{"id":196650,"date":"2020-03-04T06:00:40","date_gmt":"2020-03-03T22:00:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196650"},"modified":"2020-03-03T20:00:53","modified_gmt":"2020-03-03T12:00:53","slug":"%e4%ba%8c%e7%bb%b4%e4%b8%96%e7%95%8c%ef%bc%8c%e4%b8%8d%e4%b8%80%e6%a0%b7%e7%9a%84%e7%b2%be%e5%bd%a9-2d%e7%ba%b3%e7%b1%b3%e6%9d%90%e6%96%99%e6%9c%80%e6%96%b0%e6%88%90%e6%9e%9c%e9%80%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196650","title":{"rendered":"\u4e8c\u7ef4\u4e16\u754c\uff0c\u4e0d\u4e00\u6837\u7684\u7cbe\u5f69 —-\u00a02D\u7eb3\u7c73\u6750\u6599\u6700\u65b0\u6210\u679c\u901f\u9012"},"content":{"rendered":"

\u4e00\u3001<\/b><\/strong>\u50ac\u5316\u9886\u57df<\/b><\/strong><\/p>\n

1\u3001<\/b><\/strong>\u7528\u4e8e\u539f\u4f4d\u63ed\u793a\u589e\u5f3a\u50ac\u5316\u6d3b\u6027\u7684\u4e8c\u7ef4\u6742\u5316\u8d85\u6676\u683c\u7535\u50ac\u5316\u5fae\u5668\u4ef6\u7684\u7814\u7a76<\/b><\/strong>\u00a0<\/b><\/strong><\/p>\n

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\u56fe1\uff1a<\/b><\/strong>\u4e8c\u7ef4\u6742\u5316\u8d85\u6676\u683c\u6676\u9762\u95f4\u8ddd\u548c\u7535\u50ac\u5316\u6d4b\u8bd5\u56fe<\/b><\/strong><\/p>\n

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2\u3001<\/b><\/strong>\u7528\u4e8e\u6790\u6c22\u53cd\u5e94\u7684\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

H+<\/sup>\u7535\u50ac\u5316\u8fd8\u539f\u4e3aH2<\/sub>\u662f\u4efb\u4f55\u57fa\u4e8e\u6c22\u71c3\u6599\u7684\u53ef\u518d\u751f\u80fd\u6e90\u6280\u672f\u7684\u5173\u952e\u8fc7\u7a0b\u3002\u5982\u4f55\u5bfb\u627e\u6709\u6548\u7684\u50ac\u5316\u5242\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5de8\u5927\u5174\u8da3\u3002\u5317\u5fb7\u514b\u8428\u65af\u5927\u5b66\u7684Oliviero Andreussi\u6559\u6388\u56e2\u961f\u57fa\u4e8e\u7b2c\u4e00\u6027\u539f\u7406\u6a21\u62df\uff0c\u901a\u8fc7\u7cbe\u786e\u7684\u70ed\u529b\u5b66\u8ba1\u7b97\u7814\u7a76\u4e86\u4e8c\u7ef4\uff082D\uff09\u6750\u6599\u8868\u9762\u7684\u50ac\u5316\u6027\u80fd\u3002\u53ef\u9760\u7684\u591a\u5c3a\u5ea6\u8fde\u7eed\u4f53\u5d4c\u5165\u6a21\u578b\u7528\u4e8e\u6355\u83b7\u7535\u5316\u5b66\u73af\u5883\u5bf9\u6750\u6599\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\u3002\u8be5\u9879\u5de5\u4f5c\u4f7f\u6211\u4eec\u80fd\u591f\u4ece258\u79cd\u6613\u4e8e\u5265\u79bb\u76842D\u5019\u9009\u5316\u5408\u7269\u4e2d\u7b5b\u9009\u51fa\u5408\u9002\u7684\u50ac\u5316\u5242\u3002\u4ece\u539f\u59cb\u6570\u636e\u5e93\u4e2d\uff0c\u9274\u5b9a\u51fa15\u79cd\u6709\u5e0c\u671b\u7684HER\u7535\u50ac\u5316\u5242\u3002 \u5176\u4e2d\uff0cCoO2<\/sub>\u548cFeS\u5728\u9178\u6027pH\u4e0b\u663e\u793a\u51fa\u6700\u4f4e\u7684\u8fc7\u7535\u52bf\u548c\u8f83\u5927\u7684\u7a33\u5b9a\u6027\u3002[<\/sup>2]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cCatalytic Activity and Stability of Two-Dimensional Materials for the Hydrogen Evolution Reaction\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728ACS Energy Letters\u3002<\/p>\n

