{"id":192825,"date":"2020-01-02T06:27:08","date_gmt":"2020-01-01T22:27:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=192825"},"modified":"2020-01-01T15:27:16","modified_gmt":"2020-01-01T07:27:16","slug":"%e5%85%a8%e9%9d%a2%e5%a4%b1%e5%ae%88%ef%bc%81mofs%ef%bc%8ccofs%e5%8f%8a%e5%85%b6%e8%a1%8d%e7%94%9f%e7%89%a9%e5%a4%a7%e4%b8%be%e6%94%bb%e5%85%a5%e5%82%a8%e8%83%bd%e9%a2%86%e5%9f%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=192825","title":{"rendered":"\u5168\u9762\u5931\u5b88\uff01MOFs\uff0cCOFs\u53ca\u5176\u884d\u751f\u7269\u5927\u4e3e\u653b\u5165\u50a8\u80fd\u9886\u57df"},"content":{"rendered":"

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff08Metal-Organic<\/b><\/strong>\u00a0<\/b><\/strong>Frameworks\uff0c<\/b><\/strong>MOFs\uff09<\/b><\/strong>\u662f\u7531\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u901a\u8fc7\u914d\u4f4d\u952e\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u4e00\u7c7b\u5177\u6709\u5468\u671f\u6027\u7f51\u7edc\u7ed3\u6784\u7684\u6676\u6001\u591a\u5b54\u9aa8\u67b6\u6750\u6599\u3002\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff08Covalent Organic Frameworks\uff0cCOFs\uff09<\/b><\/strong>\u5219\u662f\u4e00\u7c7b\u65b0\u578b\u7684\u57fa\u4e8e\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u6676\u6001\u6709\u673a\u591a\u5b54\u805a\u5408\u7269\u3002\u65e0\u8bba\u662f\u4e00\u76f4\u5904\u4e8e\u7814\u7a76\u70ed\u70b9\u7684MOFs\u8fd8\u662f\u6700\u8fd1\u6108\u53d1\u706b\u70ed\u7684COFs\uff0c\u5b83\u4eec\u90fd\u6709\u7740\u72ec\u7279\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u6613\u529f\u80fd\u5316\u7684\u7279\u70b9\u3002\u9274\u4e8e\u5b83\u4eec\u72ec\u7279\u7684\u6210\u5206\u4e0e\u7ed3\u6784\uff0c\u5176\u5728\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u71c3\u6599\u7535\u6c60\u548c\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong>\u7b49\u65b9\u5411\u6709\u7740\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\uff0c\u56e0\u6b64\u5728\u50a8\u80fd\u9886\u57df\u5907\u53d7\u77a9\u76ee\u3002\u5728\u6b64\uff0c\u6211\u4eec\u603b\u7ed3\u4e86MOFs\uff0cCOFs\u53ca\u5176\u884d\u751f\u7269\u5728\u50a8\u80fd\u9886\u57df\u7684\u4e00\u4e9b\u5178\u578b\u5e94\u7528\uff0c\u4ee5\u4f9b\u5927\u5bb6\u501f\u9274\u3002<\/p>\n

1. \u9502\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/h3>\n

Energy Storage Materials<\/b><\/strong>\uff1aNi-Co\u53cc\u91d1\u5c5eMOFs\u884d\u751f\u7684\u5c42\u7ea7\u7ed3\u6784Ni-Co-Se@C\u7528\u4e8e\u9ad8\u500d\u7387\u8d5d\u7535\u5bb9\u50a8\u9502<\/b><\/strong><\/p>\n

\u7531\u4e8eMOFs\u7684\u7ed3\u6784\u548c\u6210\u5206\u5177\u6709\u663e\u8457\u7684\u53ef\u8c03\u63a7\u6027\uff0cMOFs\u53ca\u5176\u884d\u751f\u7269\u5728\u80fd\u91cf\u50a8\u5b58\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u5730\u5173\u6ce8\u3002\u5728\u6b64\uff0c\u4e2d\u56fd\u5730\u8d28\u5927\u5b66\u7684\u5218\u8273\u6539\uff0c\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\u7684\u90ed\u518d\u840d\u548c\u6fb3\u5927\u5229\u4e9a\u6089\u5c3c\u5927\u5b66\u7684\u90d1\u8363\u5764<\/b><\/strong>\u56e2\u961f\u9996\u6b21\u5728\u5ba4\u6e29\u4e0b\u5408\u6210\u4e86\u4e00\u79cd\u5177\u6709\u5c42\u7ea7\u72b6\u5fae\u7eb3\u7ed3\u6784\u76843D\u675f\u72b6Ni-Co\u53cc\u91d1\u5c5eMOFs[1]<\/sup>\u3002\u7ecf\u8fc7\u78b3\u5316\u548c\u7852\u5316\uff0cNi-Co\u53cc\u91d1\u5c5eMOFs\u5c31\u8f6c\u53d8\u4e3a\u4e86\u57cb\u8986\u7740Ni-Co-Se\u7eb3\u7c73\u9897\u7c92\u76843D\u78b3\u7f51\u7edc\uff08Ni-Co-Se@C\uff09\uff0c\u5176\u7ee7\u627f\u4e86\u539f\u59cbMOFs\u7684\u5f62\u8c8c\u4e14\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u5c42\u7ea7\u72b6\u7684\u7ed3\u6784\uff08\u56fe1\uff09\u3002\u5c06Ni-Co-Se@C\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u5e94\u7528\u65f6\uff0c\u5b83\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u4f18\u5f02\u5faa\u73af\u7a33\u5b9a\u6027\uff083<\/b><\/strong>00<\/b><\/strong>\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4ecd\u9ad8\u8fbe2<\/b><\/strong>061 mAh g<\/b><\/strong>-1<\/b><\/sup><\/strong>\uff09\u548c\u9ad8\u500d\u7387\u6027\u80fd\uff088<\/b><\/strong>\u00a0A g<\/b><\/strong>-1<\/b><\/sup><\/strong>\uff1a<\/b><\/strong>493 mAh g<\/b><\/strong>-1<\/b><\/sup><\/strong>\uff09<\/b><\/strong>\uff08\u56fe2\uff09\u3002\u8be5Ni-Co-Se@C\u7535\u6781\u5177\u6709\u5982\u4e0b\u7279\u5f81\uff1a\uff081\uff09\u53cc\u91d1\u5c5e\u7852\u5316\u7269\u50a8\u9502\u7684\u534f\u540c\u6548\u5e94\uff1b\uff082\uff09\u5c42\u7ea7\u591a\u5b54\u5e26\u72b6\u7ed3\u6784\uff1b\uff083\uff09\u7262\u56fa\u7684\u78b3\u7f51\u7edc\uff1b\uff084\uff09\u9996\u6b21\u5faa\u73af\u540e\u5f62\u6210\u7684\u5c3a\u5bf8\u66f4\u5c0f\u7684\u53cd\u5e94\u4ea7\u7269\u3002\u8fd9\u4e9b\u7279\u70b9\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u5bfc\u7535\u6027\u3001\u7f13\u89e3\u4f53\u79ef\u81a8\u80c0\uff0c\u800c\u4e14\u8fd8\u80fd\u591f\u4ea7\u751f\u66f4\u591a\u7684\u50a8\u9502\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca\u66f4\u77ed\u7684\u9502\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u4ece\u800c\u52a0\u901f\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u5e76\u5f62\u6210\u7a33\u5b9a\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\uff08SEI\uff09\uff0c\u56e0\u6b64\u6750\u6599\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50a8\u9502\u6027\u80fd\u3002\u6b64\u5916\uff0cNi-Co-Se@C\u6750\u6599\u5728\u50a8\u9502\u65f6\u7684\u8d5d\u7535\u5bb9\u884c\u4e3a\u4e5f\u4f7f\u5176\u80fd\u591f\u8fdb\u884c\u9ad8\u901f\u7684\u9502\u79bb\u5b50\u5b58\u50a8\u3002\u603b\u4e4b\uff0c\u8be5\u5de5\u4f5c\u5c55\u793a\u51fa\u4e86\u4e00\u79cd\u7b80\u6613\u7684\u5236\u59073D\u5c42\u7ea7\u7ed3\u6784\u7684MOFs\u548c\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u7684\u65b9\u6cd5\u3002<\/p>\n

