{"id":191950,"date":"2019-12-12T06:36:33","date_gmt":"2019-12-11T22:36:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=191950"},"modified":"2019-12-12T09:38:14","modified_gmt":"2019-12-12T01:38:14","slug":"%e5%a6%82%e4%bd%95%e5%88%a9%e7%94%a8%e7%ba%b3%e7%b1%b3%e7%ba%bf%e5%81%9a%e6%96%87%e7%ab%a0%ef%bc%9f%e8%ae%a9%e8%bf%99%e4%ba%9b%e6%96%87%e7%8c%ae%e5%90%af%e5%8f%91%e4%bd%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=191950","title":{"rendered":"\u5982\u4f55\u5229\u7528\u7eb3\u7c73\u7ebf\u505a\u6587\u7ae0\uff1f\u8ba9\u8fd9\u4e9b\u6587\u732e\u542f\u53d1\u4f60"},"content":{"rendered":"

\u7eb3\u7c73\u6750\u6599\u7531\u4e8e\u5176\u7eb3\u7c73\u5c3a\u5bf8\u6548\u5e94\uff0c\u4ece\u800c\u5177\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u50a8\u80fd\u3001\u6362\u80fd\u6027\u8d28\u3002\u7eb3\u7c73\u7ea7\u5c3a\u5bf8\u5728\u51b3\u5b9a\u6750\u6599\u7684\u6027\u8d28\u65b9\u9762\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u5982\u79bb\u5b50\u6269\u6563\u52a8\u529b\u5b66\u3001\u5e94\u53d8\/\u5e94\u529b\u7684\u5927\u5c0f\u4ee5\u53ca\u6750\u6599\u7684\u6d3b\u6027\u3002\u7eb3\u7c73\u7ebf\u4f5c\u4e3a\u4e00\u79cd\u4ee3\u8868\u6027\u7684\u4e00\u7ef4\u7eb3\u7c73\u6750\u6599\uff0c\u5177\u6709\u5982\u4e0b\u4f18\u70b9\uff1a1\u3001\u7eb3\u7c73\u7ebf\u4e3a\u7535\u5b50\u4f20\u9012\u63d0\u4f9b\u4e86\u76f4\u63a5\u901a\u9053\uff1b2\u3001\u5176\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u7535\u6781-\u7535\u89e3\u6db2\u63a5\u89e6\u9762\u79ef\u5927\uff1b3\u3001\u7eb3\u7c73\u7ebf\u4fbf\u4e8e\u5b9e\u73b0\u4f53\u79ef\u81a8\u80c0\uff0c\u6291\u5236\u673a\u68b0\u964d\u89e3\uff0c\u5ef6\u957f\u5faa\u73af\u5bff\u547d\uff1b4\u3001\u7eb3\u7c73\u7ebf\u5177\u6709\u4f18\u5f02\u7684\u673a\u68b0\u67d4\u97e7\u6027\u548c\u6768\u6c0f\u6a21\u91cf\u3002\u56e0\u6b64\u7eb3\u7c73\u7ebf\u5728\u80fd\u91cf\u5b58\u50a8\u3001\u8f6c\u5316\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u7eb3\u7c73\u7ebf\u7684\u5f62\u8c8c\u5404\u5f02\uff0c\u4e00\u822c\u6709\u7b80\u5355\u7eb3\u7c73\u7ebf\u3001\u6838\u58f3\/\u5305\u8986\u7eb3\u7c73\u7ebf\u3001\u5206\u5c42\/\u5f02\u8d28\u7ed3\u6784\u7eb3\u7c73\u7ebf\u3001\u591a\u5b54\/\u4ecb\u5b54\u7eb3\u7c73\u7ebf\u548c\u7eb3\u7c73\u7ebf\u9635\u5217\u7b49\u591a\u79cd\u5f62\u5f0f\u3002\u4f9d\u9760\u7eb3\u7c73\u7ebf\u7684\u6784\u5efa\uff0c\u8fd1\u5e74\u6765\u51fa\u73b0\u4e86\u8bb8\u591a\u4f18\u79c0\u79d1\u7814\u6210\u679c\uff0c\u672c\u671f\u63a8\u6587\u7279\u9009\u53d6\u5176\u4e2d\u4e00\u4e9b\u4ee3\u8868\uff0c\u4f5c\u7b80\u8981\u4ecb\u7ecd\u3002\u5e0c\u671b\u5bf9\u6709\u610f\u6784\u5efa\u7eb3\u7c73\u7ebf\u7684\u540c\u5b66\uff0c\u6709\u6240\u542f\u53d1\u3002<\/p>\n