\u56fe2\uff1a\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7535\u50ac\u5316\u6548\u7387\u7b5b\u9009\u8fc7\u7a0b\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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3\u3001<\/b><\/strong>\u7528\u4e8e\u589e\u5f3a\u9502\u6c27\u7535\u6c60\u4e2d<\/b><\/strong>OER \/ ORR<\/b><\/strong>\u50ac\u5316\u6d3b\u6027\u7684\u529f\u80fd\u5316\u4e8c\u7ef4\u6750\u6599\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u9502\u6c27\u7535\u6c60\u7531\u4e8e\u6c27\u8fd8\u539f\u4ea7\u7269\u5728\u9634\u6781\u4e0a\u6c89\u6dc0\u800c\u4ea7\u751f\u4e86\u8fc7\u9ad8\u7684\u7535\u52bf\uff0c\u5bfc\u81f4\u5faa\u73af\u80fd\u529b\u53d8\u5dee\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u3002\u65af\u5766\u798f\u5927\u5b66\u7684Matthias Ihme\u6559\u6388\u56e2\u961f\u91c7\u7528\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u548c\u53cd\u5e94\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\uff0c\u5f97\u51fa\u4e86\u8868\u9762\u529f\u80fd\u5316\u76842D MXene\u5728ORR \/ OER\u53cd\u5e94\u4e2d\u5177\u6709\u9ad8\u5ea6\u53ef\u8c03\u8282\u50ac\u5316\u6d3b\u6027\u7684\u7ed3\u8bba\u3002\u8be5\u529f\u80fd\u5316\u7684MXene\u6750\u6599\u548c\u57fa\u4e8e\u77f3\u58a8\u70ef\u7684\u9634\u6781\u6750\u6599\u76f8\u6bd4\uff0cORR\u6027\u80fd\u63d0\u9ad8\u4e8660\u500d\u3002\u6b64\u5916\uff0c\u4e0e\u529f\u80fd\u6027\u94c2\u78b3\u548c\u77f3\u58a8\u70ef\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u589e\u52a0\u529f\u80fd\u5316Ti4<\/sub>N3<\/sub>-MXene\u50ac\u5316\u5242\u7684\u6c1f\u4e0e\u6c27\u7ec8\u6b62\u6bd4\u4f7f\u7535\u8377\u8fc7\u7535\u4f4d\u964d\u4f4e\u591a\u8fbe70\uff05\u548c80\uff05\u3002\u8fd9\u4e9b\u7ed3\u679c\u4e3a\u5177\u6709\u4f18\u5f02\u50ac\u5316\u6d3b\u6027\u7684\u529f\u80fd\u53162D\u6750\u6599\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002[<\/sup>3]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cFunctionalization of 2D materials for enhancing OER\/ORR catalytic activity in Li\u2013oxygen batteries\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Communications Chemistry\u3002<\/p>\n

\u56fe3\uff1aTi-MXene\u5bf9ORR \/ OER\u7684\u7535\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n

