{"id":196770,"date":"2020-03-03T06:39:23","date_gmt":"2020-03-02T22:39:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196770"},"modified":"2020-03-02T15:40:06","modified_gmt":"2020-03-02T07:40:06","slug":"%e5%8a%a0%e6%8b%bf%e5%a4%a7%e8%83%bd%e6%ba%90-%e7%8e%af%e5%a2%83-%e6%9d%90%e6%96%99%e5%a4%a7%e7%89%9b%e9%99%88%e5%bf%a0%e4%bc%9f%ef%bc%8c%e5%ad%99%e5%ad%a6%e8%89%af%ef%bc%8c%e6%9d%8e%e6%9c%9d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196770","title":{"rendered":"\u52a0\u62ff\u5927\u80fd\u6e90\/\u73af\u5883\/\u6750\u6599\u5927\u725b\u201c\u9648\u5fe0\u4f1f\/\u5b59\u5b66\u826f\/\u674e\u671d\u519b\/Jeff R. Dahn\u548cLinda\u00a0F. Nazar\u201d\u6700\u65b0\u6210\u679c\u68b3\u7406"},"content":{"rendered":"

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2 <\/b><\/strong>\u897f\u5b89\u5927\u7565\u5927\u5b66\u5b59\u5b66\u826f<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

E<\/b><\/strong>nergy Storage Materials<\/b><\/strong>\uff1a\u53cc\u529f\u80fdLi<\/b><\/strong>3<\/b><\/sub><\/strong>PO<\/b><\/strong>4<\/b><\/sub><\/strong>\u754c\u9762\u5b9e\u73b0\u9ad8\u5ea6\u7a33\u5b9a\u7684\u9ad8\u954d\u5c42\u72b6\u6b63\u6781<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u72ec\u7279\u7684\u5b89\u5168\u6027\u548c\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u5c06\u4f1a\u9010\u6e10\u53d6\u4ee3\u4f20\u7edf\u7684\u6db2\u57fa\u9502\u79bb\u5b50\u7535\u6c60\u3002\u7136\u800c\uff0c\u5927\u90e8\u5206\u6b63\u6781\u6750\u6599\u90fd\u4e0e\u6700\u6709\u53ef\u80fd\u5b9e\u73b0\u5546\u4e1a\u5316\u7684\u786b\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u5b58\u5728\u7740\u754c\u9762\u4e0d\u5339\u914d\u95ee\u9898\uff0c\u8fd9\u4f1a\u4e25\u91cd\u5f71\u54cd\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u9274\u4e8e\u6b64\uff0c\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66\u5b59\u5b66\u826f\u4e0e\u5929\u6d25\u7406\u5de5\u5927\u5b66\u7f57\u4fca<\/b><\/strong>\u56e2\u961f\u91c7\u7528\u539f\u5b50\u5c42\u6c89\u79ef\uff08ALD\uff09\u7684\u65b9\u6cd5\u5236\u5907\u51fa\u4e86\u53cc\u529f\u80fdLi3<\/sub>PO4<\/sub>\u4fee\u9970\u7684\u9ad8\u954d\u5c42\u72b6\u6b63\u6781\u6750\u6599\uff08NMC811\uff09\u4ee5\u7528\u4e8e\u786b\u57fa\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\uff08\u56fe8\uff09[4]<\/sup>\u3002\u76f8\u6bd4\u4e8e\u7eaf\u7684NMC811\uff0c\u4fee\u9970\u540e\u7684NMC811\u6750\u6599\u8868\u73b0\u51fa\u4e86\u66f4\u9ad8\u7684\u521d\u59cb\u5bb9\u91cf\uff080.1C\uff1a170.6 mAh g-1<\/sup>\uff09\u3001\u66f4\u597d\u7684\u500d\u7387\u6027\u80fd\uff081C\uff1a115 mAh g-1<\/sup>\uff09\u548c\u66f4\u5c0f\u7684\u6781\u5316\uff08\u56fe9\uff09\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5b83\u8fd8\u6709\u7740\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff1a0.2C\u4e0b\u5faa\u73af300\u5708\uff0c\u6bcf\u5708\u5bb9\u91cf\u8870\u51cf\u4ec5\u67090.22 mAh g-1<\/sup>\u3002\u4f5c\u8005\u91c7\u7528\u4e86X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u5149\u8c31\u3001X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u548c\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u5bf9\u6750\u6599\u7684\u8868\u9762\u5316\u5b66\u72b6\u6001\u548c\u7ed3\u6784\u6f14\u53d8\u8fdb\u884c\u4e86\u8be6\u7ec6\u5730\u7814\u7a76\u3002\u7ed3\u679c\u8868\u660e\uff0cLi3<\/sub>PO4<\/sub>\u4fee\u9970\u4e0d\u4ec5\u663e\u8457\u6291\u5236\u4e86NMC811\u4e0e\u786b\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u526f\u53cd\u5e94\u8fd8\u80fd\u591f\u7f13\u89e3NMC811\u9897\u7c92\u7684\u7834\u88c2\u548c\u76f8\u7684\u6f14\u53d8\u3002\u8be5\u5de5\u4f5c\u4e3a\u5b9e\u73b0\u9ad8\u6027\u80fd\u786b\u57fa\u5168\u56fa\u6001\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7406\u60f3\u53ef\u63a7\u7684\u754c\u9762\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u4e5f\u4e3a\u5176\u4ed6\u56fa\u6001\u7535\u6c60\u4f53\u7cfb\u63d0\u4f9b\u4e86\u501f\u9274\u3002<\/p>\n

