{"id":195945,"date":"2020-02-22T06:08:44","date_gmt":"2020-02-21T22:08:44","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=195945"},"modified":"2020-02-21T21:09:09","modified_gmt":"2020-02-21T13:09:09","slug":"%e8%b7%9f%e9%9a%8f%e8%bf%99%e4%ba%9b%e6%96%87%e7%8c%ae%ef%bc%8c%e4%b8%80%e8%b5%b7%e5%8e%bb%e4%ba%86%e8%a7%a3%e5%87%a0%e7%a7%8d%e5%82%a8%e8%83%bd%e7%94%b5%e6%b1%a0%e7%9a%84%e8%bf%9b%e5%b1%95%e5%90%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=195945","title":{"rendered":"\u8ddf\u968f\u8fd9\u4e9b\u6587\u732e\uff0c\u4e00\u8d77\u53bb\u4e86\u89e3\u51e0\u79cd\u50a8\u80fd\u7535\u6c60\u7684\u8fdb\u5c55\u5427"},"content":{"rendered":"

\u9502\u79bb\u5b50\u7535\u6c60\u5df2\u7ecf\u88ab\u8bc1\u660e\u662f\u6700\u6709\u5f71\u54cd\u529b\u7684\u7535\u6c60\u6280\u672f\uff0c\u5b83\u4eec\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u3001\u7535\u52a8\u5de5\u5177\u3001\u548c\u7535\u52a8\u6c7d\u8f66\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c2019\u5e74\u8bfa\u8d1d\u5c14\u5956\u5316\u5b66\u5956\u6388\u4e88\u4e86\u4e09\u4f4d\u6770\u51fa\u7684\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u4e13\u5bb6\uff0c\u5373 John B. Goodenough, M. Stanley Whittingham\u548cAkira Yoshino\u3002\u7136\u800c\uff0c\u9502\u7684\u4e30\u5ea6\u6709\u9650\uff0c\u53ef\u80fd\u6ca1\u6709\u8db3\u591f\u7684Li\u8d44\u6e90\u7528\u4e8e\u7535\u7f51\u80fd\u6e90\u5b58\u50a8\u548c\u7535\u52a8\u6c7d\u8f66\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65b0\u4e00\u4ee3\u53ef\u5145\u7535\u7535\u6c60\u540c\u6837\u81f3\u5173\u91cd\u8981\u3002\u4e8e\u6b64\uff0c\u5c0f\u7f16\u901a\u8fc7\u68c0\u7d22\u6587\u732e\uff0c\u6311\u9009\u4e86\u51e0\u7bc7\u6709\u4ee3\u8868\u6027\u7684\u6587\u732e\uff0c\u548c\u5927\u5bb6\u4e00\u8d77\u4e86\u89e3\u51e0\u79cd\u50a8\u80fd\u7535\u6c60\u7684\u5f00\u53d1\u60c5\u51b5\u3002<\/p>\n

1\u3001<\/b><\/strong>Al\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

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\u5177\u6709\u6cb8\u77f3\u7684\u6027\u80fd\u548c\u591a\u79cd\u4ef7\u6001\u7684\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\uff0c\u666e\u9c81\u58eb\u84dd\uff08PBAs\uff09\u53ef\u4ee5\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5feb\u901f\u53d6\u4ee3\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u7684\u78b1\u91d1\u5c5e\u79bb\u5b50\uff0c\u5b9e\u73b0\u5feb\u901f\u5145\u653e\u7535\uff0c\u5e76\u5e94\u7528\u4e8e\u4e8c\u6b21\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u3002PBAs\u5177\u6709\u4e09\u7ef4(3D)\u5f00\u653e\u5f0f\u6846\u67b6\u7ed3\u6784\u548c\u79bb\u5b50\u8fc1\u79fb\uff0c\u5236\u9020\u5de5\u827a\u7b80\u5355\uff0c\u7535\u5316\u5b66\u6d3b\u6027\u826f\u597d\uff0c\u5176\u5728\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u65b9\u9762\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002<\/p>\n

Pang\u7b49\u4eba[1]<\/sup>\u521b\u9020\u6027\u5730\u5229\u7528\u6c34\u70ed\u6cd5\u548c\u4f4e\u6e29\u7145\u70e7\u8fc7\u7a0b\uff0c\u5408\u6210\u4e86\u516d\u6c30\u9178\u94b4\u94beK2<\/sub>CoFe(CN)6<\/sub>\u7eb3\u7c73\u6676\u3002\u4e0e\u4e4b\u524d\u7684\u65e0\u5e8f\u5206\u6563\u7684PBAs\u5bf9\u6bd4\uff0cK2<\/sub>CoFe(CN)6<\/sub>\u7684\u7ed3\u6784\u5c3a\u5bf8\u5747\u5300\uff0c\u7ed3\u6784\u7d27\u51d1\u5f62\u6210\u4e00\u4e2a\u7c7b\u4f3c\u4e2d\u56fd\u4f20\u7edf\u5efa\u7b51\u7ed3\u6784\u7684\u6bdb\u523a\u62fc\u56fe\u6846\u67b6\u3002\u8003\u8651\u5230\u7535\u5b50\u5bfc\u7535\u6027\uff0c\u8fd9\u6837\u4e00\u4e2a\u9ad8\u5ea6\u5806\u53e0\u7684PBA\u7ed3\u6784\u4e0d\u4ec5\u5927\u5927\u964d\u4f4e\u4e86\u79bb\u5b50\u8fc1\u79fb\u65f6\u95f4\uff0c\u63d0\u9ad8\u4e86\u7535\u5316\u5b66\u6d3b\u6027\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u7814\u7a76K2<\/sub>CoFe(CN)6<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5236\u5907\u4e86\u4ee5K2<\/sub>CoFe(CN)6<\/sub>\u4e3a\u5de5\u4f5c\u7535\u6781\u548c\u4ee51 M Al(NO3<\/sub>)3<\/sub>\u4e3a\u7535\u89e3\u6db2\u7684\u94dd\u79bb\u5b50\u7535\u6c60\uff0c\u5e76\u8fdb\u884c\u4e86\u7535\u5316\u5b66\u6d4b\u8bd5\u3002\u5236\u5907\u7684K2<\/sub>CoFe(CN)6<\/sub>\u7535\u6781\u6750\u6599\u7684\u53ef\u9006\u653e\u7535\u5bb9\u91cf\u4e3a50mAh\/g\uff0c\u57280.1 A\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa\u7406\u60f3\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe1. K2<\/sub>CoFe(CN)6<\/sub>\u7535\u6781\u6750\u6599\u7684\u8868\u5f81\u7ed3\u679c[1]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. \u4ee5K2<\/sub>CoFe(CN)6<\/sub>\u4e3a\u5de5\u4f5c\u7535\u6781\u548c\u4ee51 M Al(NO3<\/sub>)3<\/sub>\u4e3a\u7535\u89e3\u6db2\u7684\u94dd\u79bb\u5b50\u7535\u6c60\u6027\u80fd[1]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

