{"id":190421,"date":"2019-11-21T06:37:31","date_gmt":"2019-11-20T22:37:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=190421"},"modified":"2019-11-20T23:02:51","modified_gmt":"2019-11-20T15:02:51","slug":"%e6%9d%90%e6%96%99%e4%ba%ba%e9%83%bd%e7%88%b1%e4%b8%8d%e9%87%8a%e6%89%8b%e7%9a%84%e7%83%ad%e9%97%a8%e7%a0%94%e7%a9%b6%e9%a2%86%e5%9f%9f-mofs%ef%bd%9c%e8%bf%91%e6%9c%9f%e9%a1%b6%e5%88%8a%e7%a0%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=190421","title":{"rendered":"\u6750\u6599\u4eba\u90fd\u7231\u4e0d\u91ca\u624b\u7684\u70ed\u95e8\u7814\u7a76\u9886\u57df&#8212;-MOFs\uff5c\u8fd1\u671f\u9876\u520a\u7814\u7a76\u901f\u89c8"},"content":{"rendered":"<p>\u8fd1\u4e8c\u5341\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u6750\u6599\u4f5c\u4e3a\u65b0\u5174\u7684\u529f\u80fd\u6750\u6599\uff0c\u53d7\u5230\u4e86\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u9886\u57df\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5b83\u4e0d\u4ec5\u5177\u6709\u7c7b\u4f3c\u6cb8\u77f3\u5206\u5b50\u7b5b\u89c4\u5219\u5b54\u9053\u7684\u6676\u6001\u7ed3\u6784\uff0c\u540c\u65f6\u5177\u6709\u6bd4\u4f20\u7edf\u591a\u5b54\u6750\u6599\u66f4\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u7531\u4e8e\u6709\u673a\u6210\u5206\u7684\u5b58\u5728\u53c8\u4f7f\u5176\u517c\u5177\u53ef\u8bbe\u8ba1\u6027\u3001\u53ef\u526a\u88c1\u6027\u3001\u5b54\u9053\u5c3a\u5bf8\u53ef\u8c03\u8282\u6027\uff0c\u5b54\u9053\u8868\u9762\u6613\u529f\u80fd\u5316\u7b49\u7279\u70b9\u3002\u5728\u73af\u5883\u80fd\u6e90\u6c14\u4f53\u5b58\u50a8\u3001\u5206\u79bb\u3001\u6355\u96c6\uff0c\u836f\u7269\u8f93\u9001\uff0c\u9009\u62e9\u6027\u50ac\u5316\uff0c\u5149\u7535\u78c1\u5b66\uff0c\u624b\u6027\u62c6\u5206\u4ee5\u53ca\u4f20\u611f\u5668\u7b49\u8bf8\u591a\u9886\u57df\u90fd\u8868\u73b0\u51fa\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002\u7b14\u8005\u68b3\u7406\u4e86\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/p>\n<h3><strong><b>1<\/b><\/strong><strong><b>\u00a0\u4e8c\u7ef4\u4f4e\u7845\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4f5c\u4e3a\u591a\u6001\u53ef\u5207\u6362\u6750\u6599\uff5cAngew.<\/b><\/strong><\/h3>\n<p>\u7f8e\u56fd\u7ea6\u7ff0\u970d\u666e\u91d1\u65af\u5927\u5b66V. 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MOFs\u53ef\u4ee5\u5b9e\u73b0\u591a\u79cd\u6676\u6001\u548c\u975e\u6676\u6001\uff0c\u63d0\u4f9b\u4e86\u8d85\u8d8a\u4e8c\u5143\u201c\u5f00\u5173\u201d\u5e94\u7528\u7684\u65b0\u673a\u4f1a\u3002\u6211\u4eec\u5047\u8bbe\u88ab\u5c01\u88c5\u7684\u6eb6\u5242\u7684\u7279\u6027\u548c\u6781\u6027\u51b3\u5b9a\u4e86\u4e8c\u7ef4MOF\u5c42\u7684\u5806\u79ef\u6392\u5217\uff0c\u5404\u79cd\u6676\u4f53\u548c\u975e\u6676MOF\u76f8\u7684\u7ed3\u6784\u8868\u5f81\u88ab\u5b9e\u9a8c\u548c\u8ba1\u7b97\u8bc1\u660e\u3002\u8fd9\u4e9b\u7ed3\u6784\u53d8\u5316\u7684\u9ad8\u53ef\u9006\u6027\u548c\u591a\u79cd\u7a33\u5b9a\u72b6\u6001\u7684\u53ef\u7528\u6027\u5bf9\u5206\u5b50\u4f20\u611f(\u5982\u9187\u7c7b\u3001\u4e9a\u785d\u57fa\u82b3\u70c3\u7b49)\u548c\u5185\u5b58\u5b58\u50a8\u7b49\u5e94\u7528\u5177\u6709\u5438\u5f15\u529b\u3002MOF\u7684\u6a21\u5757\u5316\u548c\u591a\u6837\u6027\u5229\u7528\u4f4e\u7845\u70f7\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\uff0c\u4e3a\u5408\u6210\u4e00\u7c7b\u72ec\u7279\u7684\u6742\u5316\u4f4e\u7845\u6750\u6599\u94fa\u5e73\u4e86\u9053\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201c2D Oligosilyl Metal-Organic Frameworks as Multi-State\u00a0Switchable Materials\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1002\/anie.201912911<\/p>\n<p><strong>\u56fe1\u00a0Cu(lin-Sin) MOFs\u591a\u79cd\u72b6\u6001\u7684\u76f8\u4e92\u8f6c\u6362<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190422 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72471-24.png\" alt=\"\" width=\"680\" height=\"326\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72471-24.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72471-24-300x144.