{"id":196336,"date":"2020-02-21T06:20:48","date_gmt":"2020-02-20T22:20:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196336"},"modified":"2020-02-20T22:25:20","modified_gmt":"2020-02-20T14:25:20","slug":"%e7%99%be%e5%ae%b6%e4%ba%89%e9%b8%a3%ef%bc%81%e8%af%ba%e5%a5%96%e5%be%97%e4%b8%bbgoodenough%e3%80%81%e6%9f%93%e6%95%8f%e7%94%b5%e6%b1%a0%e4%b9%8b%e7%88%b6gratzel%e3%80%81sargent%e3%80%81abruna","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196336","title":{"rendered":"\u767e\u5bb6\u4e89\u9e23\uff01\u8bfa\u5956\u5f97\u4e3bGoodenough\u3001\u67d3\u654f\u7535\u6c60\u4e4b\u7236Gr\u00e4tzel\u3001Sargent\u3001\u4e54\u4e16\u748b\u3001\u697c\u96c4\u6587\u3001\u51af\u65b0\u4eae\u7b49\u50ac\u5316\u9886\u57df\u65b0\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u4e00\u3001\u50ac\u5316\u9886\u57df\u7814\u7a76\u80cc\u666f<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196340 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-25.png\" alt=\"\" width=\"656\" height=\"498\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-25.png 656w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-25-300x228.png 300w\" sizes=\"(max-width: 656px) 100vw, 656px\" \/><\/p>\n<p>\u50ac\u5316\u4e0e\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u7684\u65b9\u65b9\u9762\u9762\u606f\u606f\u76f8\u5173\uff0c\u662f\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u8981\u57fa\u7840\u4e4b\u4e00\u3002\u50ac\u5316\u5242\u4f7f\u4eba\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u53d1\u751f\u7ffb\u5929\u8986\u5730\u7684\u53d8\u5316\uff0c\u901a\u8fc7\u50ac\u5316\u53cd\u5e94\u53ef\u52a0\u5de5\u5404\u7c7b\u4ea7\u54c1\uff0c\u56e0\u6b64\u50ac\u5316\u5f71\u54cd\u7740\u4eba\u4eec\u8863\u98df\u4f4f\u884c\u7684\u65b9\u65b9\u9762\u9762\uff0c\u53d1\u6325\u7740\u8d85\u4e4e\u5bfb\u5e38\u7684\u91cd\u8981\u4f5c\u7528\u3002\u56e0\u5728\u5316\u5b66\u548c\u80fd\u6e90\u5de5\u4e1a\u7684\u7b49\u8bb8\u591a\u9886\u57df\u53d6\u5f97\u7684\u5f00\u521b\u6027\u5de5\u4f5c\uff0c\u5df2\u6709\u56db\u4f4d\u79d1\u5b66\u5de8\u64d8\u83b7\u5f97\u8bfa\u8d1d\u5c14\u5956\uff0cFritz Haber\u3001CarlBosch\u3001Irving Langmuir\u548cGerhardErtl\u5206\u522b\u4e8e1918\u5e74\u30011931\u5e74\u30011932\u5e74\u548c2007\u5e74\u83b7\u5f97\u8fc7\u8bfa\u8d1d\u5c14\u5956\u3002\u4e0b\u9762\u6211\u4eec\u5217\u4e3e\u4e86\u56fd\u5916\u5b66\u672f\u5927\u5496\u50ac\u5316\u9886\u57df\u7814\u7a76\u6709\u5173\u7684\u90e8\u5206\u4ee3\u8868\u6027\u6210\u679c\uff0c\u4e00\u8d77\u4ea4\u6d41\u63a2\u8ba8\u3002<\/p>\n<p><strong><b>\u4e8c\u3001\u8d85\u7ea7\u5927\u5496\u6700\u65b0\u79d1\u7814\u6210\u679c\u6c47\u603b<\/b><\/strong><\/p>\n<p><strong><b>1\u3001<\/b><\/strong><strong><b>A<\/b><\/strong><strong><b>ngew: <\/b><\/strong><strong><b>\u8d85\u7ec6Pt<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>M\u6709\u5e8f\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u5408\u6210\u7684<\/b><\/strong><strong><b>\u901a\u7528<\/b><\/strong><strong><b>\u7b56\u7565<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196341 