{"id":192213,"date":"2019-12-21T06:16:43","date_gmt":"2019-12-20T22:16:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=192213"},"modified":"2019-12-20T21:03:26","modified_gmt":"2019-12-20T13:03:26","slug":"2019%e6%96%b0%e7%a7%91%e9%99%a2%e5%a3%ab%ef%bc%9a%e6%96%bd%e5%89%91%e6%9e%97%e3%80%81%e4%bf%9e%e4%b9%a6%e5%ae%8f%e3%80%81%e5%bc%a0%e9%94%a6%e3%80%81%e6%9d%8e%e6%99%af%e8%99%b9%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=192213","title":{"rendered":"2019\u65b0\u79d1\u9662\u58eb\uff1a\u65bd\u5251\u6797\u3001\u4fde\u4e66\u5b8f\u3001\u5f20\u9526\u3001\u674e\u666f\u8679\u7814\u7a76\u56e2\u961f\u7eaa\u5b9e"},"content":{"rendered":"

\u65bd\u5251\u6797<\/b><\/strong><\/h3>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d \u9886\u519b\u4eba\u624d\u3002\u56fd\u5bb6\u91cd\u70b9\u7eb3\u7c73\u4e13\u9879\u201c\u534a\u5c01\u95ed\u7a7a\u95f4\u673a\u52a8\u8f66\u6392\u653e\u6c61\u67d3\u7269\u6cbb\u7406\u7684\u5173\u952e\u7eb3\u7c73\u6280\u672f\u201d\uff082013-2017\uff09\u9996\u5e2d\u79d1\u5b66\u5bb6\u3002\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\uff0c\u56fd\u9645\u4ecb\u5b54\u6750\u6599\u5b66\u4f1a\u7406\u4e8b\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong>\u957f\u671f\u4ece\u4e8b\u5148\u8fdb\u9676\u74f7\u5236\u5907\u79d1\u5b66\u4e0e\u70e7\u7ed3\u7406\u8bba\u3001\u4ecb\u5b54\u7ed3\u6784\u7eb3\u7c73\u6750\u6599\u53ef\u63a7\u5408\u6210\u4e0e\u50ac\u5316\u548c\u751f\u7269\u5e94\u7528\u7814\u7a76\uff0c\u57fa\u4e8e\u65e0\u673a\u7eb3\u7c73\u7ed3\u6784\u7684\u836f\u7269\u8f93\u8fd0\u4e0e\u8bca\u7597\u4e00\u4f53\u5316\uff0c\u8fd1\u5e74\u63d0\u51fa\u7eb3\u7c73\u50ac\u5316\u533b\u5b66\u7814\u7a76\u65b0\u65b9\u5411\u3001\u9762\u5411\u80fd\u6e90\/\u73af\u5883\u5e94\u7528\u7684\u65e0\u673a\u5149\/\u7535\u50ac\u5316\u6750\u6599\u3002\u5728Nature Nanotech.\u3001Nature Comm.\u3001Adv. Mater.\u3001JACS\u3001Chem. Mater.\u7b49\u56fd\u9645\u9876\u7ea7\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u6587400\u4f59\u7bc7\uff0cSCI\u4ed6\u5f1530000\u4f59\u6b21\uff0cH-index\u4e3a105\uff0c\u00a02015-2019\u5e74\u5ea6\u8fde\u7eed\u5165\u9009\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n

\u627f\u62c5\u9879\u76ee&\u6210\u679c\u5956\u52b1<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

2005\u5e74\uff0c\u83b7\u4e24\u9662\u9662\u58eb\u8bc4\u9009\u4e2d\u56fd\u5341\u5927\u79d1\u6280\u8fdb\u5c55\uff1b<\/p>\n

2008\u5e74\uff0c\u201c\u4ecb\u5b54\u4e3b\u5ba2\u4f53\u590d\u5408\u6750\u6599\u7ec4\u88c5\u65b9\u6cd5\u4e0e\u50ac\u5316\u6027\u80fd\u7814\u7a76\u201d\u9879\u76ee\u83b7\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\uff1b<\/p>\n

2011\u5e74\uff0c\u201c\u4ecb\u5b54\u57fa\u590d\u5408\u6750\u6599\u8bbe\u8ba1\u5408\u6210\u3001\u975e\u5747\u76f8\u50ac\u5316\u6027\u80fd\u4e0e\u5e94\u7528\u63a2\u7d22\u201d\u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u4e00\u9879\uff1b<\/p>\n

2014\u5e74\uff0c\u201c\u7a7a\u5fc3\u4ecb\u5b54\u6c27\u5316\u7845\u7eb3\u7c73\u9897\u7c92\u7684\u5236\u5907\u3001\u836f\u7269\u7f13\/\u63a7\u91ca\u548c\u78c1\u529f\u80fd\u5316\u201d\u9879\u76ee\u83b7\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\u3002<\/p>\n

\u90e8\u5206\u7814\u7a76\u8fdb\u5c55\uff1a<\/b><\/strong><\/p>\n

1<\/b><\/strong>\u00a0\u901a\u8fc7\u94dc\u5f15\u5165\u6539\u8fdbCO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5149\u50ac\u5316\u8fd8\u539f\u6d3b\u6027\uff0c<\/b><\/strong>\u6765<\/b><\/strong>\u7a33\u5b9aCeO<\/b><\/strong>2-x<\/b><\/sub><\/strong>\u4e2d\u7684\u6c27\u7a7a\u4f4d\u751f\u6210<\/b><\/strong>\uff5c<\/b><\/strong>A<\/b><\/strong>CS C<\/b><\/strong>atalysis<\/b><\/strong><\/p>\n

\u5728\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u7684\u6676\u683c\u4e2d\u5f15\u5165O\u7a7a\u4f4d\u53ef\u4ee5\u6539\u53d8\u5176\u56fa\u6709\u7684\u7535\u5b50\u6027\u8d28\u548c\u5e26\u9699\uff0c\u4ece\u800c\u589e\u5f3a\u53ef\u89c1\u5149\u5438\u6536\uff0c\u4fc3\u8fdb\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\/\u8f6c\u79fb\uff0c\u4ece\u800c\u63d0\u9ad8\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0cO\u7a7a\u4f4d\u53ef\u4ee5\u5438\u9644\u5e76\u6fc0\u6d3b\u5149\u50ac\u5316\u5242\u8868\u9762\u7684CO2<\/sub>\uff0c\u4f46\u5728\u5149\u8fd8\u539f\u53cd\u5e94\u4e2d\u5bb9\u6613\u88abO\u539f\u5b50\u586b\u5145\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u94dc\u88ab\u5f15\u5165\u4ee5\u589e\u52a0O\u7a7a\u4f4d\u6d53\u5ea6\u4fc3\u8fdb\u4e86CeO2-x<\/sub>\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3002\u7814\u7a76\u8868\u660e\u4e0eCeO2-x<\/sub>\u76f8\u6bd4\uff0c\u6837\u54c1Cu\/ CeO2-x<\/sub>-0.1\u57285h\u7684\u8f90\u5c04\u4e0b\u663e\u793a\u6700\u9ad8\u7684\u5149\u50ac\u5316\u6d3b\u6027\u4e0eCO\u6536\u76ca\u7387\uff088.25\u03bcmol g-1<\/sup>\uff09,\u7ea6\u662fCeO2-x<\/sub>\u768426\u500d\u3002\u6839\u636e\u62c9\u66fc\u5149\u8c31\u548cXPS\u5149\u8c31\u5206\u6790\uff0cCu\u7684\u5f15\u5165\u6709\u5229\u4e8eCeO2-x<\/sub>\u4e2dO\u7a7a\u4f4d\u5728\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u7684\u5316\u5b66\u7a33\u5b9a\uff0c\u8fd9\u662f\u63d0\u9ad8\u548c\u7ef4\u6301\u5149\u50ac\u5316\u6d3b\u6027\u7684\u539f\u56e0\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cOxygen vacancy generation and stabilization in CeO2-x <\/sub>by Cuintroduction with improved CO2 photocatalytic reduction activity\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/acscatal.8b03975<\/p>\n

CeO2-x<\/sub>\u548cCu\/CeO2-x<\/sub>-0.1\u8868\u9762O1s<\/sub>\u7684\u9ad8\u5206\u8fa8\u7387XPS\u8c31<\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u7845\u5316\u9541\u7eb3\u7c73\u9897\u7c92\u4f5c\u4e3a\u764c\u75c7\u9965\u997f<\/b><\/strong>\u7597\u6cd5<\/b><\/strong>\u7684\u8131\u6c27\u5242<\/b><\/strong>\uff5c<\/b><\/strong>Nature<\/b><\/strong>\u00a0Nanotechnology<\/b><\/strong><\/p>\n

