{"id":198417,"date":"2020-04-06T06:35:32","date_gmt":"2020-04-05T22:35:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=198417"},"modified":"2020-04-05T18:56:31","modified_gmt":"2020-04-05T10:56:31","slug":"%e6%be%b3%e6%b4%b2%e6%9d%90%e6%96%99%e5%a4%a7%e7%89%9b%e7%aa%a6%e5%a3%ab%e5%ad%a6%e3%80%81%e4%b9%94%e4%b8%96%e7%92%8b%e3%80%81%e6%b1%aa%e5%9b%bd%e7%a7%80%e3%80%81%e9%83%ad%e5%86%8d%e8%90%8d%e5%92%8cdm","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=198417","title":{"rendered":"\u6fb3\u6d32\u6750\u6599\u5927\u725b\u7aa6\u58eb\u5b66\u3001\u4e54\u4e16\u748b\u3001\u6c6a\u56fd\u79c0\u3001\u90ed\u518d\u840d\u548cDmitri Golberg\u6700\u65b0\u6210\u679c\u68b3\u7406"},"content":{"rendered":"

\u6fb3\u5927\u5229\u4e9a\u51ed\u501f\u7740\u201c\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u201d\uff0c\u201c\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u201d\uff0c\u201c\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\u201d\uff0c\u201c\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u201d\u548c\u201c\u4f0d\u4f26\u8d21\u5927\u5b66\u201d\u7b49\u4f17\u591a\u540d\u6821\u5728\u6750\u6599\u9886\u57df\u9887\u8d1f\u76db\u540d\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u5b83\u4e5f\u662f\u8bb8\u591a\u4e2d\u56fd\u540c\u5b66\u7684\u7559\u5b66\u9996\u9009\u4e4b\u5730\u3002\u5728\u6b64\uff0c\u6211\u4eec\u68b3\u7406\u4e86\u51e0\u4f4d\u6fb3\u6d32\u6750\u6599\u9886\u57df\u8457\u540d\u5b66\u8005\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\uff0c\u5e0c\u671b\u80fd\u8ba9\u5927\u5bb6\u5bf9\u6fb3\u6d32\u6750\u6599\u9886\u57df\u7684\u7814\u7a76\u6709\u66f4\u591a\u7684\u4e86\u89e3\uff0c\u4e5f\u5e0c\u671b\u80fd\u7ed9\u5927\u5bb6\u7684\u7814\u7a76\u5e26\u6765\u542f\u53d1\u3002<\/p>\n

1<\/b><\/strong>\u00a0<\/b><\/strong>\u4f0d\u4f26\u8d21\u5927\u5b66\u7aa6\u58eb\u5b66<\/b><\/strong><\/p>\n

Energy &<\/b><\/strong>\u00a0<\/b><\/strong>Environmental<\/b><\/strong>\u00a0<\/b><\/strong>Science<\/b><\/strong>\uff1a\u7535\u50ac\u5316\u201c\u591a\u786b\u5316\u94a0\u201d\u8f6c\u5316\u53cd\u5e94\u5b9e\u73b0\u9ad8\u6027\u80fd\u5ba4\u6e29Na-S\u7535\u6c60<\/b><\/strong><\/p>\n

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\u56fe1<\/b><\/strong>\u00a0<\/b><\/strong>Na-S\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u548cCN<\/b><\/strong>\/Au\/S<\/b><\/strong>\u6b63\u6781\u7684\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>2 <\/b><\/strong>\u591a\u786b\u5316\u94a0\u5728CN\u548cCN<\/b><\/strong>\/Au<\/b><\/strong>\u8f7d\u4f53\u4e0a\u7684\u80fd\u91cf\u56fe<\/b><\/strong><\/p>\n

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2<\/b><\/strong>\u00a0<\/b><\/strong>\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b<\/b><\/strong><\/p>\n

A<\/b><\/strong>dvanced Materials<\/b><\/strong>\uff1a\u5408\u7406\u6784\u5efa\u5c16\u6676\u77f3<\/b><\/strong>Co<\/b><\/strong>2<\/b><\/sub><\/strong>VO<\/b><\/strong>4<\/b><\/sub><\/strong>\u7528\u4f5c\u9ad8\u6027\u80fdORR\u7535\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>3 Co<\/b><\/strong>2<\/b><\/sub><\/strong>VO<\/b><\/strong>4<\/b><\/sub><\/strong>\u7684\u6676\u4f53\u7ed3\u6784<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>4 Co<\/b><\/strong>2<\/b><\/sub><\/strong>VO<\/b><\/strong>4<\/b><\/sub><\/strong>\u50ac\u5316\u5242\u7684ORR\u6d3b\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>dvanced Materials<\/b><\/strong>\uff1a\u7535\u5b50\u6001\u9650\u57df\u6548\u5e94\u5b9e\u73b0\u9ad8\u7a33\u5b9a\u7684Na-S\u7535\u6c60<\/b><\/strong><\/p>\n