2\u3001Li-CO<\/b><\/strong>2<\/b><\/sub><\/strong>\/O<\/b><\/strong>2<\/b><\/sub><\/strong>\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\u6700\u8fd1\uff0cLi-CO2<\/sub>\/O2<\/sub>\u7535\u6c60\u53d7\u5230\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u5b83\u4e0d\u4ec5\u4ec5\u5177\u6709\u6bd4\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u66f4\u9ad8\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff0c\u540c\u65f6\u4e5f\u662f\u4e00\u79cd\u6709\u6548\u5229\u7528\u4e8c\u6c27\u5316\u78b3\u7684\u65b9\u6cd5\u3002\u5f62\u6210\u56fa\u4f53Li2<\/sub>CO3<\/sub>\u662f\u4e8c\u6c27\u5316\u78b3\u57fa\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4e00\u4e2a\u666e\u904d\u4e8b\u4ef6\u3002\u5f53\u4e8c\u6c27\u5316\u78b3\u548c\u6c27\u6c14\u7684\u6df7\u5408\u7269\u4f5c\u4e3a\u7535\u6c60\u9634\u6781\u7684\u539f\u6599\uff0c\u653e\u7535\u8fc7\u7a0b\u4e3a4Li+<\/sup>\u00a0+ 2CO2<\/sub>\u00a0+O2<\/sub>+ 4e\u00a0–<\/sup>\u21922Li2<\/sub>CO3<\/sub>\u3002\u56e0\u6b64\uff0c\u6709\u6548\u5206\u89e3Li2<\/sub>CO3<\/sub>\u7684\u662f\u786e\u4fdd\u4e8c\u6c27\u5316\u78b3\u57fa\u7535\u6c60\u6027\u80fd\u7684\u5173\u952e\u56e0\u7d20\u3002\u4e3a\u4e86\u6709\u5229\u4e8eLi2<\/sub>CO3<\/sub>\u7684\u5206\u89e3\uff0c\u91c7\u7528\u4e00\u4e9b\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\uff0c\u5982\u5355\u6838\u548c\u53cc\u6838\u94b4\u915e\u83c1\u662f\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\u3002\u6b63\u6781\u50ac\u5316\u5242\u4f5c\u4e3a\u7535\u6c60\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u8d77\u7740\u4fc3\u8fdbLi2<\/sub>CO3<\/sub>\u5206\u89e3\u7684\u91cd\u8981\u4f5c\u7528\u3002\u5305\u62ecCNT\u548crGO\u7684\u78b3\u50ac\u5316\u5242, \u91d1\u5c5e\u6c27\u5316\u7269\u5982NiO\u548cMn2<\/sub>O3<\/sub>\uff0c\u8d35\u91d1\u5c5e\u5982Ru\u548cIrO2<\/sub>\uff0c\u90fd\u53ef\u4f5c\u4e3a\u5206\u89e3Li2<\/sub>CO3<\/sub>\u7684\u6b63\u6781\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u5728\u5b9e\u9645\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\u8fd8\u8fdc\u8fdc\u4e0d\u80fd\u4ee4\u4eba\u6ee1\u610f\u3002\u56e0\u6b64\uff0c\u5fc5\u987b\u8fd9\u5f00\u53d1\u9ad8\u6548\u3001\u7a33\u5b9a\u7684Li2<\/sub>CO3<\/sub>\u5206\u89e3\u6b63\u6781\u50ac\u5316\u5242\u3002\u53e6\u4e00\u4e2a\u5bc6\u5207\u76f8\u5173\u7684\u95ee\u9898\uff0c\u4ecb\u89c2\u5c3a\u5ea6\u548c\u5fae\u89c2\u5c3a\u5ea6\u7684\u754c\u9762\u5de5\u7a0b\u5df2\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u8c03\u5236\u5c40\u90e8\u7535\u5b50\u7ed3\u6784\u548c\u50ac\u5316\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002\u7279\u522b\u662f\u4e0e\u4e0d\u540c\u5316\u5b66\u7269\u8d28\u7ec4\u6210\u548c\u5f3a\u5ea6\u7684\u4ecb\u89c2\u5c3a\u5ea6\u56fa-\u56fa\u754c\u9762\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u901a\u8fc7\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5c3a\u5bf8\u53ef\u63a7\u5408\u6210\u548c\/\u6216\u7ed3\u6784\u5de5\u7a0b\u5b9e\u73b0\u3002<\/p>\n

Sun\u7b49[2]<\/sup>\u62a5\u9053\u901a\u8fc7Ru\u4e0eNiO\u7684\u534f\u540c\u50ac\u5316\u4f5c\u7528\u4fc3\u8fdbLi2<\/sub>CO3<\/sub>\u7535\u5316\u5b66\u5206\u89e3\uff0c\u5f97\u5230\u7684Li-CO2 <\/sub>\/O2<\/sub>\u7535\u6c60\u5177\u6709\u5353\u8d8a\u7684\u5faa\u73af\u6027\u80fd\u3002Ru\/NiO@Ni\/CNT\u50ac\u5316\u5242\u91c7\u7528CNT\u652f\u6491\u5916\u58f3\u8986\u76d6\u4e00\u5c42\u8584\u8584NiO\u768422nm\u7684Ni\u7eb3\u7c73\u9897\u7c92\uff0c2.5nm\u7684\u8d85\u7ec6Ru\u7eb3\u7c73\u9897\u7c92\u88ab\u8fdb\u4e00\u6b65\u56fa\u5b9a\u5728Ni\u7eb3\u7c73\u9897\u7c92\u4e0a\u3002\u89c2\u5bdf\u5230\u4e24\u79cd\u91d1\u5c5e\u4e4b\u95f4\u5f3a\u70c8\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd9\u79cd\u542bRu\/NiO@Ni\/CNT\u50ac\u5316\u5242\u7684Li-CO2<\/sub>\u00a0\/O2<\/sub>\u7535\u6c60\u5177\u6709\u591a\u79cd\u4f18\u70b9\uff0c\u5982\u8f83\u4f4e\u8fc7\u7535\u4f4d\u548c\u6781\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u622a\u6b62\u5bb9\u91cf\u4e3a1000mAh\/g\uff0c\u5faa\u73af105\u5468\uff0c\u8fc7\u7535\u4f4d\u4e3a1.01V\u3002\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff0c\u5bf9RuO2<\/sub>\u8f85\u52a9\u4e0b\u7684Li2<\/sub>CO3<\/sub>\u7535\u5316\u5b66\u5206\u89e3\u8fc7\u7a0b\u8fdb\u884c\u8ba1\u7b97\uff0c\u7ed3\u679c\u8868\u660eO2<\/sub>\u7684\u751f\u6210\u4e3a\u901f\u7387\u51b3\u5b9a\u6b65\u9aa4\u3002<\/p>\n