\u4e00\u3001\u7b80\u5355\u7eb3\u7c73\u7ebf<\/h3>\n

Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High-Performance Zinc-Ion Batteries1<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u8bfe\u9898\u7ec4\u3002\u5c42\u72b6\u9492\u6c27\u5316\u7269\u7531\u4e8e\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u5bb9\u91cf\u800c\u88ab\u5e94\u7528\u4e8e\u9502\u7535\u6c60\u6216\u94a0\u7535\u6c60\u7684\u7535\u6781\u6750\u6599\u4e2d\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u9492\u6c27\u5316\u7269\u5728\u79bb\u5b50\u5d4c\u5165\/\u8131\u5d4c\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u7535\u5b50\u7535\u5bfc\u7387\u4f4e\uff0c\u7ed3\u6784\u7a33\u5b9a\u6027\u5dee\uff0c\u56e0\u800c\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\u3002\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\uff0c\u5c42\u95f4\u91d1\u5c5e\u79bb\u5b50\uff08Mx<\/sub>Vn<\/sub>Om<\/sub>\uff0cM\u4e3a\u91d1\u5c5e\u79bb\u5b50\uff09\u53ef\u4ee5\u4f5c\u4e3a\u5c42\u95f4\u652f\u67f1\uff0c\u4ee5\u63d0\u9ad8\u5c42\u72b6\u9492\u6c27\u5316\u7269\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u4e9b\u9492\u6c27\u5316\u7269\u7684\u5c42\u95f4\u91d1\u5c5e\u79bb\u5b50\u53ef\u4ee5\u5927\u5927\u63d0\u9ad8\u79bb\u5b50\u6269\u6563\u901f\u7387\uff0c\u4ee5\u53ca\u7535\u5b50\u5bfc\u7535\u6027\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u950c\u7535\u6c60\u4f53\u7cfb\u4e2d\u7684\u5c42\u95f4\u91d1\u5c5e\u79bb\u5b50\u7684\u5f71\u54cd\u7814\u7a76\u5374\u5f88\u5c11\u3002\u5728\u6b64\uff0c\u7814\u7a76\u8005\u4eec\u8bbe\u8ba1\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u3001\u5b89\u5168\u3001\u9ad8\u5bb9\u91cf\u548c\u957f\u5bff\u547d\u7684\u6c34\u6027\u950c\u7535\u6c60\u2014\u2014Zn\/\/Na0.33<\/sub>V2<\/sub>O5<\/sub>\uff0c\u5176\u4e2dNa0.33<\/sub>V2<\/sub>O5<\/sub>\u4e3aNa+<\/sup>\u63d2\u5c42\u7684\u9492\u6c27\u5316\u7269\u7eb3\u7c73\u7ebf\u3002\u91c7\u7528\u573a\u53d1\u5c04\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08FESEM\uff09\u3001X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u3001\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u548cX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u7b49\u65b9\u6cd5\u7814\u7a76\u4e86NVO\u7eb3\u7c73\u7ebf\u9634\u6781\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u6f14\u53d8\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u7ec4\u88c5\u5355\u5c42\u7eb3\u7c73\u7ebf\u5668\u4ef6\u7814\u7a76\u4e86\u5c42\u95f4Na+<\/sup>\u7684\u5f71\u54cd\uff0c\u8fd9\u4e3a\u5c42\u72b6\u9492\u6c27\u5316\u7269\u7684\u5bfc\u7535\u6027\u63d0\u9ad8\u63d0\u4f9b\u4e86\u76f4\u63a5\u8bc1\u636e\u3002<\/p>\n

\u56fe\u4e00 NVO\u7eb3\u7c73\u7ebf\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

Highly Durable Na2<\/sub>V6<\/sub>O16<\/sub>\u00b71.63H2<\/sub>O Nanowire Cathode for Aqueous Zinc-Ion Battery2<\/sup><\/strong><\/p>\n

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\u8fd9\u79cdNa2<\/sub>V6<\/sub>O16<\/sub>\u00b71.63H2<\/sub>O\uff08H-NVO\uff09\u7eb3\u7c73\u7ebf\u6613\u4e8eZn2+<\/sup>\u7684\u7535\u5316\u5b66\u63d2\u5c42\uff0c\u4e14\u6709\u9ad8\u5ea6\u53ef\u9006\u6027\u3002H-NVO\u7eb3\u7c73\u7ebf\u572850 mA g-1<\/sup>\u5177\u6709352 mAh g-1<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\u548c\u57285000\u00a0mA g-1<\/sup>\u7684\u8d85\u957f\u5faa\u73af\u5bff\u547d\uff086000\u6b21\u5faa\u73af\u540e90%\u5bb9\u91cf\u4fdd\u6301\u7387\uff09\u3002\u672c\u6587\u5229\u7528X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u3001X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u7b49\u6d4b\u8bd5\uff0c\u63ed\u793a\u4e86\u7ed3\u6784\u6c34\u7684\u5b58\u5728\u6709\u52a9\u4e8e\u63d0\u9ad8\u950c\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u4e8c H-NVO\u7eb3\u7c73\u7ebf\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u4e8c\u3001\u6838\u58f3\/\u5305\u8986\u7eb3\u7c73\u7ebf<\/h3>\n

