{"id":200153,"date":"2020-05-04T06:54:04","date_gmt":"2020-05-03T22:54:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=200153"},"modified":"2020-05-03T21:54:11","modified_gmt":"2020-05-03T13:54:11","slug":"%e5%8d%95%e5%8e%9f%e5%ad%90%e6%9d%90%e6%96%99%e5%8f%af%e4%bb%a5%e5%b9%b2%e5%95%a5%ef%bc%9f%e4%bd%a0%e5%80%bc%e5%be%97%e6%8b%a5%e6%9c%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=200153","title":{"rendered":"\u5355\u539f\u5b50\u6750\u6599\u53ef\u4ee5\u5e72\u5565\uff1f\u4f60\u503c\u5f97\u62e5\u6709"},"content":{"rendered":"

\u5355\u539f\u5b50\u50ac\u5316\u5242\u662f\u8d1f\u8f7d\u578b\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7406\u60f3\u72b6\u6001\uff0c\u5b9e\u73b0\u4e86\u91d1\u5c5e\u4ee5\u5355\u539f\u5b50\u7684\u5f62\u5f0f\u5747\u5300\u5206\u5e03\u5728\u8f7d\u4f53\u4e0a\u3002\u5747\u4e00\u5206\u6563\u7684\u5355\u539f\u5b50\u4f5c\u4e3a\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u4e0e\u5747\u76f8\u50ac\u5316\u7c7b\u4f3c\uff0c\u5b9e\u73b0\u4e86\u50ac\u5316\u53cd\u5e94\u7684\u9ad8\u6d3b\u6027\u548c\u9ad8\u9009\u62e9\u6027\uff0c\u540c\u65f6\u4e5f\u4e3a\u50ac\u5316\u5242\u673a\u7406\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002\u672c\u6587\u603b\u7ed3\u4e86\u79d1\u7814\u754c\u5b66\u672f\u5927\u725b\u5728\u5355\u539f\u5b50\u6750\u6599\u9886\u57df\u7684\u6700\u65b0\u6210\u679c\uff0c\u5e0c\u671b\u5bf9\u4ece\u4e8b\u5355\u539f\u5b50\u6750\u6599\u76f8\u5173\u9886\u57df\u7684\u4f60\u6709\u6240\u542f\u53d1\u3002<\/p>\n

\u674e\u4e9a\u680b\uff08\u6e05\u534e\u5927\u5b66\uff09<\/b><\/strong><\/p>\n

1. J. Am. Chem. Soc.\u8c03\u6574\u5355\u539f\u5b50\u50ac\u5316\u5242\u4e2d\u7684\u914d\u4f4d\u73af\u5883\u5b9e\u73b0\u9ad8\u6548\u7684\u6c27\u8fd8\u539f\u53cd\u5e94<\/b><\/strong><\/p>\n

