{"id":194390,"date":"2020-01-15T06:25:51","date_gmt":"2020-01-14T22:25:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=194390"},"modified":"2020-01-14T21:27:03","modified_gmt":"2020-01-14T13:27:03","slug":"%e5%8d%8e%e4%b8%9c%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e9%a9%ac%e9%aa%a7%e8%af%be%e9%a2%98%e7%bb%84angew-chem-int-ed-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e8%91%ab%e8%8a%a68%e8%84%b2%e7%9a%84%e8%b6%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=194390","title":{"rendered":"\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u9a6c\u9aa7\u8bfe\u9898\u7ec4Angew. Chem. Int. Ed.\uff1a\u57fa\u4e8e\u846b\u82a6[8]\u8132\u7684\u8d85\u5206\u5b50\u7ec4\u88c5\u624b\u6bb5\u5b9e\u73b0\u53ef\u89c1\u5149\u6fc0\u53d1\u7684\u6c34\u76f8\u5ba4\u6e29\u78f7\u5149"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u5ba4\u6e29\u78f7\u5149\uff08Room-temperature phosphorescence, RTP\uff09\uff0c\u4f5c\u4e3a\u5149\u81f4\u53d1\u5149\u4e2d\u8f83\u4e3a\u7279\u6b8a\u7684\u4e00\u7c7b\u957f\u5bff\u547d\u53d1\u5149\uff0c\u56e0\u5176\u8f83\u5927\u7684\u65af\u6258\u514b\u65af\u4f4d\u79fb\u548c\u5bf9\u73af\u5883\u56e0\u7d20\u7684\u591a\u91cd\u54cd\u5e94\u6027\u800c\u5728\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1\u3001\u4f20\u611f\u68c0\u6d4b\u548c\u9632\u4f2a\u6750\u6599\u7b49\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u91cd\u89c6\u3002\u5df2\u7ecf\u62a5\u9053\u7684\u7eaf\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u5927\u591a\u57fa\u4e8e\u6676\u4f53\u3001\u805a\u5408\u7269\u3001\u5c0f\u5206\u5b50\u7b49\u56fa\u6001\u4f53\u7cfb\uff0c\u800c\u6db2\u6001\u6216\u6eb6\u6db2\u6001\u7684\u7eaf\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u5f80\u5f80\u5f88\u96be\u5b9e\u73b0\uff0c\u4e00\u65b9\u9762\u662f\u7531\u4e8e\u5206\u5b50\u5728\u6eb6\u6db2\u4e2d\u7684\u65e0\u89c4\u5219\u8fd0\u52a8\u4f7f\u5f97\u4e09\u7ebf\u6001\u6fc0\u53d1\u6001\u7684\u80fd\u91cf\u591a\u4ee5\u975e\u8f90\u5c04\u8dc3\u8fc1\u7684\u5f62\u5f0f\u8017\u6563\uff0c\u53e6\u4e00\u65b9\u9762\uff0c\u6eb6\u6db2\u4e2d\u7684\u6c27\u6c14\u7b49\u731d\u706d\u56e0\u5b50\u4e5f\u6781\u5927\u5730\u9650\u5236\u4e86\u78f7\u5149\u7684\u53d1\u5c04\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u9a6c\u9aa7\u6559\u6388\u79d1\u7814\u56e2\u961f<\/strong>\u5229\u7528\u5e38\u89c1\u7684\u8d85\u5206\u5b50\u5927\u73af\u4e3b\u4f53\u5206\u5b50\u846b\u82a6[8]\u8132\u548c\u7b80\u5355\u7684\u67d3\u6599\u5ba2\u4f53\u5206\u5b50\uff0c\u9996\u6b21\u5b9e\u73b0\u57fa\u4e8e\u4e3b\u5ba2\u4f53\u7ec4\u88c5\u7684\u53ef\u89c1\u5149\u6fc0\u53d1\u6c34\u76f8\u7eaf\u6709\u673aRTP\u3002\u72ec\u7279\u7684\u846b\u82a6[8]\u8132\u4e0e\u5ba2\u4f53\u5206\u5b50\u5f62\u6210\u76842\uff1a2\u5806\u53e0\u7ed3\u6784\u4e00\u65b9\u9762\u9650\u5236\u4e86\u5ba2\u4f53\u5206\u5b50\u7684\u65e0\u89c4\u632f\u52a8\uff0c\u53e6\u4e00