{"id":196255,"date":"2020-02-19T06:50:18","date_gmt":"2020-02-18T22:50:18","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196255"},"modified":"2020-02-19T15:51:08","modified_gmt":"2020-02-19T07:51:08","slug":"%e4%bd%a0%e4%b8%8d%e7%9f%a5%e9%81%93%e7%9a%84%e6%9d%90%e6%96%99%e5%a4%a7%e4%bd%ac-mit-yang-shao-horn-yet-ming-chiang-%e4%bc%af%e5%85%8b%e5%88%a9jeffrey-long","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196255","title":{"rendered":"\u5927\u725b\u8fdb\u5c55 \u76d8\u70b9\u4f60\u53ef\u80fd\u4e0d\u77e5\u9053\u76843\u4f4d\u6750\u6599\u5927\u4f6c"},"content":{"rendered":"

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No.1 <\/b><\/strong>\u90b5\u9633<\/b><\/strong>\uff08Yang<\/b><\/strong>\u00a0Shao-Horn<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u90b5\u9633<\/b><\/strong>Y<\/b><\/strong>ang<\/b><\/strong>\u00a0S<\/b><\/strong>hao<\/b><\/strong>-Horn<\/b><\/strong>\u6559\u6388\u5728Science\u3001Nat<\/b><\/strong>ure Energy<\/b><\/strong>\u3001Nat<\/b><\/strong>ure Nanotechnology<\/b><\/strong>\u3001Nat<\/b><\/strong>ure Material<\/b><\/strong>s\u3001N<\/b><\/strong>ature Chemistry<\/b><\/strong>\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587\u8d85\u8fc7<\/b><\/strong>370<\/b><\/strong>\u7bc7\uff0c\u603b\u88ab\u5f15\u8d85<\/b><\/strong>3W<\/b><\/strong>\uff0cH<\/b><\/strong>-index:86<\/b><\/strong>\u3002\uff08we<\/b><\/strong>b of science<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\u90b5\u9633\uff08Yang Shao-Horn\uff09\u6559\u63881992\u5e74\u83b7\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u5de5\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c\u540e\u4e8e\u5bc6\u6b47\u6839\u7406\u5de5\u5927\u5b66\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\u30022002\u5e74\u8fdb\u5165\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u4efb\u6559\uff0c\u73b0\u4e3a\u9ebb\u7701\u7406W. M. Keck\u80fd\u6e90\u6559\u6388\uff0c\u7f8e\u56fd\u56fd\u5bb6\u5de5\u7a0b\u9662\u9662\u58eb\uff082018\u5f53\u9009\uff09\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/b><\/strong>h<\/span>ttp:\/\/web.mit.edu\/eel\/<\/b><\/strong>\u00a0<\/b><\/strong>\uff08\u4e3b\u9875\u6709\u90b5\u9633\u8001\u5e08\u7684\u4e00\u4e9b\u7cbe\u5f69\u62a5\u544a\u89c6\u9891\uff0c\u5f88\u503c\u5f97\u5b66\u4e60\uff09<\/b><\/strong><\/span><\/p>\n

\u4e3b\u8981\u7814\u7a76\u65b9\u5411<\/b><\/strong><\/p>\n

1<\/b><\/strong>. <\/b><\/strong>\u7814\u7a76\u50ac\u5316\u5242\u8868\u9762\u7684\u7535\u5b50\u7ed3\u6784\u3001\u5bfb\u627e\u50ac\u5316\u6027\u80fd\u63cf\u8ff0\u7b26\uff08\u91d1\u5c5e\u6c27\u5316\u7269\u4e3a\u4e3b\uff09<\/b><\/strong><\/p>\n

2. \u7535\u50ac\u5316\u3001\u5149\u7535\u50ac\u5316\uff08\u6c34\u88c2\u89e3\u3001\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7b49\uff09<\/b><\/strong><\/p>\n

3. \u50a8\u80fd\u7535\u6c60\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u3001\u6db2\u6d41\u7535\u6c60\u3001\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u3001\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u3001\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60<\/b><\/strong><\/p>\n

\u6700\u65b0\u4ee3\u8868\u6027\u6210\u679c\u68b3\u7406<\/b><\/strong><\/p>\n

1<\/b><\/strong>. <\/b><\/strong>\u9502\u91d1\u5c5e\u7535\u6c60\uff1a<\/b><\/strong><\/span>FSI-inspired solvent and \u2018\u2018full fluorosulfonyl\u2019\u2019electrolyte for 4 V class lithium-metal batteries<\/b><\/strong>.<\/b><\/strong>Energy Environ. Sci., <\/i><\/b><\/em><\/strong>2020,13, 212\u2014220<\/b><\/strong>.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u5728\u6b64\uff0c\u4f5c\u8005\u4eec\u901a\u8fc7\u4eceLMA\u517c\u5bb9\u76d0\u53cc\uff08\u6c1f\u78fa\u9170\u57fa\uff09\u9170\u4e9a\u80fa\u9502\uff08LiFSI\uff09\u4e2d\u6a21\u62df\u6c1f\u78fa\u9170\u4e9a\u80fa\u57fa\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u6709\u673a\u6eb6\u5242\u4e8c\u7532\u57fa\u6c28\u78fa\u9170\u6c1f\uff08FSO2<\/sub>NC2<\/sub>H6<\/sub>\uff09\uff0c\u4e00\u79cd\u5e26\u6709\u4e24\u4e2a\u7532\u57fa\u53d6\u4ee3\u57fa\u7684\u6c1f\u78fa\u9170\u80fa\uff08FSA\uff09\uff0c\u5f00\u53d1\u65b0\u7684\u201c\u5168\u6c1f\u78fa\u9170\u57fa\u201d\uff08FFS\uff09\u7535\u89e3\u8d28\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5b83\u53ef\u5b9e\u73b0\u9ad8\u5ea6\u53ef\u9006\u7684LMA\uff0c\u5177\u6709\u51fa\u8272\u7684\u521d\u59cb\u5e93\u4ed1\u6548\u7387\uff08CE\uff0991\uff05\uff0c\u5e76\u4e14\u4ec5\u572810\u4e2a\u5faa\u73af\u5185\u5373\u53ef\u8fc5\u901f\u8fbe\u523099\uff05\uff0c\u5e73\u5747CE\u4f18\u4e8e\u4f17\u6240\u5468\u77e5\u7684LMA\u517c\u5bb9\u7684\u78b3\u9178\u6c1f\u4e9a\u4e59\u916f\uff08FEC\uff09\u57fa\u7535\u89e3\u8d28\u3002\u6b64\u5916\uff0c\u5f97\u76ca\u4e8e\u5176\u5bf9\u6c27\u5316LiNi0.6<\/sub>Mn0.2<\/sub>Co0.2<\/sub>O2<\/sub>\uff08NMC622\uff09\u548cLiMn2<\/sub>O4<\/sub>\uff08LMO\uff09\u8868\u9762\u7684\u9ad8\u9633\u6781\u7a33\u5b9a\u6027\uff0cLi\/\/<\/sub>NMC622\u7535\u6c60\u4f7f\u7528\u6709\u9650\u7684\u8fc7\u91cfLi\u9633\u6781\u5728200\u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u6301\u5176\u539f\u59cb\u5bb9\u91cf\u768489\uff05\u3002\u8fd9\u79cd\u7535\u89e3\u8d28\u8bbe\u8ba1\u7b56\u7565\u4e3a\u63a2\u7d22\u7528\u4e8e4 V\u7ea7\u9502\u91d1\u5c5e\u7535\u6c60\uff08LMB\uff09\u7684\u65b0\u578b\u4e2d\u7b49\u6d53\u5ea6\u6709\u673a\u7535\u89e3\u8d28\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002<\/p>\n

