{"id":198538,"date":"2020-03-25T06:29:32","date_gmt":"2020-03-24T22:29:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=198538"},"modified":"2020-03-24T21:30:10","modified_gmt":"2020-03-24T13:30:10","slug":"%e4%b8%9c%e5%8c%97%e5%b8%88%e5%a4%a7%e6%9c%b1%e5%b9%bf%e5%b1%b1chem-rev-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%a4%9a%e5%ad%94%e8%8a%b3%e9%a6%99%e9%aa%a8%e6%9e%b6%ef%bc%88pafs%ef%bc%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=198538","title":{"rendered":"\u4e1c\u5317\u5e08\u5927\u6731\u5e7f\u5c71Chem. Rev.\u7efc\u8ff0\uff1a\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\uff08PAFs\uff09"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u5177\u6709\u591a\u5b54\u6027\u7684\u6750\u6599\u5728\u81ea\u7136\u754c\u4e2d\u666e\u904d\u5b58\u5728\uff0c\u5176\u5b54\u9053\u5927\u5c0f\u4ece\u5fae\u89c2\u5c3a\u5ea6\u4e00\u76f4\u5ef6\u4f38\u5230\u5230\u5b8f\u89c2\u5c3a\u5ea6\u3002\u53d7\u81ea\u7136\u754c\u8fd9\u7c7b\u6750\u6599\u7684\u542f\u53d1\uff0c\u7531\u65e0\u673a\u6216\u6709\u673a\u5316\u5408\u7269\u6216\u4e24\u8005\u7ed3\u5408\u5f62\u6210\u7684\u591a\u5b54\u56fa\u4f53\u4e0d\u65ad\u5730\u88ab\u5236\u5907\u51fa\u6765\u3002\u8fd9\u4e9b\u591a\u5b54\u56fa\u4f53\u5177\u6709\u5ef6\u4f38\u7684\u9aa8\u67b6\u7ed3\u6784\uff0c\u5927\u91cf\u53ef\u5229\u7528\u7684\u5185\u8868\u9762\u3001\u5927\u7684\u5b54\u9699\u4f53\u79ef\u548c\u5206\u5b50\u5c3a\u5ea6\u7684\u5f00\u653e\u7a97\u53e3\u3002\u56e0\u6b64\uff0c\u5b83\u4eec\u73b0\u5728\u6210\u4e3a\u5728\u5438\u9644\u3001\u50ac\u5316\u548c\u5206\u5b50\u5206\u79bb\u7684\u79d1\u5b66\u548c\u6280\u672f\u7b49\u65b9\u9762\u5e7f\u6cdb\u5e94\u7528\u7684\u5148\u8fdb\u6750\u6599\u3002<\/p>\n

\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\uff08PAFs\uff09\u662f\u4e00\u79cd\u7531\u6211\u56fd\u79d1\u7814\u5de5\u4f5c\u8005\u9996\u5148\u53d1\u73b0\u5e76\u547d\u540d\u7684\u591a\u5b54\u56fa\u4f53\u6750\u6599\uff0c\u5177\u6709\u521a\u6027\u7684\u9aa8\u67b6\u7ed3\u6784\u548c\u8d85\u9ad8\u7684\u8868\u9762\u79ef\uff0c\u7279\u522b\u662f\uff0c\u5b83\u4eec\u5177\u6709\u72ec\u7279\u7684\u901a\u8fc7\u78b3\u78b3\u952e\u8fde\u63a5\u7684\u82b3\u9999\u57fa\u7ed3\u6784\u5355\u5143\u3002\u591a\u6837\u5316\u7684\u529f\u80fd\u53ef\u4ee5\u6765\u6e90\u4e8e\u5176PAFs\u7ed3\u6784\u5355\u5143\u7684\u56fa\u6709\u5316\u5b66\u6027\u8d28\uff0c\u4e5f\u53ef\u4ee5\u901a\u8fc7\u5df2\u77e5\u7684\u6709\u673a\u53cd\u5e94\u5bf9\u82b3\u9999\u57fa\u9aa8\u67b6\u8fdb\u884c\u540e\u4fee\u9970\u6765\u5b9e\u73b0\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u78b3-\u78b3\u952e\u8fde\u63a5\u65b9\u5f0f\u4f7fPAFs\u5728\u82db\u523b\u7684\u5316\u5b66\u5904\u7406\u4e0b\u80fd\u4fdd\u6301\u7a33\u5b9a\u3002\u56e0\u6b64\uff0c\u4e0e\u4f20\u7edf\u7684\u591a\u5b54\u6750\u6599\uff0c\u5982\u6cb8\u77f3\u548c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u76f8\u6bd4\uff0cPAFs\u5728\u5316\u5b66\u548c\u529f\u80fd\u4e0a\u8868\u73b0\u51fa\u7279\u5f02\u6027\u3002PAFs\u7684\u72ec\u7279\u7279\u6027\u4f7f\u5176\u901a\u8fc7\u82db\u523b\u7684\u5316\u5b66\u5904\u7406\u8fdb\u884c\u529f\u80fd\u5316\uff0c\u5e76\u80fd\u591f\u8010\u53d7\u6076\u52a3\u7684\u73af\u5883\u5b9e\u73b0\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u6731\u5e7f\u5c71\u6559\u6388<\/strong>\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u5173\u4e8e\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\uff08PAFs\uff09\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u4ee5\u201cPorous Aromatic Frameworks (PAFs)<\/strong>\u201d\u53d1\u8868\u4e8eChem. Rev.<\/strong>\u671f\u520a\u4e0a\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u4e3b\u8981\u56f4\u7ed5PAFs\u7684\u5408\u6210\u3001\u529f\u80fd\u5316\u548c\u5e94\u7528\u8fdb\u884c\u8ba8\u8bba\u548c\u7efc\u8ff0\uff0c\u56f4\u7ed5\u8fd1\u5341\u5e74\u6765\u56fd\u9645\u4e0a\u4f17\u591a\u8bfe\u9898\u7ec4\u5173\u4e8ePAFs\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u5bf9\u8fd9\u4e09\u4e2a\u90e8\u5206\u4f5c\u4e86\u5168\u9762\u7684\u89e3\u91ca\uff0c\u4ee5\u9610\u660e\u8fd9\u4e00\u9886\u57df\u7684\u53d1\u5c55\u72b6\u51b5\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u603b\u7ed3\u4e86PAFs\u5f53\u524d\u7814\u7a76\u4e2d\u6240\u5b58\u5728\u7684\u4e00\u4e9b\u95ee\u9898\uff0c\u5e76\u5c55\u671b\u4e86PAFs\u7684\u53d1\u5c55\u8d8b\u52bf\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