\u65b9\u9762\u88ab\u5305\u7ed3\u7ec4\u88c5\u7684\u4e24\u4e2a\u5ba2\u4f53\u5206\u5b50\u56e0\u7d27\u5bc6\u5e73\u884c\u6392\u5217\u800c\u4ea7\u751f\u5438\u6536\u7ea2\u79fb\u7684\u7535\u8377\u8f6c\u79fb\u6001\uff0c\u5b9e\u73b0\u4e86\u53ef\u89c1\u5149\u6fc0\u53d1\u4e0b\u7684RTP\u53d1\u5c04\uff0c\u5e76\u7528\u4e8e\u5236\u5907\u591a\u8272\u53d1\u5149\u6c34\u51dd\u80f6\u548c\u7ec6\u80de\u6210\u50cf\u3002\u8fd9\u4e00\u7ec4\u88c5\u8bf1\u5bfc\u53d1\u5149\u7684\u7b56\u7565\u6709\u52a9\u4e8e\u6784\u5efa\u65b0\u578b\u7684\u65e0\u91d1\u5c5e\u6c34\u76f8RTP\u4f53\u7cfb\uff0c\u4e3a\u78f7\u5149\u5728\u751f\u7269\u6210\u50cf\u3001\u68c0\u6d4b\u3001\u5149\u5b66\u4f20\u611f\u5668\u7b49\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u53ef\u80fd\u3002\u8be5\u6210\u679c\u4ee5 <strong>\u201c<\/strong><strong>Visible-Light-Excited Room-Temperature Phosphorescence in Water by Cucurbit[8]uril-Mediated Supramolecular Assembly<\/strong><strong>\u201d\u4e3a\u9898<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong>Angew. Chem. Int. Ed.<\/strong><strong>\u4e0a<\/strong>\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u8d85\u5206\u5b50\u4e3b\u5ba2\u4f53\u5206\u5b50\u7ed3\u6784\u53ca\u5305\u7ed3\u6027\u8d28\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194391\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r1.jpg\" alt=\"\" width=\"600\" height=\"1205\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r1-149x300.jpg 149w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r1-510x1024.jpg 510w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u5355\u6676\u7ed3\u6784<\/strong><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194392\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r2.jpg\" alt=\"\" width=\"600\" height=\"734\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r2.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r2-245x300.jpg 245w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong><strong>\u8d85\u5206\u5b50\u4e3b\u5ba2\u4f53\u5305\u7ed3\u8fc7\u7a0b\u7684\u5149\u81f4\u53d1\u5149\u5149\u8c31\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194393\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r3.jpg\" alt=\"\" width=\"600\" height=\"304\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r3.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r3-300x152.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u6c34\u76f8\u4e3b\u5ba2\u4f53\u7edc\u5408\u7269\u53d1\u5149\u5149\u8c31\u53ca\u78f7\u5149\u5bff\u547d\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194394\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r4.jpg\" alt=\"\" width=\"600\" height=\"592\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r4.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r4-300x296.