{"id":193909,"date":"2020-01-06T06:43:56","date_gmt":"2020-01-05T22:43:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=193909"},"modified":"2020-01-05T18:44:09","modified_gmt":"2020-01-05T10:44:09","slug":"%e5%8c%97%e7%a7%91%e5%a4%a7%e7%8e%8b%e6%88%88%e5%9b%a2%e9%98%9fensm-%e6%96%b0%e5%9e%8b%e5%a4%9a%e5%8a%9f%e8%83%bd%e5%ae%9a%e5%9e%8b%e5%a4%8d%e5%90%88%e7%9b%b8%e5%8f%98%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=193909","title":{"rendered":"\u5317\u79d1\u5927\u738b\u6208\u56e2\u961fEnSM: \u65b0\u578b\u591a\u529f\u80fd\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u76f8\u53d8\u6750\u6599(PCMs-Phase Change Materials)\u662f\u6307\u6e29\u5ea6\u4e0d\u53d8\u7684\u60c5\u51b5\u4e0b\u800c\u6539\u53d8\u7269\u8d28\u72b6\u6001\u5e76\u80fd\u63d0\u4f9b\u6f5c\u70ed\u7684\u6750\u6599\u3002\u8f6c\u53d8\u7269\u7406\u6027\u8d28\u7684\u8fc7\u7a0b\u79f0\u4e3a\u76f8\u53d8\u8fc7\u7a0b\uff0c\u8fd9\u65f6\u76f8\u53d8\u6750\u6599\u5c06\u5438\u6536\u6216\u91ca\u653e\u5927\u91cf\u7684\u6f5c\u70ed\u3002\u76f8\u53d8\u6750\u6599\u4e00\u65e6\u5728\u4eba\u7c7b\u751f\u6d3b\u88ab\u5e7f\u6cdb\u5e94\u7528\uff0c\u5c06\u6210\u4e3a\u8282\u80fd\u73af\u4fdd\u7684\u6700\u4f73\u7eff\u8272\u73af\u4fdd\u8f7d\u4f53\uff0c\u5728\u6211\u56fd\u5df2\u7ecf\u5217\u4e3a\u56fd\u5bb6\u7ea7\u7814\u53d1\u5229\u7528\u5e8f\u5217\u3002\u4f46\u662f\uff0c\u7eafPCMs\u7684\u6cc4\u6f0f\u548c\u4f4e\u70ed\u5bfc\u7387\u95ee\u9898\u6781\u5927\u5730\u9650\u5236\u4e86\u76f8\u53d8\u6750\u6599\u7684\u5438\u653e\u70ed\u6548\u7387\u3002\u76ee\u524d\uff0c\u8bb8\u591a\u62a5\u9053\u901a\u8fc7\u5236\u5907\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\u89e3\u51b3\u6cc4\u9732\u95ee\u9898\uff1b\u901a\u8fc7\u586b\u5145\u9ad8\u5bfc\u70ed\u7684\u6dfb\u52a0\u7269\u63d0\u5347\u70ed\u5bfc\u7387\uff0c\u6bd4\u5982\uff1a\u91d1\u5c5e\u3001\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u3001\u78b3\u7ea4\u7ef4\u7b49\u7b49\uff0c\u4ece\u800c\u6709\u6548\u5730\u6574\u5408\u4e86\u9ad8\u6548\u7684\u84c4\u70ed\/\u4f20\u70ed\u6027\u80fd\u3002\u5c3d\u7ba1\u76f8\u53d8\u6750\u6599\u5728\u84c4\u70ed\/\u4f20\u70ed\u65b9\u9762\u5df2\u7ecf\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u662f\u5355\u4e00\u7684\u70ed\u6027\u80fd\u4ecd\u7136\u65e0\u6cd5\u6ee1\u8db3\u76f8\u53d8\u6750\u6599\u65e5\u76ca\u589e\u957f\u7684\u591a\u529f\u80fd\u9700\u6c42\u3002\u56e0\u6b64\uff0c\u5728\u4fdd\u8bc1\u4f18\u5f02\u7684\u70ed\u6027\u80fd\u524d\u63d0\u4e0b\uff0c\u5982\u4f55\u6709\u6548\u5730\u5f00\u53d1\u524d\u6cbf\u6027\u7684\u65b0\u578b\u591a\u529f\u80fd\u76f8\u53d8\u590d\u5408\u6750\u6599\u4ee5\u6ee1\u8db3\u7279\u5b9a\u7684\u573a\u5408\u9700\u6c42\u6210\u4e3a\u8be5\u9886\u57df\u7814\u7a76\u7684\u7126\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u671f\uff0c\u5317\u4eac\u79d1\u6280\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u738b\u6208<\/b><\/strong>\u56e2\u961f\u5f00\u53d1\u51fa\u4e24\u79cd\u65b0\u578b\u591a\u529f\u80fd\u76f8\u53d8\u590d\u5408\u6750\u6599\u3002\u5176\u4e00\uff0c\u5229\u7528\u7b80\u4fbf\u7684\u6a21\u677f\u5408\u6210\u7b56\u7565\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7684\u78b3\u7eb3\u7c73\u7ba1\u675f\u7ec4\u88c5\u6210\u7684\u67d4\u6027\u591a\u7ea7\u5b54\u6d77\u7ef5\u57fa\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\uff0c\u5b9e\u73b0\u4e86\u5bf9\u8fc7\u654f\u6027\u9f3b\u708e\u7684\u9ad8\u6548\u70ed\u7597\u3002\u5176\u4e2d\uff0c\u6d77\u7ef5\u8f7d\u4f53\u7684\u591a\u7ea7\u5b54\u4fdd\u8bc1\u4e86\u76f8\u53d8\u6750\u6599\u7684\u9ad8\u6548\u56fa\u8f7d\uff0c\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u9ad8\u503c\u70ed\u7113\u548c\u4f4e\u70ed\u5bfc\u7387\u4fdd\u8bc1\u4e86\u957f\u65f6\u95f4\u7684\u70ed\u7597\u6548\u679c\uff0c\u6b64\u5916\u8bbe\u8ba1\u7684\u5916\u5c42\u7eaf\u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u8fd8\u53ef\u4ee5\u901a\u8fc7\u51c0\u5316\u6444\u5165\u9f3b\u8154\u7684\u7a7a\u6c14\u8d28\u91cf\u8fdb\u4e00\u6b65\u4f18\u5316\u70ed\u7597\u6548\u679c\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5<\/b><\/strong>\u201c<\/b><\/strong>Carbon Nanotube Bundles Assembled Flexible Hierarchical Framework Based Phase Change Material Composites for Thermal Energy Harvesting and Thermotherapy<\/b><\/strong>\u201d<\/b><\/strong>\u4e3a\u9898\u53d1\u8868\u5728<\/b><\/strong>Energy Storage Materials<\/b><\/strong>\u00a0(CiteScore\uff1a15.09)\uff0c\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9648\u6653\u3002<\/b><\/strong><\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe\u4e00\uff1a\u78b3\u7eb3\u7c73\u7ba1\u675f\u7ec4\u88c5\u78b3\u6d77\u7ef5\u793a\u610f\u56fe\u53caSEM\/TEM\u56fe<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u8f7d\u4f53\u5236\u5907\u793a\u610f\u56fe<\/p>\n