1<\/strong>\u3001\u5f15\u8a00<\/strong><\/p>\n

\u56fe\u4e00<\/strong><\/p>\n

\"\"\u4ee5\u56db\u9762\u4f53\u7ed3\u6784\u5355\u5143\u4e3a\u539f\u6599\uff0c\u91c7\u7528Yamamoto\u578bUllmann\u8026\u5408\u53cd\u5e94\u5408\u6210\u7684\u9996\u4e2a\u591a\u5b54\u82b3\u9999\u9aa8\u67b6PAF-1\u3002<\/p>\n

\u56fe\u4e8c<\/strong><\/p>\n

\"\"\u591a\u5b54\u56fa\u4f53\u53d1\u5c55\u5386\u7a0b\u7684\u65f6\u5e8f\u56fe\uff0c\u5305\u62ec\u65b0\u6750\u6599\u5408\u6210\u4e2d\u7684\u91cd\u8981\u53d1\u73b0\u3002<\/p>\n

\u56fe\u4e09<\/strong><\/p>\n

\"\"PAF\u7814\u7a76\u4e2d\u4e3b\u8981\u7684\u7814\u7a76\u65b9\u9762\uff1aPAF\u8bbe\u8ba1\u4e0e\u5408\u6210\u3001\u6846\u67b6\u529f\u80fd\u5316\u53ca\u5176\u5e94\u7528\u7684\u5173\u7cfb\u3002<\/p>\n

2<\/strong>\u3001<\/strong>PAFs<\/strong>\u7684\u8bbe\u8ba1\u539f\u7406\u4e0e\u5408\u6210<\/strong><\/p>\n

2.1<\/strong>\u3001<\/strong>PAF-1<\/strong>\u4e2d\u5b54\u9053\u7ed3\u6784\u7684\u5f62\u6210<\/strong><\/p>\n

2.1.1<\/strong>\u3001\u7ed3\u6784\u8bbe\u8ba1<\/strong><\/p>\n

2.1.2<\/strong>\u3001<\/strong>PAF-1<\/strong>\u7684\u5408\u6210<\/strong><\/p>\n

\u56fe\u56db<\/strong><\/p>\n

\"\"\u6765\u6e90\u4e8e\u91d1\u521a\u77f3\u7ed3\u6784\uff08a\uff09\u7684\u591a\u5b54\u82b3\u9999\u9aa8\u67b6P1\uff08b\uff09\uff0cP2\uff08c\uff09\u548cP3\uff08d\uff09\u7684\u7ed3\u6784\u8bbe\u8ba1\u601d\u60f3\u3002<\/p>\n

2.2<\/strong>\u3001\u57fa\u4e8e\u62d3\u6251\u7684<\/strong>PAFs<\/strong>\u8bbe\u8ba1<\/strong><\/p>\n

2.3<\/strong>\u3001\u5408\u6210<\/strong>PAF<\/strong>\u7684\u5efa\u7b51\u5355\u5143<\/strong><\/p>\n

2.3.1<\/strong>\u3001\u5efa\u7b51\u5355\u5143\u7684\u51e0\u4f55\u5f62\u72b6<\/strong><\/p>\n

\u56fe\u4e94<\/strong><\/p>\n

\"\"\u7ed3\u6784\u5355\u5143\u8bbe\u8ba1\u5de5\u7a0b\uff1a\u7531\u56db\u9762\u4f53\u7ed3\u6784\u884d\u751f\u7684\u4e09\u68f1\u67f1\u7ed3\u6784\uff0c\u53ca\u5176\u5f62\u6210\u7684PAF-100\u548cPAF-101\u7684\u7a7a\u9699\u548c\u9884\u6d4b\u6676\u683c\u3002<\/p>\n

\u56fe\u516d<\/strong><\/p>\n

\"\"\u4e00\u4e9b\u6709\u4ee3\u8868\u6027\u7684\u7528\u4f5c\u7ed3\u6784\u5355\u5143\u7684\u5206\u5b50\uff0c\u57fa\u4e8e\u5176\u51e0\u4f55\u5f62\u72b6\u5206\u7c7b\u5305\u62ec:\uff08a\uff09\u7acb\u65b9\u4f53\uff0c\uff08b\uff0cc\uff09\u4e09\u68f1\u67f1\uff0c\uff08d~f\uff09\u56db\u9762\u4f53\uff0c\uff08g~i\uff09\u6b63\u65b9\u5f62\uff0c\uff08j~n\uff09\u4e09\u89d2\u5f62\u3002<\/p>\n

2.3.2<\/strong>\u3001\u5efa\u7b51\u5355\u5143\u7684\u5c3a\u5bf8\u6548\u5e94<\/strong><\/p>\n

