{"id":194698,"date":"2020-01-19T06:30:22","date_gmt":"2020-01-18T22:30:22","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=194698"},"modified":"2020-01-18T17:00:55","modified_gmt":"2020-01-18T09:00:55","slug":"%e6%9d%90%e6%96%99%e5%b1%8a%e7%9a%84%e6%96%b0%e6%a0%a1%e8%8a%b1-mxenes%e5%9c%a8%e5%82%a8%e8%83%bd%e3%80%81%e5%82%ac%e5%8c%96%e3%80%81%e5%82%a8%e6%b0%a2%e3%80%81%e4%bc%a0%e6%84%9f%e6%96%b9%e9%9d%a2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=194698","title":{"rendered":"\u6750\u6599\u5c4a\u7684\u65b0\u6821\u82b1—MXenes\u5728\u50a8\u80fd\u3001\u50ac\u5316\u3001\u50a8\u6c22\u3001\u4f20\u611f\u65b9\u9762\u7684\u6700\u8fd1\u8fdb\u5c55"},"content":{"rendered":"

MXenes\u6750\u6599\u662f\u4e00\u7c7b\u5177\u6709\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\u7684\u91d1\u5c5e\u78b3\u5316\u7269\u548c\u91d1\u5c5e\u6c2e\u5316\u7269\u6750\u6599\uff0c\u5b83\u5916\u5f62\u7c7b\u4f3c\u4e8e\u7247\u7247\u76f8\u53e0\u7684\u85af\u7247\u3002\u5b83\u5177\u6709\u8bb8\u591a\u4f18\u8d8a\u7684\u7279\u6027\u5305\u62ec\u5143\u7d20\u7ec4\u6210\u548c\u7ed3\u6784\u7684\u53ef\u8c03\u6027\uff0c\u91d1\u5c5e\u7279\u6027\uff0c\u8f7d\u6d41\u5b50\u8fc1\u79fb\u5404\u5411\u5f02\u6027\uff0c\u826f\u597d\u7684\u5149\u5b66\u548c\u673a\u68b0\u6027\u80fd\u7b49\u3002\u76ee\u524d\u8be5\u7c7b\u6750\u6599\u5df2\u5728\u591a\u4e2a\u9886\u57df\uff08\u5982\u80fd\u6e90\u3001\u5149\u5b66\u3001\u50ac\u5316\u7b49\uff09\u5f15\u53d1\u4e86\u5168\u4e16\u754c\u7684\u5173\u6ce8\u3002<\/b><\/strong>\u4e3a\u4e86\u8ba9\u66f4\u591a\u7684\u7814\u7a76\u8005\u4e86\u89e3MXenes\u6750\u6599\uff0c\u4fc3\u8fdbMXenes\u6750\u6599\u7684\u5f00\u53d1\u548c\u5229\u7528\uff0c\u672c\u6587\u603b\u7ed3\u4e86\u8fd1\u5e74\u6765MXenes\u6750\u6599\u7684\u4e00\u4e9b\u4ee3\u8868\u6027\u5e94\u7528\u6210\u679c<\/b><\/strong>\uff08\u50a8\u80fd\u3001\u50a8\u6c22\u3001\u50ac\u5316\u53ca\u4f20\u611f\u7b49\u9886\u57df\uff09\uff0c\u4ee5\u4f9b\u5927\u5bb6\u53c2\u8003\u3002<\/p>\n

1\u3001\u50a8\u80fd\u9886\u57df<\/b><\/strong><\/p>\n

Energy &<\/b><\/strong>\u00a0<\/b><\/strong>Environmental<\/b><\/strong>\u00a0<\/b><\/strong>Science<\/b><\/strong>\uff1a\u4e09\u7ef4\u8936\u76b1<\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>M<\/b><\/strong>X<\/b><\/strong>ene\u590d\u5408NiCoP\u53cc\u91d1\u5c5e\u78f7\u5316\u7269\u6784\u5efa\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

N<\/b><\/strong>ano Energy<\/b><\/strong>\uff1a\u591a\u5b54MXene\u52a9\u529b\u9ad8\u6027\u80fd\u94be\u79bb\u5b50\u7535\u5bb9\u5668\u68a6\u60f3\u6210\u771f\uff01<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>3 K\u2013V<\/b><\/strong>2<\/b><\/sub><\/strong>C MXene<\/b><\/strong>\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u548c\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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2\u3001<\/b><\/strong>\u50ac\u5316\u9886\u57df<\/b><\/strong><\/p>\n

Joule<\/b><\/strong>\uff1a<\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>\u00a0M<\/b><\/strong>Xene<\/b><\/strong>\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u9ad8\u6548\u7535\u50ac\u5316\u56fa\u6c2e<\/b><\/strong><\/p>\n