\u4e00\u79cd\u5feb\u901f\u5438\u6536\u5206\u5b50\u6c27\u7684\u6750\u6599(\u88ab\u79f0\u4e3a\u8131\u6c27\u5242(DOA))\u5177\u6709\u591a\u79cd\u5de5\u4e1a\u5e94\u7528\uff0c\u5982\u98df\u54c1\u4fdd\u9c9c\u3001\u91d1\u5c5e\u9632\u8150\u548c\u7164\u70ad\u8131\u6c27\u3002\u8003\u8651\u5230\u6c27\u6c14\u5bf9\u764c\u75c7\u7684\u751f\u957f\u81f3\u5173\u91cd\u8981\uff0c\u901a\u8fc7\u6d88\u8017\u7624\u5185\u6c27\u6c14\u6765\u997f\u6b7b\u80bf\u7624\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u6709\u7528\u7684\u6297\u764c\u7b56\u7565\u3002\u5728\u8fd9\u91cc\uff0c\u65bd\u5251\u6797\u6559\u6388\u56e2\u961f\u7b49\u4eba\u91c7\u7528\u81ea\u8513\u5ef6\u9ad8\u6e29\u5408\u6210\u7b56\u7565\u5236\u5907\u7eb3\u7c73\u7c92\u5b50\uff0c\u5c55\u793a\u4e86\u4e00\u79cd\u53ef\u6ce8\u5c04\u7684\u805a\u5408\u7269\u4fee\u9970\u7684\u9541\u7845\u5316\u7269(Mg2<\/sub>Si)\u7eb3\u7c73\u9897\u7c92\uff0c\u5b83\u53ef\u4ee5\u6e05\u9664\u80bf\u7624\u4e2d\u7684\u6c27\uff0c\u5e76\u5f62\u6210\u526f\u4ea7\u7269\uff0c\u963b\u6b62\u80bf\u7624\u6bdb\u7ec6\u8840\u7ba1\u518d\u6c27\u5316\u3002\u5728\u9178\u6027\u80bf\u7624\u5fae\u73af\u5883\u4e2d\uff0cMg2<\/sub>Si\u91ca\u653e\u7845\u70f7\uff0c\u7845\u70f7\u80fd\u6709\u6548\u5730\u4e0e\u7ec4\u7ec7\u6eb6\u89e3\u7684\u6c27\u6c14\u548c\u8840\u7ea2\u86cb\u767d\u8f93\u5165\u7684\u6c27\u6c14\u53cd\u5e94\uff0c\u5f62\u6210\u6c27\u5316\u7845(SiO2<\/sub>)\u805a\u96c6\u7269\u3002SiO2<\/sub>\u7684\u539f\u4f4d\u5f62\u6210\u53ef\u4ee5\u963b\u65ad\u80bf\u7624\u8840\u6db2\u4e2d\u7684\u6bdb\u7ec6\u8840\u7ba1\uff0c\u9632\u6b62\u80bf\u7624\u83b7\u5f97\u65b0\u7684\u6c27\u6c14\u548c\u8425\u517b\u7269\u8d28\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMagnesium silicide nanoparticles as a deoxygenation agent for cancer starvation therapy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Nanotechnology\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/NNANO.2016.280<\/p>\n

MS NPs\u4f5c\u4e3a\u80bf\u7624\u5185DOA\u7279\u5f02\u6027\u764c\u9965\u997f\u6cbb\u7597\u7684\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

3 <\/b><\/strong>\u70ed\u6e17\u578b<\/b><\/strong>\u4e8c\u7ef4<\/b><\/strong>Ta<\/b><\/strong>4<\/b><\/sub><\/strong>C<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0MXene<\/b><\/strong>\uff5c<\/b><\/strong>Ad<\/b><\/strong>va<\/b><\/strong>n<\/b><\/strong>ced M<\/b><\/strong>aterials<\/b><\/strong><\/p>\n

\u9ad8\u6e29\u56fa\u76f8\u53cd\u5e94\u548c\u70e7\u7ed3\u5236\u5907\u7684\u5927\u5c3a\u5bf8\u521a\u6027\u9676\u74f7\u5757\u4ece\u672a\u8003\u8651\u8fc7\u53ef\u80fd\u8fdb\u5165\u8840\u7ba1\u5185\u5faa\u73af\u7528\u4e8e\u751f\u7269\u533b\u5b66\u5e94\u7528\uff0c\u7279\u522b\u662f\u5728\u6297\u764c\u65b9\u9762\u3002\u672c\u6587\u9996\u6b21\u62a5\u9053MAX\u9676\u74f7\u751f\u7269\u6750\u6599\u5728\u53cc\u6a21\u5149\u58f0\/\u8ba1\u7b97\u673a\u65ad\u5c42\u6210\u50cf\u65b9\u9762\u8868\u73b0\u51fa\u72ec\u7279\u7684\u529f\u80fd\uff0c\u5e76\u5bf9\u80bf\u7624\u5728\u4f53\u5185\u88ab\u5265\u79bb\u6210\u8d85\u8584\u7eb3\u7c73\u8584\u7247(MXene)\u540e\u7684\u5149\u70ed\u6d88\u878d\u975e\u5e38\u6709\u6548\u3002\u6784\u5efa\u57fa\u4e8e\u4e8c\u7ef4Ta4<\/sub>C3<\/sub>\u00a0MXene\u7eb3\u7c73\u7247\u6784\u5efa\u7684\u4f53\u5185\u53cc\u6a21\u5f0fPA\/CT\u6210\u50cf\u4e0e\u4f53\u5185\u5149\u70ed\u6cbb\u7597\u6574\u5408\u7684\u8bca\u7597\u4e00\u4f53\u5316\u7eb3\u7c73\u5e73\u53f0\uff0c\u5229\u7528Ta4<\/sub>C3<\/sub>\u00a0MXene\u7eb3\u7c73\u7247\u7684\u8d85\u8584\u5c42\u72b6\u7ed3\u6784\u548cTa\u5143\u7d20\u5177\u6709\u7684CT\u4fe1\u53f7\u589e\u5f3a\u7406\u5316\u6027\u80fd\uff0c\u5728\u53ef\u63a7\u5916\u573a\uff08\u8fd1\u7ea2\u5916\u5149\uff0cX\u5c04\u7ebf\uff09\u523a\u6fc0\u4e0b\uff0c\u5b9e\u73b0\u9ad8\u6548\u7684\u4f53\u5185\u5149\u70ed\u8f6c\u6362\u548c\u4f53\u5185PA\/CT\u53cc\u6a21\u5f0f\u6210\u50cf\uff0c\u8fbe\u5230\u70ed\u6d88\u878d\u80bf\u7624\u7ec6\u80de\u800c\u4e0d\u5bf9\u6b63\u5e38\u7ec4\u7ec7\u4ea7\u751f\u6bd2\u526f\u4f5c\u7528\u7684\u76ee\u7684\uff0c\u540c\u65f6\u8fd8\u517c\u5177\u6210\u50cf\u9020\u5f71\u589e\u5f3a\u7684\u529f\u80fd\u3002\u8be5\u8bca\u7597\u4e00\u4f53\u5316\u5e73\u53f0\u5177\u5907\u826f\u597d\u7684\u4e34\u5e8a\u8f6c\u5316\u524d\u666f\uff0c\u6709\u671b\u63a8\u52a8\u65b0\u578b\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u5728\u80bf\u7624\u8bca\u7597\u548c\u91cd\u5927\u75be\u75c5\u4e2d\u7684\u5e7f\u6cdb\u63a2\u7d22\u548c\u5e94\u7528\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTheranostic 2D Tantalum Carbide (MXene)\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002\u00a0<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adma.201703284<\/p>\n

\u5206\u5c42\u5408\u6210Ta4<\/sub>C3<\/sub>\u7eb3\u7c73\u7247\u7684\u53ca\u4f53PA\/CT\u53cc\u6a21\u6210\u50cf\u539f\u7406\u56fe<\/p>\n

\"\"<\/p>\n

4<\/b><\/strong>\u00a0<\/b><\/strong>\u901a\u8fc7\u7eb3\u7c73\u50ac\u5316\u5242\u4f20\u9012\u7684\u80bf\u7624\u9009\u62e9\u6027\u50ac\u5316\u7eb3\u7c73\u836f\u7269<\/b><\/strong>\uff5cN<\/b><\/strong>ature C<\/b><\/strong>ommunications<\/b><\/strong><\/p>\n