\u5f00\u53d1\u7528\u4e8e\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u7684\u539f\u5b50\u5206\u6563\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u5b9e\u73b0\u6709\u6548\u80fd\u91cf\u8f6c\u6362\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u8bfe\u9898\u7ec4\u4e0e\u4ed6\u4eba\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cd\u6a21\u677f\u8f85\u52a9\u6cd5\u6765\u5408\u6210\u4e00\u7cfb\u5217\u951a\u5b9a\u5728\u591a\u5b54N\uff0cS\u63ba\u6742\u78b3\uff08NSC\uff09\u57fa\u8d28\u4e0a\u7684\u5355\u4e2a\u91d1\u5c5e\u539f\u5b50\u7528\u4e8e\u9ad8\u6548\u7684ORR\u50ac\u5316\u5242\u5e76\u7814\u7a76\u7ed3\u6784\u4e0e\u5176\u50ac\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u3002\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0c\u7531\u4e8e\u6bcf\u79cd\u91d1\u5c5e\u79bb\u5b50\u5728\u521d\u59cb\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e0e\u542bN\uff0cS\u7684\u524d\u4f53\u5f62\u6210\u7edc\u5408\u7269\u7684\u8d8b\u52bf\u4e0d\u540c\uff0c\u76f8\u540c\u7684\u5408\u6210\u65b9\u6cd5\u4f1a\u5bfc\u81f4\u4ee5Fe\u4e3a\u4e2d\u5fc3\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Fe-SAs \/ NSC\uff09\u548c\u4ee5Co\u00a0\/ Ni\u4e3a\u4e2d\u5fc3\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Co-SAs \/ NSC\u548cNi- SAs \/ NSC\uff09\u6709\u6240\u4e0d\u540c\u3002Fe-SAs \/ NSC\u4e3b\u8981\u7531\u5206\u6563\u826f\u597d\u7684FeN4<\/sub>S2\u4e2d\u5fc3\u4f4d\u70b9\u7ec4\u6210\uff0c\u5176\u4e2dS\u539f\u5b50\u4e0eN\u539f\u5b50\u5f62\u6210\u952e\u3002\u53e6\u4e00\u65b9\u9762\uff0cCo-SAs \/ NSC\u548cNi-SAs \/ NSC\u4e2d\u7684S\u539f\u5b50\u5f62\u6210\u91d1\u5c5e-S\u952e\uff0c\u4ece\u800c\u5f62\u6210CoN3<\/sub>S1<\/sub>\u548cNiN3<\/sub>S1<\/sub>\u4e2d\u5fc3\u4f4d\u70b9\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7ed3\u679c\u8868\u660e\uff0c\u7531\u4e8e\u8f83\u9ad8\u7684\u7535\u8377\u5bc6\u5ea6\u3001\u8f83\u4f4e\u7684\u4e2d\u95f4\u4f53\u80fd\u5792\u548c\u6d89\u53ca\u7684\u4ea7\u7269\uff0cFeN4<\/sub>S2<\/sub>\u4e2d\u5fc3\u4f4d\u70b9\u6bd4CoN3<\/sub>S1<\/sub>\u548cNiN3<\/sub>S1<\/sub>\u4f4d\u70b9\u66f4\u5177\u6d3b\u6027\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u6240\u6709\u4e09\u79cd\u5355\u539f\u5b50\u50ac\u5316\u5242\u90fd\u53ef\u4ee5\u53d1\u6325\u9ad8ORR\u7535\u5316\u5b66\u6027\u80fd\uff0c\u800cFe-SAs \/ NSC\u8868\u73b0\u51fa\u6700\u9ad8\u7684\u6027\u80fd\uff0c\u751a\u81f3\u4f18\u4e8e\u5546\u4e1a\u5316\u7684Pt \/ C\u3002\u4e0e\u5e02\u552ePt \/ C\u76f8\u6bd4\uff0cFe-SAs \/ NSC\u8fd8\u663e\u793a\u51fa\u8f83\u9ad8\u7684\u7532\u9187\u8010\u53d7\u6027\uff0c\u5e76\u5177\u6709\u9ad8\u8fbe5000\u6b21\u5faa\u73af\u7684\u9ad8\u7a33\u5b9a\u6027\u3002\u8be5\u9879\u5de5\u4f5c\u4e3a\u5408\u7406\u8bbe\u8ba1\u5177\u6709\u53ef\u8c03\u7535\u50ac\u5316\u6d3b\u6027\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u6700\u7ec8\u7ed3\u6784\u63d0\u4f9b\u4e86\u89c1\u89e3\uff0c\u4ee5\u5b9e\u73b0\u6709\u6548\u7684\u80fd\u91cf\u8f6c\u6362\u3002[1]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cTuning the Coordination Environment in Single-Atom Catalysts to\u00a0Achieve Highly Efficient Oxygen Reduction Reactions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u4e00\uff1a\u5355\u539f\u5b50\u50ac\u5316\u5242\u5236\u5907\u793a\u610f\u56fe\u53ca\u8868\u5f81\u56fe<\/b><\/strong><\/p>\n

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2. Energy Environ. Sci.\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\u589e\u5f3a\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u539f\u5b50\u754c\u9762\u6548\u5e94<\/b><\/strong><\/p>\n