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>2 \u8d85\u7a33\u5b9aMOF\u4f5c\u4e3a\u6355\u83b7CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7684\u6700\u4f18\u9009\u62e9\uff5cAngew.<\/b><\/strong><\/h3>\n<p>\u5728MOF\u7684\u6f14\u5316\u4e2d\u5bf9\u4e8e\u78b3\u7684\u6355\u83b7\uff0c\u662f\u4e00\u4e2a\u6301\u4e45\u7684\u6311\u6218\u3002\u4e3b\u8981\u662f\u5728\u9ad8\u5438\u6536\u80fd\u529b\/\u9009\u62e9\u6027\u548c\u4f4e\u518d\u751f\u80fd\u6e90\u6210\u672c\u4e4b\u95f4\u53d6\u5f97\u5e73\u8861\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8fd9\u4e9b\u4eba\u5de5\u6750\u6599\u5fc5\u987b\u53ef\u4ee5\u5e94\u5bf9\u5b9e\u9645\u9700\u6c42\u4e2d\u7684\u56f0\u96be\uff0c\u4f8b\u5982\u5728\u6076\u52a3\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u548c\u5927\u89c4\u6a21\u5408\u6210\u7684\u53ef\u884c\u6027\u3002\u6c55\u5934\u5927\u5b66\u9ec4\u6653\u6625\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684MOF\uff1aZn(imPim) (aka.\u00a0MOF-stu-1)\uff0c\u5177\u6709\u54aa\u5511\u884d\u751f\u7269\u914d\u4f53\uff0c\u5177\u6709\u53ef\u4ee5\u7c7b\u4f3c\u624b\u5957\u7684\u65b9\u5f0f\u5bb9\u7eb3\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u7684\u201c\u7ed3\u5408\u53e3\u888b\u201d\u3002\u8fd9\u79cd\u9ad8\u5ea6\u7684\u5f62\u72b6\u4e92\u8865\u6027\u4f7f\u5176\u80fd\u591f\u76f4\u63a5\u89c2\u6d4b\u888b\u4e2d\u88c5\u8f7d\u7684\u4e8c\u6c27\u5316\u78b3\uff0c\u5e76\u4fdd\u8bc1\u5176\u6700\u4f73\u7684\u78b3\u6355\u83b7\u6027\u80fd\u8d85\u8fc7\u76ee\u524d\u8868\u73b0\u6700\u597d\u7684MOFs\u3002\u56e0\u5176\u53cc\u87af\u5408\u914d\u4f4d\u6a21\u5f0f\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u4f18\u52bf\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86MAF\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u5c24\u5176\u662f\u6c34\u7a33\u5b9a\u6027\uff09\uff1b\u6b64\u5916\uff0c\u87af\u5408\u914d\u4f4d\u7684\u52a8\u529b\u5b66\u4f18\u52bf\uff0c\u4e5f\u6709\u5229\u4e8e\u5b9e\u73b0\u6750\u6599\u5feb\u901f\u5927\u91cf\u5408\u6210\uff0c\u63d0\u9ad8\u7eaf\u5ea6\u3002MOF-stu-1\u8d85\u8fc7\u4e86\u4ee5\u7a33\u5b9a\u6027\u8457\u79f0\u7684ZIF-8\/MAF-4\u548cUiO-66\u6750\u6599\uff0c\u53d6\u5f97\u4e86\u73b0\u6709MOF\u6750\u6599\u70ed\u7a33\u5b9a\u6027\u7684\u65b0\u7eaa\u5f55(\u9ad8\u4e8e680\u2103)\u3002Zn(imPim)\u662f\u89e3\u51b3\u5f53\u524d\u4e8c\u6c27\u5316\u78b3\u6355\u83b7\u95ee\u9898\u7684\u6700\u5177\u7ade\u4e89\u529b\u7684\u5019\u9009\u6750\u6599\u4e4b\u4e00\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAn Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aAngew. Chem. Int. Ed.,\u00a02019,\u00a058, 16071-16076.<\/p>\n<p><strong>\u56fe2\u00a0Zn(imPim)\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190423 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72472-22.png\" alt=\"\" width=\"680\" height=\"802\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72472-22.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72472-22-254x300.png 254w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>3 Br\u00f8nsted\u9178\u6027MOF-808\u50ac\u5316\u8f7b\u8d28\u70ef\u70c3\u4f4e\u805a<\/b><\/strong><strong><b>\uff5cJ<\/b><\/strong><strong><b>ACS<\/b><\/strong><\/h3>\n<p>\u786b\u9178\u5316\u7684MOF-808 (S-MOF-808)\u5c55\u793a\u4e86\u5f3aBr\u00f8nsted\u9178\u4f4d\u5728\u591a\u76f8\u9178\u50ac\u5316\u65b9\u5411\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u5e38\u5dde\u5927\u5b66\u7684\u5218\u5e73\u6559\u6388\u8054\u5408\u7f8e\u56fd\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u5b9e\u9a8c\u5ba4\u7684Gabor Somorjai\u00a0\u6559\u6388\u53ca\u632a\u5a01\u5965\u65af\u9646\u5927\u5b66\u7684Unni