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-21.png\" alt=\"\" width=\"530\" height=\"458\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-21.png 530w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-21-300x259.png 300w\" sizes=\"(max-width: 530px) 100vw, 530px\" \/><\/p>\n<p><strong><b>\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5f97\u4e3bJohn B. Goodenough\u6559\u6388<\/b><\/strong><strong><b>\u4e0e\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u5d14\u5fd7\u660e\u6559\u6388\u7b49<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u3001\u5e94\u7528\u5e7f\u6cdb\u7684\u6c34\u51dd\u80f6\u51b7\u51bb\u5e72\u71e5\u65b9\u6cd5\uff0c\u7528\u4e8e\u5236\u5907\u8d85\u5c0f\u9897\u7c92\u5c3a\u5bf8\u7684\u9ad8\u6709\u5e8fPt-M\uff08M=Mn\u3001Cr\u3001Fe\u3001Co\u7b49\uff09\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u50ac\u5316\u5242\uff0c\u6210\u4e3a\u5b9e\u73b0\u5b9e\u7528\u71c3\u6599\u7535\u6c60\u7684\u4e00\u7c7b\u975e\u5e38\u7406\u60f3\u7684\u6750\u6599\u3002\u5728\u8fd9\u79cd\u65b9\u6cd5\u4e2d\uff0c\u6c34\u51dd\u80f6\u53ef\u4ee5\u5c06\u5806\u79ef\u7684GO\u7247\u5265\u79bb\u6210\u5355\u4e2a\u7684GO\u7247\uff0c\u5e76\u663e\u8457\u4fc3\u8fdb\u7eb3\u7c73\u7c92\u5b50\u7684\u826f\u597d\u5206\u6563\u3002\u672c\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u578b\u4e14\u7b80\u4fbf\u7684\u6c34\u51dd\u80f6\u51b7\u51bb\u5e72\u71e5\u7b56\u7565\uff0c\u53ef\u63a8\u5e7f\u5230\u5176\u5b83\u5408\u91d1\u50ac\u5316\u5242\u7684\u63a7\u5236\u5408\u6210\uff0c\u5305\u62ec\u4f46\u4e0d\u9650\u4e8e\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u548c\u5176\u5b83\u7535\u5316\u5b66\u80fd\u6e90\u88c5\u7f6e\u7684\u94c2\u57fa\u5408\u91d1\u548c\u94af\u57fa\u5408\u91d1\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1002\/anie.201916260<\/p>\n<p><strong><b>2\u3001<\/b><\/strong><strong><b>Joule: \u9499\u949b\u77ff\/\u7845\u4e32\u8054\u7535\u6c60\u548cTiC\u8d1f\u8f7dPt\u7eb3\u7c73\u7c07\u7535\u50ac\u5316\u5242\u7528\u4e8e\u592a\u9633\u80fd\u6c34\u5206\u89e3<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196342 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-21.png\" alt=\"\" width=\"630\" height=\"630\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-21.png 630w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-21-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-21-300x300.png 300w\" sizes=\"(max-width: 630px) 100vw, 630px\" \/><\/p>\n<p><strong><b>\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5927\u5b66\u7684Michael Gr\u00e4tzel<\/b><\/strong>\u548c<strong><b>\u5357\u5f00\u5927\u5b66\u7684Jingshan Luo\u6559\u6388<\/b><\/strong>\u8bc1\u660e\u4e86\u539f\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u80fd\u591f\u5728CC\/TiO<sub>2<\/sub>\u548cCC\/TiC\u57fa\u5e95\u4e0a\u5747\u5300\u5730\u5206\u6563\u5c0f\u7684Pt\u7eb3\u7c73\u56e2\u7c07\u3002\u91c7\u7528\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u949b\u57fa\u57fa\u5e95\uff0c\u53ef\u4ee5\u4ea7\u751f\u5f88\u5f3a\u7684\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u5bf9\u63d0\u9ad8\u94c2\u7eb3\u7c73\u7c07\u50ac\u5316\u5242\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