\u6c27\u6c14\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u4e2d\u50ac\u5316\u6d3b\u6027\u7684\u8c03\u8282\u5bf9\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u548c\u5176\u4ed6\u6d89\u53ca\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\u7684\u5f00\u53d1\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u8bfe\u9898\u7ec4\u4e0e\u4ed6\u4eba\u5408\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u539f\u5b50\u754c\u9762\u7b56\u7565\u6765\u6784\u5efa\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\uff08Cu-SA \/ SNC\uff09\uff0c\u8be5\u50ac\u5316\u5242\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u663e\u793a\u51fa\u589e\u5f3a\u7684ORR\u6d3b\u6027\uff0c\u76f8\u5bf9\u4e8eRHE\u7684\u534a\u6ce2\u7535\u52bf\u4e3a0.893V\u3002\u57fa\u4e8e\u540c\u6b65\u8f90\u5c04\u7684X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u7814\u7a76\u4ee5\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5b64\u7acb\u7684\u952e\u6536\u7f29\u4f4e\u4ef7Cu(+1)-N4<\/sub>-C8<\/sub>S2<\/sub>\u539f\u5b50\u754c\u9762\u90e8\u5206\u53ef\u4f5c\u4e3a\u5728ORR\u8fc7\u7a0b\u4e2d\u662f\u4e00\u4e2a\u6d3b\u6027\u4f4d\u70b9\uff0c\u800c\u94dc\u539f\u5b50\u4e0e\u78b3\u57fa\u4f53\u5728\u539f\u5b50\u754c\u9762\u5904\u7684\u534f\u540c\u673a\u5236\u901a\u8fc7\u8c03\u8282\u4e2d\u95f4\u5438\u9644\u7684\u53cd\u5e94\u81ea\u7531\u80fd\uff0c\u5728\u63d0\u9ad8ORR\u6548\u7387\u65b9\u9762\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u8be5\u539f\u5b50\u754c\u9762\u6982\u5ff5\u53ef\u4ee5\u4e3a\u5408\u7406\u8bbe\u8ba1\u5148\u8fdb\u7684\u6c27\u7535\u6781\u6750\u6599\u63d0\u4f9b\u65b0\u7684\u65b9\u6cd5\uff0c\u5e76\u4e3a\u63d0\u9ad8\u5176\u50ac\u5316\u6027\u80fd\u63d0\u4f9b\u65b0\u7684\u53ef\u80fd\u6027\u3002[2]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cAtomic interface effect of a single atom copper\u00a0catalyst for enhanced oxygen reduction reactions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Energy Environ. Sci.\u3002<\/p>\n

\u56fe\u4e8c\uff1a\u5355\u539f\u5b50\u94dc\u50ac\u5316\u5242\u8868\u5f81\u56fe\u53caORR\u6d3b\u6027<\/b><\/strong><\/p>\n

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3. Angew. Chem. Int. Ed.\u5355\u4e2a\u94c2\u539f\u5b50\u8bbe\u8ba1\u539f\u5b50\u754c\u9762\u589e\u5f3a\u5149\u50ac\u5316\u4ea7\u6c22<\/b><\/strong><\/p>\n

\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u4f18\u5316\u5149\u50ac\u5316\u5242\u7684\u7ed3\u6784\u4ee5\u4fc3\u8fdb\u7535\u5b50-\u7a7a\u7a74\u5bf9\u7684\u5206\u79bb\u4ee5\u63d0\u9ad8\u6027\u80fd\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u8bfe\u9898\u7ec4\u4e0e\u4ed6\u4eba\u5408\u4f5c\u901a\u8fc7\u5728\u6709\u7f3a\u9677\u7684TiO2<\/sub>\u8f7d\u4f53\u4e0a\u7ec4\u88c5\u5355\u4e2aPt\u539f\u5b50\u6765\u5f62\u6210\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5242\uff08Pt1<\/sub>\u00a0\/ def-TiO2<\/sub>\uff09\u3002\u9664\u4e86\u662f\u8d28\u5b50\u8fd8\u539f\u4f4d\u70b9\u4ee5\u5916\uff0c\u5355\u4e2aPt\u539f\u5b50\u8fd8\u4fc3\u8fdb\u76f8\u90bb\u7684TiO2<\/sub>\u5355\u5143\u751f\u6210\u8868\u9762\u6c27\u7a7a\u4f4d\u5e76\u5f62\u6210Pt-O-Ti3+<\/sup>\u539f\u5b50\u754c\u9762\u3002 \u5b9e\u9a8c\u7ed3\u679c\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cPt-O-Ti3+<\/sup>\u539f\u5b50\u754c\u9762\u6709\u6548\u5730\u4fc3\u8fdb\u4e86\u5149\u751f\u7535\u5b50\u4eceTi3+<\/sup>\u7f3a\u9677\u4f4d\u70b9\u8f6c\u79fb\u5230\u5355\u4e2aPt\u539f\u5b50\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u7535\u5b50-\u7a7a\u7a74\u5bf9\u7684\u5206\u79bb\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u7ed3\u6784\u4f7fPt1<\/sub>\u00a0\/ def-TiO2<\/sub>\u8868\u73b0\u51fa\u521b\u7eaa\u5f55\u6c34\u5e73\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\uff0c\u5176\u9ad8\u5468\u8f6c\u9891\u7387\u4e3a51423 h-1<\/sup>\uff0c\u6bd4Pt\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u7684TiO2<\/sub>\u50ac\u5316\u5242\u9ad8\u51fa591\u500d\u3002[3]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cEngineering the Atomic Interface with Single Platinum Atoms for\u00a0Enhanced Photocatalytic Hydrogen Production\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u3002<\/p>\n