\u6c28\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u5de5\u4e1a\u539f\u6599\uff0c\u5316\u80a5\u524d\u9a71\u4f53\u548c\u71c3\u6599\u5bf9\u4e8e\u4eba\u7c7b\u793e\u4f1a\u6781\u4e3a\u91cd\u8981\u3002\u8fd1\u51e0\u5341\u5e74\u6765\uff0cHaber-Bosch\u6cd5<\/b><\/strong>\u4e00\u76f4\u90fd\u662f\u5408\u6210\u6c28\u7684\u4e3b\u8981\u65b9\u6cd5\uff0c\u4f46\u8be5\u65b9\u6cd5\u9700\u8981\u5728\u9ad8\u6e29\u9ad8\u538b\u4e0b\u8fdb\u884c\uff0c\u8017\u80fd\u9ad8\uff0c\u6c61\u67d3\u5927\u3002<\/b><\/strong>\u56e0\u6b64\u4eba\u4eec\u5e0c\u671b\u80fd\u591f\u91c7\u7528\u53ef\u6301\u7eed\u80fd\u6e90\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5408\u6210\u6c28\u3002\u4e0d\u8fc7\uff0cN2<\/sub>\u4e2d\u7684N\u2261N\u975e\u5e38\u7a33\u5b9a\uff0c\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\uff0c\u6c2e\u6c14\u548c\u6c22\u6c14\u7684\u53cd\u5e94\u5728\u52a8\u529b\u5b66\u5341\u5206\u7f13\u6162\uff0c\u4e14\u6790\u6c22\u7535\u4f4d\u548c\u6c2e\u8fd8\u539f\u7535\u4f4d\u5341\u5206\u63a5\u8fd1\uff0c\u8fd9\u4f1a\u4e25\u91cd\u5236\u7ea6\u6c2e\u8fd8\u539f\u5408\u6210\u6c28\u7684\u6548\u7387\uff0c\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5404\u79cd\u50ac\u5316\u5242\u7684\u771f\u5b9e\u6548\u7387\u5c1a\u5c0f\u4e8e1%\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u51fa\u4e00\u79cd\u80fd\u591f\u5728\u5ba4\u6e29\u4e0b\u9ad8\u6548\u56fa\u6c2e\u7684\u7535\u50ac\u5316\u5242\u662f\u4e00\u5927\u6311\u6218\u3002\u5728\u6b64\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u738b\u6d77\u8f89\u548c\u4e01\u826f\u946b<\/b><\/strong>\u56e2\u961f\u5229\u7528Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/b><\/strong>MXene\u4f5c\u4e3a\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3<\/b><\/strong>\u5b9e\u73b0\u4e86\u6c28\u7684\u7535\u50ac\u5316\u9ad8\u6548\u5408\u6210\uff08\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe5.78%\uff09[3]<\/sup>\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u90fd\u8868\u660e\uff0cMXene\u7684\u57fa\u5e95\u9762\uff08basal\u00a0plane\uff09\u662f\u76f8\u5bf9\u60f0\u6027\u7684\uff0c\u5176\u50ac\u5316\u6d3b\u6027\u4e0e\u66b4\u9732\u7684\u8fb9\u7f18\u9762\uff08edge plane\uff09\u6570\u91cf\u6709\u5173\u3002\u636e\u6b64\uff0c\u4f5c\u8005\u901a\u8fc7\u51cf\u5c0fMXene\u7684\u5c3a\u5bf8\u5e76\u5c06\u5176\u8d1f\u8f7d\u5728\u5177\u6709\u5f31\u6790\u6c22\u80fd\u529b\u7684\u5782\u76f4\u6392\u5217\u7684FeOOH\u8868\u9762\u5b9e\u73b0\u4e86\u6d3b\u6027\u4f4d\u70b9\u7684\u6700\u5927\u7a0b\u5ea6\u66b4\u9732\uff08\u56fe5\uff09\u3002\u4e0e\u8d1f\u8f7d\u5728\u4e0d\u9508\u94a2\u7f51\u4e0a\u7684MXene\u76f8\u6bd4\uff081.44%\uff09\uff0c\u8d1f\u8f7d\u5728\u5782\u76f4\u6392\u5217\u7684FeOOH\u8868\u9762\u7684MXene\u5177\u6709\u66f4\u9ad8\u7684\u7535\u50ac\u5316\u6cd5\u62c9\u7b2c\u6548\u7387\uff085<\/b><\/strong>.78<\/b><\/strong>%\uff09<\/b><\/strong>\uff08\u56fe6\uff09\u3002\u5176\u6027\u80fd\u6539\u5584\u4e3b\u8981\u6e90\u4e8e\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u7684\u589e\u52a0\uff1b\uff082\uff09\u8f7d\u4f53\u5177\u6709\u4f4e\u7684\u6790\u6c22\u53cd\u5e94\uff1b\uff083\uff09\u5782\u76f4\u6392\u5217\u7684FeOOH\u6709\u5229\u4e8e\u53cd\u5e94\u6c14\u4f53\u7684\u6269\u6563\u3002\u8be5\u5de5\u4f5c\u4e5f\u5bf9\u4f18\u53162D\u50ac\u5316\u5242\u7684\u8868\u9762\u6027\u8d28\u4ee5\u7528\u4e8e\u5e38\u6e29\u5e38\u538b\u4e0b\u9ad8\u6548\u56fa\u6c2e\u63d0\u4f9b\u4e86\u91cd\u8981\u501f\u9274\u3002<\/p>\n

