{"id":196625,"date":"2020-03-17T06:43:59","date_gmt":"2020-03-16T22:43:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196625"},"modified":"2020-03-16T20:44:10","modified_gmt":"2020-03-16T12:44:10","slug":"%e4%bb%80%e4%b9%88%e6%a0%b7%e7%9a%84%e7%a0%94%e7%a9%b6%e6%88%90%e5%b0%b110%e7%af%87%e5%82%ac%e5%8c%96%e9%a2%86%e5%9f%9f%e9%ab%98%e8%a2%ab%e5%bc%95%e3%80%81%e9%ab%98%e6%b0%b4%e5%b9%b3%e6%96%87%e7%ab%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196625","title":{"rendered":"\u4ec0\u4e48\u6837\u7684\u7814\u7a76\u6210\u5c3110\u7bc7\u50ac\u5316\u9886\u57df\u9ad8\u88ab\u5f15\u3001\u9ad8\u6c34\u5e73\u6587\u7ae0\uff1f\u4eca\u5e26\u4f60\u8d70\u8fdbCO2RR\u7684\u4e16\u754c"},"content":{"rendered":"

CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u4e0d\u4ec5\u6709\u671b\u901a\u8fc7\u964d\u4f4e\u6e29\u5ba4\u6c14\u4f53\u4e2d\u7684CO2<\/sub>\u542b\u91cf\u7f13\u89e3\u65e5\u76ca\u4e25\u91cd\u7684\u6c14\u5019\u5371\u673a\uff0c\u8fd8\u80fd\u5c06\u5927\u6c14\u4e2d\u5e7f\u6cdb\u5b58\u5728\u7684CO2<\/sub>\u5206\u5b50\u8f6c\u5316\u4e3aCO\u3001\u7532\u9187\u3001\u4e59\u9187\u7b49\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u71c3\u6599\uff0c\u6ee1\u8db3\u4eba\u7c7b\u65e5\u76ca\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\uff0c\u540c\u65f6\u964d\u4f4e\u4eba\u7c7b\u5bf9\u4f20\u7edf\u5316\u77f3\u80fd\u6e90\u7684\u4f9d\u8d56\u3002\u8fd1\u5e74\u6765\uff0cCO2\u8fd8\u539f\u50ac\u5316\u5242\u7814\u5236\u53ca\u76f8\u5173\u6280\u672f\u5df2\u6210\u4e3a\u8fd1\u5e74\u6765\u50ac\u5316\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002CO2<\/sub>\u8fd8\u539f\u5236\u9ad8\u9644\u52a0\u503c\u4ea7\u54c1\u5728\u56fd\u9645\u4e0a\u8d8a\u6765\u8d8a\u591a\u5730\u53d7\u5230\u7814\u7a76\u8005\u4eec\u7684\u5173\u6ce8\u3002\u672c\u6b21\u4e3a\u5404\u4f4d\u8bfb\u8005\u5448\u4e0a\u4e8610\u7bc7CO2<\/sub>\u8fd8\u539f\u7684\u9ad8\u88ab\u5f15\u3001\u9ad8\u6c34\u5e73\u5de5\u4f5c\uff0c\u6bd4\u5982\u6784\u7b51\u672c\u5f81\u6d3b\u6027\u9ad8\u7684CO2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\u3001\u8d1f\u8f7d\u4e0d\u540c\u57fa\u5e95\u4e0a\u6784\u6210\u590d\u5408\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u673a\u7406\u63a2\u7a76\u7b49\u3002\u5e0c\u671b\u5bf9CO2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u601d\u8def\uff0c\u5bf9\u4eca\u540e\u7684\u5de5\u4f5c\u5e2e\u52a9\u6709\u6240\u5e2e\u52a9\u3002<\/p>\n

1\u3001<\/b><\/strong>\u539f\u5b50\u5206\u6563\u7684Fe<\/b><\/strong>3+<\/b><\/sup><\/strong>\u4f4d\u70b9<\/b><\/strong>\u9ad8\u6548<\/b><\/strong>\u50ac\u5316CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u8fd8\u539f\u6210CO<\/b><\/strong>\uff5c<\/b><\/strong>Science<\/b><\/strong><\/p>\n