F<\/b><\/strong>FS<\/b><\/strong>\u7535\u89e3\u6db2\u7684\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2. L<\/span><\/b><\/strong>i<\/b><\/strong>–<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60\uff1a<\/b><\/strong><\/span>Solvent-Dependent Oxidizing Power of LiI Redox Couples for Li-O<\/b><\/strong>2<\/b><\/sub><\/strong>Batteries<\/b><\/strong>.<\/b><\/strong><\/b>Joule,<\/i><\/b><\/em><\/strong>\u00a02019, 3, 1106.<\/b><\/strong>\u00a0<\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u4eec\u7cfb\u7edf\u5730\u7814\u7a76\u4e86LiI\u548cLi2<\/sub>O2<\/sub>\u548cLiOH\u4e4b\u95f4\u7684\u53cd\u5e94\uff0cLiI\u662f\u4e3a\u50ac\u5316\u5145\u7535\u8fc7\u7a0b\u800c\u6dfb\u52a0\u7684\u53ef\u6eb6\u6027\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u3002\u66f4\u5f3a\u7684Li+<\/sup>\u548cI–<\/sup>\u79bb\u5b50\u6eb6\u5242\u5316\u53ef\u4ee5\u63d0\u9ad8I3-<\/sup>\u7684\u6c27\u5316\u80fd\u529b\uff0c\u8fd9\u4f7fI3-<\/sup>\u53ef\u4ee5\u6c27\u5316DMA\uff0cDMSO\u548cMe-Im\u4e2d\u7684Li2<\/sub>O2<\/sub>\u548cLiOH\uff0c\u800c\u5728\u8f83\u5f31\u7684\u6eb6\u5242\uff08G4\uff0cDME\uff09\u4e2d\uff0c\u9700\u8981\u66f4\u591a\u7684I2<\/sub>\u6c27\u5316\u624d\u80fd\u8fdb\u884c\u53cd\u5e94\u3002\u89c2\u5bdf\u5230Li2<\/sub>O2<\/sub>\u88ab\u6c27\u5316\u6210O2<\/sub>\uff0c\u800cLiOH\u53cd\u5e94\u5f62\u6210IO–<\/sup>\u3002 \u8fd9\u9879\u5de5\u4f5c\u6f84\u6e05\u4e86\u5728\u8fd9\u4e9b\u53cd\u5e94\u4e2d\u7684\u91cd\u5927\u8bef\u89e3\uff0c\u5e76\u4e3a\u7406\u89e3LiI\u5728Li-O2<\/sub>\u7535\u6c60\u4e2d\u7684\u4f5c\u7528\u63d0\u4f9b\u4e86\u70ed\u529b\u5b66\u548c\u9009\u62e9\u6027\u6846\u67b6\u3002<\/p>\n

\u00a0<\/b><\/strong>I\u79bb\u5b50\u4e4b\u95f4\u7684\u6eb6\u5242\u4f9d\u8d56\u53cd\u5e94<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>. <\/b><\/strong>\u9499\u949b\u77ff\u6c27\u5316\u7269\u50ac\u5316<\/b><\/strong>OER<\/b><\/strong>\u7684Yang<\/b><\/strong>Shao-Horn<\/b><\/strong>\u89c4\u5219\uff1a<\/b><\/strong><\/span>A Perovskite Oxide Optimized forOxygen Evolution Catalysis fromMolecular Orbital Principles<\/b><\/strong>.<\/b><\/strong><\/b>Science, <\/i><\/b><\/em><\/strong>2011, 334, 1383.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u4f5c\u8005\u4eec\u53d1\u73b0Ba0.5<\/sub>Sr0.5<\/sub>Co0.8<\/sub>Fe0.2<\/sub>O3-d<\/sub>\uff08BSCF\uff09\u50ac\u5316\u7684OER\u5177\u6709\u6bd4\u78b1\u6027\u4ecb\u8d28\u4e2d\u6700\u5148\u8fdb\u7684\u6c27\u5316\u94f1\u50ac\u5316\u5242\u81f3\u5c11\u9ad8\u4e00\u4e2a\u6570\u91cf\u7ea7\u7684\u56fa\u6709\u6d3b\u6027\u3002\u901a\u8fc7\u5bf910\u591a\u79cd\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u8fdb\u884c\u7cfb\u7edf\u68c0\u67e5\u800c\u5efa\u7acb\u7684\u8bbe\u8ba1\u539f\u7406\u53ef\u9884\u6d4bBSCF\u7684\u9ad8\u6d3b\u6027\uff0c\u8fd9\u8868\u660e\u56fa\u6709\u7684OER\u6d3b\u6027\u5bf9\u8868\u9762\u8fc7\u6e21\u91d1\u5c5e\u5bf9\u79f0\u76843d\u7535\u5b50\u5360\u6709\u7387\u8868\u73b0\u51fa\u706b\u5c71\u72b6\u4f9d\u8d56\u6027\u3002\u9884\u6c27\u5316\u7269\u4e2d\u7684\u9633\u79bb\u5b50\u5904\u4e8eeg\u8f68\u9053\u5360\u6709\u7387\u63a5\u8fd11\uff0c\u5e76\u4e14\u5177\u6709\u9ad8\u4ef7\u7684\u8fc7\u6e21\u91d1\u5c5e-\u6c27\u952e\u7684OER\u6d3b\u6027\u6700\u9ad8\u3002<\/p>\n

\u00a0<\/b><\/strong>\u591a\u79cd\u91d1\u5c5e\u6c27\u5316\u7269\u7684O<\/b><\/strong>ER<\/b><\/strong>\u6d3b\u6027\u706b\u5c71\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