u8d77\u5230\u4e86\u5173\u952e\u4f5c\u7528\u3002\u5c06\u9499\u949b\u77ff\/Si\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u76f4\u63a5\u8fde\u63a5\u5230\u7535\u89e3\u69fd\uff0c\u53ef\u63d0\u4f9b\u5145\u8db3\u4e14\u51c6\u7406\u60f3\u7684\u5149\u7535\u538b\uff0c\u5728\u4e0d\u4f7f\u7528\u4efb\u4f55\u7535\u538b\u8f6c\u6362\u5668\u7684\u60c5\u51b5\u4e0b\u5b9e\u73b0\u9ad8\u6548\u7684\u6574\u4f53\u6c34\u5206\u89e3\uff0c\u4f7f\u6574\u4e2a\u7cfb\u7edf\u5728\u6807\u51c6AM 1.5 G\u7167\u660e\u4e0b\u7684STH\u8f6c\u6362\u6548\u7387\u8fbe\u523018.7%\u3002\u8be5\u5de5\u4f5c\u5c55\u793a\u4e86\u4e00\u4e2a\u9ad8\u6548\u7684\u592a\u9633\u80fd\u6c34\u5206\u89e3\u7cfb\u7edf\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1016\/j.joule.2019.10.002<\/p>\n<p><strong><b>3<\/b><\/strong><strong><b>\u3001<\/b><\/strong><strong><b>Science\uff1a\u5728\u5927\u4e8e1 A cm<\/b><\/strong><strong><sup><b>-2<\/b><\/sup><\/strong><strong><b>\u4e0b<\/b><\/strong><strong><b>\u9ad8\u6548\u7535\u89e3CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u751f<\/b><\/strong><strong><b>\u6210\u591a\u78b3<\/b><\/strong><strong><b>\u4ea7\u7269<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-196343\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-20.png\" alt=\"\" width=\"680\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-20.png 1359w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-20-300x206.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-20-768x528.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-20-1024x704.png 1024w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66\u7684Edward H. Sargent \u548cDavid Sinton\u56e2\u961f<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u6df7\u5408\u50ac\u5316\u5242\u8bbe\u8ba1\uff0c\u901a\u8fc7\u5206\u79bb\u6c14\u4f53\u3001\u79bb\u5b50\u548c\u7535\u5b50\u8f93\u8fd0\uff0c\u4f7fCO<sub>2<\/sub>\u548cCO\u6c14\u76f8\u7535\u89e3\u5728\u7535\u6d41\u5bc6\u5ea6\u5927\u4e8e1<strong><b>\u00a0<\/b><\/strong>A cm<sup>-2<\/sup>\u7684\u60c5\u51b5\u4e0b\u80fd\u591f\u4ea7\u751f\u591a\u78b3\u4ea7\u54c1\u3002\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u79cd\u5177\u6709\u758f\u6c34\u548c\u4eb2\u6c34\u529f\u80fd\u7684\u79bb\u805a\u7269\u5c42\uff0c\u8be5\u79bb\u805a\u7269\u5c42\u4e0e\u6709\u5229\u4e8e\u6c14\u4f53\u548c\u79bb\u5b50\u5728\u91d1\u5c5e\u8868\u9762\u5171\u5f62\u4f20\u8f93\u8def\u5f84\u7684\u4e0d\u540c\u7ed3\u6784\u57df\u7ed3\u5408\u5728\u4e00\u8d77\uff1a\u901a\u8fc7\u758f\u6c34\u7ed3\u6784\u57df\u7684\u4fa7\u94fe\u4fc3\u8fdb\u6c14\u4f53\u4f20\u8f93\uff0c\u5bfc\u81f4\u6c14\u4f53\u6269\u6563\uff0c\u800c\u6c34\u5438\u6536\u548c\u79bb\u5b50\u901a\u8fc7\u6c34\u5408\u4eb2\u6c34\u7ed3\u6784\u57df\u8fdb\u884c\u4f20\u8f93\u3002\u7ed3\u679c\uff0c\u8fd9\u4e09\u79cd\u7ec4\u5206\u805a\u96c6\u5728\u4e00\u8d77\u7684\u53cd\u5e94\u754c\u9762\uff0c\u6c14\u4f53\u53cd\u5e94\u7269\u3001\u79bb\u5b50\u548c\u7535\u5b50\u90fd\u5728\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff0c\u4ece\u4e9a\u5fae\u7c73\u8303\u56f4\u589e\u52a0\u5230\u4e86\u51e0\u4e2a\u5fae\u7c73\u7684