\u56fe5<\/b><\/strong>\u00a0Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/b><\/strong>MXene\u6750\u6599\u7684\u7269\u7406\u6027\u8d28<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>6 <\/b><\/strong>MXene\u7684\u6d3b\u6027\u4f4d\u70b9\u8bc6\u522b\u548cFeOOH\u8d1f\u8f7d\u7684MXene\u6750\u6599\u7684\u6c2e\u8fd8\u539f\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3\u3001\u50a8\u6c22\u6750\u6599<\/b><\/strong><\/p>\n

International Journal of Hydrogen Energy<\/b><\/strong>\uff1a<\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>MXene\u6539\u5584LiBH<\/b><\/strong>4<\/b><\/sub><\/strong>\u7684\u50a8\u6c22\u6027\u80fd<\/b><\/strong><\/p>\n

\u6c22\u80fd\u662f\u4e00\u79cd\u53ef\u518d\u751f\u7684\u6e05\u6d01\u80fd\u6e90\uff0c\u4eba\u4eec\u8ba4\u4e3a\u5b83\u6700\u6709\u5e0c\u671b\u53d6\u4ee3\u4f20\u7edf\u7684\u5316\u77f3\u80fd\u6e90\u3002\u7136\u800c\uff0c\u6c22\u80fd\u5728\u5b58\u50a8\u548c\u8fd0\u8f93\u65b9\u9762\u7684\u56f0\u96be\u4e25\u91cd\u5730\u7814\u5236\u4e86\u5b83\u5927\u89c4\u6a21\u7684\u5e94\u7528\u3002<\/b><\/strong>LiBH4<\/sub>\u4f5c\u4e3a\u4e00\u79cd\u50a8\u6c22\u6750\u6599\u56e0\u5177\u6709\u5927\u7684\u7406\u8bba\u50a8\u6c22\u5bb9\u91cf\uff0818.5 wt%\uff09\u548c\u9ad8\u7684\u4f53\u79ef\u50a8\u6c22\u5bc6\u5ea6\uff08121 kg m-3<\/sup>\uff09\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5730\u5173\u6ce8\u3002\u4f46\u662f\uff0cLiBH<\/b><\/strong>4<\/b><\/sub><\/strong>\u5dee\u7684\u52a8\u529b\u5b66\u548c\u9ad8\u7684\u8131\u6c22\u6e29\u5ea6\u963b\u788d\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u3002<\/b><\/strong>\u5728\u6b64\uff0c\u6cb3\u5357\u7406\u5de5\u5927\u5b66\u7684\u5218\u5baa\u4e91\u548c\u5218\u5b9d\u5fe0<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u7403\u78e8\u7684\u65b9\u6cd5\u5c06LiBH4<\/sub>\u4e0e\u4e8c\u7ef4\u5c42\u72b6Ti3<\/sub>C2<\/sub>\u00a0MXene\u76f8\u590d\u5408\uff0c\u4ee5\u671f\u6539\u5584LiBH4<\/sub