\u56fe\u4e09\uff1aPt<\/b><\/strong>1<\/b><\/sub><\/strong>\u00a0\/ def-TiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5236\u5907\u793a\u610f\u56fe\u53ca\u8868\u5f81\u56fe<\/b><\/strong><\/p>\n

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4. Sci<\/b><\/strong>. <\/b><\/strong>China Chem<\/b><\/strong>.<\/b><\/strong>,<\/b><\/strong>\u5355\u539f\u5b50\u7535\u50ac\u5316\uff1a\u4f53\u5185\u7535\u5316\u5b66\u751f\u7269\u4f20\u611f\u7684\u65b0\u65b9\u6cd5<\/b><\/strong><\/p>\n

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\u56fe\u56db\uff1aCo\u5355\u539f\u5b50\u50ac\u5316\u5242\u8868\u5f81\u56fe<\/b><\/strong><\/p>\n

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5. Chem \u7a7a\u5fc3CuS<\/b><\/strong>x<\/b><\/sub><\/strong>\u4e0a\u7684\u9ad8\u6d53\u5ea6\u5355\u539f\u5b50Pt\u4f4d\u70b9\u7528\u4e8e\u9178\u6027\u6eb6\u6db2\u4e2d\u5c06O<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u4e3aH<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong><\/p>\n

\u7531\u4e8e\u7f3a\u4e4f\u9ad8\u9009\u62e9\u6027\u548c\u6d3b\u6027\u50ac\u5316\u5242\uff0c\u5f00\u53d1\u65b0\u578b\u6027\u80fd\u4f18\u826f\u7684\u50ac\u5316\u5242\u7528\u4e8e\u7535\u5316\u5b66\u76f4\u63a5\u5408\u6210\u8fc7\u6c27\u5316\u6c22\uff08H2<\/sub>O2<\/sub>\uff09\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u8bfe\u9898\u7ec4\u5c06\u94c2\u539f\u5b50\u5206\u6563\u5728\u5177\u6709\u9ad8\u6d53\u5ea6\u5355\u539f\u5b50Pt\u4f4d\uff0824.8 at\uff05\uff09\u7684\u975e\u6676\u6001CuSx<\/sub>\u8f7d\u4f53\u4e2d\u5408\u6210\u7a7a\u5fc3\u7eb3\u7c73\u7403\uff08h-Pt1-CuSx<\/sub>\uff09\uff0c\u8be5\u50ac\u5316\u5242\u5728HClO4<\/sub>\u7535\u89e3\u8d28\u4e2d\u53ef\u4ee5\u5c06O2<\/sub>\u8fd8\u539f\u4e3aH2<\/sub>O2<\/sub>\uff0c\uff0c\u7535\u4f4d\u8303\u56f4\uff080.05-0.7 V\uff0cvs. RHE\uff09\uff0c\u9009\u62e9\u6027\u9ad8\u8fbe92\uff05-96\uff05\u3002\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548cX\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\u6cd5\u8bc1\u5b9e\u4e86Pt\u7684\u539f\u5b50\u5206\u79bb\u5f62\u5f0f\uff0c\u5176\u4f4e\u4ef7+0.75\u3002\u8be5\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u53ef\u4ee5\u4eceH2<\/sub>\u548cO2<\/sub>\u76f4\u63a5\u5408\u6210H2<\/sub>O2<\/sub>\u7684\u7535\u5316\u5b66\u88c5\u7f6e\uff0cH2<\/sub>O2<\/sub>\u7684\u751f\u4ea7\u7387\u9ad8\u8fbe546\u00b130mol kgcat<\/sub>\u00a0-1<\/sup>\u00a0h -1<\/sup>\uff0c\u5e76\u4e14\u8bc1\u5b9e\u4e86\u9ad8\u6d53\u5ea6\u7684\u5355\u539f\u5b50Pt\u4f4d\u662f\u5bfc\u81f4H2<\/sub>O2<\/sub>\u7684\u8d85\u9ad8\u751f\u4ea7\u7387\u7684\u4e3b\u8981\u56e0\u7d20\u3002[5]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cHigh-Concentration Single Atomic Pt\u00a0Sites on Hollow CuSx<\/sub>\u00a0for Selective O2<\/sub>\u00a0Reduction to H2<\/sub>O2<\/sub>\u00a0in Acid Solution\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Chem.\u3002<\/p>\n

