{"id":194071,"date":"2020-01-11T06:12:06","date_gmt":"2020-01-10T22:12:06","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=194071"},"modified":"2020-01-10T20:12:18","modified_gmt":"2020-01-10T12:12:18","slug":"%e8%8a%9d%e5%8a%a0%e5%93%a5%e5%a4%a7%e5%ad%a6%e6%9e%97%e6%96%87%e6%96%8c%e5%9b%a2%e9%98%9fjacs%ef%bc%9amofs%e6%98%be%e8%91%97%e5%a2%9e%e5%bc%ba%e4%ba%86%e9%93%9c%e5%85%89%e6%95%8f%e5%89%82%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=194071","title":{"rendered":"\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u56e2\u961fJACS\uff1aMOFs\u663e\u8457\u589e\u5f3a\u4e86\u94dc\u5149\u654f\u5242\u7684\u5149\u50ac\u5316\u6790\u6c22\u548cCO2\u8fd8\u539f\u7684\u6027\u80fd"},"content":{"rendered":"

<\/b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u901a\u8fc7\u5f62\u6210\u957f\u5bff\u547d\u7684\u7535\u8377\u5206\u79bb\u6fc0\u53d1\u6001\uff0c\u5e38\u5e38\u88ab\u7528\u4e8e\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u7535\u529b\u6216\u5316\u5b66\u71c3\u6599\u7684\u6709\u6548\u5149\u6355\u83b7\u7ec4\u5206,\u00a0\u7279\u522b\u662fRu-\u548cIr-\u57fa\u591a\u5421\u5576\u7c7b\u914d\u5408\u7269\uff0c\u662f\u516c\u8ba4\u7684\u4f18\u826f\u5149\u654f\u5242\uff08PSs\uff09\u3002\u4f46\u7531\u4e8e\u8fd9\u4e24\u79cd\u5143\u7d20\u5728\u5730\u58f3\u4e2d\u542b\u91cf\u6781\u4f4e\uff0c\u4e14\u5b58\u5728\u6210\u672c\u9ad8\u3001\u6bd2\u6027\u9ad8\u7b49\u7f3a\u9677\uff0c\u5b9e\u9645\u5e94\u7528\u53d7\u5230\u6781\u5927\u9650\u5236\u3002\u8fc7\u53bb\u7684\u5341\u5e74\u4e2d\uff0c\u4ee5\u9ad8\u5730\u58f3\u4e30\u5ea6\u7684\u5143\u7d20\uff08\u5982CuI<\/sup>\u914d\u5408\u7269\uff09\u4e3a\u57fa\u7840\uff0c\u66f4\u591a\u53ef\u4f9b\u9009\u62e9\u7684PSs\u88ab\u79d1\u5b66\u5de5\u4f5c\u8005\u5f00\u53d1\u51fa\u6765\uff0c\u5e76\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u3001\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08DSSC\uff09\u548c\u6709\u673a\u5149\u50ac\u5316\u4e2d\u663e\u793a\u51fa\u5149\u654f\u5316\u6f5c\u529b\u3002\u7136\u800c\uff0c\u7531\u4e8e\u94dc\u57fa\u5149\u654f\u5242\uff08Cu-PSs\uff09\u5b58\u5728\u76f8\u5bf9\u4e0d\u7a33\u5b9a\u7684CuI<\/sup>-\u914d\u4f53\u952e\u5408\u4f5c\u7528\u548c\u503e\u5411\u4e8e\u6eb6\u5242\u8f85\u52a9\u6dec\u706b\u7684\u6fc0\u53d1\u6001\uff0c\u5176\u6027\u80fd\u5f31\u4e8eRu\u57fa\u548cIr\u57faPSs\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u63d0\u9ad8Cu-PSs\u5149\u654f\u6027\u80fd\u7684\u65b0\u7b56\u7565\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u578b\u7684\u5177\u6709\u6e05\u6670\u7ed3\u6784\u7684\u591a\u5b54\u5206\u5b50\u6750\u6599\uff0c\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u5177\u6709\u7a33\u5b9a\u5747\u76f8\u4f53\u7cfb\u4e2d\u6781\u6613\u5931\u6d3b\u7684\u91d1\u5c5e\u4f4d\u70b9\u7684\u4f5c\u7528\uff0c\u540c\u65f6\uff0cMOFs\u7684\u5408\u6210\u591a\u6837\u6027\u8fd8\u5141\u8bb8\u591a\u4e2a\u529f\u80fd\u5316\u57fa\u56e2\u7684\u5206\u7ea7\u6574\u5408\uff0c\u4ece\u800c\u5b9e\u73b0\u534f\u540c\u53cd\u5e94\u6216\u4fc3\u8fdb\u80fd\u91cf\u548c\u7535\u5b50\u4f20\u9012\u3002\u6b63\u51fa\u4e8e\u6b64\uff0c\u8fd1\u5e74\u6765\uff0c\u672c\u56e2\u961f\u5bf9\u7531Ru\u548cIr