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5. <\/strong><strong>\u591a\u8272\u53d1\u5149\u6c34\u51dd\u80f6\u7167\u7247\u53ca\u7ec6\u80de\u6210\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194395\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r5.jpg\" alt=\"\" width=\"600\" height=\"546\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r5.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/01\/r5-300x273.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u5149\u81f4\u53d1\u5149\u53ef\u8c03\u7684\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u7cfb\uff0c\u8be5\u4f53\u7cfb\u57fa\u4e8e\u8d85\u5206\u5b50\u4e3b\u5ba2\u4f532\uff1a2\u7684\u7ec4\u88c5\u7ed3\u6784\uff0c\u53ef\u7528\u4e8e\u5236\u5907\u591a\u8272\u53d1\u5149\u6c34\u51dd\u80f6\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u846b\u82a6[8]\u8132\u7684\u7a7a\u95f4\u9650\u57df\u4fc3\u8fdb\u4e86\u5ba2\u4f53\u5206\u5b50\u7684\u4e8c\u805a\u4f53\u7ec4\u88c5\uff0c\u4fc3\u8fdb\u4e86\u846b\u82a6[8]\u8132\u7a33\u5b9a\u7684\u7535\u8377\u8f6c\u79fb\u6001\uff0c\u5728\u53ef\u89c1\u5149\u6fc0\u53d1\u4e0b\u5177\u6709\u8f83\u5f3a\u7684\u9ec4\u8272RTP\u53d1\u5c04\uff0c\u53ef\u7528\u4e8e\u7ec6\u80de\u6210\u50cf\u3002\u4f5c\u8005\u8ba4\u4e3a\u8fd9\u4e00\u7ed3\u5408\u8d85\u5206\u5b50\u7ec4\u88c5\u4e0e\u5149\u5316\u5b66\uff0c\u5e76\u901a\u8fc7\u7ec4\u88c5\u8bf1\u5bfc\u53d1\u5c04\u6765\u5b9e\u73b0\u6c34\u76f8RTP\u7684\u65b9\u6cd5\u5c06\u4e3a\u6c34\u76f8\/\u6eb6\u6db2\u76f8\u4e2d\u7684\u65b0\u578bRTP\u6750\u6599\u7684\u6784\u5efa\u63d0\u4f9b\u65b0\u7684\u7b56\u7565\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"https:\/\/www.ncbi.nlm.nih.gov\/pubmed\/31799773\" target=\"_blank\" rel=\"noopener\">Visible-Light-Excited Room-Temperature Phosphorescence in Water by Cucurbit[8]uril-Mediated Supramolecular Assembly<\/a>. <em>Angew. Chem. Int. Ed., <\/em><strong>2019<\/strong>, DOI: 10.1002\/anie.201914513.<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u56e2\u961f\u4ecb\u7ecd<\/strong><\/li>\n<\/ul>\n<p>\u9a6c\u9aa7\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u6559\u6388\uff0c\u7cbe\u7ec6\u5316\u5de5\u7814\u7a76\u6240\u5e38\u52a1\u526f\u6240\u957f\u3002\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u4f18\u9752\u9879\u76ee\u83b7\u5f97\u8005\uff0c\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1aFellow (FRSC)\u3002\u5929\u6d25\u5927\u5b66\u5b66\u58eb\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u535a\u58eb\uff0c\u66fe\u5728\u7f8e\u56fd\u80af\u7279\u5dde\u7acb\u5927\u5b66\u548c\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u548c\u8bbf\u95ee\u7814\u7a76\u3002\u9a6c\u9aa7\u6559\u6388\u56e2\u961f\u4e3b\u8981\u4ece\u4e8b\u57fa\u4e8e\u529f\u80fd\u67d3\u6599\u7684\u6709\u673a\u5149\u7535\u7ec4\u88c5\u6750\u6599\uff0c\u5149\u5316\u5b66\u4e0e\u6709\u673a\u8d85\u5206\u5b50\u5408\u6210\u5316\u5b66\u7814\u7a76\u7b49\u3002\u56