>\u7684\u8131\u6c22\u6027\u80fd[4]<\/sup>\u3002\u7a0b\u5e8f\u63a7\u6e29\u8131\u6c22\u5b9e\u9a8c\u548c\u7b49\u6e29\u8131\u6c22\u5b9e\u9a8c\u7ed3\u679c\u90fd\u8868\u660e\u52a0\u5165Ti3<\/sub>C2<\/sub>\u00a0MXene\u6709\u52a9\u4e8e\u6539\u5584LiBH4<\/sub>\u7684\u50a8\u6c22\u6027\u80fd\u3002\u5f15\u516540 wt%\u00a0Ti3<\/sub>C2<\/sub>\u00a0MXene\u7684LiBH<\/b><\/strong>4<\/b><\/sub><\/strong>\u8131\u6c22\u8d77\u59cb\u6e29\u5ea6\u4ec5\u4e3a1<\/b><\/strong>20<\/b><\/strong>\u2103\uff0c\u4f5c\u4e3a\u5bf9\u6bd4\uff0c\u7eaf\u7684<\/b><\/strong>LiBH<\/b><\/strong>4<\/b><\/sub><\/strong>\u8131\u6c22\u8d77\u59cb\u6e29\u5ea6\u5219\u9ad8\u8fbe\u8fd1<\/b><\/strong>300<\/b><\/strong>\u2103\uff08\u56fe7\uff09\u3002<\/b><\/strong>\u4e0e\u6b64\u540c\u65f6\uff0cLiBH4<\/sub>+40 wt% MXene\u6750\u6599\u5728350\u2103\u4e0b1\u00a0h\u5185\u80fd\u591f\u653e\u51fa\u5927\u7ea65.37 wt%\u7684\u6c22\uff08\u56fe7\uff09\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u4e5f\u5bf9\u5f15\u5165Ti3<\/sub>C2<\/sub>\u00a0MXene\u540eLiBH4<\/sub>\u6750\u6599\u7684\u8131\u6c22\u52a8\u529b\u5b66\u8fdb\u884c\u4e86\u7814\u7a76\uff08\u56fe8\uff09\u3002\u4e0e\u7eaf\u7684LiBH4<\/sub>\u76f8\u6bd4\uff0cLiBH<\/b><\/strong>4<\/b><\/sub><\/strong>+<\/b><\/strong>40 wt% MXene<\/b><\/strong>\u6750\u6599\u7684\u6fc0\u6d3b\u80fd\u5792\u8db3\u8db3\u964d\u4f4e\u4e867<\/b><\/strong>0.3 <\/b><\/strong>KJ<\/b><\/strong>\u00a0mol<\/b><\/strong>-1<\/b><\/sup><\/strong>\u3002<\/b><\/strong>LiBH4<\/sub>+40 wt% MXene\u6750\u6599\u4f18\u5f02\u7684\u8131\u6c22\u6027\u80fd\u53ef\u80fd\u6e90\u4e8e\u5305\u542bTi\u7684\u5c42\u72b6Ti3<\/sub>C2<\/sub>\u00a0MXene\u6750\u6599\u5177\u6709\u4e00\u5b9a\u6d3b\u6027\u4e14\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3002\u672c\u5de5\u4f5c\u4e5f\u4e3a\u5229\u7528MXene\u6750\u6599\u6539\u5584\u50a8\u6c22\u6750\u6599\u7684\u6027\u80fd\u63d0\u4f9b\u4e86\u4e00\u5b9a\u7684\u501f\u9274\u3002<\/p>\n

