{"id":196455,"date":"2020-02-27T06:22:31","date_gmt":"2020-02-26T22:22:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196455"},"modified":"2020-02-25T19:05:26","modified_gmt":"2020-02-25T11:05:26","slug":"28%e5%b2%81%e4%be%bf%e6%88%90%e4%b8%ba%e5%b9%b4%e8%bd%bb%e5%8d%9a%e5%af%bc%ef%bc%9a%e5%8c%97%e7%90%86%e5%b7%a5%e7%8e%8b%e5%8d%9a%e3%80%81%e6%b5%99%e5%a4%a7%e9%99%86%e7%9b%88%e7%9b%88%e3%80%81%e5%8c%97","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196455","title":{"rendered":"28\u5c81\u4fbf\u6210\u4e3a\u5e74\u8f7b\u535a\u5bfc\uff1a\u5317\u7406\u5de5\u738b\u535a\u3001\u6d59\u5927\u9646\u76c8\u76c8\u3001\u5317\u822a\u5bab\u52c7\u54092019\u5de5\u4f5c\u7eaa\u5b9e"},"content":{"rendered":"

\u738b\u535a<\/b><\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd<\/b><\/strong>\uff1a<\/b><\/strong>\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u5e38\u52a1\u526f\u9662\u957f\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u515a\u59d4\u5e38\u59d4\u3001\u526f\u6821\u957f\u300228\u5c81\u65f6\u5165\u9009\u201c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6770\u51fa\u4e2d\u9752\u5e74\u6559\u5e08\u53d1\u5c55\u652f\u6301\u8ba1\u5212\u201d\uff0c\u6210\u4e3a\u5b66\u6821\u6700\u5e74\u8f7b\u7684\u6559\u6388\u3001\u535a\u5bfc\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u4f5c\u4e3a\u7b2c\u4e00\u4f5c\u8005\u6216\u4e3b\u8981\u5b8c\u6210\u4eba\u5728\u56fd\u9645\u9876\u7ea7\u5b66\u672f\u671f\u520aNature\u3001Science\u7b49\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u886860\u4f59\u7bc7\u8bba\u6587\uff0c\u8bba\u6587SCI\u4ed6\u5f15\u8d85\u8fc78000\u6b21\uff1b\u83b7\u7f8e\u56fd\u6388\u6743\u4e13\u52296\u9879\uff0c\u83b7\u4e2d\u56fd\u6388\u6743\u53d1\u660e\u4e13\u52293\u9879\u3002<\/p>\n

\u5de5\u4f5c\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n

\u957f\u671f\u4ece\u4e8bMOF\u6750\u6599\u7814\u7a76\uff0c\u7814\u53d1\u7684MOF\u6750\u6599\u80fd\u8fc7\u6ee4PM2.5\u3001\u5206\u89e3\u81ed\u6c27\uff0c\u5df2\u88ab\u5e94\u7528\u4e8e\u7a7a\u6c14\u51c0\u5316\u5668\u7b49\u3002\u4e3b\u6301\u5f00\u53d1\u7684\u96fe\u973e\u6ee4\u6e05\u3001\u5371\u5316\u7269\u964d\u89e3\u6280\u672f\u5bf9\u5927\u6c14\u6c61\u67d3\u6cbb\u7406\u5177\u6709\u5f88\u9ad8\u7684\u4ef7\u503c\u548c\u793e\u4f1a\u6548\u76ca\uff0c\u4e3a\u9996\u90fd\u73af\u4fdd\u4e8b\u4e1a\u505a\u51fa\u4e86\u8d21\u732e\uff1b<\/p>\n

\u56fd\u9645\u8303\u56f4\u5185\u9996\u6b21\u63d0\u51fa\u5e76\u53d1\u5c55\u4e86\u7eb3\u7c73\u7a7f\u63d2\u7f16\u7ec7(Interweaving)\u548c\u5408\u6210\u540e\u805a\u5408(PSP)\u7b49\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u8584\u819c\u6750\u6599\u7684\u65b0\u9896\u7684\u8bbe\u8ba1\u5408\u6210\u65b9\u6cd5\u5b66\uff0c\u5b9e\u73b0\u4e86MOF\u6750\u6599\u7684\u529f\u80fd\u5316\u4e0e\u5668\u4ef6\u5316\uff0c\u8d4b\u4e88MOF\u8584\u819c\u5728\u7206\u70b8\u7269\u68c0\u6d4b\u548c\u7eff\u8272\u50a8\u80fd\u7b49\u9886\u57df\u7684\u65b0\u529f\u80fd\u548c\u65b0\u5e94\u7528\uff1b<\/p>\n

\u53c2\u4e0eMOF\u6750\u6599\u7684\u5de5\u4e1a\u5316\u91cf\u4ea7\u7814\u7a76\uff0c\u5b9e\u73b0\u4e86MOF\u5428\u7ea7\u4e2d\u8bd5\uff0c\u53c2\u4e0eMOF\u8f66\u7528\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6c22\u6c14\u3001\u7532\u70f7\u5206\u79bb\u5236\u5907\u4e0e\u50a8\u5b58\u6280\u672f\u7b49\u5de5\u4e1a\u5316\u5e94\u7528\u7814\u7a76\u3002<\/p>\n

2019\u5e74\u53d1\u6587\u60c5\u51b5\uff1a<\/b><\/strong><\/p>\n

\u57fa\u4e8eWeb of Science\u6570\u636e\uff0c2019\u5e74SCI\u53d1\u658750\u7bc7\uff0c\u5176\u4e2d\u5305\u62ecEES.\u3001Nature Commun.\u3001JACS\u3001Angew.\u7b49\u3002<\/p>\n

\u90e8\u5206\u5de5\u4f5c\u8d4f\u6790<\/b><\/strong><\/p>\n

\u8d85\u9ad8MOF\u62c5\u8f7d\u91cf\u819c\u5438\u9644\u5668\u7528\u4e8e\u9ad8\u6548\u5206\u79bb\uff5cNature Commun.<\/b><\/strong><\/p>\n