H2<\/sub>V3<\/sub>O8<\/sub>\u00a0Nanowire\/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity3<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u5a01\u65af\u5eb7\u661f\u5927\u5b66Wang Xudong\u56e2\u961f\u3002H2<\/sub>V3<\/sub>O8<\/sub>\u4e0e\u5176\u4ed6V2<\/sub>O5<\/sub>\u548cVO2<\/sub>\u7b49\u5c42\u72b6\u9492\u6c27\u5316\u7269\u76f8\u6bd4\uff0cH2<\/sub>V3<\/sub>O8<\/sub>\u4e2d\u7684\u6c22\u952e\u53ef\u4ee5\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7ef4\u6301\u66f4\u597d\u7684\u7ed3\u6784\u5b8c\u6574\u6027\u548c\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0cH2<\/sub>V3<\/sub>O8<\/sub>\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u8fd9\u662f\u7531\u4e8eV5+<\/sup>\u548cV4+<\/sup>\u7684\u6df7\u5408\u4ef7\u6001\u6240\u5f15\u8d77\u7684\uff0c\u540c\u65f6\u8f83\u9ad8\u7684\u5e73\u5747\u4ef7\u6001\uff084.67\uff09\u8d21\u732e\u4e86\u66f4\u6d3b\u8dc3\u7684\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u548c\u66f4\u5927\u7684\u6bd4\u5bb9\u91cf\u3002\u8fd9\u4e9b\u72ec\u7279\u7684\u6027\u8d28\u8868\u660e\uff0cH2<\/sub>V3<\/sub>O8<\/sub>\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u6c34\u7cfb\u950c\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002<\/p>\n

\u672c\u7bc7\u6587\u732e\u62a5\u9053\u4e86\u4e00\u79cd\u7531\u77f3\u58a8\u70ef\u5305\u8986\u7684H2<\/sub>V3<\/sub>O8<\/sub>\u7eb3\u7c73\u7ebf\uff08NWs\uff09\u590d\u5408\u6750\u6599\uff0c\u5c06\u5176\u7528\u4f5c\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u3002H2<\/sub>V3<\/sub>O8<\/sub>\u7eb3\u7c73\u7ebf\u7684\u7406\u60f3\u7ed3\u6784\u548c\u77f3\u58a8\u70ef\u7f51\u7edc\u7684\u9ad8\u5bfc\u7535\u6027\u534f\u540c\u4f5c\u7528\uff0c\u4f7f\u5f97H2<\/sub>V3<\/sub>O8<\/sub>\u00a0NW\/\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u950c\u79bb\u5b50\u5b58\u50a8\u6027\u80fd\uff0c\u57281\/3C\u4e0b\u65f6\u5bb9\u91cf\u4e3a394 mA h g-1<\/sup>\uff0c\u7cfb\u7edf\u7684\u7ed3\u6784\u548c\u5143\u7d20\u8868\u5f81\u8bc1\u5b9e\u4e86Zn2+<\/sup>\u4e0e\u6c34\u7684\u53ef\u9006\u5171\u5d4c\u5165\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u9ad8\u6027\u80fd\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u524d\u666f\u3002<\/p>\n

\u56fe\u4e09 H2<\/sub>V3<\/sub>O8<\/sub>\u7eb3\u7c73\u7ebf\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

Three-dimensional Core@Shell Co@CoMoO4<\/sub>\u00a0nanowire arrays as efficient alkaline hydrogen evolution electro-catalysts4<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u91cd\u5e86\u5927\u5b66\u9b4f\u5b50\u680b\u6559\u6388\u56e2\u961f\u3002\u5236\u5907\u9ad8\u6548\u7a33\u5b9a\u7684\u975e\u8d35\u91d1\u5c5e\u6790\u6c22\u53cd\u5e94\u7535\u50ac\u5316\u5242\uff0c\u5bf9\u7535\u89e3\u6c34\u5546\u4e1a\u5316\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u672c\u7bc7\u6587\u732e\u901a\u8fc7\u5728H2<\/sub>\/N2<\/sub>\u6c14\u6c1b\u4e0b\u7145\u70e7\u78b3\u9178\u94b4\u6c22\u6c27\u5316\u7269@CoMoO4<\/sub>\u00a0(CCH NA@CoMoO4<\/sub>)\u524d\u9a71\u4f53\uff0c\u7814\u5236\u4e86\u81ea\u652f\u6491\u7684\u6838\u58f3\u72b6Co@CoMoO4<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5217\uff08Co@CoMoO4 <\/sub>NA\uff09\u7535\u6781\u3002\u7531\u6b64,\u5efa\u7acb\u4e86\u534f\u540c\u7684Co\/CoMoO4<\/sub>\u5f02\u8d28\u7ed3\u6784\u754c\u9762\u548c\u4e09\u7ef4\u591a\u5b54\u7535\u6781\u7ed3\u6784\uff0c\u4e3a\u5176\u50ac\u5316\u6d3b\u6027\u7684\u63d0\u9ad8\u63d0\u4f9b\u4e86\u53ef\u9760\u9014\u5f84\u3002\u57281 M KOH\u6eb6\u6db2\u4e2d\uff0cCo@CoMoO4 <\/sub>NA\u7535\u6781\u8868\u73b0\u51fa\u826f\u597d\u7684\u6d3b\u6027\uff0c\u572810 mA cm-2<\/sup>\u65f6\u8fc7\u7535\u4f4d\u4f4e\u81f346 mV\uff0c\u975e\u5e38\u63a5\u8fd1\u5546\u4e1a\u94c2\u78b3\u7535\u6781\u3002\u8fd9\u6b21\u7814\u7a76\u901a\u8fc7\u8c03\u8282\u591a\u7ec4\u5206\u754c\u9762\u6765\u63d0\u9ad8HER\u50ac\u5316\u6548\u7387\uff0c\u53ef\u80fd\u4f1a\u6fc0\u53d1\u65b0\u7684\u7535\u50ac\u5316\u5242\u5f00\u53d1\u3002<\/p>\n