f4\u7ed5\u57fa\u4e8e\u7cbe\u7ec6\u6709\u673a\u529f\u80fd\u67d3\u6599\u7684\u4eb2\u6c34\u6027\u8f6f\u6750\u6599\u7684\u7cbe\u786e\u6784\u5efa\u3001\u7cbe\u51c6\u8868\u5f81\u548c\u7cbe\u7ec6\u8c03\u63a7\uff0c\u62d3\u5c55\u4f20\u7edf\u67d3\u6599\u65b0\u7684\u529f\u80fd\u6027\u5e94\u7528\u7b49\u5173\u952e\u79d1\u5b66\u95ee\u9898\uff0c\u5f00\u5c55\u4e86\u7cfb\u7edf\u7684\u5e94\u7528\u57fa\u7840\u7814\u7a76\uff1a\u4e00\u662f\u5bf9\u529f\u80fd\u67d3\u6599\u5ba2\u4f53\u8fdb\u884c\u7cbe\u786e\u8bbe\u8ba1\uff0c\u6784\u5efa\u5177\u6709\u7279\u5b9a\u7ec4\u88c5\u6a21\u5f0f\u548c\u529f\u80fd\u7684\u8d85\u5206\u5b50\u53ca\u805a\u5408\u7269\u8f6f\u6750\u6599\u4f53\u7cfb\uff0c\u5bf9\u529f\u80fd\u67d3\u6599\u5355\u5143\u7684\u8367\u5149\u53d1\u5149\u6ce2\u957f\u8fdb\u884c\u4e86\u6709\u6548\u5730\u8c03\u63a7\uff1b\u4e8c\u662f\u901a\u8fc7\u5206\u5b50\u7ec4\u88c5\u7b56\u7565\uff0c\u5bf9\u529f\u80fd\u67d3\u6599\u7684\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\u6548\u7387\u8fdb\u884c\u4e86\u6709\u6548\u7684\u8c03\u63a7\uff0c\u6784\u5efa\u4e86\u7cfb\u5217\u975e\u6676\u6001\u7eaf\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\u6750\u6599\u4f53\u7cfb\u3002\u8fd1\u5e74\u6765\u5df2\u7ecf\u5728<em>Acc. Chem. Res.<\/em><em>\u3001<\/em><em>Chem. Soc. Rev.<\/em><em>\u3001<\/em><em>JACS<\/em><em>\u3001<\/em><em>Angew<\/em>\u7b49\u4e3b\u6d41\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u6536\u5f55\u8bba\u6587\u8fd1100\u7bc7\u3002\u8bba\u6587\u88abSCI\u5f15\u75283900\u4f59\u6b21\uff0c\u7533\u8bf7\u53d1\u660e\u4e13\u522910\u4f59\u9879\uff0c\u51fa\u7248\u8bd1\u8457\u4e24\u90e8\u7b49\u3002<\/p>\n<p>\u73b0\u62c5\u4efb\u82f1\u56fd\u67d3\u8272\u5bb6\u5b66\u4f1a\uff08SDC\uff09\u989c\u6599\u548c\u6eb6\u5242\u67d3\u6599\u6280\u672f\u59d4\u5458\u4f1a\u59d4\u5458\uff0c\u4e2d\u56fd\u5316\u5b66\u4f1a\u8d85\u5206\u5b50\u5316\u5b66\u4e13\u59d4\u4f1a\u59d4\u5458\uff0c\u4e2d\u56fd\u5316\u5de5\u5b66\u4f1a\u67d3\u6599\u4e13\u59d4\u4f1a\u59d4\u5458\u548c\u7cbe\u7ec6\u5316\u5de5\u4e13\u59d4\u4f1a\u9752\u5e74\u5b66\u8005\u59d4\u5458\u4f1a\u526f\u4e3b\u4efb\u59d4\u5458\u7b49\u3002\u62c5\u4efb\u671f\u520a<em>Dyes and Pigments<\/em>\uff08IF 4.0\uff09\u6267\u884c\u4e3b\u7f16\uff0c<em>Chinese Chem. Lett.<\/em>\uff0c<em>Sci. China Chem<\/em>.\u7b49\u671f\u520a\u7684\u7f16\u59d4\u548c\u9752\u5e74\u7f16\u59d4\u7b49\u30022019\u5e74\u5f53\u9009\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1aFellow\uff08FRSC\uff09\uff0c\u83b7\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\uff0c\u4e2d\u56fd\u5316\u5de5\u5b66\u4f1a\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u5b66\u6280\u672f\u9752\u5e74\u5956\uff0c\u4e0a\u6d77\u5e02\u201c\u66d9\u5149\u5b66\u8005\u201d\uff0c2018\u5e74\u201c\u4e0a\u6d77\u5e02\u9752\u5e74\u79d1\u6280\u82f1\u624d\u201d\u7b49\u8363\u8a89\u548c\u5956\u52b1\u3002<\/p>\n<p><strong