{"id":199817,"date":"2020-04-14T06:16:46","date_gmt":"2020-04-13T22:16:46","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=199817"},"modified":"2020-04-13T19:17:48","modified_gmt":"2020-04-13T11:17:48","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e5%88%98%e6%b0%b8%e8%83%9c%e5%9b%a2%e9%98%9facs-nano-17-25%ef%bc%85%e6%95%88%e7%8e%87%ef%bc%81%e5%9f%ba%e4%ba%8e%e8%90%98%e3%80%81%e8%92%bd%e8%83%ba%e7%9a%842d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=199817","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u5218\u6c38\u80dc\u56e2\u961fACS Nano: 17.25\uff05\u6548\u7387\uff01\u57fa\u4e8e\u8418\u3001\u84bd\u80fa\u76842D\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5218\u6c38\u80dc<\/strong>\u6559\u6388\u56e2\u961f\u5f00\u53d1\u4e86\u4e24\u79cd\u591a\u73af\u82b3\u9999\u65cf\u80fa\u95f4\u9694\u9633\u79bb\u5b50\uff0c\u53731-<\/strong>\u8418\u7532\u80fa\u9633\u79bb\u5b50\uff08<\/strong>NpMA<\/strong>\uff09<\/strong>\u548c9-<\/strong>\u84bd\u7532\u80fa\u9633\u79bb\u5b50\uff08<\/strong>AnMA<\/strong>\uff09<\/strong>\uff0c\u5236\u5907\u4e86\u9ad8\u6548\u7387\u4e14\u9ad8\u7a33\u5b9a\u6027\u7684\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u3002\u7814\u7a76\u53d1\u73b0\u5728\u9499\u949b\u77ff\u8584\u819c\u4e2d\uff0c\u4e0d\u540c\u7684\u5c42\u72b6\u4e8c\u7ef4\u76f8\u548c\u4e09\u7ef4\u76f8\u5171\u5b58\u3002\u901a\u8fc7\u6838\u78c1\u5171\u632f\u6c22\u8c31\u5206\u6790\uff0c\u7814\u7a76\u4eba\u5458\u8bc1\u5b9e\u4e86\u6709\u673a\u95f4\u9694\u9633\u79bb\u5b50\u4e0e\u65e0\u673a\u5c42\u4e4b\u95f4\u5b58\u5728\u5f3a\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u3002\u901a\u8fc7\u5bf9\u9499\u949b\u77ff\u4e2d\u7684\u76f8\u5206\u5e03\u548c\u6676\u4f53\u53d6\u5411\u7684\u7814\u7a76\u6709\u52a9\u4e8e\u6df1\u523b\u7406\u89e3\u591a\u73af\u82b3\u9999\u65cf\u80fa\uff08NpMA\u548cAnMA\uff09\u5bf9\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u4f7f\u7528\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548c\u8d85\u5feb\u901f\u77ac\u6001\u5438\u6536\u5149\u8c31\u6765\u7814\u7a76\u4e8c\u7ef4\u9499\u949b\u77ff\u7684\u76f8\u5206\u5e03\u548c\u7535\u8377\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\uff0c\u4e8c\u7ef4\u76f8\u548c\u4e09\u7ef4\u76f8\u4e4b\u95f4\u7684\u8d85\u5feb\u6fc0\u5b50\u8fc1\u79fb\u8fc7\u7a0b\u53ef\u4ee5\u5b9e\u73b0\u6709\u6548\u7684\u6fc0\u5b50\u5206\u79bb\uff0c\u7535\u8377\u4f20\u8f93\u548c\u6536\u96c6\u3002\u7ecf\u8fc7\u4f18\u5316\uff0c\u57fa\u4e8eNpMA-Pb\u7684\u5668\u4ef6\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe17.25\uff05\uff0c\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u4e8c\u7ef4<\/strong> RP<\/strong>\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong>(n < 5)<\/strong>\u7684\u6700\u9ad8\u6548\u7387\u4e4b\u4e00<\/strong>\uff1b\u83b7\u5f971.24 V\u7684\u9ad8\u5f00\u8def\u7535\u538b\uff0c\u662f\u76ee\u524d\u57fa\u4e8e<\/strong>PEDOT<\/strong>\uff1a<\/strong>PSS<\/strong>\u7684\u53cd\u5f0f\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6700\u9ad8\u503c<\/strong>\u3002\u57fa\u4e8eAnMA-Pb\u7684\u5668\u4ef6\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u4e3a14.47%\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u591a\u73af\u82b3\u9999\u65cf\u80fa\u95f4\u9694\u9633\u79bb\u5b50\u7684\u4f18\u5f02\u758f\u6c34\u6027\u4ee5\u53ca\u6709\u673a\u95f4\u9694\u57fa\u9633\u79bb\u5b50\uff08NpMA\u548cAnMA\uff09\u4e0e\u65e0\u673a\u5c42\u4e4b\u95f4\u7684\u5f3a\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u4e0e\u4e09\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u76f8\u6bd4\uff0c\u4e8c\u7ef4RP \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u663e\u793a\u51fa\u663e\u8457\u589e\u5f3a\u7684\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u6210\u679c\u8fd1\u671f\u4ee5\u201cPhase Distribution and Carrier Dynamics in Multiple-Ring Aromatic Spacers-Based Two-Dimensional Ruddlesden-Popper Perovskite Solar Cells\u201d\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aACS Nano\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u57fa\u4e8eNpMA\u548cAnMA\u7684\u4e8c\u7ef4\u9499\u949b\u77ff\u7684\u5316\u5b66\u7ed3\u6784\u3001\u5149\u7269\u7406\u4ee5\u53ca\u5f62\u8c8c\u7279\u5f81\u3002<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