Olsbye\u00a0\u6559\u6388\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u4f4e\u6e29\u5e38\u538b\u4e0b\u8f7b\u8d28\u70ef\u70c3\u5728\u5177\u6709\u8d85\u5f3aBr\u00f8nsted\u9178\u4f4d\u7684MOF-808\u4e0a\u7684\u4f4e\u805a\u53cd\u5e94\u3002\u63ed\u793a\u4e86\u5728\u4f4e\u6e29\u5e38\u538b\u4e0b\u5355\u4e00\u70ef\u70c3\u4f4e\u805a\u53ca\u4e0d\u540c\u70ef\u70c3\u4ea4\u53c9\u8026\u8054\u7684\u53cd\u5e94\u673a\u7406\u3002\u7814\u7a76\u663e\u793a\u4e0d\u540c\u7684\u70ef\u70c3\u5f97\u5230\u4e86\u4e0d\u540c\u7684\u4ea7\u7269(\u4e8c\u805a\u7269\u3001\u540c\u5206\u5f02\u6784\u4f53\u548c\u8f83\u91cd\u7684\u4f4e\u805a\u7269)\uff0c\u8fd9\u8868\u660e\u7a33\u5b9a\u7684\u78b3\u6b63\u79bb\u5b50\u7684\u5f62\u6210\u53ca\u03b1\u4f4d\u53cc\u952e\u7684\u5b58\u5728\u662f\u70ef\u70c3\u4f4e\u805a\u7684\u5173\u952e\u3002\u5bf9\u4e8e\u4e0d\u540c\u70ef\u70c3\u5206\u5b50\u5f02\u4e01\u70ef\u4e0e\u5f02\u620a\u70ef\u7684\u805a\u5408\uff0c\u78b3\u6b63\u79bb\u5b50\u7684\u5f15\u53d1\u5242\u5219\u53ef\u80fd\u6765\u6e90\u4e8e\u5f02\u4e01\u70ef\u3002\u6b64\u5916\uff0c\u8fd8\u7814\u7a76\u4e86S-MOF-808\u7684\u5931\u6d3b\u548c\u518d\u751f\u3002\u50ac\u5316\u5242\u5931\u6d3b\u4e3b\u8981\u901a\u8fc7\u4e24\u79cd\u673a\u7406\u8fdb\u884c\uff0c\u5176\u5931\u6d3b\u673a\u7406\u53d6\u51b3\u4e8e\u5e95\u7269\u548c\u53cd\u5e94\u6761\u4ef6\u3002\u5f53\u6e29\u5ea6\u9ad8\u4e8e110\u2103\u65f6\uff0c\u7531\u4e8e\u6c34\u7684\u8131\u9644\uff0c\u50ac\u5316\u5242\u5931\u53bb\u4e86\u9178\u6027\u4f4d\uff0c\u800c\u5931\u6d3b\u7684\u50ac\u5316\u5242\u53ef\u4ee5\u901a\u8fc7\u7b80\u5355\u7684\u6c34\u84b8\u6c14\u5904\u7406\u6765\u518d\u751f\u3002\u5bf9\u4e8eC5\u5e95\u7269\u548c\u4e0d\u9971\u548c\u919a\uff0c\u5206\u5b50\u91cf\u589e\u52a0\u7684\u4f4e\u805a\u7269\u901a\u8fc7\u963b\u65ad\u6d3b\u6027\u4f4d\u70b9\u5bfc\u81f4\u5931\u6d3b\uff0c\u8fd9\u662f\u4e0d\u5bb9\u6613\u9006\u8f6c\u7684\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u78b3-\u78b3\u4ecb\u5bfc\u7684\u70ef\u70c3\u5185\u5076\u8054\u63d0\u4f9b\u4e86\u7b2c\u4e00\u4e2a\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cOligomerization of Light Olefins Catalyzed by Br\u00f8nsted-Acidic Metal-Organic Framework-808\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aJ. Am. Chem. Soc.,\u00a02019,\u00a0141, 11557-11564.<\/p>\n<p><strong>\u56fe3 \u786b\u9178\u5316S-MOF-808\u524d\u540e\u7ed3\u6784\u53ca\u914d\u4f4d\u6c27\u5316\u9506\u56e2\u7c07\u7684\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190424 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72473-20.png\" alt=\"\" width=\"680\" height=\"721\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72473-20.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72473-20-283x300.png 283w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>4 \u591a\u5143<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e2d\u5b98\u80fd\u56e2\u7684\u5370\u8ff9<\/b><\/strong><strong><b>\u5206\u5e03\uff5cJ<\/b><\/strong><strong><b>ACS<\/b><\/strong><\/h3>\n<p>\u5728\u751f\u7269\u7ec6\u80de\u4e2d\u5e7f\u6cdb\u89c2\u5bdf\u5230\u7684\u590d\u6742\u7684\u5316\u5b66\u8fc7\u7a0b\u9700\u8981\u5bf9\u5efa\u7b51\u5355\u5143\u8fdb\u884c\u7cbe\u786e\u7684\u5206\u914d\u8c03\u8282\uff0c\u8fd9\u6fc0\u53d1\u4e86\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u5177\u6709\u53ef\u63a7\u5f02\u8d28\u6027\u7684\u53ef\u5b9a\u5236\u5efa\u7b51\uff0c\u7528\u4e8e\u590d\u5236\u3001\u8bc6\u522b\u548c\u4fe1\u606f\u5b58\u50a8\u3002\u7136\u800c\uff0c\u5982\u4f55\u8d4b\u4e88\u591a\u5143\u6750\u6599\u5185\u90e8\u5e8f\u5217\u548c\u53ef\u63a7\u7684\u89e3\u6790\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u7f8e\u56fdTexas A&amp;M