2.3.3<\/strong>\u3001\u6846\u67b6\u4e92\u7a7f<\/strong><\/p>\n

\u56fe\u4e03<\/strong><\/p>\n

\"\"\u4e00\u7c7b\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\u6750\u6599\uff08PPN\uff09\u7684\u975e\u4e92\u7a7f\u6846\u67b6\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u516b<\/strong><\/p>\n

\"\"\u901a\u8fc7\u63a7\u5236\u5efa\u7b51\u5355\u5143\u7684\u5927\u5c0f\u6765\u5236\u5907\u975e\u4e92\u7a7f\u6846\u67b6PAFs\u7684\u7b56\u7565\u3002<\/p>\n

2.3.4<\/strong>\u3001<\/strong>PAF<\/strong>\u8bbe\u8ba1\u4e0e\u5408\u6210\u4e2d\u7684\u8ba1\u7b97\u6a21\u62df<\/strong><\/p>\n

2.4<\/strong>\u3001\u53cd\u5e94<\/strong><\/p>\n

2.4.1<\/strong>\u3001<\/strong>Yamamoto<\/strong>\u578b<\/strong>Ullmann<\/strong>\u8026\u5408\u53cd\u5e94<\/strong><\/p>\n

\u56fe\u4e5d<\/strong><\/p>\n

\"\"PAFs\u5408\u6210\u4e2d\u5e38\u7528\u7684\uff08a\uff09Yamamoto\u578bUllmann\u5076\u8054\u548c\uff08b\uff09Pd\u50ac\u5316\u7684Sonogashira\u4ea4\u53c9\u5076\u8054\u7684\u5178\u578b\u5076\u8054\u53cd\u5e94\u4e4b\u95f4\u7684\u673a\u7406\u6bd4\u8f83\u3002<\/p>\n

2.4.2<\/strong>\u3001\u5176\u4ed6\u8026\u5408\u53cd\u5e94<\/strong><\/p>\n

2.4.3<\/strong>\u3001\u6c30\u57fa\u73af\u4e09\u805a<\/strong><\/p>\n

2.4.4<\/strong>\u3001\u5408\u6210<\/strong>PAF<\/strong>\u7684\u65b0\u53cd\u5e94\u7684\u5f00\u53d1<\/strong><\/p>\n

\u56fe\u5341<\/strong><\/p>\n

\"\"\u4e00\u4e9b\u5e38\u7528\u7684\u7528\u4e8e\u5408\u6210\u591a\u5b54\u9aa8\u67b6\u7684\u5076\u8054\u53cd\u5e94\uff1a\uff08a\uff09Yamamoto\u578bUllmann\u5076\u8054\uff0c\uff08b\uff09Suzuki-Miyaura\u4ea4\u53c9\u5076\u8054\uff0c\uff08c\uff09Sonogashira-Hagihara\u4ea4\u53c9\u5076\u8054\uff0c\uff08d\uff09Mizoroki-Heck\u4ea4\u53c9\u5076\u8054\uff0c\uff08e\uff09\u6c27\u5316Eglinton\u5076\u8054\uff0c\uff08f\uff09\u78b1\u4ecb\u5bfc\u7684\u5076\u6c2e\u5f62\u6210\uff0c\uff08g\uff09\u9170\u4e9a\u80fa\u5316\u53cd\u5e94\uff0c\uff08h\uff09\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\uff0c\uff08i\uff09\u6c30\u57fa\u73af\u4e09\u805a\u548c\uff08j\uff09\u54cc\u5576\u4e0a\u7684\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u3002<\/p>\n

2.5<\/strong>\u3001<\/strong>PAFs<\/strong>\u7684\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

2.5.1<\/strong>\u3001\u56f0\u96be\u4e0e\u6311\u6218<\/strong><\/p>\n

2.5.2<\/strong>\u3001\u5085\u7acb\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u6cd5<\/strong><\/p>\n

2.5.3<\/strong>\u3001\u6838\u78c1\u5171\u632f<\/strong><\/p>\n

2.5.4<\/strong>\u3001\u70ed\u91cd\u5206\u6790\u548c\u5143\u7d20\u5206\u6790<\/strong><\/p>\n

2.5.5<\/strong>\u3001\u5b54\u9699\u7387\u6d4b\u5b9a<\/strong><\/p>\n

3<\/strong>\u3001<\/strong>PAF<\/strong>\u529f\u80fd\u5316\u7684\u4e00\u822c\u7b56\u7565\u548c\u4f8b\u5b50<\/strong><\/p>\n

\u56fe\u5341\u4e00<\/strong><\/p>\n

\"\"PAF\u529f\u80fd\u5316\u7684\u4e09\u79cd\u57fa\u672c\u7b56\u7565\u793a\u610f\u56fe\u3002<\/p>\n

3.1<\/strong>\u3001\u76f4\u63a5\u5408\u6210<\/strong><\/p>\n

\u56fe\u5341\u4e8c<\/strong><\/p>\n

\"\"\u4ece\u5934\u5408\u6210\u7b56\u7565\u5236\u5907\u7532\u57fa\uff0c\u7532\u9187\u6216\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa\u5b98\u80fd\u5316\u7684PAFs\u3002<\/p>\n

3.2<\/strong>\u3001\u5408\u6210\u540e\u4fee\u9970<\/strong><\/p>\n

\u56fe\u5341\u4e09<\/strong><\/p>\n

\"\" \"\"\u78fa\u9178\u76d0\u63a5\u679d\u7684\u591a\u5b54\u805a\u5408\u7269\u7f51\u7edc\uff08PPN-6-SO3<\/sub>H\uff09\u7684\u5408\u6210\u540e\u4fee\u9970\u7a0b\u5e8f\u56fe\u3002<\/p>\n

3.3<\/strong>\u3001\u540e\u4fee\u9970\u5177\u6709\u9884\u951a\u5b9a\u4f4d\u7f6e\u7684<\/strong>PAF<\/strong><\/p>\n