\u56fe8<\/b><\/strong>\u00a0Li<\/b><\/strong>3<\/b><\/sub><\/strong>PO<\/b><\/strong>4<\/b><\/sub><\/strong>\u4fee\u9970\u7684NMC<\/b><\/strong>811<\/b><\/strong>\u6b63\u6781\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>9 Li<\/b><\/strong>3<\/b><\/sub><\/strong>PO<\/b><\/strong>4<\/b><\/sub><\/strong>\u4fee\u9970\u7684NMC<\/b><\/strong>811<\/b><\/strong>\u5728\u786b\u57fa\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3 <\/b><\/strong>\u9ea6\u5409\u5c14\u5927\u5b66\u674e\u671d\u519b<\/b><\/strong><\/p>\n

i<\/b><\/strong>Science<\/b><\/strong>\uff1aGaN\u7eb3\u7c73\u7ebf\u9ad8\u6548\u50ac\u5316\u6c2e\u6c14\u548c\u6c34\u8f6c\u5316\u4e3a\u6c28<\/b><\/strong><\/p>\n

\u6c28\uff08NH3<\/sub>\uff09\u662f\u73b0\u4ee3\u793e\u4f1a\u6700\u91cd\u8981\u7684\u5316\u5b66\u4ea7\u54c1\u4e4b\u4e00\u3002\u81ea20\u4e16\u7eaa\u4ee5\u6765\uff0cHaber-Bosch\u6cd5\u4e00\u76f4\u90fd\u662f\u5408\u6210\u6c28\u7684\u4e3b\u8981\u65b9\u6cd5\uff0c\u4f46\u8be5\u65b9\u6cd5\u9700\u8981\u5728\u9ad8\u6e29\u9ad8\u538b\u4e0b\u4f7f\u6c2e\u6c14\u548c\u53ef\u71c3\u6027\u7684\u6c22\u6c14\u8fdb\u884c\u53cd\u5e94\uff0c\u8017\u80fd\u9ad8\u4e14\u6c61\u67d3\u5927\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u201c\u53ef\u6301\u7eed\u7684\u201d\u56fa\u6c2e\u65b9\u6cd5\u5c31\u6210\u4e86\u6750\u6599\u4eba\u548c\u5316\u5b66\u4eba\u7684\u8ffd\u6c42\uff0c\u8fd9\u4e5f\u5173\u4e4e\u4eba\u7c7b\u7684\u798f\u7949\u3002\u5728\u6b64\uff0c\u52a0\u62ff\u5927\u9ea6\u5409\u5c14\u5927\u5b66\u7684\u674e\u671d\u519b\u548c\u7f8e\u56fd\u5bc6\u6b47\u6839\u5927\u5b66\u7684Mi<\/b><\/strong>\u00a0<\/b><\/strong>Zetian<\/b><\/strong>\u56e2\u961f\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u8d85\u7a33\u5b9a\u7684\u6c2e\u57fa\u5149\u50ac\u5316\u534a\u5bfc\u4f53\u6750\u6599GaN\uff0c\u5b83\u80fd\u591f\u5b9e\u73b0\u9ad8\u6548\u3001\u6301\u4e45\u548c\u6e29\u548c\u7684\u5149\u50ac\u5316\u56fa\u6c2e\u53cd\u5e94\uff08\u56fe10\uff0c\u56fe11\uff09[5]<\/sup>\u3002\u8fd9\u4e2a\u50ac\u5316\u5242\u5bf9N2<\/sub>\u5177\u6709\u5f3a\u7684\u5316\u5b66\u5438\u9644\u4f5c\u7528\u4e14\u80fd\u591f\u4f7f\u7535\u5b50\u7acb\u5373\u4ece\u5176\u8868\u9762\u7a7a\u4f4d\u8f6c\u79fb\u81f3N2<\/sub>\u3002\u5b83\u4e0d\u9700\u8981\u4f7f\u7528H2<\/sub>\uff0c\u4ec5\u5229\u7528N2<\/sub>\u548cH2<\/sub>O\u5c31\u80fd\u5b8c\u6210\u56fa\u6c2e\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u7814\u7a76\u8fd8\u8868\u660e\u8be5\u6c2e\u57fa\u534a\u5bfc\u4f53\u8fd8\u80fd\u591f\u51cf\u5c11\u7535\u5b50-\u7a7a\u7a74\u590d\u5408\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u8be5\u6750\u6599\u5728\u5149\u50ac\u5316\u56fa\u6c2e\u65b9\u9762\u8868\u73b0\u51fa\u4e86\u8f83\u9ad8\u7684\u53ef\u884c\u6027\u548c\u5b9e\u9645\u6027\u3002<\/p>\n