University\u5468\u5b8f\u624d\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u9884\u5148\u8fde\u63a5\u7684\u53cc\u6709\u673a\u8fde\u63a5\u4f53\u6765\u8c03\u63a7\u5b98\u80fd\u56e2\u7684\u5370\u8ff9\u5206\u5e03\uff0c\u63a2\u7d22\u4e86\u6a21\u677f\u8fde\u63a5\u4f53\u7684\u67d4\u6027\u94fe\u957f\u5ea6\u5bf9\u5b98\u80fd\u56e2\u5728\u591a\u53d8\u91cfMOF\u4e2d\u5206\u5e03\u7684\u5f71\u54cd\u3002\u4f5c\u4e3a\u6982\u5ff5\u9a8c\u8bc1\uff0cZIF-8\u4e2d\u7684\u529f\u80fd\u57fa\u56e2\u5370\u8ff9\u5206\u914d\u662f\u901a\u8fc7\u5c06\u57fa\u4e8e\u4e9a\u80fa\u7684\u94fe\u63a5\u6a21\u677f\u4e0e\u539f\u59cb\u94fe\u63a5\u6a21\u677f\u8fdb\u884c\u4ea4\u6362\u6765\u5b9e\u73b0\u7684\u3002\u6c34\u89e3\u53bb\u9664\u8fde\u63a5\u7247\u6bb5\u53ef\u4ee5\u901a\u8fc7\u5408\u6210\u540e\u7684\u4e0d\u7a33\u5b9a\u6765\u5b9e\u73b0\uff0c\u4ece\u800c\u5f62\u6210\u53ef\u63a7\u5236\u975e\u5747\u8d28\u6027\u7684\u4f53\u7cfb\u7ed3\u6784\u3002\u901a\u8fc7\u5bf9\u8fde\u9501\u94fe\u957f\u5ea6\u7684\u5408\u7406\u63a7\u5236\uff0c\u53ef\u4ee5\u8c03\u6574\u5370\u8ff9MOFs\u4e2d\u5b98\u80fd\u56e2\u7684\u5206\u5e03\uff0c\u5e76\u8fdb\u4e00\u6b65\u901a\u8fc7\u8ba1\u7b97\u65b9\u6cd5\u8fdb\u884c\u5206\u6790\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u7cbe\u786e\u63a7\u5236\u591a\u7ec4\u5206\u6750\u6599\u5185\u90e8\u7684\u5b54\u9699\u73af\u5883\u548c\u529f\u80fd\u5e8f\u5217\u63d0\u4f9b\u4e86\u5408\u6210\u5de5\u5177\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cImprinted Apportionment of Functional Groups in Multivariate Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aJ. Am. Chem. Soc.,\u00a02019,\u00a0141, 14524-14529.<\/p>\n<p><strong>\u56fe4\u00a0\u63a7\u5236\u591a\u5143MOFs\u7684\u5f02\u8d28\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190425 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72474-19.png\" alt=\"\" width=\"680\" height=\"984\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72474-19.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72474-19-207x300.png 207w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>5 <\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u6676\u4f53\u7ed3\u6784\u8f6c\u53d8\u5bf9CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u8fd8\u539f<\/b><\/strong><strong><b>\u7684\u6d3b\u5316\u673a\u7406<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>Matter<\/b><\/strong><\/h3>\n<p>\u5728\u7535\u50ac\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0cCO<sub>2<\/sub>\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u5316\u88ab\u8ba4\u4e3a\u662f\u51b3\u5b9a\u53cd\u5e94\u901f\u7387\u7684\u6b65\u9aa4\uff0c\u56e0\u6b64\u7814\u7a76\u5176\u5438\u9644\u548c\u6d3b\u5316\u673a\u7406\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5170\u4e9a\u4e7e\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e00\u79cd\u7a33\u5b9a\u7684OH\u2013\u914d\u4f4d\u7684MOF\uff08NNU-15\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\u6a21\u578b\uff0c\u6765\u6a21\u62df\u78b1\u6027\u73af\u5883\u4e0b\u50ac\u5316\u5242\u7684\u8868\u9762\u72b6\u6001\uff0c\u5e76\u8fdb\u4e00\u6b65\u63a2\u7a76\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2dCO<sub>2<\/sub>\u7684\u6d3b\u5316\u673a\u5236\u3002NNU-15\u53ef\u9ad8\u9009\u62e9\u6027\u8fd8\u539fCO<sub>2<\/sub>\u751f\u6210CO\uff0c\u5728-0.6V\u65f6\u5176\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe99.2%\uff0c\u50ac\u5316\u65f6\u957f\u53ef\u8fbe\u5230110h\u4ee5\u4e0a\uff0c\u5e76\u4e14\u5728\u8f83\u5bbd\u7535\u4f4d\u8303\u56f4\u5185(-0.6V\u5230-0.9V)\u9009\u62e9\u6027\u4ecd\u53ef\u8d85\u8fc796%\u3002\u5728ECR\uff08\u7535\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\uff09\u8fc7\u7a0b\u4e2d\uff0cNNU-15\u548cNNU-15-CO<sub>2<\/sub>\u4e4b\u95f4\u7684\u5355\u6676\u5230\u5355\u6676\u7684\u8f6c\u5316\u8868\u660e\uff0c\u914d\u4f4d\u7684OH<sup>&#8211;<\/sup>\u53ef\u4ee5\u5c06CO<sub>2<\/sub>\u6d3b\u5316\u6210HCO<sub>3<\/sub><sup>&#8211;<\/sup>\uff0c HCO<sub>3<\/sub><sup>&#8211;<\/sup>\u4e0e\u91d1\u5c5e\u4e2d\u5fc3\u87af\u5408\u3002\u7406\u8bba\u8ba1\u7b97\u9a8c\u8bc1\u4e86\u5728ECR\u8fc7\u7a0b\u4e2d\uff0cO<sup>&#8211;<\/sup>\u5438\u9644\u548cC<sup>&#8211;<\/sup>\u5438\u9644\u7684\u521d\u59cb\u51e0\u4f55\u5f62\u72b6\u90fd\u503e\u5411\u4e8e\u5bfc\u81f4HCO<sub>3<\/sub><sup>&#8211;<\/sup>\u7684\u5f62\u6210\u3002\u76f8\u5173\u7814\u7a76\u201cDisclosing CO<sub>2<\/sub>\u00a0Activation Mechanism by Hydroxyl-Induced Crystalline Structure Transformation in Electrocatalytic Process\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Matter\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1016\/j.matt.2019.07.003<\/p>\n<p><strong>\u56fe5 ECR\u8fc7\u7a0b\u4e2dNNU-15\u8f6c\u5316\u4e3aNNU-15-CO<sub>2<\/sub><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190426 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72475-18.png\" alt=\"\" width=\"680\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72475-18.