\u56fe\u4e94\uff1ah-Pt1-CuS<\/b><\/strong>x<\/b><\/sub><\/strong>\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u793a\u610f\u56fe\u548c\u8868\u5f81\u56fe<\/b><\/strong><\/p>\n

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\u5218\u658c\uff08\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff09<\/b><\/strong><\/p>\n

6. Angew. Chem. Int. Ed.<\/b><\/strong>\u5355\u539f\u5b50\u954d\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f<\/b><\/strong><\/p>\n

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\u56fe\u516d\uff1a\u954d\u5355\u539f\u5b50\u50ac\u5316\u5242\u6a21\u578b\u4ee5\u53ca\u8868\u5f81\u56fe<\/b><\/strong><\/p>\n

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7. Adv. Mater. \u8d35\u91d1\u5c5e\u5355\u539f\u5b50\u7528\u4e8e\u591a\u76f8\u50ac\u5316<\/b><\/strong><\/p>\n

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\u56fe\u4e03\uff1a\u94c2\u5355\u539f\u5b50\u5728\u4e0d\u540c\u7684\u8f7d\u4f53\u4e0a\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

8. Chem\u5408\u7406\u8bbe\u8ba1\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u76f4\u63a5\u751f\u4ea7H<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong><\/p>\n

\u9178\u6027\u4ecb\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u6c27\u8fd8\u539f\u53cd\u5e94\u4e3a\u76f4\u63a5\u4ea7\u751f\u8fc7\u6c27\u5316\u6c22\uff08H2<\/sub>O2<\/sub>\uff09\u548c\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6f5c\u529b\u7684\u9014\u5f84\u3002\u4f46\u662f\uff0c\u4ecd\u7136\u7f3a\u4e4f\u5177\u6709\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u5177\u6709\u6210\u672c\u6548\u76ca\u7684\u7535\u50ac\u5316\u5242\u3002\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5218\u658c\u8bfe\u9898\u7ec4\u4ece\u7406\u8bba\u4e0a\u8bbe\u8ba1\u548c\u5b9e\u9a8c\u8bc1\u660e\uff0c\u951a\u56fa\u5728\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u4e2d\u7684\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08Co SAC\uff09\u5bf9*OOH\u4e2d\u95f4\u4f53\u6709\u4f18\u5316\u5438\u9644\u80fd\uff0c\u5177\u6709\u8f83\u9ad8\u7684H2<\/sub>O2<\/sub>\u751f\u6210\u7387\uff0c\u751a\u81f3\u7565\u5fae\u8d85\u8fc7\u4e86\u6700\u65b0\u7684\u8d35\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\u3002\u4e0e\u57280.1 M HClO4<\/sub>\u4e2d\u4f7f\u7528\u53ef\u9006\u6c22\u7535\u6781\u7684H2<\/sub>O2<\/sub>\u6cd5\u62c9\u7b2c\u6548\u7387> 90\uff05\u76f8\u6bd4\uff0cCo SAC\u4e0aH2<\/sub>O2<\/sub>\u4ea7\u751f\u7684\u52a8\u7535\u6d41\u57280.6 V\u65f6\u53ef\u8fbe\u52301 mA cm2<\/sup>\uff0c\u5e76\u4e14\u8fd9\u4e9b\u6027\u80fd\u6307\u6807\u53ef\u7ef4\u630110 