{"id":198073,"date":"2020-03-13T08:03:10","date_gmt":"2020-03-13T00:03:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=198073"},"modified":"2020-03-13T08:03:10","modified_gmt":"2020-03-13T00:03:10","slug":"%e4%b8%8d%e5%af%b9%e7%a7%b0%e5%82%ac%e5%8c%96%e6%9c%80%e6%96%b0science%ef%bc%9a%e6%89%8b%e6%80%a7%e9%98%b3%e7%a6%bb%e5%ad%90%e5%af%b9%e6%98%a0%e9%80%89%e6%8b%a9%e6%80%a7%e8%bf%9c%e7%ab%afc-h%e6%b4%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=198073","title":{"rendered":"\u4e0d\u5bf9\u79f0\u50ac\u5316\u6700\u65b0Science\uff1a\u624b\u6027\u9633\u79bb\u5b50\u5bf9\u6620\u9009\u62e9\u6027\u8fdc\u7aefC-H\u6d3b\u5316"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u79bb\u5b50\u5bf9\u4f5c\u4e3a\u4e0d\u5bf9\u79f0\u50ac\u5316\u9886\u57df\u7684\u5173\u952e\u8bbe\u8ba1\u7279\u5f81\uff0c\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u57281980\u5e74\u4ee3\uff0c\u5bf9\u6620\u4f53\u9009\u62e9\u6027\u76f8\u8f6c\u79fb\u50ac\u5316\u7684\u5f00\u521b\u6027\u7814\u7a76\u5c06\u624b\u6027\u9633\u79bb\u5b50\u4e0e\u53cd\u5e94\u6027\u9634\u79bb\u5b50\u4e2d\u95f4\u4f53\u914d\u5bf9\uff0c\u5f62\u6210\u5bf9\u6620\u4f53\u6d4b\u5b9a\u8fc7\u6e21\u6001\u3002\u5728\u8fc7\u53bb\u7684\u5341\u5e74\u4e2d\uff0c\u5229\u7528\u624b\u6027\u9634\u79bb\u5b50\u4e0e\u9633\u79bb\u5b50\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u53cd\u5411\u53cd\u5e94\u7b56\u7565\u4e5f\u88ab\u8bc1\u660e\u662f\u975e\u5e38\u6210\u529f\u7684\u3002\u540e\u4e00\u79cd\u7b56\u7565\u4e0d\u4ec5\u5728\u6709\u673a\u50ac\u5316\u73af\u5883\u4e2d\u6709\u6548\uff0c\u800c\u4e14\u5728\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5f3a\u529b\u7ed3\u5408\u4e2d\u4e5f\u6709\u6548\uff0c\u5de7\u5999\u5730\u5229\u7528\u4e86\u50ac\u5316\u5faa\u73af\u4e2d\u76f8\u5bf9\u5e38\u89c1\u7684\u9633\u79bb\u5b50\u8fc7\u6e21\u91d1\u5c5e\u7edc\u5408\u7269\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u9634\u79bb\u5b50\u8fc7\u6e21\u91d1\u5c5e\u7edc\u5408\u7269\u4f5c\u4e3a\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u60c5\u51b5\u5c31\u5c11\u89c1\u5f97\u591a\u3002\u56e0\u6b64\uff0c\u5c06\u624b\u6027\u9633\u79bb\u5b50\u4e0e\u9634\u79bb\u5b50\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u914d\u5bf9\u7684\u7535\u8377\u53cd\u8f6c\u65b9\u6cd5\u4ec5\u5728\u5c11\u6570\u5f00\u521b\u6027\u6848\u4f8b\u4e2d\u5f97\u5230\u8bc1\u5b9e\uff0c\u7279\u522b\u662f\u6d89\u53ca\u9634\u79bb\u5b50\u4e8c\u81a6\u5f02\u8fc7\u6c27\u94a8\u9178\u76d0\u548c\u8fc7\u6c27\u94bc\u9178\u76d0\u7edc\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u4e0d\u5bf9\u79f0\u6c27\u5316\u53cd\u5e94\u3002\u7531\u4e8e\u9634\u79bb\u5b50\u91d1\u5c5e\u7edc\u5408\u7269\u5728\u5927\u591a\u6570\u5e38\u7528\u7684\u5408\u6210\u65b9\u6cd5\u4e2d\u90fd\u5f88\u5c11\u89c1\uff0c\u6240\u4ee5\u5c3d\u7ba1\u4e00\u4e9b\u624b\u6027\u9633\u79bb\u5b50\u5177\u6709\u660e\u663e\u7684\u4f18\u52bf\uff0c\u4f46\u624b\u6027\u9633\u79bb\u5b50\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u901a\u7528\u53cd\u5e94\u6027\u7ed3\u5408\u7684\u66f4\u5e7f\u6cdb\u7684\u6f5c\u529b\u4ecd\u672a\u5f97\u5230\u5145\u5206\u7684\u5f00\u53d1\u3002\u9274\u4e8e\u8fd9\u4e9b\u57fa\u5e8f\u5728\u4e0d\u5bf9\u79f0\u6709\u673a\u50ac\u5316\u4e2d\u7684\u6210\u529f\u5e94\u7528\uff0c\u5c06\u5176\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u76f8\u7ed3\u5408\u7684\u603b\u4f53\u7b56\u7565\u5c06\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u9886\u57df\u4ea7\u751f\u5e7f\u6cdb\u7684\u5f71\u54cd\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u4eca\u65e5\uff0c\u5728<strong><b>\u82f1\u56fd\u5251\u6865\u5927\u5b66Robert