\u56fe7<\/b><\/strong>\u00a0Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>MXene\u5bf9LiBH<\/b><\/strong>4<\/b><\/sub><\/strong>\u8131\u6c22\u6027\u80fd\u7684\u6539\u5584<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>8 LiBH<\/b><\/strong>4<\/b><\/sub><\/strong>+<\/b><\/strong>40 wt% MXene<\/b><\/strong>\u6750\u6599\u7684\u8d28\u8c31\u66f2\u7ebf\u548c<\/b><\/strong>Kissinger<\/b><\/strong>\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4\u3001\u4f20\u611f\u5668<\/b><\/strong><\/p>\n

Nano Letters<\/b><\/strong>\uff1aMXene\u7eb3\u7c73\u7247\u5236\u5907\u7684\u53ef\u7a7f\u6234\u77ac\u6001\u538b\u529b\u4f20\u611f\u5668\u7528\u4f5c\u9ad8\u7075\u654f\u5bbd\u8303\u56f4\u7684\u4eba\u673a\u4ea4\u4e92\u754c\u9762<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u4fbf\u643a\u3001\u5b9e\u65f6\u538b\u529b\u611f\u5e94\u3001\u67d4\u6027\u548c\u5bf9\u73af\u5883\u6c61\u67d3\u5c11\u7684\u7279\u70b9\uff0c\u67d4\u6027\u53ef\u964d\u89e3\u7684\u538b\u529b\u4f20\u611f\u5668\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5b83\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u77ac\u6001\u538b\u529b\u4f20\u611f\u5668\uff0c\u67d4\u6027\u663e\u793a\u5668\u548c\u667a\u80fd\u673a\u5668\u4eba\u9886\u57df\u3002\u7136\u800c\uff0c\u8bbe\u8ba1\u5e76\u5236\u5907\u51fa\u540c\u65f6\u5177\u6709\u9ad8\u7684\u7075\u654f\u5ea6\u3001\u5bbd\u7684\u538b\u529b\u611f\u5e94\u8303\u56f4\uff08\u76f4\u523030 kPa\uff09\u3001\u5feb\u901f\u7684\u54cd\u5e94\u3001\u957f\u7684\u4f7f\u7528\u5bff\u547d\u548c\u53ef\u964d\u89e3\u7279\u6027\u7684\u538b\u529b\u4f20\u611f\u5668\u4ee5\u5b9e\u73b0\u5168\u5c3a\u5ea6\u7684\u751f\u7269\u538b\u529b\u4fe1\u606f\u76d1\u89c6\u5e76\u51cf\u5c11\u7535\u5b50\u5783\u573e\u6392\u653e\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002MXenes\u662f\u4e00\u79cd\u5177\u6709\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\u7684\u6750\u6599\uff0c\u5b83\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u5df2\u7ecf\u5728\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u4e0a\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u5728\u6b64\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u7684\u4e07\u9e4f\u535a\u548c\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u7684\u4f59\u6842\u534e<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u5c06\u542b\u6709MXene\u7684\u8584\u7eb8\uff08Tissue\uff09\u5305\u88f9\u5728\u751f\u7269\u53ef\u964d\u89e3\u7684\u805a\u4e73\u9178\uff08PLA\uff09\u5939\u5c42\u4e2d\u5236\u5907\u51fa\u4e86\u4e00\u4e2a\u5177\u6709\u9ad8\u7075\u654f\u5ea6\u3001\u67d4\u6027\u7684\u3001\u53ef\u964d\u89e3\u7684\u538b\u529b\u4f20\u611f\u5668\uff08\u56fe9\uff09[5]<\/sup>\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u8be5\u67d4\u6027\u7684\u538b\u529b\u4f20\u611f\u5668\u5177\u6709\u9ad8\u7684\u7075\u654f\u5ea6\uff08\u6700\u4f4e\u68c0\u6d4b\u965010.2 Pa\uff09\u3001\u5bbd\u7684\u538b\u529b\u68c0\u6d4b\u8303\u56f4\uff08\u6700\u9ad8\u8fbe30 kPa\uff09\u3001\u5feb\u7684\u54cd\u5e94\u901f\u5ea6\uff0811 ms\uff09\u3001\u4f4e\u7684\u529f\u7387\u6d88\u8017\uff0810–<\/sup>8<\/sup>\u00a0W\uff09\u3001\u957f\u7684\u4f7f\u7528\u6b21\u6570\uff08\u9ad8\u8fbe10000\u6b21\uff09\u548c\u4f18\u5f02\u7684\u53ef\u964d\u89e3\u6027\uff08\u56fe10\uff09\u3002\u8be5\u538b\u529b\u4f20\u611f\u5668\u4e5f\u53ef\u7528\u6765\u9884\u6d4b\u75c5\u4eba\u6f5c\u5728\u7684\u5065\u5eb7\u72b6\u51b5\u6216\u4f5c\u4e3a\u7535\u5b50\u76ae\u80a4\u6765\u663e\u793a\u538b\u529b\u523a\u6fc0\uff08\u56fe10\uff09\u3002\u8fd9\u4e9b\u90fd\u8868\u660e\u5b83\u5728\u4e2a\u4eba\u5065\u5eb7\u76d1\u89c6\u3001\u4e34\u5e8a\u8bca\u65ad\u548c\u4e0b\u4e00\u4ee3\u4eba\u5de5\u76ae\u80a4\u65b9\u9762\u975e\u5e38\u6709\u524d\u666f\u3002<\/p>\n

\u56fe<\/b><\/strong>9 <\/b><\/strong>\u91c7\u7528Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/i><\/b><\/sub><\/em><\/strong>\u00a0MXene<\/b><\/strong>\u5236\u5907\u7684\u53ef\u7a7f\u6234\u77ac\u6001\u538b\u529b\u4f20\u611f\u5668<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>10 <\/b><\/strong>\u538b\u529b\u4f20\u611f\u5668\u5236\u5907\u6210\u7684\u7535\u5b50\u76ae\u80a4\u548c\u5176\u964d\u89e3\u5b9e\u9a8c\u7ed3\u679c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5\u3001\u5149\u5b66\u9886\u57df<\/b><\/strong><\/p>\n

Advanced Science<\/b><\/strong>\uff1aTi<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0MXene<\/b><\/strong>\u91cf\u5b50\u70b9\u5b9e\u73b0\u53cc\u5149\u5b50\u767d\u8272\u8367\u5149<\/b><\/strong><\/p>\n