\u56fe\u56db Co@CoMoO4<\/sub>\u7eb3\u7c73\u7ebf\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u5206\u5c42\/\u5f02\u8d28\u7ed3\u6784\u7eb3\u7c73\u7ebf<\/h3>\n

Co3<\/sub>O4<\/sub>\/Fe0.33<\/sub>Co0.66<\/sub>P Interface Nanowire for Enhancing Water Oxidation Catalysis at High Current Density5<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u5317\u4eac\u5927\u5b66\u90ed\u5c11\u519b\u56e2\u961f\u3002\u8bbe\u8ba1\u72ec\u7279\u7684\u7eb3\u7c73\u754c\u9762\u5bf9\u4e8e\u63d0\u9ad8\u7eb3\u7c73\u7535\u50ac\u5316\u5242\u6d3b\u6027\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u7136\u800c\uff0c\u7814\u7a76\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u6027\u597d\u7684\u975e\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u672c\u6587\u9996\u5148\u7528Fe\uff08CN\uff096<\/sub>3-<\/sup>\u00a0\u5bf9Co\uff08CO3<\/sub>\uff090.5<\/sub>\uff08OH\uff09\u00b70.11H2<\/sub>O\uff08Co-CHH\uff09\u7eb3\u7c73\u7ebf\u8fdb\u884c\u5316\u5b66\u8150\u8680\uff0c\u7136\u540e\u4f5c\u4f4e\u6e29\u78f7\u5316\u5904\u7406\uff0c\u5408\u7406\u8bbe\u8ba1\u4e86\u4e00\u7c7bCo3<\/sub>O4<\/sub>\/Fe0.33<\/sub>Co0.66<\/sub>P\u754c\u9762\u7eb3\u7c73\u7ebf\uff0c\u5176\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5177\u6709\u826f\u597d\u7684\u7684\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u6027\u80fd\u30021 M KOH\u6eb6\u6db2\u4e2d\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a50 \u3001800 mA cm-2<\/sup>\u65f6\uff0c\u8fc7\u7535\u4f4d\u4ec5\u5206\u522b\u4e3a215 \u3001291mV\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u7531\u4e8e\u6d3b\u6027Co-\u548cO-\u4f4d\u70b9\u964d\u4f4e\u4e86\u7535\u89e3\u6c34\u6790\u6c27\u52bf\u5792\uff0c\u56e0\u6b64Co3<\/sub>O4<\/sub>\/Fe0.33<\/sub>Co0.66<\/sub>P\u4f18\u4e8e\u50ac\u5316OER\u3002<\/p>\n

\u56fe\u4e94 Co3<\/sub>O4<\/sub>\/Fe0.33<\/sub>Co0.66<\/sub>P\u5236\u5907\u793a\u610f\u56fe\u548c\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

Foam\u2013like Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u00a0heterostructure nanowire arrays for efficient bifunctional overall water-splitting6<\/sup><\/strong><\/p>\n

