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\u4e00<\/b><\/strong>\u3001<\/b><\/strong>\u524d\u8a00<\/b><\/strong><\/h3>\n

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\uff08\u4e8c\uff09\u6d3b\u6027\u5224\u522b<\/strong><\/p>\n

\uff081\uff09\u4e92\u65a5\u89c4\u5219<\/p>\n

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\uff082\uff09\u4e92\u5141\u89c4\u5219<\/p>\n

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\uff08\u4e09\uff09\u68c0\u6d4b\u4eea\u5668<\/strong><\/p>\n

1\uff09\u7ea2\u5916\u5149\u8c31<\/p>\n

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2\uff09\u62c9\u66fc\u5149\u8c31<\/p>\n

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\uff08\u56db\uff09\u5f02\u540c\u70b9<\/strong><\/p>\n

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2\uff09\u4e0d\u540c\u70b9<\/p>\n

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\uff088\uff09\u62c9\u66fc\u5149\u8c31\u548c\u7ea2\u5916\u5149\u8c31\u591a\u6570\u65f6\u5019\u76f8\u4e92\u8865\u5145\uff0c\u5373\uff1a\u7ea2\u5916\u5f3a\uff0c\u62c9\u66fc\u5f31\u3002\u7ea2\u5916\u5f31\uff0c\u62c9\u66fc\u5f3a\u3002<\/p>\n

\uff089\uff09\u7ea2\u5916\u5149\u8c31\u9274\u5b9a\u6709\u673a\u7269\u66f4\u4f18\uff0c\u800c\u62c9\u66fc\u5149\u8c31\u5728\u63d0\u9ad8\u65e0\u673a\u5316\u5408\u7269\u4fe1\u606f\u65f6\u66f4\u5168\u9762\u3002<\/p>\n

\uff0810\uff09\u7ea2\u5916\u5149\u8c31\u89e3\u6790\uff1a\u4e09\u8981\u7d20\uff08\u5438\u6536\u9891\u7387\u3001\u5f3a\u5ea6\u3001\u5cf0\u5f62\uff09\u3002\u62c9\u66fc\u5149\u8c31\u89e3\u6790\u9664\u4e86\u6709\u4e09\u8981\u7d20\u5916\uff0c\u8fd8\u6709\u53bb\u504f\u632f\u5ea6\u3002<\/p>\n

\u4e09\u3001\u5b9e\u4f8b\u5206\u6790<\/b><\/strong><\/h3>\n

\uff08\u4e00\uff09\u5b9e\u4f8b1[<\/sup>1]<\/sup>\u00a0<\/strong><\/p>\n

\u6587\u732e\u5bfc\u8bfb\uff1a\u4f5c\u8005\u901a\u8fc7\u4e00\u6b65\u70ed\u89e3\u6cd5\u5408\u6210\u4e86\u5305\u88f9Fe3<\/sub>C\u7eb3\u7c73\u7c92\u5b50\u7684\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\uff08Fe3<\/sub>C@NCNTs\uff09\uff0c\u5bf9\u4e0d\u540c\u6e29\u5ea6\u5408\u6210\u7684\u6750\u6599\u8fdb\u884c\u5bf9\u6bd4\u8868\u5f81\u3002\u5229\u7528\u5408\u6210\u50ac\u5316\u5242\u6d3b\u5316\u8fc7\u786b\u9178\u76d0\uff08PS\uff09\u964d\u89e3\u6297\u751f\u7d20\u78fa\u80fa\u7532\u6076\u5511 (SMX)\uff0c\u5e76\u5bf9\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u63a2\u7a76\u548c\u9610\u91ca\u3002<\/p>\n

\u56fe1 \u00a0600-1000 \u2103\u5408\u6210\u7684Fe3<\/sub>C@NCNTs\u7684\u62c9\u66fc\u5149\u8c31<\/p>\n

\"\"<\/p>\n

\u56fe2 \u00a0600-1000 \u2103\u5408\u6210\u7684Fe3<\/sub>C@NCNTs\u7684FTIR\u7ea2\u5916\u5149\u8c31<\/p>\n