3.4<\/strong>\u3001\u7535\u8377\u578b\u9aa8\u67b6<\/strong>PAFs<\/strong><\/p>\n

\u56fe\u5341\u56db<\/strong><\/p>\n

\"\"\u7531\u9634\u79bb\u5b50\u7ed3\u6784\u5355\u5143\u76f4\u63a5\u5408\u6210\u5e26\u7535PAFs\u3002<\/p>\n

3.6<\/strong>\u3001<\/strong>PAF<\/strong>\u6846\u67b6\u7684\u6da6\u6e7f\u6027\u548c\u6781\u6027<\/strong><\/p>\n

4<\/strong>\u3001<\/strong>PAF<\/strong>\u5e94\u7528\u7684\u6700\u65b0\u6280\u672f<\/strong><\/p>\n

4.1<\/strong>\u3001\u6c14\u4f53\u5438\u9644<\/strong><\/p>\n

4.1.1<\/strong>\u3001\u50a8\u6c22<\/strong><\/p>\n

\u56fe\u5341\u4e94<\/strong>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 <\/strong><\/p>\n

\"\"H2<\/sub>\u8d28\u91cf\u5bb9\u91cf\u4e0e\u76f8\u5e94PAFs\u8868\u9762\u79ef\u7684\u5173\u7cfb\u3002\u8d28\u91cf\u5bb9\u91cf\u572848\u81f360 bar\u7684\u538b\u529b\u8303\u56f4\u4e0b\u6d4b\u5f97\u3002<\/p>\n

\u56fe\u5341\u516d<\/strong><\/p>\n

\"\"H2<\/sub>\u8d28\u91cf\u5bb9\u91cf\u4e0e\u76f8\u5e94PAFs\u8868\u9762\u79ef\u7684\u5173\u7cfb\u3002\u8d28\u91cf\u5bb9\u91cf\u5728\u5728\u5e38\u538b\u4e0b\u6d4b\u5f97\u3002<\/p>\n

\u56fe\u5341\u4e03<\/strong><\/p>\n

\"\"H2<\/sub>\u7684\u5438\u9644\u70ed\/\u7113\u7684\u7edd\u5bf9\u503c\u4e0e\u76f8\u5e94PAFs\u5b54\u5f84\u7684\u5bf9\u5e94\u5173\u7cfb\u3002<\/p>\n

\u56fe\u5341\u516b<\/strong><\/p>\n

\"\"Li-PAF-1\u7684\u5408\u6210\u8fc7\u7a0b\u3002\u901a\u8fc7\u9502\u5316\u8fc7\u7a0b\uff0c\u5c06PAF-1\u4e2d\u7684\u82b3\u73af\uff08\u84dd\u8272\uff09\u8fd8\u539f\u4e3a\u6d3b\u5316\u7684H2<\/sub>\u5b58\u50a8\u4f4d\u70b9\uff08\u7ea2\u8272\uff09\u3002<\/p>\n

4.1.2<\/strong>\u3001\u7532\u70f7\u5438\u9644<\/strong><\/p>\n

\u56fe\u5341\u4e5d<\/strong><\/p>\n

\"\"\u7532\u70f7\/\u82b3\u9999\u65cf\u7c07\u5728MP2\/6-311 G\uff08d, p\uff09\u6c34\u5e73\u7684\u4f18\u5316\u7ed3\u6784\u663e\u793a\u4e86\u7532\u70f7\u5206\u5b50\u4e0ePAF\u4e2d\u5404\u79cd\u82b3\u9999\u57fa\u5355\u5143\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

\u56fe\u4e8c\u5341<\/strong><\/p>\n

\"\"CH4<\/sub>\u7684\u5438\u9644\u4e0e\u76f8\u5e94PAFs\u6750\u6599\u53ca\u884d\u751f\u7269\u7684\u8868\u9762\u79ef\u7684\u5173\u7cfb\u3002\u5bf9\u504f\u79bb\u6700\u4f73\u62df\u5408\u7ebf\u663e\u8457\u7684\u6750\u6599\u7684\u5438\u9644\u70ed\u8fdb\u884c\u6807\u8bb0\u3002<\/p>\n

4.1.3<\/strong>\u3001<\/strong>CO2<\/sub><\/strong>\u6355\u83b7<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e00<\/strong><\/p>\n

\"\"\u4e8c\u6c22\u544b\u5583\u529f\u80fd\u5316\u7684DHF_PAF-1\u6a21\u62df\u7ed3\u6784\u3002\u5728\u73af\u5883\u538b\u529b\u548c298 K\u4e0b\uff0cDHF_PAF-1\u5728\u56db\u4e2a\u6a21\u62df\u7684\u529f\u80fd\u6027PAFs\u4e2d\u8868\u73b0\u51fa\u6700\u9ad8\u7684CO2<\/sub>\u5438\u6536\u80fd\u529b\u3002<\/p>\n

\u56fe\u4e8c\u5341\u4e8c<\/strong><\/p>\n

\"\"\u7ecfPEI\u6d78\u6e0d\u7684PAF-5\u7684\u5b54\u4f53\u79ef\u51cf\u5c0f\uff0c\u4f46CO2<\/sub>\u7ed3\u5408\u5f3a\u5ea6\u63d0\u9ad8\u3002\u5e95\u90e8\u66f2\u7ebf\u8868\u793aPAF-5\uff08\u9ed1\u8272\uff09\uff0cPEI\uff0810 wt\uff05\uff09\u2282PAF-5\uff08\u7eff\u8272\uff09\uff0cPEI\uff0830 wt\uff05\uff09\u2282PAF-5\uff08\u84dd\u8272\uff09\u548cPEI\uff0840 wt\uff05\uff09\u2282PAF-5\uff08\u7ea2\u8272\uff09\u7684N2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\uff08\u5de6\u4e0b\uff09\u548cCO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\uff08\u53f3\u4e0b\uff09\u3002<\/p>\n