PSs\u5236\u5907\u7684MOFs\u5728\u592a\u9633\u80fd\u8f6c\u6362\u65b9\u9762\u7684\u5e94\u7528\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\uff08J. Am. Chem. Soc. <\/i><\/em>2011<\/b><\/strong>, 133<\/i><\/em>, 13445\uff1bJ. Am. Chem. Soc. <\/i><\/em>2018<\/b><\/strong>, 140<\/i><\/em>, 12369\uff1bJ. Am. Chem. Soc. <\/i><\/em>2019<\/b><\/strong>, 141<\/i><\/em>, 12219\uff1betc\uff09\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u6559\u6388<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u7684\u5e26\u9886\u4e0b\uff0c\u62a5\u9053\u4e86\u4e24\u79cd\u5177\u6709\u5149\u50ac\u5316\u4ea7\u6c22\uff08HER\uff09\u548cCO2<\/sub>\u8fd8\u539f \uff08CO2<\/sub>RR\uff09\u4f5c\u7528\u7684\u591a\u529f\u80fd\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599mPT-Cu\/Co<\/b><\/strong>\u548cmPT-Cu\/Re<\/b><\/strong>\uff0c\u5b83\u4eec\u5206\u522b\u7531\u94dc\u5149\u654f\u5242\uff08Cu-PSs\uff09\u548c\u5206\u5b50Co\u6216Re\u50ac\u5316\u5242\u7ec4\u6210\u3002\u5728\u8fd9\u4e9bMOFs\u4e2d\uff0cCu-PSs\u548cCo\/Re\u50ac\u5316\u5242\u7684\u5206\u7ea7\u7ed3\u6784\u6709\u52a9\u4e8e\u591a\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u5b9e\u73b0\u5728\u53ef\u89c1\u5149\u4e0b\u9a71\u52a8\u7684HER\u548cCO2<\/sub>RR\uff0cmPT-Cu\/Co<\/b><\/strong>\u7684HER\u8f6c\u6362\u6570\uff08TON\uff09\u4e3a18700\uff0c\u800cmPT-Cu\/Re<\/b><\/strong>\u7684CO2<\/sub>RR\u8f6c\u6362\u6570\u4e3a1328\uff0c\u76f8\u6bd4\u5747\u76f8\u5bf9\u7167\u7ec4\u63d0\u9ad8\u4e8695\u500d\u3002\u5149\u7269\u7406\u548c\u7535\u5316\u5b66\u7814\u7a76\u63ed\u793a\u4e86HER\u548cCO2<\/sub>RR\u50ac\u5316\u5faa\u73af\u4e2d\u7684\u8fd8\u539f\u6dec\u706d\u9014\u5f84\uff0c\u4e14MOF\u4f53\u7cfb\u6027\u80fd\u7684\u63d0\u9ad8\uff0c\u5f52\u56e0\u4e8eCu-PSs\u548c\u6d3b\u6027\u50ac\u5316\u5242\u7684\u5728MOF\u6846\u67b6\u4e2d\u7684\u7d27\u5bc6\u6392\u5217\u548cMOF\u7ed3\u6784\u5bf9Cu-PSs\u548c\u5206\u5b50\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u4f5c\u7528\uff0c\u5206\u522b\u63d0\u9ad8\u4e86\u7535\u5b50\u8f6c\u79fb\u6548\u7387\u548c\u50ac\u5316\u6d3b\u6027\u7269\u79cd\u5bff\u547d\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>Metal-Organic Frameworks Significantly Enhance Photocatalytic Hydrogen Evolution and CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Reduction with Earth-Abundant Copper Photosensitizers<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86J. Am. Chem. Soc.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1<\/b><\/strong>\u00a0\u8fc7\u6e21\u91d1\u5c5e\u5149\u654f\u5242\u7684\u5206\u5b50\u7ed3\u6784<\/b><\/strong>\"\"<\/p>\n