\u5728\u91d1\u5c5e-\u786b\u7535\u6c60\u4e2d\uff0c\u9650\u5236\u591a\u786b\u5316\u7269\u5728\u786b\u6b63\u6781\u662f\u6d88\u9664\u201c\u7a7f\u68ad\u6548\u5e94\u201d\u7684\u5173\u952e\uff0c\u8fd9\u4e5f\u662f\u5b9e\u73b0\u6b64\u7c7b\u7535\u6c60\u5927\u89c4\u6a21\u5e94\u7528\u7684\u524d\u63d0\u3002\u7136\u800c\uff0c\u4eba\u4eec\u5bf9\u4e8e\u591a\u786b\u5316\u7269\u7ea6\u675f\u4f5c\u7528\u7684\u673a\u7406\u63a2\u7d22\u53ca\u6df1\u5165\u7406\u89e3\u4ecd\u7136\u5341\u5206\u6709\u9650\u3002\u56e0\u6b64\uff0c\u5f97\u5230\u4e00\u79cd\u9ad8\u7a33\u5b9a\u7684\u91d1\u5c5e-\u786b\u7535\u6c60\u5341\u5206\u5177\u6709\u6311\u6218\u6027\u3002\u5728\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u7684\u4e54\u4e16\u748b<\/b><\/strong>\u548c\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u738b\u6d77\u8f89<\/b><\/strong>\u56e2\u961f\u57fa\u4e8e\u4e00\u79cd2D\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff082D MOF\uff09\u63d0\u51fa\u4e86\u4e00\u79cd\u5b9e\u73b0\u591a\u786b\u5316\u7269\u9650\u57df\u7684\u65b0\u673a\u7406[3]<\/sup>\u3002\u7ed3\u5408\u539f\u4f4d\u540c\u6b65\u8f90\u5c04X\u5c04\u7ebf\u884d\u5c04\u3001\u7535\u5316\u5b66\u6d4b\u8bd5\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u7814\u7a76\u8005\u4eec\u53d1\u73b02D\u00a0MOF\u4e2dNi\u4e2d\u5fc3\u7684\u7535\u5b50\u6001\u53d8\u5316\u80fd\u591f\u8c03\u8282MOF\u4e0e\u591a\u786b\u5316\u7269\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528<\/b><\/strong>\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u591a\u786b\u5316\u7269\u5f3a\u7684\u5438\u9644\u4f5c\u7528\u5e76\u4fc3\u8fdb\u5176\u5feb\u901f\u8f6c\u5316\uff08\u56fe5\uff09\u3002\u56e0\u6b64\uff0c\u8be5\u5ba4\u6e29Na-S\u7535\u6c60\u8868\u73b0\u51fa\u4e86\u8fc4\u4eca\u4e3a\u6b62\u6700\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff1a1C\u5faa\u73af1000\u6b21\u540e\u5bb9\u91cf\u4ecd\u9ad8\u8fbe347 mAh g-1<\/sup>\uff0c\u6bcf\u5708\u5bb9\u91cf\u8870\u51cf\u7387\u4ec5\u4e3a0.042%\uff08\u56fe6\uff09\u3002\u8fd9\u79cd\u65b0\u578b\u591a\u786b\u5316\u7269\u7ea6\u675f\u673a\u7406\u4e5f\u4e3a\u9ad8\u6027\u80fd\u91d1\u5c5e-\u786b\u7535\u6c60\u7684\u53d1\u5f00\u5f00\u8f9f\u4e86\u65b0\u7684\u9053\u8def\u3002<\/p>\n

\u56fe<\/b><\/strong>5 <\/b><\/strong>\u7406\u8bba\u8ba1\u7b97\u7814\u7a76<\/b><\/strong>Ni-MOF-2D<\/b><\/strong>\u5bf9\u591a\u786b\u5316\u94a0\u9650\u57df\u4f5c\u7528<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>6 S\/Ni-MOF-2D<\/b><\/strong>\u7535\u6781\u5728\u5ba4\u6e29Na-S\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

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3 <\/b><\/strong>\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u6c6a\u56fd\u79c0<\/b><\/strong><\/p>\n