No.2 <\/b><\/strong>\u848b\u4e1a\u660e<\/b><\/strong>\uff08Yet<\/b><\/strong>-Ming Chiang<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u848b\u4e1a\u660e<\/b><\/strong>\u6559\u6388\u5728Science\u3001Nat<\/b><\/strong>ure<\/b><\/strong>\u3001\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587\u8d85\u8fc7<\/b><\/strong>230<\/b><\/strong>\u7bc7\uff0c\u603b\u88ab\u5f15\u8d85<\/b><\/strong>1.7 W<\/b><\/strong>\uff0cH<\/b><\/strong>-index: 66<\/b><\/strong>\u3002\uff08we<\/b><\/strong>b of science<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\u848b\u4e1a\u660e\uff0c\u4e2d\u56fd\u53f0\u6e7e\u4eba\uff0c\u7f8e\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\uff0c\u53f0\u6e7e\u4e2d\u592e\u7814\u7a76\u9662\u9662\u58eb,\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u6750\u6599\u7cfb\u6559\u6388\uff0c\u7814\u7a76\u51fa\u7528\u94dd\u3001\u94cc\u3001\u9506\u7b49\u4e09\u79cd\u91d1\u5c5e\u505a\u6b63\u6781\u7684\u8d85\u7ea7\u9502\u7535\u6c60\u3002\u6c64\u68ee\u8def\u900f2000-2010\u5e74\u5168\u7403\u9876\u5c16\u4e00\u767e\u6750\u6599\u5b66\u5bb6\u540d\u4eba\u5802\u699c\u5355\uff0c\u848b\u4e1a\u660e\uff08Yet-MingCHIANG\uff09\uff0c\u5168\u7403\u603b\u6392\u540d\u7b2c66\u4f4d\uff0c\u534e\u4eba\u6392\u540d\u7b2c12\u4f4d\u300224M\u516c\u53f8\u521b\u59cb\u4eba\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/b><\/strong>https:\/\/dmse.mit.edu\/people\/yet-ming-chiang<\/b><\/strong><\/span><\/p>\n

\u4e3b\u8981\u7814\u7a76\u65b9\u5411<\/b><\/strong><\/p>\n

1<\/b><\/strong>. <\/b><\/strong>\u7535\u6c60\uff08\u9502\u79bb\u5b50\u7535\u6c60\u3001<\/b><\/strong>Li-S\u7535\u6c60<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

2. \u7535\u5316\u5b66\u5408\u6210<\/b><\/strong><\/p>\n

3. 3D<\/b><\/strong>\u6253\u5370\u5728\u7535\u6c60\u5236\u9020\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/p>\n

\u6700\u65b0\u4ee3\u8868\u6027\u6210\u679c\u68b3\u7406<\/b><\/strong><\/p>\n

1<\/b><\/strong>. <\/b><\/strong>\u7a33\u5b9aLi<\/b><\/strong>-S<\/b><\/strong>\u7535\u6c60\u7b56\u7565\uff1a<\/b><\/strong><\/span>Stabilizing Li-S Battery Through Multilayer Encapsulation of Sulfur<\/b><\/strong>.<\/b><\/strong><\/b>\u00a0Adv. Energy Mater.<\/i><\/b><\/em><\/strong>2019, 9, 1802213.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u4f5c\u8005\u5728\u4f7f\u7528\u5e38\u89c4\u7535\u89e3\u8d28\u7684\u540c\u65f6\u901a\u8fc7\u786b\u9897\u7c92\u7684\u591a\u5c42\u5c01\u88c5\u663e\u7740\u6539\u5584\u4e86\u7535\u6c60\u7684\u7a33\u5b9a\u6027\uff0c\u8be5\u65b9\u6cd5\u53ef\u5b9e\u73b0\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u5e76\u5728\u4f4e\u7535\u89e3\u8d28\u8fdb\u6599\u7684\u60c5\u51b5\u4e0b\u6539\u5584\u5e93\u4ed1\u6548\u7387\u3002\u5f53\u4f7f\u7528\u65e0\u7c98\u5408\u5242\u7684\u7535\u6781\u65f6\uff0c\u591a\u5c42\u5c01\u88c5\u7684\u786b\u7535\u6c60\u8868\u73b0\u51fa\u9ad8\u8fbe98\uff05\u7684\u5e93\u4ed1\u6548\u7387\u3002\u5728168\u5c0f\u65f6\u540e\uff0c\u7535\u6c60\u7684\u5168\u90e8\u81ea\u653e\u7535\u53ef\u4ee5\u4ece\u5e38\u89c4\u786b\u7535\u6c60\u4e2d\u768434\uff05\u51cf\u5c11\u5230\u5e26\u6709\u591a\u5c42\u5c01\u88c5\u786b\u7535\u6781\u7684\u7535\u6c60\u4e2d\u76849\uff05\u4ee5\u4e0b\u3002<\/p>\n

\u6750\u6599\u5408\u6210\u793a\u610f\u56fe\u4e0e\u7535\u955c\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>. <\/b><\/strong>\u7528\u4e8e\u7535\u6c60\u7684\u805a\u5408\u7269\u819c\u7684\u8bbe\u8ba1\u51c6\u5219\uff1a<\/b><\/strong><\/span>Design Rules for Membranes from Polymers of Intrinsic Micro porosity for Crossover-free Aqueous Electrochemical Device<\/b><\/strong>s<\/b><\/strong>. <\/b><\/strong>Joule, <\/i><\/b><\/em><\/strong>3, 2968\u20132985.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u4f5c\u8005\u4eec\u4e3a\u5c06\u5fae\u5b54\u805a\u5408\u7269\u819c\u7684\u7ed3\u6784\u3001\u819c\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u7535\u5bfc\u7387\u548c\u5728\u5bbd\u8303\u56f4\u7684pH\u8303\u56f4\u5185\u7684\u6c34\u6027\u7535\u89e3\u8d28\u4e2d\u7684\u8fc1\u79fb\u9009\u62e9\u6027\u8054\u7cfb\u8d77\u6765\u5960\u5b9a\u4e86\u76f8\u5173\u805a\u5408\u7269\u819c\u7684\u8bbe\u8ba1\u539f\u5219\u3002\u4f5c\u8005\u5c06\u8fd9\u4e9b\u5c5e\u6027\u4e0e\u65e0\u4ea4\u53c9\uff08crossover-free\uff09\u7535\u5316\u5b66\u7535\u6c60\u7684\u524d\u666f\u8054\u7cfb\u5728\u4e00\u8d77\u3002\u8fd9\u4e9b\u6307\u5bfc\u539f\u5219\u9002\u7528\u4e8e\u4e24\u79cd\u65b0\u5174\u7684\u7f51\u683c\u7535\u5316\u5b66\u7535\u6c60\uff1a\u5177\u4f53\u5730\u8bf4\uff0c\u662fZn\u2013TEMPO-4-\u786b\u9178\u76d0\u548cZn\u2013K4<\/sub>Fe\uff08CN\uff096<\/sub>\u7535\u6c60\u3002\u6210\u529f\u7684\u5173\u952e\u662f\u5c06\u53ef\u7535\u79bb\u7684\u805a\u5408\u7269\u80fa\u809f\u5b98\u80fd\u56e2\u653e\u7f6e\u5728\u5fae\u5b54\u68af\u72b6\u805a\u5408\u7269\u819c\u7684\u5b54\u4e2d\uff0c\u8be5\u5b98\u80fd\u56e2\u5728\u9ad8pH\u4e0b\u7a33\u5b9a\uff0c\u5206\u522b\u5728\u4f4epH\u548c\u9ad8pH\u4e0b\u4ea7\u751f\u4e00\u7c7b\u7535\u8377\u4e2d\u6027\u819c\u548c\u9633\u79bb\u5b50\u4ea4\u6362\u819c\uff0c\u6211\u4eec\u79f0\u4e4b\u4e3aAquaPIM\u3002\u5b83\u4eec\u6781\u9ad8\u7684\u7535\u5bfc\u7387\uff08\u57285.0 M\u7684KOH\u4e2d\u8fbe21.5 mS cm-1<\/sup>\uff09\u548c\u9ad8\u7684\u8fd0\u8f93\u9009\u62e9\u6027\uff08\u901a\u8fc7\u819c\u7684\u6d3b\u6027\u7269\u8d28\u6e17\u900f\u7387\u964d\u4f4e\u9ad8\u8fbe104\uff09\u4e3a\u7535\u6c60\u5f00\u53d1\u63d0\u4f9b\u4e86\u4ee4\u4eba\u5174\u594b\u7684\u673a\u4f1a\u3002<\/p>\n