\u76ee\u524d\uff0c\u5c06CO2<\/sub>\u8f6c\u5316\u4e3aCO\u7684\u6d3b\u6027\u6700\u5f3a\u7684\u7535\u50ac\u5316\u5242\u662f\u91d1\u57fa\u7eb3\u7c73\u6750\u6599\uff0c\u800c\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8f83\u4f4e\u6216\u4e2d\u7b49\u3002\u5728\u8fd9\u91cc\uff0c\u745e\u58eb\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662\u80e1\u559c\u4e50\u6559\u6388\u4e0e\u53f0\u6e7e\u5927\u5b66\u9648\u6d69\u94ed\u6559\u6388\u7b49\u62a5\u544a\u4e86\u4e00\u79cd\u5355\u539f\u5b50\u5206\u6563\u7684\u94c1\u4f4d\u70b9\u50ac\u5316\u5242\uff0c\u5b83\u5728\u4f4e\u81f380mV\u7684\u8d85\u7535\u4f4d\u4e0b\u4ea7\u751fCO\uff0c\u5f53\u8fc7\u7535\u4f4d\u4e3a340mV\u65f6\uff0c\u5206\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fbe94 mA cm-2<\/sup>\u3002\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u663e\u793a\u6d3b\u6027\u4f4d\u70b9\u662f\u79bb\u6563\u7684Fe3+<\/sup>\u79bb\u5b50\u4e0eN\u63ba\u6742\u78b3\u8f7d\u4f53\u4e0a\u7684\u5421\u54af\u6c2e(N)\u539f\u5b50\u914d\u4f4d\uff0c\u5728\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7ef4\u6301\u5176+3\u6c27\u5316\u6001\uff0c\u53ef\u80fd\u662f\u901a\u8fc7\u4e0e\u5bfc\u7535\u78b3\u8f7d\u4f53\u7684\u7535\u5b50\u8026\u5408\u5b9e\u73b0\u7684\u3002\u7535\u5316\u5b66\u6570\u636e\u8868\u660e\uff0cFe3+<\/sup>\u4f4d\u70b9\u6bd4\u4f20\u7edfFe2+<\/sup>\u4f4d\u70b9\u5177\u6709\u66f4\u5feb\u7684CO2<\/sub>\u5438\u9644\u901f\u5ea6\u548c\u66f4\u5f31\u7684CO\u5438\u9644\u80fd\u529b\uff0c\u56e0\u6b64Fe3+<\/sup>-N-C\u6bd4Fe2+<\/sup>-N-C\u5728\u53cd\u5e94\u4e2d\u5177\u6709\u66f4\u4f4e\u7684\u8fc7\u7535\u4f4d\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAtomicallydispersed Fe3+<\/sup>\u00a0sites catalyze efficient CO2 <\/sub>electroreduction to CO\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1126\/science.aaw7515<\/p>\n

\u56fe1\u00a0CO2<\/sub>\u7535\u8fd8\u539f\u6027\u80fd<\/p>\n

\"\"<\/p>\n

2<\/b><\/strong>\u3001<\/b><\/strong>\u4e8c\u6c27\u5316\u78b3\u548c\u7518\u6cb9\u7684\u5171\u7535\u89e3\u4f5c\u4e3a\u901a\u5f80\u78b3\u5316\u5408\u7269\u7684<\/b><\/strong>\u4f4e\u7535\u529b\u6d88\u8017<\/b><\/strong>\u9014\u5f84<\/b><\/strong>\uff5c<\/b><\/strong>Nature Energy<\/b><\/strong><\/p>\n

\u53ef\u518d\u751f\u7535\u529b\u9a71\u52a8\u7684CO2<\/sub>\u7535\u8fd8\u539f\u4e3a\u751f\u4ea7\u4f20\u7edf\u4e0a\u4f7f\u7528\u5316\u77f3\u71c3\u6599\u751f\u4ea7\u7684\u78b3\u5316\u5b66\u54c1\u63d0\u4f9b\u4e86\u4e00\u6761\u66ff\u4ee3\u9014\u5f84\u3002\u5178\u578b\u7684CO2<\/sub>\u7535\u8fd8\u539f\u65b9\u6cd5\u662f\u5c06\u9634\u6781CO2<\/sub>\u8fd8\u539f\u4e0e\u9633\u6781\u6c27\u53d1\u751f\u53cd\u5e94(OER)\u7ed3\u5408\u8d77\u6765\uff0c\u5bfc\u81f4OER\u6d88\u8017\u4e86\u7ea690%\u7684\u7535\u529b\u8f93\u5165\u3002\u5728\u8fd9\u91cc\uff0c\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66Paul J. A. Kenis\u6559\u6388\u7b49\u4eba\u63a2\u7d22\u4e86OER\u7684\u66ff\u4ee3\u65b9\u6848\uff0c\u5e76\u8868\u660e\u7518\u6cb9\u7684\u9633\u6781\u7535\u6c27\u5316(\u5de5\u4e1a\u751f\u7269\u67f4\u6cb9\u548c\u80a5\u7682\u751f\u4ea7\u7684\u526f\u4ea7\u54c1)\u53ef\u4ee5\u964d\u4f4e\u9ad8\u8fbe53%\u7684\u7535\u529b\u6d88\u8017\u3002\u8fd9\u964d\u4f4e\u4e86\u751f\u4ea7\u8fc7\u7a0b\u7684\u8fd0\u8425\u6210\u672c\u548c\u78b3\u8db3\u8ff9\uff0c\u4ece\u800c\u4e3a\u78b3\u4e2d\u548c\u7684\u751f\u4ea7\u8fc7\u7a0b\u5f00\u8f9f\u4e86\u9053\u8def\uff0c\u4ee5\u53ca\u5e26\u6765\u4e59\u70ef\u548c\u4e59\u9187\u7684\u7ecf\u6d4e\u751f\u4ea7\u3002\u672c\u7814\u7a76\u53ef\u4f5c\u4e3a\u4f4e\u7528\u7535\u9700\u6c42CO2<\/sub>\u7535\u8fd8\u539f\u5de5\u827a\u8bbe\u8ba1\u7684\u6846\u67b6\uff0c\u63d0\u9ad8\u5176CO2<\/sub>\u5229\u7528\u6f5c\u529b\u548c\u7ecf\u6d4e\u53ef\u884c\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCo-electrolysis of CO2<\/sub>\u00a0and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Energy\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41560-019-0374-6<\/p>\n