C<\/b><\/strong>hem<\/b><\/strong>\uff1a\u51c6\u56fa\u6001\u53cc\u79bb\u5b50\u94a0\u91d1\u5c5e\u7535\u6c60\u7528\u4e8e\u4f4e\u6210\u672c\u50a8\u80fd<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5177\u6709\u9ad8\u7684\u5de5\u4f5c\u7535\u538b\uff08\u5927\u7ea64.4 V vs<\/i><\/em>. Na\/Na+<\/sup>\uff09\u548c\u4f4e\u7684\u7535\u6781\u6750\u6599\u6210\u672c\uff0c\u53cc\u79bb\u5b50\u201c\u94a0\u91d1\u5c5e\/\/\u77f3\u58a8\u201d\u7535\u6c60\u975e\u5e38\u6709\u6f5c\u529b\u5e94\u7528\u5728\u5927\u89c4\u6a21\u56fa\u5b9a\u5f0f\u50a8\u80fd\u9886\u57df\u3002\u7136\u800c\uff0c\u5728\u5982\u6b64\u9ad8\u7684\u7535\u538b\u4e0b\uff0c\u4f20\u7edf\u7684\u6db2\u6001\u7535\u89e3\u6db2\u4f1a\u906d\u53d7\u4e25\u91cd\u7684\u5206\u89e3\u53cd\u5e94\uff0c\u4ece\u800c\u9020\u6210\u5dee\u7684\u5faa\u73af\u5bff\u547d\u3002\u5728\u6b64\uff0c\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u7684\u6c6a\u56fd\u79c0\u3001\u5468\u680b<\/b><\/strong>\u548c\u6e05\u534e\u5927\u5b66\u7684\u674e\u5b9d\u534e<\/b><\/strong>\u56e2\u961f\u91c7\u7528\u4e00\u79cd\u591a\u529f\u80fd\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08GPE\uff09\u5236\u5907\u51fa\u4e86\u4e00\u79cd\u7a33\u5b9a\u7684\u53cc\u79bb\u5b50\u94a0\u91d1\u5c5e\u7535\u6c60\uff08\u56fe7\uff09[4]<\/sup>\u3002\u8be5\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u662f\u5229\u7528\u4e59\u6c27\u57fa\u5b63\u620a\u56db\u9187\u56db\u4e19\u70ef\u9178\u916f(EPTA)\u4f5c\u4e3a\u5355\u4f53\uff0c\u6c1f\u4ee3\u78b3\u9178\u4e59\u70ef\u916f(FEC)\u4f5c\u4e3a\u5171\u6eb6\u5242\u548c1,3-\u4e19\u70f7\u78fa\u9178\u5185\u916f(PS)\u4f5c\u4e3a\u6dfb\u52a0\u5242\u7ecf\u539f\u4f4d\u805a\u5408\u800c\u6210\u7684\u3002GPE\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e0d\u4ec5\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u6297\u6c27\u5316\u6027\u8fd8\u80fd\u591f\u5728\u7535\u6781\u8868\u9762\u6784\u5efa\u8d77\u7a33\u5b9a\u7684\u4fdd\u62a4\u5c42\u3002\u6b64\u5916\uff0c\u5b83\u8fd8\u80fd\u591f\u6709\u6548\u5730\u5747\u5316\u9634\u9633\u79bb\u5b50\u6d41\u5e76\u6291\u5236\u94a0\u679d\u6676\u7684\u751f\u957f\u3002\u56e0\u6b64\uff0c\u91c7\u7528\u8be5\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u6784\u5efa\u7684\u53cc\u79bb\u5b50\u7535\u6c60\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u5bb9\u91cf\u548c\u957f\u7684\u5faa\u73af\u5bff\u547d\uff08\u56fe8\uff09\uff0c\u5f88\u6709\u53ef\u80fd\u5e94\u7528\u5728\u4f4e\u6210\u672c\u50a8\u80fd\u9886\u57df\u3002<\/p>\n

\u56fe<\/b><\/strong>7 <\/b><\/strong>\u91c7\u7528<\/b><\/strong>NaPF<\/b><\/strong>6<\/b><\/sub><\/strong>-PC:EMC<\/b><\/strong>\u7535\u89e3\u6db2\u6216GPE\u6784\u9020\u7684\u53cc\u79bb\u5b50\u94a0\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>8 <\/b><\/strong>Na<\/b><\/strong>\/\/<\/b><\/strong>\u77f3\u58a8\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>ngewandte Chemie<\/b><\/strong>\uff1a\u5171\u6676\u6eb6\u5242\u57fa\u81ea\u6108\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u6784\u5efa\u5b89\u5168\u7a33\u5b9a\u7684\u9502\u91d1\u5c5e\u7535\u6c60<\/b><\/strong><\/p>\n

\u6e90\u4e8e\u53ef\u71c3\u6027\u6db2\u6001\u7535\u89e3\u6db2\u7684\u679d\u6676\u751f\u957f\u548c\u5b89\u5168\u95ee\u9898\u5df2\u7ecf\u4e25\u91cd\u5730\u963b\u788d\u4e86\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5e94\u7528\u3002\u5728\u6b64\uff0c\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u7684\u6c6a\u56fd\u79c0\u3001\u5468\u680b<\/b><\/strong>\u548c\u6e05\u534e\u5927\u5b66\u7684\u674e\u5b9d\u534e<\/b><\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u5171\u6676\u6eb6\u5242\uff08DES\uff09\u57fa\u81ea\u6108\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08DSP\uff09\u7684\u7a33\u5b9a\u7684\u51c6\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\uff08\u56fe9\uff09[5]<\/sup>\u3002\u8be5\u7535\u89e3\u8d28\u662f\u901a\u8fc7\u5728\u5305\u542b\u6c1f\u4ee3\u78b3\u9178\u4e59\u70ef\u916f\uff08FEC\uff09\u7684DES\u57fa\u7535\u89e3\u6db2\u4e2d\u539f\u4f4d\u805a\u54082-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)ethyl methacrylate (UPyMA)\u548cpentaerythritol tetraacrylate (PETEA)\u5355\u4f53\u5236\u5f97\u7684\u3002\u8be5\u7cbe\u5fc3\u8bbe\u8ba1\u7684DSP\u7535\u89e3\u8d28\u540c\u65f6\u62e5\u6709\u7740\u4e0d\u71c3\u6027\uff0c\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u826f\u597d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u65e0\u679d\u6676\u7684\u9502\u6c89\u79ef\u3002\u5f53\u5e94\u7528\u5728LiMn2<\/sub>O4<\/sub>\u4e3a\u6b63\u6781\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u65f6\uff0cDSP\u7535\u89e3\u6db2\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236Mn\u5728\u6b63\u6781\u7684\u6eb6\u89e3\uff0c\u4ece\u800c\u8d4b\u4e88\u201cLi|DSP\u7535\u89e3\u6db2|LMO\u201d\u7535\u6c60\u65e0\u8bba\u5728\u5ba4\u6e29\u8fd8\u662f\u5728\u9ad8\u6e29\u65f6\u90fd\u6709\u7684\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5bff\u547d\uff08\u56fe10\uff09\u3002<\/p>\n

