{"id":199500,"date":"2020-04-09T06:30:20","date_gmt":"2020-04-08T22:30:20","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=199500"},"modified":"2020-04-08T20:31:24","modified_gmt":"2020-04-08T12:31:24","slug":"%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6%e9%99%88%e5%a1%ab%e7%83%bd%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e5%9c%a8%e7%ba%b3%e7%b1%b3%e8%8d%af%e7%89%a9%e6%b2%bb%e7%96%97%e7%bc%ba%e8%a1%80%e6%80%a7%e8%84%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=199500","title":{"rendered":"\u66a8\u5357\u5927\u5b66\u9648\u586b\u70fd\u6559\u6388\u56e2\u961f\u5728\u7eb3\u7c73\u836f\u7269\u6cbb\u7597\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u5e94\u7528\u4e0a\u53d6\u5f97\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u7531\u4e8e\u5176\u81f4\u6b7b\u7387\u548c\u957f\u671f\u81f4\u6b8b\u7387\u4e0d\u65ad\u4e0a\u5347\uff0c\u5df2\u7ecf\u6210\u4e3a\u5a01\u80c1\u4eba\u7c7b\u5065\u5eb7\u7684\u4e3b\u8981\u75be\u75c5\u3002\u8fd1\u5e74\u6765\uff0c\u5c3d\u7ba1\u9759\u8109\u6eb6\u6813\u4e0e\u8840\u7ba1\u5185\u6cbb\u7597\u5df2\u7ecf\u5728\u4e34\u5e8a\u4e0a\u5e94\u7528\u975e\u5e38\u5e7f\u6cdb\uff0c\u4f46\u662f\u5728\u8840\u6813\u88ab\u53d6\u51fa\u6216\u6eb6\u89e3\u540e\uff0c\u8111\u7f3a\u8840\u90e8\u4f4d\u6062\u590d\u8840\u6d41\u4f9b\u5e94\uff0c\u4f1a\u5bfc\u81f4\u8d85\u6c27\u9634\u79bb\u5b50(\u00b7O2<\/sup>\u2212<\/sup>)\u3001\u8fc7\u6c27\u5316\u6c22(H2<\/sub>O2<\/sub>)\u548c\u7f9f\u81ea\u7531\u57fa(\u00b7OH)\u7b49\u6d3b\u6027\u6c27(ROS)\u7684\u8fc7\u5ea6\u4ea7\u751f\uff0c\u7ee7\u800c\u5f15\u8d77\u8111\u8840\u7ba1\u7cfb\u7edf\u548c\u795e\u7ecf\u7f51\u7edc\u7684\u7ee7\u53d1\u6027\u635f\u4f24\uff0c\u5373\u7f3a\u8840\u518d\u704c\u6ce8\u635f\u4f24\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u548c\u5f00\u53d1\u5177\u6709\u9ad8\u6548\u6297\u6c27\u5316\u6d3b\u6027\u548c\u751f\u7269\u76f8\u5bb9\u6027\u836f\u7269\u6765\u6cbb\u7597\u7f3a\u8840\u6027\u5352\u4e2d\u518d\u704c\u6ce8\u5f15\u8d77\u7684\u7ee7\u53d1\u6027\u635f\u4f24\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u66a8\u5357\u5927\u5b66\u9648\u586b\u70fd\u6559\u6388\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u7eb3\u7c73\u5316\u5b66\u521b\u65b0\u836f\u7269\u7684\u529f\u80fd\u5316\u8bbe\u8ba1\u4e0e\u75be\u75c5\u8bca\u7597\u7684\u5e94\u7528\u7814\u7a76\u3002\u9488\u5bf9\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u518d\u704c\u6ce8\u5f15\u8d77\u7684\u6c27\u5316\u635f\u4f24\uff0c\u8be5\u56e2\u961f\u5728\u5177\u6709\u6297\u6c27\u5316\u6d3b\u6027\u7684\u4e8c\u6c27\u5316\u94c8\uff08CeO2<\/sub>\uff09\u7684\u8868\u9762\u201c\u539f\u4f4d\u5408\u6210\u201d\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08ZIF-8\uff09\u5f97\u5230CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\uff0c\u5b9e\u73b0\u589e\u5f3a\u590d\u5408\u7eb3\u7c73\u7c92\u5b50\u7684\u50ac\u5316\u548c\u6297\u6c27\u5316\u6d3b\u6027\u3002ZIF-8\u5c01\u88c5\u53ef\u4ee5\u63a7\u5236CeO2<\/sub>\u6838\u7684\u5927\u5c0f\u548c\u8868\u9762\u7535\u8377\uff0c\u7f13\u6162\u66b4\u9732CeO2<\/sub>\u6d3b\u6027\u6210\u5206\uff0c\u5ef6\u957f\u5176\u8840\u6db2\u5faa\u73af\u65f6\u95f4\uff0c\u964d\u4f4e\u6e05\u9664\u7387\uff0c\u589e\u5f3aBBB\u7a7f\u900f\u80fd\u529b\uff0c\u63d0\u9ad8\u751f\u7269\u5229\u7528\u7387\u3002\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u7eb3\u7c73\u7cfb\u7edf\u80fd\u6709\u6548\u6291\u5236\u5927\u8111\u52a8\u8109\u95ed\u585e(MCAO)\u5c0f\u9f20\u8111\u7ec4\u7ec7\u8102\u8d28\u8fc7\u6c27\u5316\uff0c\u51cf\u5c11\u8111\u7ec4\u7ec7\u795e\u7ecf\u5143\u7684\u6c27\u5316\u635f\u4f24\u548c\u51cb\u4ea1\u3002\u6709\u8da3\u7684\u662f\uff0cCeO2<\/sub>@ZIF-8\u8fd8\u901a\u8fc7\u6291\u5236\u661f\u5f62\u80f6\u8d28\u7ec6\u80de\u7684\u6fc0\u6d3b\u548c\u4fc3\u708e\u7ec6\u80de\u56e0\u5b50\u7684\u5206\u6ccc\u6765\u6291\u5236\u708e\u75c7\u548c\u514d\u75ab\u53cd\u5e94\u5f15\u8d77\u7684\u635f\u4f24\uff0c\u4ece\u800c\u5728\u7f3a\u8840\u6027\u5352\u4e2d\u7684\u795e\u7ecf\u4fdd\u62a4\u6cbb\u7597\u4e2d\u5b9e\u73b0\u4e86\u4ee4\u4eba\u6ee1\u610f\u7684\u9884\u9632\u548c\u6cbb\u7597\uff0c\u5e76\u4e14\u5177\u6709\u5f88\u9ad8\u7684\u5b89\u5168\u6027\u3002<\/p>\n