\u56fe1<\/b><\/strong>\u00a0<\/b><\/strong>MOFs\u884d\u751f\u7269Ni-Co-Se@C\u7684\u5236\u5907\u6d41\u7a0b\u53ca\u5f62\u8c8c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>2 <\/b><\/strong>MOFs\u884d\u751f\u7684Ni-Co-Se@C\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2. \u9502\u786b\u7535\u6c60<\/b><\/strong><\/h3>\n

JACS<\/b><\/strong>\uff1aL<\/b><\/strong>i<\/b><\/strong>3<\/b><\/sub><\/strong>PS<\/b><\/strong>4<\/b><\/sub><\/strong>\u529f\u80fd\u5316\u7684Zr-MOF\u5b9e\u73b0\u9ad8\u6027\u80fdLi-S\u7535\u6c60<\/b><\/strong><\/p>\n

Zr-MOFs\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u5e7f\u6cdb\u7684\u5316\u5b66\u53ef\u8c03\u63a7\u6027\u800c\u5e7f\u4e3a\u4eba\u77e5\u3002\u4e00\u4e9bZr-MOFs\u5373\u4f7f\u5728\u914d\u4f53\u7f3a\u5931\u65f6\u4e5f\u80fd\u591f\u7a33\u5b9a\u5b58\u5728\uff0c\u8fd9\u4e9b\u7f3a\u5931\u914d\u4f53\u7684\u4f4d\u7f6e\u5c31\u6210\u4e86\u201c\u5f00\u653e\u4f4d\u70b9\u201d\uff0c\u5b83\u53ef\u4ee5\u7528\u6765\u8fde\u63a5\u5ba2\u4f53\u5206\u5b50\u3002Li-S\u7535\u6c60\u56e0\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff081675 mAh g-1<\/sup>\uff09\u548c\u80fd\u91cf\u5bc6\u5ea6\uff082600 Wh kg-1<\/sup>\uff09\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u591a\u786b\u5316\u9502\uff08<\/b><\/strong>LiPS<\/b><\/strong>\uff09\u7684\u201c\u7a7f\u68ad\u6548\u5e94\u201d<\/b><\/strong>\u4e25\u91cd\u5730\u635f\u5bb3\u4e86Li-S\u7535\u6c60\u7684\u6027\u80fd\u3002\u57fa\u4e8e\u6b64\uff0c\u7f8e\u56fd\u7ea6\u7ff0\u970d\u666e\u91d1\u65af\u5927\u5b66\u7684<\/b><\/strong>V. Sara Thoi<\/b><\/strong>\u56e2\u961f\u5229\u7528Zr-MOFs\u4e0a\u7684\u5f00\u653e\u4f4d\u70b9\u5c06Li3<\/sub>PS4<\/sub>\u7a33\u5b9a\u5730\u56fa\u5b9a\u5728MOFs\u7684\u591a\u5b54\u9aa8\u67b6\u4e0a\uff0c\u4ee5\u671f\u5229\u7528Li3<\/sub>PS4<\/sub>\u4e0e\u591a\u786b\u5316\u7269\u5f62\u6210S-S\u952e\uff0c\u4ece\u800c\u6539\u5584\u7a7f\u68ad\u6548\u5e94\u5e76\u63d0\u9ad8Li-S\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff08\u56fe3\uff09[2]<\/sup>\u3002\u4f5c\u8005\u901a\u8fc7NMR\u3001XPS\u3001Raman\u5149\u8c31\u3001X\u5c04\u7ebf\u5bf9\u5206\u5e03\u51fd\u6570\u7b49\u591a\u79cd\u6280\u672f\u624b\u6bb5\u6210\u529f\u8bc1\u5b9e\u4e86PS4<\/sub>3<\/sup>–<\/sup>\u5bf9Zr-MOF\u7684\u529f\u80fd\u5316\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5728Zr-MOFs\u4e0a\u7ed3\u5408\u5f88\u5c11\u7684Li<\/b><\/strong>3<\/b><\/sub><\/strong>PS<\/b><\/strong>4<\/b><\/sub><\/strong>\u5c31\u80fd\u663e\u8457\u5730\u6539\u5584\u786b\u7684\u5229\u7528\u7387\u548c\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94<\/b><\/strong>\uff0c\u4ece\u800c\u4f7fLi-S\u7535\u6c60\u8868\u73b0\u51fa\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff08\u5927\u7ea61200 mAh g-1<\/sup>\uff09\u548c\u957f\u7684\u5faa\u73af\u6027\u80fd\uff081C\u4e0b600\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4ecd\u7136\u9ad8\u8fbe375\u00a0mAh g-1<\/sup>\uff09\uff08\u56fe4\uff09\u3002\u8be5\u529f\u80fd\u5316\u7684MOF\u6dfb\u52a0\u5242\u4e5f\u53ef\u4ee5\u963b\u6b62\u7535\u6c60\u5728\u6ee5\u7528\u6dfb\u52a0\u4e0b\u7684\u635f\u5bb3\u5e76\u5728\u5145\u653e\u7535\u901f\u7387\u53d8\u5c0f\u65f6\u6062\u590d\u9ad8\u5bb9\u91cf\u7684\u7279\u70b9\uff0c\u8fd9\u70b9\u5bf9\u4e8e\u50a8\u80fd\u5668\u4ef6\u975e\u5e38\u91cd\u8981\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u8bbe\u8ba1\u7ed3\u5408\u4e86\u7eaf\u65e0\u673aLi3<\/sub>PS4<\/sub>\u7684\u5316\u5b66\u7279\u70b9\u548cMOFs\u6750\u6599\u7684\u9ad8\u7a33\u5b9a\u6027\u548c\u5927\u6bd4\u8868\u9762\u79ef\uff0c\u4ece\u800c\u5236\u5907\u51fa\u4e86\u8d85\u8d8a\u5355\u72ec\u7ec4\u5206\u7b80\u5355\u52a0\u548c\u7684Li-S\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002<\/p>\n