(b-d) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u8f7d\u4f53\u7684SEM\u56fe<\/p>\n

(e-g) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u8f7d\u4f53\u7684TEM\u56fe<\/p>\n

\u56fe\u4e8c\uff1a\u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u70ed\u6027\u80fd\u53ca\u5faa\u73af\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a-c) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u6f5c\u70ed<\/p>\n

(d-e) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u6d3b\u5316\u80fd<\/p>\n

(f) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u70ed\u5bfc\u7387<\/p>\n

(g-h) \u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u70ed\u5faa\u73af\u6027\u80fd<\/p>\n

\u56fe\u4e09\uff1a\u78b3\u7eb3\u7c73\u7ba1\u6d77\u7ef5\u57fa\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u70ed\u7597\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) \u76f8\u53d8\u6750\u6599\u57fa\u70ed\u7597\u53e3\u7f69\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

(b) \u76f8\u53d8\u6750\u6599\u57fa\u70ed\u7597\u53e3\u7f69\u7684\u70ed\u7597\u793a\u610f\u56fe<\/p>\n

(c) \u76f8\u53d8\u6750\u6599\u57fa\u70ed\u7597\u53e3\u7f69\u7684\u70ed\u7597\u66f2\u7ebf\u56fe<\/p>\n

(d-e)\u76f8\u53d8\u6750\u6599\u57fa\u70ed\u7597\u53e3\u7f69\u7684\u7a7a\u6c14\u51c0\u5316\u6027\u80fd<\/p>\n