>\uff08<\/strong><strong>2<\/strong><strong>\uff09\u56e2\u961f\u8fd1\u671f\u5728\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b<\/strong><\/p>\n<p>\u901a\u8fc7\u8d85\u5206\u5b50\u7ec4\u88c5\u7b56\u7565\uff0c\u5bf9\u529f\u80fd\u67d3\u6599\u7684\u5ba4\u6e29\u78f7\u5149(RTP)\u53d1\u5c04\u6548\u7387\u8fdb\u884c\u4e86\u6709\u6548\u7684\u8c03\u63a7\uff0c\u6784\u5efa\u4e86\u7cfb\u5217\u7eaf\u6709\u673a\u975e\u6676\u6001\u5ba4\u6e29\u78f7\u5149\u6750\u6599\u4f53\u7cfb\uff0c\u62d3\u5c55\u4e86\u6709\u673a\u67d3\u6599\u65b0\u7684\u529f\u80fd\u5e94\u7528\u3002\u91c7\u7528\u591a\u79cd\u7b56\u7565\u5de7\u5999\u5730\u6784\u5efa\u4e86\u7cfb\u5217\u7eaf\u6709\u673a\u975e\u6676\u6001RTP\u6750\u6599\uff1a<\/p>\n<p>1) \u57fa\u4e8e\u4e3b\u4f53\u5927\u73af\u5305\u7ed3\u91cd\u539f\u5b50\u67d3\u6599\u7684\u521a\u6027\u5316\u8bf1\u5bfc\u4f5c\u7528\uff0c\u6784\u5efa\u4e86\u5177\u6709RTP\u53d1\u5c04\u529f\u80fd\u7684\u8d85\u5206\u5b50\u53ca\u8d85\u5206\u5b50\u805a\u5408\u7269\u4f53\u7cfb\u3002\u91c7\u7528\u846b\u82a6[8]\u8132\uff08CB[8]\uff09\u5927\u73af\u5305\u7ed3\u6eb4\u82ef\u5421\u5576\u884d\u751f\u7269\u5ba2\u4f53\uff0c\u6784\u5efa\u4e86\u6c34\u76f8\u53ef\u89c1\u5149\u6fc0\u53d1\u7684\u6709\u673a\u8d85\u5206\u5b50RTP\u53ca\u6c34\u51dd\u80f6\u4f53\u7cfb\uff0c\u5e76\u5c06\u5176\u6210\u529f\u5e94\u7528\u4e8e\u7ec6\u80de\u6210\u50cf (<em>Angew. Chem. Int. Ed.<\/em> <strong>2019<\/strong>, DOI: 10.1002\/anie.201914513)\u3002\u6709\u5173\u4e3b\u5ba2\u4f53\u7ec4\u88c5\u7b56\u7565\u6784\u5efa\u6709\u673aRTP\u4f53\u7cfb\u7684\u7cfb\u5217\u5de5\u4f5c\u4e5f\u53d7\u9080\u64b0\u5199\u4e86\u7efc\u8ff0 (<em>Chinese Chem. Lett<\/em>. <strong>2019<\/strong>, 30, 1809)\u3002<\/p>\n<p>2) \u53d1\u5c55\u4e86\u7cfb\u5217\u7eaf\u6709\u673a\u975e\u6676\u6001\u9ad8\u6548RTP\u53d1\u5c04\u7684\u5c0f\u5206\u5b50\u4f53\u7cfb\u3002\u901a\u8fc7\u5c06\u6709\u673a\u91cd\u539f\u5b50\u78f7\u5149\u67d3\u6599\u57fa\u56e2\u4fee\u9970\u5230\u03b2-\u73af\u7cca\u7cbe\u4e0a\uff0c\u975e\u5e38\u4fbf\u6377\u5730\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u9ad8\u6548\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\u7684\u65e0\u5b9a\u5f62\u6001\u6709\u673a\u5c0f\u5206\u5b50\u5316\u5408\u7269\uff0c\u8be5\u7814\u7a76\u6210\u679c\u9996\u6b21\u62a5\u9053\u4e86\u65e0\u5b9a\u5f62\u6001\u7eaf\u6709\u673a\u5c0f\u5206\u5b50\u5ba4\u6e29\u78f7\u5149\u6750\u6599\uff0c\u5236\u5907\u65b9\u6cd5\u65b0\u9896\u3001\u7b80\u4fbf\u4e14\u901a\u7528\uff0c\u53d1\u8868\u5728<em>J. Am. Chem. Soc.<\/em> (<strong>2018<\/strong>, 140, 1916)\u3002\u5e76\u8fdb\u4e00\u6b65\u5c06\u6709\u673a\u78f7\u5149\u4f53\u91c7\u7528\u73af\u7cca\u7cbe\u548c\u56db\u91cd\u6c22\u952e\u5355\u5143\u884d\u751f\u5316\u7b56\u7565\uff0c\u5206\u522b\u53d1\u5c55\u4e86\u65e0\u91cd\u539f\u5b50 (<em>Chem. Commun.