\"\"<\/p>\n

\u89e3\u6790\uff1a\u4f5c\u8005\u901a\u8fc7\u62c9\u66fc\u5149\u8c31\uff08\u56fe1\uff09\u8868\u5f81\u5408\u6210\u6750\u6599\u7684\u7ed3\u6784\u7279\u5f81\u53ca\u77f3\u58a8\u5316\u7a0b\u5ea6\u3002D\u5e26\u53cd\u6620\u78b3\u4e2d\u7684sp3<\/sup>\u7f3a\u9677\uff08\u4f8b\u5982\u77f3\u58a8\u70ef\u7684\u65e0\u5b9a\u578b\u78b3\u5c42\u3001\u8fb9\u7f18\u7b49\uff09\uff0c\u800cG\u5e26\u53cd\u6620sp2<\/sup>\u6742\u5316\u77f3\u58a8\u5316\u78b3\u539f\u5b50\u7684E2g<\/sub>\u632f\u52a8\u3002\u6240\u4ee5\uff0cD\u5e26\u548cG\u5e26\u7684\u5f3a\u5ea6\u6bd4ID<\/sub>\/IG<\/sub>\u503c\u8d8a\u9ad8\uff0c\u5219\u7f3a\u9677\u7a0b\u5ea6\u8d8a\u9ad8\uff0c\u77f3\u58a8\u5316\u7a0b\u5ea6\u8d8a\u4f4e\u3002\u9996\u5148\uff0c\u6240\u6709\u6837\u54c1\u5728D\u5e26(~1350 cm\u22121<\/sup>)\u548cG\u5e26(~1588 cm\u22121<\/sup>)\u5747\u663e\u793a\u4e24\u4e2a\u660e\u663e\u7684\u5cf0\u3002\u7ed3\u5408\u56fe\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5f97\u51fa\uff0cFe3<\/sub>C@NCNTs-800\u7684ID<\/sub>\/IG<\/sub>\u503c\u6700\u4f4e\uff080.86\uff09\uff0c\u8868\u660e\u5176\u5177\u6709\u6700\u5b8c\u5168\u7684sp2<\/sup>\u6742\u5316\u7ed3\u6784\uff0c\u8fd9\u53ef\u80fd\u4e0e\u5176\u5bfc\u7535\u6027\u6709\u5173\u3002\u62c9\u66fc\u5149\u8c31\u4e2d\u76842D\u5cf0(2705 cm\u22121<\/sup>)\u662f\u77f3\u58a8\u70ef\u6750\u6599\u53e6\u4e00\u4e2a\u503c\u5f97\u6ce8\u610f\u7684\u7279\u5f81\uff0c\u4ece\u5176\u4f4d\u7f6e\u548c\u5f62\u72b6\u53ef\u4ee5\u9274\u522b\u5206\u5c42\u60c5\u51b5\u3002\u5728700-1000 \u2103\u6e29\u5ea6\u4e0b\u7119\u70e7\u7684\u6240\u6709Fe3C@NCNTs\u6837\u54c1\u5747\u5177\u6709\u5bbd2D\u5cf0\uff0c\u610f\u5473\u7740\u5b58\u5728\u5c11\u5c42\u7ed3\u6784\u3002\u7efc\u4e0a\u6240\u8ff0\uff0c\u70ed\u89e3\u6e29\u5ea6\u8f83\u4f4e\u6216\u8f83\u9ad8\u65f6\uff0c\u5747\u4e0d\u80fd\u5f62\u6210\u5177\u6709\u826f\u597dsp2<\/sup>\u7ed3\u6784\u78b3\u7eb3\u7c73\u7ba1\uff0c\u5373\u9700\u8981\u9002\u5f53\u7684\u7145\u70e7\u6e29\u5ea6\u4ee5\u5f62\u6210\u5b8c\u6574\u7684\u77f3\u58a8\u70ef\u7ed3\u6784\u3002\u4eceFTIR\u7ea2\u5916\u5149\u8c31\uff08\u56fe2\uff09\u8fd8\u68c0\u6d4b\u5230\u542b\u6c27\u5b98\u80fd\u56e2\u3002\u5f53\u7145\u70e7\u6e29\u5ea6\u4ece600 \u2103\u5347\u9ad8\u52301000 \u2103\u65f6\uff0c\u9664C=C\u5cf0\u4e4b\u5916\uff0c\u5176\u4ed6\u56db\u4e2a\u5cf0\u5747\u53d8\u5f31\uff0c\u8868\u660e\u4f34\u968f\u7740\u77f3\u58a8\u70ef\u7ed3\u6784\u7684\u6f14\u53d8\uff0c\u4e0d\u7a33\u5b9a\u7684O\u548cN\u7269\u79cd\u53d1\u751f\u5206\u89e3\u3002<\/p>\n