\u672c\u7bc7\u6587\u732e\u51fa\u81ea\u5357\u4eac\u5927\u5b66\u5468\u52c7\u56e2\u961f\u3002\u4e00\u7ef4\uff081D\uff09\u7cfb\u7edf\u4fbf\u4e8e\u4fc3\u8fdb\u5f84\u5411\u7535\u8377\u4f20\u8f93\uff0c\u5e76\u6cbf\u7740\u7eb3\u7c73\u7ebf\u8fb9\u7f18\u66b4\u9732\u51fa\u5927\u91cf\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u6b64\u5916\uff0c\u758f\u677e\u7684\u591a\u5b54\u7ed3\u6784\u5c06\u4f7f\u50ac\u5316\u5242\u4e0e\u7535\u89e3\u8d28\u79bb\u5b50\u6709\u66f4\u591a\u7684\u63a5\u89e6\u4f4d\u70b9\u3002\u672c\u6587\u732e\u901a\u8fc7\u4e24\u6b65\u6cd5\u5236\u5907\u4e86Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u5f02\u8d28\u7ed3\u6ce1\u6cab\u72b6\u7eb3\u7c73\u7ebf\u9635\u3002\u5b83\u5177\u6709\u5de8\u5927\u7684\u7535\u5316\u5b66\u8868\u9762\u79ef\u548c\u4e30\u5bcc\u7684\u6676\u683c\u7f3a\u9677\u3002Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684\u53cc\u7535\u5c42\u7535\u5bb9\u503c\u4e3a81.4 mF\u00b7cm-2<\/sup>\uff0c\u662f\u524d\u9a71\u4f53\uff08NixCo1-x<\/sub>\uff08CO3<\/sub>\uff090.5<\/sub>OH\uff09\u76844\u500d,\u8fd9\u8868\u660eCo9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7eb3\u7c73\u7ebf\u9635\u5177\u6709\u66f4\u591a\u4e0e\u7535\u89e3\u8d28\u79bb\u5b50\u63a5\u89e6\u7684\u50ac\u5316\u53cd\u5e94\u4f4d\u70b9\u3002\u539f\u4f4d\u786b\u5316\u751f\u957f\u6cd5\u4fc3\u4f7fCo9<\/sub>S8<\/sub>\u548cNi3<\/sub>S2<\/sub>\u5747\u5300\u5206\u5e03\uff0c\u4e14\u5728\u5f02\u8d28\u754c\u9762\u4e0a\u5f62\u6210\u5927\u91cf\u6676\u683c\u7f3a\u9677\u3002\u8fd9\u4e9b\u6676\u683c\u7f3a\u9677\u8c03\u8282\u4e86\u5c40\u57df\u7535\u5b50\u6392\u5217\uff0c\u4f7f\u4e4b\u6210\u4e3a\u6d3b\u8dc3\u7684\u53cd\u5e94\u4e2d\u5fc3\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u7f3a\u9677\u5f02\u8d28\u754c\u9762\u6709\u5229\u4e8eH+<\/sup>\u548cOH–<\/sup>\u7684\u5316\u5b66\u5438\u9644\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0cCo9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7535\u6781\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u5177\u6709\u826f\u597d\u7684\u6790\u6c27\u3001\u6790\u6c22\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u516d Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7eb3\u7c73\u7ebf\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56db\u3001\u591a\u5b54\u7eb3\u7c73\u7ebf<\/h3>\n

NiO\/CoN Porous Nanowires as Efficient Bifunctional Catalysts for Zn\u2212Air Batteries7<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u5317\u4eac\u5927\u5b66\u90ed\u5c11\u519b\u56e2\u961f\u3002\u5f00\u53d1\u9ad8\u6548\u7684\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u548c\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u53cc\u529f\u80fd\u50ac\u5316\u5242\u662f\u63d0\u9ad8\u950c\u7a7a\u6c14\u7535\u6c60\u6548\u7387\u7684\u5173\u952e\u3002\u672c\u7814\u7a76\u62a5\u9053\u4e86\u5177\u6709\u6c27\u7a7a\u4f4d\u7684\u591a\u5b54NiO\/CoN\u754c\u9762\u7eb3\u7c73\u7ebf\u9635\u5217\uff08PINWs\uff09\uff0c\u8fd9\u79cd\u9635\u5217\u7684NiO\u548cCoN\u4e4b\u95f4\u5b58\u5728\u4e92\u8fde\u7eb3\u7c73\u754c\u9762\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86OER\u548cORR\u7684\u7535\u50ac\u5316\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u3002X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\u3001\u7535\u5b50\u81ea\u65cb\u5171\u632f\u548c\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u7814\u7a76\u8868\u660e\uff0c\u94b4\u914d\u4f4d\u6570\u51cf\u5c11\uff0cNiO\/CoN\u7eb3\u7c73\u754c\u9762\u4e0a\u6c27\u7a7a\u4f4d\u589e\u52a0\u3002NiO\/CoN-PINWs\u5177\u6709\u826f\u597d\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u6027\u80fd\u3002\u4f7f\u7528NiO\/CoN-PINWs\u4f5c\u4e3a\u6b63\u6781\u7684\u950c\u7a7a\u6c14\u7535\u6c60\u5177\u67091.46V\u7684\u5f00\u8def\u7535\u4f4d\u300179.6 mW cm-2<\/sup>\u7684\u9ad8\u529f\u7387\u5bc6\u5ea6\u548c945 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u7531NiO\/CoN-PINWs\u5236\u5907\u7684\u4e09\u5143\u56fa\u4f53\u7535\u6c60\u53ef\u4ee5\u7ef4\u6301\u4e00\u4e2a\u7535\u5b50\u8868\u5de5\u4f5c12h\u4ee5\u4e0a\uff0c\u8fd9\u9879\u5de5\u4f5c\u8bc1\u660e\u4e86\u754c\u9762\u8026\u5408\u548c\u6c27\u7a7a\u4f4d\u5728\u9ad8\u6027\u80fd\u950c\u7a7a\u6c14\u7535\u6c60\u53d1\u5c55\u4e2d\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u56fe\u4e03 NiO\/CoN-PINWs\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u4e94\u3001\u7eb3\u7c73\u7ebf\u9635\u5217<\/h3>\n