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72475-18-300x206.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>6 \u6c27\u5316\u8fd8\u539f\u8c03\u6574\u53cc\u91d1\u5c5e<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4ee5\u63d0\u9ad8\u6cd5\u62c9\u7b2c\u7535\u5bb9<\/b><\/strong><strong><b>\uff5cA<\/b><\/strong><strong><b>M<\/b><\/strong><\/h3>\n<p>\u9ad8\u6548\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u662f\u9ad8\u6027\u80fd\u50a8\u80fd\u88c5\u7f6e\u7684\u524d\u6cbf\u7814\u7a76\u65b9\u5411\u3002\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u590f\u5b9d\u7389\u6559\u6388\u8054\u5408\u6210\u5747\u9986\u5927\u5b66Ho Seok Park\u6559\u6388\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u79cd\u6709\u6548\u7684\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u65b9\u6cd5\u6765\u8c03\u6574\u53cc\u91d1\u5c5e\u94b4\/\u954d\u6709\u673a\u6846\u67b6(Co-Ni MOFs)\u7684\u6676\u4f53\u548c\u7535\u5b50\u7ed3\u6784\uff0c\u4ee5\u4fc3\u8fdb\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u6cd5\u62c9\u7b2c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u6240\u5f97\u7684\u94b4\/\u954d\u787c\u5316\u7269\/\u786b\u5316\u7269\u5177\u6709\u9ad8\u7684\u7279\u6b8a\u7535\u5bb9(1281 F g<sup>\u22121<\/sup>\u00a0at 1 A g<sup>\u22121<\/sup>)\uff0c\u663e\u8457\u7684\u901f\u7387\u6027\u80fd(802.9 F g<sup>\u22121<\/sup>\u00a0at 20 A g<sup>\u22121<\/sup>)\uff0c\u4ee5\u53ca\u663e\u8457\u7684\u5faa\u73af\u7a33\u5b9a\u6027(10000\u4e2a\u5faa\u73af\u540e\u7684\u4fdd\u7559\u7387\u4e3a92.1%)\u3002\u91c7\u7528\u94b4\/\u954d\u787c\u5316\u7269\/\u786b\u5316\u7269\u7535\u6781\u5236\u4f5c\u7684\u50a8\u80fd\u88c5\u7f6e\uff0c\u5728\u529f\u7387\u5bc6\u5ea6\u4e3a857.7 W kg<sup>\u22121<\/sup>\u7684\u60c5\u51b5\u4e0b\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u4e3a50.0 Wh kg<sup>\u22121<\/sup>\uff0c\u5e76\u4e14\u5176\u5bb9\u91cf\u4fdd\u6301\u80fd\u529b\u4e3a87.7% (12 A g<sup>\u22121<\/sup>\u53ef\u8fbe5000\u4e2a\u5468\u671f)\u3002\u8fd9\u79cd\u6709\u6548\u7684\u6c27\u5316\u8fd8\u539f\u65b9\u6cd5\u5b9e\u73b0\u4e86\u7cfb\u7edf\u7684\u7535\u5b50\u8c03\u8c10\uff0c\u6fc0\u6d3b\u4e86\u94b4\/\u954d\u787c\u5316\u7269\/\u786b\u5316\u7269\u4e2d\u91d1\u5c5e\u7269\u79cd\u7684\u5feb\u901f\u6cd5\u62c9\u7b2c\u53cd\u5e94\uff0c\u8fd9\u53ef\u80fd\u4e3a\u6fc0\u53d1\u80fd\u91cf\u5b58\u50a8\u88c5\u7f6e\u7684MOFs\u53ca\u5176\u884d\u751f\u7269\u63d0\u4f9b\u91cd\u8981\u7684\u542f\u793a\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cRedox Tuning in Crystalline and Electronic Structure of Bimetal\u2013Organic Frameworks Derived Cobalt\/Nickel Boride\/Sulfde for Boosted Faradaic Capacitance\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aAdv. Mater. 2019, 1905744.<\/p>\n<p><strong>\u56fe6\u00a0\u53cc\u91d1\u5c5eCo-Ni MOFs\u7684\u6d3b\u5316\u65b9\u6cd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190427 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72476-14.png\" alt=\"\" width=\"680\" height=\"283\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72476-14.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72476-14-300x125.