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4\u3001<\/b><\/strong>\u7528\u4e8e\u9ad8\u6548\u7387C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7532\u70f7\u5316\u7684\u954d<\/b><\/strong>@<\/b><\/strong>\u7845\u6c27\u70ef\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u5bf9\u4e8e\u4e8c\u6c27\u5316\u78b3\u7532\u70f7\u5316\u7684\u975e\u5747\u76f8\u50ac\u5316\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u7814\u7a76\u4ef7\u503c\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u4f46\u5bf9\u4e8e\u5728\u5730\u58f3\u4e2d\u542b\u91cf\u8f83\u4e3a\u4e30\u5bcc\u7684\u4e8c\u7ef4\u7845\u6c27\u70ef\u7eb3\u7c73\u7247\u7814\u7a76\u8f83\u5c11\u3002\u592a\u539f\u7406\u5de5\u5927\u5b66\u7684\u95eb\u6653\u4eae\u6559\u6388\u548c\u591a\u4f26\u591a\u5927\u5b66\u7684Geoffrey A. Ozin\u6559\u6388\u56e2\u961f\u8bc1\u660e\u4e86\u954d@\u7845\u6c27\u70ef\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5177\u6709\u663e\u7740\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u4e14\u590d\u5408\u6750\u6599\u7684\u50ac\u5316\u6d3b\u6027\u5bf9\u954d\u5143\u7d20\u5728\u7845\u6c27\u70ef\u7eb3\u7c73\u7247\u5c42\u5185\u90e8\u6216\u8005\u5916\u90e8\u7684\u4f4d\u7f6e\u5341\u5206\u654f\u611f\u3002\u7814\u7a76\u7ed3\u679c\u53d1\u73b0\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u7845\u6c27\u70ef\u7684\u672b\u7aef\u57fa\u56e2\u548c\u5176\u6210\u6838\u548c\u751f\u957f\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u7684\u6eb6\u5242\u6765\u8c03\u63a7\u954d\u5143\u7d20\u7684\u4f4d\u7f6e\uff0c\u800c\u8fd9\u6b63\u597d\u51b3\u5b9a\u4e86CO2<\/sub>\u7532\u70f7\u5316\u50ac\u5316\u4e2d\u95f4\u4ea7\u7269\u548c\u8def\u5f84\u7684\u4e0d\u540c\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u5f53\u954d\u5143\u7d20\u5b58\u5728\u4e8e\u7845\u6c27\u70ef\u7684\u7247\u5c42\u4e4b\u95f4\uff0c\u5176\u8868\u73b0\u51fa90%\u4ee5\u4e0a\u7684\u9009\u62e9\u6027\u548c100\u2009mmol\u2009gNi<\/sub>\u22121<\/sup>\u2009h\u22121<\/sup>\u7684\u8f6c\u5316\u7387\u3002[<\/sup>4]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cNickel@Siloxene catalytic nanosheets for high-performance CO2<\/sub>\u00a0methanation\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nature Communications \u3002<\/p>\n

\u56fe4\uff1a<\/b><\/strong>\u539f\u4f4d<\/b><\/strong>DRIFTS<\/b><\/strong>\u5b9e\u9a8c\u6d4b\u8bd5\u548c\u50ac\u5316\u673a\u7406\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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5\u3001<\/b><\/strong>\u7528\u4e8e\u6790\u6c22\u53cd\u5e94\u7684MoTe<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684\u5feb\u901f\u7535\u5316\u5b66\u6d3b\u5316\u8fc7\u7a0b\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u7535\u50ac\u5316\u4ea7\u6c22\u662f\u7528\u4e8e\u751f\u4ea7\u53ef\u6301\u7eed\u71c3\u6599\u7684\u5173\u952e\u6280\u672f\u3002\u73b0\u9636\u6bb5\u4eba\u4eec\u666e\u904d\u8ba4\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u786b\u5c5e\u5316\u7269\u663e\u793a\u51fa\u4f5c\u4e3a\u8be5\u53cd\u5e94\u50ac\u5316\u5242\u7684\u5de8\u5927\u5e0c\u671b\u3002\u4f46\u662f\u8fc4\u4eca\u4e3a\u6b62\u5f88\u5c11\u6709\u78b2\u5316\u7269\u7684\u62a5\u9053\uff0c\u56e0\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u78b2\u5316\u7269\u50ac\u5316\u5242\u6d3b\u6027\u5f88\u4f4e\u3002\u683c\u62c9\u65af\u54e5\u5927\u5b66\u7684Jessica C. McGlynn\u548cAlexey Y. Ganin\u6559\u6388\u56e2\u961f\u7814\u7a76\u8868\u660e\u5f53\u7535\u6781\u4fdd\u6301\u9634\u6781\u504f\u538b\u65f6\uff0c\u91d1\u5c5e1T’-MoTe2<\/sub>\u7684\u50ac\u5316\u6027\u80fd\u5f97\u5230\u4e86\u663e\u7740\u63d0\u9ad8\uff0c\u540c\u65f6\u53d1\u73b0\u7ef4\u630110\u00b5mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7684\u8fc7\u7535\u4f4d\u4ece320\u00b5mV\u964d\u4f4e\u5230178\u00b5mV\u3002\u7ed3\u679c\u8ba4\u4e3a\u8fd9\u79cd\u5feb\u901f\u4e14\u53ef\u9006\u7684\u6d3b\u5316\u8fc7\u7a0b\u8d77\u6e90\u4e8eH\u57281T’-MoTe2<\/sub>\u8868\u9762\u4e0a\u7684Te\u4f4d\u7f6e\u7684\u5438\u9644\u3002\u8be5\u6d3b\u5316\u8fc7\u7a0b\u7a81\u51fa\u4e86\u7535\u6781\u6750\u6599\u7535\u5b50\u7ed3\u6784\u4e2d\u7ec6\u5fae\u53d8\u5316\u5bf9\u968f\u540e\u7535\u50ac\u5316\u6d3b\u6027\u5f71\u54cd\u7684\u91cd\u8981\u6027\u3002[<\/sup>5]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cThe rapid electrochemical activation of MoTe2<\/sub>\u00a0for the hydrogen evolution reaction\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nature Communications\u3002<\/p>\n