\u56fe<\/b><\/strong>9 <\/b><\/strong>\u91c7\u7528\u5171\u6676\u6eb6\u5242\uff08DES\uff09\u57fa\u7535\u89e3\u6db2\u6216\u5171\u6676\u6eb6\u5242\u57fa\u81ea\u6108\u5408\u805a\u5408\u7269\uff08DSP\uff09\u7535\u89e3\u8d28\u6784\u9020\u7684\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>10 <\/b><\/strong>\u91c7\u7528\u51c6\u56fa\u6001\u7535\u89e3\u6db2\u6784\u5efa\u7684\u201cLi<\/b><\/strong>|DSP<\/b><\/strong>\u7535\u89e3\u6db2<\/b><\/strong>|LMO<\/b><\/strong>\u201d\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4 <\/b><\/strong>\u4f0d\u4f26\u8d21\u5927\u5b66\u90ed\u518d\u840d<\/b><\/strong><\/p>\n

A<\/b><\/strong>dvanced Materials<\/b><\/strong>\uff1a\u8026\u5408\u201c\u62d3\u6251\u7edd\u7f18\u4f53SnSb<\/b><\/strong>2<\/b><\/sub><\/strong>Te<\/b><\/strong>4<\/b><\/sub><\/strong>\u201d\u548c\u201cTe\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u201d\u7528\u4e8e\u9ad8\u500d\u7387\u80fd\u91cf\u5b58\u50a8<\/b><\/strong><\/p>\n

\u5185\u90e8\u7edd\u7f18\u3001\u754c\u9762\u5bfc\u7535\u7684\u62d3\u6251\u7edd\u7f18\u4f53\u81ea\u53d1\u73b0\u4ee5\u6765\u5f15\u8d77\u4e86\u5168\u4e16\u754c\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u4f46\u662f\u5176\u72ec\u7279\u7684\u6027\u8d28\u5374\u5f88\u5c11\u88ab\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u3002\u7136\u800c\uff0c\u50a8\u80fd\u9886\u57df\u7684\u5feb\u901f\u53d1\u5c55\u5374\u53c8\u6025\u9700\u5f00\u53d1\u51fa\u5177\u6709\u9ad8\u500d\u7387\u548c\u957f\u5faa\u73af\u6027\u80fd\u7684\u7535\u6781\u6750\u6599\u3002\u57fa\u4e8e\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\u7684\u90ed\u518d\u840d<\/b><\/strong>\u548c\u6fb3\u5927\u5229\u4e9a\u540c\u6b65\u8f90\u5c04\u5149\u6e90\u7684<\/b><\/strong>Bernt Johannessen<\/b><\/strong>\u901a\u8fc7\u5c06p\u578b\u62d3\u6251\u7edd\u7f18\u4f53SnSb2<\/sub>Te4<\/sub>\u7eb3\u7c73\u70b9\u951a\u5b9a\u5728\u5c11\u5c42\u77f3\u58a8\u70ef\u4e0a\u5236\u5907\u51fa\u4e86\u4e00\u79cdSnSb2<\/sub>Te4<\/sub>\/G\u590d\u5408\u6750\u6599\u5e76\u5c06\u5176\u7528\u4f5c\u9ad8\u500d\u7387\u548c\u7a33\u5b9a\u7684\u9502\/\u94be\u79bb\u5b50\u7535\u6c60\u8d1f\u6781[6]<\/sup>\u3002\u50a8\u9502\u6027\u80fd\u6d4b\u8bd5\u8868\u660e\uff08\u56fe11\uff09\uff0cSnSb2<\/sub>Te4<\/sub>\/G\u590d\u5408\u6750\u6599\u8868\u73b0\u51fa\u4e86\u8d85\u957f\u7684\u5faa\u73af\u5bff\u547d\uff081A\u00a0g-1<\/sup>\u5faa\u73af1000\u6b21\u540e\u5bb9\u91cf\u4ecd\u9ad8\u8fbe478 mAh g-1<\/sup>\uff09\u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0810 A\u00a0g-1<\/sup>\uff1a373 mAh g-1<\/sup>\uff09\u3002\u8fd9\u53ef\u5f52\u56e0\u4e8ePN\u5f02\u8d28\u7ed3\u8d4b\u4e88\u7684\u5feb\u901f\u79bb\u5b50\u4f20\u8f93\u80fd\u529b\uff08\u56fe12\uff09\uff0c\u62d3\u6251\u8868\u9762\u6001\u63d0\u4f9b\u7684\u7535\u5b50\u4f20\u8f93\u9ad8\u901f\u901a\u9053\u548c\u8d85\u9ad8\u7684\u8d5d\u7535\u5bb9\u8d21\u732e\u7387\u3002\u540c\u6b65\u8f90\u5c04\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u5206\u6790\u4e5f\u8bc1\u660e\u6750\u6599\u5177\u6709\u4f18\u5f02\u7684\u76f8\u53ef\u9006\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5373\u65f6\u5728\u5b9e\u9645\u5e94\u7528\u7684\u9762\u8f7d\u91cf\u4e0b\uff0810 mg cm-2<\/sup>\uff09\uff0cSnSb2<\/sub>Te4<\/sub>\/G\u4e5f\u8868\u73b0\u51fa\u4e86\u957f\u7684\u50a8\u9502\u5faa\u73af\u5bff\u547d\u3002\u4e0e\u6b64\u540c\u65f6\uff0cSnSb2<\/sub>Te4<\/sub>\/G\u4e5f\u6709\u7740\u4f18\u5f02\u7684\u50a8\u94be\u6027\u80fd\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4e5f\u4e3a\u901a\u8fc7\u52a0\u901f\u5bfc\u7535\u62d3\u6251\u9762\u79bb\u5b50\/\u7535\u5b50\u4f20\u5bfc\u3001\u539f\u5b50\u63ba\u6742\u548c\u754c\u9762\u4ea4\u4e92\u4f5c\u7528\u6765\u8bbe\u8ba1\u9ad8\u500d\u7387\u7535\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u72ec\u7279\u7684\u6307\u5bfc\u3002<\/p>\n