\u56fe1<\/b><\/strong>0 <\/b><\/strong>GaN\u7eb3\u7c73\u7ebf\u5149\u50ac\u5316\u56fa\u6c2e\u793a\u610f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>1 <\/b><\/strong>\u5149\u50ac\u5316\u56fa\u6c2e\u7ed3\u679c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4 <\/b><\/strong>\u8fbe\u5c14\u8c6a\u65af\u5927\u5b66Jeff<\/b><\/strong>\u00a0R. Dahn<\/b><\/strong><\/p>\n

C<\/b><\/strong>hemistry of Materials<\/b><\/strong>\uff1a\u65e0\u94b4\u9ad8\u954d\u6838\u58f3\u7ed3\u6784\u6b63\u6781\u6750\u6599<\/b><\/strong><\/p>\n

\u6838\u58f3\u7ed3\u6784\uff08Core-Shell\uff0cCS\uff09\u548c\u6d53\u5ea6\u68af\u5ea6\u7ed3\u6784\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u7528\u4e8e\u9ad8\u954d\u7535\u6781\u6750\u6599\u4ece\u800c\u6539\u5584\u5176\u7ed3\u6784\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u4e0a\u8ff0\u7684\u8bbe\u8ba1\u601d\u60f3\u5374\u8fd8\u6ca1\u6709\u5728\u65e0\u94b4\u4f53\u7cfb\u4e2d\u5e94\u7528\u8fc7\u3002\u5728\u6b64\uff0c\u8fbe\u5c14\u8c6a\u65af\u5927\u5b66\u7684Jeff<\/b><\/strong>\u00a0R. Dahn<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u901a\u8fc7\u4e00\u79cd\u8fde\u7eed\u7684\u7f50\u5f0f\u53cd\u5e94\u5668\u5236\u5907\u51fa\u4e86\u4e00\u79cdNi(OH)<\/b><\/strong>2<\/b><\/sub><\/strong>\u6838\uff1a<\/b><\/strong>Ni<\/b><\/strong>0.83<\/b><\/sub><\/strong>M<\/b><\/strong>0.17<\/b><\/sub><\/strong>(OH)<\/b><\/strong>2<\/b><\/sub><\/strong>\u58f3\u524d\u9a71\u4f53<\/b><\/strong>\uff08M = Mg, Al\u548cMn\uff09[6]<\/sup>\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u4e5f\u5236\u5907\u4e86\u5747\u5300\u7684<\/b><\/strong>Ni<\/b><\/strong>0.95<\/b><\/sub><\/strong>M<\/b><\/strong>0.05<\/b><\/sub><\/strong>(OH)<\/b><\/strong>2<\/b><\/sub><\/strong>\u524d\u9a71\u4f53\uff0c\u5b83\u4e0e\u4e0a\u8ff0\u6838\u58f3\u7ed3\u6784\u7684\u6750\u6599\u5177\u6709\u76f8\u540c\u7684\u5e73\u5747\u6210\u5206\u3002\u6df7\u9502\u7145\u70e7\u4e4b\u540e\uff0c\u5b83\u4eec\u5c31\u8f6c\u53d8\u4e3a\u4e86\u76f8\u5e94\u7684\u9502\u5316\u6c27\u5316\u7269LNO\uff1aNiM83\/17\u548cLNMO\u3002\u5728\u7145\u70e7\u7684\u65f6\u5019\uff0cM\u539f\u5b50\u4f1a\u53d1\u751f\u6269\u6563\uff0c\u7814\u7a76\u8868\u660eMg\u5728\u9897\u7c92\u95f4\u5448\u73b0\u5747\u5300\u5206\u5e03\u7684\u72b6\u6001\uff0cAl\u548cMn\u5219\u4e3b\u8981\u805a\u96c6\u5728\u9897\u7c92\u8868\u9762\uff08\u56fe12\uff09\u3002\u540c\u65f6\u8fd8\u53d1\u73b0\uff0cLNO\uff1aNiMn<\/b><\/strong>83\/17\u51fa\u73b0\u4e86\u660e\u663e\u7684Li\/Ni\u6df7\u6392\u73b0\u8c61\uff0cLNO\uff1aNiAl<\/b><\/strong>83\/17\u548cLNO\uff1aNiMg<\/b><\/strong>83\/17\u5219\u4ec5\u67092%\u7684Ni\u5728Li\u4f4d\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u542b\u6709Al\u7684\u6838\u58f3\u7ed3\u6784\u7ed3\u6784\u6750\u6599\u62e5\u6709\u8005\u6700\u597d\u7684\u7535\u6027\u80fd\uff08\u56fe13\uff09\u3002\u7136\u800c\uff0c\u6838\u58f3\u4e4b\u95f4\u4e0d\u53ef\u907f\u514d\u7684\u76f8\u4e92\u6269\u6563\u4e5f\u4f7f\u5236\u5907\u51fa\u5177\u6709\u7cbe\u786e\u5fae\u7ed3\u6784\u7684\u6750\u6599\u53d8\u5f97\u5341\u5206\u56f0\u96be\u3002<\/p>\n