(f) \u76f8\u53d8\u6750\u6599\u57fa\u70ed\u7597\u53e3\u7f69\u7684\u70ed\u7597\u7ea2\u5916\u6210\u50cf\u56fe<\/p>\n

\u5176\u4e8c\uff0c\u5229\u7528\u6eb6\u5242\u70ed\u6cd5\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7684Metal organic frameworks (MOFs)\u57fa\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\uff0c\u5b9e\u73b0\u84c4\/\u4f20\u70ed\u529f\u80fd\u7684\u540c\u65f6\u8fd8\u5177\u6709\u5149\u81f4\u53d1\u5149\u529f\u80fd\uff0c\u5176\u4e2dCarbon quantum dot (CQD)\u4f5c\u4e3a\u5149\u81f4\u53d1\u5149\u6d3b\u6027\u5ba2\u4f53\uff0c\u786c\u8102\u9178\u4f5c\u4e3a\u70ed\u80fd\u5b58\u50a8\u5ba2\u4f53\uff0cCr-MIL-101-NH2<\/sub>\u4f5c\u4e3a\u517c\u5bb9\u6027\u826f\u597d\u7684\u591a\u5b54\u8f7d\u4f53\u4e3b\u4f53\u3002MOF\u548cCQD\u53cc\u91cd\u4f18\u52bf\u7684\u534f\u540c\u6574\u5408\u65e2\u4fdd\u8bc1\u4e86\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u4f18\u5f02\u70ed\u7279\u6027(\u9ad8\u80fd\u91cf\u5b58\u50a8\u5bc6\u5ea6\uff0c\u70ed\u7a33\u5b9a\u6027\u548c\u4f18\u5f02\u7684\u5b9a\u578b\u80fd\u529b)\uff0c\u53c8\u8fdb\u4e00\u6b65\u6fc0\u53d1\u51fa\u5177\u6709\u4f18\u5f02\u989c\u8272\u7a33\u5b9a\u6027\u7684\u9ad8\u5f3a\u5ea6\u7ea2\u7eff\u84dd\u8367\u5149\u3002\u8fd9\u79cd\u4e0d\u540c\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\u7684\u534f\u540c\u6574\u5408\u7b56\u7565\u4e3a\u5f00\u53d1\u5148\u8fdb\u7684\u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u4e2a\u521b\u65b0\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5<\/b><\/strong>\u201c<\/b><\/strong>Smart Integration of Carbon Quantum Dots in Metal-Organic Frameworks for Fluorescence-functionalized Phase Change Materials<\/b><\/strong>\u201d<\/b><\/strong>\u4e3a\u9898\u53d1\u8868\u5728<\/b><\/strong>Energy Storage Materials<\/b><\/strong>\u00a0(CiteScore\uff1a15.09)\uff0c\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9648\u6653\u3002<\/b><\/strong><\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe\u56db\uff1a\u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u5236\u5907\u793a\u610f\u56fe\u53caCQDs\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u5236\u5907\u793a\u610f\u56fe<\/p>\n

(b) CQDs\u7684\u8367\u5149\u56fe\u50cf<\/p>\n

(c-d) CQDs\u7684TEM\u53ca\u7c92\u5f84\u5206\u5e03\u56fe<\/p>\n

(e) CQDs\u7684UV-Vis\u548cPL\u56fe\u8c31<\/p>\n

\u56fe\u4e94\uff1a\u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u70ed\u6027\u80fd\u548c\u5149\u81f4\u53d1\u5149\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a-b) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684DSC<\/p>\n

(c) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u76f8\u53d8\u7113<\/p>\n

(d-e) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n

(f) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684\u8367\u5149\u5bff\u547d<\/p>\n