\u56fe3. Ru\/NiO@Ni\/CNT\u50ac\u5316\u5242\u7684\u8868\u5f81[2]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u5728\u6240\u5408\u6210\u7684Ru\/NiO@Ni\/CNT\u50ac\u5316\u5242\u4e2d\uff0c\u4e00\u7ef4CNTs\u76f8\u4e92\u4ea4\u8054\u3002\u76f4\u5f84\u4e3a2.5nm\u7684\u8d85\u7ec6Ru\u7eb3\u7c73\u9897\u7c92\u5747\u5300\u9644\u7740\u5728Ni\u548cCNTs\u7684\u8868\u9762\u3002HRTEM\u56fe\u50cf\u4e2d\u6676\u683c\u95f4\u8ddd\u4e3a0.215nm\uff0c0.203nm\u548c0.242nm\u5bf9\u5e94Ru(002)\uff0cNi(111)\u548cNiO(111)\u6676\u9762\u3002<\/p>\n

\u56fe4. \u91c7\u7528\u4e0d\u540c\u50ac\u5316\u5242\u7684Li-CO2 <\/sub>\/O2<\/sub>\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4[2]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u7ec4\u88c5\u4e86Li-CO2 <\/sub>\/O2<\/sub>\uff08V:V=4:1\uff09\u7535\u6c60\u8003\u5bdf\u4e0d\u540c\u50ac\u5316\u5242\u5bf9Li2<\/sub>CO3<\/sub>\u7684\u7535\u5316\u5b66\u5206\u89e3\u6027\u80fd\u3002\u5bf9\u4e8eRu\/NiO@Ni\/CNT\u50ac\u5316\u5242\uff0cCV\u66f2\u7ebf\u4e2dLi2<\/sub>CO3<\/sub>\u7684\u5f62\u6210\u5cf0\u4f4d\u4e8e2.64V\uff0c\u800cRu\/CNT\uff0cNiO@Ni\/CNT\u548cCNT\u7684Li2<\/sub>CO3<\/sub>\u5f62\u6210\u5cf0\u4f4d\u4e8e2.3V\uff0c\u8868\u660e\u524d\u8005\u66f4\u5bb9\u6613\u5f62\u6210Li2<\/sub>CO3<\/sub>\u3002CV\u6b63\u626b\u65f6\uff0cRu\/NiO@Ni\/CNT\u50ac\u5316\u5242\u57284.27V\u51fa\u73b0\u6c27\u5316\u5cf0\uff0c\u51fa\u5cf0\u4f4d\u7f6e\u6bd4\u5176\u4ed6\u4e09\u79cd\u50ac\u5316\u5242\u4f4e\uff0c\u8fdb\u4e00\u6b65\u8868\u660e\u5176\u5177\u6709\u4f18\u79c0\u7684\u50ac\u5316Li2<\/sub>CO3<\/sub>\u53d1\u751f\u7535\u5316\u5b66\u5206\u89e3\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f7f\u7528Ru\/NiO@Ni\/CNT\u50ac\u5316\u5242\u65f6\uff0c\u7535\u6c60\u53ef\u4ee5\u5e73\u7a33\u5faa\u73af105\u6b21\uff0c\u8d85\u8fc7\u4e86\u5176\u4ed63\u7ec4\u5bf9\u7167\u7ec4\u3002<\/p>\n

3\u3001Li\/Na-H<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60<\/b><\/strong><\/p>\n