\u56fe1<\/b><\/strong>2 <\/b><\/strong>\u6838\u58f3\u7ed3\u6784<\/b><\/strong>LNO<\/b><\/strong>\uff1a<\/b><\/strong>NiM83\/17<\/b><\/strong>\u6750\u6599\u7684\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>3 <\/b><\/strong>\u6838\u58f3\u7ed3\u6784<\/b><\/strong>LNO<\/b><\/strong>\uff1a<\/b><\/strong>NiM83\/17<\/b><\/strong>\u6750\u6599\u7684\u7535\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Journal of The Electrochemical Society<\/b><\/strong>\uff1a\u5355\u6676<\/b><\/strong>LiNi<\/b><\/strong>1-x-y<\/b><\/sub><\/strong>Mn<\/b><\/strong>x<\/b><\/sub><\/strong>Co<\/b><\/strong>y<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6750\u6599\u957f\u5faa\u73af\u524d\u540e\u5fae\u7ed3\u6784\u89c2\u5bdf<\/b><\/strong><\/p>\n

LiNi1-x-y<\/sub>Mnx<\/sub>Coy<\/sub>O2<\/sub>\u6750\u6599\uff08NMC532\uff0cNMC622\u548cNMC811\uff09\u5df2\u7ecf\u6210\u529f\u5b9e\u73b0\u5546\u4e1a\u5316\u5e76\u5e7f\u6cdb\u5e94\u7528\u5728\u7535\u52a8\u6c7d\u8f66\u4e0a\u3002\u4f46\u7814\u7a76\u8005\u4eec\u4ecd\u81f4\u529b\u4e8e\u63a2\u7a76\u5b83\u4eec\u5faa\u73af\u65f6\u7684\u8870\u51cf\u673a\u7406\u4ee5\u671f\u8fdb\u4e00\u6b65\u6539\u8fdb\u5b83\u7684\u5faa\u73af\u6027\u80fd\u3002\u5bf9\u4e8e\u591a\u6676NMC\u6750\u6599\u800c\u8a00\uff0c\u5fae\u88c2\u7eb9\u7684\u6269\u5c55\u662f\u6750\u6599\u7535\u6027\u80fd\u4e0b\u964d\u7684\u4e3b\u8981\u539f\u56e0\u3002\u8fd9\u4e9b\u5fae\u88c2\u7eb9\u8d77\u6e90\u4e8e\u4e8c\u6b21\u9897\u7c92\u4e2d\u5c0f\u6676\u7c92\u5728\u5145\u653e\u7535\u65f6\u5404\u5411\u5f02\u6027\u7684\u4f53\u79ef\u53d8\u5316\u3002\u7531\u4e8e\u5177\u6709\u5404\u5411\u540c\u6027\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u5355\u6676NMC\u6750\u6599\u4e0d\u4f1a\u4ea7\u751f\u5fae\u88c2\u7eb9\uff0c\u4ece\u800c\u76f8\u6bd4\u591a\u6676\u6750\u6599\u62e5\u6709\u66f4\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/b><\/strong>\u7136\u800c\uff0c\u8fc4\u4eca\u4e3a\u6b62\u9c9c\u6709\u5b66\u8005\u5bf9\u5355\u6676NMC\u6750\u6599\u