\uff08\u4e8c\uff09\u5b9e\u4f8b2[<\/sup>2]<\/sup><\/strong><\/p>\n

\u6587\u732e\u5bfc\u8bfb\uff1a\u4f5c\u8005\u5236\u5907\u77f3\u58a8\u70ef\u8d1f\u8f7dCuO\u6750\u6599\uff0c\u63a2\u7a76\u4e86\u77f3\u58a8\u70ef\u5bf9CuO\u7eb3\u7c73\u7ed3\u6784\u7684\u7ed3\u6784\u3001\u5149\u5b66\u548c\u58f0\u5b50\u6027\u8d28\u7684\u5f71\u54cd\u3002\u7814\u7a76\u548c\u8ba8\u8bba\u4e0d\u540c\u77f3\u58a8\u70ef\u8d1f\u8f7d\u91cf\u4e0b\uff0c\u590d\u5408\u6750\u6599\u7eb3\u7c73\u7ed3\u6784\u5f62\u8c8c\u3001\u6676\u7c92\u5c3a\u5bf8\u548c\u5e26\u9699\u7684\u53d8\u5316\uff0c\u5e76\u901a\u8fc7\u5904\u7406\u67d3\u6599\u5e9f\u6c34\u5bf9\u5236\u5907\u6750\u6599\u8fdb\u884c\u76f4\u63a5\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n

\u56fe3\u00a0\u00a0\u77f3\u58a8\u70ef\u8d1f\u8f7dCuO\u6750\u6599<\/p>\n

\"\"<\/p>\n

(a) FTIR\u7ea2\u5916\u5149\u8c31\uff1b(b)\u58f0\u5b50\u8c31\u3002\uff08\u6ce8\uff1a\u201cC\u201d\u6307CuO\uff0c\u201cGCXX\u201d\u4e2d\u6570\u5b57\u4ee3\u8868\u590d\u5408\u6750\u6599CuO\u524d\u9a71\u4f53\u7684\u8d28\u91cf\u5206\u6570\uff09<\/p>\n

\u56fe4<\/p>\n

\"\"<\/p>\n

\u00a0(a)\u00a0\u77f3\u58a8\u70ef\u8d1f\u8f7dCuO\u62c9\u66fc\u5149\u8c31\uff1b(b) G\u5e26\u548c(c) 2D\u5e26\u7684\u58f0\u5b50\u80fd\u5e26\u4f4d\u7f6e\u548c\u58f0\u5b50\u5f3a\u5ea6\uff1b(d) G\u5e26\u548c2D\u5e26\u7684\u589e\u5f3a\u56e0\u5b50<\/p>\n

\u89e3\u6790\uff1a\u901a\u8fc7\u5206\u6790FTIR\u7ea2\u5916\u5149\u8c31\u548c\u62c9\u66fc\u5149\u8c31\uff0c\u63a2\u7a76\u4e86\u5408\u6210\u7eb3\u7c73\u6750\u6599\u7684\u58f0\u5b50\u6027\u8d28\u3002\u53ef\u4ee5\u5f97\u51fa\uff1a\u6676\u7c92\u5c3a\u5bf8\u7684\u589e\u52a0\u5bfc\u81f4\u4f1aCuO\u4e2d\u81ea\u65cb-\u58f0\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u589e\u5f3a\uff0c\u53d7\u5230\u5f3a\u81ea\u65cb-\u58f0\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u5f71\u54cd\uff0c\u9009\u62e9\u5b9a\u5219\u4f1a\u53d1\u751f\u677e\u5f1b\uff1b\u89c2\u5bdf\u5230\u7684CuO\u7684\u591a\u58f0\u5b50\u662f\u7531\u4e8eCuO\u7eb3\u7c73\u7ed3\u6784\u7684\u5f62\u8c8c\u6539\u6027\u4f7f\u9009\u62e9\u5b9a\u5219\u677e\u5f1b\u6240\u81f4\uff1b\u77f3\u58a8\u70ef\u7684\u5b58\u5728\u5bf9CuO\u5404\u58f0\u5b50\u80fd\u5e26\u4f4d\u7f6e\u548c\u5f3a\u5ea6\u6709\u8f7b\u5fae\u7684\u5f71\u54cd\u3002<\/p>\n

\uff08\u4e09\uff09\u5b9e\u4f8b3[<\/sup>3]<\/sup><\/strong><\/p>\n

\u6587\u732e\u5bfc\u8bfb\uff1a\u672c\u6587\u7efc\u8ff0\u4e86\u62c9\u66fc\u5149\u8c31\u68c0\u6d4b\u5fae\u5851\u6599(<\u00a020 \u03bcm)\u7684\u73b0\u72b6\u53ca\u4f18\u7f3a\u70b9\uff0c\u5e76\u4e0e\u5176\u4ed6\u68c0\u6d4b\u6280\u672f\u4f5c\u6bd4\u8f83\uff08\u5982\u7ea2\u5916\u5149\u8c31\uff09\u3002<\/p>\n