\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cHighly bioactive zeolitic imidazolate framework-8-capped nanotherapeutics for efficient reversal of reperfusion-induced injury in ischemic stroke\u201d\u7684\u7814\u7a76\u8bba\u6587\u53d1\u8868\u5728Science Advances<\/em>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u7ed3\u6784\u5206\u6790<\/p>\n

\"\"<\/p>\n

(A<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u6750\u6599\u6cbb\u7597\u7f3a\u8840\u6027\u5352\u4e2d\u518d\u704c\u6ce8\u5f15\u8d77\u7684\u7ee7\u53d1\u6027\u635f\u4f24\u53ca\u4f5c\u7528\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

(B<\/strong>, C<\/strong>, D<\/strong>, E<\/strong>) CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8 \u7684SEM\uff0cTEM\u548c\u5143\u7d20\u5206\u6790\u3002<\/p>\n

(F<\/strong>, G<\/strong>, H<\/strong>) CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8\u7684XRD\uff0cUV-Vis\uff0cRaman\u5149\u8c31\u5206\u6790\u3002<\/p>\n

(I<\/strong>, J<\/strong>, H<\/strong>) CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8 \u7684XPS\u5206\u6790\u4e0eZn 2p\u548cCe 3d\u7cbe\u7ec6\u8c31\u56fe\u3002<\/p>\n

\u56fe2\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u4f53\u5916\u6e05\u9664ROS\u80fd\u529b\u68c0\u6d4b<\/p>\n

\"\"<\/p>\n

(A<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u7c92\u5b50\u4f53\u5916\u6e05\u9664ROS\u793a\u610f\u56fe\u3002<\/p>\n

(B<\/strong>) ABTS\u6cd5\u68c0\u6d4bCeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8 \u4e09\u8005\u603b\u6e05\u9664\u81ea\u7531\u57fa\u80fd\u529b\u3002<\/p>\n

(C<\/strong>) \u539f\u4f4d\u62c9\u66fc\u68c0\u6d4bCeO2<\/sub>@ZIF-8 \u5faa\u73af\u6e05\u9664\u8fc7\u6c27\u5316\u6c22\uff08H2<\/sub>O2<\/sub>\uff09\u80fd\u529b\u3002<\/p>\n

(D<\/strong>) 5%\u8fc7\u6c27\u5316\u6c22\u6eb6\u6db2\u5206\u89e3CeO2<\/sub>@ZIF-8\u5916\u58f3\uff08ZIF-8\uff09 \u7684TEM\u56fe\u3002<\/p>\n