h\u800c\u4e0d\u4f1a\u8870\u51cf\u3002\u8fdb\u4e00\u6b65\u7684\u52a8\u529b\u5b66\u5206\u6790\u548cX\u5c04\u7ebf\u5438\u6536\u7814\u7a76\u4e0e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u8ba1\u7b97\u76f8\u7ed3\u5408\u8868\u660e\uff0c\u6c2e\u914d\u4f4d\u7684\u5355\u4e2aCo\u539f\u5b50\u662f\u6d3b\u6027\u4f4d\u70b9\uff0c\u53cd\u5e94\u53d7\u7b2c\u4e00\u6b65\u7535\u5b50\u8f6c\u79fb\u6b65\u9aa4\u7684\u901f\u7387\u9650\u5236\u3002\u8be5\u9879\u7814\u7a76\u4e3a\u7535\u5316\u5b66\u5236\u5907\u8fc7\u6c27\u5316\u6c22\u63d0\u4f9b\u4e00\u79cd\u65b0\u7684\u7b56\u7565\u3002[8]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cEnabling Direct H2<\/sub>O2<\/sub>\u00a0Production\u00a0in Acidic Media through Rational Design\u00a0of Transition Metal Single Atom Catalyst\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Chem\u3002<\/p>\n

\u56fe\u516b\uff1a\u5355\u539f\u5b50\u50ac\u5316\u5242\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u66fe\u6770\uff08\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\uff09<\/b><\/strong><\/p>\n

9. Nature Commun.<\/b><\/strong>\u7535\u5316\u5b66\u6c89\u79ef\u5236\u5907\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u901a\u7528\u9014\u5f84<\/b><\/strong><\/p>\n

\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SAC\uff09\u7531\u4e8e\u5176\u6700\u5927\u7684\u539f\u5b50\u5229\u7528\u7387\u548c\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u800c\u5c55\u73b0\u51fa\u4ee4\u4eba\u7740\u8ff7\u7684\u50ac\u5316\u6027\u80fd\u3002\u4f46\u662f\uff0c\u76ee\u524d\u5408\u6210SAC\u7684\u7b56\u7565\u901a\u5e38\u5bf9\u951a\u5b9a\u91d1\u5c5e\u6216\u8f7d\u4f53\u6709\u7279\u6b8a\u8981\u6c42\u3002\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u66fe\u6770\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7535\u5316\u5b66\u6c89\u79ef\u7684\u901a\u7528\u65b9\u6cd5\u7528\u4e8e\u5e7f\u6cdb\u7684\u91d1\u5c5e\u548cSAC\u7684\u5236\u5907\u3002\u6c89\u79ef\u540c\u65f6\u5728\u9634\u6781\u548c\u9633\u6781\u4e0a\u8fdb\u884c\uff0c\u5176\u4e2d\u4e0d\u540c\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4f7fSAC\u5177\u6709\u4e0d\u540c\u7684\u7535\u5b50\u6001\u3002\u9634\u6781\u6c89\u79ef\u7684SAC\u5bf9\u6c22\u6c14\u6790\u51fa\u53cd\u5e94\u8868\u73b0\u51fa\u9ad8\u6d3b\u6027\uff0c\u800c\u9633\u6781\u6c89\u79ef\u7684SAC\u5bf9\u6c27\u6c14\u6790\u51fa\u53cd\u5e94\u8868\u73b0\u51fa\u9ad8\u6d3b\u6027\u3002\u5f53\u5c06\u5728Co0.8<\/sub>Fe0.2<\/sub>Se2<\/sub>@Ni\u6ce1\u6cab\u4e0a\u9634\u6781\u548c\u9633\u6781\u6c89\u79ef\u7684Ir\u5355\u539f\u5b50\u6574\u5408\u5230\u4e24\u7535\u6781\u7535\u89e3\u6c60\u4e2d\u4ee5\u8fdb\u884c\u6c34\u5206\u89e3\u65f6\uff0c\u5728\u78b1\u6027\u7535\u89e3\u6db2\u4e2d\u7535\u6d41\u5bc6\u5ea610 mA cm-2<\/sup>\u65f6\u9700\u89811.39 V\u7684\u7535\u538b\u3002\u8be5\u9879\u7814\u7a76\u4e3a\u5408\u6210SAC\u7684\u65b9\u6cd5\u4ee5\u53ca\u5f00\u53d1\u9488\u5bf9\u76ee\u6807\u5316\u5b66\u53cd\u5e94\u7684\u9ad8\u6548\u50ac\u5316\u5242\u63d0\u4f9b\u65b0\u7684\u89c1\u89e3\u3002[9]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cElectrochemical deposition as a universal route\u00a0for fabricating single-atom catalysts\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nature Commun.\u3002<\/p>\n