\u56fe<\/b><\/strong>3 <\/b><\/strong>LiPS-MOF\u6750\u6599\u7684\u8bbe\u8ba1\u7406\u5ff5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>4 <\/b><\/strong>LiPS-MOF\u6750\u6599\u5728Li-S\u7535\u6c60\u4e2d\u7684\u7535\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3. \u94a0\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/h3>\n

JACS<\/b><\/strong>\uff1a\u8c03\u63a7COFs\u4e2d\u81ea\u7531\u57fa\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u548c\u7a33\u5b9a\u6027\u6784\u7b51\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\u968f\u7740\u4eba\u4eec\u5bf9\u65b0\u578b\u50a8\u80fd\u7cfb\u7edf\u7684\u9700\u6c42\u9010\u6e10\u589e\u957f\uff0c\u6709\u673a\u5316\u5408\u7269<\/b><\/strong>\u56e0\u5177\u5176\u72ec\u7279\u7684\u4f18\u52bf\uff08\u900f\u660e\uff0c\u8d28\u8f7b\uff0c\u67d4\u6027\uff0c\u8d44\u6e90\u4e30\u5bcc\u548c\u53ef\u6301\u7eed\u6027\uff09\u800c\u6781\u6709\u53ef\u80fd\u66ff\u4ee3\u73b0\u6709\u7684\u5546\u7528\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u6781\u6750\u6599\u3002\u5bf9\u4e8e\u6709\u673a\u7535\u6781\u6750\u6599\u800c\u8a00\uff0c\u81ea\u7531\u57fa\u662f\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u4e0d\u53ef\u907f\u514d\u7684\u4e2d\u95f4\u4ea7\u7269\u3002\u589e\u5927\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269\uff08Radical\u00a0intermediates\uff09\u7684\u53cd\u5e94\u6d3b\u6027\u53ef\u4ee5\u6700\u5927\u7a0b\u5ea6\u5730\u63d0\u9ad8\u6709\u673a\u7535\u6781\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\uff0c\u4f46\u8fd9\u5374\u4e0d\u5229\u4e8e\u7535\u6781\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5e73\u8861\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\u4ee5\u53ca\u7a33\u5b9a\u6027<\/b><\/strong>\u4ee5\u4f18\u5316\u7535\u6781\u6750\u6599\u7684\u7535\u6027\u80fd\uff08\u540c\u65f6\u5b9e\u73b0\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u5faa\u73af\u5bff\u547d\uff09\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u57fa\u4e8e\u6b64\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u5362\u5468\u5e7f<\/b><\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u53ef\u4ee5\u8c03\u63a7COFs\u6750\u6599\u4e2d\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u7b56\u7565\uff0c\u4ece\u800c\u5f97\u5230\u4e86\u9ad8\u6bd4\u5bb9\u91cf\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781[3]<\/sup>\u3002\u6df1\u5165\u7684\u8868\u5f81\u548c\u7406\u8bba\u6a21\u62df\u8bc1\u5b9eC-O\u2e31\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u548c\u03b1-C\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269<\/b><\/strong>\u5728\u94a0\u5316\/\u53bb\u94a0\u5316\u8fc7\u7a0b\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\uff08\u56fe6\uff09\u3002\u5177\u4f53\u800c\u8a00\uff0c\u4e8c\u7ef4COFs\u7684\u5806\u79ef\u884c\u4e3a\u53ef\u4ee5\u8f7b\u6613\u5730\u901a\u8fc7\u6539\u53d8\u5176\u539a\u5ea6\u800c\u8fdb\u884c\u8c03\u63a7<\/b><\/strong>\uff0c\u800c\u5176\u5806\u79ef\u884c\u4e3a\u53c8\u51b3\u5b9a\u4e86\u03b1-C\u81ea\u7531\u57fa\u4e2d\u95f4\u4ea7\u7269\u7684\u53cd\u5e94\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u4ee5\u53ca\u5b83\u4eec\u7684\u5bb9\u91cf\u8d21\u732e\uff08\u56fe7\uff09\u3002\u8fd9\u79cd\u53ef\u8c03\u63a7\u81ea\u7531\u57fa\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\u4ee5\u53ca\u7a33\u5b9a\u6027\u7684\u673a\u7406\u5bf9\u8bbe\u8ba1\u65b0\u578b\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u9053\u8def\u3002<\/p>\n

\u56fe<\/b><\/strong>5 <\/b><\/strong>\u4e8c\u7ef4DAAQ-COF\u7684\u5408\u6210\u8def\u7ebf\uff0c\u6a21\u62df\u7ed3\u6784\u53ca\u5c42\u5c42\u5806\u79ef<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>6 <\/b><\/strong>\u4e8c\u7ef4DAAQ-COF\u6750\u6599\u7684\u50a8\u94a0\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>7 <\/b><\/strong>\u4e0d\u540c\u539a\u5ea6\u7684\u4e8c\u7ef4DAAQ-COF\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4. \u950c\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/h3>\n