\u5c3a\u5ea6\u3002\u672c\u6587\u6240\u63cf\u8ff0\u7684\u73b0\u8c61\u5c55\u793a\u4e86\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u539f\u5219\uff0c\u8fd9\u4e9b\u539f\u5219\u4e0d\u53d7\u5148\u524d\u7684\u6c14-\u79bb\u5b50-\u7535\u5b50\u4f20\u8f93\u9650\u5236\u7684\u7ea6\u675f\u3002CIBH\u50ac\u5316\u5242\u4e3a\u5b9e\u73b0\u5de5\u4e1a\u5e94\u7528\u6240\u9700\u7684\u64cd\u4f5c\u7535\u6d41\u7684\u70c3\u751f\u4ea7\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/science.sciencemag.org\/content\/367\/6478\/661\u00a0<\/p>\n<p><strong><b>4\u3001<\/b><\/strong><strong><b>Adv. Energy Mater.<\/b><\/strong><strong><b>\uff1a\u534a\u5bfc\u4f53\u5149\u50ac\u5316CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u8fd8\u539f\u7684\u539f\u5b50\u7ea7\u53cd\u5e94\u4e2d\u5fc3<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196344 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-19.png\" alt=\"\" width=\"623\" height=\"400\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-19.png 623w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-19-300x193.png 300w\" sizes=\"(max-width: 623px) 100vw, 623px\" \/><\/p>\n<p><strong><b>\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u5316\u5de5\u4e0e\u5148\u8fdb\u6750\u6599\u5b66\u9662\u4e54\u4e16\u748b\u6559\u6388\u548c\u5189\u666f\u6da6\u7b49\u4eba<\/b><\/strong>\u4ece\u539f\u5b50\u7ea7\u7684\u89d2\u5ea6\u63d0\u51fa\u4e86\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u5e76\u5bf9\u539f\u5b50\u80fd\u5229\u7528\u6548\u7387\u548c\u9ad8\u9009\u62e9\u6027\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u7814\u7a76\uff0c\u4e3a\u8bbe\u8ba1\u548c\u5408\u6210\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u5b9e\u7528\u7684\u6307\u5bfc\u3002\u6b64\u5916\uff0c\u8fd8\u5bf9\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u5404\u79cd\u53cd\u5e94\u4f4d\u70b9\uff0c\u4ee5\u53ca\u8868\u5f81\u65b9\u6cd5\u3001\u529f\u80fd\u548c\u673a\u5236\u8fdb\u884c\u4e86\u6279\u5224\u6027\u8bc4\u4f30\u548c\u5168\u9762\u5ba1\u67e5\u3002\u5728\u6df1\u5165\u4e86\u89e3\u7684\u57fa\u7840\u4e0a\uff0c\u5c55\u671b\u4e86\u5236\u5907\u9ad8\u6548\u5149\u50ac\u5316\u5242\u7684\u524d\u666f\u3002\u7efc\u8ff0\u4e86\u5236\u5907\u591a\u6d3b\u6027\u4f4d\u70b9\u7684\u65b0\u7b56\u7565\u548c\u65b0\u65b9\u6cd5\uff0c\u5982\u53cc\u7a7a\u4f4d\u3001\u6d3b\u6027\u4f4d\u70b9\u7684\u4e0d\u540c\u7ec4\u5206\u3001FLPs\u7b49\u3002\u7efc\u8ff0\u4e86\u4e0d\u540c\u6750\u6599\u7684CO<sub>2<\/sub>\u5149\u8fd8\u539f\u9014\u5f84\u548c\u5173\u952e\u5f71\u54cd\u56e0\u7d20\uff0c\u5e76\u5bf9\u9ad8\u9009\u62e9\u6027\u6750\u6599\u7684\u8bbe\u8ba1\u8fdb\u884c\u4e86\u8ba8\u8bba\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1002\/aenm.201903879<\/p>\n<p><strong><b>5<\/b><\/strong><strong><b>\u3001<\/b><\/strong><strong><b>Joule\uff1a\u80fd\u91cf\u8f6c\u6362\u6280\u672f\u4e2d<\/b><\/strong><strong><b>ORR\u5148\u8fdb\u7535\u50ac\u5316\u5242\u7684\u7814\u7a76\u8fdb\u5c55<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196346 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-16.png\" alt=\"\" width=\"685\" height=\"306\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-16.