\u56fe2\u00a0\u5de5\u4e1a\u4e0aCO2<\/sub>\u7535\u8fd8\u539f\u6d89\u53ca\u7684\u6b65\u9aa4<\/p>\n

\"\"<\/p>\n

3\u3001<\/b><\/strong>\u5168\u6c1f\u78b3\u7eb3\u7c73\u4e73\u4fc3\u8fdb\u4e86\u7535\u529b\u9a71\u52a8\u5fae\u751f\u7269CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\uff5c<\/b><\/strong>Nature Catalysis<\/b><\/strong><\/p>\n

\u5c06\u65e0\u673a\u50ac\u5316\u5242\u4e0e\u56fa\u78b3\u5fae\u751f\u7269\u76f8\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86\u7535\u529b\u9a71\u52a8\u7684CO2<\/sub>\u8fd8\u539f\u3002\u7136\u800c\uff0c\u6700\u5927\u7684\u4ea7\u91cf\u53ef\u80fd\u4f1a\u53d7\u5230\u9650\u5236\uff0c\u56e0\u4e3a\u4ecb\u8d28\u7684\u6eb6\u89e3\u5ea6\u5f88\u4f4e\uff0c\u6bd4\u5982H2<\/sub>\uff0c\u5b83\u53ef\u4ee5\u5c06\u8fd8\u539f\u5f53\u91cf\u4ece\u7535\u6781\u4f20\u9012\u5230\u5fae\u751f\u7269\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u5218\u7fc0\u6559\u6388\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u79cd\u751f\u7269\u76f8\u5bb9\u6027\u7684\u5168\u6c1f\u78b3\u7eb3\u7c73\u4e73\u4f5c\u4e3aH2<\/sub>\u8f7d\u4f53\uff0c\u5b83\u7684\u5f15\u5165\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u918b\u9178\u7684\u4ea7\u91cf\u589e\u52a0\u4e86190%\u3002\u82e5\u4ee5\u5176\u4e2d\u4e00\u79cd\u53ef\u4ea7\u4e59\u9178\u83cc\u7684\u5375\u5f62\u5b62\u56ca\u4e9a\u79cd\u4e3a\u6a21\u578b\uff0c4\u5929\u5185\u918b\u9178\u7684\u5e73\u5747\u6ef4\u5ea6\u4e3a6.4\u00b11.1 gl\u22121<\/sup>\u00a0(107 mM)\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u63a5\u8fd1100%\u3002\u8fd9\u76f8\u5f53\u4e8e1.1 mM h\u22121<\/sup>\u7684\u4ea7\u91cf\uff0c\u5728\u751f\u7269\u7535\u5316\u5b66\u7cfb\u7edf\u4e2d\u662f\u6700\u9ad8\u7684\u3002\u529b\u5b66\u7814\u7a76\u8868\u660e\uff0c\u5168\u6c1f\u78b3\u7eb3\u7c73\u4e73\u7684\u975e\u7279\u5f02\u6027\u7ed3\u5408\u4f7fH2<\/sub>\u8f6c\u79fb\u548c\u968f\u540e\u7684\u6c27\u5316\u52a8\u529b\u5b66\u63d0\u9ad8\u4e86\u4e09\u500d\u591a\u3002\u8fd9\u8868\u660e\u5f15\u5165\u7eb3\u7c73\u6c14\u4f53\u8f7d\u4f53\u662f\u53ef\u884c\u7684\uff0c\u53ef\u4ee5\u7f13\u89e3\u7531\u7535\u529b\u9a71\u52a8\u7684\u5fae\u751f\u7269\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u5546\u54c1\u5316\u5b66\u54c1\u7684\u751f\u4ea7\u74f6\u9888\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cPerfluorocarbon nanoemulsion promotes the delivery of reducing equivalents for electricity-driven microbial CO2<\/sub>\u00a0reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41929-019-0264-0<\/p>\n

\u56fe3\u00a0PFC\u7eb3\u7c73\u4e73\u7684\u5f15\u5165\u63d0\u9ad8\u4e86CO2<\/sub>\u8fd8\u539f\u7684\u6548\u7387<\/p>\n

\"\"<\/p>\n

4\u3001<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u70ed\u50ac\u5316\u548c\u7535\u50ac\u5316\u8f6c\u5316\u51c0\u8fd8\u539f<\/b><\/strong>\uff5c<\/b><\/strong>Nature Catalysis<\/b><\/strong><\/p>\n