\u6700\u8fd1\uff0c\u4e8c\u7ef4\u65e0\u673a\u6750\u6599MXenes\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u4e0e\u5173\u6ce8\u3002\u5982\u679c\u80fd\u591f\u5c06\u5b83\u4eec\u7684\u5c3a\u5bf8\u4ece2D\u7247\u5c42\u72b6\u53d8\u4e3a0D\u7684\u91cf\u5b50\u70b9\uff08QDs\uff09\uff0c\u6211\u4eec\u5c31\u80fd\u5f97\u5230\u66f4\u591a\u6709\u7528\u7684\u6027\u8d28\u548c\u529f\u80fd\uff0c\u5982\u7528\u4e8e\u5149\u81f4\u53d1\u5149\u548c\u5149\u50ac\u5316\u7b49\u3002\u7136\u800c\uff0c\u8fd9\u65b9\u9762\u7684\u7814\u7a76\u5374\u6bd4\u8f83\u5c11\uff0c\u5df2\u6709\u7684\u7814\u7a76\u4e5f\u8868\u660eTi3<\/sub>C2<\/sub>\u00a0MXene\u91cf\u5b50\u70b9\uff08Ti3<\/sub>C2<\/sub>\u00a0MQDs\uff09\u4ec5\u80fd\u53d1\u51fa\u84dd\u8272\u8367\u5149\u3002\u9274\u4e8e\u6b64\uff0c\u90d1\u5dde\u5927\u5b66\u7684\u5362\u601d\u5b87<\/b><\/strong>\uff0c<\/b><\/strong>\u5409\u6797\u5927\u5b66\u8096\u51a0\u519b<\/b><\/strong>\u548c<\/b><\/strong>\u6cb3\u5357\u7406\u5de5<\/b><\/strong>\u5927\u5b66<\/b><\/strong>\u5218\u5b9d\u5fe0<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u6613\u9ad8\u6548\u7684\u5236\u5907\u5177\u6709\u5f3a\u70c8\u767d\u8272\u8367\u5149\u7684Ti3<\/sub>C2<\/sub>\u00a0MQDs\u7684\u65b9\u6cd5[6]<\/sup>\u3002\u6700\u7ec8\u5236\u5907\u7684Ti3<\/sub>C2<\/sub>\u00a0MQDs\u4ea7\u7269\u539a\u5ea6\u5927\u7ea6\u4e3a2\u5c42\uff0c\u5c3a\u5bf8\u5927\u7ea6\u4e3a13.1 nm\uff08\u56fe11\uff09\u3002\u91cd\u8981\u7684\u662f\uff0c\u5408\u6210\u51fa\u7684Ti3<\/sub>C2<\/sub>\u00a0MQDs\u8868\u73b0\u51fa\u5f3a\u70c8\u7684\u53cc\u5149\u5b50\u767d\u8272\u8367\u5149\u3002\u4f5c\u8005\u4e5f\u7814\u7a76\u4e86Ti3<\/sub>C2<\/sub>\u00a0MQDs\u5728\u9ad8\u538b\u6761\u4ef6\u4e0b\u53d1\u5149\u6027\u8d28\uff1a\u5b83\u4ecd\u7136\u80fd\u591f\u53d1\u51fa\u7a33\u5b9a\u7684\u767d\u5149\u4f46\u989c\u8272\u4ece\u51b7\u767d\u8272\u53d8\u4e3a\u6696\u767d\u8272\uff08\u56fe12\uff09\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u8fd8\u5c06Ti3<\/sub>C2<\/sub>\u00a0MQDs\u5728\u805a\u4e8c\u7532\u7845\u6c27\u70f7\uff08PDMS\uff09\u6eb6\u6db2\u4e2d\u8fdb\u884c\u805a\u5408\u5236\u5907\u51fa\u4e86\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff0c\u5e76\u5c06\u8fd9\u79cd\u80fd\u591f\u53d1\u51fa\u4eae\u767d\u8272\u5149\u7684\u590d\u5408\u6750\u6599\u5e94\u7528\u5728\u4e86\u767d\u5149LEDs\u4e2d\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4e3a\u8c03\u63a7MXene\u6750\u6599\u7684\u5c3a\u5bf8\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u6613\u901a\u7528\u7684\u65b9\u6cd5\uff0c\u5e76\u80fd\u591f\u8fdb\u4e00\u6b65\u5730\u4fc3\u8fdbMXene\u6750\u6599\u5728\u5149\u5b66\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

\u56fe<\/b><\/strong>11 <\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0MXene<\/b><\/strong>\u91cf\u5b50\u70b9<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>12 <\/b><\/strong>\u538b\u529b\u5bf9Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0MXene<\/b><\/strong>\u91cf\u5b50\u70b9\u53d1\u5149\u6027\u80fd\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

6\u3001\u5176\u4ed6<\/b><\/strong><\/p>\n

\u7531\u4e8eMXenes\u6750\u6599\u5177\u6709\u72ec\u7279\u7684\u6210\u5206\u548c\u7ed3\u6784\u4ee5\u53ca\u5e7f\u6cdb\u5730\u53ef\u8c03\u63a7\u6027\uff0c\u5b83\u4eec\u8fd8\u5e7f\u6cdb\u5730\u5e94\u7528\u5728\u7535\u78c1\u5e72\u6270\u5c4f\u853d\uff0c\u901a\u4fe1\uff0c\u590d\u5408\u6750\u6599\u589e\u5f3a\uff0c\u6c34\u51c0\u5316\uff0c\u6da6\u6ed1\u548c\u6c14\u4f53\u5206\u79bb\u7b49\u5404\u79cd\u9886\u57df\u3002<\/p>\n

