{"id":194341,"date":"2020-01-12T06:31:28","date_gmt":"2020-01-11T22:31:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=194341"},"modified":"2020-01-11T22:31:41","modified_gmt":"2020-01-11T14:31:41","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e7%8e%8b%e5%ad%a6%e6%96%8c%e5%9b%a2%e9%98%9facs-nano%ef%bc%9a%e7%ba%a4%e7%bb%b4%e7%b4%a0%e5%9f%ba%e4%b8%89%e7%bb%b4%e5%af%bc%e7%94%b5%e7%a2%b3%e7%bd%91%e7%bb%9c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=194341","title":{"rendered":"\u5357\u4eac\u5927\u5b66\u738b\u5b66\u658c\u56e2\u961fACS Nano\uff1a\u7ea4\u7ef4\u7d20\u57fa\u4e09\u7ef4\u5bfc\u7535\u78b3\u7f51\u7edc\u7528\u4e8e\u9ad8\u6027\u80fd\u7535\u5316\u5b66\u50a8\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5f53\u524d\u5546\u7528\u9502\u79bb\u5b50\u7535\u6c60 \u7684\u8d1f\u6781\u6750\u6599\u4e00\u822c\u4e3a\u77f3\u58a8\uff0c\u4f46\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\u8f83\u4f4e\uff08372 mAh\/g\uff09\uff0c\u96be\u4ee5\u6ee1\u8db3\u751f\u4ea7\u751f\u6d3b\u5bf9\u9ad8\u6bd4\u80fd\u3001\u5927\u529f\u7387\u7535\u6c60\u7684\u9700\u6c42\u3002\u4f7f\u7528\u91d1\u5c5e\u6c27\u5316\u7269\u66ff\u4ee3\u77f3\u58a8\uff0c\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u65b0\u578b\u8d1f\u6781\u6750\u6599\uff0c\u80fd\u591f\u63d0\u4f9b\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff08>1000 mAh\/g\uff09\uff0c\u4f46\u5728\u91d1\u5c5e\u6c27\u5316\u7269\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f1a\u51fa\u73b0\u4f53\u79ef\u7684\u53cd\u590d\u6536\u7f29\u81a8\u80c0\uff0c\u4f7f\u7535\u6c60\u7684\u5faa\u73af\u80fd\u529b\u5927\u5927\u964d\u4f4e\u3002\u5df2\u6709\u4e24\u79cd\u601d\u8def\u6765\u6539\u5584\u8fd9\u4e00\u95ee\u9898\uff1a\u4e00\u662f\u8bbe\u8ba1\u7eb3\u7c73\u7ea7\u91d1\u5c5e\u6c27\u5316\u7269\/\u4e09\u7ef4\u78b3\u7535\u6781\uff0c\u4e8c\u662f\u8bbe\u8ba1\u4e09\u660e\u6cbb\u5939\u5c42\u7ed3\u6784\u7535\u6781\uff0c\u4ee5\u6539\u5584\u7535\u6c60\u500d\u7387\u6027\u80fd\u3001\u7f13\u51b2\u5145\u653e\u7535\u4f53\u79ef\u53d8\u5316\u3002\u4e0d\u8fc7\uff0c\u5c06\u4e09\u7ef4\u5bfc\u7535\u78b3\u7f51\u7edc\u4e0e\u4e09\u660e\u6cbb\u7ed3\u6784\u7535\u6781\u8fd9\u4e24\u79cd\u7b56\u7565\u76f8\u7ed3\u5408\uff0c\u76ee\u524d\u4ecd\u9762\u4e34\u7740\u6311\u6218\u3002\u00a0<\/strong><\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5927\u5b66\u738b\u5b66\u658c\u6559\u6388\u56e2\u961f<\/strong>\u7cfb\u7edf\u7814\u7a76\u4e86\u7ea4\u7ef4\u7d20\u7684\u6c27-\u6c28\u8054\u5408\u70ed\u89e3\u53cd\u5e94\u8fc7\u7a0b\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u5236\u5907\u4e09\u7ef4\u77f3\u58a8\u70ef\u72b6\u78b3\u7eb8\uff08CP\uff09\u7684\u65b0\u65b9\u6cd5\uff0c\u5373\u9170\u80fa\u5316\u8bf1\u5bfc\u7684\u7ea4\u7ef4\u7d20\u7a7a\u95f4\u5206\u79bb\u7126\u5316\u6cd5\u3002\u8be5\u5de5\u4f5c\u8fdb\u4e00\u6b65\u4ee5CP\u4e3a\u8f7d\u4f53\uff0c\u901a\u8fc7\u81ea\u7ec4\u88c5\u7684\u65b9\u6cd5\u5236\u5907\u4e86\u4e09\u660e\u6cbb\u7ed3\u6784\u7684\u81ea\u652f\u6491\u7535\u6781\uff08CP@Fe3<\/sub>O4<\/sub>@RGO\uff09\uff0c\u5c06\u6b64\u7535\u6781\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u53ef\u4ee5\u7f13\u89e3\u5145\u653e\u7535\u4f53\u79ef\u6548\u5e94\uff0c\u5c55\u793a\u4e86\u6781\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u53ca\u500d\u7387\u6027\u80fd\u3002CP\u6750\u6599\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u9ad8\u7535\u5bfc\u7387\u3001\u67d4\u97e7\u6027\u7b49\u7279\u70b9\uff0c\u53ef\u88ab\u89c6\u4e3a\u4e00\u79cd\u901a\u7528\u7684\u78b3\u57fa\u4e09\u7ef4\u5bfc\u7535\u7f51\u7edc\u5757\u4f53\u6750\u6599\uff0c\u6709\u671b\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u7535\u6781\u7b49\u9886\u57df\u3002\u8be5\u6210\u679c\u8fd1\u65e5\u4ee5\u201cBiomass-Derived Carbon Paper to Sandwich Magnetite Anode for Long-Life Li-Ion Battery<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u7eb3\u7c73\u6750\u6599\u9886\u57df\u56fd\u9645\u6743\u5a01\u671f\u520aACS Nano<\/strong>\u4e0a\uff0c\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u4eac\u5927\u5b66\u535a\u58eb\u751f\u9ad8\u5929<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. CP<\/strong>\u53ca<\/strong>CP@Fe3<\/sub>O4<\/sub>@RGO<\/strong>\u7684\u5408\u6210\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. CP<\/strong>\u53ca<\/strong>CP@Fe3<\/sub>O4<\/sub>@RGO<\/strong>\u7684\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