<\/em> <strong>2019<\/strong>, 55, 5355)\u548c\u5bf9\u6e7f\u5ea6\u548c\u6c27\u6c14\u5747\u4e0d\u654f\u611f(<em>Ind. Eng. Chem. Res., <\/em><strong>2019<\/strong>, 58, 7778) \u7684\u6709\u673aRTP\u5c0f\u5206\u5b50\u4f53\u7cfb\uff0c\u5c55\u73b0\u51fa\u4e86\u5728\u4fe1\u606f\u548c\u6307\u7eb9\u8bc6\u522b\u65b9\u9762\u826f\u597d\u7684\u6f5c\u5728\u5e94\u7528\u3002<\/p>\n<p>3)\u5ba4\u6e29\u78f7\u5149\u5171\u805a\u7269\u4f53\u7cfb\u3002\u91c7\u7528\u78f7\u5149\u4f53\u67d3\u6599\u7684\u5355\u4f53\u5316\u5408\u7269\uff0c\u4e0e\u4e19\u70ef\u9170\u80fa\u5171\u805a\u7684\u7b56\u7565\uff0c\u57fa\u4e8e\u805a\u5408\u7269\u4f53\u7cfb\u4e2d\u7684\u6c22\u952e\u521a\u6027\u5316\u4f5c\u7528\uff0c\u7387\u5148\u6784\u5efa\u4e86\u7cfb\u5217\u9ad8\u6548RTP\u53d1\u5c04\u7684\u975e\u6676\u6001\u805a\u5408\u7269\uff0c\u5e76\u5c06\u5176\u5e94\u7528\u4e8e\u52a0\u5bc6\u4e66\u5199(<em>Adv. Opt. Mater. <\/em><strong>2016,<\/strong> 4, 1397\uff1b<em>Ind. Eng. Chem. Res., <\/em><strong>2017<\/strong>, 56, 3123; <strong>2020<\/strong>, DOI: org\/10.1021\/acs.iecr.9b06314 )\u548c\u6e7f\u5ea6\u4f20\u611f(<em>Ind. Eng. Chem. Res. <\/em><strong>2018<\/strong>, 57, 2866)\u3002\u91c7\u7528\u78f7\u5149\u4f53\u4e0e\u73af\u5185\u9170\u80fa\u5355\u4f53\u5171\u805a\u7269\u7684\u521a\u6027\u5316\u6548\u5e94\u4ea6\u53ef\u4ee5\u6709\u6548\u53d1\u5c55\u9ad8\u6548\u975e\u6676\u6001RTP\u5171\u805a\u7269\u6750\u6599\u4f53\u7cfb\uff0c\u8be5\u7c7b\u805a\u5408\u7269\u4f18\u5f02\u7684\u751f\u7269\u76f8\u5bb9\u6027\u3001\u4f4e\u5ec9\u7684\u6210\u672c\u548c\u826f\u597d\u7684\u6c34\u6eb6\u6027\u4f7f\u5176\u5728\u5b9e\u9645\u5e94\u7528\u9886\u57df\u6709\u7740\u4e0d\u5c0f\u7684\u6f5c\u529b (<em>Adv. Opt. Mater. <\/em><strong>2019<\/strong>, 7, 1901277)\u3002\u901a\u8fc7\u8fdb\u4e00\u6b65\u62d3\u5c55\u78f7\u5149\u4f53\u7684\u5171\u8f6d\u5927\u5c0f\uff0c\u5b9e\u73b0\u4e86\u5177\u6709\u8fd1\u7ea2\u5916\u957f\u6ce2\u957fRTP\u53d1\u5c04\uff08RTP\u53d1\u5c04\u6ce2\u957f\u8fbe770nm\uff09\u7684\u7eaf\u6709\u673a\u805a\u5408\u7269\u53ca\u6c34\u51dd\u80f6\u4f53\u7cfb (<em>Chem. Sci.<\/em> <strong>2020<\/strong>, 11, 482-487)\u3002\u4e3a\u4e86\u62d3\u5c55RTP\u7684\u53d1\u5c04\u5bff\u547d\uff0c\u8fd8\u8fdb\u4e00\u6b65\u901a\u8fc7\u5c06\u5404\u79cd\u542b\u6c27\u5b98\u80fd\u56e2\u53d6\u4ee3\u7684\u82ef\u57fa\u78f7\u5149\u5355\u4f53\u4e0e\u4e19\u70ef\u9170\u80fa\u4e8c\u5143\u5171\u805a\uff0c\u975e\u5e38\u4fbf\u6377\u5730\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u9ad8\u6548\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\u7684\u65e0\u5b9a\u5f62\u6001\u805a\u5408\u7269\u6750\u6599\uff0c\u6b64\u7c7b\u65e0\u5b9a\u5f62\u6001\u6750\u6599\u56e0\u5176\u8d85\u957f\u7684\u5bff\u547d\u548c\u9ad8\u6548\u7684\u91cf\u4ea7\u53ef\u4ee5\u901a\u8fc7\u8089\u773c\u89c2\u5bdf\u5230\u53d1\u5149\u73b0\u8c61\uff0c\u5e76\u4e14\u8be5\u5de5\u4f5c\u4e2d\u5229\u7528\u6c27\u539f\u5b50\u4e0a\u5b64\u5bf9\u7535\u5b50\u4fc3\u8fdb\u7684n\u2013\u03c0*\u8dc3\u8fc1\u6765\u63d0\u9ad8\u7cfb\u95f4\u7a7f\u8d8a\u51e0\u7387\uff0c\u4ee3\u66ff\u4e86\u8be5\u7c7b\u4f53\u7cfb\u4e2d\u5e38\u89c1\u7684\u5364\u7d20\u91cd\u539f\u5b50\uff0c\u7387\u5148\u62a5\u9053\u4e86\u65e0\u91cd\u539f\u5b50\u65e0\u5b9a\u5f62\u6001\u7eaf\u6709\u673a\u805a\u5408\u7269\u5ba4\u6e29\u78f7\u5149\u6750\u6599(<em>Angew. Chem. Int. Ed.