\u5177\u6709\u9ad8\u5b54\u9699\u7387\u548c\u53ef\u8bbe\u8ba1\u529f\u80fd\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5177\u6709\u9ad8\u6e17\u900f\u7387\u548c\u9ad8\u9009\u62e9\u6027\u7684\u4f18\u70b9\u3002\u7136\u800c\uff0c\u5236\u9020\u5177\u6709\u826f\u597d\u67d4\u6027\u548c\u8d85\u9ad8MOF\u8d1f\u8f7d\u7684\u6df7\u5408\u57fa\u8d28\u819c(MMMs)\u7684\u53ef\u6269\u5c55\u5236\u9020\u65b9\u6cd5\u662f\u8feb\u5207\u9700\u8981\u7684\uff0c\u4f46\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u8fd8\u6ca1\u6709\u5f97\u5230\u6ee1\u8db3\u3002\u5728\u6b64\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u7684\u738b\u535a\u3001\u51af\u9704\u7814\u7a76\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u70ed\u8bf1\u5bfc\u76f8\u5206\u79bb-\u70ed\u538b(TIPS-HoP)\u7b56\u7565\uff0c\u4ee5\u751f\u4ea710\u79cd\u4e0d\u540c\u7684\u8f8a\u5bf9\u8f8a\u9ad8\u62c5\u8f7d\u91cf\u3001\u67d4\u6027MOF\u819c(\u8d1f\u8f7d\u91cd\u91cf\u53ef\u8fbe86% wt%)\u3002MOF\u5206\u6563\u5230\u7194\u878d\u6001\u7684\u8d85\u9ad8\u5206\u5b50\u91cf\u7684\u805a\u4e59\u70ef\u9897\u7c92\u4e2d\uff0c\u4ea4\u7ec7\u5728\u4e00\u8d77\uff0c\u63d0\u9ad8\u4e86\u5176\u673a\u68b0\u5f3a\u5ea6\u3002\u7814\u7a76\u8868\u660e\u6c34\u901a\u91cf\u4e3a125.7 L m-2<\/sup>\u00a0h-1<\/sup>\u00a0bar-1<\/sup>\u7684\u6709\u673a\u67d3\u6599\u5728\u6a2a\u6d41\u8fc7\u6ee4\u6a21\u5f0f\u4e0b\u7684\u6b8b\u7559\u4e3a99%\uff0cNH2<\/sub>-UiO-66 PE MMMs \u4e2dMOF\u9897\u7c92\u95f4\u7684\u5fae\u7c73\u7ea7\u901a\u9053\u8f6c\u5316\u4e3a\u5feb\u901f\u6c34\u6e17\u900f\uff0c\u800c\u591a\u5b54MOFs\u901a\u8fc7\u5feb\u901f\u5438\u9644\u6392\u65a5\u6eb6\u8d28\u3002\u8fd9\u4e00\u7b56\u7565\u4e3a\u5f00\u53d1\u7528\u4e8e\u5173\u952e\u5206\u79bb\u8fc7\u7a0b\u7684\u9ad8\u6027\u80fd\u819c\u5438\u9644\u5668\u94fa\u5e73\u4e86\u9053\u8def\u3002\u4f5c\u4e3a\u6982\u5ff5\u7684\u8bc1\u660e\uff0c\u819c\u5438\u9644\u5242\u5206\u79bb\u5916\u6d88\u65cb\u4f53\u548c\u86cb\u767d\u8d28\u7684\u80fd\u529b\u5df2\u7ecf\u5f97\u5230\u8bc1\u660e\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMembrane adsorbers with ultrahigh metal-organic framework loading for high flux separations\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41467-019-12114-8<\/p>\n

\u56fe1\u00a0TIPS-HoP\u7f16\u5199\u7684MOF PE MMM\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u5149\u50ac\u5316\u6740\u83cc\u6d3b\u6027<\/b><\/strong>M<\/b><\/strong>OF\u7528\u4e8e\u6574\u4f53\u7a7a\u6c14\u51c0\u5316<\/b><\/strong>\uff5c<\/b><\/strong>Nature Commun<\/b><\/strong>.<\/b><\/strong>\u00a0<\/b><\/strong><\/p>\n

\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u6559\u6388\u56e2\u961f\u5728\u7a7a\u6c14\u7efc\u5408\u51c0\u5316\u65b9\u9762\u53d6\u5f97\u65b0\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u8be5\u7814\u7a76\u56e2\u961f\u7ed3\u5408\u524d\u671f\u7684\u7814\u7a76\u5de5\u4f5c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u5149\u50ac\u5316\u6d3b\u6027\u7684MOFs\uff0c\u7b5b\u9009\u4e86\u5177\u6709\u8d85\u9ad8\u5149\u50ac\u5316\u6740\u83cc\u6d3b\u6027\u7684ZIF-8\uff0c\u5b9e\u73b0\u5bf9\u6c34\u4f53\u4e2d\u5927\u80a0\u6746\u83cc\u7684\u9ad8\u6548\u6740\u706d\uff0c\u6740\u83cc\u7387\u5927\u4e8e99.9999%\u3002\u7136\u540e\u5229\u7528\u70ed\u538b\u6cd5\u8bbe\u8ba1\u5408\u6210\u4e86\u65b0\u578b\u7684\u9ad8\u6548\u7efc\u5408\u7a7a\u6c14\u8fc7\u6ee4\u5668(MOFilter)\uff0cPM\u5fae\u7c92\u6355\u83b7\u6548\u7387\u80fd\u8fbe\u523098%\u4ee5\u4e0a\uff0c\u540c\u65f6\u8fd8\u53ef\u4ee5\u6740\u706d\u7a7a\u6c14\u4e2d99.99%\u7684\u7ec6\u83cc\u3002\u673a\u7406\u7814\u7a76\u53d1\u73b0\uff0cZIF-8\u5728\u592a\u9633\u5149\u50ac\u5316\u4f5c\u7528\u4e0b\u5149\u751f\u7535\u5b50\u4ea7\u751f\u4e8eLMCT\uff08\u914d\u4f53\u4e0e\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\uff09\uff0c\u5e76\u4e14\u53ef\u4ee5\u6709\u6548\u7684\u6d3b\u5316O2<\/sub>\u5f62\u6210\u2022O2\u2013<\/sup>\u548cH2<\/sub>O2<\/sub>\uff0c\u5176\u53ef\u4ee5\u4f7f\u7a7a\u6c14\u4e2d\u7684\u81f4\u75c5\u7ec6\u83cc\u6c27\u5316\u81f4\u6b7b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning\u201d\u4e3a\u9898\u76ee,\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002\u00a0<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41467-019-10218-9.<\/p>\n

\u56fe2\u57fa\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u7684\u6ee4\u6ce2\u5668\u539f\u7406\u56fe<\/p>\n

\"\"<\/p>\n

3D\u77f3\u58a8\u70ef\u7f51\u7edc(MnO@NC-G) <\/b><\/strong>\u5b9e\u73b0<\/b><\/strong>\u9ad8\u6548Li\u2013CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u6b63\u6781\u8bbe\u8ba1<\/b><\/strong>\uff5c<\/b><\/strong>EES<\/b><\/strong><\/p>\n