Zhao\u7b49[3]<\/sup>\u62a5\u9053\u4e86\u4e00\u79cd\u5177\u6709\u201c\u9633\u79bb\u5b50\u5bfc\u7535\u201d\u4e0e\u201c\u6eb6\u5242\u5206\u5b50\u963b\u585e\u201d\u7684\u53cc\u91cd\u529f\u80fd\u805a\u5408\u819c\uff0c\u53ef\u7528\u5728\u91c7\u7528\u6df7\u5408\u7535\u89e3\u8d28\u914d\u7f6e\u7684\u7535\u6c60\u4e0a\u3002\u8fd9\u79cd\u805a\u5408\u7269\u662f\u901a\u8fc7\u7528\u7fa7\u57fa\u4fee\u9970\u4e00PIM\u805a\u5408\u7269(PIM -1)\u6765\u5236\u5907\u7684\u3002\u6539\u6027\u4e0d\u4ec5\u5728PIM-\u4e2d\u5f15\u5165\u4e86\u9633\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u8fd8\u53ef\u5c06\u6709\u6548\u5b54\u9699\u5927\u5c0f\u964d\u81f3\u6700\u4f18\u503c(\u00010.8 nm)\uff0c\u4ece\u800c\u6392\u9664\u6eb6\u5242\u5206\u5b50\u901a\u8fc7\u3002\u4ee5\u7fa7\u57fa-\u6539\u6027\u805a\u4e19\u70ef\u9170\u80fa\u4e3a\u539f\u6599\u5236\u5907\u7684\u819c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6eb6\u5242\u5206\u5b50\u5835\u585e\u80fd\u529b\uff0c\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u7a33\u5b9a\u6027\u597d\u3002\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u6db2\u6ef4\u6a21\u677f\u6cd5\u5728\u819c\u7684\u4e24\u4fa7\u4ea7\u751f\u5927\u5b54\uff0c\u8fd9\u79cd\u7ed3\u6784\u589e\u52a0\u4e86\u819c\u4e0e\u7535\u89e3\u8d28\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u65b9\u4fbf\u4e86\u79bb\u5b50\u8fd0\u8f93\u3002\u968f\u540e\u4f5c\u8005\u4f7f\u7528\u8fd9\u79cd\u819c\u6765\u6784\u5efaLi\/Na – H2<\/sub>O2<\/sub>\u7535\u6c60\uff0c\u5176\u4e2d\u6d3b\u6027\u78b1\u91d1\u5c5e(Li\u6216Na)\u4f5c\u4e3a\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u7684\u9633\u6781\uff0c\u9634\u6781\u4e3a\u6c34\u6eb6\u6db2\u7535\u89e3\u8d28\u4e2d\u7684\u5f3a\u6c27\u5316\u5242(H2<\/sub>O2<\/sub>)\u3002H2<\/sub>O\u6216H2<\/sub>O2<\/sub>\u4ece\u9634\u6781\u4fa7\u5411\u9633\u6781\u4fa7\u53d1\u751f\u7684\u4efb\u4f55\u6e17\u900f\u73b0\u8c61\uff0c\u90fd\u4f1a\u5bfc\u81f4\u9502\u91d1\u5c5e\u8150\u8680\u548c\u7535\u6c60\u5931\u6548\u3002\u5177\u6709\u963b\u6321\u6eb6\u5242\u5206\u5b50\u548c\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u7684PIM-1\u819c\uff0c\u4fdd\u8bc1\u4e86\u6709\u673a\/\u6c34\u6df7\u5408\u7535\u89e3\u8d28\u7535\u6c60\u7684\u53ef\u518d\u751f\u3002 \u00a0\u00a0\u00a0<\/p>\n

\u56fe5.<\/p>\n

\"\"<\/p>\n

(a) PIM-1\u548cPIM-1-COOM (M=Li\u6216Na)\u7684\u5408\u6210\u8def\u7ebf\u548c\u5316\u5b66\u7ed3\u6784\u3002(b-d) \u91c7\u7528\u6db2\u6ef4\u6a21\u677f\u6cd5\uff0c\u5728PIM-1-COOM\u819c\u7684\u4e24\u4e2a\u8868\u9762\u4e0a\u4ea7\u751f\u5927\u5b54\u7684\u7b56\u7565\u3002(e-h)PIM-1-COOM\u819c\u5728\u6298\u53e0\u548c\u5c55\u5f00\u7684\u72b6\u6001\uff0c\u663e\u793a\u5176\u7075\u6d3b\u6027[3]<\/sup>\u3002<\/p>\n

\u56fe6.Li\/Na -H2<\/sub>O2<\/sub>\u7535\u6c60\u793a\u610f\u56fe\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd[3]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u5176\u4e2d\uff0c\u9634\u6781\u53cd\u5e94\u4e3aH2<\/sub>O2 <\/sub>+ 2e\u21922OH\uff0c\u9633\u6781\u53cd\u5e94\u4e3aLi (Na)\u2192Li (Na)+<\/sup>\u00a0+ e\uff1b\u603b\u53cd\u5e94\u4e3aLi (Na) + H2<\/sub>O2<\/sub>\u2192Li (Na)OH[3]<\/sup>\u3002<\/p>\n

\u6052\u7535\u6d41\u653e\u7535\u6d4b\u8bd5\u8868\u660e\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1mA\/cm2<\/sup>\u65f6\uff0cLi-H2<\/sub>O2<\/sub>\u7535\u6c60\u7684\u8f93\u51fa\u7535\u538b\u4e3a3.2V\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\u81f30.3mA\/cm2<\/sup>\u65f6\uff0c\u8f93\u51fa\u7535\u538b\u7565\u5fae\u4e0b\u964d\u81f33.0V\u3002\u4e3a\u4e86\u5bf9\u6bd4\u7814\u7a76\uff0c\u7ec4\u88c5\u4e86\u4ee5LISICON\u819c\u4e3a\u9694\u819c\u7684\u53e6\u4e00\u79cd\u7535\u6c60\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4ece\u653e\u7535\u7535\u538b\u89d2\u5ea6\u770b\uff0c\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u65f6PIM-1-COOLi\u7684\u6027\u80fd\u751a\u81f3\u7565\u5fae\u597d\u4e8eLISICON\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5c3d\u7ba1LISICON\u5177\u6709\u9502\u79bb\u5b50\u4f20\u8f93\u548c\u6eb6\u5242\u963b\u9694\u7684\u53cc\u91cd\u7279\u6027\uff0c\u4f46\u662f\u5b83\u5728\u5f3a\u78b1\u6216\u5f3a\u9178\u4e0b\u4e0d\u7a33\u5b9a\uff0c\u673a\u68b0\u67d4\u97e7\u6027\u5dee\uff0c\u8fd9\u4e5f\u5c31\u9650\u5236\u4e86\u5b83\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5f53LISICON\u819c\u7ecf\u8fc7\u5f2f\u66f2\u540e\uff0c\u4ea7\u751f\u7684\u88c2\u7eb9\u964d\u4f4e\u4e86\u963b\u788d\u6c34\u6e17\u900f\u7684\u963b\u529b\uff0c\u5bfc\u81f4\u6700\u7ec8\u51fa\u73b0\u5b89\u5168\u95ee\u9898\u3002\u76f8\u53cd\uff0cPIMs\u5373\u4f7f\u7ecf\u8fc7\u4e25\u82db\u7684\u6298\u53e0\u4ecd\u7136\u5177\u6709\u7a33\u5b9a\u7684\u67d4\u97e7\u6027\u3002\u6052\u7535\u6d41\u653e\u7535\u6d4b\u8bd5\u4e5f\u8868\u660e\u5728\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u4e3a0.1\u548c0.3mA\/cm2<\/sup>\u65f6\uff0cNa-H2<\/sub>O2<\/sub>\u7535\u6c60\u7684\u8f93\u51fa\u7535\u538b\u5206\u522b\u4e3a2.75V\u548c2.50V\u3002<\/p>\n