\u56fe5\u00a0\u00a0\u805a\u4e19\u70ef<\/p>\n

\"\"<\/p>\n

(a)\u62c9\u66fc\u56fe\u50cf(\u5de6)\u548c\u7ea2\u5916\u56fe\u50cf(\u53f3)\uff1b(b)\u62c9\u66fc\u5149\u8c31(\u5de6)\u548c\u7ea2\u5916\u900f\u5c04\u5149\u8c31(\u53f3)<\/p>\n

\u89e3\u6790\uff1a\u4e3a\u4e86\u9a8c\u8bc1\u7ea2\u5916\u5149\u8c31\u548c\u62c9\u66fc\u6210\u50cf\u7684\u6709\u6548\u6027\uff0c\u4f5c\u8005\u5bf9\u5c3a\u5bf8<\u00a0400\u00a0\u03bcm\u7684\u6d77\u6d0b\u5fae\u5851\u6599\u6837\u54c1\u8fdb\u884c\u7eaf\u5316\u3001\u8fc7\u6ee4\uff0c\u9009\u53d61000\u00a0\u00d7 1000\u00a0\u03bcm\u7684\u6ee4\u5149\u7247\u8fdb\u884c\u62c9\u66fc\u6210\u50cf\u548cFTIR\u900f\u5c04\u6210\u50cf\u5206\u6790\uff0c\u5e76\u5bf9\u4e24\u79cd\u5149\u8c31\u6d4b\u91cf\u7684\u7ed3\u679c\u8fdb\u884c\u6bd4\u8f83\uff0c\u5305\u62ec\u53ef\u68c0\u6d4b\u5fae\u5851\u6599\u6570\u91cf\u3001\u7c7b\u578b\u548c\u5c3a\u5bf8\u4ee5\u53ca\u5149\u8c31\u8d28\u91cf\u3001\u5904\u7406\u548c\u6d4b\u91cf\u65f6\u95f4\u3002\u56fe5b\u663e\u793a\u5c3a\u5bf8\u8f83\u5c0f\uff0815-20 \u03bcm\uff09\u805a\u4e19\u70ef\uff08PP\uff09\u9897\u7c92\u5149\u8c31\uff0c\u6e05\u6670\u7684\u62c9\u66fc\u5149\uff08\u5de6\uff09\u4e0e\u5f31\u4e14\u6709\u566a\u58f0\u7684\u7ea2\u5916\u5149\u8c31(\u53f3)\u5f62\u6210\u5bf9\u6bd4\u3002\u5bf9\u4e8e\u7ea2\u5916\u5149\u8c31\uff0c\u7531\u4e8e\u9897\u7c92\u7684\u5c3a\u5bf8\u63a5\u8fd1\u7ea2\u5916\u663e\u5fae\u5149\u8c31\u7684\u6a2a\u5411\u5206\u8fa8\u7387\u548c\u884d\u5c04\u6781\u9650\uff0c\u5bfc\u81f4\u8f83\u4f4e\u4fe1\u566a\u6bd4\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u68c0\u6d4b\u7684\u7ea2\u5916\u5149\u8c31\u53ef\u80fd\u662f\u6765\u81ea\u76ee\u6807\u68c0\u6d4b\u7269\u548c\u76f8\u90bb\u9897\u7c92\u6df7\u5408\u7269\u7684\u5149\u8c31\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u540c\u4e00\u7c92\u5b50\u7684\u62c9\u66fc\u5149\u8c31\u663e\u793a\u51fa\u8f83\u597d\u7684PP\u5149\u8c31\uff0c\u867d\u7136\u62c9\u66fc\u4fe1\u53f7\u5f3a\u5ea6\u76f8\u5bf9\u8f83\u4f4e\uff0c\u4f46\u4fe1\u566a\u6bd4\u660e\u663e\u63d0\u9ad8\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/h3>\n

[1]\u00a0Shang Y, Chen C, Zhang P, et al. Removal of sulfamethoxazole from water via activation of persulfate by Fe3C@ NCNTs including mechanism of radical and nonradical Process[J]. Chemical Engineering Journal, 2019: 122004.<\/p>\n