Li-CO2<\/sub>\u7535\u6c60\u662f\u8fd1\u5e74\u6765\u53d1\u5c55\u8d77\u6765\u7684\u4e00\u79cd\u6709\u6548\u7684\u50a8\u80fd\u4ecb\u8d28\uff0c\u4f46\u4ecd\u5b58\u5728\u80fd\u6548\u4f4e\u3001\u901f\u7387\u80fd\u529b\u5dee\u3001\u5faa\u73af\u5bff\u547d\u77ed\u7b49\u95ee\u9898\uff0c\u9700\u8981\u8bbe\u8ba1\u66f4\u9ad8\u6548\u7684CO2<\/sub>\u9634\u6781\u3002\u5728\u6b64\uff0c\u738b\u535a\u6559\u6388\u7814\u7a76\u56e2\u961f\u8054\u5408\u5317\u4eac\u5e02\u5149\u7535\/\u7535\u5149\u8f6c\u6362\u6750\u6599\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5236\u5907\u4e86\u8d85\u7ec6MnO\u7eb3\u7c73\u9897\u7c92\u5d4c\u5165\u6c2e\u63ba\u6742\u78b3\u9aa8\u67b6\u76843D\u77f3\u58a8\u70ef\u7f51\u7edc(MnO@NC-G)\u3002\u8be5\u6750\u6599\u6ee1\u8db3\u4e86\u9ad8\u6548CO2<\/sub>\u6b63\u6781\u8bbe\u8ba1\u5e94\u8be5\u8003\u8651\u7684\u4e09\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u5206\u6563\u7684\u50ac\u5316\u4f4d\u70b9\uff1b\uff082\uff09\u5feb\u901f\u7684\u7535\u5b50\u4f20\u8f93\uff1b\uff083\uff09\u7a33\u56fa\u7684\u4e92\u8054\u7f51\u7edc\u3002\u5c06\u8be5\u6750\u6599\u7528\u4f5cLi\u2013CO2<\/sub>\u7535\u6c60\u7684\u6b63\u6781\uff0c\u53ef\u4ee5\u5728\u7535\u6c60\u4e2d\u5b9e\u73b0\u4f4e\u7535\u538b\u6ede\u540e(50 mA g-1\u65f6\u4e3a0.88 V)\uff0c\u9ad8\u500d\u7387\u6027\u80fd(\u9ad8\u8fbe1 A g-1<\/sup>)\u548c\u957f\u5faa\u73af\u5bff\u547d(\u8d85\u8fc7200\u5708\u5faa\u73af)\u3002\u5728\u7535\u538b\u533a\u95f4\u4e3a2.0\u20134.5 V\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a50 mA g-1<\/sup>\u65f6\uff0c\u7535\u6c60\u7684\u6700\u5927\u653e\u7535\u5bb9\u91cf\u53ef\u8fbe25021 mA h g-1<\/sup>\u3002\u53e6\u5916\uff0c\u53ef\u5faa\u73af\u7684MnO@NC-G\u9634\u6781\u53ea\u9700\u66f4\u6362\u9633\u6781\u5c31\u53ef\u4ee5\u8865\u5145\u5176\u6027\u80fd\uff0c\u8fd9\u8868\u660e\u6709\u6548\u7684\u9633\u6781\u4fdd\u62a4\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5ef6\u957f\u7535\u6c60\u7684\u5bff\u547d\u3002\u5176\u4e3a\u63d0\u9ad8\u9502-\u4e8c\u6c27\u5316\u78b3\u7535\u6c60\u7684\u6027\u80fd\u63d0\u4f9b\u4e86\u6709\u7528\u7684\u6307\u5bfc\uff0c\u4ece\u800c\u4e3a\u5f00\u53d1\u57fa\u4e8e\u6c14\u4f53\u9634\u6781\u7684\u9502\u7535\u6c60\u7cfb\u7edf\u63d0\u4f9b\u4e86\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMonodispersed MnO nanoparticles in graphene-an interconnected N-doped 3D carbon framework as a highly efficient gas cathode in Li\u2013CO2<\/sub>\u00a0batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728EES\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1039\/c8ee03283a<\/p>\n

\u56fe3\u7528\u4e8eLi-CO2<\/sub>\u7535\u6c60\u7684\u4e0d\u540cMn\uff08II\uff09\u50ac\u5316\u5242\u7684\u7ed3\u6784\u7279\u5f81\u793a\u610f\u56fe\u53ca\u6750\u6599\u6027\u8d28\u548c\u7535\u6c60\u6027\u80fd\u7684\u5bf9\u6bd4<\/p>\n

\"\"<\/p>\n

\u805a\u4e59\u4e8c\u9187<\/b><\/strong>\u52a0\u901fC<\/b><\/strong>OF\u5185\u79bb\u5b50\u8f6c\u8fd0\u9014\u5f84<\/b><\/strong>\uff5c<\/b><\/strong>JACS<\/b><\/strong><\/p>\n

\u4e3a\u4e86\u89e3\u51b3\u5168\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u6b8b\u7559\u7684\u5fae\u91cf\u7535\u89e3\u6db2\u53ef\u80fd\u4f1a\u5728\u5b9e\u9645\u5e94\u7528\u8fc7\u7a0b\u4e2d\u5e26\u6765\u4e00\u5b9a\u7684\u5b89\u5168\u9690\u60a3\uff0c\u8be5\u56e2\u961f\u5c06\u4f4e\u5206\u5b50\u91cf\u805a\u4e59\u4e8c\u9187\uff08PEG\uff09\u88c5\u8f7d\u5165COF\u5b54\u9053\u4e2d\u52a0\u901f\u9502\u79bb\u5b50\u4f20\u5bfc\uff0c\u5236\u5907\u51fa\u6ca1\u6709\u6eb6\u5242\u6b8b\u7559\u7684\u5168\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5e76\u7cfb\u7edf\u6027\u7814\u7a76\u4e86COF\u9aa8\u67b6\u7535\u8377\u5bf9\u4e8e\u9502\u79bb\u5b50\u4f20\u5bfc\u884c\u4e3a\u7684\u5f71\u54cd\uff0c\u5b9e\u73b0\u5927\u4e8e0.6\u7684\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u4ee5\u53ca120\u00b0C\u4e0b1.8 mS cm\u22121<\/sup>\u7684\u79bb\u5b50\u4f20\u5bfc\u901f\u7387\u3002\u8fd9\u4e00\u7b80\u5355\u7684\u901a\u8fc7\u62c5\u8f7dPEG\u52a0\u901f\u79bb\u5b50\u4f20\u5bfc\u5e76\u63d0\u9ad8\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u7684\u7b56\u7565\u4e3a\u5c06\u591a\u5b54\u6750\u6599\u8fdb\u4e00\u6b65\u5e94\u7528\u4e8e\u5168\u56fa\u6001\u7535\u6c60\u9886\u57df\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFast Ion Transport Pathway Provided by Polyethylene Glycol Confined in Covalent Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/jacs.8b13551<\/p>\n

\u56fe4\u00a0COFs\u4e2dLi+<\/sup>\u8fd0\u8f93\u7684\u793a\u610f\u56fe\u53ca\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u6c34\u7a33\u6027M<\/b><\/strong>OF\u5177\u6709\u5149\u50ac\u5316\u6291\u83cc\u6d3b\u6027\uff0c\u7528\u4e8e\u81ea\u4e3b\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236<\/b><\/strong>\uff5cAngew<\/b><\/strong>.<\/b><\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5177\u6709\u957f\u671f\u7a33\u5b9a\u6027\u548c\u53ef\u9006\u7684\u9ad8\u5438\u6c34\u6027\u80fd\uff0c\u662f\u96c6\u6c34\u548c\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236\u7684\u7406\u60f3\u9009\u62e9\u3002\u5728\u6b64\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u3001\u6797\u653f\u56fd\u6559\u6388\u7b49\u4eba\u62a5\u5bfc\u4e86\u4e00\u79cd\u65b0\u578b\u4ecb\u5b54\u4e14\u9ad8\u5ea6\u7a33\u5b9a\u7684MOF(BIT-66)\uff0c\u5177\u6709\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236\u80fd\u529b\u548c\u5149\u50ac\u5316\u6291\u83cc\u6548\u679c\u3002BIT-66: (V3<\/sub>(O)3<\/sub>(H2<\/sub>O)(BTB)2<\/sub>),\u5728\u76f8\u5bf9\u6e7f\u5ea6\u4e3a45% ~ 60%\u7684\u8303\u56f4\u5185\uff0c\u6c34\u5206\u53ef\u8c03\u6027\u663e\u8457\uff0c\u5438\u6c34\u7387\u548c\u5de5\u4f5c\u80fd\u529b\u5206\u522b\u4e3a71%\u548c55% wt%\uff0c\u5206\u522b\u5728\u6c34\u7684\u5438\u9644-\u89e3\u5438\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u53ef\u56de\u6536\u6027\u548c\u4f18\u5f02\u7684\u6027\u80fd\u3002\u91cd\u8981\u7684\u662f\uff0cBIT-66\u5728\u53ef\u89c1\u5149\u4e0b\u8868\u73b0\u51fa\u72ec\u7279\u7684\u5149\u50ac\u5316\u6291\u83cc\u884c\u4e3a\uff0c\u53ef\u6709\u6548\u6539\u5584\u5438\u6c34\u6027\u6750\u6599\u4e2d\u7684\u7ec6\u83cc\u3001\u9709\u83cc\u6ecb\u751f\u95ee\u9898\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Hydrolytically Stable V(IV)-Metal-Organic Framework with Photocatalytic Bacteriostatic Activity for Autonomous Indoor Humidity Control\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/anie.201914762<\/p>\n