NiMo Solid Solution Nanowire Array Electrodes for Highly Efficient Hydrogen Evolution Reaction8<\/sup><\/strong><\/p>\n

\u672c\u6587\u51fa\u81ea\u6e05\u534e\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u6768\u8bda\u8bfe\u9898\u7ec4\u3002\u8c03\u6574\u975e\u8d35\u91d1\u5c5e\u7684\u5f62\u6001\u3001\u7ed3\u6784\u548c\u7ec4\u6210\uff0c\u662f\u63d0\u5347\u6750\u6599\u50ac\u5316\u6d3b\u6027\u7684\u5173\u952e\u3002\u50ac\u5316\u91d1\u5c5e\u5408\u91d1\u5316\u53ef\u4ee5\u4ea7\u751f\u534f\u540c\u6548\u5e94\uff0c\u4ece\u800c\u83b7\u5f97\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6027\u80fd\u3002\u7531\u4e8e\u6210\u6838\u548c\u751f\u957f\u673a\u5236\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u53d7\u63a7\uff0c\u5728\u4f4e\u6e29\u6eb6\u6db2\u4e2d\u5f62\u6210\u5408\u91d1\u53ef\u80fd\u6bd4\u5728\u9ad8\u6e29\u4e0b\u5f62\u6210\u7684\u5408\u91d1\u5177\u6709\u66f4\u597d\u50ac\u5316\u6027\u80fd\u3002\u5728\u8fd9\u7bc7\u6587\u732e\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u6c34\u6eb6\u6db2\u7684\u5236\u5907\u6280\u672f\u6765\u5236\u5907NiMo\u5408\u91d1\u7eb3\u7c73\u7ebf\u9635\u5217\u3002NiMo\u5408\u91d1\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u50ac\u5316\u6d3b\u6027\u663e\u8457\u63d0\u9ad8\uff0c\u572810\u548c400 mA cm-2<\/sup>\u4e0b\u7684\u8fc7\u7535\u4f4d\u5206\u522b\u4e3a17\u548c98 mV\uff0c\u6bd4\u5927\u591a\u6570\u6700\u5148\u8fdb\u7684\u975e\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u8981\u597d\uff0c\u751a\u81f3\u53ef\u4ee5\u4e0e\u94c2\u7535\u6781\u76f8\u6bd4\u3002\u5206\u6790\u8868\u660e\uff0cMo\u63ba\u6742\u5f15\u8d77\u7684\u6676\u683c\u7578\u53d8\u3001\u5408\u91d1\u5f62\u6210\u589e\u52a0\u7684\u754c\u9762\u6d3b\u6027\u4ee5\u53ca\u7eb3\u7c73\u7ebf\u8868\u9762\u5927\u91cf\u7684MoNi4<\/sub>\u6d3b\u6027\u4e2d\u5fc3\u5171\u540c\u4fc3\u8fdb\u4e86\u50ac\u5316\u6d3b\u6027\u7684\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n

\u56fe\u516b NiO\/CoN-PINWs\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