\u4e0e\u5927\u591a\u6570\u6b63\u5e38\u7ec4\u7ec7\u7ec6\u80de\u76f8\u6bd4\uff0c\u80bf\u7624\u7ec6\u80de\u6709\u4e0d\u540c\u7684\u4ee3\u8c22\u9014\u5f84\u3002\u7531\u6b64\u4ea7\u751f\u7684\u80bf\u7624\u5fae\u73af\u5883\u4e3a\u9009\u62e9\u6027\u80bf\u7624\u6cbb\u7597\u63d0\u4f9b\u4e86\u72ec\u7279\u7684\u7406\u5316\u6761\u4ef6\u3002\u5728\u8fd9\u91cc\uff0c\u65bd\u5251\u6797\u6559\u6388\u56e2\u961f\u4ecb\u7ecd\u4e86\u4e00\u4e2a\u6982\u5ff5\uff0c\u5e8f\u8d2f\u50ac\u5316\u7eb3\u7c73\u836f\u7269\u4e3a\u6709\u6548\u7684\u80bf\u7624\u6cbb\u7597\uff0c\u901a\u8fc7\u8bbe\u8ba1\u548c\u63d0\u4f9b\u751f\u7269\u76f8\u5bb9\u6027\u7eb3\u7c73\u50ac\u5316\u5242\u5230\u80bf\u7624\u90e8\u4f4d\u3002\u5c06\u5929\u7136\u8461\u8404\u7cd6\u6c27\u5316\u9176(GOD\uff0c\u9176\u50ac\u5316\u5242)\u548c\u8d85\u7ec6Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u9897\u7c92(\u65e0\u673a\u7eb3\u7c73\u9176\uff0c\u82ac\u987f\u53cd\u5e94\u50ac\u5316\u5242)\u96c6\u6210\u5230\u5927\u5b54\u5f84\u3001\u53ef\u751f\u7269\u964d\u89e3\u7684\u6811\u72b6\u4e8c\u6c27\u5316\u7845\u7eb3\u7c73\u9897\u7c92\u4e2d\uff0c\u5236\u5907\u6709\u5e8f\u7684\u7eb3\u7c73\u50ac\u5316\u5242\u3002\u8fde\u7eed\u7eb3\u7c73\u50ac\u5316\u5242GOD\u53ef\u4ee5\u6709\u6548\u7684\u6d88\u8017\u80bf\u7624\u7ec6\u80de\u4e2d\u7684\u8461\u8404\u7cd6\uff0c\u540c\u65f6\u5728Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u9897\u7c92\u5bf9\u5f31\u9178\u6027\u80bf\u7624\u5fae\u73af\u5883\u7684\u53cd\u5e94\u4e2d\u751f\u6210\u5927\u91cf\u7684H2<\/sub>O2<\/sub>\u3002\u8fd9\u4e9b\u9ad8\u6bd2\u6027\u7684\u7f9f\u57fa\u81ea\u7531\u57fa\u901a\u8fc7\u8fd9\u4e9b\u8fde\u7eed\u7684\u50ac\u5316\u53cd\u5e94\u6765\u89e6\u53d1\u80bf\u7624\u7ec6\u80de\u7684\u51cb\u4ea1\u548c\u6b7b\u4ea1\u3002\u76ee\u524d\u7684\u5de5\u4f5c\u8bc1\u660e\u4e86\u50ac\u5316\u7eb3\u7c73\u836f\u7269\u7684\u6982\u5ff5\uff0c\u540c\u65f6\u63a5\u8fd1\u9009\u62e9\u6027\u548c\u6548\u7387\u7684\u80bf\u7624\u6cbb\u7597\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTumor-selective catalytic nanomedicine by nanocatalyst delivery\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Communications\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41467-017-00424-8<\/p>\n

\u4f53\u5916\u7ec6\u80de\u6bd2\u6027\u6982\u51b5\u548c\u7ec6\u80de\u5185\u50ac\u5316\u673a\u5236<\/p>\n

\"\"<\/p>\n

\u65bd\u5251\u6797\u9662\u58eb\u8bfe\u9898\u7ec4\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

http:\/\/www.skl.sic.cas.cn\/yjly\/swyy\/sjl\/<\/b><\/strong><\/p>\n

\u4fde\u4e66\u5b8f<\/b><\/strong><\/h3>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u4e2d\u56fd\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u6559\u6388\u3001\u526f\u9662\u957f\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u5956\u52b1\u8ba1\u5212\u201d\u7279\u8058\u6559\u6388\uff1b\u56fd\u5bb6\u91cd\u5927\u79d1\u5b66\u7814\u7a76\u8ba1\u5212\u9996\u5e2d\u79d1\u5b66\u5bb6\u3002\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\u957f\u671f\u4ece\u4e8b\u4eff\u751f\u9ad8\u6027\u80fd\u7eb3\u7c73\u590d\u5408\u7ed3\u6784\u6750\u6599\u3001\u81ea\u7ec4\u88c5\u53ca\u5e94\u7528\uff1b\u805a\u5408\u7269\u63a7\u5236\u6676\u5316\u4e0e\u6a21\u62df\u751f\u7269\u77ff\u5316\uff1b\u591a\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u6a21\u677f\u8bf1\u5bfc\u5408\u6210\u548c\u7ec4\u88c5\u6280\u672f\uff1b\u65b0\u578b\u65e0\u673a-\u6709\u673a\u6742\u5316\u6750\u6599\u7684\u5236\u5907\u3001\u6027\u80fd\u4e0e\u7ec4\u88c5\u4f53\u529f\u80fd\uff1b\u9762\u5411\u80fd\u6e90\u3001\u73af\u5883\u9886\u57df\u5e94\u7528\u7684\u65b0\u578b\u78b3\u6750\u6599\u7684\u5236\u5907\u548c\u80fd\u91cf\u5b58\u50a8\uff1b\u7eb3\u7c73\u6750\u6599\u7684\u5149\u3001\u7535\u3001\u78c1\u6027\u80fd\u8c03\u63a7\u548c\u7eb3\u7c73\u50ac\u5316\u6548\u5e94\u7b49\u7814\u7a76\uff0c\u5728Science, Nature Materials, Nature Nanotechnology, Science Adv., Nature Commun., J. Am. Chem. Soc., Adv. Mater.\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868\u8bba\u6587400\u4f59\u7bc7\uff0c\u3002SCI\u8bba\u6587\u4ed6\u5f1530000\u4f59\u6b21\uff0cH\u56e0\u5b50122\uff0c2014-2019\u5e74\u8fde\u7eed\u5165\u9009\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n

\u627f\u62c5\u9879\u76ee&\u6210\u679c\u5956\u52b1<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

2010\u5e74\uff0c\u201c\u590d\u6742\u5f62\u6001\u548c\u7ed3\u6784\u7684\u65e0\u673a\u529f\u80fd\u6750\u6599\u7684\u6784\u7b51\u3001\u81ea\u7ec4\u88c5\u539f\u7406\u53ca\u6027\u80fd\u7814\u7a76\u201d\u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\uff1b<\/p>\n

2014\u5e74\uff0c\u83b7\u5b89\u5fbd\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\uff1b<\/p>\n

2016\u5e74\uff0c\u201c\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\u7684\u5b8f\u91cf\u5236\u5907\u4e0e\u5b8f\u89c2\u5c3a\u5ea6\u7ec4\u88c5\u4f53\u7684\u529f\u80fd\u5316\u7814\u7a76\u201d \u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\uff1b<\/p>\n

2018\u5e74\uff0c\u83b7\u5b89\u5fbd\u7701\u91cd\u5927\u79d1\u6280\u6210\u5c31\u5956\u3002<\/p>\n

\u90e8\u5206\u7814\u7a76\u8fdb\u5c55\uff1a<\/b><\/strong><\/p>\n

1<\/b><\/strong>\u00a0\u901a\u8fc7\u9884\u5148\u8bbe\u8ba1\u7684\u57fa\u8d28\u5bfc\u5411\u77ff\u5316\u5408\u6210\u73cd\u73e0<\/b><\/strong>\u8d28<\/b><\/strong>\uff5c<\/b><\/strong>Science<\/b><\/strong><\/p>\n

