/rGO\u57280.1 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf;(b) SnS\/rGO\u521d\u59cb\u4e09\u4e2a\u5faa\u73af0.1 A g-1<\/sup>\u7684\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf;(c) SnS\u548cSnS\/rGO\u57280.5 A g-1<\/sup>\u7684\u5faa\u73af\u6027\u80fd;(d) SnS\/rGO\u548cSnS\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd<\/p>\n

\"\"<\/p>\n

\u56fe6 (a) SnS\/rGO\u548c(b) SnS\u5728\u4e0d\u540c\u5faa\u73af\u540e\u7684Nyquist\u56fe;(c) SnS\/rGO\u548cSnS\u5728\u4e0d\u540c\u5faa\u73af\u540e\u7684Re\u503c;(d)\u4e0d\u540c\u5faa\u73af\u7684SnS\/rGO\u548cSnS\u7684Rf+Rct;(e)\u548c(f) \u662fSnS \/ rGO, SnS\u4e0d\u540c\u5faa\u73af\u5708\u6570\u540e\u963b\u6297\u7684Z`\u4e0e\u03c9-1\/2<\/sup>\u00a0\u7684\u70b9\u7ebf\u56fe\u00a0<\/p>\n

\u88682 \u00a0SnS\u4e0eSnS\/rRO\u4e0d\u540c\u5faa\u73af\u540e\u7684DNa+<\/sub>\u00a0(Na\u79bb\u5b50\u6269\u6563\u7cfb\u6570)\u6bd4\u8f83\"\"<\/p>\n

\u968f\u7740\u5faa\u73af\u5708\u6570\u7684\u589e\u52a0SnS\u7535\u6781\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u6025\u5267\u51cf\u5c0f\uff0c\u800cSnS\/rRO \u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u57fa\u672c\u7ef4\u6301\u4e0d\u53d8\uff0c\u4e14\u4e0d\u540c\u5faa\u73af\u5708\u6570SnS\/rGO\u7684\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u5747\u5927\u4e8eSnS\u3002\u8fd9\u8bf4\u660eSnS\/rGO\u6bd4SnS\u5177\u6709\u66f4\u9ad8\u7684Na+<\/sup>\u6269\u6563\u52a8\u529b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7 (a) SnS\/rGO\u548c(b) SnS\u7535\u6781\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b(c)\u548c(d)\u662fSnS \/ rGO\u548cSnS\u7684\u62df\u5408\u503cb\uff1b(e) SnS\/rGO\u57287mV s-1<\/sup>\u65f6\u7684\u7535\u5bb9\u8d21\u732e\u548c\u6269\u6563\u8d21\u732e\u9762\u79ef\u56fe\uff1b(f) SnS\/rGO\u4ece0.1mV s-1<\/sup>\u52307mV s-1<\/sup>\u7535\u5bb9\u6027\u8d21\u732e\u767e\u5206\u6bd4<\/p>\n

\u8d5d\u7535\u5bb9\u8ba1\u7b97\u53d1\u73b0SnS\/rGO\u76f8\u6bd4\u4e8eSnS\u5177\u6709\u66f4\u5927\u7684\u8d5d\u7535\u5bb9\u8d21\u732e\uff0c\u8fd9\u4e5f\u89e3\u91ca\u4e86\u4e3a\u4ec0\u4e48\u590d\u5408\u6750\u6599\u5177\u6709\u66f4\u9ad8\u500d\u7387\u6027\u80fd\u3002\u540c\u65f6\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u8bf4\u660e\u590d\u5408\u6750\u6599\u53ef\u4ee5\u88ab\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u3002<\/p>\n

\"\"\u56fe8 (a) 0.1mV s-1<\/sup>\u65f6AC\/\/SnS\/rGO SICs\u4e0d\u540c\u7535\u4f4d\u7a97\u7684CV\u66f2\u7ebf;(b) \u57280.02\u81f35A g-1 <\/sup>\u4e0bAC\/\/SnS\/rGO SICs\u7684\u65f6\u95f4-\u7535\u538b\u56fe;(c) AC\/\/SnS\/rGO SICs\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd;(d) AC\/\/SnS\/rGO\u5728\u00a01A g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u56fe\u00a0(e)\u5f53\u524d\u5de5\u4f5c\u4e0e\u5148\u524d\u62a5\u5230\u5bf9\u6b64\u56fe\u00a0<\/p>\n