Enhanced Catalytic Activity in Nitrogen-Anion Modified Metallic Cobalt Disulfide Porous Nanowire Arrays for Hydrogen Evolution9<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u51fa\u81ea\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8c22\u6bc5\u6559\u6388\u8bfe\u9898\u7ec4\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u7814\u7a76\u8005\u63d0\u51fa\u4e86\u4e00\u4e2a\u7b80\u5355\u7684\u6c2e\u79bb\u5b50\u4fee\u9970\u7b56\u7565\uff0c\u4ece\u800c\u8c03\u8282CoS2<\/sub>\u591a\u5b54\u7eb3\u7c73\u7ebf\u9635\u5217\u4e2d\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u3001\u7535\u5b50\u7ed3\u6784\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u901a\u8fc7XPS\u548cXANES\u5149\u8c31\u7684\u7814\u7a76\u8868\u660e\uff0c\u6c2e\u7684\u5f15\u5165\u4e0d\u4ec5\u6539\u53d8\u4e86\u4f53\u7cfb\u7684\u5f62\u8c8c\uff0c\u63d0\u4f9b\u4e86\u989d\u5916\u7684\u6d3b\u6027\u4f4d\uff0c\u800c\u4e14\u63d0\u9ad8\u4e86\u4f53\u7cfb\u7684\u5bfc\u7535\u6027\uff0c\u4fc3\u8fdb\u4e86HER\u8fc7\u7a0b\u7684\u5feb\u901f\u7535\u8377\u8f6c\u79fb\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8bc1\u5b9e\uff0c\u6c2e\u7684\u63ba\u5165\u4f7fS\u6216Co\u6d3b\u6027\u4e2d\u5fc3\u7684\u6c22\u5438\u9644\u81ea\u7531\u80fd\u66f4\u4e3a\u7406\u60f3\uff0c\u4fc3\u8fdb\u5176\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u6b63\u5982\u6240\u9884\u671f\u7684\uff0cN-CoS2<\/sub>\u00a0NW\/\u78b3\u5e03\uff08CC\uff09\u7535\u6781\u7684\u8fc7\u7535\u4f4d\u8f83\u4f4e\uff0c\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u8f83\u5927\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u7535\u6781\u7684\u50ac\u5316\u6027\u80fd\u3002\u8fd9\u4e00\u5de5\u4f5c\u4e3a\u5408\u7406\u8bbe\u8ba1\u5148\u8fdb\u9ad8\u6548\u7684\u5236\u6c22\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6709\u76ca\u7684\u601d\u8def\u3002<\/p>\n

\u56fe\u4e5d N-CoS2<\/sub>\u00a0NW\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u516d\u3001\u7eb3\u7c73\u7ebf\u7f51\u7edc<\/h3>\n

Earth Abundant Fe\/Mn-Based Layered Oxide Interconnected Nanowires for Advanced K\u2011Ion Full Batteries10<\/sup><\/strong><\/p>\n

\u8fd9\u7bc7\u6587\u732e\u51fa\u81ea\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u8bfe\u9898\u7ec4\u3002\u94be\u79bb\u5b50\u7535\u6c60\uff08KIB\uff09\u662f\u4e00\u79cd\u65b0\u578b\u7684\u50a8\u80fd\u88c5\u7f6e\uff0c\u5177\u6709\u4f4e\u6210\u672c\u548c\u4e30\u5bcc\u7684\u94be\u539f\u6750\u6599\u8d44\u6e90\u7684\u6f5c\u5728\u4f18\u52bf\u3002\u7136\u800c\uff0c\u4e3b\u8981\u7684\u6311\u6218\u5728\u4e8e\u7f3a\u4e4f\u7a33\u5b9a\u7684\u6b63\u6781\u6750\u6599\uff0c\u6765\u9002\u5e94\u5927\u5c3a\u5bf8K+<\/sup>\u7684\u63d2\u5c42\u3002\u8fd9\u5219\u6587\u732e\u9996\u6b21\u8bbe\u8ba1\u4e00\u79cd\u65b0\u7684Fe\/Mn\u57fa\u5c42\u72b6\u6c27\u5316\u7269\u4e92\u8fde\u7eb3\u7c73\u7ebf\uff0c\u5c06\u5176\u4f5c\u4e3a\u94be\u7535\u6c60\u6b63\u6781\uff0c\u8868\u73b0\u51fa\u9ad8\u5bb9\u91cf\u548c\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u76f8\u4e92\u8fde\u63a5\u7684\u7eb3\u7c73\u7ebf\u7f51\u7edc\uff0c\u6709\u52a9\u4e8e\u63d0\u5347\u6750\u6599\u7535\u5316\u5b66\u50a8\u80fd\u6027\u8d28\u3002\u5728\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u5206\u6790\u548c\u7535\u5316\u5b66\u8868\u5f81\u7684\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u8005\u8bc1\u5b9e\u4e86\u4e92\u8fde\u7684K0.7<\/sub>Fe0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u7eb3\u7c73\u7ebf\u53ef\u4ee5\u5728\u79bb\u5b50\u5d4c\u5165\/\u8131\u51fa\u8fc7\u7a0b\u4e2d\u63d0\u4f9b\u7a33\u5b9a\u7684\u9aa8\u67b6\u7ed3\u6784\u3001\u5feb\u901f\u7684K+<\/sup>\u6269\u6563\u901a\u9053\u548c\u4e09\u7ef4\u7535\u5b50\u4f20\u8f93\u7f51\u7edc\u3002\u5c06\u5176\u7ec4\u88c5\u4e3a\u94be\u7535\u6c60\u540e\uff0c\u8be5\u7535\u6c60\u5177\u6709178 mAh g-1<\/sup>\u7684\u521d\u59cb\u5bb9\u91cf\uff0c\u5faa\u73af250\u6b21\u4ee5\u4e0a\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a76%\u3002<\/p>\n

\u56fe\u5341 K0.7<\/sub>Fe0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u4e00 K0.7<\/sub>Fe0.5<\/sub>Mn0.5<\/sub>O2<\/sub>\u7ed3\u6784\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e<\/h3>\n