(a-d) CP\u7684SEM\u3001TEM\u56fe\u3002<\/p>\n

(e) XRD \u56fe\u3002<\/p>\n

(f, g) CP@Fe3<\/sub>O4<\/sub>\u7684SEM\u56fe\u53ca\u5176\u8868\u9762Fe3<\/sub>O4<\/sub>\u9897\u7c92\u7684HRTEM \u56fe\u3002<\/p>\n

(h, i) CP@Fe3<\/sub>O4<\/sub>@RGO\u7684SEM\u56fe\u53ca\u5176\u8868\u9762Fe3<\/sub>O4<\/sub>\u9897\u7c92\u7684HRTEM \u56fe\u3002<\/p>\n

(j-m) CP@Fe3<\/sub>O4<\/sub>@RGO\u7684TEM\u56fe\u53ca\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u7ea4\u7ef4\u7d20\u7ecf\u6c27<\/strong>–<\/strong>\u6c28\u8054\u5408\u70ed\u89e3\u53cd\u5e94\u5236\u5907<\/strong>CP<\/strong>\u8fc7\u7a0b\u7684\u751f\u957f\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

(a, b) XRD\u56fe\u53caFTIR\u56fe\u3002<\/p>\n

(c, d) XRD \u5cf0\u7684\u76f8\u5bf9\u5f3a\u5ea6\u6bd4\u3001\u8d28\u91cf\u5269\u4f59\u7387\u53caTG-XPS\u5143\u7d20\u8d28\u91cf\u635f\u5931\u56fe\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u7ea4\u7ef4\u7d20<\/strong>\u5728<\/strong>\u6c27<\/strong>–<\/strong>\u6c28\u8054\u5408\u70ed\u89e3\u53cd\u5e94<\/strong>\u5236\u5907<\/strong>CP<\/strong>\u8fc7\u7a0b\u4e2d\u7684\u5316\u5b66\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5. CP@Fe3<\/sub>O4<\/sub>@RGO<\/strong>\u7535\u6781\u53ca\u5bf9\u6bd4\u6837\u7684\u50a8\u9502\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a) CP@Fe3<\/sub>O4<\/sub>@RGO\u7535\u6781\u53ca\u5bf9\u6bd4\u6837\u5728\u7b2c100\u5708\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff080.5 A\/g\uff09\u3002<\/p>\n