\u805a\u5408\u7269\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

No.3 Jeffrey R. Long<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Long\u6559\u6388\u5728Science\u3001Nature\u3001Nat<\/b><\/strong>ure Material<\/b><\/strong>s\u3001N<\/b><\/strong>ature Chemistry<\/b><\/strong>\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587\u8d85\u8fc74<\/b><\/strong>90<\/b><\/strong>\u7bc7\uff0c\u603b\u88ab\u5f15\u8d855<\/b><\/strong>W<\/b><\/strong>\uff0cH<\/b><\/strong>-index:101<\/b><\/strong>\u3002\uff08we<\/b><\/strong>b of science<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

Long\u6559\u63881991\u5e74\u4e8e\u5eb7\u5948\u5c14\u5927\u5b66\u83b7\u4e00\u7b49\u8363\u8a89\u5316\u5b66\u548c\u8363\u8a89\u6570\u5b66\u5b66\u58eb\u5b66\u4f4d\u30021995\u5e74\u62ff\u5230\u54c8\u4f5b\u535a\u58eb\u5b66\u4f4d\u5e08\u4eceProf. Richard H. Holm\uff0c\u4e4b\u540e\u5728\u54c8\u4f5b\u548c\u4f2f\u514b\u5229\u505a\u535a\u540e\u30021997\u5e74\u52a0\u5165\u4f2f\u514b\u5229\u4efb\u52a9\u7406\u6559\u6388\uff0c03\u5e74\u62ff\u5230\u7ec8\u8eab\u6559\u804c\uff0c08\u5e74\u5347\u4e3a\u6b63\u6559\u6388\u3002\u73b0\u4e3a\u4f2f\u514b\u5229\u5316\u5b66\u7cfb\u548c\u5316\u5b66\u4e0e\u751f\u7269\u533b\u836f\u5de5\u7a0b\u7cfb\u53cc\u6559\u6388\u4e0e\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u9ad8\u7ea7\u79d1\u5b66\u5bb6\u3002Long\u6559\u6388\u662f\u7f8e\u56fd\u5316\u5b66\u4f1a\u65e0\u673a\u5316\u5b66\u4e3b\u5e2d\uff0c\u8fd8\u662f\u591a\u4e2a\u9876\u7ea7\u671f\u520a\u7f16\u59d4\uff0c\u4f8b\u5982Chemical Society Reviews<\/i><\/em>\u3001<\/i><\/em>Energy & Environmental Science<\/i><\/em>\u3001<\/i><\/em>Chemistry of Materials<\/i><\/em>\u548cACS Materials Letters<\/i><\/em>\u3002Long\u6559\u6388\u83b7\u5956\u65e0\u6570\uff0c2013\u5e74\u6210\u4e3a\u5409\u6797\u5927\u5b66\u8363\u8a89\u6559\u6388\u3002Long\u4e5f\u662f\u591a\u5bb6\u9ad8\u79d1\u6280\u516c\u53f8\u521b\u59cb\u4eba\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/b><\/strong>http:\/\/alchemy.cchem.berkeley.edu\/home\/<\/b><\/strong><\/span><\/p>\n

\u4e3b\u8981\u7814\u7a76\u65b9\u5411<\/b><\/strong><\/p>\n

1.<\/b><\/strong>\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08M<\/b><\/strong>OF<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

2.<\/b><\/strong>\u57fa\u4e8eM<\/b><\/strong>OF<\/b><\/strong>\u7684\u6c14\u4f53\u5b58\u50a8\u548c\u5206\u79bb\u7814\u7a76<\/b><\/strong><\/p>\n

3.<\/b><\/strong>\u5f00\u53d1\u7814\u7a76\u5177\u6709\u4f53\u76f8\u7535\u5bfc\u6027\uff08\u7535\u5b50\u3001\u79bb\u5b50\uff09\u7684\u591a\u5b54\u6750\u6599<\/b><\/strong><\/p>\n

4.<\/b><\/strong>\u5355\u6838\u548c\u591a\u6838\u5355\u5206\u5b50\u78c1\u4f53<\/b><\/strong><\/p>\n

5.<\/b><\/strong>\u50ac\u5316\uff1a\u5408\u6210\u5177\u6709\u5f00\u653e\u87af\u5408\u4f4d\u70b9\u7684\u53ef\u8c03\u63a7<\/b><\/strong>MOF<\/b><\/strong>\u548c\u5206\u5b50\u914d\u5408\u7269\u7528\u4e8e\u5404\u79cd\u50ac\u5316\u53cd\u5e94<\/b><\/strong><\/p>\n

Long<\/b><\/strong>\u6559\u6388\u7684\u7814\u7a76\u65b9\u5411<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6700\u65b0\u4ee3\u8868\u6027\u6210\u679c\u68b3\u7406<\/b><\/strong><\/p>\n