\u56fe5\uff1a<\/b>1T’-MoTe2<\/sub>\u6d3b\u5316\u673a\u7406\u7684XPS\u548cCV\u6d4b\u8bd5\u56fe<\/strong><\/p>\n

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1\u3001<\/b><\/strong>\u7528\u4e8e\u751f\u7269\u4f53\u5185\u548c\u4f53\u5916\u5149\u52a8\u529b\u7597\u6cd5\u7684\u5b89\u5168\u6709\u6548\u4e14\u5177\u6709\u5149\u50ac\u5316\u6d3b\u6027\u77f3\u58a8\u6c2e\u5316\u7269\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u7531\u4e8e\u5177\u6709\u5149\u50ac\u5316\u6d3b\u6027\u6210\u4e3a\u4e86\u7eb3\u7c73\u533b\u5b66\u9886\u57df\u4e2d\u6bd4\u8f83\u6709\u5e0c\u671b\u7684\u4e00\u79cd\u5e94\u7528\u6750\u6599\u3002\u7136\u800c\u7531\u4e8e\u5176\u6f5c\u5728\u7684\u5206\u5b50\u4f5c\u7528\u673a\u5236\u5c1a\u4e0d\u6e05\u695a\uff0c\u5173\u4e8e\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u5728\u764c\u75c7\u6cbb\u7597\u4e2d\u7684\u9002\u7528\u6027\u7814\u7a76\u5341\u5206\u6709\u9650\u3002\u91cc\u96c5\u65af\u7279\u5927\u5b66\u7684Maurizio Prato\uff0c\u79d1\u514b\u5927\u5b66\u7684\u00d6nder Metin\u548c\u5b89\u5361\u62c9\u5927\u5b66\u7684A\u00e7elya Yilmazer\u6559\u6388\u56e2\u961f\u8bc1\u660e\u5728\u6ca1\u6709\u5176\u4ed6\u4efb\u4f55\u8f7d\u4f53\u6216\u5149\u654f\u5242\u7684\u6761\u4ef6\u4e0b\uff0c\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u7684\u5149\u6fc0\u53d1\u53ef\u76f4\u63a5\u7528\u4e8e\u5149\u52a8\u529b\u7597\u6cd5\u3002\u5728\u5149\u7ebf\u7167\u5c04\u4e0b\uff0c\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u7684\u5904\u7406\u53ef\u4ee5\u6740\u6b7b\u764c\u7ec6\u80de\uff0c\u5e76\u4e14\u65e0\u9700\u4efb\u4f55\u5176\u4ed6\u7eb3\u7c73\u7cfb\u7edf\u6216\u5316\u5b66\u6cbb\u7597\u836f\u7269\u3002\u8be5\u7269\u8d28\u5728\u4f53\u5916\u53ef\u4ee5\u88ab\u80bf\u7624\u7ec6\u80de\u6709\u6548\u5438\u6536\u3002\u7ecf\u8fc7\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u548c\u5149\u5904\u7406\u7ec6\u80de\u7684\u8f6c\u5f55\u7ec4\u548c\u86cb\u767d\u8d28\u7ec4\u8868\u660e\u4e0e\u6c27\u5316\u5e94\u6fc0\uff0c\u7ec6\u80de\u6b7b\u4ea1\u548c\u7ec6\u80de\u51cb\u4ea1\u8fc7\u7a0b\u4e2d\u5b58\u5728\u6fc0\u6d3b\u7684\u73b0\u8c61\u3002\u8fd9\u6709\u529b\u5730\u8868\u660e\uff0c\u4ec5\u5f53\u4e0e\u5149\u7167\u7ec4\u5408\u4f7f\u7528\u65f6\uff0c\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u624d\u80fd\u6740\u6b7b\u764c\u7ec6\u80de\u3002\u4ecb\u5b54\u5f62\u5f0f\u7684\u5168\u8eab\u7ed9\u836f\u5bfc\u81f4\u4ece\u8180\u80f1\u4e2d\u6d88\u9664\u800c\u6ca1\u6709\u4efb\u4f55\u5168\u8eab\u6bd2\u6027\u3002\u5f53\u4e0e\u5c40\u90e8\u5149\u7597\u76f8\u7ed3\u5408\u65f6\uff0c\u6750\u6599\u7684\u65bd\u7528\u624d\u80fd\u663e\u7740\u51cf\u5c0f\u80bf\u7624\u4f53\u79ef\u3002\u8fd9\u9879\u7814\u7a76\u4e3a\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\u4ee5\u53ca\u5176\u4ed62D\u7eb3\u7c73\u6750\u6599\u5728\u672a\u6765\u764c\u75c7\u6cbb\u7597\u4e2d\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002[<\/sup>6]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cPhotocatalytically Active Graphitic Carbon Nitride as an Effective and Safe 2D Material for In Vitro and In Vivo Photodynamic Therapy\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Small\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>\uff1a<\/b><\/strong>g-C<\/b><\/strong>3<\/b><\/sub><\/strong>N<\/b><\/strong>4<\/b><\/sub><\/strong>\u4ecb\u5bfc\u7684\u5149\u52a8\u529b\u7597\u6cd5\u7684\u4f53\u5185\u8bc4\u4f30\u7ed3\u679c\u56fe<\/b><\/strong><\/p>\n