Joule<\/b><\/strong>\uff1a<\/b><\/strong>MOF<\/b><\/strong>\u884d\u751f\u7269\u5b9e\u73b0Zn\u91d1\u5c5e\u8d1f\u6781\u9ad8\u5ea6\u53ef\u9006\u3001\u65e0\u679d\u6676\u7684\u6c89\u79ef\/\u6eb6\u89e3<\/b><\/strong><\/p>\n

Zn\u91d1\u5c5e\u5177\u6709\u4f4e\u6210\u672c\u3001\u9ad8\u5bb9\u91cf\uff08820 mAh g-1<\/sup>\uff09\u3001\u4f4e\u7535\u52bf\u548c\u73af\u5883\u53cb\u597d\u7684\u7279\u70b9\uff0c\u56e0\u6b64\u975e\u5e38\u6709\u5e0c\u671b\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u5e94\u7528\u5728\u6c34\u7cfb\u50a8\u80fd\u5668\u4ef6\u4e2d\u3002\u7136\u800c\uff0c\u91d1\u5c5eZn\u8d1f\u6781\u5728\u7535\u5316\u5b66\u6c89\u79ef\/\u6eb6\u89e3\u65f6\u5b58\u5728\u7684\u679d\u6676\u751f\u957f\u3001\u53ef\u9006\u6027\u5dee\u3001\u6790\u6c22\u53cd\u5e94<\/b><\/strong>\u7b49\u95ee\u9898\u5374\u9650\u5236\u4e86\u5b83\u7684\u5b9e\u9645\u5e94\u7528\u3002\u4e3a\u4e86\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\uff0c\u590d\u65e6\u5927\u5b66\u7684\u738b\u6c38\u521a<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u5728500\u2103\u4e0b\u7145\u70e7MOF\uff08ZIF-8\uff09\u7684\u65b9\u6cd5\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578bZn\u8f7d\u4f53\u6750\u6599\uff08ZIF-8-500\uff09\uff08\u56fe8\uff09[4]<\/sup>\u3002\u8be5\u6750\u6599\u5177\u6709\u5982\u4e0b\u7279\u70b9\uff1a\uff081\uff09\u5177\u6709\u591a\u5b54\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u7684\u6d78\u6da6\u5e76\u5bb9\u7eb3\u4f53\u79ef\u81a8\u80c0\uff1b\uff082\uff09\u9aa8\u67b6\u4e2d\u542b\u6709\u5c11\u91cf\u7684Zn\u5355\u8d28\uff0c\u53ef\u4ee5\u589e\u5f3a\u6750\u6599\u7684\u5bfc\u7535\u6027\u5e76\u8bf1\u5bfcZn\u7684\u5747\u5300\u6c89\u79ef\uff1b\uff083\uff09\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u6790\u6c22\u8fc7\u7535\u4f4d\uff0c\u53ef\u4ee5\u51cf\u5c11\u526f\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5f53\u5176\u4f5c\u4e3aZn\u91d1\u5c5e\u8d1f\u6781\u8f7d\u4f53\u6750\u6599\u65f6\uff0c\u5b83\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u5e93\u4f26\u6548\u7387\u4e14\u65e0Zn\u679d\u6676<\/b><\/strong>\u7684\u4ea7\u751f\uff08\u56fe9\uff09\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u4e5f\u5c06\u6c89\u79efZn\u91d1\u5c5e\u540e\u7684Zn@ZIF-8-500\u8d1f\u6781\uff0810 mAh cm-2<\/sup>\u00a0Zn\uff09\u4e0eI2<\/sub>\u6b63\u6781\u914d\u5bf9\u6784\u9020\u4e86I<\/b><\/strong>2<\/b><\/sub><\/strong>\/\/Zn@<\/b><\/strong>ZIF-<\/b><\/strong>8<\/b><\/strong>–<\/b><\/strong>500<\/b><\/strong>\u53ef\u5145\u7535\u7535\u6c60<\/b><\/strong>\uff08\u56fe10\uff09\u3002\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u8868\u660e\uff0cI2<\/sub>\/\/Zn@ZIF-8-500\u5177\u6709\u7740\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff088\u00a0A g-1<\/sup>\uff1a80 mAh g-1<\/sup>\uff09\u548c\u957f\u7684\u5faa\u73af\u5bff\u547d\uff081600\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a97%\uff09\u3002\u8be5\u65b9\u6cd5\u4e5f\u4e3a\u5236\u5907\u65b0\u578b\u3001\u4f4e\u6210\u672c\u548c\u9ad8\u53ef\u9006\u6027\u7684Zn\u91d1\u5c5e\u8d1f\u6781\u63d0\u4f9b\u4e86\u501f\u9274\u3002<\/p>\n

\u56fe<\/b><\/strong>8 <\/b><\/strong>Z<\/b><\/strong>IF-8<\/b><\/strong>\u884d\u751f\u7269\u7684\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe9<\/b><\/strong>\u00a0<\/b><\/strong>ZIF-<\/b><\/strong>8<\/b><\/strong>–<\/b><\/strong>500<\/b><\/strong>\u6750\u6599\u7684\u534a\u7535\u6c60\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>0 <\/b><\/strong>ZIF-<\/b><\/strong>8<\/b><\/strong>–<\/b><\/strong>500<\/b><\/strong>\u4e0eI<\/b><\/strong>2<\/b><\/sub><\/strong>\u7ec4\u6210\u7684\u5168\u7535\u6c60\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5. \u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><\/h3>\n

A<\/b><\/strong>CS Applied Materials & Interfaces<\/b><\/strong>\uff1a\u8d85\u7a33\u5b9a\u7684\u4e09\u55ea\u57faCOF\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><\/p>\n