J. Phipps\u7814\u7a76\u5458<\/b><\/strong><strong><b>\u56e2\u961f\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u62a5\u544a\u4e00\u79cd\u7b56\u7565\uff0c\u4f7f\u4e00\u4e2a\u5e38\u89c1\u7684\u8054\u5421\u5576\u914d\u4f53\u9634\u79bb\u5b50\u5316\uff0c\u5e76\u5c06\u5176\u94f1\u914d\u5408\u7269\u4e0e\u884d\u751f\u81ea\u594e\u5b81\u7684\u624b\u6027\u9633\u79bb\u5b50\u914d\u5bf9\u3002\u56e2\u961f\u5df2\u7ecf\u5c06\u8fd9\u4e9b\u79bb\u5b50\u914d\u5bf9\u7684\u590d\u5408\u7269\u5e94\u7528\u4e8e\u78b3\u6216\u78f7\u4e2d\u5fc3\u7684\u4e8c\u82b3\u57fa\u57fa\u5e8f\u7684\u53bb\u5bf9\u79f0\u5316\uff0c\u901a\u8fc7\u5bf9\u6620\u9009\u62e9\u6027\u7684C-H\u787c\u5316\u6765\u5b9e\u73b0\u957f\u7a0b\u7684\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u3002\u539f\u5219\u4e0a\uff0c\u8bb8\u591a\u5e38\u89c1\u7c7b\u578b\u7684\u914d\u4f53\u4e5f\u53ef\u4ee5\u91c7\u7528\u8fd9\u79cd\u65b9\u6cd5\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a<strong><b>\u201c<\/b><\/strong><strong><b>Enantioselective remote C\u2013H activation directed by a chiral cation<\/b><\/strong><strong><b>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86<strong><b>Science<\/b><\/strong>\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u5c06\u624b\u6027\u9633\u79bb\u5b50\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u7ed3\u5408\u7684\u7b56\u7565<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198074\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F1.large_-1.jpg\" alt=\"\" width=\"600\" height=\"757\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F1.large_-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F1.large_-1-238x300.jpg 238w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2 \u5bf9\u6620\u9009\u62e9\u6027\u53bb\u5bf9\u79f0\u5316\u82ef\u7532\u57fa\u9170\u80fa\u7684C-H\u787c\u6c22\u5316\u53cd\u5e94<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198075\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F2.large_-1.jpg\" alt=\"\" width=\"600\" height=\"710\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F2.large_-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F2.large_-1-254x300.jpg 254w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3 <\/b><\/strong><strong><b>\u4e8c\u82b3\u57fa\u6b21\u81a6\u9170\u80fa\u7684\u5bf9\u6620\u9009\u62e9\u6027C<\/b><\/strong><strong><b>&#8211;<\/b><\/strong><strong><b>H<\/b><\/strong><strong><b>\u787c\u6c22\u5316\u53cd\u5e94<\/b><\/strong><strong><b>\u7684\u5e95\u7269\u8303\u56f4<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198076\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F3.large_-1.jpg\" alt=\"\" width=\"600\" height=\"808\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F3.large_-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F3.large_-1-223x300.jpg 223w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4 <\/b><\/strong><strong><b>\u4ea7\u54c1\u7684<\/b><\/strong><strong><b>\u5236\u5907<\/b><\/strong><strong><b>\u548c\u8fdb\u4e00\u6b65\u7684\u5b9e\u9a8c<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198077\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F4.large_-1.jpg\" alt=\"\" width=\"600\" height=\"373\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F4.large_-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/03\/F4.large_-1-300x187.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><a href=\"https:\/\/science.sciencemag.org\/content\/367\/6483\/1246\"><u>Enantioselective remote C\u2013H activation directed by a chiral cation<\/u><\/a>\uff08Science\uff0c2020\uff0cDOI:10.1126\/science.aba1120\uff09<\/p>\n<p>\u672c\u6587\u7531<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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