a\uff09\u5e38\u89c1\u5747\u76f8\u8fc7\u6e21\u91d1\u5c5e\u5149\u654f\u5242\u7684\u5206\u5b50\u7ed3\u6784\u3002<\/p>\n

b\uff09mPT-Cu\/Co<\/b><\/strong>\u548cmPT-Cu\/Re<\/b><\/strong>\u00a0MOFs\u7684\u9aa8\u67b6\u7ed3\u6784\u548c\u6865\u8054\u914d\u4f53\u3002Cu-PSs\u548c\u5206\u5b50Co\/Re\u50ac\u5316\u5242\u5728MOFs\u4e2d\u66f4\u8fd1\u7684\u8ddd\u79bb\u589e\u5f3a\u4e86\u591a\u7535\u5b50\u8f6c\u79fb\u548c\u5149\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u56fe2<\/b><\/strong>\u00a0mPT-Cu\/Co\u548cmPT-Cu\/Re<\/b><\/strong>\u7684\u5149\u8c31\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

a\uff09\u901a\u8fc7mPT-MOF\u7684\u5408\u6210\u540e\u4fee\u9970\u5f97\u5230mPT-Cu\/Co<\/b><\/strong>\u548cmPT-Cu\/Re<\/b><\/strong>\u3002<\/p>\n

b\uff09mPT-MOF\uff08\u9ed1\u8272\uff09\u3001mPT-Cu\/Co<\/b><\/strong>\uff08\u7ea2\u8272\uff09\u3001mPT-Cu\/Re<\/b><\/strong>\uff08\u7eff\u8272\uff09\u548c\u5728HER\u53cd\u5e94\u540e\u7684mPT-Cu\/Co<\/b><\/strong>\uff08\u84dd\u8272\uff09\u7684PXRD\u884d\u5c04\u56fe\u8c31\u548c\u5728\u00a0CO2<\/sub>RR\u53cd\u5e94\u540e\u7684mPT-Cu\/Re<\/b><\/strong>\uff08\u7d2b\u8272\uff09\u7684PXRD\u56fe\u8c31\u3002<\/p>\n

c\uff09mPT-Cu\/Co<\/b><\/strong>\uff08\u7ea2\u8272\uff09\u548cmPT-Cu\/Re<\/b><\/strong>\uff08\u84dd\u8272\uff09\u7684N2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

d\uff0ce\uff09R\u7a7a\u95f4\u4e2d\u5728Cu K\u8fb9\uff08d\uff09\u548cCo K\u8fb9\uff08e\uff09\u5904mPT-Cu\/Co<\/b><\/strong>\u7684EXAFS\u5149\u8c31\uff08\u7070\u8272\u5b9e\u7ebf\uff09\u548c\u62df\u5408\uff08\u9ed1\u8272\u5706\u5708\uff09\u3002<\/p>\n

f\uff09mPT-Cu\/M<\/b><\/strong>\uff08\u7ea2\u8272\uff09\u3001Me2<\/sub>LCu<\/sub>\uff08\u84dd\u8272\uff09\u3001CuCl2<\/sub>\uff08\u9ed1\u8272\uff09\u548cCu(CH3<\/sub>CN)4<\/sub>PF6<\/sub>\uff08\u7eff\u8272\uff09\u7684\u5f52\u4e00\u5316XANES\u8868\u5f81\u3002<\/p>\n

\u56fe3<\/b><\/strong>\u00a0mPT-Cu\/Co\u548cmPT-Cu\/Re<\/b><\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

a\uff09\u968f\u65f6\u95f4\u53d8\u5316\u7684mPT-Cu\/Co<\/b><\/strong>\u548c\u5747\u76f8\u5bf9\u7167\u7ec4\u7684HER \u53cd\u5e94\u8f6c\u5316\u6570TON\u3002<\/p>\n

b\uff09\u968f\u65f6\u95f4\u53d8\u5316\u7684mPT-Cu\/Re<\/b><\/strong>\u548c\u5747\u76f8\u5bf9\u7167\u7ec4\u7684CO2<\/sub>RR \u53cd\u5e94\u8f6c\u5316\u6570TON\u3002<\/p>\n