5728\u957f\u5faa\u73af\u524d\u540e\u7684\u5fae\u7ed3\u6784\u8fdb\u884c\u89c2\u5bdf\u7814\u7a76\u3002\u5728\u6b64\uff0c\u8fbe\u5c14\u8c6a\u65af\u5927\u5b66\u7684Jeff<\/b><\/strong>\u00a0R. Dahn<\/b><\/strong>\u56e2\u961f\u5c31\u5bf9\u4e09\u79cdNCM\u6750\u6599\uff08NMC532\uff0cNMC622\u548cNMC811\uff09\u957f\u5faa\u73af\u540e\u7684\u5fae\u7ed3\u6784\u8fdb\u884c\u4e86\u7814\u7a76\uff08\u56fe14\uff09[7]<\/sup>\u3002\u4ee5\u5355\u6676NMC622\u6750\u6599\u4e3a\u4f8b\uff0c\u5373\u65f6\u5faa\u73af4<\/b><\/strong>000<\/b><\/strong>\u6b21\u540e\u5b83\u4e5f\u51e0\u4e4e\u4e0d\u5b58\u5728\u5f88\u5c0f\u7684\u5fae\u88c2\u7eb9\uff0c\u800c\u4e14\u5fae\u7ed3\u6784\u4e0e\u521d\u59cb\u7684\u7535\u6c60\u6750\u6599\u65e0\u5f02<\/b><\/strong>\uff08\u56fe15\uff09\u3002\u4e0d\u8fc7\uff0c\u65e0\u8bba\u662f\u521d\u59cb\u7684\u7535\u6c60\u6750\u6599\u8fd8\u662f\u6df1\u5ea6\u5faa\u73af\u540e\u7684\u6750\u6599\u90fd\u6709\u4e00\u4e9b\u5355\u6676\u9897\u7c92\u5b58\u5728\u7740\u5e73\u884c\u7684\u5fae\u88c2\u7f1d\uff0c\u8fd9\u662f\u7535\u6781\u5728\u6eda\u538b\u7684\u65f6\u5019\u4ea7\u751f\u7684\u3002\u8fd9\u8868\u660e\u5355\u6676NMC\u6750\u6599\u975e\u5e38\u6709\u5e0c\u671b\u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u5faa\u73af\u6027\u80fd\u7684\u9502\u79bb\u5b50\u7535\u6c60\u3002<\/p>\n

\u56fe1<\/b><\/strong>4 <\/b><\/strong>\u4e09\u79cd\u7ec4\u5206NMC\u6750\u6599\u7684\u5faa\u73af\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>5 <\/b><\/strong>\u5355\u6676NMC<\/b><\/strong>622<\/b><\/strong>\u6750\u6599\u5faa\u73af\u524d\u540e\u5fae\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5 <\/b><\/strong>\u6ed1\u94c1\u5362\u5927\u5b66Linda<\/b><\/strong>\u00a0F. Nazar<\/b><\/strong><\/p>\n

A<\/b><\/strong>dvanced Energy Materials<\/b><\/strong>\uff1a\u591a\u79bb\u5b50\u534f\u540c\u8fc1\u79fb\u63d0\u9ad8<\/b><\/strong>NaSICON<\/b><\/strong>\u578b\u56fa\u6001\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u7387<\/b><\/strong><\/p>\n