2<\/b><\/strong>020\u300aNature\u300b<\/b><\/strong><\/span><\/p>\n

1<\/b><\/strong>. <\/b><\/strong>MOF\u9650\u57df\u5408\u6210\u539f\u5b50\u7ea7<\/b><\/strong>\u7cbe\u786e\u7684\u8d85\u5c0f\u4e8c\u7ef4\u91d1\u5c5e\u5364\u5316\u7269\uff1a<\/b><\/strong><\/span>Confinement of atomically defined metal halide sheets in a metal\u2013organic framework<\/b><\/strong>.<\/b><\/strong><\/b>N<\/i><\/b><\/em><\/strong>ature<\/i><\/b><\/em><\/strong>, 2020, 577, 64.<\/b><\/strong><\/p>\n

\u89e3\u8bfb\uff1aa. \u4f5c\u8005\u4eec\u9009\u62e9\u4e86Zr6<\/sub>O4<\/sub>(OH)4<\/sub>(bpydc)6<\/sub>\uff08\u5176\u4e2dbpydc2-<\/sup>\u00a0= 2,2′-\u8054\u5421\u5576-5,5′-\u4e8c\u7fa7\u9178\u76d0\uff09\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff0c\u5176\u9aa8\u67b6\u5bbd\u5ea6\u7ea6\u4e3a1.3\u7eb3\u7c73\u516b\u9762\u4f53\u7b3c\u5b50\uff0c\u5185\u6709\u87af\u5408\u4f4d\u70b9\uff0c\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u5c06\u5404\u79cd\u91d1\u5c5e\u6e90\u7ed3\u5408\u4e3a\u5b64\u7acb\u7684\u5355\u6838\u7edc\u5408\u7269\uff0c\u5305\u62ec\u4e8c\u4ef7\u5364\u5316\u91d1\u5c5e\u3002(\u8054\u5421\u5576\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u7684\u914d\u4f4d\u8d77\u5230\u4e86\u5173\u952e\u4f5c\u7528)\u00a0b. \u901a\u8fc7MOF\u7684\u9650\u57df\u4f5c\u7528\uff0c\u4e8c\u7ef4\u91d1\u5c5e\u5364\u5316\u7269\u7684\u539a\u5ea6\u3001\u5c3a\u5bf8\u90fd\u5f97\u5230\u4e86\u539f\u5b50\u7ea7\u7684\u7cbe\u786e\u63a7\u5236\uff08\u4e8c\u7ef4\u6750\u6599\u91cf\u5b50\u70b9\u7684\u5408\u6210\u5145\u6ee1\u56f0\u96be\uff0c\u4f5c\u8005\u7ed9\u51fa\u4e86MOF\u9650\u57df\u89e3\uff09\u3002c.\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\u53ef\u4ee5\u62ff\u5230\u6750\u6599\u7684\u5355\u6676\u6570\u636e\u3002\u4f5c\u8005\u901a\u8fc7\u6539\u53d8\u524d\u9a71\u4f53\u91d1\u5c5e\u76d0\u7684\u7528\u91cf\uff0c\u795e\u5947\u5730\u7814\u7a76\u4e86\u4e8c\u7ef4\u6750\u6599\u5728MOF\u79cd\u7684\u751f\u957f\u8fc7\u7a0b\uff0c\u5982\u4e0b\u56fe\u6240\u793a\u3002d.\u5408\u6210\u65b9\u6cd5\u5177\u6709\u666e\u9002\u6027\uff0cNiBr2<\/sub>\u3001NiCl2<\/sub>\u3001CoCl2<\/sub>\u3001FeCl\u8981\u5565\u6765\u5565\u3002e.\u65b0\u9896\u78c1\u6027\uff1a\u5c06\u7eb3\u7c73\u7247\u5b64\u7acb\u8d77\u6765\u6d88\u9664\u4e86\u53cd\u94c1\u78c1\u5c42\u95f4\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u9694\u79bb\u4e86\u94c1\u78c1\u8026\u5408\u7684\u5927\u81ea\u65cb\u57fa\u6001\u3002\u5bfc\u81f4\u4e0e\u5757\u4f53\u6750\u6599\u8fe5\u5f02\u7684\u78c1\u5b66\u6027\u8d28\u3002<\/p>\n

http:\/\/alchemy.cchem.berkeley.edu\/static\/pdf\/papers\/paper322.pdf<\/p>\n

\u5364\u5316\u954d\u7eb3\u7c73\u7247\u7684\u751f\u957f\u8fc7\u7a0b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2019<\/b><\/strong>\u300a<\/b><\/strong>JACS<\/b><\/strong>\u300b<\/b><\/strong><\/span><\/p>\n