4\u3001\u9499\u7535\u6c60<\/b><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u5bf9\u9499\u91d1\u5c5e\u7535\u6c60\u4ea7\u751f\u4e86\u7814\u7a76\u7684\u5174\u8da3\u3002\u9499\u91d1\u5c5e\u5177\u6709\u63a5\u8fd1Li\u7684\u8fd8\u539f\u7535\u4f4d(+ 0.172 V vs. Li)\uff0cCa2+<\/sup>\/Ca\u7535\u5bf9\u4e5f\u5177\u6709\u660e\u663e\u4f18\u52bf\uff0c\u9499\u662f\u5730\u58f3\u4e2d\u7b2c\u4e94\u4e30\u5bcc\u7684\u5143\u7d20\uff0c\u5177\u6709\u5b89\u5168\u3001\u65e0\u6bd2\u3001\u6210\u672c\u4f4e\u7b49\u4f18\u70b9\u3002\u9499\u7684\u91cd\u91cf\u6bd4\u5bb9\u91cf\u4e3a1337 mAh\/g\uff0c\u4f53\u79ef\u6bd4\u5bb9\u91cf\u4e3a2099 mA h\/ cm3<\/sup>\u3002\u4e0e\u6807\u51c6\u6c22\u7535\u6781(SHE)\u76f8\u6bd4\uff0c\u8fd8\u539f\u7535\u4f4d\u4e3a-2.87V\uff0c\u63a5\u8fd1Li (-3.04 V vs. SHE)\uff0c\u800c\u6bd4Mg (-2.37 V vs. SHE)\u4f4e0.5 V\u3002\u56e0\u6b64\uff0cCa\u7535\u6c60\u7684\u7535\u6c60\u7535\u538b\u548c\u80fd\u91cf\u5bc6\u5ea6\u53ef\u80fd\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u5f53\uff0c\u6bd4Mg\u7535\u6c60\u8981\u9ad8\u3002\u53e6\u5916\uff0cCa2+<\/sup>\u79bb\u5b50\u7684\u534a\u5f84(0.112nm)\u6bd4Mg2+<\/sup>\u79bb\u5b50\u7684\u534a\u5f84(0.072 nm)\u5927\uff0c\u540c\u65f6\u643a\u5e26\u76f8\u540c\u7684\u7535\u8377\uff0cCa2+<\/sup>\u79bb\u5b50\u5728\u9634\u6781\u4e2d\u7684\u6269\u6563\u53ef\u80fd\u66f4\u5feb\u3002\u56e0\u6b64\uff0c\u53ef\u5145\u7535Ca\u7535\u6c60\u53ef\u89c6\u4e3a\u6700\u6709\u5438\u5f15\u529b\u7684\u540e\u9502\u79bb\u5b50\u7535\u6c60\u6280\u672f\u5019\u9009\u3002\u7136\u800c\uff0cCa\u7535\u6c60\u7684\u53d1\u5c55\u56e0\u4e3a\u7f3a\u4e4f\u5408\u9002\u7684\u7535\u89e3\u8d28\u800c\u53d7\u5230\u4e86\u963b\u788d\u3002<\/p>\n

Karger\u7b49[4]<\/sup>\u53d7Mg\u7535\u89e3\u8d28\u7684\u542f\u53d1\uff0c\u5f00\u53d1\u4e86Ca[B(hfip)4<\/sub>]2<\/sub>\uff08\u5168\u79f0\uff1acalcium tetrakis(hexafluoroisopropyloxy)borate \uff09\u7535\u89e3\u8d28\u3002\u5c06Ca(BH4<\/sub>)2<\/sub>\u4e0e\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7(DME)\u4e2d\u7684\u516d\u6c1f\u5f02\u4e19\u9187\u53cd\u5e94\u5236\u5f97Ca[B(hfip)4<\/sub>]2<\/sub>\u3002\u53ef\u4ee5\u4ece\u672a\u6405\u62cc\u7684\u6d53\u7f29DME\u6eb6\u6db2\u4e2d\u5206\u79bb\u5f97\u5230\u5355\u6676\u3002X\u5c04\u7ebf\u5355\u6676\u5206\u6790\u8bc1\u5b9e\u5355\u6676\u4e3aCa[B(hfip)4<\/sub>]2\u00b7<\/sub>4DME\u3002<\/p>\n

\u56fe7. Ca[B(hfip)4<\/sub>]2<\/sub>\u7535\u89e3\u8d28\u7684\u5408\u6210\u793a\u610f\u56fe\u548c Ca[B(hfip)4<\/sub>]2\u00b7<\/sub>4DME\u7684X\u5c04\u7ebf\u5355\u6676[4]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8.\u00a0<\/p>\n

\"\"<\/p>\n

(a) Ca[B(hfip)4<\/sub>]2<\/sub>\/DME\u7535\u89e3\u8d28\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002(b)\u57280.2mA\/cm2<\/sup>\u4e0b\u7684\u5178\u578b\u7535\u538b\u66f2\u7ebf[4]<\/sup>\u3002<\/p>\n

Ca[B(hfip)4<\/sub>]2<\/sub>\/DME\u7535\u89e3\u8d28\u57280.1\u548c0.2mA\/cm2<\/sup>\u65f6\u7684\u6781\u5316\u7535\u52bf\u5206\u522b\uff1c60mV\u548c\uff1c200mV\u3002\u57280.2mA\/cm2<\/sup>\u4e0b\u7684\u7535\u538b\u66f2\u7ebf\u5177\u6709\u5e73\u53f0\uff0c\u8868\u660e\u5b58\u5728\u5e73\u7f13\u7684Ca\u6c89\u79ef\/\u6eb6\u89e3\u8fc7\u7a0b\u3002\u8fdb\u4e00\u6b65\u589e\u5927\u7535\u6d41\u5bc6\u5ea6\u81f30.5mA\/cm2<\/sup>\uff0cCa\u6c89\u79ef\/\u6eb6\u89e3\u7684\u8fc7\u7535\u52bf\u589e\u5927\u81f3\uff1e500mV\u3002\u7136\u800c\uff0c\u00a0Ca[B(hfip)4<\/sub>]2<\/sub>\/DME\u7535\u89e3\u8d28\u5df2\u7ecf\u8fd0\u884c\u8d85\u8fc7\u4e86250h\uff0c\u8868\u660e\u5176\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n

5\u3001Zn-I<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60<\/b><\/strong><\/p>\n

