{"id":195681,"date":"2020-02-20T06:50:05","date_gmt":"2020-02-19T22:50:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=195681"},"modified":"2020-02-19T15:50:29","modified_gmt":"2020-02-19T07:50:29","slug":"%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e5%9b%a2%e9%98%9fangewandte-chemie%ef%bc%9a%e4%b8%80%e7%a7%8d%e9%ab%98%e6%95%88%e3%80%81%e9%ab%98%e5%ae%b9%e9%87%8f%e5%82%a8%e9%94%82%e7%9a%84%e6%b0%a7%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=195681","title":{"rendered":"\u5929\u6d25\u5927\u5b66\u56e2\u961fAngewandte Chemie\uff1a\u4e00\u79cd\u9ad8\u6548\u3001\u9ad8\u5bb9\u91cf\u50a8\u9502\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u60272D\u91d1\u5c5e\u6709\u673a\u6846\u67b6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u5341\u5e74\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u56e0\u5176\u9ad8\u529f\u7387\/\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u800c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u50a8\u80fd\u8bbe\u5907\u4e2d\u3002\u7136\u800c\uff0c\u7528\u8fc7\u6e21\u91d1\u5c5e\u590d\u5408\u9634\u6781\u548c\u77f3\u58a8\u9633\u6781\u5efa\u9020\u7684\u5546\u7528LIBs\u5df2\u7ecf\u8fbe\u5230\u4e86\u5b83\u4eec\u7684\u6027\u80fd\u6781\u9650\u3002\u7279\u522b\u662f\u8fc7\u6e21\u91d1\u5c5e\u590d\u5408\u9634\u6781\u5177\u6709\u8f83\u4f4e\u7684\u91cd\u91cf\u5bb9\u91cf\uff08<200 mA h g-1<\/sup>\uff09\uff0c\u56e0\u6b64\u5728\u6ee1\u8db3\u9ad8\u91cd\u91cf\u7535\u6c60\u7cfb\u7edf\u7684\u9700\u6c42\u65b9\u9762\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u56e0\u6b64\uff0c\u9ad8\u5bb9\u91cf\u9634\u6781\u6750\u6599\u662f\u63d0\u9ad8LIBs\u6027\u80fd\u7684\u7406\u60f3\u6750\u6599\u3002\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u76f8\u6bd4\uff0c\u6709\u673a\u6750\u6599\u5177\u6709\u66f4\u5438\u5f15\u4eba\u7684\u7279\u6027\uff0c\u5305\u62ec\u751f\u6001\u9ad8\u6548\u7684\u751f\u4ea7\u548c\u5904\u7f6e\u3001\u6210\u672c\u6548\u76ca\u548c\u6709\u9002\u5f53\u6750\u6599\u8bbe\u8ba1\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3002\u7136\u800c\uff0c\u975e\u6c34\u7535\u89e3\u8d28\u7684\u6eb6\u89e3\u6027\u548c\u5c0f\u5206\u5b50\u672c\u8eab\u7684\u4f4e\u7535\u5bfc\u7387\u4e25\u91cd\u963b\u788d\u4e86\u5b83\u4eec\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5728LIBs\u4e2d\u7684\u5e94\u7528\u3002\u8fd1\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u4f5c\u4e3a\u4e00\u79cd\u7531\u6709\u673a\u8fde\u63a5\u4f53\u548c\u91d1\u5c5e\u8282\u70b9\u6784\u6210\u7684\u65b0\u578b\u7ed3\u6676\u6027\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\uff0c\u7531\u4e8e\u5176\u521a\u6027\u548c\u5916\u5ef6\u7ed3\u6784\uff0c\u4f7f\u5176\u4e0d\u6eb6\u4e8e\u6709\u673a\u7535\u89e3\u8d28\uff0c\u5f15\u8d77\u4e86\u4eba\u4eec\u5bf9\u5176\u7535\u5316\u5b66\u50a8\u80fd\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6709\u673a\u6865\u63a5\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\/\u7c07\u7684\u591a\u6837\u6027\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u8c03\u6574MOFs\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0c\u56fa\u6709\u7684\u591a\u5b54\u901a\u9053\u4f7f\u79bb\u5b50\u8fd0\u8f93\u548c\u7535\u89e3\u8d28\u6e17\u900f\u53d8\u5f97\u5bb9\u6613\u3002\u8fd9\u4e9b\u4f18\u70b9\u4f7fMOFs\u6210\u4e3a\u6781\u6709\u524d\u9014\u7684LIBs\u7535\u6781\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u5929\u6d25\u5927\u5b66\u9648\u9f99\u6559\u6388\u3001\u8bb8\u8fd0\u534e\u6559\u6388<\/b><\/strong>\u548c\u7f8e\u56fd\u5e03\u9c81\u514b\u9ed1\u6587\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u80e1\u6069\u6e90\u56e2\u961f<\/b><\/strong>\uff08<\/b><\/strong>\u5171\u540c<\/b><\/strong>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u5728\u975e\u5e38\u6e29\u548c\u548c\u7eff\u8272\u7684\u6761\u4ef6\u4e0b\u5408\u6210\u4e862D\u7684\u94dc\u82ef\u5e76\u918c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff082D Cu-THQ MOF\uff09\u3002\u8fd9\u79cd\u6750\u6599\u6210\u672c\u4f4e\u3001\u73af\u5883\u53cb\u597d\uff0c\u56e0\u4e3a\u6709\u673a\u8fde\u63a5\u5242\u53ef\u4ee5\u4ece\u81ea\u7136\u8d44\u6e90\u4e2d\u83b7\u5f97\uff0c\u5e76\u4e14\u94dc\u662f\u4e00\u79cd\u4e30\u5bcc\u7684\u91d1\u5c5e\u5143\u7d20\u3002\u6b64\u5916\uff0c2D\u5171\u8f6dCu-THQ MOF\u7684\u5b54\u9699\u7387\u548c\u534a\u5bfc\u4f53\u7279\u6027\u6709\u5229\u4e8e\u7535\u8377\u4f20\u8f93\u548c\u80fd\u91cf\u5b58\u50a8\u30022D Cu-THQ MOF\u5177\u6709\u524d\u6240\u672a\u6709\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff08> 350 mA hg-1<\/sup>\uff09\u548c\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5168\u9762\u7684\u5149\u8c31\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u79cd\u9ad8\u5bb9\u91cf\u5f97\u76ca\u4e8e\u4e00\u79cd\u65b0\u7684\u50a8\u9502\u673a\u5236\uff0c\u8be5\u673a\u5236\u6d89\u53ca\u91d1\u5c5e\u79bb\u5b50\u548c\u914d\u4f53\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u3002\u8be5\u6210\u679c\u4ee5\u5c01\u9762\u6587\u7ae0\u9898\u4e3a\u201c<\/b><\/strong>A Redox-Active 2D Metal-Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Angewandte Chemie<\/b><\/strong>\u4e0a\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5929\u6d25\u5927\u5b66\u5316\u5b66\u7cfb\u7855\u58eb\u751f\u6c5f\u5f3a\uff0c\u6750\u6599\u5b66\u9662\u535a\u58eb\u751f\u718a\u4f69\u52cb\u3002<\/p>\n