2<\/b><\/strong>. <\/b><\/strong>M<\/b><\/strong>OF<\/b><\/strong>\u4e2d1-\u4e01\u70ef\u4e0e2-\u4e01\u70ef\u7684\u70ed\u529b\u5b66\u5206\u79bb\uff1a<\/b><\/strong><\/span>Thermodynamic Separation of 1\u001eButene from 2\u001eButene in Metal\u2212Organic Frameworks with Open Metal Sites<\/b><\/strong>.<\/b><\/strong>Am.Chem.Soc., <\/i><\/b><\/em><\/strong>2019, 141, 18325\u221218333.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u5927\u591a\u6570C4\u78b3\u6c22\u5316\u5408\u7269\u662f\u4f5c\u4e3a\u4e59\u70ef\u751f\u4ea7\u6216\u70bc\u6cb9\u7684\u526f\u4ea7\u54c1\u83b7\u5f97\u7684\uff0c\u5206\u79bb\u5b83\u4eec\u8fc7\u7a0b\u590d\u6742\u4e14\u8017\u80fd\u5de8\u5927\u3002\u5927\u91cf\u7684\u5de5\u4e1a\u548c\u5b66\u672f\u5c4a\u52aa\u529b\u5f00\u53d1\u66f4\u5177\u6210\u672c\u6548\u76ca\u7684\u57fa\u4e8e\u5438\u9644\u5242\u6216\u819c\u7684\u65b9\u6cd5\u6765\u7eaf\u5316\u5316\u5b66\u54c1\uff0c\u4f8b\u59821,3-\u4e01\u4e8c\u70ef\u3001\u5f02\u4e01\u70ef\u548c1-\u4e01\u70ef\u3002\u4f46\u662f\uff0c\u8fd9\u4e9bC4\u70c3\u7684\u7269\u7406\u6027\u8d28\u975e\u5e38\u76f8\u4f3c\uff0c\u4f7f\u8fd9\u6210\u4e3a\u4e00\u9879\u5177\u6709\u6311\u6218\u6027\u7684\u4efb\u52a1\u3002\u8fd9\u7bc7\u6587\u7ae0\u4e2d\u4f5c\u8005\u6c47\u603b\u7814\u7a76\u4e861-\u4e01\u70ef\u3001\u987a\u5f0f-2-\u4e01\u70ef\u548c\u53cd\u5f0f-2-\u4e01\u70ef\u5728\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6M2<\/sub>\uff08dobdc\uff09\u4e2d\u7684\u5438\u9644\u884c\u4e3a\uff08M = Mn\uff0cFe\uff0cCo\uff0cNi\uff1b dobdc4- <\/sup>= 2,5 -\u4e8c\u6c27\u5316\u82ef-1,4-\u4e8c\u7fa7\u9178\u76d0\uff09\u548cM2<\/sub>\uff08m-dobdc\uff09\uff08m-dobdc4- = 4,6-\u4e8c\u6c27\u5316\u82ef-1,3-\u4e8c\u7fa7\u9178\u76d0\uff09\uff0c\u90fd\u542b\u6709\u9ad8\u5bc6\u5ea6\u7684\u914d\u4f4d\u4e0d\u9971\u548cM2 +<\/sup>\u4f4d\u70b9\u3002\u4f5c\u8005\u53d1\u73b0\uff0cCo2<\/sub>\uff08m-dobdc\uff09\u548cNi2<\/sub>\uff08m-dobdc\uff09\u90fd\u80fd\u591f\u4ece2-\u4e01\u70ef\u5f02\u6784\u4f53\u4e2d\u5206\u79bb\u51fa1-\u4e01\u70ef\uff0c\u8fd9\u662f\u4e00\u4e2a\u5173\u952e\u7684\u5de5\u4e1a\u8fc7\u7a0b\uff0c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8e\u80fd\u6e90\u9700\u6c42\u8f83\u5927\u7684\u4f4e\u6e29\u84b8\u998f\u3002 1-\u4e01\u70ef\u9009\u62e9\u6027\u7684\u8d77\u6e90\u53ef\u8ffd\u6eaf\u5230M2<\/sub>\uff08m-dobdc\uff09\u7ed3\u6784\u4e2d\u66b4\u9732\u7684M2 +<\/sup>\u91d1\u5c5e\u4e2d\u5fc3\u4fdd\u7559\u7684\u9ad8\u7535\u8377\u5bc6\u5ea6\uff0c\u8fd9\u5bfc\u81f4\u901a\u5e38\u5728\u9aa8\u67b6\u5f00\u653e\u91d1\u5c5e\u4f4d\u70b9\u89c2\u5bdf\u5230\u7684\u987a\u5f0f2-\u4e01\u70ef\u9009\u62e9\u6027\u7684\u9006\u8f6c\u3002\u4f5c\u8005\u901a\u8fc7\u7a81\u7834\uff08breakthrough\uff09\u548c\u5206\u6279\u5438\u9644\u5b9e\u9a8c\u8bc1\u660e\u4e86Ni2<\/sub>\uff08m-dobdc\uff09\u5728\u6c14\u76f8\u548c\u6db2\u76f8\u4e2d\u5728\u591a\u7ec4\u5206\u6761\u4ef6\u4e0b\u5bf91-\u4e01\u70ef\u5438\u9644\u7684\u9009\u62e9\u6027\u3002<\/p>\n

http:\/\/alchemy.cchem.berkeley.edu\/static\/pdf\/papers\/paper318.pdf<\/p>\n

M<\/b><\/strong>OF<\/b><\/strong>\u7684\u7ed3\u6784\u53ca\u4e0e1-\u4e01\u70ef\u7ed3\u5408\u65b9\u5f0f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2019<\/b><\/strong>\u300a<\/b><\/strong>JACS<\/b><\/strong>\u300b<\/b><\/strong><\/span><\/p>\n

3<\/b><\/strong>. <\/b><\/strong>\u6297\u6c27\u5316M<\/b><\/strong>OF<\/b><\/strong>\u4e2d\uff0c\u6c34\u63d0\u9ad8C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\u6548\u7387\uff1a<\/b><\/strong><\/span>Water Enables Efficient CO<\/b><\/strong>2<\/b><\/sub><\/strong>Capture from Natural Gas Flue Emissions in an Oxidation-Resistant Diamine-Appended Metal\u2212Organic Framework<\/b><\/strong>.<\/b><\/strong><\/b> Am. Chem. Soc., <\/i><\/b><\/em><\/strong>2019, 141, 13171\u221213186. <\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u7531\u4e8e\u4e8c\u6c27\u5316\u78b3\u5206\u538b\u4f4e\uff0c\u71c3\u6c14\u7535\u5382\u70df\u9053\u6c14\u4e2d\u7684\u4e8c\u6c27\u5316\u78b3\u4e0e\u5176\u4ed6\u6210\u5206\u7684\u5206\u79bb\u7279\u522b\u5177\u6709\u6311\u6218\u6027\uff0c\u8fd9\u5c31\u8981\u6c42\u5019\u9009\u5206\u79bb\u6750\u6599\u5fc5\u987b\u5728\u8f83\u4f4e\u7684\u5206\u538b\uff08\u22644\u6beb\u5df4\uff09\u4e0b\u4e0e\u4e8c\u6c27\u5316\u78b3\u7d27\u5bc6\u7ed3\u5408\u3002\u8fd9\u4e9b\u70df\u9053\u6c14\u4e2d\u7684O2<\/sub>\uff08120 mbar\uff09\u548c\u6c34\uff0880 mbar\uff09\u7684\u9ad8\u5206\u538b\u4e5f\u4e3a\u90e8\u7f72\u4ece\u71c3\u6c14\u53d1\u7535\u5382\u6355\u83b7CO2<\/sub>\u7684\u65b0\u6280\u672f\u63d0\u51fa\u4e86\u91cd\u5927\u969c\u788d\u3002\u5728\u8fd9\u91cc\uff0c\u4f5c\u8005\u4eec\u8bc1\u660e\u4e86\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6Mg2<\/sub>\uff08dobpdc\uff09\uff08dobpdc4- = 4,4′-dioxidobiphenyl-3,3′-dicarboxylate\uff09\u4e0e\u73af\u72b6\u4e8c\u80fa2-\uff08\u6c28\u57fa\u7532\u57fa\uff09\u54cc\u5576\uff082-ampd\uff09\u7684\u5b98\u80fd\u5316\u4f5c\u7528\uff0c\u8fd9\u79cd\u5438\u9644\u5242\u80fd\u591f\u4ece\u6f6e\u6e7f\u7684\u5929\u7136\u6c14\u70df\u9053\u6392\u653e\u6d41\u4e2d\u6355\u83b790\uff05\u4ee5\u4e0a\u7684CO2<\/sub>\u3002\u8be5\u6750\u6599\u901a\u8fc7\u4e00\u79cd\u534f\u540c\u673a\u5236\u6355\u83b7CO2<\/sub>\uff0c\u8be5\u673a\u5236\u80fd\u591f\u5728\u8f83\u5c0f\u7684\u6e29\u5ea6\u6ce2\u52a8\u4e0b\u83b7\u5f97\u8f83\u5927\u7684CO2<\/sub>\u5faa\u73af\u80fd\u529b\uff082.4 mmol CO2 <\/sub>\/ g\uff0c\u0394T= 100\u00b0C\uff09\u3002\u91cd\u8981\u7684\u662f\uff0c\u591a\u7ec4\u5206\u5438\u9644\u5b9e\u9a8c\uff0c\u7ea2\u5916\u5149\u8c31\uff0c\u9b54\u89d2\u56fa\u6001NMR\u5149\u8c31\u548c\u8303\u5fb7\u534e\u6821\u6b63\u7684\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0c\u6c34\u901a\u8fc7\u4e0e\u6c28\u57fa\u7532\u9178\u916f\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u589e\u5f3a\u4e862-ampd-Mg2<\/sub>\uff08dobpdc\uff09\u4e2d\u7684CO2<\/sub>\u6355\u83b7\u3002 CO\u00a02<\/sub>\u5438\u9644\u5f62\u6210\u6c28\u57fa\u7532\u9178\u94f5\u94fe\u7684\u4e24\u4e2a\u57fa\u56e2\uff0c\u4ece\u800c\u589e\u52a0\u4e86CO2<\/sub>\u7ed3\u5408\u7684\u70ed\u529b\u5b66\u9a71\u52a8\u529b\u3002\u8003\u8651\u52302-ampd-Mg2<\/sub>\uff08dobpdc\uff09\u51fa\u8272\u7684\u70ed\u548c\u6c27\u5316\u7a33\u5b9a\u6027\uff0c\u5176\u9ad8\u7684CO2<\/sub>\u5438\u9644\u80fd\u529b\u4ee5\u53ca\u4ece\u6a21\u62df\u7684\u5929\u7136\u6c14\u70df\u9053\u6c14\u4e2d\u83b7\u5f97\u7684\u9ad8CO2<\/sub>\u6355\u83b7\u7387\uff0c\u8be5\u6750\u6599\u662f\u8fc4\u4eca\u4e3a\u6b62\u7528\u4e8e\u8fd9\u4e00\u5206\u79bb\u5904\u7406\u6700\u6709\u5e0c\u671b\u7684\u5438\u9644\u5242\u4e4b\u4e00\u3002<\/p>\n