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>7 ZIF-8\u819c\u7528\u4e8e\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb<\/b><\/strong><strong><b>\uff5cA<\/b><\/strong><strong><b>FM<\/b><\/strong><\/h3>\n<p>\u7535\u5316\u5b66\u6c89\u79ef\u662f\u5236\u5907MOF\u819c\u7684\u4e00\u79cd\u65b0\u65b9\u6cd5\u3002\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66Zhiping Lai\u6559\u6388\u7b49\u4eba\u9996\u6b21\u63d0\u51fa\u4e86\u4e00\u79cd\u5229\u7528\u6c34\u76f8\u9634\u6781\u6c89\u79ef(ACD)\u6280\u672f\uff0c\u4e0d\u6dfb\u52a0\u4efb\u4f55\u652f\u6301\u7535\u89e3\u8d28\u5236\u5907ZIF-8\u578bMOF\u819c\u7684\u65b9\u6cd5\u3002\u5236\u5907\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u7eaf\u6c34\u4f5c\u4e3a\u552f\u4e00\u6eb6\u5242\uff0c\u5728\u5ba4\u6e29\u4e0b\u53ea\u970060\u5206\u949f\u5373\u53ef\u5f97\u5230\u4f4e\u7f3a\u9677\u5bc6\u5ea6\u7684\u819c\uff0c\u65e0\u9700\u4efb\u4f55\u9884\u5408\u6210\u5904\u7406\u3002\u8be5\u819c\u5728C<sub>3<\/sub>H<sub>6<\/sub>\/C<sub>3<\/sub>H<sub>8<\/sub>\u5206\u79bb\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\uff0c182 GPU C<sub>3<\/sub>H<sub>6<\/sub>\u7684\u901a\u900f\u6027\u548c142\u7684\u9009\u62e9\u6027\uff0c\u4f7f\u5176\u4f4d\u4e8e\u901a\u900f\u6027\u548c\u9009\u62e9\u6027\u56fe\u7684\u4e0a\u754c\uff0c\u622a\u6b622019\u5e74\u8d85\u8fc7\u4e86\u5927\u591a\u6570\u5df2\u53d1\u8868\u7684\u62a5\u9053\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u79cd\u65b9\u6cd5\u4f7f\u7528\u4e86\u6781\u4f4e\u7684\u7535\u6d41\u5bc6\u5ea6(0.13 mA cm<sup>\u22122<\/sup>)\uff0c\u5728\u8d85\u5feb\u901f\u88c5\u7f6e\u4e0b\u8fd0\u884c\uff0c\u4e3a\u73af\u5883\u53cb\u597d\u3001\u8282\u80fd\u3001\u6613\u4e8e\u6269\u5c55\u7684MOF\u819c\u5236\u9020\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u5438\u5f15\u529b\u7684\u65b9\u5f0f\u3002\u672c\u5de5\u4f5c\u8868\u660e\u4e86\u6c34\u76f8\u7535\u5316\u5b66\u6c89\u79efMOF\u819c\u5728\u672a\u6765\u7814\u7a76\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAqueously Cathodic Deposition of ZIF-8 Membranes for Superior Propylene\/Propane Separation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aAdv. Funct. Mater. 2019, 1907089.<\/p>\n<p><strong>\u56fe7\u00a0ZIF-8\u819cACD\u5b9e\u9a8c\u88c5\u7f6e\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190428 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72477-9.png\" alt=\"\" width=\"680\" height=\"446\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72477-9.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72477-9-300x197.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>8 <\/b><\/strong><strong><b>\u5f02\u6784\u5316M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u5149\u50ac\u5316\u5242\u7528\u4e8eC<\/b><\/strong><strong><b>O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u8f6c\u6362\uff5c<\/b><\/strong><strong><b>EES<\/b><\/strong><\/h3>\n<p>\u5149\u50ac\u5316\u5206\u5b50\u7684\u5f02\u6784\u5316\u901a\u5e38\u4ee5\u727a\u7272\u6d3b\u6027\u4e3a\u4ee3\u4ef7\u6765\u589e\u5f3a\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u6765\u7a33\u5b9a\u5206\u5b50\u50ac\u5316\u5242\u800c\u4e0d\u635f\u5bb3\u5176\u539f\u6709\u7684\u50ac\u5316\u7279\u6027\u662f\u975e\u5e38\u5fc5\u8981\u7684\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u97e9\u56fd\u6dd1\u660e\u5973\u5b50\u5927\u5b66Wooyul Kim\u3001Kyung Min Choi\u6559\u6388\u7b49\u4eba\u53d1\u73b0Zr\u57faMOF\u7a33\u5b9a\u4e86\u5149\u50ac\u5316\u5316\u5408\u7269ReTC [Re<sup>I<\/sup>(CO)<sub>3<\/sub>(BPYDC)(Cl)\uff0c BPYDC = 2,2\u2019-\u8054\u5421\u5576-5,5\u2019-\u4e8c\u7fa7\u9178\u76d0]\uff0c\u800c\u6ca1\u6709\u964d\u4f4e\u5176\u50ac\u5316\u6d3b\u6027\u3002ReTC\u88ab\u5316\u5b66\u5730\u7ed1\u5b9a\u5728\u62d6\u628a\u5f0f\u7684\u5206\u79bb\u7b3c\u4e2d\uff0c\u5e76\u88ab\u53d1\u73b0\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u81f3\u5c1124h\u5185\u4fdd\u6301\u5176\u6700\u5927\u7684CO<sub>2<\/sub>&#8211;CO\u8f6c\u6362\u6d3b\u6027(660 h<sup>&#8211;<\/sup><sup>1<\/sup>\u00a0TOF))\u3002\u76f8\u540c\u5316\u5408\u7269(H<sub>2<\/sub>ReTC)\u7684\u81ea\u7531\u5206\u5b50\u5f62\u5f0f\u6700\u521d\u8868\u73b0\u51fa131 h<sup>&#8211;<\/sup><sup>1 <\/sup>TOF\u7684\u6d3b\u6027\uff0c\u4f46\u57282h\u5185\u6d88\u5931\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u53cd\u5e9424 