(b) CP@Fe3<\/sub>O4<\/sub>@RGO\u7535\u6781\u53ca\u5bf9\u6bd4\u6837\u7684\u957f\u671f\u5faa\u73af\u66f2\u7ebf\uff080.5 A\/g\uff09\u3002<\/p>\n

(c, d) \u500d\u7387\u6d4b\u8bd5\u56fe\u3001EIS\u8c31\u56fe\u3002<\/p>\n

\u56fe<\/strong>6. SEI<\/strong>\u819c\u7a33\u5b9a\u6027\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

(a-c) CP@Fe3<\/sub>O4<\/sub>@RGO\u3001CP@Fe3<\/sub>O4<\/sub>\u53caFe3<\/sub>O4<\/sub>\u7c89\u672b\u7535\u6781SEI\u819c\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n

(d-g) CP@Fe3<\/sub>O4<\/sub>@RGO\u7535\u6781\u5728\u5faa\u73af\u524d\u540e\u7684\u8868\u9762\u5f62\u8c8c\u5bf9\u6bd4\uff08\u5faa\u73af300\u5708\uff0c\u8131\u9502\u72b6\u6001\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u9996\u5148\u5229\u7528\u7ea4\u7ef4\u7d20\u7684\u6c27-\u6c28\u8054\u5408\u70ed\u89e3\u53cd\u5e94\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u4f18\u826f\u7684\u7eb8\u72b6\u7684\u4e09\u7ef4\u77f3\u58a8\u70ef\u2014\u2014\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u77f3\u58a8\u70ef\u72b6\u78b3\u7eb8CP\u3002\u901a\u8fc7XRD\u3001FTIR\u3001XPS\u7b49\u5206\u6790\u65b9\u6cd5\u5bf9\u7ea4\u7ef4\u7d20\u6c27-\u6c28\u8054\u5408\u70ed\u89e3\u7684\u6f14\u5316\u8fc7\u7a0b\u8fdb\u884c\u4e86\u7cfb\u7edf\u6027\u7814\u7a76\uff0c\u53d1\u73b0\u7ea4\u7ef4\u7d20\u7ecf\u9884\u6c27\u5316\u540e\u66f4\u6613\u53d1\u751f\u9170\u80fa\u5316\u4e0e\u6c28\u89e3\uff0c\u4e14\u9170\u80fa\u5316\u7684\u8fc7\u7a0b\u4f1a\u7834\u574f\u5176\u7ed3\u6676\u533a\u7684\u6c22\u952e\u7f51\u7edc\uff0c\u4f7f\u7ea4\u7ef4\u7d20\u94fe\u76f8\u4e92\u5206\u79bb\u6563\u5f00\uff0c\u4ece\u800c\u4f7f\u540e\u7eed\u7684\u7126\u5316\u53cd\u5e94\u503e\u5411\u4e8e\u5728\u76f8\u4e92\u5206\u5f00\u7684\u7a7a\u95f4\u4e2d\u53d1\u751f\u3002\u8fd9\u6837\u53ef\u4ee5\u907f\u514d\u81f4\u5bc6\u7126\u5316\uff0c\u907f\u514d\u5b9e\u5fc3\u78b3\u6216\u5927\u5757\u78b3\u7b49\u526f\u4ea7\u7269\uff0c\u6700\u7ec8\u5f97\u5230\u4e86\u9ad8\u54c1\u8d28\u7684\u8d85\u8584\u77f3\u58a8\u70ef\u72b6\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\uff0c\u53ef\u89c6\u4e3a\u4e00\u79cd\u4e09\u7ef4\u77f3\u58a8\u70ef\u3002\u8fd9\u4e00\u6750\u6599\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u4f18\u826f\u8010\u6298\u5ea6\u3001\u4f18\u79c0\u673a\u68b0\u5f3a\u5ea6\u548c\u5bfc\u7535\u6027\u3002<\/p>\n

