{"id":196994,"date":"2020-03-14T06:19:58","date_gmt":"2020-03-13T22:19:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=196994"},"modified":"2020-03-13T19:20:12","modified_gmt":"2020-03-13T11:20:12","slug":"%e6%98%a5%e8%8a%82%e5%9c%a8%e5%ae%b6%e9%98%b2%e7%96%ab%e6%9c%9f%e9%97%b4%ef%bc%8c%e4%bd%a0%e9%94%99%e8%bf%87%e4%ba%86%e5%93%aa%e4%ba%9b%e7%b2%be%e5%bd%a9%ef%bc%9fnature%e3%80%81nat-energy%e3%80%81nat","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=196994","title":{"rendered":"\u6625\u8282\u5728\u5bb6\u9632\u75ab\u671f\u95f4\uff0c\u4f60\u9519\u8fc7\u4e86\u54ea\u4e9b\u7cbe\u5f69\uff1fNature\u3001Nat. Energy\u3001Nat. Commun.\u3001JACS\u3001Angew\u3001AM\u7b49\u9876\u520a\u9499\u949b\u77ff\u6587\u7ae0\u5927\u5408\u96c6\uff01"},"content":{"rendered":"

\u4e00\u3001\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u80cc\u666f\u4ecb\u7ecd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u4e8c\u3001Nature\u3001<\/b><\/strong>Nat. Energy<\/b><\/strong>\u7b49\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u8fdb\u5c55<\/b><\/strong><\/p>\n

1\u3001Nature: \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u4e0a\u94c5<\/b><\/strong>\u7684<\/b><\/strong>\u9694\u79bb<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u7f8e\u56fd<\/b><\/strong>\u56fd\u5bb6\u53ef\u518d\u751f\u80fd\u6e90\u5b9e\u9a8c\u5ba4<\/b><\/strong>\u7684\u6731\u51ef\u6559\u6388\u548c\u5317\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66Tao Xu\u6559\u6388\u56e2\u961f<\/b><\/strong>\u5c06\u900f\u660e\u7684\u5438\u6536Pb\u7684DMDP\u819c\u6c89\u79ef\u5728\u73bb\u7483\u4e0a\u3002DMDP\u819c\u4e0d\u6eb6\u4e8e\u6c34\uff0c\u4f46\u5177\u6709\u826f\u597d\u7684\u900f\u6c34\u6027\u3002\u8fd9\u6837\uff0c\u5f53\u6c34\u6e17\u5165\u8bbe\u5907\u65f6\uff0c\u529f\u80fd\u6027\u81a6\u9178\u57fa\u56e2\u53ef\u4ee5\u6709\u6548\u5438\u6536\u6c34\u4e2d\u7684Pb2+<\/sup>\u3002\u7814\u7a76\u4eba\u5458\u5728\u80cc\u9762\u4f7f\u7528\u4e86\u9884\u5e72\u71e5\u819c\uff0c\u5176\u4e2d\u5305\u542b\u5f3a\u5546\u54c1Pb-\u87af\u5408\u5242EDTMP\u63ba\u5165\u4e3b\u4f53\u805a\u5408\u7269\u57fa\u8d28\u4e2d\uff0c\u4ee5\u786e\u4fdd\u5355\u72ec\u4f7f\u7528\u87af\u5408\u5242\u6216\u5f62\u6210\u7684Pb\u87af\u5408\u590d\u5408\u7269\u4e0d\u80fd\u7528\u6c34\u51b2\u6d17\u3002\u7814\u7a76\u4eba\u5458\u7814\u7a76\u4e86\u5728\u7ea650\u00b0C\u7684\u7a7a\u6c14\u4e2d\u6a21\u62df\u76841\u9633\u5149\u7167\u5c04\u5f3a\u5ea6\u4e0b\uff0c\u8fd9\u4e9b\u8bbe\u5907\u5728\u8fde\u7eed\u64cd\u4f5c\u4e0b\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002\u8fde\u7eed\u8fd0\u884c\u7ea6500\u5c0f\u65f6\u540e\u672a\u89c2\u5bdf\u5230\u8bbe\u5907\u6027\u80fd\u7684\u5dee\u5f02\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u4f7f\u7528Pb\u5438\u6536\u5c42\uff08\u5c24\u5176\u662fDMDP\u819c\uff0c\u5b83\u5728\u76f4\u63a5\u5149\u8def\u4e2d\u5165\u5c04\u5149\u5f3a\u5ea6\uff09\u4e0d\u4f1a\u5bf9\u8bbe\u5907\u6027\u80fd\u548c\u957f\u671f\u8fd0\u884c\u7a33\u5b9a\u6027\u4ea7\u751f\u8d1f\u9762\u5f71\u54cd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41586-020-2001-x<\/p>\n