[2]\u00a0Araujo C F, Nolasco M M, Ribeiro A M P, et al. Identification of microplastics using Raman spectroscopy: latest developments and future prospects[J]. Water research, 2018, 142: 426-440.<\/p>\n

[3] Araujo C F, Nolasco M M, Ribeiro A M P, et al. Identification of microplastics using Raman spectroscopy: latest developments and future prospects[J]. Water research, 2018, 142: 426-440.<\/p>\n

[4]\u00a0\u5b59\u732e\u6587. \u6709\u5e8f\u94f6\u7eb3\u7c73\u7ebf\u9635\u5217\u548c\u2018\u5316\u5b66\u7eaf\u2019\u94f6\u80f6\u7684\u5236\u5907\u53ca\u5176SERS\u5e94\u7528[D]. \u6cb3\u5357\u5927\u5b66, 2003.<\/p>\n

[5]\u00a0\u6768\u91d1\u6885, \u5f20\u6d77\u660e, \u738b\u65ed, et al. \u7ea2\u5916\u5149\u8c31\u548c\u62c9\u66fc\u5149\u8c31\u7684\u8054\u7cfb\u548c\u533a\u522b[J]. \u7269\u7406\u4e0e\u5de5\u7a0b, 2014, 24(4):26-29.<\/p>\n

[6]\u00a0\u6731\u660e\u534e \u80e1\u576a. \u4eea\u5668\u5206\u6790(\u7b2c4\u7248)(BZ)[M]. \u9ad8\u7b49\u6559\u80b2\u51fa\u7248\u793e, 2009.<\/p>\n

\u672c\u6587\u7531whuchx<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u76f8\u5173\u8bfe\u7a0b<\/strong><\/p>\n

\u6750\u6599\u4eba\u5df2\u5f00\u8bbe\u62c9\u66fc\u5206\u6790\u548c\u7ea2\u5916\u5149\u8c31\u5206\u6790\u7ebf\u4e0a\u8bb2\u5ea7\uff0c\u60f3\u8981\u4e86\u89e3\u66f4\u591a\u66f4\u5168\u9762\u7684\u7ea2\u5916\u548c\u62c9\u66fc\u7684\u76f8\u5173\u77e5\u8bc6\uff0c\u8bf7\u4e0b\u8f7d\u6750\u6599\u4ebaAPP\uff0c\u5b66\u4e60\u76f8\u5173\u8bfe\u7a0b\u3002<\/p>\n

\"\"<\/p>\n

\u626b\u7801\u4e0b\u8f7d\u6750\u6599\u4ebaAPP<\/p>\n

\u62c9\u66fc\u5206\u6790\u8bb2\u5ea7<\/strong><\/p>\n

\u8bfe\u7a0b\u5185\u5bb9<\/p>\n

\u7b2c\u4e00\u8bb2 \u62c9\u66fc\u5149\u8c31\u57fa\u7840\u77e5\u8bc6\u53ca\u80cc\u666f\u7b80\u4ecb<\/p>\n

\u7b2c\u4e8c\u8bb2 \u62c9\u66fc\u5149\u8c31\u7684\u5de5\u4f5c\u539f\u7406\u53ca\u4eea\u5668\u7ed3\u6784<\/p>\n

\u7b2c\u4e09\u8bb2 \u62c9\u66fc\u5149\u8c31\u6837\u54c1\u5236\u5907\uff0c\u6570\u636e\u91c7\u96c6\u53ca\u5206\u6790<\/p>\n

\u7b2c\u56db\u8bb2 \u62c9\u66fc\u5149\u8c31\u5e94\u7528\u5b9e\u4f8b<\/p>\n

\u542c\u8bfe\u65b9\u6cd5<\/p>\n

\u6750\u6599\u4ebaAPP\u5185\u641c\u7d22\u201c\u62c9\u66fc\u201d\u3002<\/p>\n

\u7ea2\u5916\u5206\u6790\u8bb2\u5ea7<\/strong><\/p>\n

\u8bfe\u7a0b\u5185\u5bb9<\/p>\n

\u7b2c\u4e00\u8bb2 \u7ea2\u5916\u5438\u6536\u5149\u8c31\u6cd5\u6982\u8ff0<\/p>\n

\u7b2c\u4e8c\u8bb2 \u7ea2\u5916\u5438\u6536\u5149\u8c31\u7684\u57fa\u672c\u539f\u7406<\/p>\n

\u7b2c\u4e09\u8bb2\u00a0\u57fa\u56e2\u9891\u7387\u548c\u7279\u5f81\u5438\u6536\u5cf0<\/p>\n

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