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-16-300x134.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong><b>\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u7684\u697c\u96c4\u6587\u6559\u6388\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u7684\u590f\u5b9d\u7389\u6559\u6388<\/b><\/strong>\u7b49\u4eba\u7efc\u8ff0\u4e86\u65b0\u578b\u50ac\u5316\u5242\u5728\u66f4\u6613\u83b7\u5f97\u548c\u66f4\u5b9e\u7528\u7684\u9178\u6027\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002\u9996\u5148\uff0c\u7b80\u8981\u8ba8\u8bba\u4e86ORR\u7684\u52a8\u529b\u5b66\u548c\u673a\u7406\uff0c\u7136\u540e\u5c06ORR\u7535\u50ac\u5316\u5242\u5206\u4e3a\u56db\u5927\u7c7b\uff1aPGM\u6216\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3001\u975ePGM\u50ac\u5316\u5242\u3001\u78b3\u57fa\u50ac\u5316\u5242\u548c\u5355\u539f\u5b50\u50ac\u5316\u5242\u3002\u6587\u4e2d\u8fd8\u7b80\u8981\u4ecb\u7ecd\u4e86\u8fd9\u56db\u79cd\u50ac\u5316\u5242\u7684\u5408\u6210\u65b9\u6cd5\u3001\u8868\u5f81\u548c\u5e94\u7528\u3002\u6b64\u5916\uff0c\u5206\u6790\u7684\u5f88\u5927\u4e00\u90e8\u5206\u662f\u5173\u4e8e\u4e3a\u4ec0\u4e48\u4ee5\u53ca\u5982\u4f55\u5408\u7406\u5730\u8bbe\u8ba1\u7535\u50ac\u5316\u5242\u514b\u670d\u7f13\u6162\u6216\u52a8\u529b\u5b66\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5728\u6574\u4e2a\u5ba1\u67e5\u8fc7\u7a0b\u4e2d\uff0c\u4f5c\u8005\u7740\u91cd\u4e8e\u5b9e\u9645\u5e94\u7528\uff0c\u8ba8\u8bba\u4e86\u66ff\u4ee3\u6027\u7535\u50ac\u5316\u5242\u7684\u6311\u6218\u548c\u673a\u9047\uff0c\u8fd9\u53ef\u80fd\u6709\u52a9\u4e8e\u4e3a\u71c3\u6599\u7535\u6c60\u548c\u5176\u4ed6\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u7684\u5546\u4e1a\u5316\u5f00\u53d1\u66f4\u7406\u60f3\u7684\u6750\u6599\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>http:\/\/doi.org\/10.1016\/j.joule.2019.12.014<\/p>\n<p><strong><b>6\u3001<\/b><\/strong><strong><b>Adv. Funct. Mater.<\/b><\/strong><strong><b>\uff1a\u4ece\u51e0\u4f55\u5230\u6d3b\u6027\uff1a\u5149\u7535\u5316\u5b66\u6c34\u88c2\u89e3WO<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>\/Si\u5fae\u67f1\u9635\u5217\u7684\u5b9a\u91cf\u5206\u6790<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196347 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-11.png\" alt=\"\" width=\"803\" height=\"671\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-11.png 803w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-11-300x251.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-11-768x642.png 768w\" sizes=\"(max-width: 803px) 100vw, 803px\" \/><\/p>\n<p><strong><b>\u8377\u5170\u57fa\u7840\u80fd\u6e90\u7814\u7a76\u6240\u7684Anja