2\u3001Nat. Energy: 23%\u8bb0\u5f55\u6548\u7387\uff01<\/b><\/strong>\u914d\u4f53\u951a\u5b9a<\/b><\/strong>\u5236\u5907\u9ad8\u6548\u5012\u7f6e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66Osman M. Bakr\u6559\u6388\u548c\u591a\u4f26\u591a\u5927\u5b66Edward H. Sargent \u6559\u6388\u56e2\u961f<\/b><\/strong>\u62a5\u9053\u4e86AALs\uff0c\u7279\u522b\u662f\u957f\u70f7\u57fa\u94feAALs\u5728\u901a\u8fc7\u4fc3\u8fdb\u6709\u5229\u7684\u6676\u7c92\u53d6\u5411\u548c\u6291\u5236\u9677\u9631\u80fd\u7ea7\u5bc6\u5ea6\u6765\u6539\u5584\u5149\u7535\u6027\u80fd\u65b9\u9762\u7684\u4f5c\u7528\u3002\u7814\u7a76\u4eba\u5458\u4f7f\u7528\u57fa\u4e8e\u957f\u70f7\u57fa\u94feAALs\u7684\u7b56\u7565\u5f97\u5230\u5177\u670923.0\uff05\u7684\u6548\u7387\uff08\u7ecf\u8ba4\u8bc1\u768422.3\uff05\uff09\u548c\u826f\u597d\u7684\u64cd\u4f5c\u7a33\u5b9a\u6027\u7684p\u2013i\u2013n\u7ed3\u6784\u7684\u8bbe\u5907\u3002\u9499\u949b\u77ff\u6676\u7c92\u548c\u754c\u9762\u7684\u5206\u5b50\u4fee\u9970\u5bf9\u4e8e\u63d0\u9ad8PSC\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\u81f3\u5173\u91cd\u8981\u3002\u7814\u7a76\u7ed3\u679c\u8fd8\u8868\u660e\uff0c\u9499\u949b\u77ff\u6676\u9762\u7684\u5404\u5411\u5f02\u6027\u7535\u5b50\u7279\u6027\u4f7f\u8584\u819c\u7684\u6676\u4f53\u53d6\u5411\u7ba1\u7406\u6210\u4e3a\u5b9e\u73b0\u9ad8\u6548PSC\u7684\u91cd\u8981\u9014\u5f84\u3002\u8fdb\u4e00\u6b65\u4e86\u89e3\u591a\u6676\u9499\u949b\u77ff\u4e2d\u4e0d\u540c\u8868\u9762\u523b\u9762\u7684\u6027\u8d28\uff08\u5305\u62ec\u7f3a\u9677\u7c7b\u578b\u548c\u6d53\u5ea6\uff09\u53ef\u80fd\u5bf9\u9499\u949b\u77ff\u8bbe\u5907\u7684\u53d1\u5c55\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41560-019-0538-4<\/p>\n

3\u3001Nat. Commun.\uff1a\u5b9a\u5411\u5c42\u72b6\u6742\u5316\u9499\u949b\u77ff\u57283D\u9499\u949b\u77ff\u4e0a\u7684\u6a21\u677f\u5316\u751f\u957f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41467-019-13856-1<\/p>\n