\u53ef\u5145\u7535\u7684\u6c34\u6027\u950c\u57fa\u7535\u6c60\u662f\u5b89\u5168\u50a8\u80fd\u7684\u7406\u60f3\u9009\u62e9\uff0c\u8be5\u6280\u672f\u5177\u6709\u6210\u672c\u4f4e\u3001\u5bb9\u91cf\u5927\u3001\u7535\u4f4d\u5408\u9002\u3001\u5316\u5b66\u6027\u8d28\u7a33\u5b9a\u3001\u7535\u89e3\u8d28\u4e0d\u6613\u71c3\u7b49\u7279\u70b9\u3002\u5176\u4e2dZn-I2<\/sub>\u6db2\u6d41\u7535\u6c60\u56e0\u4e3a\u5176\u826f\u597d\u7684\u53ef\u9006\u6027\u548c\u9ad8\u80fd\u91cf\u6548\u7387(> 80%)\u800c\u6210\u4e3a\u6700\u6709\u5438\u5f15\u529b\u7684\u5019\u9009\u8005\u4e4b\u4e00\u3002\u4f46\u4f53\u79ef\u5927\u3001\u7ed3\u6784\u590d\u6742\u3001\u80fd\u91cf\u5bc6\u5ea6\u4e0d\u7406\u60f3\u548cNafion115\u819c\u4ef7\u683c\u6602\u8d35\u7b49\u7f3a\u70b9\uff0c\u9650\u5236\u4e86\u5b83\u7684\u5b9e\u9645\u5e94\u7528\u3002\u4e3a\u4e86\u907f\u514dZn-I2<\/sub>\u6db2\u6d41\u7535\u6c60\u6240\u9047\u5230\u7684\u7f3a\u70b9\uff0c\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u5177\u6709\u56fa\u4f53\u7535\u6781\u548c\u7d27\u51d1\u7ed3\u6784\u7684Zn-I2<\/sub>\u7535\u6c60\u3002\u7136\u800c\uff0c\u56fa\u4f53I2<\/sub>\u7684\u6eb6\u89e3\u5ea6\u9ad8\uff0c\u5bfc\u7535\u6027\u5dee\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u5c06I2<\/sub>\u5c01\u88c5\u5230\u5bfc\u7535\u591a\u5b54\u7684\u8f7d\u4f53\u4e2d\uff0c\u589e\u5f3a\u5b83\u7684\u5bfc\u7535\u6027\u5e76\u6291\u5236\u5176\u6eb6\u89e3\u662f\u975e\u5e38\u5408\u7406\u7684\u65b9\u6cd5\u3002\u4f8b\u5982\uff0c\u77f3\u58a8\u70ef\u6d82\u8986\u7684\u7898\u91cf\u5b50\u70b9\u4f5c\u4e3a\u975e\u6c34\u6027Na- I2<\/sub>\u7535\u6c60\u7684\u9634\u6781\uff0c\u5b9e\u73b0\u4e86\u975e\u5e38\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\u3002\u5c3d\u7ba1\u53d6\u5f97\u4e86\u4e00\u4e9b\u6210\u679c\uff0c\u4f46\u662f\u5305\u62ecI2<\/sub>\u8d1f\u8f7d\u91cf\u7684\u5f71\u54cd\u3001\u7535\u89e3\u8d28\u7684\u5dee\u5f02\u548c\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u5bf9\u7535\u5316\u5b66\u884c\u4e3a\u7684\u5f71\u54cd\u7b49\u5173\u952e\u95ee\u9898\u5c1a\u4e0d\u6e05\u695a\u3002<\/p>\n

\u5f71\u54cdZn-I2<\/sub>\u7535\u6c60\u5b9e\u9645\u5e94\u7528\u7684\u53e6\u4e00\u4e2a\u95ee\u9898\u662f\u7531\u4e8e\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86Zn\u679d\u6676\uff0c\u5bfc\u81f4Zn\u9634\u6781\u7684\u53ef\u5145\u7535\u6027\u5dee\u3002\u5e38\u7528\u7684\u6291\u5236\u950c\u679d\u6676\u7684\u65b9\u6cd5\u662f\u901a\u8fc7\u5c06Zn\u6c89\u79ef\u5230\u5bfc\u7535\u5bc4\u4e3b\u4e2d\u6765\u9650\u5236Zn\u7684\u751f\u957f\uff0c\u4f46\u8fd9\u6837\u505a\u4e0d\u80fd\u907f\u514d\u6df1\u5145\u653e\u7535\u65f6\u5f62\u6210\u950c\u679d\u6676\u3002\u6b64\u5916\uff0c\u950c\u5265\u79bb\/\u9540\u950c\u7684\u5e93\u4ed1\u6548\u7387\u4f4e\uff0c\u9700\u8981\u8fc7\u91cf\u7684\u950c\uff0c\u8fd9\u4f1a\u964d\u4f4e\u950c\u7684\u4f7f\u7528\u6548\u7387\u548c\u603b\u80fd\u91cf\u5bc6\u5ea6\u3002<\/p>\n

Li\u7b49[5]<\/sup>\u62a5\u544a\u4e86\u4e00\u79cd\u57fa\u4e8e\u6d3b\u6027\u70ad\u5c01\u88c5\u7684I2<\/sub>\u00a0(I2<\/sub>@ C -50)\u590d\u5408\u6750\u6599\u7684\u957f\u5bff\u547d\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60\u6c60\u3002\u7531\u4e8e\u8d1f\u79bb\u5b50CF3<\/sub>SO3<\/sub>–<\/sup>\u548cI2<\/sub>\u7684\u914d\u4f4d\u6548\u5e94\u4ee5\u53ca2 M Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0cI2<\/sub>@C-50\u9634\u6781\u7684\u52a8\u529b\u5b66\u548c\u6548\u7387\u6709\u660e\u663e\u6539\u5584\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u539f\u4f4d\u5f62\u6210\u7684SEI\u819c\uff0cZnI2<\/sub>\u548cZn\u8868\u9762\u7684Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u80fd\u663e\u8457\u7a33\u5b9aZn\u7684\u5265\u79bb\/\u7535\u9540\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u6d3b\u6027\u70ad\u7684\u5f3a\u5438\u9644\u4f5c\u7528\u53ef\u5927\u5927\u6291\u5236I2<\/sub>\u6eb6\u89e3\uff0c\u63d0\u5347I2<\/sub>@C-50\u7684\u957f\u5bff\u547d\u3002I2<\/sub>@C-50\u590d\u5408\u6750\u6599\u5177\u6709\u9ad8\u5bb9\u91cf(210 mAh\/g)\u3001\u80fd\u91cf\u5bc6\u5ea6(237 Wh\/kg)\u548c\u9ad8\u6548\u7387(96.7%)\u548c\u7a33\u5b9a\u7684\u5faa\u73af\uff0810,000\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a66%\uff09\u3002<\/p>\n