h\u540e\uff0cReTC-MOF\u7684\u7d2f\u79ef\u5468\u8f6c\u6570\u4e3a12847\uff0c\u81ea\u7531\u5206\u5b50\u768442.0\u500d\u3002ReTC-MOF\u5177\u6709\u5f88\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u8fd9\u662f\u56e0\u4e3a\u8fd9\u79cdMOF\u6750\u6599\u4e3aReTC\u7684\u5316\u5b66\u7ed3\u5408\u63d0\u4f9b\u4e86\u4e00\u4e2a\u975e\u5e38\u5c0f\u7684\u6846\u67b6\uff0c\u4f7f\u5f97\u50ac\u5316\u5242\u5728\u53cd\u5e94\u6eb6\u6db2\u4e2d\u53d7\u5230\u4fdd\u62a4\u7684\u540c\u65f6\u5177\u6709\u9ad8\u5ea6\u7684\u8fd0\u52a8\u81ea\u7531\u5ea6\u548c\u589e\u5f3a\u7684\u5149\u5438\u6536\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA highly active, robust photocatalyst heterogenized in discrete cages of metal\u2013organic polyhedral for CO<sub>2<\/sub>\u00a0reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728EES\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aEnergy Environ. Sci DOI: 10.1039\/c9ee02619c<\/p>\n<p><strong>\u56fe8\u00a0\u5149\u50ac\u5316\u5242\u5728MOF\u4e0a\u7684\u5f02\u6784\u5316\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190429 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72478-9.png\" alt=\"\" width=\"680\" height=\"403\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72478-9.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72478-9-300x178.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<h3><strong><b>9<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u7528\u975e\u6676M<\/b><\/strong><strong><b>OF\u6765\u5305\u88c5\u548c\u8fd0\u8f93\u9176<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>ature<\/b><\/strong><strong><b>\u00a0C<\/b><\/strong><strong><b>o<\/b><\/strong><strong><b>mmunications<\/b><\/strong><\/h3>\n<p>\u6d3b\u7ec6\u80de\u7684\u9176\u50ac\u5316\u53ef\u4ee5\u539f\u4f4d\u68c0\u6d4b\u5355\u4e2a\u7ec6\u80de\u7684\u7ec6\u80de\u4ee3\u8c22\u7269\uff0c\u6709\u52a9\u4e8e\u75be\u75c5\u7684\u65e9\u671f\u8bca\u65ad\u3002\u5929\u6d25\u5927\u5b66\u7684\u5f20\u9e9f\u6559\u6388\u53ca\u6e05\u534e\u5927\u5b66\u9b4f\u97e1\u6559\u6388\u7b49\u8054\u5408\u4e2d\u56fd\u79d1\u5b66\u9662\u5de5\u827a\u5de5\u7a0b\u7814\u7a76\u6240\u5728\u73af\u5883\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u4e00\u9505\u5171\u6c89\u6dc0\u6cd5\u5c06\u9176\u5305\u88f9\u5728\u65e0\u5b9a\u5f62\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6(MOFs)\u4e2d\uff0c\u5176\u8868\u89c2\u6d3b\u6027\u662f\u5305\u88f9\u5728\u76f8\u5e94\u6676\u4f53MOFs\u4e2d\u76845-20\u500d\u3002\u5206\u5b50\u6a21\u62df\u548c\u4f4e\u6e29\u7535\u5b50\u65ad\u5c42\u626b\u63cf(Cryo-ET)\u7b49\u6280\u672f\u7684\u7ed3\u5408\u8868\u660e\uff0c\u5728\u8fd9\u79cd\u65e0\u5e8f\u548c\u6a21\u7cca\u7684\u7ed3\u6784\u4e2d\u4ea7\u751f\u7684\u4e2d\u5b54\u8d4b\u4e88\u4e86\u5305\u88f9\u9176\u8f83\u9ad8\u7684\u9176\u6d3b\u6027\u3002\u7531\u65e0\u5b9a\u5f62\u7ed3\u6784\u4f20\u9012\u7684\u9ad8\u6d3b\u6027\u8461\u8404\u7cd6\u6c27\u5316\u9176MOF\u7eb3\u7c73\u9897\u7c92\u53ef\u4ee5\u5bf9\u5355\u4e2a\u6d3b\u7ec6\u80de\u4e2d\u7684\u8461\u8404\u7cd6\u8fdb\u884c\u65e0\u521b\u3001\u7b80\u4fbf\u7684\u6d4b\u91cf\uff0c\u4ece\u800c\u7528\u6765\u533a\u5206\u764c\u7ec6\u80de\u548c\u6b63\u5e38\u7ec6\u80de\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cPackaging and delivering enzymes by amorphous metal-organic frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Communications\u4e0a\u3002<\/p>\n<p><strong><b>\u6587<\/b><\/strong>\u732e\u94fe\u63a5:<strong><b>\u00a0<\/b><\/strong>Nature Communications.2019,10,5165 https:\/\/doi.org\/10.1038\/s41467-019-13153-x<\/p>\n<p><strong>\u56fe9\u00a0\u542b\u9176\u590d\u5408\u6750\u6599\u7684\u7ed3\u6784\u7279\u5f81<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190430 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72479-5.png\" alt=\"\" width=\"680\" height=\"362\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72479-5.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u72479-5-300x160.