\u867d\u7136\u4eff\u751f\u8bbe\u8ba1\u6709\u671b\u5728\u63a2\u7d22\u672a\u6765\u7ed3\u6784\u6750\u6599\u4e2d\u53d1\u6325\u5173\u952e\u4f5c\u7528\uff0c\u4f46\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u65b9\u4fbf\u5730\u5236\u5907\u5757\u72b6\u4eff\u751f\u6750\u6599\u4ecd\u7136\u662f\u4e00\u4e2a\u4e3b\u8981\u7684\u6311\u6218\u3002\u5728\u8fd9\u91cc\uff0c\u4fde\u4e66\u5b8f\u6559\u6388\u56e2\u961f\u7b49\u4eba\u63cf\u8ff0\u4e86\u4e00\u79cd\u4e2d\u5c3a\u5ea6\u7684\u201c\u7ec4\u5408-\u77ff\u5316\u201d\u65b9\u6cd5\uff0c\u5176\u7075\u611f\u6765\u81ea\u4e8e\u8f6f\u4f53\u52a8\u7269\u7684\u81ea\u7136\u8fc7\u7a0b\uff0c\u5373\u5236\u9020\u5927\u91cf\u5408\u6210\u73cd\u73e0\u8d28\uff0c\u8fd9\u79cd\u5408\u6210\u73cd\u73e0\u5c42\u4e0e\u5929\u7136\u73cd\u73e0\u6bcd\u7684\u5316\u5b66\u6210\u5206\u548c\u5c42\u6b21\u7ed3\u6784\u9ad8\u5ea6\u76f8\u4f3c\u3002\u8fd9\u4e00\u6beb\u7c73\u539a\u7684\u5408\u6210\u73cd\u73e0\u8d28\u7531\u6709\u673a\u5c42\u548c\u6587\u77f3\u677f\u5c42\u4ea4\u66ff\u7ec4\u6210(\u91cd\u91cf\u536091%)\uff0c\u5177\u6709\u826f\u597d\u7684\u6781\u9650\u5f3a\u5ea6\u548c\u65ad\u88c2\u97e7\u6027\u3002\u8fd9\u79cd\u9884\u5148\u8bbe\u8ba1\u7684\u57fa\u8d28\u5bfc\u5411\u77ff\u5316\u65b9\u6cd5\u662f\u4e00\u79cd\u5408\u7406\u7684\u7b56\u7565\uff0c\u7528\u4e8e\u5236\u5907\u5177\u6709\u5c42\u6b21\u6709\u5e8f\u7ed3\u6784\u7684\u7a33\u5065\u590d\u5408\u6750\u6599\uff0c\u5176\u4e2d\u5404\u79cd\u6210\u5206\u662f\u53ef\u9002\u5e94\u7684\uff0c\u5305\u62ec\u8106\u6027\u548c\u70ed\u4e0d\u7a33\u5b9a\u6750\u6599\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSynthetic nacre by predesigned matrix-directed mineralization\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1126\/science.aaf8991\u00a0<\/p>\n

\u5408\u6210\u73cd\u73e0\u8d28\u7684\u5236\u4f5c\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u00a0\u00a0C-C\u5076\u8054<\/b><\/strong>\u540e<\/b><\/strong>\u7535\u50ac\u5316CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u9009\u62e9\u5236\u591a\u78b3\u9187\u71c3\u6599\u65b0\u601d\u8def<\/b><\/strong>\uff5c<\/b><\/strong>Nature<\/b><\/strong>\u00a0Catalysis<\/b><\/strong><\/p>\n

\u5728\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u9762\uff0c\u9488\u5bf9C-C\u8026\u5408\u6b65\u9aa4\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u5f88\u5927\u8fdb\u5c55\uff1b\u800c\u9488\u5bf9C-C\u540e\u5076\u8054\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\u3002\u4fde\u4e66\u5b8f\u6559\u6388\u8bfe\u9898\u7ec4\u4e0e\u591a\u4f26\u591a\u5927\u5b66Edward H. Sargent\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u7535\u50ac\u5316CO2<\/sub>\u5236\u5907\u591a\u78b3\u9187\u71c3\u6599\u65b9\u9762\u53d6\u5f97\u7a81\u7834\u6027\u8fdb\u5c55\u3002\u7814\u7a76\u8005\u62a5\u9053\u4e86\u4e00\u7c7b\u5229\u7528\u7eb3\u7c73\u7c92\u5b50\u6838\u5185\u7684\u786b\u539f\u5b50\u548c\u58f3\u5185\u7684\u94dc\u7a7a\u4f4d\u5b9e\u73b0\u9ad8\u6548\u7535\u5316\u5b66\u8fd8\u539f\u4e19\u9187\u548c\u4e59\u9187\u7684\u6838-\u58f3\u7a7a\u4f4d\u5de5\u7a0b\u50ac\u5316\u5242\u3002\u9996\u6b21\u63d0\u51fa\u5728CO2<\/sub>\u7684\u7535\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7\u8c03\u63a7\u78b3-\u78b3\u5076\u8054\u201c\u540e\u53cd\u5e94\u201d\u6b65\u9aa4\uff0c\u6291\u5236\u70ef\u70c3\u4ea7\u751f\u5b9e\u73b0\u9ad8\u6548\u591a\u78b3\u9187\u8f6c\u6362\uff0c\u4e3a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6db2\u4f53\u9187\u71c3\u6599(\u53d1\u52a8\u673a\u71c3\u6599)\u7684\u9009\u62e9\u6027\u5236\u5907\u63d0\u4f9b\u4e86\u8bbe\u8ba1\u601d\u8def\u3002\u5229\u7528\u6d41\u52a8\u7535\u89e3\u6c60\u8bbe\u5907\u89e3\u51b3\u4e86\u4e8c\u6c27\u5316\u78b3\u4f20\u8d28\u9650\u5236\uff0c\u4fc3\u4f7f\u8fd9\u4e00\u6838-\u58f3-\u7a7a\u4f4d\u94dc\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u591a\u78b3\u9187\u6cd5\u62c9\u7b2c\u8f6c\u6362\u6548\u7387\u8fbe\u523032 %\u4ee5\u53ca\u8f6c\u6362\u901f\u7387\u8d85\u8fc7120 mA cm-2<\/sup>\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSteering post-C\u2013C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41929-018-0084-7<\/p>\n

\u50ac\u5316\u5242\u8bbe\u8ba1\u548c\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>\u00a0\u8d85\u5f39\u6027\u548c\u9694\u70ed<\/b><\/strong>\u7684<\/b><\/strong>\u4eff\u751f\u78b3\u7ba1\u6c14\u51dd\u80f6<\/b><\/strong>\uff5c<\/b><\/strong>Chem<\/b><\/strong><\/p>\n

\u53d7\u5317\u6781\u718a\u6bdb\u53d1\u5fae\u89c2\u7ed3\u6784\u7684\u542f\u53d1\uff0c\u4fde\u4e66\u5b8f\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u5373\u5236\u9020\u4e00\u79cd\u5177\u6709\u8d85\u5f39\u6027\u548c\u826f\u597d\u9694\u70ed\u6027\u80fd\u7684\u5b8f\u89c2\u5c3a\u5ea6\u7684\u8f7b\u8d28\u78b3\u7ba1\u6c14\u51dd\u80f6\u3002\u5fae\u7ed3\u6784\u5bfc\u51fa\u7684\u70ed\u5bfc\u7387\u548c\u8d85\u5f39\u6027\u4e0e\u6c14\u51dd\u80f6\u7684\u5b54\u5f84\u4ee5\u53ca\u4e92\u8fde\u7ba1\u7684\u58f3\u5c42\u539a\u5ea6\u5bc6\u5207\u76f8\u5173\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7ecf\u4f18\u5316\u540e\u7684\u6c14\u51dd\u80f6\u572830%\u5e94\u53d8\u6761\u4ef6\u4e0b\u538b\u7f29\u91ca\u653e100\u4e07\u6b21\u4ee5\u4e0a\uff0c\u572890%\u5e94\u53d8\u6761\u4ef6\u4e0b\u538b\u7f29\u91ca\u653e10000\u6b21\u4ee5\u4e0a\uff0c\u4ecd\u80fd\u4fdd\u6301\u7ed3\u6784\u7684\u5b8c\u6574\u6027\u3002\u6b64\u5916\uff0c\u8be5\u4eff\u751f\u6c14\u51dd\u80f6\u5bf9\u5bbd\u5e26\u9891\u54cd\u5e94\u5177\u6709\u5feb\u901f\u3001\u51c6\u786e\u7684\u52a8\u6001\u538b\u963b\u54cd\u5e94\uff0c\u5176\u6700\u4f4e\u70ed\u5bfc\u7387\u4ec5\u4e3a23 mW m-1<\/sup>\u00a0K-1<\/sup>\uff0c\u4f4e\u4e8e\u5e72\u71e5\u7a7a\u6c14\u7684\u70ed\u5bfc\u7387\uff0c\u9ad8\u56de\u5f39\u901f\u5ea6\uff081434 mm s-1<\/sup>\uff09\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBiomimetic Carbon Tube Aerogel Enables Super-Elasticity and Thermal Insulation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1016\/j.chempr.2019.04.025<\/p>\n