Bieberle\u2010H\u00fctter\u7b49\u4eba<\/b><\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u6709\u524d\u9014\u7684\u5fae\u8154\u9635\u5217\u7ed3\u6784\u5149\u7535\u7ba1\u3002\u5149\u5b66\u4eff\u771f\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u7ed3\u6784\u80fd\u6709\u6548\u5730\u964d\u4f4e\u5149\u7167\u4e0b\u7684\u9634\u5f71\u6548\u5e94\u3002\u5728WO<sub>3<\/sub>\/pn-Si\u5fae\u67f1\u9635\u5217\u4e2d\uff0c\u968f\u7740\u67f1\u5bc6\u5ea6\u7684\u589e\u52a0\uff0c\u5149\u7535\u6d41\u5bc6\u5ea6\u5148\u589e\u5927\u540e\u51cf\u5c0f\u3002\u901a\u8fc7\u6d4b\u91cf\u65a9\u6ce2\u5355\u8272\u7ea2\u5916\u7167\u660e\u4e0b\u7684\u5f00\u8def\u7535\u4f4d\uff0c\u8bc1\u660eWO<sub>3<\/sub>\/pn-Si\u5fae\u67f1\u9635\u5217\u7684\u5149\u7535\u6d41\u5bc6\u5ea6\u589e\u5f3a\u662f\u7531p-n\u7ed3\u4ea7\u751f\u7684\u5149\u7535\u538b\u51b3\u5b9a\u7684\u3002\u7136\u800c\uff0c\u968f\u7740\u67f1\u95f4\u8ddd\u7684\u51cf\u5c0f\uff0c\u589e\u5927\u7684\u8868\u9762\u79ef\u4e5f\u4f1a\u5bfc\u81f4\u6b7b\u533a\uff08\u5373\u91cdp\u63ba\u6742Si\u8868\u9762\uff09\u7684\u589e\u52a0\uff0c\u4ece\u800c\u964d\u4f4ep-n\u7ed3\u4ea7\u751f\u7684\u5149\u7535\u538b\uff0c\u4ece\u800c\u964d\u4f4e\u5149\u7535\u6d41\u5bc6\u5ea6\u7684\u589e\u5f3a\u3002\u8fd9\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u4e2a\u66f4\u6df1\u5165\u7684\u4e86\u89e3\u4e09\u7ef4\u51e0\u4f55\u7ed3\u6784\u5bf9\u4f7f\u7528\u5b9a\u4e49\u826f\u597d\u7684WO<sub>3<\/sub>\/n-Si\u548cWO<sub>3<\/sub>\/pn-Si\u5fae\u67f1\u9635\u5217\u7684PEC\u6027\u80fd\u7684\u5f71\u54cd\u3002\u7535\u6781\u660e\u786e\u7684\u51e0\u4f55\u7ed3\u6784\u9996\u6b21\u5c06\u5149\u5bc6\u5ea6\u5206\u5e03\u548c\u5149\u7535\u6781\u7684\u5fae\u89c2\u7ed3\u6784\u51e0\u4f55\u7ed3\u6784\u8054\u7cfb\u8d77\u6765\uff0c\u4ece\u800c\u8868\u8fbe\u4e86\u8fd9\u79cd\u5173\u7cfb\u5bf9PEC\u6027\u80fd\u7684\u5f71\u54cd\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u663e\u793a\u4e86\u7845\u52a0\u5de5\u5728\u4e09\u7ef4\u7eb3\u7c73\/\u5fae\u7ed3\u6784\u5b9a\u5236\u8bbe\u8ba1\u548c\u9ad8\u6027\u80fd\u7535\u6781\u65b9\u9762\u7684\u6f5c\u529b\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1002\/adfm.201909157<\/p>\n<p><strong><b>7<\/b><\/strong><strong><b>\u3001<\/b><\/strong><strong><b>JACS\uff1a<\/b><\/strong><strong><b>\u8f93\u8fd0\u6761\u4ef6\u4e0b\u91d1\u7535\u6781\u4e0aCO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u8fd8\u539f\u4e0e\u6790\u6c22\u7684\u7ade\u4e89<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-196348\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-11.png\" alt=\"\" width=\"680\" height=\"555\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-11.png 891w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-11-300x245.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-11-768x627.png 768w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>\u83b1\u987f\u5927\u5b66Marc Koper\u6559\u6388\u8bfe\u9898\u7ec4<\/b><\/strong>\u5c55\u793a\u4e86\u5728\u826f\u597d\u5b9a\u4e49\u7684\u8d28\u91cf\u8f93\u9001\u6761\u4ef6\u4e0b\uff0cCO<sub>2<\/sub>RR\u7684\u901f\u7387\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u72ec\u7acb\u4e8e\u8d28\u91cf\u8f93\u8fd0\u6548\u5e94\uff08\u5373\u76d8\u65cb\u8f6c\u901f\u7387\uff09\u3002\u7136\u800c\uff0c\u7531\u4e8eHER\u901f\u7387\u7684\u964d\u4f4e\uff0cCO<sub>2<\/sub>RR\u7684\u6cd5\u62c9\u7b2c\u9009\u62e9\u6027\u968f\u7740\u5706\u76d8\u8f6c\u901f\u7684\u589e\u52a0\u800c\u63d0\u9ad8\uff08\u8d28\u91cf\u8f93\u8fd0\u589e\u5f3