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/b><\/strong><\/p>\n<h3><strong><b>10 \u94dc\u57fa<\/b><\/strong><strong><b>MOF<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong>SO<sub>2<\/sub><strong><b>\u7684\u53ef\u9006\u914d\u4f4d\u7ed3\u5408\u4e0e\u5206\u79bb\uff5c<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>a<\/b><\/strong><strong><b>ture Materials<\/b><\/strong><\/h3>\n<p>\u70df\u6c14\u548c\u6d77\u6d0b\u8fd0\u8f93\u6392\u653e\u7684SO<sub>2<\/sub>\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u6709\u4e0d\u5229\u5f71\u54cd\uff0c\u4f46\u5982\u679c\u80fd\u591f\u6709\u6548\u5730\u56de\u6536\u3001\u50a8\u5b58\u548c\u8fd0\u8f93\uff0cSO<sub>2<\/sub>\u4e5f\u662f\u91cd\u8981\u7684\u5de5\u4e1a\u539f\u6599\u3002\u5728\u8fd9\u91cc, \u82f1\u56fd\u8bfa\u4e01\u6c49\u5927\u5b66\u7684Sihai Yang\u200a\u6559\u6388\u53caMartin Schr\u00f6der\u200a\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u7279\u6b8a\u5438\u9644\u548c\u5206\u79bbSO<sub>2<\/sub>\u7684\u591a\u5b54\u6750\u6599,[Cu<sub>2<\/sub>\u00a0(L)] (H<sub>4<\/sub>L = 4\u2032, 4\u2034- (pyridine-3,5-diyl) bis([1,1\u2019-biphenyl)3,5 -dicarboxylic acid))\uff1aMFM-170\u3002MFM-170\u5728298k\u30011.0 bar\u6761\u4ef6\u4e0b\u5b8c\u5168\u53ef\u9006\u5730\u5438\u6536\u4e8617.5 mmol g<sup>\u22121<\/sup>\u7684SO<sub>2<\/sub>\uff0c\u5e76\u4e14\u5df2\u7ecf\u786e\u5b9a\u4e86MFM-170\u4e2d\u88ab\u6355\u83b7\u5206\u5b50\u7684SO<sub>2<\/sub>\u7ed3\u5408\u57df\u3002\u6211\u4eec\u62a5\u9053\u4e86SO<sub>2<\/sub>\u4e0eCu(ii)\u4f4d\u70b9\u7684\u53ef\u9006\u914d\u4f4d\uff0c\u8fd9\u6709\u52a9\u4e8e\u7406\u89e3MFM-170\u5728\u89e3\u5438\u540e\u5bf9SO<sub>2<\/sub>\u7684\u5438\u9644\u70ed\u529b\u5b66\u548c\u9009\u62e9\u6027\uff0c\u4ee5\u53ca\u65b9\u4fbf\u7684\u518d\u751f\u3002MFM-170\u5bf9\u6c34\u3001\u9178\u3001\u78b1\u7a33\u5b9a\uff0c\u5728\u6a21\u62df\u70df\u6c14\u6df7\u5408\u7269\u4e2d\u52a8\u6001\u5206\u79bbSO<sub>2<\/sub>\u65b9\u9762\u5177\u6709\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cReversible coordinative binding and separation of sulfur dioxide in a robust metal\u2013organic framework with open copper sites\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41563-019-0495-0.<\/p>\n<p><strong>\u56fe10 1.0 bar\u548c298k\u4e0bSO<sub>2<\/sub>\u5438\u6536\u5bf9\u6bd4<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-190431 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u724710-4.png\" alt=\"\" width=\"680\" height=\"398\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u724710-4.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/11\/\u56fe\u724710-4-300x176.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~~<\/p>\n<p>\u672c\u6587\u7531<strong>Junas<\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd1\u4e8c\u5341\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u6750\u6599\u4f5c\u4e3a\u65b0\u5174\u7684\u529f\u80fd\u6750\u6599\uff0c\u53d7\u5230\u4e86\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u9886\u57df\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5b83\u4e0d\u4ec5\u5177\u6709\u7c7b\u4f3c\u6cb8\u77f3\u5206\u5b50\u7b5b\u89c4\u5219\u5b54\u9053\u7684\u6676\u6001\u7ed3\u6784\uff0c\u540c\u65f6\u5177\u6709\u6bd4\u4f20\u7edf\u591a\u5b54\u6750\u6599&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":182227,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-190421","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/190421"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=190421"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/190421\/revisions"}],"predecessor-version":[{"id":190546,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/190421\/revisions\/190546"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/182227"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=190421"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=190421"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=190421"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}