\u56fe<\/b><\/strong>4 Cu-PS\u7684\u8fd8\u539f\u6216\u6c27\u5316\u6dec\u706d\u9014\u5f84<\/b><\/strong>\"\"<\/p>\n

a\uff09Me2<\/sub>LCu<\/sub>\uff08\u9ed1\u8272\uff09\u548cmPT-Cu<\/b><\/strong>\uff08\u7ea2\u8272\uff09\u5728DMA\u4e2d\u7684Cu\u6d53\u5ea6\u4e3a20\u03bcM\u7684\u5f52\u4e00\u5316\u5438\u6536\u548c\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

b\uff09Cu-PS\u7684\u8fd8\u539f\u6216\u6c27\u5316\u6dec\u706d\u9014\u5f84\u3002<\/p>\n

c\uff0cd\uff09\u57282 mL CH3<\/sub>CN\u4e2d\u6dfb\u52a0\u4e0d\u540c\u91cf\u7684BIH\uff08c\uff09\u548cCo(phen)Cl2<\/sub>\uff08d\uff09\u540e\uff0cMe2<\/sub>LCu<\/sub>\uff0810\u03bcM\uff09\u7684\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

e\uff09\u5728\u5149\u50ac\u5316HER\u6761\u4ef6\u4e0b\uff08\u542b\u6709150\u03bcL\u00a0AcOH\u768410 mL 0.1 M TBAH\/CH3<\/sub>CN\u6eb6\u6db2\uff0cTBAH =\u516d\u6c1f\u78f7\u9178\u56db\u4e01\u57fa\u94f5\u516d\u6c1f\u78f7\u9178\u76d0\uff09\u5728\u7535\u6781\u8868\u9762\u6d82\u8986\u7684mPT-Co<\/b><\/strong>\uff08\u9ed1\u8272\uff09\u548cCo(phen)Cl2<\/sub>\uff08\u7ea2\u8272\uff09\u7684CV\u3002<\/p>\n

f\uff09\u7535\u6781\u8868\u9762\u6d82\u8986\u7684mPT-Cu<\/b><\/strong>\uff08\u9ed1\u8272\uff09\u548cMe2<\/sub>LCu<\/sub>\uff08\u7ea2\u8272\uff09\u572810 mL 0.1 M TBAH\u7684CH3<\/sub>CN\u6eb6\u6db2\u4e2d\u7684CV\u3002<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0mPT-Cu\/<\/b><\/strong>Co<\/b><\/strong>\u50ac\u5316HER\u7684\u50ac\u5316\u5faa\u73af<\/b><\/strong>\"\"<\/p>\n

\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u56e2\u961f\u5236\u5907\u4e86\u7531Cu-PS\u548c\u5206\u5b50Co\/Re\u50ac\u5316\u5242\u7ec4\u6210\u7684\u591a\u529f\u80fdMOFs\uff0c\u5206\u522b\u7528\u4e8e\u5149\u50ac\u5316HER\u548cCO2<\/sub>RR\u3002Cu-PSs\u548cCo\/Re\u50ac\u5316\u5242\u5728MOFs\u4e2d\u7684\u96c6\u6210\u663e\u8457\u589e\u5f3a\u4e86\u5b83\u4eec\u7684\u5149\u50ac\u5316\u6d3b\u6027\uff0cmPT-Cu\/Co<\/b><\/strong>\u7684HER TON\u4e3a18700\uff0cmPT-Cu\/Re<\/b><\/strong>\u7684CO2<\/sub>RR TON\u4e3a1328\uff0c\u8fd9\u4e00\u6570\u503c\u76f8\u6bd4\u4e8e\u5747\u76f8\u4f53\u7cfb\u589e\u5f3a\u4e86\u8fd1\u4e24\u4e2a\u6570\u91cf\u7ea7\u3002\u8fd9\u4e00\u7ed3\u679c\u53ef\u4ee5\u5f52\u56e0\u4e8e\u4e24\u70b9\uff1a\u4e00\u662fMOFs\u6846\u67b6\u663e\u8457\u5730\u589e\u52a0\u4e86Cu-PSs\u548c\u5206\u5b50\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\uff0c\u4e8c\u662fMOFs\u4e2dCu-PSs\u548cCo\/Re\u50ac\u5316\u5242\u4e4b\u95f4\u8fd1\u8ddd\u79bb\u6392\u5217\u6781\u5927\u5730\u4fc3\u8fdb\u4e86\u591a\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u5149\u7269\u7406\u548c\u7535\u5316\u5b66\u7814\u7a76\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u8fd8\u539f\u6dec\u706d\u9014\u5f84\uff0c\u5149\u6fc0\u53d1\u6001[Cu-PS]*\u7684BIH\u6dec\u706d\u9996\u5148\u4ea7\u751f\u4e86\u8fd8\u539f\u6001[Cu-PS]–<\/sup>\uff0c\u4e4b\u540e[Cu-PS]–<\/sup>\u5c06\u7535\u5b50\u8f6c\u79fb\u5230\u50ac\u5316\u4f4d\u70b9\u4ee5\u9a71\u52a8HER\u548cCO2<\/sub>RR\u3002\u8fd9\u4e00\u5173\u4e8e\u529f\u80fd\u5316MOFs\u7684\u7814\u7a76\u5de5\u4f5c\u4e3a\u5c06\u9ad8\u5730\u58f3\u4e30\u5ea6\u7684Cu-PSs\u548c\u5206\u5b50\u50ac\u5316\u5242\u5e94\u7528\u4e8e\u592a\u9633\u80fd\u8f6c\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6781\u6709\u6f5c\u529b\u7684\u5e73\u53f0\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Metal-Organic Frameworks Significantly Enhance Photocatalytic Hydrogen Evolution and CO<\/u>2<\/sub><\/u>\u00a0Reduction with Earth-Abundant Copper Photosensitizers<\/u><\/a>\uff08J. Am. Chem. Soc.\uff0c\u00a02020\uff0cDOI:10.1021\/jacs.9b12229\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd<\/b>\u3011\"\"<\/p>\n