\u56fe9. I2<\/sub>@ C -50\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u793a\u610f\u56fe\u53ca\u8868\u5f81[5]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u53ef\u4ee5\u901a\u8fc7\u5c06I2<\/sub>\u9897\u7c92\u6d78\u6da6\u5230\u591a\u5b54\u6d3b\u6027\u78b3\u4e2d\uff0c\u4e8e80\u2103\u4e0b\u53cd\u5e944h\u83b7\u5f97I2<\/sub>@ C -50\u590d\u5408\u6750\u6599\u3002\u6d3b\u6027\u78b3\u9897\u7c92\u7684\u5e73\u5747\u5c3a\u5bf8\u4e3a10\u03bcm\u3002\u5f97\u5230\u7684I2<\/sub>@ C -50\u590d\u5408\u6750\u6599\u53ea\u663e\u793a\u65e0\u5e8f\u78b3\u7684XRD\u5cf0\uff0c\u6bd4\u8868\u9762\u79ef\u4e3a387m2<\/sup>\/g\u3002<\/p>\n

\u56fe10. I2<\/sub>@ C -50\u590d\u5408\u6750\u6599\u57282M Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd[5]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

I2<\/sub>@ C -50\u57280.1A\/g\u65f6\u7684\u5bb9\u91cf\u4e3a187.7mAh\/g\uff0c\u57280.2\u30010.5\u30011\u30012\u30015\u300110A\/g\u65f6\u5bf9\u5e94\u7684\u5bb9\u91cf\u5206\u522b\u4e3a167.6, 152.3, 141.9,130.6, 116.7\u548c86.3mAh\/g\u3002\u5f53\u7535\u6d41\u4ece0.1\u589e\u52a0\u523010A\/g\u65f6\uff0c\u7535\u538b\u5e73\u53f0\u4ece41mV\u589e\u52a0\u81f3612mV\uff0c\u8868\u660e\u5177\u6709\u9ad8\u7535\u538b\u548c\u80fd\u91cf\u6548\u7387\u3002\u57282M Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u7535\u89e3\u8d28\u4e2d\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1A\/g\u65f6\uff0c\u7535\u538b\u548c\u80fd\u91cf\u6548\u7387\u53ef\u5206\u522b\u8fbe\u523097%\u548c96.7%\u3002\u5373\u4f7f\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523010A\/g\uff0c\u7535\u538b\u548c\u80fd\u91cf\u6548\u7387\u4ecd\u8d85\u8fc750%\uff0c\u6bd4\u5176\u4ed6\u62a5\u9053\u7684Zn-I2<\/sub>\u6db2\u6d41\u7535\u6c60\u6548\u7387\u9ad8\u3002\u5f53I2<\/sub>\u7684\u8d1f\u8f7d\u91cf\u4ece3.78\u589e\u52a0\u81f35.63mg\/cm2<\/sup>\u65f6\uff0cI2<\/sub>@ C -50\u7684\u5bb9\u91cf\u51e0\u4e4e\u6ca1\u6709\u53d8\u5316\uff0c\u57281A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af5000\u6b21\uff0c\u5bb9\u91cf\u7a33\u5b9a\u5728~120mAh\/g\u3002\u6b64\u5916\uff0c\u5bb9\u91cf\u964d\u4f4e\u4e3b\u8981\u53d1\u751f\u5728\u7b2c\u4e00\u4e2a1000\u6b21\u5faa\u73af\uff0c\u8868\u660eI2<\/sub>\u7684\u8fdb\u4e00\u6b65\u6eb6\u89e3\u53ef\u88ab\u6291\u5236\uff0c\u5f52\u56e0\u4e8eI2<\/sub>\u88ab\u9650\u5236\u5728\u591a\u5b54\u78b3\u4e2d\u3002\u8fd9\u4e9b\u7ed3\u679c\u90fd\u8868\u660e\u5728\u4e0d\u540c\u8d1f\u8f7d\u91cf\u6761\u4ef6\u4e0b\uff0cI2<\/sub>@ C\u590d\u5408\u6750\u6599\u90fd\u53ef\u4ee5\u83b7\u5f97\u9ad8\u5bb9\u91cf\u548c\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

6\u3001Zn-Mn\u7535\u6c60<\/b><\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\uff0c\u57fa\u4e8e\u9530\u7684\u7535\u6c60\u5f97\u5230\u4e86\u5927\u5bb6\u7684\u5173\u6ce8\uff0c\u5b83\u4eec\u5728\u5730\u7403\u7684\u542b\u91cf\u4e30\u5bcc\uff0c\u6210\u672c\u4f4e\uff0c\u5e76\u4e14\u5bf9\u73af\u5883\u53cb\u597d\u3002\u7136\u800c\uff0c\u9530\u57fa\u7535\u6781\u7684\u76f8\u53d8\u4e0e\u7ed3\u6784\u7834\u574f\u95ee\u9898\u4ee5\u53ca\u56e0\u4e3aMn3+<\/sup>\u6b67\u5316\u5bfc\u81f4\u7684\u526f\u53cd\u5e94\u4f7f\u5f97\u950c\u9530\u53ef\u5145\u7535\u7535\u6c60\u5faa\u73af\u5bff\u547d\u5f88\u5dee\u3002\u4e8e\u6b64\uff0cXin\u7b49[6]<\/sup>\u5c55\u793a\u4e86\u901a\u8fc7CH3<\/sub>COO–<\/sup>\u5728Mn2+<\/sup>\u7684\u914d\u4f4d\u53cd\u5e94\uff0c\u5b9e\u73b0\u4e86\u53ef\u9006\u3001\u7a33\u5b9a\u7684Mn2+<\/sup>\/MnO2<\/sub>\u7684\u4e2d\u6027\u6db2-\u56fa\u53cd\u5e94\u3002\u57fa\u4e8e\u6b64\u8bbe\u8ba1\uff0cMn(CH3<\/sub>COO)2<\/sub>\u00a0(Mn(Ac)2<\/sub>)\u53ef\u4ee5\u76f4\u63a5\u6c89\u79ef\u5728\u6b63\u6781\u4e0a\uff0c\u4ee5MnO2<\/sub>\u7684\u5f62\u5f0f\u5b58\u5728\u800c\u4e0d\u4ea7\u751fMn3+<\/sup>\uff0c\u5b8c\u5168\u6291\u5236\u6b67\u5316\u526f\u53cd\u5e94\u3002\u4e0e\u5e38\u7528\u7684\u63d2\/\u8131\u63d2\u539f\u7406\u76f8\u6bd4\uff0c\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6c89\u79ef\/\u6eb6\u89e3\u673a\u7406\u53ef\u4ee5\u907f\u514d\u6b63\u6781\u7ed3\u6784\u51fa\u73b0\u574d\u584c\u7684\u95ee\u9898\uff0c\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u663e\u8457\u63d0\u9ad8\u3002\u56e0\u6b64\uff0c\u950c\u9530\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u8fd0\u884c\u8d85\u8fc7400\u4e2a\u5faa\u73af\uff0c\u5e93\u4f26\u6548\u7387\u7ea6\u4e3a99%\u3002<\/p>\n