\u56fe3. NpMA-Pb\u548cAnMA-Pb\u7684\u6676\u4f53\u53d6\u5411\u6027\u548c\u76f8\u5206\u5e03\u7279\u5f81\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. NpMA-Pb\u548cAnMA-Pb\u7684\u7535\u8377\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5. \u4e8c\u7ef4\u9499\u949b\u77ff\u6fc0\u5b50\u8fc1\u79fb\u52a8\u529b\u5b66\u793a\u610f\u56fe<\/p>\n

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\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u5f00\u53d1\u4e86\u4e24\u79cd\u7528\u4e8e\u4e8c\u7ef4RP\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u591a\u73af\u82b3\u9999\u65cf\u80fa\u95f4\u9694\u9633\u79bb\u5b50(NpMA\u548cAnMA)\uff0c\u5e76\u5236\u5907\u4e86\u9ad8\u6548\u7a33\u5b9a\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3002\u7531\u4e8e\u4e8c\u7ef4\u76f8\u548c\u4e09\u7ef4\u76f8\u4e4b\u95f4\u7684\u8d85\u5feb\u6fc0\u5b50\u8fc1\u79fb\u8fc7\u7a0b\uff0c\u57fa\u4e8e(NpMA)2<\/sub>(MA)n-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff08n=4\uff09\u7684\u5668\u4ef6\u663e\u793a\u51fa1.24 V\u7684\u9ad8\u5f00\u8def\u7535\u538b\uff0c\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe17.25\uff05\uff1b\u57fa\u4e8e(AnMA)2<\/sub>(MA)n-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff08n=4\uff09\u7684\u5668\u4ef6\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u4e3a14.47%\u3002\u540c\u65f6\uff0c\u4e0e\u4e09\u7ef4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u76f8\u6bd4\uff0c\u4e8c\u7ef4RP \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u663e\u793a\u51fa\u663e\u8457\u589e\u5f3a\u7684\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u6709\u52a9\u4e8e\u6df1\u5165\u7406\u89e3\u4e8c\u7ef4RP\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5de5\u4f5c\u673a\u5236\uff0c\u5e76\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\u63d0\u4f9b\u6709\u6548\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Phase Distribution and Carrier Dynamics in Multiple-Ring Aromatic Spacers-Based Two-Dimensional Ruddlesden-Popper Perovskite Solar Cells <\/strong>\uff08<\/strong>ACS Nano, 2020, <\/strong>https:\/\/doi.org\/10.1021\/acsnano.0c00875<\/strong><\/a>\uff09<\/strong><\/p>\n

\u672c\u6587\u7531eric<\/strong>\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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