{"id":191700,"date":"2019-12-14T06:02:40","date_gmt":"2019-12-13T22:02:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=191700"},"modified":"2019-12-13T00:15:40","modified_gmt":"2019-12-12T16:15:40","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e5%88%98%e9%94%b4acs-nano-%e5%ba%94%e7%94%a8%e4%ba%8e%e6%a8%aa%e5%90%91%e5%92%8c%e5%9e%82%e7%9b%b4%e7%94%b5%e5%ad%90%e5%99%a8%e4%bb%b6%e7%9a%84%e5%8f%8c%e5%8a%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=191700","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u5218\u9534ACS Nano \u5e94\u7528\u4e8e\u6a2a\u5411\u548c\u5782\u76f4\u7535\u5b50\u5668\u4ef6\u7684\u53cc\u529f\u80fdNbS2\u57fa\u975e\u5bf9\u79f0\u5f02\u8d28\u7ed3"},"content":{"rendered":"<p><strong>\u5f15\u8a00<\/strong><\/p>\n<p>\u91d1\u5c5e\u6027\u7684\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u786b\u65cf\u5316\u5408\u7269\uff08TaS<sub>2<\/sub>, VS<sub>2<\/sub>, NbSe<sub>2<\/sub>, NbS<sub>2<\/sub>, TiSe<sub>2<\/sub>\u7b49\uff09\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5bfc\u7387\u3001\u5b58\u5728\u4e8c\u7ef4\u8d85\u5bfc\u3001\u7535\u8377\u5bc6\u5ea6\u6ce2\u7b49\u65b0\u5947\u7684\u7269\u6027\u4ee5\u53ca\u9762\u5185\u50ac\u5316\u6d3b\u6027\u7b49\u4f18\u52bf\u800c\u5728\u4e8c\u7ef4\u7535\u5b50\u5668\u4ef6\u3001\u7535\u5316\u5b66\u5668\u4ef6\u7b49\u8868\u73b0\u51fa\u4e86\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u7136\u800c\u6b64\u7c7b\u6750\u6599\u5728\u7a7a\u6c14\u4e2d\u8fdb\u884c\u8f6c\u79fb\u548c\u5668\u4ef6\u52a0\u5de5\u8fc7\u7a0b\u4e2d\uff0c\u5176\u8868\u9762\u4f1a\u8fc5\u901f\u751f\u6210\u6570\u7eb3\u7c73\u539a\u7684\u5929\u7136\u6c27\u5316\u5c42\uff0c\u4ece\u800c\u5728\u5668\u4ef6\u5e94\u7528\u4e2d\u4ea7\u751f\u63a5\u89e6\u95ee\u9898\u5e76\u964d\u4f4e\u5668\u4ef6\u6027\u80fd\u3002 <\/p>\n<p> <strong>\u6210\u679c\u7b80\u4ecb<br \/>\n <\/strong><br \/>\n \u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u5218\u9534\u8bfe\u9898\u7ec4\u5728\u5355\u5c42MoS<sub>2<\/sub>\u4e0a\u5916\u5ef6\u751f\u957fNbS<sub>2<\/sub>\u4ece\u800c\u5b9e\u73b0\u4e86\u5bf9NbS<sub>2<\/sub>\u5e95\u9762\u7684\u539f\u4f4d\u4fdd\u62a4\u3002\u5355\u5c42MoS<sub>2<\/sub>\u4e0d\u4f46\u53ef\u4ee5\u907f\u514d\u5e95\u9762NbS<sub>2<\/sub>\u4ea7\u751f\u6c27\u5316\u5c42\uff0c\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u5c42\u96a7\u7a7f\u5bfc\u7535\u5c42(~0.8 nm)\uff0c\u4ece\u800c\u4f7f\u5f02\u8d28\u7ed3\u5e95\u9762\u8868\u73b0\u51fa\u4e86\u8f83\u9ad8\u7684\u7535\u5bfc\u7387\uff081200 S