\u94a0\u8d85\u79bb\u5b50\u5bfc\u4f53\uff08NaSICON\uff09\uff0cNa1<\/sub>+n<\/sub>Zr2<\/sub>Sin<\/sub>P3-n<\/sub>O12<\/sub>\uff0c\u662f\u6700\u6709\u5e0c\u671b\u7684Na+<\/sup>\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u4eba\u4eec\u5bf9\u5176\u672c\u5f81\u7684\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u4ecd\u7136\u6ca1\u6709\u5b8c\u5168\u660e\u767d\u3002\u5728\u6b64\uff0c\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66\u7684<\/b><\/strong>Linda F. Nazar<\/b><\/strong>\u3001\u4e0a\u6d77\u5927\u5b66\u65bd\u601d\u9f50\u3001\u6fb3\u5927\u5229\u4e9a\u6089\u5c3c\u5927\u5b66<\/b><\/strong>Maxim Avdeev<\/b><\/strong>\u548c\u4e2d\u79d1\u9662\u7269\u7406\u6240\u80e1\u52c7\u80dc<\/b><\/strong>\u56e2\u961f\u5408\u4f5c\u63ed\u793a\u4e86\u5355\u659cNa3<\/sub>Zr2<\/sub>Si2<\/sub>PO12<\/sub>\u4e2d\u4e00\u79cd\u672a\u66fe\u62a5\u9053\u7684Na5\u4f4d\u7f6e\uff08\u56fe16\uff09[8]<\/sup>\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5728\u8be5\u7ed3\u6784\u4e2dNa+<\/sup>\u79bb\u5b50\u66f4\u503e\u5411\u4e8e\u4ee5\u591a\u79bb\u5b50\u534f\u540c\u7684\u65b9\u5f0f\u8fdb\u884c\u8fc1\u79fb\u3002\u56e0\u4e3a\u76f8\u6bd4\u4e8e\u5355\u79bb\u5b50\u8fc1\u79fb\uff0c\u591a\u79bb\u5b50\u534f\u540c\u8fc1\u79fb\u7684\u80fd\u5792\u66f4\u5c0f\uff08\u56fe17\uff09\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u4e5f\u91c7\u7528\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86\u8fd9\u79cdNaSICON\u6750\u6599\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u7684\u539f\u56e0\uff1a\u968f\u7740\u4f53\u7cfbNa+<\/sup>\u6d53\u5ea6\u7684\u589e\u52a0\uff0c\u5e93\u4f26\u65a5\u529b\u5f15\u8d77\u7684\u534f\u540c\u8fc1\u79fb\u6548\u5e94\u589e\u5f3a\u3002\u9274\u4e8e\u6b64\uff0c\u4f5c\u8005\u5236\u5907\u51fa\u4e86\u4e0d\u540cNa+<\/sup>\u6d53\u5ea6\u7684NaSICON\u6750\u6599\u5e76\u91c7\u7528\u963b\u6297\u5bf9\u5176\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u968f\u7740Na+<\/sup>\u6d53\u5ea6\u75313.0\u589e\u52a0\u52303.30-3.55 mol formula unit-1<\/sup>\uff0c\u6750\u6599\u7684\u4f53\u76f8\u548c\u603b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u90fd\u5f97\u5230\u4e86\u663e\u8457\u589e\u5f3a\uff0c\u5206\u522b\u8fbe\u5230\u4e864.0 mS cm–<\/sup>1<\/sup>\u548c2.4 mS cm–<\/sup>1<\/sup>\uff0825\u2103\uff09\u3002\u8fd9\u4e2a\u7814\u7a76\u4e5f\u8bc1\u660e\u5c06\u9633\u79bb\u5b50\u63a8\u5230\u9ad8\u80fd\u4f4d\u70b9\u4ece\u800c\u964d\u4f4e\u8fc1\u79fb\u80fd\u5792\u4ee5\u589e\u5f3a\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u65b9\u6cd5\u662f\u53ef\u884c\u7684\u3002<\/p>\n