\u751f\u7269\u6fc0\u53d1\u7684\u5b8f\u89c2\u78b3\u7ba1\u6c14\u51dd\u80f6(CTA)<\/p>\n

\"\"<\/p>\n

4\u00a0<\/b><\/strong>\u5728\u9178\u6027\u4ecb\u8d28<\/b><\/strong>\u4e2d\u591a\u6001\u4e8c\u70ef\u5316\u94b4<\/b><\/strong>\u4f5c\u4e3a\u6781\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u5242<\/b><\/strong>\uff5cN<\/b><\/strong>ature Communications<\/b><\/strong><\/p>\n

\u8bb8\u591a\u94c2\u65cf\u65e0\u91d1\u5c5e\u65e0\u673a\u50ac\u5316\u5242\u5728\u5404\u79cd\u91cd\u8981\u7684\u7535\u6781\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4e86\u5f88\u9ad8\u7684\u5185\u5728\u6d3b\u6027\uff0c\u4f46\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5f80\u5f80\u5b58\u5728\u7ed3\u6784\u9000\u5316\uff0c\u7a33\u5b9a\u6027\u5dee\u7684\u95ee\u9898\uff0c\u7279\u522b\u662f\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u3002\u4fde\u4e66\u5b8f\u6559\u5e08\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u78b1\u70ed\u5408\u6210\u6cd5\uff0c\u4ee5\u83b7\u5f97\u7acb\u65b9\u548c\u6b63\u4ea4\u6676\u76f8\u51e0\u4e4e\u5747\u5300\u5206\u5e03\u7684\u76f8\u6df7\u5408\u7684\u4e8c\u70ef\u5316\u94b4\u6750\u6599\u3002\u4ee5\u6c34\u7535\u8fd8\u539f\u4e3a\u6a21\u578b\u53cd\u5e94\uff0c\u89c2\u5bdf\u5230\u5728\u9178\u6027\u7535\u89e3\u6db2\u4e2d\uff0c\u5f53\u8fc7\u7535\u4f4d\u4ec5\u4e3a124 mv\u65f6\uff0c\u76f8\u6df7\u5408\u7684\u4e8c\u70ef\u5316\u94b4\u7684\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523010mA\u00a0cm-2<\/sup>\u3002\u8fde\u7eed\u8fd0\u884c400 h\u4ee5\u4e0a\uff0c\u50ac\u5316\u5242\u65e0\u5931\u6d3b\u8ff9\u8c61\uff0c5\u4e07\u6b21\u7535\u4f4d\u5faa\u73af\u540e\uff0c\u6781\u5316\u66f2\u7ebf\u4ecd\u4fdd\u6301\u826f\u597d\u3002\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u53d1\u73b0\uff0c\u63d0\u9ad8\u5171\u4ef7Co\u548cSe\u4e4b\u95f4\u7684\u76f8\u6df7\u5408\uff0c\u5927\u5927\u589e\u5f3a\u4e86\u6676\u683c\u7684\u9c81\u68d2\u6027\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u7a33\u5b9a\u6027\uff0c\u7814\u7a76\u7ed3\u679c\u4e3a\u957f\u5bff\u547d\u9178\u50ac\u5316\u5242\u7684\u6676\u4f53\u76f8\u5de5\u7a0b\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4f9d\u636e\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cPolymorphic cobalt diselenide as extremely stable electrocatalyst in acidic media via a phase-mixing strategy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Communications\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41467-019-12992-y<\/p>\n

m-CoSe2<\/sub>\u7684\u7ed3\u6784\u7a33\u5b9a\u6027<\/p>\n

\"\"<\/p>\n

\u4fde\u4e66\u5b8f\u9662\u58eb\u8bfe\u9898\u7ec4\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

http:\/\/staff.ustc.edu.cn\/~yulab\/<\/b><\/strong><\/p>\n

\u5f20\u9526<\/b><\/strong><\/h3>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u6559\u6388\uff0c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u526f\u4e3b\u4efb\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u5956\u52b1\u8ba1\u5212\u201d\u7279\u8058\u6559\u6388\u3002\u4e2d\u7ec4\u90e8\u4e07\u4eba\u8ba1\u5212\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff0c\u82f1\u56fd\u7687\u5bb6\u5b66\u4f1a\u4f1a\u58eb\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\u957f\u671f\u4ece\u4e8b\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7684\u7ed3\u6784\u63a7\u5236\u751f\u957f\uff1b\u91d1\u5c5e\u548c\u534a\u5bfc\u4f53SWNTs\u7684\u5206\u79bb\uff1b\u65b0\u578b\u78b3\u6750\u6599\u7684\u5236\u5907\uff1b\u57fa\u4e8e\u8868\u9762\u589e\u5f3a\u5149\u8c31\u7684\u4e8c\u7ef4\u539f\u5b50\u6676\u4f53\u6750\u6599\u4ee5\u53ca\u5e73\u9762\u57fa\u5e95\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u6563\u5c04\u53ca\u5176\u5b9e\u9645\u5e94\u7528\u7b49\u7814\u7a76\u3002\u5728Nature, Nature\u5b50\u520a, J. Am. Chem. Soc., Adv. Mater.\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868\u8bba\u6587200\u4f59\u7bc7\u3002SCI\u8bba\u6587\u4ed6\u5f159000\u4f59\u6b21\uff0cH\u56e0\u5b5051\u3002<\/p>\n

\u627f\u62c5\u9879\u76ee&\u6210\u679c\u5956\u52b1<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

2007\u5e74\uff0c\u201c\u51c6\u4e00\u7ef4\u7eb3\u7535\u5b50\u6750\u6599\u4e0e\u7ed3\u6784\u7684\u63a7\u5236\u751f\u957f\u3001\u52a0\u5de5\u7ec4\u88c5\u53ca\u5668\u4ef6\u57fa\u7840\u201d\u9879\u76ee\u83b7\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956<\/p>\n

2008\u5e74\uff0c\u201c\u7528\u4e8e\u7eb3\u7535\u5b50\u6750\u6599\u7684\u78b3\u7eb3\u7c73\u7ba1\u63a7\u5236\u751f\u957f\u3001\u52a0\u5de5\u7ec4\u88c5\u53ca\u5668\u4ef6\u57fa\u7840\u201d\u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u5956\u4e8c\u7b49\u5956<\/p>\n

2017\u5e74\uff0c\u201c\u4f4e\u7ef4\u78b3\u6750\u6599\u7684\u62c9\u66fc\u5149\u8c31\u5b66\u7814\u7a76\u201d\u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956<\/p>\n

\u90e8\u5206\u7814\u7a76\u8fdb\u5c55\uff1a<\/b><\/strong><\/p>\n

1\u00a0\u8bbe\u8ba1\u50ac\u5316\u5242\u52a9\u529b\u5355\u58c1\u78b3<\/b><\/strong>\u7eb3\u7c73\u7ba1\u53ef\u63a7\u624b\u6027\u751f\u957f<\/b><\/strong>\uff5cN<\/b><\/strong>ature<\/b><\/strong><\/p>\n

\u5f20\u9526\u6559\u6388\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u5173\u4e8e\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWNTs\uff09\u751f\u957f\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u8be5\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u63a7\u5236\u6d3b\u6027\u50ac\u5316\u5242\u8868\u9762\u5bf9\u79f0\u6027\u6765\u63a7\u5236\u6c34\u5e73SWNT\u9635\u5217\u7684\u624b\u6027\uff0c\u5e76\u5728\u56fa\u6001\u78b3\u5316\u7269\u50ac\u5316\u5242\u8868\u9762\u751f\u957f\u83b7\u5f97\u4e86\u5177\u6709\u53d7\u63a7\u624b\u6027\u7684\u6c34\u5e73SWNT\u9635\u5217\u3002\u6240\u83b7\u5f97\u7684\u6c34\u5e73\u6392\u5217\u91d1\u5c5eSWNT\u9635\u5217\u5e73\u5747\u5bc6\u5ea6\u5927\u4e8e20\u7ba1\/\u5fae\u7c73\uff0c\u5176\u4e2d90%\u7684\u7ba1\u5177\u6709(12,6)\u7684\u624b\u6027\u6307\u6570\u3002\u540c\u65f6\uff0c\u8fd8\u83b7\u5f97SWNT\u9635\u5217\u534a\u5bfc\u4f53\uff0c\u5176\u5e73\u5747\u5bc6\u5ea6\u5927\u4e8e10\u7ba1\/\u5fae\u7c73\uff0c\u5176\u4e2d80%\u7684\u7eb3\u7c73\u7ba1\u5177\u6709(8,4)\u7684\u624b\u6027\u6307\u6570\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cArrays of horizontal carbon nanotubes of controlled chirality grown using designed catalysts\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/nature21051<\/p>\n