4.1.4<\/strong>\u3001\u70c3\u7c7b\u6df7\u5408\u7269\u7684\u5438\u9644\u5206\u79bb<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e09<\/strong><\/p>\n

\"\" \"\"\u5728PAF-1\u4e2d\u5f15\u5165\u94f6\u4f4d\u70b9\uff0c\u901a\u8fc7\u03c0\u7edc\u5408\u7269\u4f5c\u7528\u5b9e\u73b0\u4e59\u70ef\/\u4e59\u70f7\u9ad8\u6548\u5206\u79bb\u3002<\/p>\n

4.1.5<\/strong>\u3001\u6c28\u7684\u6355\u83b7<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u56db<\/strong><\/p>\n

\"\"\u57fa\u4e8e\u6846\u67b6\u4e92\u7a7f\u6027\u80fd\u5b9e\u73b0\u7684\u5177\u6709\u7fa7\u57fa\u534f\u540c\u529f\u80fd\u7684PAF\u6750\u6599\u7528\u4e8e\u6c28\u6c14\u7684\u9ad8\u6548\u5438\u9644\u3002<\/p>\n

4.2<\/strong>\u3001\u819c\u5206\u79bb<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e94<\/strong><\/p>\n

\"\"PAF-1\/\u8d85\u73bb\u7483\u6001\u805a\u5408\u7269\u590d\u5408\u57fa\u8d28\u819c\u7684\u6297\u9648\u5316\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e8c\u5341\u516d<\/strong><\/p>\n

\"\"\u5f53\u4f7f\u7528PIM-1\u819c\u548cPIM-1\/PAF-1\u6df7\u5408\u57fa\u8d28\u819c\u5206\u79bbH2<\/sub>\/N2<\/sub>\u6df7\u5408\u7269\u65f6\uff0c\u6e17\u900f\u7269\u4e2d\u7684H2<\/sub>\u6e17\u900f\u6027\u548cH2<\/sub>\u6d53\u5ea6\u4f1a\u968f\u65f6\u95f4\u53d8\u5316\u3002<\/p>\n

4.3<\/strong>\u3001\u6709\u5bb3\u6709\u673a\u7269\u7684\u5438\u9644<\/strong><\/p>\n

4.3.1<\/strong>\u3001\u6709\u5bb3\u6709\u673a\u7269\u7684\u6355\u83b7<\/strong><\/p>\n

4.3.2<\/strong>\u3001\u75d5\u91cf\u6709\u673a\u7269\u7684\u5bcc\u96c6\u5206\u6790<\/strong><\/p>\n

4.4<\/strong>\u3001\u65e0\u673a\u7269\u7684\u5438\u9644<\/strong><\/p>\n

4.4.1<\/strong>\u3001\u6355\u83b7\u91d1\u5c5e\u4ee5\u8fdb\u884c\u73af\u5883\u4fee\u590d\u548c\u68c0\u6d4b<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e03<\/strong><\/p>\n

\"\"PAF-1-SMe\u53ef\u9009\u62e9\u6027\u5730\u4ece\u751f\u7269\u4f53\u6db2\u4e2d\u6355\u83b7\u94dc\u5e76\u901a\u8fc7\u6bd4\u8272\u6cd5\u6d4b\u91cf\u94dc\u6d53\u5ea6\u3002<\/p>\n

4.4.2<\/strong>\u3001\u6d77\u6c34\u63d0\u94c0<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u516b<\/strong><\/p>\n

\"\"\u5177\u6709\u94c0\u6355\u83b7\u4f4d\u70b9\u7684\u5206\u5b50\u5370\u8ff9PAF\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u7b56\u7565\u3002\uff08a\uff09\u7ed3\u6784\u5355\u5143\u548c\u94c0\u6355\u83b7\u4f4d\u70b9\uff0c\uff08b\uff09\u901a\u8fc7Mizoroki-Heck\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5408\u6210\u7684PAF\u9aa8\u67b6\uff0c\u4ee5\u53ca\uff08c\uff09\u5728\u9aa8\u67b6\u4e0a\u4fee\u9970\u4e86\u94c0\u6355\u83b7\u4f4d\u70b9\u7684\u5206\u5b50\u5370\u8ff9PAF\u3002<\/p>\n

4.4.3<\/strong>\u3001\u975e\u91d1\u5c5e\u5316\u5408\u7269\u7684\u5438\u9644<\/strong><\/p>\n

4.5<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u50ac\u5316<\/strong><\/p>\n

4.5.1<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u7ea7\u8054\u50ac\u5316<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e5d<\/strong><\/p>\n

\"\"\u5728\u591a\u5b54\u805a\u5408\u7269\u82b3\u9999\u9aa8\u67b6\uff08PPAF\uff09\u4e0a\u8fdb\u884c\u53cc\u529f\u80fd\u4fee\u9970\uff0c\u5c06\u9178\u6027\u4f4d\u70b9\u548c\u78b1\u6027\u4f4d\u70b9\u5f15\u5165\u540c\u4e00\u9aa8\u67b6\u5b9e\u73b0\u4e32\u8054\u50ac\u5316\u3002<\/p>\n

4.5.2<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u4e0d\u5bf9\u79f0\u50ac\u5316<\/strong><\/p>\n

4.5.3<\/strong>\u3001\u535f\u5549<\/strong>PAFs<\/strong>\u7528\u4e8e\u6c27\u5316\u8fd8\u539f\u50ac\u5316<\/strong><\/p>\n