\u8be5\u5de5\u4f5c\u8fdb\u4e00\u6b65\u5728CP\u7684\u57fa\u7840\u4e0a\u6784\u5efa\u4e09\u7ef4\u7535\u6781\u3002\u9996\u5148\u5728CP\u8868\u9762\u751f\u957fFe3<\/sub>O4<\/sub>\u9897\u7c92\uff0c\u518d\u5305\u8986\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70efRGO\uff0c\u4ece\u800c\u5f97\u5230\u4e09\u660e\u6cbb\u7ed3\u6784\u7684\u81ea\u652f\u6491\u4e09\u7ef4\u7f51\u7edc\u590d\u5408\u7535\u6781CP@Fe3<\/sub>O4<\/sub>@RGO\u3002\u7535\u5316\u5b66\u6df1\u5165\u5206\u6790\u8868\u660e\uff0c\u5728\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cCP\u4e09\u7ef4\u78b3\u7f51\u7edc\u80fd\u951a\u5b9aFe3<\/sub>O4<\/sub>\u9897\u7c92\u9632\u6b62\u8131\u843d\uff0c\u4e09\u660e\u6cbb\u7535\u6781\u7ed3\u6784\u80fd\u6709\u6548\u7f13\u51b2Fe3<\/sub>O4<\/sub>\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u7a33\u5b9a\u949d\u5316\u5c42\uff0c\u63d0\u9ad8\u5e93\u4ed1\u6548\u7387\u3002\u6700\u7ec8\u4ee5CP@Fe3<\/sub>O4<\/sub>@RGO\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u5177\u6709\u8d85\u957f\u5faa\u73af\u5bff\u547d\uff08\u8d85\u8fc72000\u5faa\u73af\uff09\u3001\u9ad8\u6bd4\u5bb9\u91cf\uff081160 mAh\/g\uff09\u3002\u7531\u4e8e\u751f\u7269\u8d28\u7ea4\u7ef4\u7d20\u539f\u6599\u6765\u6e90\u5e7f\u6cdb\u3001\u4ef7\u683c\u4f4e\u5ec9\uff0c\u8fd9\u79cd\u4ee5\u7ea4\u7ef4\u7d20\u4f5c\u4e3a\u539f\u6599\u7684\u70ed\u89e3\u65b9\u6cd5\uff0c\u6709\u671b\u5927\u89c4\u6a21\u5236\u5907\u4e09\u7ef4\u7f51\u7edc\u77f3\u58a8\u70ef\u7eb8\uff0c\u5177\u6709\u826f\u597d\u53d1\u5c55\u524d\u666f\u3002\u77f3\u58a8\u70ef\u7eb8\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u901a\u7528\u7684\u591a\u5b54\u7535\u6781\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u3001\u7535\u50ac\u5316\u7b49\u9886\u57df\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>\u201c<\/strong>Biomass-Derived Carbon Paper to Sandwich Magnetite Anode for Long-Life Li-Ion Battery<\/strong><\/a>\u201d (ACS Nano, 2019, 13, 11901-11911)<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5f53\u524d\u5546\u7528\u9502\u79bb\u5b50\u7535\u6c60 \u7684\u8d1f\u6781\u6750\u6599\u4e00\u822c\u4e3a\u77f3\u58a8\uff0c\u4f46\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\u8f83\u4f4e\uff08372 mAh\/g\uff09\uff0c\u96be\u4ee5\u6ee1\u8db3\u751f\u4ea7\u751f\u6d3b\u5bf9\u9ad8\u6bd4\u80fd\u3001\u5927\u529f\u7387\u7535\u6c60\u7684\u9700\u6c42\u3002\u4f7f\u7528\u91d1\u5c5e\u6c27\u5316\u7269\u66ff\u4ee3\u77f3\u58a8…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-194341","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194341"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=194341"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194341\/revisions"}],"predecessor-version":[{"id":194348,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194341\/revisions\/194348"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=194341"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=194341"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=194341"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}