\u6709\u7740\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5355\u5143\u7684COFs\u6750\u6599<\/b><\/strong>\u662f\u4e00\u7c7b\u7406\u60f3\u7684\u7535\u5316\u5b66\u50a8\u80fd\u6750\u6599\u3002\u8fd1\u65e5\uff0c\u897f\u5317\u5e08\u8303\u5927\u5b66\u7684\u90ed<\/b><\/strong>\u660a<\/b><\/strong>\u548c\u6768\u6b66<\/b><\/strong>\u56e2\u961f\u91c7\u7528PDC\uff081,4-piperazinedicarboxaldehyde\uff09\u548cMA\uff08melamine\uff09\u4f5c\u4e3a\u7ed3\u6784\u5355\u5143\u901a\u8fc7\u919b\u80fa\u7f29\u5408\u53cd\u5e94\u5236\u5907\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u4e8c\u7ef4\uff08<\/b><\/strong>2<\/b><\/strong>D\uff09COF\u6750\u6599\uff08PDC-MA-COF\uff09<\/b><\/strong>\u4ee5\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\uff08\u56fe11\uff09[5]<\/sup>\u3002PDC-MA-COF\u6709\u7740\u4e09\u55ea\u57fa\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5355\u5143\uff0c\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff08748.2 m2<\/sup>\u00a0g-1<\/sup>\uff09\uff0c\u6781\u5c0f\u7684\u5b54\uff081.9 nm\uff09\uff0c\u5927\u7684\u5b54\u4f53\u79ef\uff081.21 cm3<\/sup>\u00a0g-1<\/sup>\uff09\u4ee5\u53ca\u9ad8\u7684\u6c2e\u542b\u91cf\uff0847.87%\uff09\u3002\u4e8c\u7ef4PDC-MA-COF\u5c42\u95f4\u5b58\u5728\u7740C-H\u2e31\u2e31\u2e31<\/b><\/strong>N\u6c22\u952e\uff0c\u5b83\u53ef\u4ee5\u201c\u9501\u4f4f\u201d\u76f8\u90bb\u5c42\u4e4b\u95f4\u7684\u76f8\u5bf9\u8ddd\u79bb\u4ee5\u907f\u514d\u5c42\u95f4\u6ed1\u52a8\uff0c\u8fd9\u6709\u5229\u4e8e\u4fdd\u6301COF\u7684\u6709\u5e8f\u591a\u5b54\u7ed3\u6784\u5e76\u63d0\u9ad8\u7535\u6781\u754c\u9762\u4e0e\u4e09\u55ea\u57fa\u6d3b\u6027\u5355\u5143\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u901f\u7387\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u8be5PDC-MA-COF\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong>\uff1a\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u6bd4\u7535\u5bb9\u6700\u9ad8\u53ef\u8fbe335 F\u00a0g–<\/sup>1<\/sup>\u4e1419.71%\u7684\u4e09\u55ea\u57fa\u6d3b\u6027\u5355\u5143\u90fd\u53c2\u4e0e\u4e86\u53cd\u5e94\uff1b\u5728\u4e8c\u7535\u6781\u4f53\u7cfb\uff0c1.0 A\u00a0g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u6bd4\u7535\u5bb9\u9ad8\u8fbe94 F\u00a0g-1<\/sup>\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u5c06PDC-MA-COF\u4e8e\u6d3b\u6027\u78b3\uff08AC\uff09\u914d\u5bf9\u6784\u6210\u4e86\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668PDC-MA-COF\/\/AC\uff0c\u5b83\u5728750 W kg-1<\/sup>\u7684\u529f\u7387\u5bc6\u5ea6\u4e0b\u4ecd\u7136\u8868\u73b0\u51fa\u4e8629.2 Wh\u00a0kg–<\/sup>1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\uff08\u56fe12\uff09\u3002\u6b64\u5916\uff0c\u8be5\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u4e5f\u663e\u793a\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5373\u4f7f\u57282<\/b><\/strong>0000<\/b><\/strong>\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u7136\u67098<\/b><\/strong>8<\/b><\/strong>%<\/b><\/strong>\uff0c\u8fd9\u6bd4\u6700\u8fd1\u62a5\u9053\u7684\u7c7b\u4f3c\u6750\u6599\u6027\u80fd\u90fd\u8981\u597d\u3002\u8be5\u9879\u7814\u7a76\u4e5f\u4e3a\u8bbe\u8ba1\u53ef\u5e94\u7528\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684COFs\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\u3002<\/p>\n

\u56fe1<\/b><\/strong>1 PDC-MA-COF<\/b><\/strong>\u7684\u5408\u6210\u8fc7\u7a0b\u53ca\u6a21\u62df\u7684\u7ed3\u6784\u6a21\u578b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>2 <\/b><\/strong>\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668PDC-<\/b><\/strong>MA-COF\/\/<\/b><\/strong>AC\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

6. \u71c3\u6599\u7535\u6c60<\/b><\/strong><\/h3>\n

Energy & Environmental Science\uff1a\u8868\u9762\u6d3b\u6027\u5242\u52a9\u529bMOFs\u6750\u6599\u8f6c\u5316\u4e3a\u5177\u6709\u9ad8\u6d3b\u6027\u4f4d\u70b9\u5bc6\u5ea6\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