\u8bb8\u591a\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u6709\u4ef7\u503c\u4ea7\u54c1\u7684\u7814\u7a76\u90fd\u662f\u4e3a\u4e86\u964d\u4f4e\u5927\u6c14\u4e2d\u7684\u4e8c\u6c27\u5316\u78b3\u6d53\u5ea6\u3002\u7136\u800c\uff0c\u76ee\u524d\u8fd8\u4e0d\u6e05\u695a\u5b9e\u9a8c\u5ba4\u7684\u50ac\u5316\u7ed3\u679c\u5982\u4f55\u6210\u4e3a\u51cf\u5c11\u5927\u6c14CO2<\/sub>\u51cf\u6392\u7684\u76ee\u6807\uff0c\u8fd9\u9700\u8981\u8fdb\u884c\u6574\u4f53\u7684\u80fd\u91cf\u548c\u8d28\u91cf\u5e73\u8861\u6838\u7b97\uff0c\u5728\u6b64\uff0c\u7f8e\u56fd\u54e5\u4f26\u6bd4\u4e9a\u5927\u5b66Jingguang G. Chen\u6559\u6388\u7b49\u4eba\u5206\u6790\u4e86\u6700\u8fd1\u62a5\u9053\u7684\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u7532\u9187\u7684\u70ed\u50ac\u5316\u548c\u7535\u50ac\u5316\u6027\u80fd\u3002\u8ba1\u7b97\u8868\u660e\uff0c\u5373\u4f7f\u662f\u7406\u60f3\u7684\u50ac\u5316\u8fc7\u7a0b\uff0c\u4e5f\u9700\u8981\u7531\u6bcf\u5343\u74e6\u65f6\u6392\u653e\u81f3\u5c110.2\u516c\u65a4\u4e8c\u6c27\u5316\u78b3\u7684\u7535\u529b\u6765\u9a71\u52a8\uff0c\u4ee5\u5b9e\u73b0\u4e8c\u6c27\u5316\u78b3\u7684\u51c0\u8fd8\u539f\u3002\u6211\u4eec\u7684\u7ed3\u8bba\u662f\uff0c\u53ea\u8981\u5b9e\u7528\u7684\u7535\u50ac\u5316\u5242\u7684\u53cd\u5e94\u901f\u7387\u6bd4\u76ee\u524d\u5b9e\u9a8c\u5ba4\u68c0\u6d4b\u7684\u53cd\u5e94\u901f\u7387\u5927\u4e24\u4e2a\u6570\u91cf\u7ea7\uff0c\u70ed\u50ac\u5316\u548c\u7535\u50ac\u5316\u76f8\u7ed3\u5408\u7684\u6df7\u5408\u5de5\u827a\u662f\u5c06CO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9187\u7684\u6709\u5e0c\u671b\u7684\u673a\u4f1a\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cNet reduction of CO2<\/sub>\u00a0via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41929-019-0266-y<\/p>\n

\u56fe4\u00a0CO2<\/sub>\u8f6c\u5316\u4e3a\u7532\u9187\u7684\u60c5\u51b5\u4e0b\uff0c\u6bcf\u5355\u4f4d\u7535\u529b\u7684CO2<\/sub>\u6392\u653e\u91cf\u51fd\u6570<\/p>\n

\"\"<\/p>\n

5<\/b><\/strong>\u3001<\/b><\/strong>\u5de5\u4e1a\u7535\u6d41\u5bc6\u5ea6\u4e0b\u56fa\u4f53\u954d-\u6c2e-\u78b3\u50ac\u5316\u5242\u4e0a\u7684\u9ad8\u6548CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u89e3<\/b><\/strong>\uff5cE<\/b><\/strong>ES<\/b><\/strong><\/p>\n

\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO2<\/sub>RR)\u5728\u7535\u89e3\u69fd\u8bbe\u5907\u4e2d\u5bf9\u7eafCO\u6d41\u7684\u53cd\u5e94\u6709\u671b\u6210\u4e3a\u5728\u805a\u5408\u7269\u5de5\u4e1a\u4e2d\u5546\u4e1a\u5316\u548c\u5e94\u7528\u7684\u6700\u6709\u53ef\u80fd\u7684\u8fc7\u7a0b\u3002\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u5728Ag\u3001Au\u7b49\u8d35\u91d1\u5c5e(PGM)\u50ac\u5316\u5242\u4e0a\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u6210CO\uff0c\u6210\u672c\u9ad8\uff0c\u9650\u5236\u4e86\u5176\u5e7f\u6cdb\u5e94\u7528\u3002\u5728\u8fd9\u91cc\uff0c\u67cf\u6797\u5de5\u4e1a\u5927\u5b66\u7684Peter Strasser\u6559\u6388\u7b49\u4eba\u62a5\u544a\u4e00\u4e2a\u65e0PGM\u7684\u954d\u548c\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u50ac\u5316\u5242(Ni-N-C)\uff0c\u5176\u50ac\u5316\u6027\u80fd\u53ef\u4e0e\u5de5\u4e1a\u7535\u89e3\u6761\u4ef6\u4e0b\u6700\u5148\u8fdb\u7684\u7535\u50ac\u5316\u5242\u76f8\u5ab2\u7f8e\u3002\u6211\u4eec\u4ece\u5c0f\u578bCO2<\/sub>\u9971\u548c\u6db2\u4f53\u7535\u89e3\u8d28H\u7535\u6c60\u7b5b\u9009\u8bd5\u9a8c\u8f6c\u5411\u5927\u578b\u7684\u4e8c\u6c27\u5316\u78b3\u7535\u89e3\u69fd\uff0c\u5176\u4e2d\u50ac\u5316\u5242\u88ab\u90e8\u7f72\u4e3a\u6c14\u4f53\u6269\u6563\u7535\u6781(GDEs)\uff0c\u4ee5\u521b\u5efa\u4e00\u4e2a\u53cd\u5e94\u4e09\u76f8\u754c\u9762\u3002\u5728\u73af\u5883\u538b\u529b\u3001\u6e29\u5ea6\u548c\u4e2d\u6027pH\u503c\u7684\u78b3\u9178\u6c22\u76d0\u6d41\u4f5c\u7528\u4e0b\uff0c\u6bd4\u8f83\u4e86Ni-N-C\u50ac\u5316\u5242\u7684\u6cd5\u62c9\u7b2c\u514b\u4ea7\u7387\u548cCO\u504f\u7535\u6d41\u5bc6\u5ea6\u3002\u5728\u5de5\u4e1a\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe700\u00a0<\/b><\/strong>mA cm-2<\/sup>\u7684\u60c5\u51b5\u4e0b\u8fdb\u884c\u4e86\u957f\u65f6\u95f4\u7684\u7535\u89e3\u8bd5\u9a8c\u3002Ni-N-C\u7535\u6781\u88ab\u8bc1\u660e\u53ef\u4ee5\u63d0\u4f9b200 mA cm-2<\/sup>\u4ee5\u4e0a\u7684CO\u5206\u7535\u6d41\u5bc6\u5ea6\uff0c\u5e76\u572820h\u5185\u63d0\u4f9b\u7ea685%\u7684\u7a33\u5b9a\u7684CO\u6548\u7387\u3002\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u50ac\u5316\u53cd\u5e94\u9014\u5f84\u7684\u8ba1\u7b97\u6709\u52a9\u4e8e\u4e3a\u89c2\u5bdf\u5230\u7684Ag\u548cM-N-C\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u8d8b\u52bf\u63d0\u4f9b\u5206\u5b50\u673a\u5236\u3002\u9664\u4e86\u5177\u6709\u6210\u672c\u6548\u76ca\u5916\uff0cNi-N-C\u7c89\u672b\u50ac\u5316\u5242\u5728\u9178\u6027\u3001\u4e2d\u6027\u548c\u78b1\u6027\u6761\u4ef6\u4e0b\u53ef\u4ee5\u7075\u6d3b\u64cd\u4f5c\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cE\ufb03cient CO2<\/sub>\u00a0to CO electrolysis on solid Ni\u2013N\u2013C catalysts at industrial current densities\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728EES\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1039\/c8ee02662a<\/p>\n

