{"id":191998,"date":"2019-12-14T06:36:24","date_gmt":"2019-12-13T22:36:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=191998"},"modified":"2019-12-13T21:36:36","modified_gmt":"2019-12-13T13:36:36","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e7%8e%8b%e8%ae%ad%e5%9b%a2%e9%98%9fadv-mater-%e6%8a%a5%e9%81%93%ef%bc%9a%e5%88%a9%e7%94%a8van-der-waals%e8%b0%83%e6%8e%a7%e5%87%ba%e5%85%b7%e6%9c%89%e8%b6%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=191998","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u738b\u8bad\u56e2\u961fAdv. Mater.\u62a5\u9053\uff1a\u5229\u7528Van der Waals\u8c03\u63a7\u51fa\u5177\u6709\u8d85\u7ed3\u6784\u7684\u6df7\u5408POM-ZrO2\u67d4\u6027\u5e26\u72b6\u6750\u6599"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u8fd1\u4e9b\u5e74\u6765\uff0c\u968f\u7740\u4eba\u4eec\u5bf9\u7eb3\u7c73\u9897\u7c92\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u53ca\u5176\u8c03\u63a7\u7684\u4e0d\u65ad\u6df1\u5165\u7406\u89e3\uff0c\u7814\u53d1\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u7eb3\u7c73\u9897\u7c92\u7684\u65b0\u578b\u6750\u6599\u3002\u5176\u4e2d\uff0c\u8fd9\u7c7b\u6750\u6599\u53ef\u5206\u4e3a\u7eb3\u7c73\u7ea7\u8d85\u7ed3\u6784\u548c\u5408\u6210\u7ed3\u6784\u3002\u5728\u6750\u6599\u79d1\u5b66\u4e2d\uff0c\u8bbe\u8ba1\u6b64\u7c7b\u8d85\u7ed3\u6784\u7684\u5de5\u7a0b\u4ecd\u7136\u5b58\u5728\u5f88\u5927\u7684\u6311\u6218\u6027\u3002\u56e0\u4e3a\u8fd9\u4e9b\u8d85\u7ed3\u6784\u5177\u6709\u826f\u597d\u7684\u6709\u5e8f\u6027\u3001\u4f18\u5f02\u7684\u53ef\u8c03\u78c1\u6027\u3001\u50ac\u5316\u6027\u3001\u5149\u5b66\u548c\u7535\u5b50\u6027\u80fd\uff0c\u56e0\u800c\u5176\u5728\u5149\u7535\u3001\u50ac\u5316\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/p>\n<p>\u867d\u7136\u76ee\u524d\u5728\u751f\u7269\u6750\u6599\u7684\u5c42\u6b21\u7ec4\u88c5\u65b9\u9762\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u6210\u529f\uff0c\u4f46\u662f\u5173\u4e8e\u57fa\u4e8e\u7eb3\u7c73\u9897\u7c92\u6709\u5e8f\u7ec4\u88c5\u7684\u8d85\u7ed3\u6784\u4ecd\u7136\u5f88\u5c11\u62a5\u9053\uff0c\u4e3b\u8981\u662f\u56e0\u4e3a\u5bf9\u5f62\u6210\u673a\u5236\u7684\u7f3a\u4e4f\u7406\u89e3\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8bb8\u591a\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u5982ZnO\u3001TiO<sub>2<\/sub>\u3001Fe<sub>2<\/sub>O<sub>3<\/sub>\u548cCuO\uff09\u7684\u8d85\u7ed3\u6784\u5df2\u88ab\u5408\u6210\u62a5\u9053\u3002\u7136\u800c\uff0c\u5728\u4e24\u79cd\u4e0d\u76f8\u5173\u7684\u7269\u79cd\uff08\u5982\u6742\u591a\u9178\u76d0\uff08POMs\uff09\u548c\u91d1\u5c5e\u6c27\u5316\u7269\uff09\u4e2d\u5229\u7528van der Waals\u5408\u6210\u5f02\u8d28\u6750\u6599\u4e5f\u4ecd\u7136\u5f88\u5c11\u62a5\u9053\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u6e05\u534e\u5927\u5b66\u7684\u738b\u8bad\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5355\u6b65\u6eb6\u5242\u70ed\u6cd5\u8bbe\u8ba1\u5236\u5907\u7684\u7531Keggin\u578b\u78f7\u94bc\u9178\u76d0\uff08POMs\uff09\u548c\u6c27\u5316\u9506\uff08ZrO<sub>2<\/sub>\uff09\u7ec4\u6210\u5e76\u4e14\u5229\u7528Van der Waals\u96c6\u6210\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u5f02\u8d28\u6750\u6599\uff08POM-ZrO<sub>2<\/sub>\uff09\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u7ed3\u6784\u662f\u5728\u4e0d\u4f7f\u7528\u4efb\u4f55\u6709\u673a\u8868\u9762\u6d3b\u6027\u5242\u7684\u60c5\u51b5\u4e0b\uff0c\u901a\u8fc7\u4e00\u79cd\u7279\u6b8a\u7684\u975e\u7ecf\u5178\u7684\u805a\u96c6\u751f\u957f\u673a\u5236\u5f62\u6210\u7684\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u7eff\u8272\u6c27\u5316\u5242\u5728\u6709\u673a\u5316\u5b66\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u56e0\u6b64\u5229\u7528\u786b\u919a\u50ac\u5316\u6c27\u5316\u5b9e\u9a8c\u4f5c\u4e3a\u5b9e\u4f8b\u3002\u901a\u8fc7\u5b9e\u9a8c\u53d1\u73b0\uff0c\u8fd9\u79cd\u5f02\u8d28\u6750\u6599\u662f\u4