A<\/b><\/strong>dvanced Functional Materials<\/b><\/strong>\uff1a\u4e8c\u7ef4<\/b><\/strong>Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>MXene\u5b9e\u73b0\u9ad8\u6548\u7535\u78c1\u5c4f\u853d\u548c\u65e0\u7ebf\u901a\u4fe1<\/b><\/strong><\/p>\n

\u5728\u7269\u8054\u7f51\u5174\u8d77\u7684\u8fc7\u7a0b\u4e2d\uff0c\u53ef\u4f38\u5c55\u7684\u5929\u7ebf\u80fd\u591f\u4fc3\u8fdb\u53ef\u7a7f\u6234\u8bbe\u5907\u548c\u79fb\u52a8\u7535\u5b50\u8bbe\u5907\u5728\u4eba\u4f53\u5468\u8fb9\u7684\u65e0\u7ebf\u901a\u4fe1\u3002\u7136\u800c\uff0c\u5927\u91cf\u7684\u65e0\u7ebf\u4fe1\u53f7\u4f20\u8f93\u4e0d\u4ec5\u4f1a\u4e92\u76f8\u5e72\u6270\u800c\u4e14\u8fd8\u4f1a\u5f15\u53d1\u5065\u5eb7\u95ee\u9898\uff0c\u56e0\u6b64\u5982\u4f55\u5236\u5907\u4e00\u79cd\u53ef\u4f38\u5c55\u7684\u6750\u6599\u4ee5\u540c\u65f6\u5b9e\u73b0\u65e0\u7ebf\u901a\u4fe1\u5e76\u5c4f\u853d\u7535\u78c1\u5e72\u6270\u5c31\u663e\u5f97\u5f88\u91cd\u8981\u3002\u9274\u4e8e\u6b64\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u7684<\/b><\/strong>Po-Yen Chen<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u901a\u8fc7\u5728\u4e73\u80f6\uff08Latex\uff09\u4e0a\u6c89\u79ef\u4e00\u5c42\u5305\u542b2D\u00a0Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0MXene\u7eb3\u7c73\u7247\u548c\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff08SWNT\uff09\u7684\u8936\u76b1\u72b6\u7ec7\u7269\u6d82\u5c42\u5236\u5907\u51fa\u4e86\u4e00\u79cd\u53ef\u4f38\u5c55\u7684\u5bfc\u4f53\uff08\u56fe13\uff09\uff0c\u5b83\u53ef\u7528\u4e8e\u5236\u5907\u9ad8\u6027\u80fd\u53ef\u7a7f\u6234\u5929\u7ebf\u548c\u7535\u5b50\u5c4f\u853d\u5668\u4ef6<\/b><\/strong>[7]<\/sup>\u3002\u6d4b\u8bd5\u8868\u660e\uff0c\u8be5MXene-SWNT\/Latex\uff08S-MXene\/Latex\uff09\u5668\u4ef6\u80fd\u591f\u627f\u53d7\u9ad8\u8fbe800%\u7684\u9762\u5e94\u53d8\u4e14\u5728\u6301\u7eed500\u6b21\u7684\u75b2\u52b3\u8bd5\u9a8c\u4e2d\u5c55\u793a\u51fa\u5e94\u53d8\u4e0d\u654f\u611f\u7684\u7535\u963b\u7279\u6027\uff08\u56fe13\uff09\u3002\u5355\u5c42\u53ef\u4f38\u5c55\u7684S-MXene\u5bfc\u4f53\u7684\u7535\u78c1\u5c4f\u853d\u6027\u80fd\u5927\u7ea6\u4e3a3<\/b><\/strong>0 dB<\/b><\/strong>\u4e14\u4e0d\u968f\u5e94\u53d8\u800c\u53d8\u3002<\/b><\/strong>\u5f53\u53e0\u52a05\u5c42\u548c10\u5c42S-MXene\u5bfc\u4f53\u65f6\uff0c\u5668\u4ef6\u7684\u7535\u78c1\u5c4f\u853d\u6027\u80fd\u5206\u522b\u63d0\u5347\u5230\u4e8647\u548c52 dB\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5c06S-MXene\u5bfc\u4f53\u5236\u5907\u6210\u4e86\u5076\u6781\u5b50\u5929\u7ebf\uff0c\u5b83\u80fd\u591f\u62c9\u4f38\u53d8\u5f621<\/b><\/strong>50<\/b><\/strong>%\u5e76\u4fdd\u6301\u53cd\u5c04\u529f\u7387\u57fa\u672c\u4e0d\u53d8\u3002<\/b><\/strong>\u901a\u8fc7\u96c6\u6210S-MXene\u7684\u7535\u78c1\u5c4f\u853d\u529f\u80fd\u4e0eS-MXene\u5076\u6781\u5b50\u5929\u7ebf\uff0c\u6700\u7ec8\u4f5c\u8005\u5c55\u793a\u4e86\u4e00\u4e2a\u53ef\u7a7f\u6234\u7684\u65e0\u7ebf\u901a\u4fe1\u7cfb\u7edf\uff08\u56fe14\uff09\uff0c\u5b83\u80fd\u591f\u5b9e\u73b0\u7a33\u5b9a\u7684\u65e0\u7ebf\u901a\u4fe1\u5e76\u5b9e\u73b0\u7535\u78c1\u5c4f\u853d\u4ee5\u4fdd\u62a4\u4eba\u4f53\u5065\u5eb7\u3002<\/p>\n