\u56fe\u4e5d\uff1a\u7535\u5316\u5b66\u6c89\u79ef\u673a\u5236\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

10. Adv. Sci. \u70ed\u50ac\u5316\u53cd\u5e94\u4e2d\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u9759\u6001\u8c03\u8282\u548c\u52a8\u6001\u6f14\u5316<\/b><\/strong><\/p>\n

\u5355\u539f\u5b50\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7406\u60f3\u7684\u5e73\u53f0\uff0c\u4ee5\u5f25\u5408\u5747\u76f8\u548c\u5f02\u76f8\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u5dee\u8ddd\u3002\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u66fe\u6770\u8bfe\u9898\u7ec4\u4ece\u9759\u6001\u8c03\u8282\u548c\u52a8\u6001\u6f14\u53d8\u7684\u89d2\u5ea6\u62a5\u9053\u4e86\u8be5\u9886\u57df\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u7b80\u8981\u8ba8\u8bba\u4e86\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5408\u6210\u548c\u8868\u5f81\u4ee5\u53ca\u4f5c\u4e3a\u50ac\u5316\u7814\u7a76\u7684\u524d\u63d0\u3002\u4ece\u9759\u6001\u8c03\u8282\u7684\u89d2\u5ea6\uff0c\u901a\u8fc7\u8f7d\u4f53\u5982\u4f55\u6539\u53d8\u5355\u4e2a\u539f\u5b50\u7684\u7535\u5b50\u7279\u6027\u4ee5\u53ca\u5355\u4e2a\u539f\u5b50\u5982\u4f55\u6fc0\u6d3b\u8f7d\u4f53\u4e2d\u7684\u60f0\u6027\u539f\u5b50\u6765\u8bf4\u660e\u91d1\u5c5e\u4e0e\u8f7d\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u5355\u4e2a\u539f\u5b50\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u7a81\u51fa\u663e\u793a\u4ee5\u53ca\u8868\u9762\u91cd\u5efa\uff0c\u4f8b\u5982\u50ac\u5316\u6761\u4ef6\u4e0b\u5355\u4e2a\u539f\u5b50\u7684\u7f6e\u6362\u548c\u805a\u96c6\u3002\u6700\u540e\uff0c\u8ba8\u8bba\u4e86\u5355\u539f\u5b50\u975e\u5747\u76f8\u50ac\u5316\u5242\u4e2d\u5f53\u524d\u7684\u6280\u672f\u6311\u6218\u548c\u673a\u7406\u4e89\u8bba\u3002[10]<\/sup>\u76f8\u5173\u6210\u679c\u4ee5\u201cStatic Regulation and Dynamic Evolution of Single-Atom\u00a0Catalysts in Thermal Catalytic Reactions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Adv. Sci.\u3002<\/p>\n

\u56fe\u5341\uff1a\u5355\u539f\u5b50\u50ac\u5316\u5242\u5236\u5907\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