(E<\/strong>, F<\/strong>) EPR\u4e0e\u7d2b\u5916\u5149\u8c31\u5206\u6790CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8\u6e05\u9664\u7f9f\u81ea\u7531\u57fa\u80fd\u529b\u3002<\/p>\n

(G<\/strong>, H<\/strong>) EPR\u4e0e\u8367\u5149\u5149\u8c31\u5206\u6790CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8\u6e05\u9664\u8d85\u6c27\u9634\u79bb\u5b50\u81ea\u7531\u57fa\u80fd\u529b\u3002<\/p>\n

\u56fe3\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u901a\u8fc7\u6e05\u9664ROS\u51cf\u5c11\u8111\u7ec4\u7ec7\u795e\u7ecf\u7ec6\u80de\u7684\u6c27\u5316\u635f\u4f24\u548c\u51cb\u4ea1<\/p>\n

\"\"<\/p>\n

(A<\/strong>) CeO2<\/sub>, ZIF-8, CeO2<\/sub>@ZIF-8 \u9006\u8f6ct-BOOH\u5f15\u8d77\u795e\u7ecf\u7ec6\u80de\u6b7b\u4ea1\u3002<\/p>\n

(B<\/strong>, C<\/strong>) \u6d41\u5f0f\u7ec6\u80de\u4eea\u68c0\u6d4bCeO2<\/sub>@ZIF-8\u9006\u8f6ct-BOOH\u5f15\u8d77\u7684\u7ec6\u80de\u51cb\u4ea1\u3002<\/p>\n

(D<\/strong>) CeO2<\/sub>@ZIF-8 \u6e05\u9664t-BOOH\u5f15\u8d77\u7684\u7ec6\u80de\u5185\u8fc7\u91cfROS\u7d2f\u79ef\u3002<\/p>\n

(E<\/strong>) \u8367\u5149\u663e\u5fae\u955c\u4e0b\u89c2\u5bdfCeO2<\/sub>@ZIF-8\u9006\u8f6ct-BOOH\u5f15\u8d77\u7684\u7ec6\u80de\u5185\u7ebf\u7c92\u4f53\u65ad\u88c2\u3002<\/p>\n

(F<\/strong>, G<\/strong>, H<\/strong>) \u4f53\u5916\u68c0\u6d4bCeO2<\/sub>@ZIF-8\u7a7f\u900f\u8840\u8111\u5c4f\u969c\u3002<\/p>\n

\u56fe4\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u80de\u541e\u8fdb\u5165\u7ec6\u80de\u7684\u673a\u5236\u7814\u7a76<\/p>\n

\"\"<\/p>\n

(A<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u7684\u80de\u541e\u673a\u5236\u793a\u610f\u56fe\u3002<\/p>\n

(B<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u80de\u541e\u8fdb\u5165\u7ec6\u80de\u7684TEM\u56fe\u3002<\/p>\n

(C<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u5206\u522b\u5728\u2160\uff1a\u6c34\uff1b\u2161\uff1aPBS (pH=7.4)\uff1b\u2162\uff1aPBS ( pH=5.3) \u6eb6\u6db2\u4e2d\u7684TEM\u56fe\u3002<\/p>\n

(D<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u5728\u7ec6\u80de\u5185\u4e0e\u6eb6\u9176\u4f53\u5171\u5b9a\u4f4d\u8367\u5149\u7167\u7247\u3002<\/p>\n

(E<\/strong>) CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u5728\u7ec6\u80de\u5185\u7684\u5438\u6536\u60c5\u51b5\u3002<\/p>\n

(F<\/strong>, G<\/strong>) \u80de\u541e\u6291\u5236\u5242\u9a8c\u8bc1CeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u8fdb\u5165\u7ec6\u80de\u7684\u9014\u5f84\u3002<\/p>\n

\u56fe5\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u6291\u5236\u5927\u8111\u4e2d\u52a8\u8109\u95ed\u585e(MCAO)\u5c0f\u9f20\u8111\u7ec4\u7ec7\u8102\u8d28\u8fc7\u6c27\u5316<\/p>\n

\"\"<\/p>\n

(A<\/strong>, B<\/strong>, C<\/strong>) MCAO\u6a21\u578b\u5c0f\u9f20\u8111\u7ec4\u7ec7TTC\u67d3\u8272\u7167\u7247\u3001\u6897\u6b7b\u9762\u79ef\u5206\u6790\u548c\u884c\u4e3a\u5b66\u5206\u6790\uff0c\u8bc4\u4ef7CeO2<\/sub>@ZIF-8\u51cf\u5c11\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u5f15\u8d77\u7684\u6897\u6b7b\u9762\u79ef\u6269\u5927\u3002<\/p>\n