\u56fe5\u00a0BIT-66 N2<\/sub>\u7b49\u6e29\u7ebf\u5438\u9644\u66f2\u7ebf\u53ca\u6c34\u84b8\u6c14\u7b49\u6e29\u7ebf\u5438\u9644\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

\u9646\u76c8\u76c8<\/b><\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n

2010\u5e746\u6708\u6bd5\u4e1a\u4e8e\u6d59\u6c5f\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u751f\u7269\u5de5\u7a0b\u5b66\u9662\uff0c\u83b7\u5f97\u5b66\u58eb\u5b66\u4f4d\uff1b2014\u5e746\u6708\u83b7\u5f97\u7f8e\u56fd\u5eb7\u5948\u5c14\u5927\u5b66\uff08Cornell \u00a0 University\uff09\u535a\u58eb\u5b66\u4f4d\uff1b\u535a\u58eb\u6bd5\u4e1a\u540e\u5728\u5eb7\u5948\u5c14\u5927\u5b66\u548c\u65af\u5766\u798f\u5927\u5b66\uff08Stanford \u00a0 University\uff09\u4ece\u4e8b\u80fd\u6e90\u6750\u6599\u9886\u57df\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\u30022015\u5e74\u56de\u6d59\u6c5f\u5927\u5b66\u5de5\u4f5c\uff0c\u6210\u4e3a\u6d59\u592727\u5c81\u5e74\u8f7b\u535a\u5bfc\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2015\u5e7410\u6708\u5168\u804c\u56de\u6d59\u6c5f\u5927\u5b66\u5de5\u4f5c\uff0c\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u627f\u62c5\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u9762\u4e0a\u9879\u76ee\u3001\u56fd\u5bb6\u79d1\u6280\u90e8\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u8bfe\u9898\u7b49\uff0c\u53d1\u8868\u9ad8\u6c34\u5e73\u7814\u7a76\u8bba\u6587\u4e09\u5341\u4f59\u7bc7\u3002<\/p>\n

\u5de5\u4f5c\u4ecb\u7ecd:<\/b><\/strong>\u00a0<\/b><\/strong><\/p>\n

\u9488\u5bf9\u76ee\u524d\u9502\u79bb\u5b50\u7535\u6c60\u5728\u80fd\u91cf\u5bc6\u5ea6\u65b9\u9762\u7684\u5c40\u9650\u6027\uff0c\u63d0\u51fa\u7814\u7a76\u91d1\u5c5e\u9502\u7535\u6c60\u7b49\u65b0\u578b\u7535\u6c60\uff0c\u5bf9\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u5b89\u5168\u6027\u63d0\u9ad8\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff1b<\/p>\n

\u901a\u8fc7\u6539\u5584\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u3001\u5f00\u53d1\u9ad8\u673a\u68b0\u5f3a\u5ea6\u7535\u89e3\u8d28\u7b49\u65b9\u6cd5\u589e\u52a0\u7535\u6c60\u5bff\u547d\uff1b<\/p>\n

\u901a\u8fc7\u5408\u6210\u591a\u529f\u80fd\u79bb\u5b50\u6db2\u4f53\uff0c\u5e76\u4e0e\u65e0\u673a\u7eb3\u7c73\u9897\u7c92\u63a5\u679d\u5f62\u6210\u65e0\u673a\u6709\u673a\u7eb3\u7c73\u7ed3\u6784\u6742\u5316\u7269\uff0c\u53ef\u6709\u6548\u6539\u5584\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u7535\u89e3\u8d28\u6750\u6599\u7684\u9502\u79bb\u5b50\u8fc1\u79fb\u7387\u53ca\u673a\u68b0\u5f3a\u5ea6\u7b49\u6027\u80fd\u3002<\/p>\n

2019\u5e74\u53d1\u6587\u60c5\u51b5\uff1a<\/b><\/strong><\/p>\n

\u57fa\u4e8eWeb of Science\u6570\u636e\uff0c2019\u5e74SCI\u53d1\u658717\u7bc7\uff0c\u5176\u4e2d\u5305\u62ecAEM\u3001AFM\u3001CM\u7b49\u3002<\/p>\n

\u90e8\u5206\u5de5\u4f5c\u8d4f\u6790<\/b><\/strong><\/p>\n

\u4f18\u5f02\u7684\u4eb2Na\/Li\u7279\u6027\u7684\u591a\u7ea7Co<\/b><\/strong>3<\/b><\/sub><\/strong>O<\/b><\/strong>4<\/b><\/sub><\/strong>\u7eb3\u7c73\u7ea4\u7ef4-\u78b3\u7247\u9aa8\u67b6\u7528\u4e8e\u9ad8\u5ea6\u7a33\u5b9a\u7684\u78b1\u91d1\u5c5e\u7535\u6c60<\/b><\/strong>\uff5c<\/b><\/strong>A<\/b><\/strong>FM<\/b><\/strong><\/p>\n

\u78b1\u91d1\u5c5e\u9633\u6781\u4e0d\u53ef\u63a7\u7684\u679d\u6676\u884c\u4e3a\u548c\u81a8\u80c0\u5bfc\u81f4\u9ad8\u80fd\u7535\u6c60\u5b58\u5728\u4e25\u91cd\u7684\u5b89\u5168\u9690\u60a3\u548c\u4f7f\u7528\u5bff\u547d\u77ed\u3002\u6784\u5efa\u4e00\u4e2a\u7a33\u5b9a\u7684\u3001\u5177\u6709\u4f18\u8d8a\u7684\u4eb2Na\/Li\u6027\u8d28\u7684\u5bbf\u4e3b\u662f\u5b9e\u73b0\u5546\u4e1a\u5316\u7684\u524d\u63d0\u3002\u5728\u8fd9\u91cc\uff0c\u6d59\u6c5f\u5927\u5b66\u9646\u76c8\u76c8\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u5177\u6709\u4f18\u5f02\u4eb2Na\/Li\u7684\u591a\u7ea7Co3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ea4\u7ef4-\u78b3\u7247\uff08CS\uff09\u9aa8\u67b6\uff0c\u4f5c\u4e3a\u78b1\u91d1\u5c5e\u7535\u6781\u7684\u7a33\u5b9a\u57fa\u4f53\u3002\u91c7\u7528\u5546\u7528\u5bfc\u7535\u78b3\u5e03\u4f5c\u4e3a\u4e00\u7ea7\u7ed3\u6784\uff0c\u91c7\u7528\u7b80\u5355\u7684\u6c34\u70ed\u6cd5\u5236\u5907\u5782\u76f4\u751f\u957f\u7684\u4e8c\u7ea7Co3<\/sub>O4<\/sub>\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u4e4b\u540e\u518d\u5c06\u7194\u878d\u78b1\u91d1\u5c5e\u6ce8\u5165\u9aa8\u67b6\u4e2d\u5f62\u6210\u91d1\u5c5e\/Co-CS\u590d\u5408\u8d1f\u6781\u3002\u4e0e\u4f20\u7edf\u7684\u94dc\u7f51\u548c\u954d\u6ce1\u6cab\u7b493D\u91d1\u5c5e\u96c6\u6d41\u4f53\u76f8\u6bd4\uff0c\u6240\u5236\u5907\u7684Li\/Na-Co\u78b3\u7247\u590d\u5408\u8d1f\u6781\uff0c\u63d0\u4f9b\u8db3\u591f\u7684\u9502\u6210\u6838\u4f4d\u70b9\u548c\u5145\u8db3\u7684\u7535\u89e3\u8d28\/\u7535\u6781\u63a5\u89e6\u6765\u5feb\u901f\u7535\u8377\u8f6c\u79fb\u3002\u57fa\u4e8e\u4e0a\u8ff0\u65b0\u9896\u7684\u8bbe\u8ba1\u548c\u4f18\u70b9\uff0cLi\/Co-CS\u5bf9\u79f0\u7535\u6c60\u53ef\u4ee5\u572820mA cm-2<\/sup>\u7684\u8d85\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af\u8d85\u8fc7120\u5708\u3002\u4e0eLiFePO4<\/sub>\u6b63\u6781\u914d\u5bf9\u65f6\uff0cLi\/Co-CS\u7535\u6c60\u57282C\u4e0b200\u6b21\u5faa\u73af\u540e\u663e\u793a\u51fa88.4%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u4f7f\u7528NaClO4<\/sub>\u57fa\u7535\u89e3\u8d28\u7684Na\/Co-CS\u5bf9\u79f0\u7535\u6c60\u4e2d\u4e5f\u89c2\u5bdf\u5230\u660e\u663e\u7684\u6539\u5584\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u9898\u4e3a\u201cHierarchical Co3<\/sub>O4 <\/sub>Nanofiber\u2013Carbon Sheet Skeleton with Superior Na\/Li-Philic Property Enabling Highly Stable Alkali Metal Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adfm.201808847<\/p>\n