(g-i) \u591a\u529f\u80fd\u590d\u5408\u76f8\u53d8\u6750\u6599\u7684PL\u5149\u8c31<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u672c\u56e2\u961f\u4e00\u76f4\u81f4\u529b\u4e8e\u7814\u53d1\u524d\u6cbf\u6027\u7684\u65b0\u578b\u591a\u529f\u80fd\u76f8\u53d8\u590d\u5408\u6750\u6599\u4ee5\u6ee1\u8db3\u7279\u5b9a\u7684\u573a\u5408\u9700\u6c42\u3002\u8fd1\u671f\uff0c\u5229\u7528\u7b80\u4fbf\u7684\u6a21\u677f\u5408\u6210\u7b56\u7565\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7684\u78b3\u7eb3\u7c73\u7ba1\u675f\u7ec4\u88c5\u6210\u7684\u67d4\u6027\u591a\u7ea7\u5b54\u6d77\u7ef5\u57fa\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\uff0c\u5b9e\u73b0\u4e86\u5bf9\u8fc7\u654f\u6027\u9f3b\u708e\u7684\u9ad8\u6548\u70ed\u7597\u3002\u5229\u7528\u6eb6\u5242\u70ed\u6cd5\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7684MOFs\u57fa\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\uff0c\u5b9e\u73b0\u84c4\/\u4f20\u70ed\u529f\u80fd\u7684\u540c\u65f6\u8fd8\u5177\u6709\u5149\u81f4\u53d1\u5149\u529f\u80fd\u3002\u8fd9\u79cd\u591a\u529f\u80fd\u534f\u540c\u6574\u5408\u7b56\u7565\u4e3a\u5f00\u53d1\u5148\u8fdb\u7684\u591a\u529f\u80fd\u5b9a\u578b\u590d\u5408\u76f8\u53d8\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u4e2a\u521b\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>\u00a0<\/i><\/em><\/p>\n

    \n
  1. <\/i>Xiao Chen, Hongyi Gao, Guangtong Hai, Dandan Jia, Liwen Xing, Siyuan Chen, Piao Cheng, Mengyi Han, Wenjun Dong, Ge Wang, Carbon Nanotube Bundles Assembled Flexible Hierarchical Framework Based Phase Change Material Composites for Thermal Energy Harvesting and Thermotherapy, Energy Storage Materials, DOI: 10.1016\/j.ensm.2019.12.029<\/i><\/em><\/li>\n
  2. <\/i>Xiao Chen, Hongyi Gao, Mu Yang, Liwen Xing, Wenjun Dong, Ang Li, Haiyan Zheng, Ge Wang,\u00a0<\/i><\/em>Smart Integration of Carbon Quantum Dots in Metal-Organic Frameworks for Fluorescence-functionalized Phase Change Materials.<\/i><\/em><\/i>Energy Storage Materials 18 (2019) 349\u2013355.<\/i><\/em><\/li>\n<\/ol>\n

    \u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

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    \u3010\u56e2\u961f\u8fd1\u671f\u7814\u7a76\u6210\u679c\u3011<\/b><\/strong><\/p>\n

      \n
    1. <\/i>Xiao Chen, Hongyi Gao, Guangtong Hai, Dandan Jia, Liwen Xing, Siyuan Chen, Piao Cheng, Mengyi Han, Wenjun Dong, Ge Wang. Carbon Nanotube Bundles Assembled Flexible Hierarchical Framework Based Phase Change Material Composites for Thermal Energy Harvesting and Thermotherapy, Energy Storage Materials, DOI: 10.1016\/j.ensm.2019.12.029.<\/i><\/em><\/li>\n
    2. <\/i>Xiao Chen, Hongyi Gao, Mu Yang, Liwen Xing, Wenjun Dong, Ang Li, Haiyan Zheng, Ge Wang.\u00a0<\/i><\/em>Smart Integration of Carbon Quantum Dots in Metal-Organic Frameworks for Fluorescence-functionalized Phase Change Materials.<\/i><\/em><\/i>Energy <\/i><\/em>Storage Materials 18 (2019) 349\u2013355.<\/i><\/em><\/li>\n
    3. <\/i>Xiao Chen, Hongyi Gao, Liwen Xing, Wenjun Dong, Ang Li, Piao Cheng, Panpan Liu, Ge Wang. Nanoconfinement effects of N-doped hierarchical carbon on thermal behaviors of organic phase change materials. Energy Storage Materials 18 (2019) 280\u2013288.<\/i><\/em><\/li>\n
    4. <\/i>Xiao Chen, Hongyi Gao, Mu Yang, Wenjun Dong, Xiubing Huang, Ang Li, Cheng Dong, Ge Wang. Highly graphitized 3D network carbon for shape-stabilized composite PCMs with superior thermal energy harvesting. Nano Energy 49 (2018) 86\u201394.<\/i><\/em><\/li>\n
    5. <\/i>Hongyi Gao, Jingjing Wang, Xiao Chen, Ge Wang, Xiubing Huang, Ang Li, Wenjun Dong. Nanoconfinement effects on thermal properties of nanoporous shapestabilized composite PCMs: A review. Nano Energy 53 (2018) 769\u2013797.<\/i><\/em><\/li>\n<\/ol>\n

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