e00\u79cd\u6709\u6548\u7684\u786b\u919a\u50ac\u5316\u6c27\u5316\u50ac\u5316\u5242\u3002\u5176\u4e2d\uff0c\u5bcc\u6c27\u7684POM\u7ec4\u5206\u7684\u72ec\u7279\u6c27\u5316\u8fd8\u539f\u7279\u6027\u548cZrO<sub>2<\/sub>\u7684\u8def\u6613\u65af\u9178\u6027\u7279\u5f81\u4e3a\u8be5\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u8db3\u591f\u7684\u9a71\u52a8\u529b\u3002\u540c\u65f6\u5b9e\u9a8c\u7ed3\u679c\u8fd8\u8868\u660e\uff0c\u5728\u6ca1\u6709\u50ac\u5316\u5242\u7684\u60c5\u51b5\u4e0b\uff0c\u867d\u7136H<sub>2<\/sub>O<sub>2<\/sub>\u5bf9\u786b\u919a\u6216\u4e9a\u781c\u7684\u6c27\u5316\u8f6c\u5316\u662f\u70ed\u529b\u5b66\u4e0a\u6709\u5229\u7684\uff0c\u4f46\u662f\u786b\u919a\u6216\u4e9a\u781c\u5747\u4e0d\u4f1a\u88ab\u6c27\u5316\u5242\u8fc5\u901f\u7684\u6c27\u5316\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a<strong>\u201cVan der Waals Integrated Hybrid POM-Zirconia Flexible Belt-Like Superstructures\u201d<\/strong>\u53d1\u5e03\u5728\u8457\u540d\u671f\u520a<strong>Adv. Mater<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001PZBS\u7684\u7ed3\u6784\u8868\u5f81<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-191999\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-12.jpg\" alt=\"\" width=\"600\" height=\"460\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/1-12-300x230.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a-c\uff09\u4e0d\u540c\u653e\u5927\u500d\u6570\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08d\uff09STEM\u56fe\u7247\uff1b<\/p>\n<p>\uff08e\uff09HRTEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08f\uff09\u7ebf\u626b\u63cf\u5149\u8c31\uff1b<\/p>\n<p>\uff08g\uff09\u901a\u8fc7EDX\u8fdb\u884c\u5143\u7d20\u6620\u5c04\u3002<\/p>\n<p><strong>\u56fe\u4e8c\u3001ZrO<sub>2<\/sub>\u7eb3\u7c73\u7247\u548cPZBS\u7684\u5236\u5907\u793a\u610f\u56fe\u53ca\u5176\u8868\u5f81<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192000\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-12.jpg\" alt=\"\" width=\"600\" height=\"454\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/2-12-300x227.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09\u4ecb\u5b54ZrO<sub>2<\/sub>\u548cPZBS\u5728\u57fa\u4e8e\u805a\u96c6\u7684\u81ea\u7ec4\u88c5\u673a\u5236\u751f\u957f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u81ea\u7ec4\u88c5\u524dZrO<sub>2<\/sub> NPs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08c\uff09\u4ecb\u5b54ZrO<sub>2<\/sub>\u5e26\u72b6\u8d85\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08d\uff09\u4ecb\u5b54ZrO<sub>2<\/sub>\u5e26\u72b6\u8d85\u7ed3\u6784\u7684N<sub>2<\/sub>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\u3002<\/p>\n<p><strong>\u56fe\u4e09\u3001ZrO<sub>2<\/sub>\u548cPZBS\u7684XPS\u5149\u8c31\u548cMAS <sup>31<\/sup>P NMR\u5149\u8c31<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192001\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-12.jpg\" alt=\"\" width=\"600\" height=\"386\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/3-12-300x193.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a-b\uff09ZrO<sub>2<\/sub>\u548cPZBS\u7684XPS\u5149\u8c31\uff08a\uff09Zr 3d<sub>3\/2<\/sub>\u548cZr 3d<sub>5\/2<\/sub>\u5cf0\u3001\uff08b\uff09O 1s\u3001\uff08c\uff09Mo 3d<sub>3\/2<\/sub>\u548cMo 3d<sub>5\/2<\/sub>\u5cf0\u548c\uff08d\uff09P 2p\u7684\u7ed3\u5408\u80fd\uff1b<\/p>\n<p>\uff08e\uff09\u6e38\u79bbPOM\u548cPZBS\u7684MAS <sup>31<\/sup>P NMR\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001\u5bf9\u6bd4\u4e0d\u540c\u50ac\u5316\u5242\u7684\u6c27\u5316\u6027\u80fd<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192002\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-12.jpg\" alt=\"\" width=\"600\" height=\"374\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/12\/4-12-300x187.