\u56fe1\u00a0\u78b1\u91d1\u5c5e\/Co-CS\u590d\u5408\u8d1f\u6781\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u901a\u8fc7\u8c03\u8282\u754c\u9762\u6709\u673a\u76f8LUMO\u80fd\u7ea7\u63d0\u5347\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u7a33\u5b9a\u6027<\/b><\/strong>\uff5c<\/b><\/strong>A<\/b><\/strong>CS E<\/b><\/strong>nergy<\/b><\/strong>\u00a0Letters<\/b><\/strong><\/p>\n

\u754c\u9762\u7a33\u5b9a\u6027\u88ab\u8ba4\u4e3a\u662f\u9ad8\u80fd\u9502\u91d1\u5c5e\u7535\u6c60(LMBs)\u7684\u4e00\u4e2a\u91cd\u70b9\uff0c\u8fd9\u662f\u7531\u4e8e\u9502\u91d1\u5c5e\u6781\u4f4e\u7684\u7535\u5316\u5b66\u7535\u4f4d\u548c\u5176\u56fa\u6709\u7684\u9ad8\u53cd\u5e94\u6d3b\u6027\u3002\u9502\u91d1\u5c5e\u6781\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\u4f1a\u5bfc\u81f4\u7535\u89e3\u6db2\u7b49\u5728\u8d1f\u6781\u754c\u9762\u5904\u81ea\u53d1\u7684\u526f\u53cd\u5e94\uff0c\u4ece\u800c\u6784\u6210\u539f\u751f\u7684SEI\u5c42\u3002\u539f\u751f\u7684SEI\u5c42\u542b\u6709\u6709\u673a\u7ec4\u5206\uff08\u6bd4\u5982R1<\/sub>OCOOR2<\/sub>, ROLi\uff09\u548c\u65e0\u673a\u7ec4\u5206\uff08\u6bd4\u5982Li2<\/sub>CO3<\/sub>, Li3<\/sub>N)\uff0c\u4ed6\u4eec\u76f8\u5bf9\u4e8e\u9502\u91d1\u5c5e\u800c\u8a00\u70ed\u529b\u5b66\u4e0d\u7a33\u5b9a\uff0c\u4ece\u800c\u4f1a\u52a0\u5267\u754c\u9762\u4e0d\u7a33\u5b9a\u6027\u5e76\u8fdb\u4e00\u6b65\u5f15\u53d1\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u6d59\u6c5f\u5927\u5b66\u9646\u76c8\u76c8\u8bfe\u9898\u7ec4\u8054\u5408\u6d2a\u946b\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u4e2a\u9ad8\u5ea6\u7a33\u5b9a\u7684\u6709\u673a\u95f4\u76f8(HSOI)\u4e0e\u826f\u597d\u7684\u8c03\u8c10\uff0c\u63d0\u9ad8SEI\u7ec4\u5206\u7684\u6297\u8fd8\u539f\u80fd\u529b\uff0c\u589e\u5f3aLMBs\u7684\u957f\u671f\u5faa\u73af\u80fd\u529b\u3002\u5728SEI\u7684\u5206\u5b50\u7ed3\u6784\u4e2d\u4f7f\u7528\u2212CF3<\/sub>\uff0c\u7531\u4e8e\u2212CF3<\/sub>\u5b98\u80fd\u56e2\u5177\u6709\u5f88\u5f3a\u7684\u5438\u7535\u5b50\u6027\uff0c\u56e0\u6b64\u53ef\u4ee5\u663e\u8457\u5730\u8c03\u8282\u8f68\u9053\u80fd\u91cf\u548cHOMO – LUMO\u95f4\u9699\u3002\u5728\u9ad8\u5316\u5b66\u7a33\u5b9a\u6709\u673a\u76f8\uff08HSOI\uff09\u7684\u4fdd\u62a4\u4e0b\uff0cLi\/Li\u5bf9\u79f0\u7535\u6c60\u53ef\u4ee5\u6301\u7eed\u5faa\u73af1300h\uff0c\u5bff\u547d\u63d0\u9ad8\u4e865\u500d,\u00a0Li\/S\u7535\u6c60\u53ef\u4ee5\u57283.345 \u00a0mA\/cm2<\/sup>\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u5faa\u73af300\u5708\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTuning the LUMO Energy of an Organic \u00a0Interphase to Stabilize Lithium Metal Batteries \u201c\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Energy\u00a0Letters\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/acsenergylett.8b02483<\/p>\n

\u56fe2\u00a0\u9ad8\u5316\u5b66\u7a33\u5b9a\u6709\u673a\u76f8\uff08HSOI\uff09\u4fdd\u62a4\u4e0b\u7684\u9502\u91d1\u5c5e\u8d1f\u6781<\/p>\n

\"\"<\/p>\n

\u901a\u8fc7\u4e09\u7ef4\u7eb3\u7c73\u91d1\u521a\u77f3\u7a33\u5b9a\u9502\u91d1\u5c5e\u6c89\u79ef<\/b><\/strong>\uff5c<\/b><\/strong>Small Methods<\/b><\/strong><\/p>\n