\u5f00\u53d1\u80fd\u591f\u9ad8\u6548\u50ac\u5316\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7684\u65e0\u94c2\u50ac\u5316\u5242\u662f\u5b9e\u73b0\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u4f4e\u6210\u672c\u3001\u5546\u4e1a\u5316\u5e94\u7528\u7684\u5173\u952e\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u5339\u5179\u5821\u5927\u5b66\u7684\u738b\u56fd\u950b<\/b><\/strong>\uff0c\u7f8e\u56fd\u5361\u8010\u57fa\u6885\u9686\u5927\u5b66\u7684Shawn Litster<\/b><\/strong>\u548c\u7f8e\u56fd\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5e03\u6cd5\u7f57\u5206\u6821<\/b><\/strong>\u7684\u6b66\u521a<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u8868\u9762\u6d3b\u6027\u5242\u8f85\u52a9\u4fee\u9970MOF\u968f\u540e\u8fdb\u884c\u9650\u57df\u78b3\u5316\u7684\u65b9\u6cd5\u5236\u5907\u51fa\u4e86\u6838\u58f3\u7ed3\u6784\u7684Co-N-C\u50ac\u5316\u5242\uff08\u56fe13\uff09[6]<\/sup>\u3002\u8868\u9762\u6d3b\u6027\u5242\u4e0eCo\u63ba\u6742\u7684ZIF-8 MOF\u6750\u6599\u4e4b\u95f4\u7684\u5b58\u5728\u7740\u914d\u4f4d\u6548\u5e94\uff0c\u5b83\u53ef\u4ee5\u4ea7\u751f\u72ec\u7279\u7684\u9650\u57df\u6548\u679c\uff0c\u4ece\u800c\u907f\u514d\u5728\u9ad8\u6e29\u70ed\u89e3\u7684\u65f6\u5019Co\u5355\u539f\u5b50\u4f4d\u70b9\u95f4\u7684\u805a\u96c6\u548cZIF-8\u5185\u90e8\u5fae\u5b54\u7ed3\u6784\u7684\u584c\u9677<\/b><\/strong>\u3002\u5728\u7814\u7a76\u7684\u8868\u9762\u6d3b\u6027\u5242\u4e2d\uff0cF127\u5d4c\u6bb5\u5171\u805a\u7269<\/b><\/strong>\u6709\u7740\u6700\u597d\u7684\u7ed3\u679c\uff0c\u76f8\u6bd4\u4e8e\u4e0d\u4f7f\u7528\u8868\u9762\u6d3b\u6027\u5242\u6240\u5236\u5f97\u7684\u6750\u6599\u800c\u8a00\uff0c\u5b83\u80fd\u591f\u4f7f\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4f4d\u70b9\u5bc6\u5ea6\u6210\u500d\u589e\u52a0<\/b><\/strong>\u3002\u6839\u636e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7684\u7ed3\u679c\uff0c\u4e0e\u5176\u4ed6Co\u50ac\u5316\u5242\u4e0d\u540c\u7684\u662f\uff0c\u8be5\u65b0\u578b\u539f\u5b50\u7ea7\u5206\u6563\u7684Co-N-C@F127\u50ac\u5316\u5242\u5305\u542b\u7740\u5927\u91cf\u7684CoN2<\/sub>+<\/sub>2<\/sub>\u4f4d\u70b9\uff0c\u8be5\u4f4d\u70b9\u5177\u6709\u50ac\u5316\u6d3b\u6027\u4e14\u80fd\u6709\u6548\u5730\u901a\u8fc7\u56db\u4e2a\u7535\u5b50\u8def\u5f84\u50ac\u5316ORR\u3002\u50ac\u5316\u6027\u80fd\u6d4b\u8bd5\u8868\u660e\uff0cCo-N-C@F127\u50ac\u5316\u5242\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u8868\u73b0\u51fa\u4e86\u6781\u597d\u7684ORR\u6d3b\u6027\uff08\u534a\u6ce2\u7535\u4f4d\u4ec5\u4e3a0<\/b><\/strong>.84 <\/b><\/strong>V\uff09\u548c\u589e\u5f3a\u7684\u7a33\u5b9a\u6027\u3002<\/b><\/strong>\u6b64\u5916\uff0c\u4f5c\u8005\u4e5f\u7814\u7a76\u4e86\u8be5\u50ac\u5316\u5242\u7684\u5b9e\u9645\u5e94\u7528\u6548\u679c\uff0c\u5728H2<\/sub>-O2<\/sub>\u71c3\u6599\u7535\u6c60\u4e2d\u5b83\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u521d\u59cb\u529f\u7387\u5bc6\u5ea6\uff080.87 W\u00a0cm-2<\/sup>\uff09\u548c\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff08\u56fe14\uff09\u3002\u8fd9\u79cd\u8868\u9762\u6d3b\u6027\u5242\u8f85\u52a9\u7684\u9650\u57df\u7b56\u7565\u4e5f\u5bf9\u5408\u6210\u5177\u6709\u9ad8\u6d3b\u6027\u4f4d\u70b9\u5bc6\u5ea6\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n

\u56fe1<\/b><\/strong>3<\/b><\/strong>\u00a0Co-N-C\u548cCo-N-C@F127\u50ac\u5316\u5242\u7684\u5236\u5907\u6d41\u7a0b\u548c\u5fae\u89c2\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>4<\/b><\/strong>\u00a0Co-N-C@F127\u50ac\u5316\u5242\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