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09\u7b2c\u4e00\u6b21\u8fd0\u884c\u7684\u53cd\u5e94\u65f6\u95f4\u4e0e\u4e8c\u82ef\u786b\u919a\u8f6c\u5316\u7387\u7684\u5173\u7cfb\uff1b<\/p>\n<p>\uff08b\uff09\u4e8c\u82ef\u786b\u919a\u5728PZBS\u50ac\u5316\u5242\u4e0a\u7684\u518d\u5faa\u73af\u6027\u80fd\u3001\u8f6c\u5316\u7387\u548c\u9009\u62e9\u6027\u5173\u7cfb\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u5355\u6b65\u6eb6\u5242\u70ed\u6cd5\u6765\u8bbe\u8ba1\u7531\u4e24\u4e2a\u7ed3\u6784\u4e0d\u540c\u7684\u7269\u79cd\u81ea\u7ec4\u88c5\u5e76\u5229\u7528Van der Waals\u96c6\u6210\u7684\u5f02\u8d28\u6750\u6599\u7684\u8d85\u7ed3\u6784\u3002\u901a\u8fc7\u975e\u7ecf\u5178\u7684\u805a\u96c6\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u751f\u957f\u800c\u5f62\u6210\u7684\u3002\u5176\u4e2d\uff0c\u5f15\u5165POM\u53ef\u4ee5\u63d0\u9ad8\u6240\u5236\u5907\u7684POM-ZrO<sub>2<\/sub>\u8d85\u7ed3\u6784\u7684\u5f39\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\u3002\u7531\u4e8e\u8be5\u6750\u6599\u7684\u5f62\u6001\u3001\u7ec4\u6210\u548c\u7ed3\u6784\u7684\u7279\u6b8a\u6027\uff0c\u5176\u5bf9\u786b\u919a\u7684\u50ac\u5316\u6c27\u5316\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6027\u80fd\u3002\u6b64\u5916\uff0c\u8be5\u6750\u6599\u8fd8\u5728\u5149\u50ac\u5316\u5242\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u7535\u5316\u5b66\u4f20\u611f\u5668\u7b49\u9886\u57df\u5177\u6709\u5e94\u7528\u6f5c\u529b\u3002\u603b\u4e4b\uff0c\u8be5\u7b56\u7565\u53ef\u80fd\u4e3a\u5408\u7406\u8bbe\u8ba1\u590d\u6742\u7684\u5f02\u8d28\u50ac\u5316\u5242\u7ec4\u88c5\u4f53\u63d0\u4f9b\u4e00\u6761\u53ef\u884c\u7684\u9014\u5f84\uff0c\u5e76\u5728\u4e0d\u540c\u9886\u57df\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adma.201906794\" target=\"_blank\" rel=\"noopener\">Van der Waals Integrated Hybrid POM-Zirconia Flexible Belt-Like Superstructures<\/a><\/strong>\uff08<em>Adv. Mater.<\/em>, <strong>2019<\/strong>, DOI:10.1002\/adma.201906794\uff09<\/p>\n<p style=\"text-align: center;\"><strong>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n<p><strong>\u738b\u8bad\uff0c\u535a\u58eb\uff0c\u6559\u6388\u3002\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u201d\u7279\u8058\u6559\u6388\uff0c\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u7cfb\u4e3b\u4efb<\/strong>\u3002\u4e3b\u8981\u4ece\u4e8b\u65e0\u673a\u7eb3\u7c73\u6750\u6599\u5316\u5b66\u7814\u7a76\uff0c\u5728\u65e0\u673a\u7eb3\u7c73\u6676\u4f53\u65b0\u7ed3\u6784\u63a7\u5236\u5408\u6210\u3001\u5f62\u6210\u673a\u5236\u53ca\u7ec4\u88c5\u9886\u57df\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\u3002\u5171\u53d1\u8868SCI\u8bba\u6587200\u4f59\u7bc7\u3002<\/p>\n<p>\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u8fd1\u4e9b\u5e74\u6765\uff0c\u968f\u7740\u4eba\u4eec\u5bf9\u7eb3\u7c73\u9897\u7c92\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u53ca\u5176\u8c03\u63a7\u7684\u4e0d\u65ad\u6df1\u5165\u7406\u89e3\uff0c\u7814\u53d1\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u7eb3\u7c73\u9897\u7c92\u7684\u65b0\u578b\u6750\u6599\u3002\u5176\u4e2d\uff0c\u8fd9\u7c7b\u6750\u6599\u53ef\u5206\u4e3a\u7eb3\u7c73\u7ea7\u8d85\u7ed3\u6784\u548c\u5408\u6210\u7ed3\u6784\u3002\u5728&#8230;<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4264],"class_list":["post-191998","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-4264"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/191998"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=191998"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/191998\/revisions"}],"predecessor-version":[{"id":192451,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/191998\/revisions\/192451"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=191998"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=191998"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=191998"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}