\u9ad8\u80fd\u91d1\u5c5e\u9502\u7535\u6c60\u7684\u5b9e\u9645\u4f7f\u7528\u4ecd\u7136\u9762\u4e34\u5f88\u5927\u7684\u6311\u6218\uff0c\u4e3b\u8981\u662f\u9502\u6c89\u79ef\u4e0d\u5747\u5300\uff0c\u9633\u6781\u4fa7\u4f53\u79ef\u6ce2\u52a8\u8f83\u5927\uff0c\u589e\u52a0\u4e86\u7535\u6c60\u77ed\u8def\u7684\u6f5c\u5728\u98ce\u9669\u3002\u5728\u6b64\u6d59\u6c5f\u5927\u5b66\u9646\u76c8\u76c8\u6559\u6388\u5229\u7528\u7b80\u5355\u7684\u70ed\u704c\u6ce8\u7b56\u7565\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u7eb3\u7c73\u91d1\u521a\u77f3\u9502\u590d\u5408\u9633\u6781(ND-Li)\uff0c\u5b83\u53ef\u4ee5\u673a\u68b0\u5730\u5728\u9495\u57fa\u4f53\u4e2d\u6ce8\u5165\u6d3b\u6027\u9502\u91d1\u5c5e\uff0c\u5e76\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c0f\u7535\u6781\u4f53\u79ef\u7684\u53d8\u5316\u3002\u5177\u6709\u8d85\u9ad8\u6a21\u91cf\u7684\u51e0\u4f55\u9650\u5236\u6027\u9495\u57fa\u4f53\u53ef\u4ee5\u4f7f\u4e0d\u5747\u5300\u7684\u9502\u6c89\u79ef\u53d1\u751f\u673a\u68b0\u53d8\u5f62\uff0c\u4f7f\u6c89\u79ef\u4e0e\u9495\u57fa\u4f53\u76f8\u7ed3\u5408\u3002Li\/Li\u5bf9\u79f0\u7535\u6c60\u572810mA\/cm2<\/sup>\u4e0b\u8fc7\u7535\u4f4d\u4ec5\u4e3a60mV\uff0cLi\/S\u7535\u6c60\u57281C\u4e0b\u5faa\u73af500\u5708\u5bb9\u91cf\u4fdd\u6301\u4e3a607.3mAh\/g\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cStable Li-metal Deposition via a 3D Nanodiamond Matrix with Ultrahigh Young\u2019s Modulus\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Small Methods\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/smtd.201900325<\/p>\n

\u56fe3\u00a0ND-Li\u590d\u5408\u8d1f\u6781\u5236\u5907\u65b9\u6cd5\u548c\u5f62\u8c8c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u5bab\u52c7\u5409<\/b><\/strong><\/p>\n

\u4eba\u7269\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n

\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u6559\u6388\uff0c28\u5c81\u6210\u4e3a\u5317\u822a\u5e74\u8f7b\u7684\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u00a02011\u5e74\u6bd5\u4e1a\u4e8e\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\uff0c\u83b7\u5f97\u672c\u79d1\u5b66\u58eb\u5b66\u4f4d\u30022011.08-2015.12\u5728\u7f8e\u56fd\u83b1\u65af\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4eceAjayan\u6559\u6388\uff0c\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u65b0\u578b\u4e8c\u7ef4\u6750\u6599\u53ca\u5176\u5f02\u8d28\u7ed3\u6784\uff1b2016.03-2017.05\u5728\u7f8e\u56fd\u65af\u5766\u798f\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c\u5e08\u4eceYi Cui\u6559\u6388\uff0c\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u4e8c\u7ef4\u6750\u6599\u7684\u6027\u8d28\u8c03\u63a7\u4ee5\u53ca\u65b0\u80fd\u6e90\u6750\u6599\u7b49\u3002<\/p>\n

\u7814\u7a76\u9886\u57df\uff1a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6700\u8fd15\u5e74\uff0c\u5728\u6750\u6599\u5b66\u76f8\u5173\u9886\u57df\u53d1\u8868\u9876\u7ea7\u671f\u520a20\u7bc7\uff0c\u5305\u62ecnature materials, nature communications\uff0cAdvanced materials\uff0cNano letters\u7b49\u3002\u5916\u4ee5\u5171\u540c\u4f5c\u8005\u7684\u8eab\u4efd\u53d1\u8868\u8bba\u6587\u517160\u7bc7\u5de6\u53f3\uff0c\u5305\u62ecNature\uff0cNature nanotechnology\u7b49\u3002<\/p>\n

\u5de5\u4f5c\u4ecb\u7ecd: <\/b><\/strong><\/p>\n

\u63a2\u7d22\u5408\u6210\u5927\u89c4\u6a21\u4e8c\u7ef4\u6750\u6599\u53ca\u53ef\u5f97\u5230\u4e8c\u7ef4\u534a\u5bfc\u4f53\u5355\u6676\u7684\u65b9\u6cd5\uff0c\u7cfb\u7edf\u5206\u6790\u4e8c\u7ef4\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\u4e0e\u5b8f\u89c2\u6027\u8d28\u76f4\u63a5\u7684\u6784\u6548\u5173\u7cfb;<\/p>\n

\u901a\u8fc7\u5bf9\u7f3a\u9677\u8c03\u63a7\u53ca\u6742\u539f\u5b50\u63ba\u6742\u7684\u65b9\u6cd5\u63d0\u9ad8\u4e8c\u7ef4\u6750\u6599\u7684\u6027\u80fd\uff0c\u83b7\u5f97\u9ad8\u6027\u80fd\u7684\u77f3\u58a8\u70ef\u57fa\u7684\u573a\u6548\u5e94\u6676\u4f53\u7ba1\uff0c\u6210\u529f\u7684\u5f97\u5230\u7a33\u5b9a\u7684T\u76f8\u786b\u5316\u94bc\u7684\u5408\u91d1\uff0c\u5e76\u5b9e\u73b0\u4e86\u7a33\u5b9a\u9ad8\u6548\u7684\u7535\u89e3\u6c34\u7684\u50ac\u5316\u5242\uff1b<\/p>\n

\u53d1\u5c55\u4e86\u5408\u6210\u4e8c\u7ef4\u534a\u5bfc\u4f53\u5f02\u8d28\u7ed3\u7684\u65b9\u6cd5\uff0c\u5b9e\u73b0\u4e86\u539f\u5b50\u7ea7\u522b\u9510\u5229\u7684\u5f02\u8d28\u7ed3\u7684\u754c\u9762\uff1b\u9996\u6b21\u5c06\u63d2\u5c42\u6280\u672f\u5e94\u7528\u5230\u9502\u786b\u7535\u6c60\u7684\u7814\u7a76\u4e2d\uff0c\u901a\u8fc7\u63d2\u5c42\u6280\u672f\u5c06\u91d1\u5c5e\u539f\u5b50\u63d2\u5165\u5230\u4e8c\u7ef4\u5c42\u72b6MOs\u7684\u8303\u5fb7\u74e6\u5c14\u65af\u5c42\u95f4\uff0c\u4e0d\u4ec5\u6709\u6548\u7684\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\uff0c\u8fd8\u6709\u6548\u7684\u6291\u5236\u4e86\u201c\u7a7f\u68ad\u201d\u6548\u5e94\u7684\u53d1\u751f\u3002<\/p>\n

2019\u5e74\u53d1\u6587\u60c5\u51b5<\/b><\/strong>:<\/b><\/strong><\/p>\n

\u57fa\u4e8eWeb of Science\u6570\u636e\uff0c2019\u5e74SCI\u53d1\u658717\u7bc7\u5176\u4e2d\u5305\u62ecAEM\u3001AFM\u3001ACS Energy\u00a0Letters\u7b49\u3002<\/p>\n

\u90e8\u5206\u5de5\u4f5c\u8d4f\u6790<\/b><\/strong><\/p>\n

\u63d2\u5c42\u6280\u672f\u5e94\u7528\u5230\u9502\u786b\u7535\u6c60<\/b><\/strong>\uff5c<\/b><\/strong>A<\/b><\/strong>EM<\/b><\/strong><\/p>\n