cm<sup>-1<\/sup>\uff09\u3002\u56e0\u6b64\u5229\u7528\u8be5\u96a7\u7a7f\u5bfc\u7535\u9762\u4f5c\u4e3a\u63a5\u89e6\u7535\u6781\u7684MoS<sub>2<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u6bd4\u673a\u68b0\u5265\u79bbNbS<sub>2<\/sub>\uff08\u9876\u9762\u3001\u5e95\u9762\u5747\u5b58\u5728\u5929\u7136\u6c27\u5316\u5c42\uff09\u63a5\u89e6\u7684\u5668\u4ef6\u8fc1\u79fb\u7387\u63d0\u9ad8\u4e86\u7ea6140\u500d\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7814\u7a76\u56e2\u961f\u53d1\u73b0\uff0c\u867d\u7136\u91d1\u5c5e\u6027NbS<sub>2<\/sub>\u6750\u6599\u6613\u4e8e\u88ab\u6c27\u5316\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u4e00\u4e2a\u8d1f\u9762\u56e0\u7d20\uff0c\u4f46\u5176\u8868\u9762\u5b58\u5728\u7684\u6570\u7eb3\u7c73\u539a\u7684\u5929\u7136\u6c27\u5316\u5c42\uff08NbO<sub>x<\/sub>\uff09\u53ef\u4ee5\u8868\u73b0\u51fa\u7a33\u5b9a\u7684\u5fc6\u963b\u884c\u4e3a\uff0c\u5e76\u53ef\u4ee5\u7528\u6765\u591f\u6784\u5efa\u4f4e\u538b\uff08~1V\uff09\u5de5\u4f5c\u7684\u6a2a\u5411\u548c\u5782\u76f4\u5fc6\u963b\u5668\u4ef6\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u5355\u9762\u4fdd\u62a4\u3001\u5355\u9762\u6c27\u5316\u7684\u975e\u5bf9\u79f0\u5782\u76f4\u5f02\u8d28\u7ed3\u6784\uff08MoS<sub>2<\/sub>-NbS<sub>2<\/sub>-NbO<sub>x<\/sub>\uff09\uff0c\u517c\u5177\u96a7\u7a7f\u5bfc\u7535\u548c\u963b\u53d8\u5bfc\u7535\u4e24\u79cd\u4e0d\u540c\u7684\u5bfc\u7535\u529f\u80fd\u3002\u7814\u7a76\u56e2\u961f\u8fdb\u4e00\u6b65\u7ed3\u5408\u6fc0\u5149\u76f4\u5199\u5de5\u827a\uff0c\u5728\u8fde\u7eed\u7684\u5f02\u8d28\u7ed3\u533a\u57df\u6784\u5efa\u4e86\u5fc6\u963b\u9635\u5217\u6765\u5b9e\u73b0\u975e\u6613\u5931\u6027\u7684\u5b58\u50a8\u5e94\u7528\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u8be5\u5f02\u8d28\u7ed3\u6240\u5236\u5907\u7684\u67d4\u6027\u5668\u4ef6\u53ef\u4ee5\u8868\u73b0\u51fa\u826f\u597d\u7684\u5f2f\u6298\u8010\u4e45\u6027\uff08~2000\u6b21\uff09\u3002\u7531\u4e8e\u5929\u7136\u6c27\u5316\u73b0\u8c61\u666e\u904d\u5b58\u5728\u4e8e\u91d1\u5c5e\u6027\u4e8c\u7ef4\u6750\u6599\u4e2d\uff0c\u800c\u5bf9\u5e94\u7684\u5929\u7136\u6c27\u5316\u5c42\uff08NbO<sub>x<\/sub>, TaO<sub>x<\/sub>, TiO<sub>x<\/sub>\u7b49\uff09\u540c\u6837\u53ef\u80fd\u5177\u6709\u5fc6\u963b\u7279\u6027\uff0c\u56e0\u6b64\u91c7\u7528\u5408\u9002\u7684\u7ed3\u6784\u8bbe\u8ba1\u53ef\u4ee5\u5236\u5907\u7c7b\u4f3c\u7684\u53cc\u529f\u80fd\u975e\u5bf9\u79f0\u5f02\u8d28\u7ed3\u3002\u8be5\u9879\u7814\u7a76\u5bf9\u91d1\u5c5e\u6027\u4e8c\u7ef4\u6750\u6599\u7684\u672a\u6765\u5e94\u7528\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u7b56\u7565\u3002\u8fd9\u9879\u6210\u679c\u4ee5\u201cBifunctional NbS<sub>2<\/sub>\u2011Based Asymmetric Heterostructure for Lateral and Vertical Electronic Devices\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520aACS