4<\/b><\/strong>\u3001<\/b><\/strong>JACS<\/b><\/strong>\uff1a<\/b><\/strong>CdI<\/b><\/strong>2<\/b><\/sub><\/strong>\u964d\u4f4e\u8868\u9762\u7f3a\u9677\uff0c1.2 V&21.9\uff05\u6548\u7387\u7684\u522e\u6d82\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/jacs.9b13418<\/p>\n

5<\/b><\/strong>\u3001<\/b><\/strong>A<\/b><\/strong>ngew\uff1a<\/b><\/strong>CsPbBr<\/b><\/strong>3<\/b><\/sub><\/strong>\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9ad8\u8fbe10.85\uff05\u6548\u7387<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/anie.202000199<\/p>\n

6\u3001<\/b><\/strong>A<\/b><\/strong>ngew\uff1a<\/b><\/strong>6.43\uff05\u6548\u7387\uff01DJ\u578b\u4e8c\u7ef4\u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/anie.202000460<\/p>\n

7<\/b><\/strong>\u3001<\/b><\/strong>AM<\/b><\/strong>\uff1a\u7a33\u5b9a\u9ad8\u6548\u7684\u65e0\u7532\u94f5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

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\u745e\u58eb\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662Yi Zhang<\/b><\/strong>\u3001Mohammad Khaja Nazeeruddin<\/b><\/strong>\u548c\u5929\u6d25\u5927\u5b66\u51af\u4e9a\u9752\u6559\u6388<\/b><\/strong>\u5728\u9499\u949b\u77ff\u53cc\u9633\u79bb\u5b50\uff08Cs\uff0cFA\uff09\u4e2d\u4f7f\u7528\u6c2f\u5316\u94ef\uff08CsCl\uff09\u548c\u6eb4\u5316\u94c5\uff08PbBr2<\/sub>\uff09\u53ef\u4ee5\u663e\u7740\u7a33\u5b9aFAPbI3<\/sub>\u7684\u9ed1\u76f8\uff08\u03b1\u76f8\uff09\uff0c\u5e76\u589e\u5f3aFAPbI3<\/sub>\u7684\u7a33\u5b9a\u6027\u548c\u6027\u80fd\u3002\u8003\u8651\u5230\u6eb4\u5316\u7269\uff08Br–<\/sup>\uff09\u7684\u5e26\u9699\u4e0d\u7406\u60f3\uff0c\u7814\u7a76\u4eba\u5458\u8c03\u8282\u4e86\u6eb4\u5316\u7269\uff08Br–<\/sup>\uff09\u7684\u91cf\uff0c\u5bfc\u81f4\u540c\u65f6\u5177\u6709\u6700\u4f73\u6c2f\u5316\u94ef\uff08CsCl\uff09\u548c\u6eb4\u5316\u94c5\uff08PbBr2<\/sub>\uff09\u7684\u9ad8\u7ed3\u6676\u5ea6\u548c\u5927\u6676\u7c92\u5c3a\u5bf8\u7684\u9499\u949b\u77ff\u3002\u7ed3\u679c\uff0c\u5177\u6709\u6700\u4f73\u6761\u4ef6\u7684\u65e0MA\u7684PSC\u8868\u73b0\u51fa20.50\uff05\u7684\u6700\u4f73PCE\u3002\u9664\u4e86\u5668\u4ef6\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u957f\u671f\u7a33\u5b9a\u6027\u5916\uff0c\u6027\u80fd\u4e5f\u5f97\u5230\u4e86\u6539\u5584\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u6c2f\u5316\u94ef\uff08CsCl\uff09\u548c\u6eb4\u5316\u94c5\uff08PbBr2<\/sub>\uff09\u53ef\u4ee5\u6709\u6548\u5730\u9650\u5236\u4e0d\u826f\u7684\u76f8\u53d8\uff0c\u4ece\u800c\u663e\u7740\u589e\u5f3a\u53cc\u9633\u79bb\u5b50\uff08Cs\uff0cFA\uff09\u88c5\u7f6e\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/adma.201905502<\/p>\n