\u56fe5\u00a0N-C\u3001Fe-N-C\u3001Ni-N-C\u3001AgOx<\/sub>\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u53ca\u4ea7\u7269\u5206\u6790<\/p>\n

\"\"<\/p>\n

6\u3001<\/b><\/strong>Sn\/Cu\u5408\u91d1\u5728\u4f4e\u8fc7\u7535\u4f4d\u4e0b\u9ad8\u6548\u7684CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u8fd8\u539f<\/b><\/strong>\uff5c<\/b><\/strong>Nature Catalysis<\/b><\/strong><\/p>\n

\u901a\u8fc7\u7535\u5316\u5b66\u65b9\u6cd5\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6210\u7532\u9178\u76d0\uff0c\u4e3a\u51cf\u5c11\u5168\u7403\u52a0\u901f\u7684\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u548c\u751f\u4ea7\u6709\u9644\u52a0\u503c\u7684\u4ea7\u54c1\u63d0\u4f9b\u4e86\u9014\u5f84\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u7532\u9178\u76d0\u7535\u5408\u6210\u7684\u9ad8\u9009\u62e9\u6027\u8fc4\u4eca\u4e3a\u6b62\u53ea\u5728\u9ad8\u9634\u6781\u7535\u4f4d\u4e0b\u624d\u80fd\u5b9e\u73b0\u3002\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u6559\u6388\u7b49\u4eba\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7814\u7a76\u4e86\u5408\u91d1\u94dc\u548c\u9521\u5bf9\u7532\u9178\u76d0\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u5bf9\u53cd\u5e94\u70ed\u529b\u5b66\u7684\u7406\u8bba\u5206\u6790\u8868\u660e\uff0c\u94dc\u4e0e\u9521\u7684\u7ed3\u5408\u53ef\u4ee5\u6291\u5236\u6c22\u7684\u751f\u6210\u548cCO\u7684\u751f\u6210\uff0c\u4ece\u800c\u6709\u5229\u4e8e\u7532\u9178\u76d0\u7684\u751f\u6210\u3002\u4e0e\u7406\u8bba\u8d8b\u52bf\u76f8\u4e00\u81f4\uff0c\u901a\u8fc7\u5171\u7535\u6c89\u79ef\u8bbe\u8ba1\u7684CuSn3<\/sub>\u50ac\u5316\u5242\u5bf9\u7532\u9178\u76d0\u751f\u6210\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a95%\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u572850h\u5185\u6ca1\u6709\u964d\u89e3\u3002\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u8c31\u8868\u660e\uff0c\u7535\u5b50\u4eceSn\u4f20\u9012\u5230Cu\uff0c\u4ece\u800c\u4f7fSn\u5728\u5de5\u4f5c\u6761\u4ef6\u4e0b\u4fdd\u6301\u6b63\u4ef7\u6c27\u5316\u6001\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTheory-guided Sn\/Cu alloying for efficient CO2<\/sub>\u00a0electroreduction at low overpotentials\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41929-018-0200-8<\/p>\n

\u56fe6\u00a0Cux<\/sub>Sny<\/sub>\u50ac\u5316\u5242\u7684\u5236\u5907\u53ca\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