\u56fe<\/b><\/strong>13 MXene<\/b><\/strong>-SWNT<\/b><\/strong>\/Latex<\/b><\/strong>\uff08S-MXene\/<\/b><\/strong>Latex<\/b><\/strong>\uff09\u5668\u4ef6\u53ca\u5176\u62c9\u4f38\u6027\u80fd <\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>14 <\/b><\/strong>\u53ef\u7a7f\u6234\u7684S-M<\/b><\/strong>X<\/b><\/strong>ene\u7cfb\u7edf<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

[1] D. Zhao, R. Zhao, S. Dong, X. Miao, Z. Zhang, C. Wang, L. Yin, Alkali-induced 3D crinkled porous Ti3<\/sub>C2<\/sub>\u00a0MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries, Energy & Environmental Science, 12 (2019) 2422-2432.<\/p>\n

[2] F. Ming, H. Liang, W. Zhang, J. Ming, Y. Lei, A.-H. Emwas, H.N. Alshareef, Porous MXenes enable high performance potassium ion capacitors, Nano Energy, 62 (2019) 853-860.<\/p>\n

[3] Y. Luo, G.-F. Chen, L. Ding, X. Chen, L.-X. Ding, H. Wang, Efficient Electrocatalytic N2<\/sub>\u00a0Fixation with MXene under Ambient Conditions, Joule, 3 (2019) 279-289.<\/p>\n

[4] Y. Fan, D. Chen, X. Liu, G. Fan, B. Liu, Improving the hydrogen storage performance of lithium borohydride by Ti3<\/sub>C2<\/sub>\u00a0MXene, International Journal of Hydrogen Energy, 44 (2019) 29297-29303.<\/p>\n

[5] Y. Guo, M. Zhong, Z. Fang, P. Wan, G. Yu, A Wearable Transient Pressure Sensor Made with MXene Nanosheets for Sensitive Broad-Range Human-Machine Interfacing, Nano Lett, 19 (2019) 1143-1150.<\/p>\n

[6] S. Lu, L. Sui, Y. Liu, X. Yong, G. Xiao, K. Yuan, Z. Liu, B. Liu, B. Zou, B. Yang, White Photoluminescent Ti3<\/sub>C2<\/sub>\u00a0MXene Quantum Dots with Two-Photon Fluorescence, Adv Sci (Weinh), 6 (2019) 1801470.<\/p>\n

[7] Y. Li, X. Tian, S.P. Gao, L. Jing, K. Li, H. Yang, F. Fu, J.Y. Lee, Y.X. Guo, J.S. Ho, P.Y. Chen, Reversible Crumpling of 2D Titanium Carbide (MXene) Nanocoatings for Stretchable Electromagnetic Shielding and Wearable Wireless Communication, Advanced Functional Materials, (2019) 1907451.<\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08<\/b>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

MXenes\u6750\u6599\u662f\u4e00\u7c7b\u5177\u6709\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\u7684\u91d1\u5c5e\u78b3\u5316\u7269\u548c\u91d1\u5c5e\u6c2e\u5316\u7269\u6750\u6599\uff0c\u5b83\u5916\u5f62\u7c7b\u4f3c\u4e8e\u7247\u7247\u76f8\u53e0\u7684\u85af\u7247\u3002\u5b83\u5177\u6709\u8bb8\u591a\u4f18\u8d8a\u7684\u7279\u6027\u5305\u62ec\u5143\u7d20\u7ec4\u6210\u548c\u7ed3\u6784\u7684\u53ef\u8c03\u6027\uff0c\u91d1\u5c5e\u7279\u6027\uff0c\u8f7d\u6d41\u5b50…<\/p>\n","protected":false},"author":10213,"featured_media":194699,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-194698","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194698"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=194698"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194698\/revisions"}],"predecessor-version":[{"id":194811,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/194698\/revisions\/194811"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/194699"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=194698"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=194698"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=194698"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}