CVD\u4e2dSWNTs\u624b\u6027\u7684\u4e24\u6b65\u63a7\u5236<\/p>\n

\"\"<\/b><\/strong><\/p>\n

2<\/b><\/strong>\u00a0\u77f3\u58a8\u70ef\/\u77f3\u58a8\u70ef\u5f02\u8d28\u7ed3\u6784\u4e0a\u7684\u539f\u5b50\u94af\u4f5c\u4e3a\u82b3\u57fa\u8fd8\u539f\u7684\u6709\u6548\u50ac\u5316\u5242<\/b><\/strong>\uff5cA<\/b><\/strong>FM<\/b><\/strong><\/p>\n

\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SACs\uff09\u4ee5\u5176\u6700\u5927\u7684\u539f\u5b50\u5229\u7528\u6548\u7387\uff0c\u8fd1\u5e74\u6765\u5f15\u8d77\u4e86\u50ac\u5316\u79d1\u5b66\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e3a\u4e86SACs\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\uff0c\u9700\u9762\u4e34\u4ee5\u4e0b\u6311\u6218\uff1a\u5982\u4f55\u7a33\u5b9a\u548c\u907f\u514dSACs\u7684\u805a\u5408\uff0c\u5982\u4f55\u63d0\u9ad8\u652f\u6491\u7269\u7684\u6bd4\u8868\u9762\u79ef\u548c\u5bfc\u7535\u6027\uff0c\u5982\u4f55\u4ee5\u4f4e\u6210\u672c\u5b9e\u73b0\u89c4\u6a21\u5316\u751f\u4ea7\uff0c\u56e0\u6b64\u5f20\u9526\u6559\u6388\u56e2\u961f\u5408\u6210\u4e86\u4e00\u79cd\u7531\u5355\u4e2aPd\u539f\u5b50\u7ec4\u6210\u7684SAC\uff0c\u5e76\u4e14\u56fa\u5b9a\u5728\u8bbe\u8ba1\u826f\u597d\u7684\u77f3\u58a8\u7094\/\u77f3\u58a8\u70ef(GDY\/G)\u5f02\u8d28\u7ed3\u6784(Pd1<\/sub>\/GDY\/G)\u4e0a\u30024-\u785d\u57fa\u82ef\u915a\u8fd8\u539f\u53cd\u5e94\u8868\u660e\uff0cPd1<\/sub>\/GDY\/G\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6027\u80fd\u3002\u6b64\u5916\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u77f3\u58a8\u70ef\u5728GDY\/G\u5f02\u8d28\u7ed3\u6784\u4e2d\u7531\u4e8e\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u800c\u5bf9\u50ac\u5316\u6548\u7387\u7684\u63d0\u9ad8\u8d77\u5173\u952e\u4f5c\u7528\uff0c\u8fd9\u662f\u7531\u77f3\u58a8\u70ef\u7684\u8d39\u7c73\u80fd\u7ea7\u4e0eGDY\u7684\u5bfc\u5e26\u6700\u5c0f\u503c\u4e4b\u95f4\u7684\u95f4\u9699\u4ea7\u751f\u7684\u3002GDY\/G\u5f02\u8d28\u7ed3\u6784\u4e3a\u5236\u5907\u9ad8\u6548\u7a33\u5b9a\u7684\u56ca\u6ce1\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u652f\u6491\uff0c\u53ef\u7528\u4e8e\u672a\u6765\u5de5\u4e1a\u53cd\u5e94\u7684\u5e7f\u6cdb\u9886\u57df\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAtomic Pd on Graphdiyne\/Graphene Heterostructure as Effcient Catalyst for Aromatic Nitroreduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adfm.201905423<\/p>\n

Pd1<\/sub>\/GDY\/G\u7684\u5236\u5907\u53ca\u50ac\u53164-NP\u7684\u8fd8\u539f<\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>\u00a0<\/b><\/strong>\u76f8\u540c<\/b><\/strong>\u94b4\u50ac\u5316\u5242\u4e0a<\/b><\/strong>\u5408\u6210<\/b><\/strong>\u4e0d\u540c\u624b\u6027\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1<\/b><\/strong>\uff5cSmall<\/b><\/strong><\/p>\n

\u8bbe\u8ba1\u9ad8\u6e29\u56fa\u4f53\u50ac\u5316\u5242\u662f\u5b9e\u73b0\u5177\u6709\u7279\u6b8a\u624b\u6027\u7684\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1(SWNTs)\u7684\u4e3b\u8981\u7b56\u7565\uff0c\u8fd9\u610f\u5473\u7740\u521b\u9020\u65b0\u7684\u50ac\u5316\u5242\u6216\u65b0\u7684\u624b\u6027\u662f\u975e\u5e38\u56f0\u96be\u548c\u5177\u6709\u6311\u6218\u6027\u7684\u3002\u4f4e\u6e29\u4f7f\u5927\u591a\u6570\u50ac\u5316\u5242\u5448\u56fa\u4f53\u72b6\u6001\uff0c\u5f00\u53d1\u4f4e\u6e29\u56fa\u76f8\u50ac\u5316\u5242\u662f\u5b9e\u73b0\u63a7\u5236\u624b\u6027\u7eb3\u7c73\u7ba1\u7684\u9700\u8981\u3002\u5f20\u9526\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u4f4e\u6e29(650\u2103)\u5728\u76f8\u540c\u56fa\u4f53Co\u50ac\u5316\u5242\u4e0a\u751f\u957f\u4e0d\u540c\u624b\u6027\u7684SWNTs\u9635\u5217\u7684\u5408\u7406\u65b9\u6cd5\u3002\u5229\u7528\u56fa\u4f53Co\u50ac\u5316\u5242\uff0c\u5206\u522b\u5b9e\u73b0\u4e86\u5bf9(10\u30019)\u00a0\u624b\u6027\u6307\u6570\u7684\u7eb3\u7c73\u7ba1\u9009\u62e9\u6027\u224875%\uff0c(12\u30016)\u00a0\u624b\u6027\u6307\u6570\u9009\u62e9\u6027\u224882%\u3002(10,9)\u7eb3\u7c73\u7ba1\u4e3a\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u800c\u5bcc\u96c6\uff0c(12,6)\u7eb3\u7c73\u7ba1\u4e3a\u52a8\u529b\u5b66\u751f\u957f\u901f\u7387\u800c\u5bcc\u96c6\u3002\u8fd9\u4e24\u79cd\u7ba1\u6750\u5747\u8868\u73b0\u51fa\u4e0eCo(1,1,1)\u9762\u76f8\u4f3c\u7684\u4e09\u6b21\u5bf9\u79f0\u5bf9\u79f0\u5339\u914d\u6210\u6838\u673a\u5236\u3002\u8be5\u65b9\u6cd5\u4e3a\u7814\u7a76\u6210\u6838\u673a\u7406\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff0c\u4e3a\u5236\u5907\u65b0\u578b\u56fa\u4f53\u50ac\u5316\u5242\u63a7\u5236\u78b3\u7eb3\u7c73\u7ba1\u7ed3\u6784\u63d0\u4f9b\u4e86\u65b0\u7684\u53ef\u80fd\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cGrowth of Single-Walled Carbon Nanotubes with Different Chirality on Same Solid Cobalt Catalysts at Low Temperature\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Small\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/smll.201903896<\/p>\n

\u5b9e\u73b0SWNTs\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u9009\u62e9\u6027\u7684\u7b56\u7565\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

4<\/b><\/strong>\u00a0\u534a\u5bfc\u4f53\u78b3\u7eb3\u7c73\u7ba1(n, n-1)\u65cf\u7684\u53ef\u63a7\u751f\u957f<\/b><\/strong>\uff5cChem<\/b><\/strong><\/p>\n