7<\/b><\/strong>\u3001<\/b><\/strong>\u94dc\u539f\u5b50\u5bf9\u50ac\u5316\u5242\u56fa\u5b9a\u5728\u5408\u91d1\u7eb3\u7c73\u7ebf\u4e0a\u7528\u4e8e\u7535\u5316\u5b66\u8fd8\u539fCO<\/b><\/strong>2<\/b><\/sub><\/strong>\uff5cNature<\/b><\/strong>\u00a0Chemistry<\/b><\/strong><\/p>\n

\u4f5c\u4e3a\u78b3\u80fd\u6e90\u5faa\u73af\u7684\u4e00\u90e8\u5206\uff0c\u4e8c\u6c27\u5316\u78b3\u7684\u7535\u5316\u5b66\u8fd8\u539f\u53ef\u4ee5\u5728\u89e3\u51b3\u6c14\u5019\u53d8\u5316\u95ee\u9898\u548c\u5168\u7403\u80fd\u6e90\u9700\u6c42\u65b9\u9762\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002\u5355\u539f\u5b50\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6027\u80fd\uff1b\u7136\u800c\uff0c\u8003\u8651\u5230\u5b83\u4eec\u7684\u5355\u4f4d\u70b9\u6027\u8d28\uff0c\u5b83\u4eec\u901a\u5e38\u53ea\u5bf9\u6d89\u53ca\u5355\u5206\u5b50\u7684\u53cd\u5e94\u654f\u611f\u3002\u5bf9\u4e8e\u6d89\u53ca\u591a\u4e2a\u5206\u5b50\u7684\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u901a\u8fc7\u5f00\u53d1\u5177\u6709\u66f4\u9ad8\u590d\u6742\u6027\u7684\u539f\u5b50\u5206\u6563\u50ac\u5316\u5242\u6765\u6539\u5584\u50ac\u5316\u6027\u80fd\u3002\u5728\u8fd9\u91cc\uff0c\u6e05\u534e\u5927\u5b66\u7684\u9648\u6668\u6559\u6388\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u79cd\u5177\u6709\u4e24\u4e2a\u76f8\u90bb\u7684\u94dc\u539f\u5b50\u7684\u50ac\u5316\u5242\uff0c\u6211\u4eec\u79f0\u4e4b\u4e3a\u201c\u539f\u5b50\u5bf9\u50ac\u5316\u5242\u201d\uff0c\u5b83\u4eec\u5171\u540c\u4f5c\u7528\u6765\u5b8c\u6210\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u5173\u952e\u53cc\u5206\u5b50\u6b65\u9aa4\u3002\u539f\u5b50\u5bf9\u50ac\u5316\u5242\u5177\u6709\u7a33\u5b9a\u7684Cu1<\/sub>0<\/sup>\u00a0– Cu1<\/sub>x+<\/sup>\u5bf9\u7ed3\u6784\uff0cCu1<\/sub>x+<\/sup>\u5438\u9644H2<\/sub>O\uff0c\u90bb\u8fd1\u7684Cu1<\/sub>0<\/sup>\u5438\u9644CO2<\/sub>\uff0c\u4ece\u800c\u4fc3\u8fdbCO2<\/sub>\u6d3b\u5316\u3002\u8fd9\u4f7f\u5f97CO\u751f\u6210\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u572892%\u4ee5\u4e0a\uff0c\u4e0e\u4e4b\u7ade\u4e89\u7684\u6790\u6c22\u53cd\u5e94\u51e0\u4e4e\u5b8c\u5168\u88ab\u6291\u5236\u3002\u5b9e\u9a8c\u8868\u5f81\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8868\u660e\uff0c\u5438\u9644\u6784\u578b\u964d\u4f4e\u4e86\u6d3b\u5316\u80fd\uff0c\u5728\u8f83\u4f4e\u7535\u4f4d\u4e0b\u5177\u6709\u8f83\u9ad8\u7684\u9009\u62e9\u6027\u3001\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCopper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2<\/sub>\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Chemistry\u4e0a\u3002<\/b><\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41557-018-0201-x<\/p>\n

\u56fe7\u00a0Cu-APC\u548c\u5176\u4ed6Pd10<\/sub>Te3<\/sub>\u7eb3\u7c73\u7ebf\u5728CO2<\/sub>RR\u4e2d\u7684\u50ac\u5316\u6027\u80fd<\/p>\n

\"\"<\/p>\n

8\u3001<\/b><\/strong>\u94dc\u50ac\u5316\u5242<\/b><\/strong>\u7535\u5316\u5b66<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f<\/b><\/strong>\u7279\u5b9a<\/b><\/strong>\u4ea7\u7269\u6d3b\u6027\u4e2d\u5fc3\u7684\u8bc1\u636e<\/b><\/strong>\uff5c<\/b><\/strong>Nature Catalysis<\/b><\/strong><\/p>\n