\u5229\u7528\u6742\u539f\u5b50\u63ba\u6742\u7b56\u7565\u6765\u6539\u5584\u4e8c\u7ef4\u6750\u6599\u7684\u5bfc\u7535\u6027\u80fd\u548c\u6781\u6027\uff0c\u4ee5\u63d0\u9ad8\u5176\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u4e2d\u786b\u9634\u6781\u7684\u6027\u80fd\u3002\u7136\u800c\uff0c\u7531\u4e8e\u63ba\u6742\u539f\u5b50\u7684\u4e0d\u5747\u5300\u6027\u548c\u6570\u91cf\u5c11\uff0c\u8fdb\u4e00\u6b65\u7684\u6539\u8fdb\u53d7\u5230\u4e86\u9650\u5236\u3002\u5317\u822a\u5bab\u52c7\u5409\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u901a\u8fc7\u63d2\u5c42\u6280\u672f\u5c06\u91d1\u5c5e\u539f\u5b50\u63d2\u5165\u5230\u4e8c\u7ef4\u5c42\u72b6MOs\u7684\u8303\u5fb7\u74e6\u5c14\u65af\u5c42\u95f4\uff0c\u4e0d\u4ec5\u6709\u6548\u7684\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\uff0c\u8fd8\u6709\u6548\u7684\u6291\u5236\u4e86\u201c\u7a7f\u68ad\u201d\u6548\u5e94\u7684\u53d1\u751f\u3002\u7b2c\u4e00\u6b21\u539f\u7406\u8ba1\u7b97\u8868\u660e\uff0cSn\u63d2\u5c42\u540e\uff0cMoO3<\/sub>\u4e0e\u9502\u591a\u786b\u5316\u7269\u3001\u9502\u786b\u5316\u7269\u548c\u786b\u7684\u7ed3\u5408\u80fd\u660e\u663e\u63d0\u9ad8\u3002Sn0.063<\/sub>MoO3<\/sub>-S\u9634\u6781\u57280.1 C\u65f6\u7684\u521d\u59cb\u7279\u6b8a\u5bb9\u91cf\u4e3a1390.3 mAh g\u22121<\/sup>\uff0c\u5e93\u4ed1\u6548\u7387\u9ad8\u8fbe99.7%\uff0c\u800c\u4e14\uff0cSn0.063<\/sub>MoO3<\/sub>-S\u7535\u6781\u57281C\u5145\u653e\u7535\u6761\u4ef6\u4e0b\u5faa\u73af500\u6b21\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe79.6%\uff0c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u5176\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u3002\u8fd9\u79cd\u63d2\u5c42\u65b9\u6cd5\u4e3a\u4e8c\u7ef4\u6750\u6599\u7684\u5de5\u7a0b\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTin Intercalated Ultrathin MoO3<\/sub>\u00a0Nanoribbons for Advanced Lithium\u2013Sulfur Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AEM\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/aenm.201803137<\/p>\n

\u56fe1\u00a0MoO3<\/sub>\u548cSn0.063<\/sub>MoO3<\/sub>\u7684\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u57fa\u4e8e\u5927\u9762\u79ef\u539f\u5b50\u5c42SnS<\/b><\/strong>2<\/b><\/sub><\/strong>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u7535\u5b66\u6027\u80fd\u7814\u7a76<\/b><\/strong>\uff5cSmall<\/b><\/strong><\/p>\n

\u4e8c\u7ef4\u91d1\u5c5e\u53cc\u5364\u65cf\u5316\u5408\u7269\u5c42\u56e0\u5176\u72ec\u7279\u7684\u7535\u5b50\u6027\u8d28\u548c\u539f\u5b50\u8584\u7684\u51e0\u4f55\u5f62\u72b6\u800c\u53d7\u5230\u9ad8\u6027\u80fd\u7535\u5b50\u5668\u4ef6\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5e26\u9699\u7ea6\u4e3a2.6 eV\u7684\u4e8c\u7ef4SnS2<\/sub>\u7eb3\u7c73\u7247\u4f5c\u4e3a\u73b0\u4ee3\u7535\u50ac\u5316\u3001\u7535\u5b50\u6216\u5149\u7535\u5b50\u6be1\u7684\u6f5c\u5728\u5019\u9009\u6750\u6599\uff0c\u4e00\u76f4\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5927\u5c3a\u5bf8\u3001\u9ad8\u8d28\u91cf\u7684SnS2<\/sub>\u539f\u5b50\u5c42\u7684\u53ef\u63a7\u751f\u957f\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u5728\u6b64\uff0c\u5317\u4eac\u822a\u5929\u822a\u7a7a\u5927\u5b66\u5bab\u52c7\u5409\u6559\u6388\u8054\u5408\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u80e1\u5fd7\u9ad8\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u7b80\u6613\u7684\u7194\u878d\u76d0\u8f85\u52a9CVD\u6cd5\uff0c\u6210\u529f\u5730\u5408\u6210\u4e86\u5927\u5c3a\u5bf8\u548c\u9ad8\u8d28\u91cf\u539f\u5b50\u5c42\u7684SnS2<\/sub>\u3002SnS2<\/sub>\u7684\u6a2a\u5411\u5c3a\u5bf8\u53ef\u4ee5\u957f\u8fbe410 \u00b5m\uff0c\u5e76\u4e14\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5747\u5300\u6027\u3002\u901a\u8fc7\u539f\u5b50\u5206\u8fa8\u7387\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08STEM\uff09\u89c2\u5bdf\u5230SnS2<\/sub>\u5728\u4e0d\u540c\u5c42\u95f4\u5177\u6709\u9ad8\u8d28\u91cf2H\u5806\u79ef\u6676\u683c\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u8d85\u8584SnS2<\/sub>\u7eb3\u7c73\u7247\u7684\u573a\u6548\u5e94\u6676\u4f53\u7ba1\uff08FET\uff09\u5c55\u73b0\u51fa\u9ad8\u5f00\/\u5173\u6bd4\uff08~108\uff09\u548c\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff082.58 cm2<\/sup>V-1<\/sup>s-1<\/sup>\uff09\uff0c\u8868\u660eSnS2<\/sub>\u5728\u4f4e\u529f\u8017FET\u4e2d\u7684\u6f5c\u5728\u9002\u7528\u6027\u3002\u6b64\u5916\uff0c\u4e8c\u7ef4SnS2<\/sub>\u7684\u8fd9\u79cd\u826f\u597d\u6027\u80fd\u53ca\u5176\u53ef\u63a7\u65b9\u6cd5\u5c06\u4f7f\u6211\u4eec\u80fd\u591f\u5728\u50a8\u80fd\u5e94\u7528\u4e2d\u91ca\u653e\u5176\u7535\u50ac\u5316\u80fd\u529b\uff0c\u4f8b\u5982\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u3001\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u548c\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cLarge-Scale Growth and Field-Effect Transistors Electrical Engineering of Atomic-Layer SnS2\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Small\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/smll.201904116<\/p>\n

\u56fe2\u00a0\u8d85\u8584SnS2<\/sub>\u7eb3\u7c73\u7247\u7684\u5236\u5907\u53ca\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u901a\u8fc7<\/b><\/strong>\u5355\u539f\u5b50\u63ba\u6742\u8f85\u52a9\u5747\u5300\u9502\u6c89\u79ef<\/b><\/strong>\u7684<\/b><\/strong>\u9ad8\u6027\u80fd\u91d1\u5c5e\u9502\u9633\u6781<\/b><\/strong>\uff5cA<\/b><\/strong>EM<\/b><\/strong><\/p>\n