\u56fe1<\/b><\/strong>6 <\/b><\/strong>AIMD\u548cMEM\u8ba1\u7b97\u5f97\u5230\u7684\u5355\u659c\u548c\u83f1\u65b9\u76f8<\/b><\/strong>Na<\/b><\/strong>3<\/b><\/sub><\/strong>Zr<\/b><\/strong>2<\/b><\/sub><\/strong>Si<\/b><\/strong>2<\/b><\/sub><\/strong>PO<\/b><\/strong>12<\/b><\/sub><\/strong>\u4e2dNa<\/b><\/strong>+<\/b><\/sup><\/strong>\u6269\u6563\u8def\u5f84<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>7<\/b><\/strong>\u5355\u659c\u76f8<\/b><\/strong>Na<\/b><\/strong>3<\/b><\/sub><\/strong>Zr<\/b><\/strong>2<\/b><\/sub><\/strong>Si<\/b><\/strong>2<\/b><\/sub><\/strong>PO<\/b><\/strong>12<\/b><\/sub><\/strong>\u4e2d\u5355\u79bb\u5b50\u8fc1\u79fb\u80fd\u5792\u548c\u591a\u79bb\u5b50\u534f\u540c\u8fc1\u79fb\u80fd\u5792\u7684\u6bd4\u8f83<\/b><\/strong><\/p>\n

\"\"<\/p>\n

ACS Energy Letters<\/b><\/strong>\uff1a\u65b0\u578b\u9ad8\u7535\u538b\u5364\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28<\/b><\/strong>Li<\/b><\/strong>3<\/b><\/sub><\/strong>–<\/b><\/sub><\/strong>x<\/b><\/sub><\/strong>M<\/b><\/strong>1<\/b><\/sub><\/strong>–<\/b><\/sub><\/strong>x<\/b><\/sub><\/strong>Zr<\/b><\/strong>x<\/b><\/sub><\/strong>Cl<\/b><\/strong>6<\/b><\/sub><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\uff08ASSBs\uff09\u662f\u975e\u5e38\u6709\u6f5c\u529b\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u5668\u4ef6\uff0c\u800c\u56fa\u6001\u7535\u89e3\u8d28\u5219\u662f\u5176\u5173\u952e\u7ec4\u4efd\u3002\u57fa\u4e8e\u786b\u4ee3\u78f7\u9178\u76d0\u7684\u56fa\u6001\u7535\u89e3\u8d28\u56e0\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u4f46\u662f\u8fd9\u4e9b\u7535\u89e3\u8d28\u7684\u9633\u6781\u7a33\u5b9a\u6027\u5f88\u5dee\u800c\u4e14\u9700\u8981\u5bf9\u91d1\u5c5e\u9502\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u8fdb\u884c\u7279\u6b8a\u7684\u5305\u8986\u3002\u6b64\u5916\uff0c\u786b\u4ee3\u78f7\u9178\u76d0\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u8f83\u7a84\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u4e5f\u9650\u5236\u4e86\u56fa\u6001\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u63d0\u9ad8\u3002\u5728\u6b64\uff0c\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66\u7684<\/b><\/strong>Linda F. Nazar<\/b><\/strong>\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u6df7\u5408\u91d1\u5c5e\u5364\u5316\u7269\u00a0Li3-x<\/sub>M1-x<\/sub>Zrx<\/sub>Cl6<\/sub>(M = Y, Er)\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u5b83\u6709\u7740\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\uff081.4 mS cm-1<\/sup>\uff09\u800c\u4e14\u5728\u5f88\u9ad8\u7684\u7535\u538b\u4e0b\u4e5f\u80fd\u4fdd\u6301\u7a33\u5b9a[9]<\/sup>\u3002Zr\u66ff\u4ee3M(M = Y, Er)\u4f1a\u4fc3\u4f7f\u6750\u6599\u7531\u4e09\u659c\u76f8\u8f6c\u53d8\u4e3a\u6b63\u4ea4\u76f8\uff0c\u4e2d\u5b50\u884d\u5c04\u548c\u5355\u6676XRD\u5206\u6790\u63ed\u793a\u4e86\u8fd9\u79cd\u65b0\u7684\u7ed3\u6784\uff08\u56fe18\uff09\u3002\u7531\u4e8e\u8fd9\u7c7b\u5364\u5316\u7269\u5177\u6709\u9ad8\u7684\u7535\u5316\u5b66\u6c27\u5316\u7a33\u5b9a\u6027\uff0c\u56fa\u6001\u7535\u6c60\u53ef\u4ee5\u76f4\u63a5\u4f7f\u7528>4 V\u7684\u6b63\u6781\u6750\u6599\u800c\u65e0\u9700\u4efb\u4f55\u4fdd\u62a4\u6027\u7684\u5305\u8986\u63aa\u65bd\u3002\u91c7\u7528Li3-x<\/sub>M1-x<\/sub>Zrx<\/sub>Cl6<\/sub>\u4f5c\u4e3a\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u7535\u6c60\u5373\u65f6\u5728\u5145\u7535\u7535\u538b\u9ad8\u8fbe4.5 V\u4e0b\u8868\u73b0\u4e5f\u51fa\u4e86\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe19\uff09\u3002<\/p>\n

