{"id":193463,"date":"2019-12-28T06:19:43","date_gmt":"2019-12-27T22:19:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=193463"},"modified":"2019-12-27T21:19:59","modified_gmt":"2019-12-27T13:19:59","slug":"nature-communications%ef%bc%9a%e7%a8%b3%e5%ae%9a%e4%b8%94%e9%ab%98%e6%95%88%e7%9a%84%e6%96%b0%e5%9e%8b%e9%92%af%e5%9f%ba%e7%94%b5%e5%ad%90%e5%8c%96%e5%90%88%e7%89%a9%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=193463","title":{"rendered":"Nature Communications\uff1a\u7a33\u5b9a\u4e14\u9ad8\u6548\u7684\u65b0\u578b\u94af\u57fa\u7535\u5b50\u5316\u5408\u7269\u50ac\u5316\u5242\u7528\u4e8eSuzuki\u4ea4\u53c9\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"

\u5f15\u8a00<\/strong><\/p>\n

\u94af\uff08Pd\uff09\u50ac\u5316Suzuki\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7531\u9234\u6728\u7ae0\uff08Suzuki Akira\uff09\u4e8e1979\u5e74\u9996\u6b21\u62a5\u9053\uff0c\u8be5\u53cd\u5e94\u5728\u6709\u673a\u5408\u6210\u4e2d\u7528\u9014\u5f88\u5e7f\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5e95\u7269\u9002\u5e94\u6027\u53ca\u5b98\u80fd\u56e2\u8010\u53d7\u6027\uff0c\u5e38\u7528\u4e8e\u5408\u6210\u591a\u70ef\u70c3\u3001\u82ef\u4e59\u70ef\u548c\u8054\u82ef\u7684\u884d\u751f\u7269\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u591a\u79cd\u5929\u7136\u4ea7\u7269\u3001\u6709\u673a\u6750\u6599\u7684\u5408\u6210\u4e2d\u3002\u4e3a\u4e86\u514b\u670d\u5e95\u7269\u6d3b\u5316\u800c\u9020\u6210\u7684\u9ad8\u53cd\u5e94\u52bf\u5792\uff0c\u65e0\u8bba\u662f\u5747\u76f8\u548c\u5f02\u76f8Pd\u57fa\u50ac\u5316\u5242\u90fd\u4f9d\u8d56\u4e8e\u9ad8\u7535\u5b50\u5bc6\u5ea6\u7684Pd\u6d3b\u6027\u4f4d\u70b9\uff0c\u800c\u5f02\u76f8\u50ac\u5316\u6bd4\u5747\u76f8\u50ac\u5316\u5177\u6709\u660e\u663e\u6613\u4e8e\u5206\u79bb\u518d\u5229\u7528\u7684\u4f18\u52bf\uff0c\u4f46\u662f\u8d1f\u8f7d\u578b\u7684\u5f02\u76f8Pd\u57fa\u50ac\u5316\u5242\u540c\u6837\u5b58\u5728\u6d3b\u6027\u91d1\u5c5ePd\u6eb6\u89e3\u6216\u8005\u56e2\u805a\u7b49\u95ee\u9898\uff0c\u5bfc\u81f4\u4e86\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u5b58\u5728\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u8bbe\u8ba1\u4e00\u79cd\u5177\u6709\u9ad8\u7535\u5b50\u5bc6\u5ea6\u7684Pd\u6d3b\u6027\u4e2d\u5fc3\u7684\u5f02\u76f8\u50ac\u5316\u5242\uff0c\u540c\u65f6\u4fdd\u8bc1\u5176\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u80fd\u662fSuzuki\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u4e00\u5927\u96be\u9898\u3002<\/p>\n

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\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u65e5\u672c\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u5927\u5b66\u5143\u7d20\u6218\u7565\u7814\u7a76\u4e2d\u5fc3\u53f6\u5929\u5357(Tian-Nan Ye)\u52a9\u7406\u6559\u6388\uff0c\u9c81\u6768\u5e06\uff08Yangfan Lu\uff09\u52a9\u7406\u6559\u6388\u4e0e\u7ec6\u91ce\u79c0\u96c4\uff08Hideo Hosono\uff09\u6559\u6388\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u6b66\u6c49\u5149\u7535\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u8096\u6cfd\u6587(Zewen Xiao)\u6559\u6388<\/strong>\u5408\u4f5c\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684Pd\u57fa\u91d1\u5c5e\u9593\u5316\u5408\u7269\u7535\u5b50\u76d0\u6750\u6599Y3<\/sub>Pd2<\/sub>\uff0c\u5b9e\u73b0\u4e86Pd\u6d3b\u6027\u4e2d\u5fc3\u9ad8\u7535\u5b50\u5bc6\u5ea6\u7684\u7279\u6027\uff0c\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u5e26\u8d1f\u7535\u7684Pd\u6d3b\u6027\u4f4d\u70b9\u4fc3\u8fdb\u4e86\u6709\u673a\u5364\u5316\u7269\u5206\u5b50\u7684\u6d3b\u5316\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86Suzuki\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u6d3b\u6027\uff0c\u4e0e\u91d1\u5c5ePd\u76f8\u6bd4\uff0cY3<\/sub>Pd2<\/sub>\u6d3b\u6027\u63d0\u9ad8\u4e86\u8fd110\u500d\uff0c\u6d3b\u5316\u80fd\u964d\u4f4e\u4e86\u8fd1~35%\u3002\u6b64\u5916\uff0cY3<\/sub>Pd2<\/sub>\u50ac\u5316\u5242\u7ecf\u8fc720\u6b21\u5faa\u73af\u4e4b\u540e\u65e0\u660e\u663e\u5931\u6d3b\uff0c\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u8be5\u7535\u5b50\u76d0\u5316\u5408\u7269\u6676\u683cPd\u6d3b\u6027\u4e2d\u5fc3\u5177\u6709\u5f88\u5f3a\u7684\u6297\u6eb6\u89e3\u548c\u6297\u56e2\u805a\u7279\u6027\uff0c\u4ece\u800c\u4fdd\u8bc1\u4e86\u5176\u4f18\u5f02\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201cPalladium-bearing intermetallic electride as efficient and stable catalyst for Suzuki cross-coupling reactions<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNature Communications <\/strong>\u4e0a\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb:<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Palladium-bearing intermetallic electride as efficient and stable catalyst for Suzuki cross-coupling reactions. Nature Communications, 2019.<\/p>\n

https:\/\/doi.org\/10.1038\/s41467-019-13679-0<\/strong><\/a><\/p>\n

\u53f6\u5929\u5357\u6559\u6388\u7b80\u4ecb\uff1a<\/strong><\/p>\n

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\u00a0<\/strong>\u9c81\u6768\u5e06\u6559\u6388\u7b80\u4ecb\uff1a<\/strong><\/p>\n

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