\u4f7f\u7528Cu\u50ac\u5316\u5242\u5728\u6c34\u4ecb\u8d28\u4e2d\u8fdb\u884c\u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f\u53ef\u4ee5\u751f\u6210\u8bb8\u591a\u4e0d\u540c\u7684C2<\/sub>\u548cC3<\/sub>\u4ea7\u7269\uff0c\u8fd9\u5c31\u4ea7\u751f\u4e86\u4e00\u4e2a\u95ee\u9898\uff0c\u5373\u662f\u5426\u6240\u6709\u7684\u4ea7\u7269\u90fd\u662f\u7531\u76f8\u540c\u7c7b\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\u4ea7\u751f\u7684\uff0c\u8fd8\u662f\u7279\u5b9a\u7684\u4ea7\u7269\u6d3b\u6027\u4f4d\u70b9\u4ea7\u751f\u4e86\u7279\u5b9a\u7684\u4ea7\u7269\u3002\u5728\u8fd9\u91cc\uff0c\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684Joel W. Ager\u6559\u6388\u901a\u8fc7\u8fd8\u539f13<\/sup>CO\u548c12<\/sup>CO2<\/sub>\u7684\u6df7\u5408\u7269\uff0c\u53d1\u73b0\u6c27\u5316\u7269\u884d\u751f\u7684Cu\u50ac\u5316\u5242\u5bf9\u4e8eC-C\u5076\u8054\u4ea7\u7269\u6709\u4e09\u79cd\u4e0d\u540c\u7c7b\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4e00\u79cd\u4ea7\u751f\u4e59\u9187\u548c\u4e59\u9178\uff0c\u53e6\u4e00\u79cd\u4ea7\u751f\u4e59\u70ef\uff0c\u8fd8\u6709\u4e00\u79cd\u4ea7\u751f1-\u4e19\u9187\u3002\u76f8\u53cd\uff0c\u7814\u7a76\u53d1\u73b0\u6ca1\u6709\u5728\u591a\u6676\u94dc\u548c\u53d6\u5411(100)\u548c(111)\u94dc\u8868\u9762\u53d1\u73b0\u4ea7\u54c1\u7279\u5f02\u6027\u4f4d\u70b9\u7684\u8bc1\u636e\u3002\u901a\u8fc7\u5bf9\u4ea7\u7269\u7684\u540c\u4f4d\u7d20\u7ec4\u6210\u8fdb\u884c\u5206\u6790\uff0c\u53ef\u4ee5\u9884\u6d4b\uff0c*COOH (CO2<\/sub>\u8fd8\u539f\u7b2c\u4e00\u6b65\u7684\u4ea7\u7269)\u7684\u5438\u9644\u80fd\u53ef\u4ee5\u63cf\u8ff0\u7ed9\u5b9a\u6d3b\u6027\u4f4d\u70b9\u7684\u4ea7\u7269\u9009\u62e9\u6027\u3002\u8fd9\u4e9b\u65b0\u7684\u89c1\u89e3\u5c06\u4f7f\u9ad8\u9009\u62e9\u6027\u50ac\u5316\u5242\u5f97\u4ee5\u5f00\u53d1\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEvidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2<\/sub>\u00a0reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Catalysis\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41929-018-0201-7<\/p>\n

\u56fe8\u00a0\u751f\u6210\u4ea7\u7269\u7684\u540c\u4f4d\u7d20\u7ec4\u6210\u548c12<\/sup>C\/13<\/sup>C\u5206\u5e03<\/p>\n

\"\"<\/p>\n

9\u3001\u5728\u6db2\u6d41\u7535\u6c60\u4e2d\u5206\u5b50\u7535\u50ac\u5316\u5242<\/b><\/strong>\u5feb\u901f<\/b><\/strong>\u3001<\/b><\/strong>\u9009\u62e9\u6027<\/b><\/strong>\u7684C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f<\/b><\/strong>\uff5cScience<\/b><\/strong><\/p>\n

\u5b9e\u9645\u7684\u7535\u5316\u5b66CO2<\/sub>\u8f6c\u6362\u9700\u8981\u4e00\u79cd\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u7684\u6761\u4ef6\u4e0b\uff0c\u4ee5\u9ad8\u9009\u62e9\u6027\u7684\u65b9\u5f0f\u8c03\u8282\u5355\u4e2a\u4ea7\u7269\u7684\u6709\u6548\u5f62\u6210\u3002\u56fa\u6001\u7535\u50ac\u5316\u5242\u5728\u7535\u6d41\u5bc6\u5ea6\u2265150 mA\/cm2<\/sup>\u65f6\u53ef\u4ee5\u5b9e\u73b0CO2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO2<\/sub>RR)\uff0c\u4f46\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u548c\u9ad8\u6548\u7387\u4e0b\u4fdd\u6301\u9ad8\u9009\u62e9\u6027\u4ecd\u662f\u4e00\u4e2a\u6311\u6218\u3002\u5206\u5b50CO2<\/sub>RR\u50ac\u5316\u5242\u53ef\u4ee5\u8bbe\u8ba1\u6210\u9ad8\u9009\u62e9\u6027\u548c\u4f4e\u8fc7\u7535\u4f4d\uff0c\u4f46\u4ec5\u5728\u4e0e\u5546\u4e1a\u64cd\u4f5c\u65e0\u5173\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u3002\u5728\u6b64\uff0c\u52a0\u62ff\u5927\u4e0d\u5217\u98a0\u54e5\u4f26\u6bd4\u4e9a\u5927\u5b66\u7684Curtis P.Berlinguette\u6559\u6388\u548c\u6cd5\u56fd\u5df4\u9ece\u5927\u5b66\u7684Marc Robert\u6559\u6388\u7b49\u5728\u6b64\u8bc1\u660e\uff0c\u915e\u83c1\u94b4\u662f\u4e00\u79cd\u5e7f\u6cdb\u4f7f\u7528\u7684\u5206\u5b50\u50ac\u5316\u5242\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a150 mA\/cm2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u4e3aCO\u7684\u9009\u62e9\u6027\u9ad8\u4e8e95%\u3002\u5206\u5b50\u50ac\u5316\u5242\u5728\u8fd9\u4e9b\u64cd\u4f5c\u6761\u4ef6\u4e0b\u7684\u9ad8\u6548\u5de5\u4f5c\uff0c\u4e3a\u4f18\u5316CO2<\/sub>RR\u50ac\u5316\u5242\u548c\u7535\u89e3\u69fd\u63d0\u4f9b\u4e86\u4e00\u6761\u72ec\u7279\u7684\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMolecular electrocatalysts can mediate fast, selective CO2<\/sub>\u00a0reduction in a flow cell\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1126\/science.aax4608<\/p>\n