1. He, P.; Zhang, G.; Liao, X.; Yan, M.; Xu, X.; An, Q.; Liu, J.; Mai, L. Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High-Performance Zinc-Ion Batteries. Advanced Energy Materials <\/i><\/em>2018,<\/b><\/strong>8 (10), DOI: 10.1002\/aenm.201702463.<\/p>\n

2. Hu, P.; Zhu, T.; Wang, X.; Wei, X.; Yan, M.; Li, J.; Luo, W.; Yang, W.; Zhang, W.; Zhou, L.; Zhou, Z.; Mai, L. Highly Durable Na2<\/sub>V6<\/sub>O16<\/sub>.1.63H2<\/sub>O Nanowire Cathode for Aqueous Zinc-Ion Battery. Nano Lett <\/i><\/em>2018,<\/b><\/strong>18 (3), 1758-1763 DOI: 10.1021\/acs.nanolett.7b04889.<\/p>\n

3. Pang, Q.; Sun, C.; Yu, Y.; Zhao, K.; Zhang, Z.; Voyles, P. M.; Chen, G.; Wei, Y.; Wang, X. H2<\/sub><\/p>\n

V3<\/sub>O8<\/sub>Nanowire\/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity. Advanced Energy Materials <\/i><\/em>2018,<\/b><\/strong>\u00a08 (19), DOI: 10.1002\/aenm.201800144.<\/p>\n

4. Xiang, R.; Duan, Y.; Peng, L.; Wang, Y.; Tong, C.; Zhang, L.; Wei, Z. Three-dimensional Core@Shell Co@CoMoO4<\/sub>nanowire arrays as efficient alkaline hydrogen evolution electro-catalysts. Applied Catalysis B: Environmental <\/i><\/em>2019,<\/b><\/strong>246, 41-49 DOI: 10.1016\/j.apcatb.2019.01.035.<\/p>\n

5. Zhang, X.; Li, J.; Yang, Y.; Zhang, S.; Zhu, H.; Zhu, X.; Xing, H.; Zhang, Y.; Huang, B.; Guo, S.; Wang, E. Co3<\/sub>O4<\/sub>\/Fe0.33 <\/sub>Co0.66<\/sub>P Interface Nanowire for Enhancing Water Oxidation Catalysis at High Current Density. Adv Mater <\/i><\/em>2018,<\/b><\/strong>30 (45), e1803551 DOI: 10.1002\/adma.201803551.<\/p>\n

6. Du, F.; Shi, L.; Zhang, Y.; Li, T.; Wang, J.; Wen, G.; Alsaedi, A.; Hayat, T.; Zhou, Y.; Zou, Z. Foam\u2013like Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>heterostructure nanowire arrays for efficient bifunctional overall water\u2013splitting. Applied Catalysis B: Environmental <\/i><\/em>2019,<\/b><\/strong>253, 246-252 DOI: 10.1016\/j.apcatb.2019.04.067.<\/p>\n

7. Yin, J.; Li, Y.; Lv, F.; Fan, Q.; Zhao, Y. Q.; Zhang, Q.; Wang, W.; Cheng, F.; Xi, P.; Guo, S. NiO\/CoN Porous Nanowires as Efficient Bifunctional Catalysts for Zn-Air Batteries. ACS Nano <\/i><\/em>2017,<\/b><\/strong>11 (2), 2275-2283 DOI: 10.1021\/acsnano.7b00417.<\/p>\n

8. Nairan, A.; Zou, P.; Liang, C.; Liu, J.; Wu, D.; Liu, P.; Yang, C. NiMo Solid Solution Nanowire Array Electrodes for Highly Efficient Hydrogen Evolution Reaction. Advanced Functional Materials <\/i><\/em>2019,<\/b><\/strong>29 (44), DOI: 10.1002\/adfm.201903747.<\/p>\n

9. Chen, P.; Zhou, T.; Chen, M.; Tong, Y.; Zhang, N.; Peng, X.; Chu, W.; Wu, X.; Wu, C.; Xie, Y. Enhanced Catalytic Activity in Nitrogen-Anion Modified Metallic Cobalt Disulfide Porous Nanowire Arrays for Hydrogen Evolution. ACS Catalysis <\/i><\/em>2017,<\/b><\/strong>7 (11), 7405-7411 DOI: 10.1021\/acscatal.7b02218.<\/p>\n

10. Wang, X.; Xu, X.; Niu, C.; Meng, J.; Huang, M.; Liu, X.; Liu, Z.; Mai, L. Earth Abundant Fe\/Mn-Based Layered Oxide Interconnected Nanowires for Advanced K-Ion Full Batteries. Nano Lett <\/i><\/em>2017,<\/b><\/strong>17 (1), 544-550 DOI: 10.1021\/acs.nanolett.6b04611.<\/p>\n

\u672c\u6587\u7531Buhuoyou<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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