\u56fe<\/b><\/strong>11 SnSb<\/b><\/strong>2<\/b><\/sub><\/strong>Te<\/b><\/strong>4<\/b><\/sub><\/strong>\/G<\/b><\/strong>\u590d\u5408\u6750\u6599\u7684\u50a8\u9502\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>12 SnSb<\/b><\/strong>2<\/b><\/sub><\/strong>Te<\/b><\/strong>4<\/b><\/sub><\/strong>\/G<\/b><\/strong>\u590d\u5408\u6750\u6599\u9ad8\u500d\u7387\u50a8\u9502\/\u94be\u7684\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>dvanced Energy Materials<\/b><\/strong>\uff1a\u9502\u5316\u8f85\u52a9\u5316\u5b66\u5265\u79bb\u6cd5\u5236\u5907\u8d85\u8584\u5c11\u5c42GeP\u7eb3\u7c73\u7247\u53ca\u5176\u50a8\u94a0\u5e94\u7528<\/b><\/strong><\/p>\n

\u8d85\u8584\u5c11\u5c42\u6750\u6599\u7531\u4e8e\u5177\u6709\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u5c11\u5c42GeP\uff08FL-GP\uff09\u7531\u4e8e\u5177\u6709\u5408\u9002\u7684\u5e26\u9699\u548c\u826f\u597d\u7684\u7a33\u5b9a\u6027\u800c\u975e\u5e38\u6709\u6f5c\u529b\u5e94\u7528\u5728\u7535\u5b50\u548c\u5149\u7535\u5b50\u9886\u57df\u3002\u7136\u800c\uff0c\u5982\u4f55\u5c06\u4f53\u76f8GeP\u6676\u4f53\u5265\u79bb\u4e3a\u8d85\u8584\u7684\u5c11\u5c42\u6216\u5355\u5c42GeP\u5374\u5341\u5206\u56f0\u96be\u3002\u5728\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\u7684\u90ed\u518d\u840d\u548c\u9648\u519b<\/b><\/strong>\uff08\u6ce8\uff1a\u672c\u7bc7\u901a\u8baf\u5355\u4f4d\u786e\u4e3a\u6b64\uff09\u56e2\u961f\u91c7\u7528\u4e00\u79cd\u9502\u5316\u8f85\u52a9\u7684\u5316\u5b66\u5265\u79bb\u6cd5\u6210\u529f\u5236\u5907\u51fa\u4e86FL-GP[7]<\/sup>\u3002\u5728\u8be5\u7b56\u7565\u4e2d\uff0c\u9502\u79bb\u5b50\u7684\u9884\u5148\u63d2\u5165\u6709\u6548\u5730\u6269\u5927\u4e86GeP\u7684\u5c42\u95f4\u8ddd\uff0c\u4ece\u800c\u5728\u63a5\u4e0b\u6765\u7684\u8d85\u58f0\u9636\u6bb5\u6210\u529f\u5730\u5c06\u4f53\u76f8GeP\u5265\u79bb\u5f00\uff08\u56fe13\uff09\u3002\u4f5c\u4e3a\u5c55\u793a\uff0cFL-GP\/rGO\u6750\u6599\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50a8\u94a0\u6027\u80fd\u3002\u8fd9\u662f\u56e0\u4e3a\u4e8c\u7ef4\u7ed3\u6784\u7684FL-GP\u4e0d\u4ec5\u53ef\u4ee5\u7f29\u77ed\u79bb\u5b50\u4f20\u8f93\u7684\u8ddd\u79bb\u8fd8\u80fd\u591f\u7f13\u89e3\u6750\u6599\u5728\u94a0\u5316\u65f6\u7684\u4f53\u79ef\u53d8\u5316\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u590d\u5408\u6750\u6599\u4e2d\u7684rGO\u8fd8\u80fd\u591f\u663e\u8457\u6539\u5584\u7535\u6781\u7684\u7535\u5b50\u7535\u5bfc\u7387\u3002\u94a0\u79bb\u5b50\u534a\u7535\u6c60\u6d4b\u8bd5\u8868\u660e\uff0cFL-GP\/rGO\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff08100 mA g-1<\/sup>\uff1a504.2 mAh g-1<\/sup>\uff09\uff0c\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u548c\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u7ec4\u88c5\u4e86FL-GP\/rGO\/\/Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u5168\u7535\u6c60\uff0c\u5176\u4e5f\u8868\u73b0\u51fa\u4e86\u4ee4\u4eba\u6ee1\u610f\u7684\u7535\u6027\u80fd\uff08\u56fe14\uff09\u3002<\/p>\n