\u6797\u6587\u658c<\/strong>\uff0c\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u5316\u5b66\u7cfb\u548c\u8f90\u5c04\u4e0e\u7ec6\u80de\u80bf\u7624\u7cfb\u7684James Franck\u8bb2\u5ea7\u6559\u6388\u3002\u6797\u6587\u658c\u6559\u6388\u5728\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u53ca\u7eb3\u7c73\u533b\u5b66\u65b9\u9762\u6709\u91cd\u8981\u8d21\u732e\uff0c\u5728\u5305\u62ecNat. Biomed. Eng.<\/i><\/em>\uff0c<\/i><\/em>Nat. Chem.<\/i><\/em>\uff0c<\/i><\/em>Nat. Catal.<\/i><\/em>\uff0c<\/i><\/em>J. Am. Chem. Soc.<\/i><\/em>\uff0c<\/i><\/em>Angew. Chem. Int. Ed. <\/i><\/em>\u7b49\u4e16\u754c\u9876\u7ea7\u6742\u5fd7\u4e0a\u53d1\u8868\u6587\u7ae0350\u4f59\u7bc7\uff0c\u6587\u7ae0\u88ab\u5e7f\u6cdb\u5f15\u7528\uff08h-index >105\uff09\u30021999-2009 \u5e74\u5ea6\u6587\u7ae0\u5f15\u7528\u4e16\u754c\u524d\u5341\u4f4d\u5316\u5b66\u5bb6\u3002\u6c64\u68ee\u8def\u900f\u96c6\u56e22000-2010\u5e74\u5168\u7403\u9876\u5c16\u4e00\u767e\u5316\u5b66\u5bb6\u540d\u4eba\u5802\u699c\u5355\u7b2c54\u540d\u3002\u6797\u6587\u658c\u56e2\u961f\u7814\u53d1\u7684\u4e09\u4e2a\u6297\u764c\u836f\u7269\u5df2\u5728\u8fdb\u884c\u4e34\u5e8a\u8bd5\u9a8c\u5e76\u53d6\u5f97\u826f\u597d\u7684\u4e34\u5e8a\u7ed3\u679c\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u7f51\u7ad9\u00a0\u00a0http:\/\/linlab.uchicago.edu\/<\/u><\/a><\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u901a\u8fc7\u5f62\u6210\u957f\u5bff\u547d\u7684\u7535\u8377\u5206\u79bb\u6fc0\u53d1\u6001\uff0c\u5e38\u5e38\u88ab\u7528\u4e8e\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u7535\u529b\u6216\u5316\u5b66\u71c3\u6599\u7684\u6709\u6548\u5149\u6355\u83b7\u7ec4\u5206,\u00a0\u7279\u522b\u662fRu-\u548cIr-\u57fa\u591a\u5421\u5576\u7c7b\u914d\u5408\u7269\uff0c\u662f\u516c\u8ba4\u7684…<\/p>\n","protected":false},"author":2109,"featured_media":194076,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3852,3002,3064],"class_list":["post-194071","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-mof","tag-3002","tag-her"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194071"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=194071"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194071\/revisions"}],"predecessor-version":[{"id":194238,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194071\/revisions\/194238"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/194076"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=194071"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=194071"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=194071"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}