<\/em> <strong>2018<\/strong>, 57, 10854)\u3002<\/p>\n<p>\u8fd1\u671f\u8fd8\u53d7\u9080\u64b0\u5199\u4e86\u7efc\u8ff0 (<em>Acc. Chem. Res.<\/em> <strong>2019<\/strong>, 52, 738\uff1b<em>Angew. Chem. Int. Ed.<\/em> <strong>2019<\/strong>, DOI: 10.1002\/anie.201915433) \uff0c\u603b\u7ed3\u4e86\u901a\u8fc7\u8d85\u5206\u5b50\u7ec4\u88c5\u8bf1\u5bfc\u53d1\u5149\uff08\u7279\u522b\u662f\u6709\u673a\u5ba4\u6e29\u78f7\u5149RTP\uff09\u7684\u7cfb\u5217\u5de5\u4f5c\uff0c\u91cd\u70b9\u5173\u6ce8\u4e86\u901a\u8fc7\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff08\u5982\u4e3b\u5ba2\u4f53\u548c\u6c22\u952e\u521a\u6027\u5316\u4f5c\u7528\uff09\u6291\u5236\u975e\u8f90\u5c04\u8dc3\u8fc1\uff0c\u4ece\u800c\u8bf1\u5bfc\u6216\u589e\u5f3a\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\uff0c\u603b\u7ed3\u5e76\u63d0\u51fa\u4e86 \u201c\u7ec4\u88c5\u8bf1\u5bfc\u53d1\u5149\u201d\u7684\u65b0\u601d\u60f3\u3002\u8fd1\u671f\u6709\u5173\u6709\u673a\u975e\u6676\u6001\u5ba4\u6e29\u78f7\u5149\u6750\u6599\u4f53\u7cfb\u7684\u7814\u7a76\u6210\u679c\u5df2\u7533\u8bf7\u53d1\u660e\u4e13\u5229<strong>9<\/strong>\u9879\uff09\u3002<\/p>\n<ul>\n<li><strong>\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350<\/strong><\/li>\n<li><strong>Xiang Ma*<\/strong>, Jie Wang and He Tian*.\u00a0Assembling-Induced Emission: An Efficient Approach for Amorphous Metal-Free Organic Emitting Materials with Room-Temperature Phosphorescence.\u00a0<em> Chem. Res.<\/em>,\u00a0<strong>2019<\/strong>, 52, 738-748.<\/li>\n<li>Ting Zhang,\u00a0<strong>Xiang Ma*<\/strong>, Hongwei Wu, Liangliang Zhu, Yanli Zhao and He Tian*. Molecular engineering for metal-free amorphous room-temperature phosphorescent materials.\u00a0<em> Chem. Int. Ed.<\/em>,\u00a0<strong>2019<\/strong>, DOI: 10.1002\/anie.201915433.<\/li>\n<li>Jie Wang, Zizhao Huang,\u00a0<strong>Xiang Ma*<\/strong>and He Tian.\u00a0Visible-Light-Excited Room-Temperature Phosphorescence in Water by Cucurbit[8]uril-Mediated Supramolecular Assembly.\u00a0<em> Chem. Int. Ed<\/em>,\u00a0<strong>2019<\/strong>,\u00a0DOI:\u00a010.1002\/anie.201914513.\u00a0<\/li>\n<li>Dengfeng Li, Feifei Lu, Jie Wang, Wende Hu, Xiao-Ming Cao,\u00a0<strong>Xiang Ma*<\/strong>and He Tian. Amorphous Metal-Free Room-Temperature Phosphorescent Small Molecules with Multicolor Photoluminescence via a Host-Guest and Dual-Emission Strategy.\u00a0<em> Am. Chem. Soc.<\/em>,\u00a0<strong>2018<\/strong>, 140, 1916-1923.