8<\/b><\/strong>\u3001<\/b><\/strong>AM<\/b><\/strong>\uff1a\u901a\u8fc7\u8986\u76d6\u8d85\u85842D\u5c42<\/b><\/strong>\u63d0\u9ad8<\/b><\/strong>\u9521\u94c5\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n

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\u5357\u4eac\u5927\u5b66\u8c2d\u6d77\u4ec1\u6559\u6388\u548c\u591a\u4f26\u591a\u5927\u5b66Edward H. Sargent\u6559\u6388<\/b><\/strong>\u91c7\u7528\u6709\u673a\u9633\u79bb\u5b50\u82ef\u4e59\u94f5\uff08PEA\uff09\u6765\u951a\u5b9aSn-Pb\u9499\u949b\u77ff\u9897\u7c92\u3002\u901a\u8fc7\u5c06PEA\u9633\u79bb\u5b50\u76f4\u63a5\u5f15\u5165\u6297\u6eb6\u5242\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5728\u9499\u949b\u77ff\u8584\u819c\u8868\u9762\u4ee5\u53ca\u8584\u819c\u5185\u7684\u6676\u754c\u5904\u5747\u5b9e\u73b0\u4e86\u539f\u4f4d\u7f3a\u9677\u949d\u5316\u3002\u540c\u65f6\u4e5f\u907f\u514d\u4e86\u9499\u949b\u77ff\u5c42\u72b6\u76f8\u7684\u8fc7\u91cf\u5f62\u6210\u3002\u4f7f\u7528\u8fd9\u79cd\u65b9\u6cd5\uff0c\u4e0e\u672a\u949d\u5316\u7684Sn-Pb PSC\u5728\u5b8c\u5168AM1.5G\u5149\u7167\u4e0b\u76f8\u6bd4\uff0c\u8be5\u8bbe\u5907\u4f7f\u7528\u5bff\u547d\u5ef6\u957f\u4e86200\u500d\uff0c\u800c\u5728\u7ecf\u8fc7\u8fc7\u6ee4\u7684AM1.5G\u5149\u7167\u4e0b\u663c\u591c\u8bbe\u5907\u8fd0\u884c200\u5c0f\u65f6\u540e\uff0c\u6548\u7387\u6ca1\u6709\u4e0b\u964d\u3002\u586b\u5145\u56e0\u5b50\u9ad8\u8fbe79\uff05\uff0c\u5b9e\u9a8c\u5ba4\u6d4b\u91cf\u7684PCE\u4e3a19.4\uff05\uff08\u8ba4\u8bc1\u768418.95\uff05\uff09\u3002\u7136\u540e\uff0c\u79d1\u7814\u4eba\u5458\u5236\u5907\u4e86\u91c7\u7528PEA\u951a\u5b9a\u7684Sn-Pb PSC\u4f5c\u4e3a\u5e95\u7535\u6c60\u7684\u9ad8\u6548\u4e24\u7aef\u5b50\u5168\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u3002\u5bf9\u4e8e\u4e32\u8054\u7535\u6c60\uff0c\u83b7\u5f97\u4e8623.5\uff05\u7684\u7a33\u5b9aPCE\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/adma.201907058<\/p>\n

9<\/b><\/strong>\u3001<\/b><\/strong>AM<\/b><\/strong>\uff1a<\/b><\/strong>23.5\uff05\u6548\u7387\uff01\u4e24\u6027\u5206\u5b50\u949d\u5316\u7528\u4e8e\u5236\u5907\u9ad8\u6548\u7a33\u5b9a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/adma.201907757<\/p>\n

10<\/b><\/strong>\u3001<\/b><\/strong>AM<\/b><\/strong>\uff1a\u4e00\u79cd\u65e0\u6bd2\u7684\u53cc\u529f\u80fd\u6297\u6eb6\u5242<\/b><\/strong>\u7528\u4e8e\u5236\u5907<\/b><\/strong>\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201907123<\/p>\n

\u672c\u6587\u7531eric\u4f9b\u7a3f\u3002<\/p>\n

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