4.5.4<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u5149\u50ac\u5316<\/strong><\/p>\n

4.5.5<\/strong>\u3001<\/strong>PAFs<\/strong>\u8d1f\u8f7d\u91d1\u5c5e\u50ac\u5316<\/strong><\/p>\n

\u56fe\u4e09\u5341<\/strong><\/p>\n

\"\"\u5177\u6709\u6c34\u89e3\u548c\u8f6c\u79fb\uff08\u5438\u9644\uff09\u4f4d\u70b9\u7684\u4eba\u5de5\u9176\u5206\u5b50\u5370\u8ff9PAF\u3002<\/p>\n

4.5.6<\/strong>\u3001\u591a\u7ea7\u5b54\u50ac\u5316\u5242<\/strong><\/p>\n

\u56fe\u4e09\u5341\u4e00<\/strong><\/p>\n

\"\"\u4ecb\u5b54PAF70-NH2<\/sub>\u7684\u5408\u6210\u53ca\u5177\u6709\u8f83\u5927\u7a7a\u95f4\u4f4d\u963b\u7684\u786b\u8132\u5206\u5b50\u7684\u4fee\u9970\uff0c\u5f97\u5230PAF70-\u786b\u8132\u3002<\/p>\n

\u56fe\u4e09\u5341\u4e8c<\/strong><\/p>\n

\"\"\u5177\u6709\u52a8\u6001\u9633\u79bb\u5b50\u57fa\u56e2\u7684\u7c7b\u91d1\u521a\u77f3PAF\u4e2d\u7531\u4e8e\u9634\u79bb\u5b50\u4ea4\u6362\u5f15\u8d77\u7684\u7ed3\u6784\u53d8\u5316\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u3002<\/p>\n

4.5.7<\/strong>\u3001<\/strong>PAFs<\/strong>\u57fa\u50ac\u5316\u6240\u9762\u4e34\u7684\u6311\u6218<\/strong><\/p>\n

4.6<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u7eb3\u7c73\u53cd\u5e94\u5668<\/strong><\/p>\n

\u56fe\u4e09\u5341\u4e09<\/strong><\/p>\n

\"\"PAFs\u4f5c\u4e3a\u7eb3\u7c73\u53cd\u5e94\u5668\uff1a\u901a\u8fc7\u4e19\u70ef\u8148\u5728PAF-1\u9aa8\u67b6\u7684\u5bc6\u95ed\u7a7a\u95f4\u4e2d\u539f\u4f4d\u805a\u5408\u5f62\u6210\u805a\u4e19\u70ef\u8148\u3002<\/p>\n

4.7<\/strong>\u3001<\/strong>PAFs<\/strong>\u7528\u4e8e\u4f20\u611f<\/strong><\/p>\n

4.8<\/strong>\u3001<\/strong>PAFs<\/strong>\u5728\u533b\u5b66\u65b9\u9762\u7684\u5e94\u7528<\/strong><\/p>\n

4.9<\/strong>\u3001<\/strong>PAFs<\/strong>\u53ca\u5176\u7535\u5316\u5b66\u884d\u751f\u7269<\/strong><\/p>\n

4.10<\/strong>\u3001\u523a\u6fc0\u54cd\u5e94\u578b<\/strong>PAFs<\/strong><\/p>\n

\u56fe\u4e09\u5341\u56db<\/strong><\/p>\n

\"\"\u4ee5\u87ba\u5421\u5583\u4f5c\u4e3a\u529f\u80fd\u6027\u7ed3\u6784\u5355\u5143\u7684PAFs\u5728\u9178\u6027\u548c\u78b1\u6027\u6c14\u4f53\u66b4\u9732\u4e0b\u8868\u73b0\u51fa\u53ef\u9006\u7684\u53d8\u8272\u5f00\u5173\u6027\u8d28\u3002<\/p>\n

5<\/strong>\u3001\u603b\u7ed3\u548c\u5c55\u671b<\/strong><\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u975e\u5e38\u5168\u9762\u5730\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u5173\u4e8e\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\uff08PAFs\uff09\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u4f5c\u8005\u4ecePAFs\u7ed3\u6784\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u5165\u624b\uff0c\u9610\u8ff0PAFs\u7684\u529f\u80fd\u5316\u548c\u5e94\u7528\u7814\u7a76\uff0c\u5305\u62ec\u5438\u9644\u3001\u5206\u79bb\u548c\u50ac\u5316\u7684\u5e38\u89c4\u5e94\u7528\u4ee5\u53ca\u7eb3\u7c73\u53cd\u5e94\u5668\uff0c\u4f20\u611f\u548c\u5bf9\u523a\u6fc0\u654f\u611f\u7684\u667a\u80fd\u6750\u6599\u7b49\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0cPAFs\u7684\u72ec\u7279\u6027\u5728\u4e8e\u5176\u5177\u6709\u6846\u67b6\u7a33\u5b9a\u6027\u548c\u529f\u80fd\u4fee\u9970\u6027\u3002\u56e0\u6b64\uff0cPAFs\u53ef\u901a\u8fc7\u66f4\u4e3a\u666e\u9002\u7684\u529f\u80fd\u5316\u65b9\u6cd5\uff0c\u5c06\u5408\u6210\u548c\u5e94\u7528\u6027\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u6700\u7ec8\u5b9e\u73b0\u4ee5\u529f\u80fd\u4e3a\u5bfc\u5411\u7684\u8bbe\u8ba1\u5408\u6210\u5177\u6709\u6240\u9700\u7279\u6027\u7684PAFs\u3002\u540c\u65f6\uff0cPAFs\u7684\u9776\u5411\u5b9a\u5411\u5408\u6210\u3001\u529f\u80fd\u5316\u548c\u5e94\u7528\u4ee5\u96c6\u6210\u65b9\u5f0f\u8868\u73b0\u51fa\u6765\uff0c\u90fd\u4fc3\u8fdb\u4e86\u8be5\u9886\u57df\u98de\u901f\u53d1\u5c55\u3002\u4f5c\u8005\u5728\u6587\u4e2d\u4e5f\u63d0\u5230\uff0cPAFs\u7684\u5e94\u7528\u7814\u7a76\u4ecd\u9762\u4e34\u7740\u8bb8\u591a\u56f0\u96be\u548c\u6311\u6218\u3002\u6bd4\u5982\u9ad8\u8868\u9762\u79efPAFs\u7684\u529f\u80fd\u5316\u4f1a\u5bfc\u81f4\u5176\u5b54\u9699\u7387\u660e\u663e\u964d\u4f4e\uff1bPAFs\u5408\u6210\u6210\u672c\u6602\u8d35\u4e14\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\u6b8b\u7559\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u5835\u585e\u7a7a\u9699\uff1bPAFs\u7684\u6eb6\u89e3\u6027\u5dee\u3001\u52a0\u5de5\u6027\u80fd\u4e0d\u4f73\u7b49\u7b49\uff0c\u8fd9\u4e9b\u95ee\u9898\u548c\u56f0\u96be\u666e\u904d\u5b58\u5728\u4e8e\u73b0\u9636\u6bb5PAFs\u7814\u7a76\u4e2d\uff0c\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\u5c06\u8fdb\u4e00\u6b65\u63a8\u52a8PAFs\u7684\u53d1\u5c55\u3002<\/p>\n