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\u00a0<\/b><\/strong>\u56fe2 <\/b><\/strong>2D Cu-THQ MOF\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff090.1 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\u3002<\/p>\n

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\u56fe3 <\/b><\/strong>2D Cu-THQ MOF\u7535\u6781<\/b><\/strong>\u7684\u5149\u8c31\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

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\u56fe4 <\/b><\/strong>2D Cu-THQ MOF\u7684\u5404\u79cd\u4e0d\u540c\u5145\u653e\u7535\u8fc7\u7a0b<\/b><\/strong>\"\"<\/p>\n

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\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

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\u00a0<\/b><\/strong>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>A Redox<\/u>–<\/u>Active 2D Metal<\/u>–<\/u>Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity<\/u><\/a>\uff08Angewandte Chemie\uff0c 2020\uff0cDOI:10.1002\/ange.201914395\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd<\/b>\u3011<\/p>\n

\u5929\u6d25\u5927\u5b66\u5316\u5b66\u7cfb\u9648\u9f99<\/strong>\u8bfe\u9898\u7ec4\u957f\u671f\u81f4\u529b\u4e8e\u65b0\u578b\u6709\u673a\u591a\u5b54\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u548c\u5e94\u7528\u63a2\u7a76\uff0c\u5728\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\uff082017YFA0207500\uff09\u7684\u5927\u529b\u652f\u6301\u4e0b\uff0c\u8bfe\u9898\u7ec4\u56f4\u7ed5\u4e8c\u7ef4\u5171\u8f6d\u9ad8\u5206\u5b50\u7684\u5236\u5907\uff0c\u8f93\u8fd0\u6027\u8d28\u8c03\u63a7\u53ca\u5fae\u7eb3\u5668\u4ef6\u6784\u7b51\u5f00\u5c55\u5de5\u4f5c\uff0c\u8fd1\u5e74\u6765\u5728\u4e8c\u7ef4\u5171\u8f6d\u9ad8\u5206\u5b50\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u4ee5\u53ca\u65b0\u7684\u5408\u6210\u7b56\u7565\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u8fdb\u5c55\uff0c\u76f8\u5173\u6210\u679c\u53d1\u8868\u5728J.<\/i><\/em>\u00a0<\/i><\/em>Am.<\/i><\/em>\u00a0<\/i><\/em>Chem.<\/i><\/em>\u00a0<\/i><\/em>Soc.<\/i><\/em>, 2019<\/b><\/strong>, 141<\/i><\/em>, 13822\uff1bAdv<\/i><\/em>. Mater. <\/i><\/em>2019<\/b><\/strong>, 31<\/i><\/em>, 1901640; Chem. Mater. <\/i><\/em>2019<\/b><\/strong>, 31<\/i><\/em>, 8100;\u00a0Macromolecules<\/i><\/em>\u00a02019<\/b><\/strong>, 52<\/i><\/em>, 7977; Angew. Chem. Int. Ed.<\/i><\/em>, 2019<\/b><\/strong>, 58<\/i><\/em>,\u00a015742\uff1bAngew. Chem. Int. Ed.<\/i><\/em>, 2020<\/b><\/strong>, 59<\/i><\/em>, 1081\uff1bAngew. Chem. Int. Ed<\/i><\/em>., 2020<\/b><\/strong>, 59<\/i><\/em>, 1118\u3002<\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec\u4f9b\u7a3f<\/b><\/strong>\u3002<\/p>\n

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