7. \u50a8\u6c22<\/b><\/strong><\/h3>\n

International Journal of Hydrogen Energy<\/b><\/strong>\uff1a\u5421\u5576\u6865\u63a5\u7684\u535f\u5549COF\u7528\u4e8e\u9ad8\u6548\u50a8\u6c22<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u6750\u6599\uff08COFs\uff09\u662f\u4e00\u7c7b\u78b3\u57fa\u805a\u5408\u7269\u6750\u6599\uff0c\u5176\u72ec\u7279\u7684\u5b54\u9053\u7ed3\u6784\u548c\u5927\u7684\u6bd4\u8868\u9762\u79ef\u4f7f\u5176\u975e\u5e38\u6709\u5e0c\u671b\u7528\u4e8e\u5438\u9644\u6c22\u6c14\u3002\u5c3d\u7ba13D\u00a0COFs\u6709\u7740\u8f83\u9ad8\u7684\u50a8\u6c22\u91cf\uff0c\u4f46\u662f\u5176\u5bc6\u5ea6\u4f4e\u3001\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u56e0\u6b64\u5b83\u4eec\u7684\u7a33\u5b9a\u6027\u4e0d\u59822D\u00a0COFs\u3002\u57fa\u4e8e\u6b64\uff0c\u5370\u5ea6\u7406\u5de5\u5b66\u9662\u7684<\/b><\/strong>Sarbani Ghosh<\/b><\/strong>\u56e2\u961f\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff0c\u8499\u7279\u5361\u7f57\u6a21\u62df\u548c\u5b9e\u9a8c\u7684\u65b9\u5f0f\u7814\u7a76\u4e86\u535f\u55492D\u00a0COF\u7684\u50a8\u6c22\u6027\u80fd\u5e76\u5c06\u5176\u4e0e\u5e38\u89c1\u76842D\u00a0COFs\uff0cCOF-1\u548cCOF-5\u8fdb\u884c\u4e86\u6bd4\u8f83[7]<\/sup>\u3002\u5706\u67f1\u72b6\u7684\u535f\u55492D\u00a0COFs\u662f\u7531\u72ec\u7acb\u7684\u5355\u5143\u5757\u901a\u8fc7\u591a\u5c42\u5806\u53e0\u7684\u65b9\u5f0f\u6784\u5efa\u8d77\u6765\u7684\uff0c\u5c42\u4e0e\u5c42\u4e4b\u95f4\u7531\u8303\u5fb7\u74e6\u5c14\u65af\u952e\u8fde\u63a5\uff0c\u8fd9\u53ef\u4ee5\u6709\u6548\u5730\u589e\u52a0\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u4ee5\u4fbf\u4e8e\u5b58\u50a8\u6c22\u6c14\uff08\u56fe15\uff09\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u8fd8\u91c7\u7528\u5355\u4e2a\u3001\u4e24\u4e2a\u3001\u4e09\u4e2a\u548c\u56db\u4e2a\u5421\u5576\u5206\u5b50\u5c06\u535f\u5549COFs\u5c42\u95f4\u7684\u95f4\u9699\u8fdb\u884c\u4e86\u6865\u63a5\uff08\u56fe15\uff09\u3002\u5421\u5576\u5206\u5b50\u7684\u63d2\u5165\u53ef\u4ee5\u589e\u52a0\u5c42\u4e4b\u95f4\u7684\u95f4\u8ddd\u4ee5\u53ca\u81ea\u7531\u4f53\u79ef<\/b><\/strong>\u3002\u4e3a\u4e86\u786e\u4fdd\u6865\u63a5\u540e\u7684COFs\u5728\u50a8\u6c22\u540e\u7684\u7a33\u5b9a\u6027\uff0c\u4f5c\u8005\u91c7\u7528\u4e86\u4ea4\u66ff\u5c42\u72b6\u7684\u535f\u5549COF\u4f5c\u4e3a\u6865\u63a5\u5bf9\u8c61\u3002\u8499\u7279\u5361\u7f57\u6a21\u62df\u7ed3\u679c\u8868\u660e\u7ecf\u8fc7\u5421\u5576\u63ba\u6742\u4e4b\u540e\uff0c2D\u535f\u5549COFs\u7684\u50a8\u6c22\u5bb9\u91cf\u6709\u4e86\u663e\u8457\u5730\u63d0\u5347\uff0c\u8fd9\u6e90\u4e8e\u63ba\u6742\u540e2D\u535f\u5549COFs\u6750\u6599\u81ea\u7531\u4f53\u79ef\u7684\u589e\u52a0\u3002\u7814\u7a76\u53d1\u73b0\uff0c4\u4e2a\u5421\u5576\u5206\u5b50\u63ba\u6742\u7684\u535f\u5549COF\u6709\u7740\u6700\u9ad8\u7684\u50a8\u6c22\u5bb9\u91cf\u3002\u5728298K\u548c100 bar\u4e0b\uff0c\u5b83\u7684\u5bb9\u91cf\/\u6bd4\u5bb9\u91cf\u8fbe\u5230\u4e865.1 wt%\u548c20 g\u00a0H2<\/sub>\/L\uff0c\u8fd9\u9ad8\u4e8e\u7f8e\u56fd\u80fd\u6e90\u90e8\u8bbe\u5b9a\u7684\u8d28\u91cf\u6bd4\u5bb9\u91cf\u6807\u51c6\uff08\u56fe16\uff09\u3002<\/p>\n

\u56fe1<\/b><\/strong>5<\/b><\/strong>\u00a0COF\u7684\u7ed3\u6784\u53ca\u4e0d\u540c\u7c7b\u578b\u7684\u5421\u5576\u63ba\u6742\u7684\u7ba1\u72b6\u535f\u5549COF<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>6<\/b><\/strong>\u00a0\u4e0d\u540c\u7c7b\u578b\u7684\u5421\u5576\u63ba\u6742\u7684\u7ba1\u72b6\u535f\u5549COF\u5438\u9644\u7684\u6c22\u6c14\u91cf<\/b><\/strong><\/p>\n

\"\"<\/p>\n

8. \u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/h3>\n

Advanced Science<\/b><\/strong>\uff1a\u9499\u949b\u77ff\/Zr-MOF\u5f02\u8d28\u7ed3\u63d0\u9ad8\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n