\u6c34\u5bf9C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\u6548\u7387<\/b><\/strong>\u6709\u660e\u663e\u63d0\u9ad8<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2019<\/b><\/strong>\u300a<\/b><\/strong>A<\/b><\/strong>d<\/b><\/strong>v. Mater.<\/b><\/strong>\u300b<\/b><\/strong><\/span><\/p>\n

4. \u65b0\u578b\u6750\u6599\u7528\u4e8eC<\/span><\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\uff1a<\/b><\/strong><\/span>Runaway Carbon Dioxide Conversion Leads to Enhanced Uptake in a Nanohybrid Form of Porous Magnesium Borohydride<\/b><\/strong>.<\/b><\/strong><\/b>Adv. Mater., <\/i><\/b><\/em><\/strong>2019, 1904252.<\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u8fd1\u5e74\u6765\uff0c\u5229\u7528\u5206\u5b50\u6c34\u5e73\u7684\u63a7\u5236\u6765\u589e\u5f3a\u56fa\u6001\u6750\u6599\u4e2d\u7684CO2<\/sub>\u6355\u96c6\u53d7\u5230\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u6742\u5316\u7eb3\u7c73\u6750\u6599\uff0c\u8be5\u6742\u5316\u7eb3\u7c73\u6750\u6599\u7531\u672c\u5f81\u591a\u5b54\u7684\u03b3-Mg\uff08BH4<\/sub>\uff092<\/sub>\u7eb3\u7c73\u6676\u4f53\u548c\u8fd8\u539f\u7684\u6c27\u5316\u77f3\u58a8\u70ef\uff08MBHg\uff09\u6784\u6210\u3002\u8be5\u7eb3\u7c73\u6750\u6599\u8868\u73b0\u51fa\u52a8\u529b\u5b66\u53ef\u63a7\u3001\u4e0d\u53ef\u9006\u7684CO2<\/sub>\u5438\u6536\u66f2\u7ebf\uff0c\u5728\u4f4e\u5206\u538b\u548c40\u81f3100\u00b0C\u7684\u6e29\u5ea6\u4e0b\uff0c\u5177\u6709\u9ad8\u5438\u6536\u80fd\u529b\uff08> 19.9 mmol g-1\uff09\u3002\u7cfb\u7edf\u6027\u5b9e\u9a8c\u548c\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u63ed\u793a\u4e86CO2<\/sub>\u4e0eMBHg\u4e4b\u95f4\u7684\u53cd\u5e94\u673a\u7406\uff0c\u5e76\u63ed\u793a\u4e86\u5316\u5b66\u6d3b\u5316\u7684\u4e9a\u7a33\u6001\uff08BH3<\/sub>-HCOO\uff09–<\/sup>\u4e2d\u5fc3\u7684\u4f5c\u7528\uff0c\u8be5\u4e2d\u5fc3\u6bd4\u6bcd\u4f53BH4-<\/sup>\u4e2d\u5fc3\u70ed\u529b\u5b66\u4e0a\u66f4\u6709\u5229\u548c\u53ef\u80fd\u66f4\u5feb\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

http:\/\/alchemy.cchem.berkeley.edu\/static\/pdf\/papers\/paper317.pdf<\/p>\n

MBHg\u7684\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

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2018<\/b><\/strong>\u300a<\/b><\/strong>Nat<\/b><\/strong>.<\/b><\/strong>\u00a0Mater.<\/b><\/strong>\u300b<\/b><\/strong><\/span><\/p>\n

5<\/b><\/strong>. <\/b><\/strong>\u7535\u5b50\u79bb\u57df\u548c\u7535\u8377\u8fc1\u79fb\u7387\u968f\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u7684\u8fd8\u539f\u800c\u53d8\u5316\uff1a<\/b><\/strong><\/span>Electron delocalization and charge mobility as a function of reduction in a metal\u2013organic framework. <\/b><\/strong>Nat<\/i><\/b><\/em><\/strong>.\u00a0<\/i><\/b><\/em><\/strong><\/i><\/b>Mater.\u00a0<\/i><\/b><\/em><\/strong><\/i><\/b>2018, 17, 625. <\/b><\/strong><\/p>\n