\u56fe<\/b><\/strong>13 FL-GP\/rGO<\/b><\/strong>\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u53ca\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>14 FL-GP\/rGO<\/b><\/strong>\u8d1f\u6781\u4e0e<\/b><\/strong>Na<\/b><\/strong>3<\/b><\/sub><\/strong>V<\/b><\/strong>2<\/b><\/sub><\/strong>(PO<\/b><\/strong>4<\/b><\/sub><\/strong>)<\/b><\/strong>3<\/b><\/sub><\/strong>\u6b63\u6781\u7ec4\u6210\u7684\u5168\u7535\u6c60\u7684\u7535\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5<\/b><\/strong>\u00a0<\/b><\/strong>\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66<\/b><\/strong>Dmitri Golberg<\/b><\/strong><\/p>\n

N<\/b><\/strong>ano Energy<\/b><\/strong>\uff1a\u81ea\u7ec4\u88c5\u78f7\u9178\u954d\u57fa\u7eb3\u7c73\u7ba1\u6784\u5efa\u4e8c\u7ef4\u8936\u76b1\u5c42\u72b6\u7ed3\u6784\u7528\u4f5c\u9ad8\u6027\u80fd\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><\/p>\n

\u6700\u8fd1\uff0c\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u3001\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240\u7684<\/b><\/strong>Dmitri Golberg<\/b><\/strong>\uff0c\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240<\/b><\/strong>Yoshio Bando<\/b><\/strong>\u548c\u9752\u5c9b\u79d1\u6280\u5927\u5b66\u7684<\/b><\/strong>Yusuke Yamauchi<\/b><\/strong>\u56e2\u961f\u4ee5\u7518\u6cb9\u9178\u954d\u9897\u7c92\u4f5c\u4e3a\u727a\u7272\u6a21\u677f\uff0c\u91c7\u7528\u4e24\u6b65\u78f7\u9178\u8f85\u52a9\u7684\u6eb6\u5242\u70ed\u6cd5\u901a\u8fc7\u81ea\u7ec4\u88c5\u7684\u65b9\u5f0f\u5236\u5907\u51fa\u4e86\u65e0\u5b9a\u578b\u78f7\u9178\u954d\u57fa\u7eb3\u7c73\u7ba1\u6784\u5efa\u7684\u4e8c\u7ef4\u8936\u76b1\u5c42\u72b6\u7ed3\u6784\uff08\u56fe15\uff09[8]<\/sup>\u3002\u7518\u6cb9\u9178\u954d\u6a21\u677f\u201c\u81ea\u89e3\u6784-\u81ea\u7f16\u7ec7\u201d\u673a\u7406\u662f\u4e0a\u8ff0\u4e8c\u7ef4\u8936\u76b1\u5c42\u72b6\u7ed3\u6784\u5f62\u6210\u7684\u539f\u56e0\u3002\u7531\u7eb3\u7c73\u7ba1\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u65e0\u5b9a2D\u78f7\u9178\u954d\uff08NiHPi-500\uff09\u4f5c\u6b63\u6781\u548c\u6d3b\u6027\u70ad\uff08AC\uff09\u4f5c\u8d1f\u6781\u6784\u5efa\u7684\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\uff08ASC\uff09\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff08\u56fe16\uff09\uff1a\u5728362 W kg-1<\/sup>\uff0c1443 W kg-1<\/sup>\uff0c\u548c2838 W kg-1<\/sup>\u7684\u529f\u7387\u5bc6\u5ea6\u4e0b\uff0c\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe50 Wh\u00a0kg-1<\/sup>\uff0c40 Wh\u00a0kg-1<\/sup>\u548c32 Wh\u00a0kg-1<\/sup>\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u5373\u4f7f\u57287242 W kg-1<\/sup>\u7684\u529f\u7387\u5bc6\u5ea6\u4e0b\uff0c\u8be5\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u5bc6\u5ea6\u4ecd\u7136\u670918 Wh\u00a0kg-1<\/sup>\u3002\u6b64\u5916\uff0cNiHPi-500\/\/AC\u7535\u5bb9\u5668\u4e5f\u8868\u73b0\u51fa\u4e86\u826f\u597d\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\uff1a\u572810 A\u00a0g–<\/sup>1<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af5000\u6b21\u540e\u5bb9\u91cf\u51e0\u4e4e\u6ca1\u6709\u8870\u51cf\u3002\u5176\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u4e3b\u8981\u6e90\u4e8e\uff1a\uff081\uff09\u72ec\u7279\u7684\u7eb3\u7c73\u7ba1\u7ec4\u88c5\u6210\u76842D\u7ed3\u6784\uff1b\uff082\uff09\u7eb3\u7c73\u7ba1\u4e4b\u95f4\u826f\u597d\u7684\u8fde\u63a5\uff1b\uff083\uff09\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u8fd9\u6709\u5229\u4e8e\u63d0\u4f9b\u66f4\u591a\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u5e76\u4fc3\u8fdb\u7535\u89e3\u6db2\u79bb\u5b50\u7684\u4f20\u8f93\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\u8be5\u65e0\u5b9a\u578b\u78f7\u9178\u954d\u57fa\u7eb3\u7c73\u7ba1\u6784\u5efa\u7684\u4e8c\u7ef4\u8936\u76b1\u5c42\u72b6\u7ed3\u6784\u975e\u5e38\u6709\u5e0c\u671b\u5e94\u7528\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0a\u3002<\/p>\n