\u6700\u8fd1\uff0c\u6709\u673a-\u65e0\u673a\u6df7\u5408\u9499\u949b\u77ff<\/b><\/strong>\u5728\u5149\u4f0f\u9886\u57df\u53d7\u5230\u4e86\u5e7f\u6cdb\u5730\u7814\u7a76\uff0c\u8fd9\u662f\u56e0\u4e3a\u5b83\u6709\u7740\u7b80\u6613\u7684\u5236\u5907\u65b9\u6cd5\u4ee5\u53ca\u4f18\u5f02\u7684\u5149\u7535\u6027\u8d28\u3002\u4e0d\u65ad\u63d0\u9ad8\u9499\u949b\u77ff\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u662f\u4e00\u4e2a\u91cd\u8981\u76ee\u6807\u3002\u4f46\u4e0e\u6b64\u540c\u65f6\uff0c\u8003\u8651\u5230\u5176\u5728\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u6027\u8f83\u5dee<\/b><\/strong>\uff0c\u8bb8\u591a\u5b66\u8005\u4e5f\u5728\u91cd\u70b9\u7814\u7a76\u5982\u4f55\u63d0\u9ad8\u5176\u957f\u671f\u7684\u7a33\u5b9a\u6027\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u56fd\u7acb\u53f0\u6e7e\u5927\u5b66\u7684<\/b><\/strong>Kevin C.-W. Wu<\/b><\/strong>\u548c<\/b><\/strong>\u00a0Chu-Chen Chueh<\/b><\/strong>\u56e2\u961f\u5c55\u793a\u4e86\u9499\u949b\u77ff\/Zr-MOF\u5f02\u8d28\u7ed3\u5728\u6539\u5584\u5012\u7f6e\u7684p-i-n\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u548c\u7a33\u5b9a\u6027\u65b9\u9762\u7684\u5de8\u5927\u4f5c\u7528[8]<\/sup>\u3002\u4f5c\u8005\u4e3b\u8981\u9009\u53d6\u4e86\u4e24\u79cd\u7c7b\u578b\u7684Zr-MOFs\uff1aUiO-<\/b><\/strong>66<\/b><\/strong>\u548cMOF-<\/b><\/strong>808<\/b><\/strong>\u6765\u8fdb\u884c\u7814\u7a76\uff0c\u56e0\u4e3a\u5b83\u4eec\u90fd\u5177\u5f88\u597d\u7684\u6c34\u5206\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u56fe17\uff09\u3002MOFs\u4f5c\u4e3a\u9694\u5c42\u4e0e\u9499\u949b\u77ff\u8584\u819c\u76f8\u7ed3\u5408\u53ef\u4ee5\u8fc7\u6ee4\u7d2b\u5916\u7ebf\u5e76\u63d0\u9ad8\u9499\u949b\u77ff\u7684\u7ed3\u6676\u5ea6<\/b><\/strong>\u3002\u56e0\u6b64\uff0c\u76f8\u6bd4\u4e8e\u5bf9\u6bd4\u6837\uff0815.79%\uff09\uff0cUiO-66\/MOF-808\u4fee\u9970\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u8868\u73b0\u51fa\u4e86\u6539\u5584\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0817.01%\/16.55%\uff09\u3002\u5f53\u8fdb\u4e00\u6b65\u5229\u7528\u9499\u949b\u77ff\/Zr-MOF\u5f02\u8d28\u7ed3\u5236\u5907\u5668\u4ef6\u65f6\uff0c\u6df7\u5408\u7684MOFs\u53ef\u80fd\u5206\u6563\u5728\u9499\u949b\u77ff\u6676\u754c\u4e0a\uff0c\u8fd9\u4f1a\u4ea7\u751f\u201c\u6676\u7c92\u9501\u5b9a\u201d\u6548\u5e94\u4ee5\u4f7f\u7f3a\u9677\u949d\u5316\u5e76\u589e\u5f3a\u8584\u819c\u5bf9\u6c34\u5206\u7684\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0cUiO-66\/MOF-808-\u6df7\u5408\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u8fdb\u4e00\u6b65\u63d0\u5347\u5230\u4e861<\/b><\/strong>8.01<\/b><\/strong>%\u548c1<\/b><\/strong>7.81<\/b><\/strong>%<\/b><\/strong>\u3002\u6b64\u5916\uff0c\u5373\u4f7f\u5728\u7a7a\u6c14\u4e2d\u4fdd\u5b58\u8d85\u8fc72\u5468\u65f6\u95f4<\/b><\/strong>\uff08\u6e29\u5ea6\uff1a25\u2103\uff0c\u76f8\u5bf9\u6e7f\u5ea6\uff1a60\u00b15%\uff09\uff0c\u8fd9\u4e24\u79cd\u6df7\u5408\u5668\u4ef6\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u4fdd\u6301\u7387\u4ecd\u7136\u8d85\u8fc77<\/b><\/strong>0<\/b><\/strong>%<\/b><\/strong>\uff0c\u8fd9\u662f\u56e0\u4e3aMOFs\u4fee\u9970\u7684\u9499\u949b\u77ff\u8584\u819c\u5177\u6709\u66f4\u597d\u7684\u7a33\u5b9a\u6027\uff08\u56fe18\uff09\u3002\u8fd9\u9879\u7814\u7a76\u4e5f\u8868\u660e\u91c7\u7528\u9499\u949b\u77ff\/MOF\u5f02\u8d28\u7ed3\u6765\u5236\u5907\u9ad8\u6548\u7a33\u5b9a\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u662f\u975e\u5e38\u6709\u6f5c\u529b\u7684\u3002<\/p>\n

\u56fe1<\/b><\/strong>7<\/b><\/strong>\u00a0<\/b><\/strong>\u4e24\u79cdUiO-<\/b><\/strong>66<\/b><\/strong>\u548cMOF-<\/b><\/strong>808 <\/b><\/strong>MOF\u7684\u7ed3\u6784\u3001\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u548c\u5149\u81f4\u53d1\u5149\u5149\u8c31<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>8\u00a0<\/b><\/strong>\u5668\u4ef6\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u968f\u65f6\u95f4\u7684\u53d8\u5316\u89c4\u5f8b\u53ca3<\/b><\/strong>0<\/b><\/strong>\u5929\u8001\u5316\u540e\u7684\u8868\u9762\u5f62\u8c8c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

[1] T. Yang, Y. Liu, D. Yang, B. Deng, Z. Huang, C.D. Ling, H. Liu, G. Wang, Z. Guo, R. Zheng, Bimetallic metal-organic frameworks derived Ni-Co-Se@C hierarchical bundle-like nanostructures with high-rate pseudocapacitive lithium ion storage, Energy Storage Mater., 17 (2019) 374-384.<\/p>\n

[2] A.E. Baumann, X. Han, M.M. Butala, V.S. Thoi, Lithium Thiophosphate Functionalized Zirconium MOFs for Li-S Batteries with Enhanced Rate Capabilities, J Am. Chem. Soc., 141 (2019) 17891-17899.<\/p>\n

[3] S. Gu, S. Wu, L. Cao, M. Li, N. Qin, J. Zhu, Z. Wang, Y. Li, Z. Li, J. Chen, Z. Lu, Tunable Redox Chemistry and Stability of Radical Intermediates in 2D Covalent Organic Frameworks for High Performance Sodium Ion Batteries, J Am. Chem. Soc., 141 (2019) 9623-9628.<\/p>\n

[4] Z. Wang, J. Huang, Z. Guo, X. Dong, Y. Liu, Y. Wang, Y. Xia, A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes, Joule, 3 (2019) 1289-1300.<\/p>\n

[5] L. Li, F. Lu, R. Xue, B. Ma, Q. Li, N. Wu, H. Liu, W. Yao, H. Guo, W. Yang, Ultrastable Triazine-Based Covalent Organic Framework with an Interlayer Hydrogen Bonding for Supercapacitor Applications, ACS Appl. Mater. Interfaces, 11 (2019) 26355-26363.<\/p>\n

[6] Y. He, S. Hwang, D.A. Cullen, M.A. Uddin, L. Langhorst, B. Li, S. Karakalos, A.J. Kropf, E.C. Wegener, J. Sokolowski, M. Chen, D. Myers, D. Su, K.L. More, G. Wang, S. Litster, G. Wu, Highly active atomically dispersed CoN4<\/sub>\u00a0fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy, Energy Environ. Sci, 12 (2019) 250-260.<\/p>\n

[7] S. Ghosh, J.K. Singh, Hydrogen adsorption in pyridine bridged porphyrin-covalent organic framework, Int. J. Hydrogen Energy, 44 (2019) 1782-1796.<\/p>\n

[8] C.C. Lee, C.I. Chen, Y.T. Liao, K.C. Wu, C.C. Chueh, Enhancing Efficiency and Stability of Photovoltaic Cells by Using Perovskite\/Zr-MOF Heterojunction Including Bilayer and Hybrid Structures, Adv. Sci. (Weinh), 6 (2019) 1801715.<\/p>\n

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