a\uff09\u3002\u7ed3\u679c\u8868\u660e\uff0c\u57280.1m\u78b3\u9178\u6c22\u76d0\u6d53\u5ea6\u4e0b\uff0c\u6c34\u7684\u8fd8\u539f\u4f5c\u7528\u662f\u5176\u4e0eCO<sub>2<\/sub>RR\u7ade\u4e89\u7684\u4f18\u52bf\u5206\u652f\uff0c\u800c\u589e\u5f3a\u7684\u8d28\u91cf\u8f93\u8fd0\u672c\u8d28\u4e0a\u7f13\u89e3\u4e86\u5c40\u90e8\u78b1\u5ea6\uff0c\u4ece\u800c\u6291\u5236\u4e86\u6c34\u7684\u8fd8\u539f\u901f\u7387\u3002\u8be5\u5de5\u4f5c\u8868\u660e\uff0c\u63a7\u5236\u8d28\u91cf\u8f93\u8fd0\u6761\u4ef6\u5bf9\u9009\u62e9\u6027CO<sub>2<\/sub>RR\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\uff0c\u5e76\u4e3a\u5b9e\u9645\u7535\u6781\u7ed3\u6784\u4e2d\u7684\u6d53\u5ea6\u68af\u5ea6\u548c\u4ea7\u7269\u9009\u62e9\u6027\u63d0\u4f9b\u4e86\u5408\u7406\u7684\u6307\u5bfc\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.9b10061<\/p>\n<p><strong><b>8<\/b><\/strong><strong><b>\u3001<\/b><\/strong><strong><b>JACS\uff1a<\/b><\/strong><strong><b>\u4e09\u660e\u6cbb\u7c07\u5408\u7eb3\u7c73\u50ac\u5316\u5242ZIF-8@Au<\/b><\/strong><strong><sub><b>25<\/b><\/sub><\/strong><strong><b>@ZIF-67\u7684\u8bbe\u8ba1\u4e0e\u9ad8\u6548\u6027<\/b><\/strong><strong><b>\u7814\u7a76<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196349 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-12.png\" alt=\"\" width=\"539\" height=\"433\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-12.png 539w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-12-300x241.png 300w\" sizes=\"(max-width: 539px) 100vw, 539px\" \/><\/p>\n<p><strong><b>\u6cd5\u56fd\u6ce2\u5c14\u591a\u4e00\u5927Didier Astruc\u3001\u5b89\u5fbd\u5927\u5b66\u6731\u6ee1\u6d32\u548c\u76db\u9e3f\u5a77\u7b49\u4eba<\/b><\/strong>\u5408\u4f5c\u9996\u6b21\u5f00\u53d1\u4e86\u4e00\u79cd\u534f\u540c\u8f85\u52a9\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6765\u63a7\u5236\u4e09\u660e\u6cbbZIF-8@Au<sub>25<\/sub>@ZIF-8[tkn]\u548cZIF-8@Au<sub>25<\/sub>@ZIF67[tkn]\u7684\u5236\u9020\u3002\u8fd9\u4e9b\u5b9a\u4e49\u660e\u786e\u7684\u590d\u5408\u6750\u6599\u540c\u65f6\u63d0\u9ad8\u4e86CO<sub>2<\/sub>\u548c4-NP\u52a0\u6c22\u4f5c\u7528\u4e0b\u672b\u7aef\u7094\u70c3\u7fa7\u5316\u53cd\u5e94\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u6709\u8da3\u7684\u662f\uff0c\u901a\u8fc7\u7cbe\u786e\u8c03\u6574\u58f3\u539a\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u4f18\u5316\u4e09\u660e\u6cbb\u4f53\u7cfb\u7684\u50ac\u5316\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u5de5\u4f5c\u5e94\u8be5\u6fc0\u53d1\u4e86\u7eb3\u7c73\u5316\u5b66\u5bb6\u5bf9\u8bbe\u8ba1\u6027\u80fd\u5b8c\u7f8e\u7684\u4e09\u660e\u6cbb\u590d\u5408\u6750\u6599MOF@APNC@MOF\u7684\u5174\u8da3\uff0c\u4e3a\u7eb3\u7c73\u6750\u6599\u7814\u7a76\u5f00\u8f9f\u4e86\u65b0\u7684\u89c6\u91ce\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c00378<\/p>\n<p><strong><b>9<\/b><\/strong><strong><b>\u3001<\/b><\/strong><strong><b>JACS: <\/b><\/strong><strong><b>\u78b1\u6027\u71c3\u6599\u7535\u6c60\u94af\u57fa\u6c27\u8fd8\u539f\u7535\u50ac\u5316\u5242\u7684\u7ec4\u5408\u7814\u7a76<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196350 