Nano\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u535a\u58eb\u751f\u738b\u535a\u4f26\u3002<\/p>\n<p> <strong>\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n<p> \u56fe1 NbS2\u57fa\u975e\u5bf9\u79f0\u5f02\u8d28\u7ed3\u7684\u5408\u6210\u4e0e\u7535\u5b66\u6027\u8d28<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192341\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-20.jpg\" alt=\"\" width=\"600\" height=\"427\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-20-300x214.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5355\u5c42MoS<sub>2<\/sub>\u4e0a\u5916\u5ef6\u751f\u957fNbS<sub>2<\/sub>\u7684\u673a\u7406\u793a\u610f\u56fe\uff1b<br \/>\n (b) NbS<sub>2<\/sub>\u57fa\u5f02\u8d28\u7ed3\u7684AFM\u56fe\uff1b<br \/>\n (c) \u5177\u6709\u5e95\u90e8\u96a7\u7a7f\u5bfc\u7535\u9762\u548c\u9876\u90e8\u5fc6\u963b\u9762\u7684NbS<sub>2<\/sub>\u57fa\u975e\u5bf9\u79f0\u5f02\u8d28\u7ed3\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<br \/>\n (d) \u5f02\u8d28\u7ed3\u9876\u90e8\u5fc6\u963b\u9762\u548c\u5e95\u90e8\u96a7\u7a7f\u5bfc\u7535\u9762\u7684\u7535\u5b66\u6027\u8d28\uff0c\u5185\u7f6e\u63d2\u56fe\u5206\u522b\u4e3a\u91d1\u7535\u6781\u4e0e\u5f02\u8d28\u7ed3\u9876\u9762\u63a5\u89e6\u7684\u5668\u4ef6\u793a\u610f\u56fe\uff08\u5de6\u4e0a\u89d2\uff09\u548c\u91d1\u7535\u6781\u4e0e\u5f02\u8d28\u7ed3\u5e95\u9762\u63a5\u89e6\u7684\u5668\u4ef6\u793a\u610f\u56fe\uff08\u53f3\u4e0b\u89d2\uff09\u3002<\/p>\n<p>\u56fe2 NbS2\u57fa\u975e\u5bf9\u79f0\u5f02\u8d28\u7ed3\u7684\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192342\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-20.jpg\" alt=\"\" width=\"600\" height=\"514\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-20-300x257.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5f02\u8d28\u7ed3\u7684\u4f4e\u500dHAADF-STEM\u56fe\uff1b<br \/>\n (b) \u5f02\u8d28\u7ed3\u539f\u5b50\u7ea7\u5206\u8fa8\u7684HAADF-STEM\u56fe\uff1b<br \/>\n (c) \u5f02\u8d28\u7ed3\u7684SAED\u56fe\uff1b<br \/>\n (d) \u5f02\u8d28\u7ed3\u7684\u622a\u9762TEM\u56fe\uff1b<br \/>\n (e) \u5f02\u8d28\u7ed3\u7684\u622a\u9762\u5143\u7d20\u5206\u5e03\u56fe\uff1b<br \/>\n (f) \u4e0d\u540c\u7a7a\u6c14\u66b4\u9732\u65f6\u95f4\u7684\u5f02\u8d28\u7ed3\u7684XPS\u56fe\u8c31\uff1b<br \/>\n (g) \u5f02\u8d28\u7ed3\u7684\u8868\u9762Nb<sup>5+<\/sup>\u542b\u91cf\u4e0e\u7a7a\u6c14\u66b4\u9732\u65f6\u95f4\u5173\u7cfb\u56fe\uff1b<br \/>\n (h) \u5f02\u8d28\u7ed3\u7684KPFM\u56fe\u3002<\/p>\n<p>\u56fe3 \u4ee5NbS2\u57fa\u5f02\u8d28\u7ed3\u4e3a\u63a5\u89e6\u7535\u6781\u7684MoS2\u573a\u6548\u5e94\u6676\u4f53\u7ba1<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192343\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-20.jpg\" alt=\"\" width=\"600\" height=\"484\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-20-300x242.