\u56fe<\/b><\/strong>15 <\/b><\/strong>\u78f7\u9178\u954d\u57fa\u7eb3\u7c73\u7ba1\u81ea\u7ec4\u88c5\u6784\u5efa\u4e8c\u7ef4\u7ed3\u6784\u7684\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>16 NiHPi-500\/\/AC<\/b><\/strong>\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Journal of Materials Chemistry A<\/b><\/strong>\uff1a\u81ea\u7f16\u7ec7\u78f7\u9178\u6c22\u954d\u94b4\u7eb3\u7c73\u7ba1\u6784\u9020\u53ef\u8c03\u63a7\u7eb3\u7c73\u7ed3\u6784\u5b9e\u73b0\u9ad8\u6548ORR\u53cd\u5e94<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u3001\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240\u7684<\/b><\/strong>Dmitri Golberg<\/b><\/strong>\uff0c\u65e5\u672c\u56fd\u7acb\u6750\u6599\u7814\u7a76\u6240<\/b><\/strong>Yoshio Bando<\/b><\/strong>\u548c\u9752\u5c9b\u79d1\u6280\u5927\u5b66\u7684<\/b><\/strong>Yusuke Yamauchi<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u5229\u7528\u5355\u5206\u6563\u7684\u7518\u6cb9\u9178Ni-Co\u7403\u4f5c\u4e3a\u727a\u7272\u6a21\u677f\uff0c\u901a\u8fc7\u81ea\u7f16\u7ec7\u53cc\u91d1\u5c5e\u78f7\u9178\u6c22\u954d\u94b4\u7eb3\u7c73\u7ba1\u5236\u5907\u51fa\u4e861D\u7684\u5fae\u7c73\u7eba\u9524\u548c2D\u7684\u7247\u5c42\u7ed3\u6784\u7684\u6750\u6599\uff08\u56fe17\uff09[9]<\/sup>\u3002\u6574\u4e2a\u8fc7\u7a0b\u662f\u5728\u78f7\u9178\u4f5c\u4e3a\u78f7\u6e90\u548c\u81ea\u7f16\u7ec7\u63a8\u52a8\u5242\u7684\u60c5\u51b5\u4e0b\u901a\u8fc7\u4e24\u6b65\u6eb6\u5242\u70ed\u6cd5\u6765\u5b9e\u73b0\u7684\u3002\u53cc\u91d1\u5c5e\u78f7\u9178\u6c22\u954d\u94b4\u7eb3\u7c73\u7ba1\u9996\u5148\u751f\u957f\u5728\u7518\u6cb9\u9178Ni-Co\u7403\u7684\u8868\u9762\uff0c\u968f\u540e\u901a\u8fc7\u201c\u5265\u79bb-\u81ea\u7f16\u7ec7\u201d\u673a\u5236\u6784\u5efa\u8d771D\u7684\u5fae\u7c73\u7eba\u9524\u548c2D\u7684\u7247\u5c42\u7ed3\u6784\u3002\u7518\u6cb9\u9178Ni-Co\u7403\u4e2dNi\/Co\u7684\u6469\u5c14\u6bd4\u51b3\u5b9a\u4e86\u81ea\u7f16\u7ec7\u7ed3\u6784\u7684\u6700\u7ec8\u5f62\u8c8c\u3002\u7535\u50ac\u5316\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u8868\u660e\uff0c\u5bccNi\u7684\u78f7\u9178\u6c22\u954d\u94b4\u7535\u6781\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff08\u56fe18\uff0c\u8fc7\u7535\u52bf\u4e3a320 mV\uff0c\u5854\u83f2\u5c14\u659c\u7387\u4ec5\u4e3a 84 mV dec-1<\/sup>\uff09\uff0c\u4f18\u4e8e\u5bccCo\u548c\u7b49\u6469\u5c14\u6bd4\u7684\u78f7\u9178\u6c22\u954d\u94b4\u7535\u6781\u3002\u5206\u6790\u8868\u660e\uff0c\u5bccNi\u7684\u78f7\u9178\u6c22\u954d\u94b4\u7535\u6781\u9ad8\u7684OER\u6d3b\u6027\u6e90\u4e8e\u5176\u8868\u9762\u5f62\u6210\u7684\u6d3b\u6027\u6c22\u6c27\u5316\u954d\u94b4\u76f8\u3002<\/p>\n