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2\u3001<\/b><\/strong>\u901a\u4e0e\u8840\u6d46\u819c\u7ed3\u5408\u4fc3\u8fdb<\/b><\/strong>TGF-\u03b2<\/b><\/strong>\u4fe1\u53f7\u4f9d\u8d56\u7684\u4e0a\u76ae-\u95f4\u5145\u8d28\u8f6c\u5316\u7684\u6c27\u5316\u77f3\u58a8\u70ef\u589e\u5f3a\u764c\u75c7\u8f6c\u79fb\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>7\uff1a<\/b><\/strong>\u6c27\u5316\u77f3\u58a8\u70ef\u589e\u5f3a\u764c\u75c7\u8f6c\u79fb\u673a\u7406\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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3\u3001<\/b><\/strong>\u7528\u4e8e\u6c27\u5316\u8fd8\u539f\u5206\u5b50\u7684\u5b9e\u65f6\u5149\u81f4\u53d1\u5149\u6210\u50cf<\/b><\/strong>MoS<\/b><\/strong>2<\/b><\/sub><\/strong>\u50cf\u7d20\u9635\u5217\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u5206\u5b50\u5728\u65f6\u7a7a\u4e0a\u884c\u4e3a\u7684\u76d1\u6d4b\u5bf9\u4e8e\u7406\u89e3\u751f\u7269\u5316\u5b66\u7cfb\u7edf\u4ee5\u53ca\u5f00\u53d1\u65b0\u6280\u672f\u81f3\u5173\u91cd\u8981\u3002\u5c3d\u7ba1\u5149\u5b66\u65b9\u6848\u662f\u65e0\u521b\u4e14\u53ef\u6269\u5c55\u7684\uff0c\u4f46\u4e0e\u7535\u68c0\u6d4b\u65b9\u6cd5\u76f8\u6bd4\uff0c\u54cd\u5e94\u901f\u5ea6\u901a\u5e38\u8f83\u6162\u3002\u6b64\u5916\uff0c\u8bb8\u591a\u7528\u4e8e\u6c27\u5316\u8fd8\u539f\u68c0\u6d4b\u7684\u8367\u5149\u5206\u5b50\u5728\u957f\u65f6\u95f4\u66dd\u5149\u540e\u4eae\u5ea6\u4f1a\u964d\u4f4e\u3002\u5eb7\u5948\u5c14\u5927\u5b66\u7684P. L. McEuen\u6559\u6388\u56e2\u961f\u8bc1\u660e\u5355\u5c42MoS2<\/sub>\u7684\u201c\u50cf\u7d20\u201d\u9635\u5217\u7684\u5149\u81f4\u53d1\u5149\u53ef\u4ee5\u53cd\u6620\u6c27\u5316\u8fd8\u539f\u5206\u5b50\u6d53\u5ea6\u7684\u65f6\u7a7a\u53d8\u5316\u3002\u7531\u4e8e\u63ba\u6742\u5bf9MoS2<\/sub>\u5149\u81f4\u53d1\u5149\u6709\u5f88\u5927\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\u5176\u5c40\u90e8\u5316\u5b66\u52bf\u7684\u53d8\u5316\u53ef\u8c03\u8282MoS2<\/sub>\u7684\u5149\u81f4\u53d1\u5149\u3002\u5176\u57285\u03bcm\u00d75\u03bcm\u50cf\u7d20\u4e0a\u7684\u7075\u654f\u5ea6\u4e3a0.9 mV \/ Hz\uff0c\u76f8\u5f53\u4e8e\u5728100\u6beb\u79d2\u5e27\u901f\u7387\u4e0b\uff0c\u4f4e\u81f3\u7eb3\u6469\u5c14\u6d53\u5ea6\u7684\u6c27\u5316\u8fd8\u539f\u5206\u5b50\u6d53\u5ea6\u53d8\u5316\u8d85\u8fc7\u767e\u5206\u6570\u3002[<\/sup>8]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cMoS2<\/sub>\u00a0pixel arrays for real-time photoluminescence imaging of redox molecules\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science Advances\u3002<\/p>\n