\u7b80\u4ecb\uff1a<\/b><\/strong>\u5728\u8fd9\u91cc\uff0c\u6211\u4eec\u62a5\u544a\u4e86Kx<\/sub>Fe2<\/sub>\uff08BDP\uff093<\/sub>\uff080\u2264x\u22642; BDP2-<\/sup>\u00a0= 1,4-\u82ef\u4e8c\u5421\u5511\u9178\u916f\uff09\u7684\u5408\u6210\uff0c\u5176\u5728\u6bcd\u4f53\u6846\u67b6\u5185\u663e\u793a\u51fa\u5b8c\u5168\u7684\u7535\u8377\u79bb\u57df\u5316\uff0c\u5e76\u4e14\u7535\u8377\u8fc1\u79fb\u7387\u53ef\u4e0e\u6280\u672f\u4e0a\u76f8\u5173\u7684\u805a\u5408\u7269\u548c\u9676\u74f7\u5ab2\u7f8e\u3002\u901a\u8fc7\u4e00\u7cfb\u5217\u7684\u5149\u8c31\u5b66\u65b9\u6cd5\uff0c\u8ba1\u7b97\u6280\u672f\u548c\u5355\u5fae\u6676\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u6d4b\u91cf\uff0c\u4f5c\u8005\u4eec\u8bc1\u660eFe2<\/sub>\uff08BDP\uff093<\/sub>\u7684\u90e8\u5206\u8fd8\u539f\u4f1a\u5bfc\u81f4\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u663e\u793a\u51fa\u5728\u5355\u6676\u8f74\u4e0a\u8fd110,000\u500d\u7684\u7535\u5bfc\u7387\u589e\u5f3a\u3002\u5728Kx<\/sub>Fe2<\/sub>\uff08BDP\uff093<\/sub>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u4e2d\u8fbe\u5230\u8fd9\u6837\u7684\u6027\u80fd\uff0c\u4ee3\u8868\u4e86\u521b\u5efa\u65b0\u7684\u57fa\u4e8e\u591a\u5b54\u5bfc\u4f53\u7684\u5668\u4ef6\u7684\u901a\u7528\u5408\u6210\u7b56\u7565\u7684\u5b9e\u73b0\u3002<\/p>\n

http:\/\/alchemy.cchem.berkeley.edu\/static\/pdf\/papers\/paper276.pdf<\/p>\n

K<\/b><\/strong>x<\/b><\/sub><\/strong>Fe<\/b><\/strong>2<\/b><\/sub><\/strong>\uff08BDP\uff09<\/b><\/strong>3<\/b><\/sub><\/strong>\u7684\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Prof. <\/b><\/strong>Long<\/b><\/strong>\u9ad8\u88ab\u5f15<\/b><\/strong>\u8bba\u6587<\/b><\/strong>Top 5 (Google Scholar)<\/b><\/strong><\/p>\n

1. Carbon dioxide capture in metal\u2013organic frameworks. <\/b><\/strong>Chem. Rev. <\/i><\/b><\/em><\/strong>2012<\/b><\/strong>,<\/b><\/strong>112<\/b><\/strong>,<\/b><\/strong>724.<\/b><\/strong>\u00a0<\/i><\/b><\/em><\/strong>\u88ab\u5f15\u6b21\u6570\uff1a4<\/b><\/strong>586<\/b><\/strong><\/span>\u3002<\/b><\/strong><\/p>\n

2<\/b><\/strong>. <\/i><\/b><\/em><\/strong>Hydrogen storage in metal\u2013organic frameworks<\/b><\/strong>.<\/b><\/strong> Chem. Soc. Rev. <\/i><\/b><\/em><\/strong>2009, 38, 1294.<\/b><\/strong>\u00a0\u88ab\u5f15\u6b21\u6570\uff1a<\/span><\/b><\/strong>3911<\/b><\/strong><\/span>\u3002<\/b><\/strong><\/p>\n

3<\/b><\/strong>.<\/b><\/strong><\/b>Introduction to metal\u2013organic frameworks. Chem. <\/i><\/em><\/b><\/strong> Rev. <\/i><\/b><\/em><\/strong>2012<\/b><\/strong>,<\/b><\/strong>112<\/b><\/strong>,<\/b><\/strong>\u00a0673.<\/b><\/strong>\u00a0\u88ab\u5f15\u6b21\u6570\uff1a<\/span><\/b><\/strong>3468<\/b><\/strong><\/span>\u3002<\/b><\/strong><\/p>\n

4<\/b><\/strong>. \u00a0Carbon dioxide capture: prospects for new materials. Angew.\u00a0<\/em><\/b><\/strong>Chem. Int. Ed.<\/i><\/b><\/em><\/strong>2010, 49, 6058. <\/b><\/strong>\u88ab\u5f15\u6b21\u6570\uff1a<\/b><\/strong>2968<\/b><\/strong><\/span>\u3002<\/b><\/strong><\/p>\n

5<\/b><\/strong>. The pervasive chemistry of metal\u2013organic frameworks.<\/b><\/strong><\/b> Chem. Soc. Rev. <\/i><\/b><\/em><\/strong>2009, 38, 1213.<\/b><\/strong>\u88ab\u5f15\u6b21\u6570\uff1a<\/b><\/strong>1791<\/b><\/strong><\/span>\u3002<\/b><\/strong><\/p>\n

Long\u6559\u6388\u8bfe\u9898\u7ec4\u5176\u4e50<\/b><\/strong>\u878d\u878d^_^<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u672c\u6587\u7531\u8e0f\u6d6a<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5c71\u5916\u6709\u5c71\u3001\u4eba\u5916\u6709\u4eba\u3002\u79d1\u7814\u5c4a\u85cf\u9f99\u5367\u864e\uff0c\u65e0\u6570\u201c\u626b\u5730\u50e7\u201d\u6b66\u529f\u76d6\u4e16\u5374\u4f4e\u8c03\u5982\u5c18\u3002\u770b\u591a\u4e86\u5149\u73af\u7480\u74a8\u7684\u77e5\u540d\u5927\u725b\uff0c\u6750\u6599\u4eba\u5e26\u5927\u5bb6\u63a2\u9669\u79d1\u7814\u5c4a\uff0c\u4e00\u8d77\u73af\u6e38\u4e16\u754c\uff0c\u4e86\u89e3\u6750\u6599\u9886\u57df\u4e0d\u751a\u4e3a\u56fd\u4eba\u719f\u77e5…<\/p>\n","protected":false},"author":10213,"featured_media":196273,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-196255","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196255"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=196255"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196255\/revisions"}],"predecessor-version":[{"id":196390,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196255\/revisions\/196390"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/196273"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=196255"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=196255"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=196255"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}