<\/li>\n<li><strong>Xiang Ma*<\/strong>, Chao Xu, Jie Wang and He Tian*. Amorphous Pure Organic Polymers for Heavy-Atom-Free Efficient Room-Temperature Phosphorescence Emission.\u00a0<em> Chem. Int. Ed.<\/em>,\u00a0<strong>2018<\/strong>, 57, 10854-10858.<\/li>\n<li>Qi-Wei Zhang,\u00a0Dengfeng Li,\u00a0Xin Li, Paul\u00a0White,\u00a0Jasmin Mecinovic,\u00a0<strong>Xiang Ma*<\/strong>, Hans\u00a0\u00c5gren,\u00a0\u00a0Roeland Nolte,\u00a0He Tian*.\u00a0Multicolor Photoluminescence Including White-Light Emission by a Single Host-Guest Complex.\u00a0<em> Am. Chem. Soc.<\/em>,\u00a0<strong>2016<\/strong>, 138 (41), 13541-13550.<\/li>\n<li>Ting Zhang,\u00a0<strong>Xiang Ma*<\/strong>and He Tian.\u00a0A Facile Way to Obtain Near-Infrared Room-Temperature phosphorescent Soft Materials based on Bodipy Dyes.\u00a0<em> Sci.<\/em>,\u00a0<strong>2020<\/strong>, 11, 482-487.<\/li>\n<li>Dengfeng Li, Wende Hu, Jie Wang, Qiwei Zhang, Xiao-Ming Cao,\u00a0<strong>Xiang Ma*\u00a0<\/strong>and He Tian. White-Light Emission from a Single Organic Compound with Unique Self-Folded Conformation and Multistimuli Responsiveness.\u00a0<em> Sci.<\/em>,\u00a0<strong>2018<\/strong>, 9, 5709-5715.<\/li>\n<li>Tao Jiang, Xi Wang, Jie Wang, Guoping Hu,\u00a0<strong>Xiang Ma*<\/strong>. Humidity and Temperature Tunable Multicolor Luminescence of Cucurbit[8]uril-based Supramolecular Assembly.\u00a0<em>ACS Appl.\u00a0Mater. Inter.<\/em>,\u00a0<strong>2019<\/strong>, 11, 14399-14407<\/li>\n<li>Dengfeng Li, Jie Wang,<strong>Xiang Ma*<\/strong>.\u00a0White-light emitting materials constructed from supramolecular approaches.\u00a0<em> Opt. Mater.<\/em>,\u00a0<strong>2018<\/strong>, 6, 1800273.<\/li>\n<\/ul>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5ba4\u6e29\u78f7\u5149\uff08Room-temperature phosphorescence, RTP\uff09\uff0c\u4f5c\u4e3a\u5149\u81f4\u53d1\u5149\u4e2d\u8f83\u4e3a\u7279\u6b8a\u7684\u4e00\u7c7b\u957f\u5bff\u547d\u53d1\u5149\uff0c\u56e0\u5176\u8f83\u5927\u7684\u65af\u6258\u514b\u65af\u4f4d\u79fb&#8230;<\/p>\n","protected":false},"author":7336,"featured_media":194392,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4295],"class_list":["post-194390","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-4295"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194390"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=194390"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194390\/revisions"}],"predecessor-version":[{"id":194525,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194390\/revisions\/194525"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/194392"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=194390"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=194390"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=194390"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}