\u56fe9\u00a0\u819c\u6d41\u53cd\u5e94\u5668\u4e0e\u94b4\u57fa\u5206\u5b50\u7535\u50ac\u5316\u5242\u7684\u9ad8\u6548CO2<\/sub>RR<\/p>\n

\"\"<\/p>\n

10\u3001\u539f\u4f4d<\/b><\/strong>X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31<\/b><\/strong>\u7528\u4e8e\u76f4\u63a5Z-scheme<\/b><\/strong>\u00a0<\/b><\/strong>\u578b<\/b><\/strong>TiO<\/b><\/strong>2<\/b><\/sub><\/strong>\/CdS\u590d\u5408\u819c\u5149\u50ac\u5316\u5242<\/b><\/strong>\u7684\u7814\u7a76<\/b><\/strong>\uff5c<\/b><\/strong>A<\/b><\/strong>M<\/b><\/strong><\/p>\n

\u53d7\u5927\u81ea\u7136\u542f\u53d1\uff0c\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u901a\u8fc7\u76f4\u63a5\u6784\u5efaZ-scheme\u5149\u50ac\u5316\u5242\u7528\u4e8e\u53ef\u6301\u7eed\u7684\u592a\u9633\u80fd\u71c3\u6599\u751f\u4ea7\u3002\u56e0\u5176\u63d0\u9ad8\u5149\u8f6c\u6362\u6548\u7387\u7684\u6709\u6548\u6027\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u7136\u800c\uff0c\u5bf9\u4e8e\u8fd9\u4e9b\u5149\u50ac\u5316\u5242\u4e2d\u76f4\u63a5\u7684Z-scheme\u7535\u8377\u8f6c\u79fb\u8fd8\u7f3a\u4e4f\u900f\u5f7b\u7684\u7406\u89e3\u548c\u76f4\u63a5\u7684\u8bc1\u636e\u3002\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u4f59\u5bb6\u56fd\u6559\u6388\u56e2\u961f\u5236\u5907\u4e86\u4e00\u79cd\u7531\u4e8c\u6c27\u5316\u949b\u548c\u786b\u5316\u9549(TiO2<\/sub>\/CdS)\u7ec4\u6210\u7684\u53ef\u56de\u6536\u7684\u76f4\u63a5Z-scheme\u590d\u5408\u8584\u819c\uff0c\u7528\u4e8e\u9ad8\u6548\u5149\u50ac\u5316\u8fd8\u539fCO2<\/sub>\u3002\u539f\u4f4dX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31(ISI-XPS)\u7814\u7a76\u4e86\u5149\u50ac\u5316\u4f53\u7cfb\u4e2d\u7535\u8377-\u8f7d\u6d41\u5b50\u76f4\u63a5\u8fc1\u79fb\u9014\u5f84\u3002\u6b64\u5916\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u6a21\u62df\u786e\u5b9a\u4e86TiO2<\/sub>\u4e0eCdS\u76f4\u63a5Z-scheme\u578b\u5f02\u8d28\u7ed3\u5f62\u6210\u7684\u5185\u5728\u539f\u56e0\u3002\u7531\u4e8e\u76f4\u63a5Z-scheme\u7cfb\u7edf\u4e2d\u8f7d\u6d41\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\u663e\u8457\u589e\u5f3a\uff0c\u4f18\u5316\u540e\u7684TiO2<\/sub>\/CdS\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u6027\u80fd\u4e3a3.5\uff0c\u4ea7\u7532\u70f7\u91cf\u5206\u522b\u662fCdS\u3001TiO2<\/sub>\u548c\u5546\u4e1aTiO2 <\/sub>(P25)\u76845.4\u500d\u548c6.3\u500d\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u5236\u5907\u9ad8\u6548\u53ef\u5faa\u73af\u5229\u7528\u7684\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cIn Situ Irradiated X-Ray Photoelectron Spectroscopy Investigation on a Direct Z-Scheme TiO2<\/sub>\/CdS Composite Film Photocatalyst\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adma.201802981<\/p>\n

\u56fe10\u00a0CdS\u3001TiO2<\/sub>\u3001TiO2<\/sub>\/CdS\u3001P25\u6837\u54c1\u7684\u5149\u50ac\u5316\u6027\u80fd\u6bd4\u8f83\u3001\u9ad8\u5206\u8fa8XPS\u53ca\u5f02\u8d28\u7ed3\uff0c\u7535\u8377\u8f7d\u6d41\u5b50\u8fc1\u79fb\u673a\u5236\u7684\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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