\u534a\u5bfc\u4f53\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1(SWNTs)\u53ef\u4ee5\u63a7\u5236\u624b\u6027(n, m)\u548c\u5e26\u9699\u6709\u671b\u521b\u9020\u4e00\u4e2a\u65b0\u7684\u7535\u5b50\u65f6\u4ee3\u3002\u5728\u8fd9\u91cc\uff0c\u5f20\u9526\u6559\u6388\u56e2\u961f\u62a5\u544a\u4e86\u4e00\u4e2a\u5408\u7406\u7684\u8bbe\u8ba1\uff0c\u4f7fSWNTs\u8fd1\u5e73\u8861\u5f62\u6838\uff0c\u7136\u540e\u751f\u957f\u4e00\u4e2a\u65b0\u7684\u5bb6\u65cf\u534a\u5bfc\u4f53SWNTs:(n, n-1)\u78b3\u7eb3\u7c73\u7ba1\u3002\u901a\u8fc7\u53cd\u5c04\u5149\u8c31\u6d4b\u91cf\uff0c\u5728100\u4e2a\u6837\u54c1\u4e2d\u6ca1\u6709\u89c2\u5bdf\u5230\u91d1\u5c5e\u7eb3\u7c73\u7ba1\u3002\u7ed3\u5408\u50ac\u5316\u5242\u63a7\u5236\uff0c\u6211\u4eec\u6210\u529f\u5730\u5408\u6210\u4e86\u5927\u76f4\u5f84(>2 nm) (n, n-1)\u5355\u624b\u6027(10,9)SWNTs\uff0c\u4e30\u5ea6\u5206\u522b\u4e3a88%\u548c80%\u3002\u7406\u8bba\u5206\u6790\u8868\u660e(n, n-1)\u7ba1\u7684\u624b\u6027\u8d8b\u5411\u4e8e(n, n)\uff0c\u901a\u8fc7\u5728\u7ba1\u58c1\u4e2d\u52a8\u6001\u5730\u5408\u5e76\u4e00\u4e2a\u80fd\u91cf\u4f18\u5148\u7684\u4e94\u8fb9\u5f62\u5bf9\u800c\u6539\u53d8\u4e3a(n, n)\uff0c\u8fd9\u4e00\u7b56\u7565\u4e3aSWNT\u5bb6\u65cf\u7684\u53d1\u5c55\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cControllable Growth of (n, n-1) Family of Semiconducting Carbon Nanotubes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1016\/j.chempr.2019.02.012<\/p>\n

\u624b\u6027(n, n-1)\u3001(n, n-2) SWNT\u7684\u751f\u957f\u673a\u5236\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u674e\u666f\u8679<\/b><\/strong><\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u5956\u52b1\u8ba1\u5212\u201d\u7279\u8058\u6559\u6388\u3002\u82f1\u56fd\u5316\u5b66\u4f1a\u4f1a\u58eb\uff0c\u653f\u534f\u7b2c\u5341\u4e09\u5c4a\u5168\u56fd\u59d4\u5458\u4f1a\u59d4\u5458<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\u957f\u671f\u4ece\u4e8b\u7535\u5206\u6790\u5316\u5b66\u4e0e\u751f\u7269\u5206\u6790\u5316\u5b66\uff1b\u7535\u5316\u5b66\u4e0e\u7535\u5316\u5b66\u80fd\u6e90\uff1b\u7eb3\u7c73\u7535\u5316\u5b66\u4e0e\u6750\u6599\u7535\u5316\u5b66\u7684\u7814\u7a76\u3002\u5728Nature Nanotech., Nature Protocol, Nature Commun., J. Am. Chem. Soc., Angew. Chem., Anal. Chem.\u7b49\u56fd\u9645\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587300\u4f59\u7bc7\uff0c\u8bba\u6587\u88ab\u5f15\u7528>40000\u6b21\uff0cH\u56e0\u5b50106\u30022015\u5e74-2019\u5e74\u8fde\u7eed\u5165\u9009\u6c64\u68ee\u8def\u900f\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n

\u627f\u62c5\u9879\u76ee&\u6210\u679c\u5956\u52b1<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

2007\u5e74\uff0c\u83b7\u4e2d\u56fd\u5206\u6790\u6d4b\u8bd5\u534f\u4f1a\u79d1\u5b66\u6280\u672f\u4e00\u7b49\u5956<\/p>\n

2011\u5e74\uff0c\u83b7\u4e2d\u56fd\u5316\u5b66\u4f1a-\u5df4\u65af\u592b\u9752\u5e74\u521b\u65b0\u5956<\/p>\n

2015\u5e74\uff0c\u201c\u77f3\u58a8\u70ef\u7684\u7535\u5206\u6790\u5316\u5b66\u548c\u751f\u7269\u5206\u6790\u5316\u5b66\u7814\u7a76\u201d\u9879\u76ee\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u5956\u4e8c\u7b49\u5956\u3001\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\u3002<\/p>\n

\u90e8\u5206\u7814\u7a76\u8fdb\u5c55\uff1a<\/b><\/strong><\/p>\n

1<\/b><\/strong>\u00a0\u78b3\u70b9\u652f\u6491\u7684\u539f\u5b50\u5c3a\u5ea6\u5206\u6563\u7684\u91d1\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u6297\u764c\u7eb3\u7c73\u6750\u6599<\/b><\/strong>\uff5c<\/b><\/strong>Na<\/b><\/strong>ture N<\/b><\/strong>ano<\/b><\/strong>technology<\/b><\/strong><\/p>\n

\u7ebf\u7c92\u4f53\u6c27\u5316\u8fd8\u539f\u7a33\u6001\u662f\u6d3b\u6027\u6c27\u548c\u6297\u6c27\u5316\u5242\u5982\u8c37\u80f1\u7518\u80bd\u4e4b\u95f4\u7684\u5e73\u8861\uff0c\u5728\u8bb8\u591a\u751f\u7269\u8fc7\u7a0b\u4e2d\u8d77\u7740\u5173\u952e\u4f5c\u7528\uff0c\u5305\u62ec\u751f\u7269\u5408\u6210\u548c\u7ec6\u80de\u51cb\u4ea1\uff0c\u56e0\u6b64\u662f\u6f5c\u5728\u7684\u764c\u75c7\u6cbb\u7597\u9776\u70b9\u3002\u5728\u8fd9\u91cc\uff0c\u674e\u666f\u8679\u6559\u6388\u8054\u5408\u56fd\u5bb6\u7eb3\u7c73\u4e2d\u5fc3\u7684\u6881\u5174\u6770\u7814\u7a76\u5458\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u4e2a\u7ebf\u7c92\u4f53\u6c27\u5316\u5e94\u6fc0\u653e\u5927\u5668\uff0cMitoCAT-g\uff0c\u5b83\u662f\u7531\u78b3\u70b9\u652f\u6301\u7684\u539f\u5b50\u5206\u6563\u91d1(CAT-g)\u4e0e\u8fdb\u4e00\u6b65\u8868\u9762\u4fee\u9970\u7684\u4e09\u82ef\u57fa\u81a6\u548c\u8089\u6842\u919b\u7ec4\u6210\u3002\u6211\u4eec\u53d1\u73b0MitoCAT-g\u9897\u7c92\u7279\u5f02\u6027\u9776\u5411\u7ebf\u7c92\u4f53\uff0c\u53ef\u4ee5\u6d88\u8017\u7ebf\u7c92\u4f53\u8c37\u80f1\u7518\u80bd\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u8089\u6842\u919b\u5bf9\u6d3b\u6027\u6c27\u7684\u635f\u4f24\uff0c\u6700\u7ec8\u5bfc\u81f4\u764c\u7ec6\u80de\u51cb\u4ea1\u3002\u6211\u4eec\u53d1\u73b0\uff0c\u5728\u6210\u50cf\u5f15\u5bfc\u4e0b\u4ecb\u5165\u6ce8\u5c04\u8fd9\u4e9b\u9897\u7c92\u80fd\u6709\u6548\u5730\u6291\u5236\u76ae\u4e0b\u548c\u539f\u4f4d\u79fb\u690d\u809d\u7ec6\u80de\u764c\u6a21\u578b\u4e2d\u80bf\u7624\u7684\u751f\u957f\uff0c\u4e14\u65e0\u4e0d\u826f\u53cd\u5e94\u3002\u6211\u4eec\u7684\u7814\u7a76\u8868\u660e\uff0cMitoCAT-g\u5728\u4f53\u5185\u589e\u5f3a\u7ebf\u7c92\u4f53\u7684\u6c27\u5316\u5e94\u6fc0\uff0c\u6291\u5236\u80bf\u7624\u751f\u957f\uff0c\u662f\u4e00\u79cd\u6709\u524d\u9014\u7684\u6297\u764c\u836f\u7269\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCarbon-dot-supported atomically dispersed gold as a mitochondrial oxidative stress amplifier for cancer treatment\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Nanotechnology\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41565-019-0373-6<\/p>\n

MitoCAT-g\u589e\u5f3aHepG-2\u764c\u7ec6\u80de\u7ebf\u7c92\u4f53\u6c27\u5316\u5e94\u6fc0<\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u00a0\u539f\u5b50<\/b><\/strong>\u7ea7<\/b><\/strong>\u4e8c\u6c27\u5316\u94bc\u4e0a\u89e6\u53d1\u8868\u9762\u6c27\u7a7a\u4f4d\u8fbe\u5230\u4f4e\u80fd\u8017\u7684\u56fa\u6c2e\u9014\u5f84<\/b><\/strong>\uff5c<\/b><\/strong>Na<\/b><\/strong>no Energy<\/b><\/strong><\/p>\n