 <\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPorous Aromatic Frameworks (PAFs)<\/a>\uff08Chem.Rev.<\/em>, 2020<\/strong>. DOI: https:\/\/dx.doi.org\/10.1021\/acs.chemrev.9b00687.\uff09<\/p>\n

 <\/p>\n

\u3010\u6731\u5e7f\u5c71\u6559\u6388\u7b80\u4ecb\u3011<\/strong><\/p>\n

\"\"\u6731\u5e7f\u5c71<\/strong>\uff0c\u7537\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388<\/strong>\u3001\u535a\u58eb\u751f\u5bfc\u5e08<\/strong>\uff0c\u5316\u5b66\u5b66\u9662\u9662\u957f<\/strong>\uff0c\u591a\u9178\u79d1\u5b66\u6559\u80b2\u90e8\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb<\/strong>\uff0c\u957f\u6c5f\u5b66\u8005<\/strong>\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005<\/strong>\uff0c\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d<\/strong>\uff0c\u4eab\u53d7\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\uff0c\u6c11\u76df\u4e2d\u592e\u59d4\u5458\u30022014\u5e74\u8d77\uff0c\u62c5\u4efb\u300aScience China Materials\u300b\u3001\u300a\u5316\u5b66\u5b66\u62a5\u300b\u3001\u300a\u4e2d\u56fd\u5316\u5b66\u5feb\u62a5\u300b\u7f16\u59d4\u3002\u662f\u56fd\u9645\u77e5\u540d\u671f\u520aMatter\u53caACS Central Science\u7684\u987e\u95ee\u59d4\u5458\u4f1a\u6210\u5458\uff08Editorial Advisory Board\uff09\u3002\u7814\u7a76\u5de5\u4f5c\u6d89\u53ca\u5438\u9644\u5206\u79bb\u5bfc\u5411\u7684\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\uff08PAFs\uff09\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u5148\u8fdb\u529f\u80fd\u5e94\u7528\uff0c\u591a\u5b54\u652f\u6491\u819c\u7684\u5236\u5907\u53ca\u5176\u6c14\u4f53\u5206\u79bb\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\u4ee5\u53ca\u7eb3\u7c73\u5b54\u6750\u6599\u836f\u7269\u4f20\u8f93\u4f53\u7cfb\u7b49\u65b9\u9762\u7684\u7814\u7a76\u3002\u5728J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001Nat. Commun.\u3001Adv. Mater.<\/em>\u7b49\u56fd\u5185\u5916\u6742\u5fd7\u53d1\u8868\u7814\u7a76\u8bba\u6587390<\/strong>\u4f59\u7bc7\uff0cH-Index\u4e3a65<\/strong>\uff0c\u51fa\u7248\u82f1\u6587\u4e13\u84571<\/strong>\u90e8\uff0c\u83b7\u5f97\u56fd\u5185\u6388\u6743\u4e13\u522920<\/strong>\u4f59\u9879\u3002\u4e3b\u6301\u53c2\u4e0e\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff08\u5305\u62ec\u91cd\u70b9\u9879\u76ee\u3001\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u3001\u9762\u4e0a\u9879\u76ee\u3001\u56fd\u9645\u5408\u4f5c\u7b49\uff09\u3001\u7701\u90e8\u7ea7\u9879\u76ee\u7b4910<\/strong>\u9879\u4ee5\u53ca973\u9879\u76ee\u5b50\u8bfe\u98982<\/strong>\u9879\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u8fd1\u671f\u6587\u7ae0\uff1a<\/p>\n

1\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Ben, T.; Ren, H.; Ma, S.; Cao, D.; Lan, J.; Jing, X.; Wang, W.; Xu, J.; Deng, F.; Simmons, J. M. et al.<\/em>, Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area.Angew. Chem.Int. Ed.<\/em>2009<\/strong>, 48<\/em>, 9457-9460.<\/p>\n

2\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Yuan, Y.; Meng, Q. H.; Faheem, M.; Yang, Y. J.; Li, Z. N.; Wang, Z. Y.; Deng, D.; Sun, F. X.; He, H. M.; Huang, Y. H. et al.<\/em>, A Molecular Coordination Template Strategy for Designing Selective Porous Aromatic Framework Materials for Uranyl Capture.ACS Cent. Sci.<\/em> 2019<\/strong>, 5<\/em>, 1432-1439.<\/p>\n