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5f02\u8d28\u7ed3\u63a5\u89e6\u7684MoS<sub>2<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u793a\u610f\u56fe\uff1b<br \/>\n (b) \u5f02\u8d28\u7ed3\u63a5\u89e6\u548c\u673a\u68b0\u5265\u79bb NbS<sub>2<\/sub>\u63a5\u89e6\u7684MoS<sub>2<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u6027\u80fd\u5bf9\u6bd4\u56fe\uff0c\u63d2\u56fe\u4e3a\u5f02\u8d28\u7ed3\u63a5\u89e6\u5668\u4ef6\u7684\u8f6c\u79fb\u7279\u6027\u66f2\u7ebf\uff1b<br \/>\n (c) \u5f02\u8d28\u7ed3\u63a5\u89e6\u7684MoS<sub>2<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u7684\u8f93\u51fa\u7279\u6027\u66f2\u7ebf\uff1b<br \/>\n (d) \u673a\u68b0\u5265\u79bb NbS<sub>2<\/sub>\u63a5\u89e6\u7684MoS<sub>2<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u7684\u8f93\u51fa\u7279\u6027\u66f2\u7ebf\u3002<\/p>\n<p>\u56fe4 \u57fa\u4e8eNbS<sub>2<\/sub>\u57fa\u5f02\u8d28\u7ed3\u7684\u5782\u76f4\u5fc6\u963b\u5668<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192344\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-20.jpg\" alt=\"\" width=\"600\" height=\"358\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-20-300x179.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u57fa\u4e8e\u5f02\u8d28\u7ed3\u5782\u76f4\u5fc6\u963b\u5668\u7684\u5149\u5b66\u7167\u7247\uff1b<br \/>\n (b) \u5fc6\u963b\u5668\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff1b<br \/>\n (c) \u5fc6\u963b\u5668\u7684\u9ad8\u963b\u6001-\u4f4e\u963b\u6001\u5faa\u73af\u66f2\u7ebf\uff1b<br \/>\n (d) \u5229\u7528\u5fc6\u963b\u5668\u6a21\u62df\u795e\u7ecf\u7a81\u89e6\u7684\u793a\u610f\u56fe\uff1b<br \/>\n (e) 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sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u57fa\u4e8e\u5f02\u8d28\u7ed3\u76843\u00d73\u5fc6\u963b\u9635\u5217\u7ed3\u6784\u793a\u610f\u56fe\uff1b<br \/>\n (b) \u5fc6\u963b\u9635\u5217\u5355\u5143\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff1b<br \/>\n (c) \u5229\u7528\u5fc6\u963b\u9635\u5217\u6a21\u62df\u6570\u636e\u5199\u5165\u4e0e\u8bfb\u53d6\uff0c\u4f4e\u7ec4\u6001\u4e0e\u9ad8\u963b\u6001\u5355\u5143\u6784\u6210X\u5f62\u56fe\u6848\uff1b<br \/>\n (d) \u67d4\u6027\u5fc6\u963b\u5668\u4ef6\u7684\u5b8f\u89c2\u5149\u5b66\u7167\u7247\uff1b<br \/>\n (e) \u67d4\u6027\u5fc6\u963b\u5668\u4ef6\u5355\u5143\u7684\u5149\u5b66\u7167\u7247\uff1b<br \/>\n (f) \u67d4\u6027\u5fc6\u963b\u5668\u76842000\u6b21\u5f2f\u6298\u8010\u4e45\u6027\u3002<\/p>\n<p>\n <strong>\u5c0f\u7ed3<br \/>\n <\/strong><br \/>\n 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