\u56fe1<\/b><\/strong>8 Li<\/b><\/strong>2.5<\/b><\/sub><\/strong>Er<\/b><\/strong>0.5<\/b><\/sub><\/strong>Zr<\/b><\/strong>0.5<\/b><\/sub><\/strong>Cl<\/b><\/strong>6<\/b><\/sub><\/strong>\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1<\/b><\/strong>9<\/b><\/strong>\u91c7\u7528<\/b><\/strong>\u00a0Li<\/b><\/strong>2.5<\/b><\/sub><\/strong>Er<\/b><\/strong>0.5<\/b><\/sub><\/strong>Zr<\/b><\/strong>0.5<\/b><\/sub><\/strong>Cl<\/b><\/strong>6<\/b><\/sub><\/strong>\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

[1] G. Li, F. Lu, X. Dou, X. Wang, D. Luo, H. Sun, A. Yu, Z. Chen, Polysulfide Regulation by the Zwitterionic Barrier toward Durable Lithium-Sulfur Batteries, J. Am. Chem. Soc., (2020).<\/p>\n

[2] Z. Ma, S. Li, L. Wu, L. Song, G. Jiang, Z. Liang, D. Su, Y. Zhu, R.R. Adzic, J.X. Wang, Z. Chen, NbOx<\/sub>\u00a0nano-nail with a Pt head embedded in carbon as a highly active and durable oxygen reduction catalyst, Nano Energy, 69 (2020) 104455.<\/p>\n

[3] H. Huo, Y. Chen, R. Li, N. Zhao, J. Luo, J.G. Pereira da Silva, R. M\u00fccke, P. Kaghazchi, X. Guo, X. Sun, Design of a mixed conductive garnet\/Li interface for dendrite-free solid lithium metal batteries, Energy Environ. Sci., 13 (2020) 127-134.<\/p>\n

[4] S. Deng, X. Li, Z. Ren, W. Li, J. Luo, J. Liang, J. Liang, M.N. Banis, M. Li, Y. Zhao, X. Li, C. Wang, Y. Sun, Q. Sun, R. Li, Y. Hu, H. Huang, L. Zhang, S. Lu, J. Luo, X. Sun, Dual-functional interfaces for highly stable Ni-rich layered cathodes in sulfide all-solid-state batteries, Energy Storage Mater., 27 (2020) 117-123.<\/p>\n

[5] M. Liu, Y. Wang, X. Kong, L. Tan, L. Li, S. Cheng, G. Botton, H. Guo, Z. Mi, C.J. Li, Efficient Nitrogen Fixation Catalyzed by Gallium Nitride Nanowire Using Nitrogen and Water, iScience, 17 (2019) 208-216.<\/p>\n

[6] N. Zhang, N. Zaker, H. Li, A. Liu, J. Inglis, L. Jing, J. Li, Y. Li, G.A. Botton, J.R. Dahn, Cobalt-Free Nickel-Rich Positive Electrode Materials with a Core\u2013Shell Structure, Chem. Mater., 31 (2019) 10150-10160.<\/p>\n

[7] Y. Liu, J. Harlow, J. Dahn, Microstructural Observations of \u201cSingle Crystal\u201d Positive Electrode Materials Before and After Long Term Cycling by Cross-section Scanning Electron Microscopy, J. Electrochem. Soc., 167 (2020) 020512.<\/p>\n

[8] Z. Zhang, Z. Zou, K. Kaup, R. Xiao, S. Shi, M. Avdeev, Y.S. Hu, D. Wang, B. He, H. Li, X. Huang, L.F. Nazar, L. Chen, Correlated Migration Invokes Higher Na+<\/sup>\u2010Ion Conductivity in NaSICON\u2010Type Solid Electrolytes, Adv. Energy Mater., 9 (2019) 1902373.<\/p>\n

[9] K.-H. Park, K. Kaup, A. Assoud, Q. Zhang, X. Wu, L.F. Nazar, High-Voltage Superionic Halide Solid Electrolytes for All-Solid-State Li-Ion Batteries, ACS Energy Lett., (2020) 533-539.<\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08\u4f9b\u7a3f\u3002<\/p>\n

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