(D<\/strong>) CeO2<\/sub>@ZIF-8\u7eb3\u7c73\u4f53\u7cfb\u5728\u8111\u7ec4\u7ec7\u7ec6\u80de\u4e2d\u7684TEM\u56fe\u3002<\/p>\n

(E<\/strong>, F<\/strong>) CeO2<\/sub>\u4e0eCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u7684\u836f\u4ee3\u52a8\u529b\u5b66\u5206\u6790\u4e0e\u810f\u5668\u5206\u5e03\u3002<\/p>\n

(G<\/strong>, H<\/strong>) CeO2<\/sub>@ZIF-8\u51cf\u5c11MCAO\u5c0f\u9f20\u8111\u7ec4\u7ec7\u635f\u4f24\u90e8\u4f4d\u7684\u8d85\u6c27\u9634\u79bb\u5b50\u548c\u8102\u8d28\u8fc7\u6c27\u5316\u4ee3\u8c22\u7269\u4e19\u4e8c\u919b\u3002<\/p>\n

(I<\/strong>, J<\/strong>) MCAO\u5c0f\u9f20\u8111\u7ec4\u7ec7\u635f\u4f24\u90e8\u4f4d\u8fc7\u6c27\u5316\u7269\u6b67\u5316\u9176\u548c\u8c37\u80f1\u7518\u80bd\u8fc7\u6c27\u5316\u7269\u9176\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe6\uff1aCeO2<\/sub>@ZIF-8\u590d\u5408\u7eb3\u7c73\u4f53\u7cfb\u6291\u5236\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u518d\u704c\u6ce8\u5f15\u8d77\u7684\u708e\u75c7\u635f\u4f24\u3002<\/p>\n

\"\"<\/p>\n

(A<\/strong>, B<\/strong>) MCAO\u5c0f\u9f20\u8111\u7ec4\u7ec7\u5207\u7247HE\u67d3\u8272\u4e0e\u5c3c\u6c0f\u67d3\u8272\u8bc4\u4f30CeO2<\/sub>@ZIF-8\u51cf\u5c11\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u5f15\u8d77\u7684\u635f\u4f24\u3002<\/p>\n

(C<\/strong>) \u8111\u7ec4\u7ec7\u5207\u7247TUNEL\u4e0eHoechst\u53cc\u67d3\u8bc4\u4f30CeO2<\/sub>@ZIF-8\u51cf\u5c11\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u5f15\u8d77\u7684\u795e\u7ecf\u7ec6\u80de\u51cb\u4ea1\u3002<\/p>\n

(D<\/strong>, E<\/strong>, F<\/strong>) CeO2<\/sub>@ZIF-8\u964d\u4f4eGFAP\uff08\u661f\u5f62\u80f6\u8d28\u7ec6\u80de\u7684\u6807\u5fd7\u7269\uff09\u4e0eIba-1\uff08\u5c0f\u80f6\u8d28\u7ec6\u80de\u7684\u6807\u5fd7\u7269\uff09\u5728\u8111\u7ec4\u7ec7\u635f\u4f24\u90e8\u4f4d\u7684\u8868\u8fbe\u3002<\/p>\n

(G<\/strong>, H<\/strong>, I<\/strong>) CeO2<\/sub>@ZIF-8\u964d\u4f4e\u8111\u7ec4\u7ec7\u635f\u4f24\u90e8\u4f4d\u708e\u75c7\u76f8\u5173\u7ec6\u80de\u56e0\u5b50\u7684\u8868\u8fbe\u3002<\/p>\n

\u5c0f\u7ed3\uff1a<\/strong><\/p>\n

\u603b\u800c\u8a00\u4e4b\uff0c\u8be5\u7814\u7a76\u5c06\u591a\u79cd\u7eb3\u7c73\u7ea7\u522b\u7684\u6297\u6c27\u5316\u7eb3\u7c73\u7c92\u5b50\uff0c\u901a\u8fc7\u5316\u5b66\u7ed3\u5408\uff0c\u83b7\u5f97\u5177\u6709\u66f4\u52a0\u4f18\u5f02\u7684\u6297\u6c27\u5316\u6d3b\u6027\u7684\u65b0\u578b\u590d\u5408\u7eb3\u7c73\u836f\u7269\uff0c\u51cf\u5c11\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u518d\u704c\u6ce8\u635f\u4f24\uff0c\u4e3a\u7f3a\u8840\u6027\u8111\u5352\u4e2d\u6cbb\u7597\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u8bba\u6587\u94fe\u63a5\uff1ahttps:\/\/advances.sciencemag.org\/content\/6\/12\/eaay9751<\/a><\/p>\n

\u00a0<\/strong>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a<\/strong><\/p>\n

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