\u957f\u671f\u4ee5\u6765\uff0c\u9502\u91d1\u5c5e\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u524d\u9014\u7684\u4e0b\u4e00\u4ee3\u5145\u7535\u7535\u6c60\u9633\u6781\u6750\u6599\u4e4b\u4e00\u3002\u5c3d\u7ba1\u7ecf\u8fc7\u51e0\u5341\u5e74\u7684\u96c6\u4e2d\u7814\u7a76\uff0c\u5176\u5b9e\u9645\u5e94\u7528\u4ecd\u7136\u53d7\u5230\u9502\u91d1\u5c5e\u9633\u6781\u7684\u679d\u6676\u9502\u6c89\u79ef\u548c\u6676\u4f53\u4f53\u79ef\u53d8\u5316\u7684\u963b\u788d\u3002\u5728\u6b64\uff0c\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u5bab\u52c7\u5409\u6559\u6388\u3001\u5f20\u5343\u5e06\u526f\u6559\u6388\u4e0e\u71d5\u5c71\u5927\u5b66\u8042\u5b89\u6c11\u6559\u6388\u5408\u6210\u4e86\u539f\u5b50\u7ea7\u5206\u6563\u7684\u91d1\u5c5e\u63ba\u6742\u77f3\u58a8\u70ef\u7528\u6765\u8c03\u63a7\u9502\u91d1\u5c5e\u7684\u6210\u6838\u8fc7\u7a0b\u5e76\u8bf1\u5bfc\u9502\u91d1\u5c5e\u6c89\u79ef\u3002\u63ba\u6c2e\u77f3\u58a8\u70ef\u8d1f\u8f7d\u7684\u5355\u539f\u5b50\uff08SA\uff09\u91d1\u5c5e\u4e0d\u4ec5\u80fd\u4ee5\u4e2d\u7b49\u7684\u5438\u9644\u80fd\u68af\u5ea6\u589e\u52a0\u91d1\u5c5e\u539f\u5b50\u4f4d\u70b9\u5468\u56f4\u5c40\u90e8\u533a\u57df\u7684Li\u5438\u9644\u80fd\uff0c\u800c\u4e14\u80fd\u901a\u8fc7\u6784\u5efaM-NX-C\u7684\u914d\u4f4d\u6a21\u5f0f\u63d0\u9ad8\u6574\u4f53\u6750\u6599\u7684\u539f\u5b50\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u7531\u6b64\u5236\u5907\u7684\u7535\u6781\u80fd\u591f\u5b9e\u73b0\u4f4e\u81f319 mV\u7684\u7535\u538b\u8fdf\u6ede\uff0c\u5faa\u73af250\u5468\u540e\u9ad8\u8fbe98.45%\u7684\u5e93\u4f26\u6548\u7387\u4ee5\u53ca4.0mA\/cm2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u7684\u6c89\u79ef-\u5265\u79bb\u8fc7\u7a0b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cUniform Lithium Deposition Assisted by Single-Atom Doping toward High-Performance Lithium Metal Anodes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AEM\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/aenm.201804019<\/p>\n

\u56fe3\u00a0\u9502\u79bb\u5b50\u7684\u6210\u6838\u548c\u7535\u9540\u8fc7\u7a0b\u53ca\u76f8\u5e94\u7684\u80fd\u91cf\u5206\u5e03\u56fe<\/p>\n

\"\"<\/p>\n

\u6539\u53d8\u805a\u567b\u5429\u884d\u751f\u7269\u886c\u5e95<\/b><\/strong>\u6765<\/b><\/strong>\u63a7\u5236<\/b><\/strong>\u7eb3\u7c73\u91d1<\/b><\/strong>\u7535\u6c89\u79ef\u5f62\u8c8c<\/b><\/strong>\uff5c<\/b><\/strong>Chem. Commun.<\/b><\/strong><\/p>\n

\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u6539\u53d8\u805a\u567b\u5429\u884d\u751f\u7269\u886c\u5e95\u6765\u63a7\u5236AuNPs\u5f62\u8c8c\u7684\u65b0\u7b56\u7565\uff0c\u91c7\u7528\u7535\u5316\u5b66\u5408\u6210\u6cd5\u5728ITO\u7535\u6781\u4e0a\u5408\u6210\u4e86\u56db\u79cd\u94c2\u57fa\u677f\uff0c\u5728\u94c2\u57fa\u677f\u8868\u9762\u8fdb\u884c\u4e86AuNP\u7535\u6c89\u79ef\uff0c\u5e76\u901a\u8fc7\u7b2c\u539f\u7406\u8ba1\u7b97\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u94c2\u57fa\u677f\u4e0e\u91d1\u79bb\u5b50\u4e4b\u95f4\u7684\u70ed\u529b\u5b66\u6027\u8d28\u3002\u5e76\u4ece\u7406\u8bba\u4e0a\u8fdb\u4e00\u6b65\u63a2\u8ba8\u4e86AuNPs\u5728PTs\u4e0a\u7684\u6210\u6838\u673a\u7406\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4fa7\u94fe\u8f83\u957f\u7684PTs\u53ef\u4ee5\u8bf1\u5bfc\u4e0d\u540c\u5f62\u8c8c\u3001\u4e0d\u540c\u7c92\u5f84\u7684AuNPs\u7535\u6c89\u79ef\u3002\u540c\u65f6\uff0cPTs\u7684\u6d3b\u6027\u5438\u9644\u4f4d\u70b9\u6709\u5229\u4e8e\u5f62\u6210\u91d1\u79bb\u5b50\u7684\u65e9\u671f\u6c89\u79ef\u4f4d\u70b9\uff0c\u5f62\u6210\u6210\u6838\u8868\u9762\uff0c\u4f7f\u7eb3\u7c73\u9897\u7c92\u5f62\u8c8c\u5206\u5e03\u5747\u5300\uff0c\u7c92\u5f84\u8f83\u5c0f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAltering polythiophene derivative substrates to control the electrodeposition morphology of Au particles toward ultrafine nanoparticles\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem. Commun.\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aChem. Commun., 2019, 55, 12088\u201412091.<\/p>\n

\u56fe4\u00a0\u91d1\u79bb\u5b50\u5438\u9644\u540e\u7684PTs\u7ed3\u6784\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u8bf7\u6279\u8bc4\u6307\u6b63\u3002\u4f60\u8eab\u8fb9\u5b58\u5728\u7740\u54ea\u4e9bNB\u7684\u5e74\u8f7b\u535a\u5bfc\uff0c\u5c06\u4ed6\u4eec\u7684\u5de5\u4f5c\u6210\u679c\u5206\u4eab\u7ed9\u5927\u5bb6\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u738b\u535a \u4eba\u7269\u4ecb\u7ecd\uff1a\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u5e38\u52a1\u526f\u9662\u957f\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u515a\u59d4\u5e38\u59d4\u3001\u526f\u6821\u957f\u300228\u5c81\u65f6\u5165\u9009\u201c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6770\u51fa\u4e2d\u9752\u5e74\u6559\u5e08\u53d1…<\/p>\n","protected":false},"author":10213,"featured_media":196456,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-196455","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196455"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=196455"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196455\/revisions"}],"predecessor-version":[{"id":196496,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/196455\/revisions\/196496"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/196456"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=196455"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=196455"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=196455"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}