\u5c0f\u7ed3<\/strong><\/p>\n

\u4e0a\u8ff0\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u4e8c\u7ef4\u91d1\u5c5e\u786b\u5316\u7269\u8d1f\u6781\u6750\u6599\u901a\u8fc7\u9650\u57df\u751f\u957f\u673a\u5236\uff0c\u53ef\u4fc3\u8fdb\u5f62\u6210\u5f00\u653e\u7684\u4e8c\u7ef4\u8fb9\u7f18\u7ed3\u6784\uff0c\u7f29\u77ed\u4e86\u94a0\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u52a0\u5feb\u94a0\u79bb\u5b50\u5728\u4f53\u76f8\u4e2d\u7684\u79bb\u5b50\u4f20\u8f93\uff1b\u540c\u65f6\u5f15\u5165\u6c27\u7f3a\u9677\uff0c\u53ef\u4ee5\u5236\u9020\u4e30\u5bcc\u7684\u6d3b\u6027\u8fb9\u7f18\uff0c\u4fc3\u8fdb\u94a0\u79bb\u5b50\u7684\u8d5d\u7535\u5bb9\u5b58\u50a8\u80fd\u529b\uff0c\u4ee5\u5f25\u8865\u94a0\u79bb\u5b50\u6269\u6563\u52a8\u529b\u4e0d\u8db3\u7684\u7f3a\u9677\u3002\u8be5\u534f\u540c\u4f5c\u7528\u4e3a\u4e8c\u7ef4\u91d1\u5c5e\u786b\u5316\u7269\u5728\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u672c\u6587\u4ee5\u201cSnS Nanosheets Confined Growth by S and N Codoped Graphenewith Enhanced Pseudocapacitance for Sodium-Ion Capacitors<\/b><\/strong>\u201d\u4e3a\u9898\uff0c\u5728\u7ebf\u53d1\u8868\u5728ACS Applied Materials & Interfaces\uff08DOI: 10.1021\/acsami.9b14098\uff09<\/b><\/strong>\u3002\u672c\u6587\u7684\u5b9e\u9a8c\u5de5\u4f5c\u4e3b\u8981\u7531\u7855\u58eb\u7814\u7a76\u751f\u8bb8\u6d69\u5f00\u5c55\u3002\u5de5\u4f5c\u83b7\u5f97\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0851604250, 51502250, 51474196\uff09\uff0c\u56db\u5ddd\u7701\u79d1\u6280\u5385\u9879\u76ee\uff082019YFG0220, 2016RZ0071, 2017JQ0044\uff09\u7b49\u7684\u8d44\u52a9\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSnS Nanosheets Confined Growth by S and N Codoped Graphene with Enhanced Pseudocapacitance for Sodium-Ion Capacitors. Mingshan Wang,*\u2020 Hao Xu,\u2020 Zhenliang Yang,\u2021 Hua Yang,\u2020 Anmin Peng,\u2020 Jun Zhang,\u2020Junchen Chen,\u2020 Yun Huang,\u2020 Xing Li,*\u2020 and Guozhong Cao*\u00a7.<\/p>\n

https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acsami.9b14098<\/p>\n

\u672c\u6587\u7531\u897f\u5357\u77f3\u6cb9\u5927\u5b66\u674e\u661f\u6559\u6388\u56e2\u961f<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 \u94a0\u79bb\u5b50\u7535\u5bb9\u5668(SIC)\u662f\u4e00\u79cd\u65b0\u578b\u7684\u6df7\u5408\u578b\u7535\u5bb9\u5668\uff0c\u81ea2012\u5e74\u9996\u6b21\u7814\u7a76\u4ee5\u6765\uff0c\u5176\u5de5\u4f5c\u539f\u7406\u662f\u4ee5\u7535\u6c60\u578b\u6750\u6599\u4e3a\u8d1f\u6781\uff0c\u4ee5\u7535\u5bb9\u578b\u6750\u6599(\u5982\u6d3b\u6027\u70ad)\u4e3a\u6b63\u6781\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9634…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-189899","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189899"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=189899"}],"version-history":[{"count":11,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189899\/revisions"}],"predecessor-version":[{"id":190018,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/189899\/revisions\/190018"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=189899"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=189899"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=189899"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}