\u56fe8\uff1aMoS<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0PL\u6d4b\u91cf\u503c\u4e0e\u79bb\u5b50\u6db2\u4f53\u6805\u6781\u7535\u538b\u5173\u7cfb<\/b><\/strong>(VLG)<\/b><\/strong>\u7684\u7535\u8def\u539f\u7406\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

    \n
  1. Guo Y, Chen Q, Nie A, et al. 2D Hybrid Superlattice-Based On-Chip Electrocatalytic Microdevice for In Situ Revealing Enhanced Catalytic Activity[J]. ACS nano, 2020.<\/li>\n
  2. Karmodak N, Andreussi O. Catalytic Activity and Stability of Two-Dimensional Materials for the Hydrogen Evolution Reaction[J]. ACS Energy Letters, 2020.<\/li>\n
  3. Ostadhossein A, Guo J, Simeski F, et al. Functionalization of 2D materials for enhancing OER\/ORR catalytic activity in Li\u2013oxygen batteries[J]. Communications Chemistry, 2019, 2(1): 1-11.<\/li>\n
  4. Yan X, Sun W, Fan L, et al. Nickel@ Siloxene catalytic nanosheets for high-performance CO2<\/sub>methanation[J]. Nature communications, 2019, 10(1): 1-11.<\/li>\n
  5. McGlynn J C, Dankwort T, Kienle L, et al. The rapid electrochemical activation of MoTe2<\/sub>for the hydrogen evolution reaction[J]. Nature communications, 2019, 10(1): 1-9.<\/li>\n
  6. Taheri H, Unal M A, Sevim M, et al. Photocatalytically Active Graphitic Carbon Nitride as an Effective and Safe 2D Material for In Vitro and In Vivo Photodynamic Therapy[J]. Small, 2020: 1904619.<\/li>\n
  7. Zhu J, Li B, Xu M, et al. Graphene Oxide Promotes Cancer Metastasis through Associating with Plasma Membrane to Promote TGF-\u03b2 Signaling-Dependent Epithelial-Mesenchymal Transition[J]. ACS nano, 2019.<\/li>\n
  8. Reynolds M F, Guimar\u00e3es M H D, Gao H, et al. MoS2<\/sub>pixel arrays for real-time photoluminescence imaging of redox molecules[J]. Science advances, 2019, 5(11): eaat9476.<\/li>\n<\/ol>\n

    \u672c\u6587\u7531L<\/b><\/strong>eo<\/b><\/strong>\u00a0W<\/b><\/strong>u<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

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