\u5728\u50ac\u5316\u6c2e\u6c14\u8fd8\u539f\u53cd\u5e94(NRR)\u4e2d\uff0c\u50ac\u5316\u5242\u65e2\u53ef\u4ee5\u88c2\u89e3N\u2261N\u952e\uff0c\u53c8\u53ef\u4ee5\u6253\u7834\u6790\u6c22\u53cd\u5e94\u7684\u7ade\u4e89\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u901a\u8fc7\u5728\u539f\u5b50\u5c42\u72b6MoO2<\/sub>\u4e2d\u7cbe\u7ec6\u9650\u5236\u6c27\u7a7a\u4f4d(OVs)\uff0c\u674e\u666f\u8679\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u6301\u7eed\u7684\u6218\u7565\uff0c\u4ee5\u5e94\u5bf9\u4e25\u683c\u7684\u8981\u6c42\uff0c\u4ece\u800c\u63ed\u793a\u4e86\u589e\u91cf\u673a\u5236\u4e0b\u7684\u6df1\u5c42\u673a\u5236\u3002X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7f18\u7ed3\u6784(XANES)\u548c\u7535\u5b50\u987a\u78c1\u5171\u632f(EPR)\u7ed3\u679c\u521d\u6b65\u8868\u660e\uff0c\u7edd\u5927\u591a\u6570\u4e0d\u540c\u6d53\u5ea6\u7684OVs\u5728\u5c42\u72b6MoO2<\/sub>\u4e0a\u5206\u5e03\u826f\u597d\u3002\u57fa\u4e8eN2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u548cDFT\u8ba1\u7b97\u7684\u7ed3\u5408\u7ed3\u679c\uff0c\u53d1\u73b0OVs\u66f4\u503e\u5411\u4e8e\u901a\u8fc7Mo\u7f3a\u9677\u4e0a\u7684\u7535\u5b50\u4f9b\u4f53\u5bf9N2<\/sub>\u5206\u5b50\u8fdb\u884c\u5316\u5b66\u5438\u9644\uff0c\u8fd9\u4e3a\u540e\u7eed\u7684\u6d3b\u5316\u63d0\u4f9b\u4e86\u524d\u63d0\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u80fd\u91cf\u53d8\u5316\u8ba1\u7b97\u63ed\u793a\u4e86\u9002\u7528\u4e8eMoO2<\/sub>\u00a0NRR\u7684\u53d7\u9650OVs\u91c7\u7528\u4e86\u4e00\u79cd\u65b0\u7684\u8fdc\u7aef\/\u4ea4\u53d8\u6df7\u5408\u8def\u5f84\uff0c\u5373N2<\/sub>H2<\/sub>\u00a0* –HN2<\/sub>H2<\/sub>\u00a0*(\u0394G = 0.36 eV)\u76f4\u63a5\u8d28\u5b50\u5316\u4f5c\u7528\u540e\u80fd\u91cf\u52bf\u5792\u662f\u6709\u6548\u5730\u964d\u4f4e\u7684\uff0c\u6240\u4ee5OVs-MoO2<\/sub>\u50ac\u5316\u5242\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u6d3b\u6027\u3001\u9009\u62e9\u6027\u4e0eNH3<\/sub>\u6536\u76ca\u7387\uff0812.20 \u03bcg h-1<\/sup>\u00a0mg-1<\/sup>\uff09\uff0c\u5728\u4f4e\u7535\u4f4d\u4e3a-0.15 V\u65f6\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a8.2%\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTriggering surface oxygen vacancies on atomic layered molybdenum dioxide for a low energy consumption path toward nitrogen fixation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nano\u00a0Energy\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1016\/j.nanoen.2019.02.028<\/p>\n

MoO2<\/sub>\u8868\u9762\u6c27\u7a7a\u4f4d\u7684\u8bc6\u522b<\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>\u00a0RMSApt\u5bf9<\/b><\/strong>\u4f4e\u4eb2\u548c<\/b><\/strong>\u5c0f\u5206\u5b50\u8fdb\u884c\u6570\u5b57\u91cf\u5316<\/b><\/strong>\uff5c<\/b><\/strong>Analytical Chemistry<\/b><\/strong><\/p>\n

\u9002\u914d\u4f53\u662f\u516c\u8ba4\u7684\u7ade\u4e89\u6027\u4eb2\u548c\u8bd5\u5242\uff0c\u4f46\u5176\u5e94\u7528\u5f80\u5f80\u53d7\u5230\u5176\u76f8\u5bf9\u8f83\u4f4e\u7684\u76ee\u6807\u7ed3\u5408\u4eb2\u548c\u5ea6\u7684\u5f71\u54cd\uff0c\u5c24\u5176\u662f\u5bf9\u5c0f\u5206\u5b50\u3002\u674e\u666f\u8679\u6559\u6388\u4ecb\u7ecd\u4e86\u8bc6\u522b\u589e\u5f3a\u4e9a\u7a33\u5c4f\u853d\u9002\u914d\u4f53\u63a2\u9488(RMSApt)\u7684\u6982\u5ff5\uff0c\u5e76\u63a2\u8ba8\u4e86\u5176\u5bf9\u4f4e\u4eb2\u548c\u5c0f\u5206\u5b50\u7684\u6570\u5b57\u91cf\u5316\u6027\u80fd\u3002RMSApt\u8bbe\u8ba1\u91c7\u7528\u6784\u5efa\u53d8\u6784\u9002\u914d\u4f53\u63a2\u9488\u7684\u601d\u60f3\uff0c\u5728\u8bc6\u522b\u5207\u6362\u8fc7\u7a0b\u4e2d\u8d4b\u4e88\u8f83\u5c0f\u7684\u80fd\u91cf\u95f4\u9699\uff0c\u4fc3\u8fdb\u76ee\u6807\u7ed3\u5408\u548c\u63a2\u9488\u54cd\u5e94\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4f4e\u4eb2\u548c\u529b\u76ee\u6807\u7684\u8bc6\u522b\u6548\u7387\u3002\u63a2\u9488\u8bbe\u8ba1\u7b56\u7565\u4fc3\u8fdb\u4e86\u9002\u914d\u4f53\u7684\u5e94\u7528\uff0c\u7528\u4e8e\u7cbe\u786e\u5b9a\u91cf\u89e3\u79bb\u5e38\u6570Kd\u572810-4<\/sup>\u523010-9<\/sup>\u00a0M\u8303\u56f4\u5185\u7684\u76ee\u6807\uff0c\u8fd9\u5c06\u6db5\u76d6\u5927\u591a\u6570\u5b58\u5728\u7ed3\u5408\u9002\u914d\u4f53\u7684\u5c0f\u5206\u5b50\u7269\u79cd\u3002\u56e0\u6b64\uff0cRMSApt\u5c06\u4fc3\u8fdb\u9002\u914d\u4f53\u5728\u533b\u5b66\u8bca\u65ad\u3001\u98df\u54c1\u5b89\u5168\u548c\u73af\u5883\u7b5b\u9009\u4e2d\u7684\u8f6c\u5316\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cRecognition-enhanced metastably shielded aptamer (RMSApt) enables digitally quantifying small molecules\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Analytical Chemistry\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/acs.analchem.8b03763<\/p>\n

RMSApt\u7684\u5de5\u4f5c\u539f\u7406\u53ca\u5176\u5728\u5c0f\u5206\u5b50\u6570\u5b57\u91cf\u5316\u4e2d\u7684\u5e94\u7528<\/p>\n

\"\"<\/p>\n

4<\/b><\/strong>\u00a0<\/b><\/strong>\u8fd8\u539f<\/b><\/strong>\u6c27\u5316\u77f3\u58a8\u70ef\u4e3a\u8f7d\u4f53<\/b><\/strong>\u7684<\/b><\/strong>\u975e\u6676\u6001Fe<\/b><\/strong>x<\/b><\/sub><\/strong>P\u6d82\u5c42Fe<\/b><\/strong>2<\/b><\/sub><\/strong>N<\/b><\/strong>\u4f5c\u4e3a<\/b><\/strong>\u9178\u6027\u4ecb\u8d28\u4e2d\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u7535\u50ac\u5316\u6790\u6c22<\/b><\/strong>\uff5cSmall<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/smll.201801717<\/p>\n

P-Fe2<\/sub>N\/rGO\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

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\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao*cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

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