3\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Song, J.; Li, Y.; Cao, P.; Jing, X. F.; Faheem, M.; Matsuo, Y.; Zhu, Y. L.; Tian, Y. Y.; Wang, X. H.; Zhu, G. S., Synergic Catalysts of Polyoxometalate@Cationic Porous Aromatic Frameworks: Reciprocal Modulation of Both Capture and Conversion Materials. Adv. Mater.<\/em>2019<\/strong>, 31<\/em>, 9.<\/p>\n

4\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Yu, G. L.; Zou, X. Q.; Sun, L.; Liu, B. S.; Wang, Z. Y.; Zhang, P. P.; Zhu, G. S., Constructing Connected Paths between UiO-66 and PIM-1 to Improve Membrane CO2<\/sub> Separation with Crystal-Like Gas Selectivity. Adv. Mater.<\/em>2019<\/strong>, 31<\/em>, 9.<\/p>\n

5\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Tian, Y. Y.; Song, J.; Zhu, Y. L.; Zhao, H. Y.; Muhammad, F.; Ma, T. T.; Chen, M.; Zhu, G. S., Understanding the desulphurization process in an ionic porous aromatic framework. Chem. Sci.<\/em>2019<\/strong>, 10<\/em>, 606-613.<\/p>\n

6\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Jiang, L. C.; Tian, Y. Y.; Sun, T.; Zhu, Y. L.; Ren, H.; Zou, X. Q.; Ma, Y. H.; Meihaus, K. R.; Long, J. R.; Zhu, G. S., A Crystalline Polyimide Porous Organic Framework for Selective Adsorption of Acetylene over Ethylene. J. Am. Chem. Soc.<\/em>2018<\/strong>, 140<\/em>, 15724-15730.<\/p>\n

7\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Li, M. P.; Ren, H.; Sun, F. X.; Tian, Y. Y.; Zhu, Y. L.; Li, J. L.; Mu, X.; Xu, J.; Deng, F.; Zhu, G. S., Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering. Adv. Mater.<\/em> 2018<\/strong>, 30<\/em>, 7.<\/p>\n

8\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Yuan, Y.; Yang, Y. J.; Faheem, M.; Zou, X. Q.; Ma, X. J.; Wang, Z. Y.; Meng, Q. H.; Wang, L. L.; Zhao, S.; Zhu, G. S., Molecularly Imprinted Porous Aromatic Frameworks Serving as Porous Artificial Enzymes. Adv. Mater.<\/em>2018<\/strong>, 30<\/em>, 9.<\/p>\n

9\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Yang, Y. J.; Faheem, M.; Wang, L. L.; Meng, Q. H.; Sha, H. Y.; Yang, N.; Yuan, Y.; Zhu, G. S., Surface Pore Engineering of Covalent Organic Frameworks for Ammonia Capture through Synergistic Multivariate and Open Metal Site Approaches. ACS Cent. Sci.<\/em>2018<\/strong>, 4<\/em>, 748-754.<\/p>\n

10\u00a0\u00a0\u00a0\u00a0 Jing, L. P.; Sun, J. S.; Sun, F. X.; Chen, P.; Zhu, G. S., Porous aromatic framework with mesopores as a platform for a super-efficient heterogeneous Pd-based organometallic catalysis. Chem. Sci.<\/em> 2018<\/strong>, 9<\/em>, 3523-3530.<\/p>\n

11\u00a0\u00a0\u00a0\u00a0 Zou, X. Q.; Zhu, G. S., Microporous Organic Materials for Membrane-Based Gas Separation. Adv. Mater.<\/em> 2018<\/strong>, 30<\/em>, 13.<\/p>\n

12\u00a0\u00a0\u00a0\u00a0 Yuan, Y.; Cui, P.; Tian, Y. Y.; Zou, X. Q.; Zhou, Y. X.; Sun, F. X.; Zhu, G. S., Coupling fullerene into porous aromatic frameworks for gas selective sorption. Chem. Sci.<\/em> 2016<\/strong>, 7<\/em>, 3751-3756.<\/p>\n

13\u00a0\u00a0\u00a0\u00a0 Yan, Z. J.; Yuan, Y.; Tian, Y. Y.; Zhang, D. M.; Zhu, G. S., Highly Efficient Enrichment of Volatile Iodine by Charged Porous Aromatic Frameworks with Three Sorption Sites. Angew. Chem.Int. Ed.<\/em>2015<\/strong>, 54<\/em>, 12733-12737.<\/p>\n

14\u00a0\u00a0\u00a0\u00a0 Ye, Y.; Yajie, Y.; Xujiao, M.; Qinghao, M.; Lili, W.; Shuai, Z.; Guangshan, Z., Molecularly Imprinted Porous Aromatic Frameworks and Their Composite Components for Selective Extraction of Uranium Ions. Adv. Mater.<\/em>2018<\/strong>, 30<\/em>, 1706507.<\/p>\n

15\u00a0\u00a0\u00a0\u00a0 Gao, X.; Zou, X.; Ma, H.; Meng, S.; Zhu, G., Highly Selective and Permeable Porous Organic Framework Membrane for CO2 Capture. Adv. Mater.<\/em> 2014<\/strong>, 26<\/em>, 3644-3648.<\/p>\n

16\u00a0\u00a0\u00a0\u00a0 Yuan, Y.; Sun, F.; Li, L.; Cui, P.; Zhu, G., Porous aromatic frameworks with anion-templated pore apertures serving as polymeric sieves. Nat. Commun.<\/em>2014<\/strong>, 5<\/em>, 4260.<\/p>\n

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