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u724710-9.png\" alt=\"\" width=\"720\" height=\"776\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u724710-9.png 720w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/02\/\u56fe\u724710-9-278x300.png 278w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p><strong><b>\u5eb7\u5948\u5c14\u5927\u5b66<\/b><\/strong><strong><b>H<\/b><\/strong><strong><b>\u00e9<\/b><\/strong><strong><b>ctor D. Abru\u00f1a<\/b><\/strong><strong><b>\u548c<\/b><\/strong><strong><b>R. Bruce van Dover<\/b><\/strong><strong><b>\u7b49\u4eba<\/b><\/strong>\u62a5\u544a\u4e86\u4e00\u79cd\u4ee5\u53ef\u66ff\u6362\u7684\u73bb\u7483\u78b3\u76d8\u7535\u6781\u4e3a\u57fa\u5e95\u7684\u7b80\u4fbf\u50ac\u5316\u5242\u7b5b\u9009\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u80fd\u591f\u4f7f\u7528\u6807\u51c6RDE\u6d4b\u91cf\u5feb\u901f\u53ef\u9760\u5730\u8bc4\u4f30ORR\u6d3b\u6027\u3002\u91c7\u7528\u9ad8\u901a\u91cf\u78c1\u63a7\u6e85\u5c04\u5ba4\uff0c\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5236\u5907\u4e86\u4e8c\u5143Pd-Cu\u56fa\u6eb6\u4f53\u7535\u50ac\u5316\u5242\u8584\u819c\u3002\u57289\u79cd\u4e0d\u540c\u7684Pd-Cu\u5408\u91d1\u6210\u5206\u4e2d\uff0cPd<sub>50<\/sub>Cu<sub>50<\/sub>\uff08\u53731:1\u6469\u5c14\u6bd4\uff0c\u6216\u4ec5PdCu\uff09\u662f\u6700\u6709\u524d\u9014\u7684\u5019\u9009\u6210\u5206\u3002\u5728\u6b64\u6307\u5bfc\u4e0b\uff0c\u7814\u7a76\u4eba\u5458\u91c7\u7528\u6d78\u6e0d\u8fd8\u539f\u6cd5\u8fdb\u4e00\u6b65\u5408\u6210\u4e86Pd<sub>50<\/sub>Cu<sub>50<\/sub>\u7eb3\u7c73\u7c92\u5b50\uff0c\u5728\u78b1\u6027\u7535\u5316\u5b66\u4f53\u7cfb\u4e2d\u663e\u793a\u51fa\u826f\u597d\u7684\u6d3b\u6027\u548c\u8010\u4e45\u6027\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1021\/jacs.9b13400<\/p>\n<p>\u672c\u6587\u7531<strong>eric<\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u50ac\u5316\u9886\u57df\u7814\u7a76\u80cc\u666f \u50ac\u5316\u4e0e\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u7684\u65b9\u65b9\u9762\u9762\u606f\u606f\u76f8\u5173\uff0c\u662f\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u8981\u57fa\u7840\u4e4b\u4e00\u3002\u50ac\u5316\u5242\u4f7f\u4eba\u4eec\u7684\u65e5\u5e38\u751f\u6d3b\u53d1\u751f\u7ffb\u5929\u8986\u5730\u7684\u53d8\u5316\uff0c\u901a\u8fc7\u50ac\u5316\u53cd\u5e94\u53ef\u52a0\u5de5\u5404\u7c7b&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":196315,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-196336","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196336"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=196336"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196336\/revisions"}],"predecessor-version":[{"id":196500,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196336\/revisions\/196500"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/196315"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=196336"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=196336"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=196336"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}