\u56fe11. Mn(Ac)2<\/sub>\u548cMnSO4<\/sub>\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u673a\u7406[6]<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe12. Zn-Mn\u6db2\u6d41\u7535\u6c60\u57280.5M\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

(a) \u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a40mA\/cm2<\/sup>\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(b) \u9762\u79ef\u5bb9\u91cf\u4e3a7mAh\/cm2<\/sup>\u65f6\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u548c\u5bf9\u5e94\u7684\u5e93\u4f26\u6548\u7387\u3002(c) \u7535\u6d41\u5bc6\u5ea6\u4ece20mA\/cm2<\/sup>\u523080mA\/cm2<\/sup>\u533a\u95f4\u7684\u500d\u7387\u6027\u80fd\u3002(d) \u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a40mA\/cm2<\/sup>\u3001\u9762\u79ef\u5bb9\u91cf\u4e3a10mAh\/cm2<\/sup>\u65f6\u7684\u5faa\u73af\u6027\u80fd[6]<\/sup>\u3002<\/p>\n

\u7ec4\u88c5\u7684Zn-Mn\u6db2\u6d41\u7535\u6c60\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a40mA\/cm2<\/sup>\u65f6\uff0c\u5e93\u4f26\u6548\u7387\u4e3a~99%\uff0c\u80fd\u91cf\u6548\u7387\u63a5\u8fd178%\u3002Zn-Mn\u6db2\u6d41\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af\u8d85\u8fc7400\u6b21\u3002\u7535\u6d41\u5bc6\u5ea6\u4ece20mA\/cm2<\/sup>\u589e\u52a0\u523080mA\/cm2<\/sup>\uff0c\u7535\u538b\u6548\u7387\uff08VE\uff09\u4ece82%\u964d\u81f368%\uff0c\u5f52\u56e0\u4e8e\u7535\u5316\u5b66\u6027\u80fd\u7684\u6539\u5584\u548c\u6781\u5316\u7684\u6539\u5584\u3002\u5e93\u4f26\u6548\u7387\u4ecd\u63a5\u8fd1100%\u3002\u5f53\u589e\u5927\u8d1f\u8f7d\u91cf\u523016mg\/cm2<\/sup>\u65f6\uff0c\u7535\u6c60\u80fd\u8fd0\u884c120\u4e2a\u5faa\u73af\u4ee5\u4e0a\u800c\u4e0d\u53d1\u751f\u5bb9\u91cf\u548c\u6548\u7387\u7684\u964d\u4f4e\u3002<\/p>\n

\u5c0f\u7ed3\uff1a<\/b><\/strong><\/p>\n

\u80fd\u6e90\u95ee\u9898\u548c\u4eba\u7c7b\u7684\u65e5\u5e38\u751f\u6d3b\u606f\u606f\u76f8\u5173\u3002\u5f00\u53d1\u53ef\u6301\u7eed\u3001\u6210\u672c\u4f4e\u5ec9\u3001\u73af\u5883\u53cb\u597d\u7684\u50a8\u80fd\u6280\u672f\u662f21\u4e16\u7eaa\u4eba\u7c7b\u793e\u4f1a\u7684\u91cd\u70b9\u594b\u6597\u76ee\u6807\u4e4b\u4e00\u3002\u9502\u79bb\u5b50\u7535\u6c60\u6280\u672f\u548c\u8bb8\u591a\u5176\u4ed6\u975e\u9502\u79bb\u5b50\u7535\u6c60\u50a8\u80fd\u6280\u672f\uff0c\u7a76\u7adf\u8c01\u5360\u4e0a\u98ce\uff0c\u6291\u6216\u662f\u5e76\u9a7e\u9f50\u9a71\uff0c\u6211\u4eec\u62ed\u76ee\u4ee5\u5f85\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

1\u3001Potassium cobalt hexacyanoferrate nanocubic assemblies for high-performance aqueous aluminum ion batteries\uff1bdoi:10.1016\/j.cej.2019.122853.<\/p>\n

2\u3001Synergetic Effect of Ru and NiO in Electrocatalytic Decomposition of Li2<\/sub>CO3<\/sub>for Enhancing the Performance of Li-CO2<\/sub>\/O2<\/sub>Battery; DOI: 10.1021\/acscatal.9b04138.<\/p>\n

3\u3001Bifunctional polymer-of-intrinsic-microporosity membrane for flexible Li\/Na\u2013H2<\/sub>O2<\/sub>batteries with hybrid electrolytes; DOI: 10.1039\/c9ta13210d.<\/p>\n

4\u3001Towards stable and efficient electrolytes for room-temperature rechargeable calcium batteries; DOI: 10.1039\/c9ee01699f.<\/p>\n

5\u3001A high energy efficiency and long life aqueous Zn-I2<\/sub>battery; DOI: 10.1039\/C9TA13081K.<\/p>\n

6\u3001A highly reversible neutral zinc\/manganese battery for stationary energy storage; DOI: 10.1039\/c9ee03702k.<\/p>\n

\u672c\u6587\u7531\u5c0f\u4e50\u8001\u5e08<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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