1. Zhang J.,Zhao Y.,Chen C.,\u00a0Huang Y.,\u00a0Dong C., Chen C., Liu R., Wang C., Yan K., Li Y., Wang\u00a0G.,\u00a0Tuning the Coordination Environment in Single-Atom Catalysts to\u00a0Achieve Highly Efficient Oxygen Reduction Reactions. [J] J. Am. Chem. Soc. 2019, 141, 20118\u221220126.<\/p>\n

2. Jiang Z.,Sun W.,Shang H.,\u00a0Chen W.,\u00a0Sun T., Li H.,\u00a0Dong J.,\u00a0Zhou J.,\u00a0Li Z.,\u00a0Wang Y.,\u00a0Cao R.,\u00a0Sarangi R., Yang Z.,\u00a0Wang D., Zhang J., Li Y., Atomic interface effect of a single atom copper\u00a0catalyst for enhanced oxygen reduction reactions. [J] Energy Environ. Sci.\u00a02019, 12, 3508-3514.<\/p>\n

3. Chen Y., Ji S., Sun W., Lei Y., Wang Q., Li A.,Chen W., Zhou G.,Zhang Z., Wang\u00a0Y., Zheng L., Zhang Q., Gu L.,\u00a0Han X., Wang D.,\u00a0Li\u00a0Y.,\u00a0Engineering the Atomic Interface with Single Platinum Atoms for\u00a0Enhanced Photocatalytic Hydrogen Production. [J] Angew. Chem. Int. Ed. 2020, 59, 1295-1301.<\/p>\n

4. Hou H, Mao J, Han Y, Wu F, Zhang M, Wang D, Mao L, Li Y. Single-atom electrocatalysis: a new approach to in vivo electrochemical biosensing. [J] Sci. China Chem., 2019, 62,1720-1724.<\/p>\n

5. Shen R.,Chen W.,Peng Q.,\u00a0Lu S.,\u00a0Zheng L.,\u00a0Cao X.,\u00a0Wang Y., Zhu W.,\u00a0Zhang J.,\u00a0Zhuang Z.,\u00a0Chen C.,\u00a0Wang D.,\u00a0Li Y., High-Concentration Single Atomic Pt\u00a0Sites on Hollow CuSx for Selective O2\u00a0Reduction to H2O2 in Acid Solution. [J] Chem 2019, 5, 2099-2110.<\/p>\n

6. Liu S., Yang H., Hung S., Ding J., Cai W., Liu L., Gao J.,Li X., Ren X., Kuang Z., Huang Y.,Zhang T., Liu B., Elucidating the Electrocatalytic CO2 Reduction Reaction over\u00a0a\u00a0Model\u00a0Single-Atom Nickel Catalyst. [J] Angew. Chem. Int. Ed. 2020, 59, 798-803.<\/p>\n

7. Li X., Yang X., Huang Y., Zhang T.,Liu B., Supported Noble-Metal Single Atoms for HeterogeneousCatalysis. [J] Adv. Mater. 2019, 31, 1902031.<\/p>\n

8. Gao J.,Yang H.,Huang X.,\u00a0Hung S.,\u00a0Cai W.,\u00a0Jia C., Miao S.,\u00a0Chen H.,\u00a0Yang X.,\u00a0Huang Y.,\u00a0Zhang T.,\u00a0Liu B., Enabling Direct H2<\/sub>O2<\/sub>\u00a0Production in Acidic\u00a0Media through Rational Design of Transition\u00a0Metal Single Atom Catalyst. [J] Chem 2020, 6, 658-674.<\/p>\n

9. Zhang Z., Feng C., Liu C., Zuo M., Qin L., Yan X., Xing Y., Li H.,Si R., Zhou S.,Zeng J.,\u00a0Electrochemical deposition as a universal route\u00a0for fabricating single-atom catalysts. [J] Nature Commun.,\u00a02020,\u00a011, 1215.<\/p>\n

10. Li H., Wang M., Luo L., Zeng J., Static Regulation and Dynamic Evolution of Single-AtomCatalysts in Thermal Catalytic Reactions. [J] Adv. Sci. 2019, 6, 1801471.<\/p>\n

\u672c\u6587\u7531\u559c\u6b22\u957f\u9888\u9e7f\u7684\u9ad8\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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