\u56fe<\/b><\/strong>17 <\/b><\/strong>\u78f7\u9178\u6c22\u954d\u94b4\u7eb3\u7c73\u7ba1\u81ea\u7f16\u7ec7\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>18 <\/b><\/strong>\u78f7\u9178\u6c22\u954d\u94b4\u7535\u6781OER\u50ac\u5316\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

[1] N. Wang, Y. Wang, Z. Bai, Z. Fang, X. Zhang, Z. Xu, Y. Ding, X. Xu, Y. Du, S. Dou, G. Yu, High-performance room-temperature sodium\u2013sulfur battery enabled by electrocatalytic sodium polysulfides full conversion, Energy Environ. Sci., 13 (2020) 562-570.<\/p>\n

[2] C. Mu, J. Mao, J. Guo, Q. Guo, Z. Li, W. Qin, Z. Hu, K. Davey, T. Ling, S.Z. Qiao, Rational Design of Spinel Cobalt Vanadate Oxide Co2<\/sub>VO4<\/sub>\u00a0for Superior Electrocatalysis, Adv. Mater., (2020) 1907168.<\/p>\n

[3] C. Ye, Y. Jiao, D. Chao, T. Ling, J. Shan, B. Zhang, Q. Gu, K. Davey, H. Wang, S.Z. Qiao, Electron-State Confinement of Polysulfides for Highly Stable Sodium-Sulfur Batteries, Adv. Mater., (2020) 1907557.<\/p>\n

[4] Q. Cheng, C. Hu, G. Wang, Z. Zou, H. Yang, L. Dai, Carbon-defect-driven electroless deposition of Pt atomic clusters for highly efficient hydrogen evolution, J Am Chem Soc, (2020).<\/p>\n

[5] P. Jaumaux, Q. Liu, D. Zhou, X. Xu, T. Wang, Y. Wang, F. Kang, B. Li, G. Wang, Deep Eutectic Solvent-Based Self-Healing Polymer Electrolyte for Safe and Long-Life Lithium Metal Batteries, Angew. Chem. Int. Ed. Engl., (2020).<\/p>\n

[6] Z. Wu, G. Liang, W.K. Pang, T. Zhou, Z. Cheng, W. Zhang, Y. Liu, B. Johannessen, Z. Guo, Coupling Topological Insulator SnSb2<\/sub>Te4<\/sub>\u00a0Nanodots with Highly Doped Graphene for High-Rate Energy Storage, Adv. Mater., 32 (2020) 1905632.<\/p>\n

[7] F. Yang, J. Hong, J. Hao, S. Zhang, G. Liang, J. Long, Y. Liu, N. Liu, W.K. Pang, J. Chen, Z. Guo, Ultrathin Few\u2010Layer GeP Nanosheets via Lithiation\u2010Assisted Chemical Exfoliation and Their Application in Sodium Storage, Adv. Energy Mater., (2020) 1903826.<\/p>\n

[8] N.L. Wulan Septiani, Y.V. Kaneti, K.B. Fathoni, J. Wang, Y. Ide, B. Yuliarto, Nugraha, H.K. Dipojono, A.K. Nanjundan, D. Golberg, Y. Bando, Y. Yamauchi, Self-assembly of nickel phosphate-based nanotubes into two-dimensional crumpled sheet-like architectures for high-performance asymmetric supercapacitors, Nano Energy, 67 (2020) 104270.<\/p>\n

[9] N.L.W. Septiani, Y.V. Kaneti, K.B. Fathoni, Y. Guo, Y. Ide, B. Yuliarto, X. Jiang, Nugraha, H.K. Dipojono, D. Golberg, Y. Yamauchi, Tailorable nanoarchitecturing of bimetallic nickel\u2013cobalt hydrogen phosphate via the self-weaving of nanotubes for efficient oxygen evolution, J. Mater. Chem. A, 8 (2020) 3035-3047.<\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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