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\/><\/p>\n<p>\u8d85\u539f\u5b50\u4e0a\u7684\u5c01\u7aef\u914d\u4f53\u4e0d\u4ec5\u53ef\u4ee5\u5f15\u5bfc\u8d85\u539f\u5b50\u6676\u4f53\u7684\u7ec4\u88c5\uff0c\u8fd8\u80fd\u5f71\u54cd\u6750\u6599\u7684\u96c6\u5408\u6027\u6027\u8d28\u3002\u5982\u56fe2\u6240\u793a<sup>[6]<\/sup>\uff0c\u7532\u70f7\u884d\u751f\u914d\u4f53\u88ab\u88c5\u8f7d\u5728\u91d1\u7c07Au<sub>21<\/sub>\uff0c\u8fd9\u4e00\u914d\u4f53\u4f5c\u4e3a\u201c\u94a9\u5b50\u201d\u901a\u8fc7\u03c0\u2013\u03c0\u548c\u03c0\u2013\u9634\u79bb\u5b50\u4f5c\u7528\u94fe\u63a5\u5468\u8fb9\u7684\u8d85\u539f\u5b50\uff0c\u5e76\u5f62\u6210\u4e00\u7ef4\u7ea4\u4e1d\u3002\u8fd9\u4e9b\u7ea4\u4e1d\u5219\u53ef\u4ee5\u8fdb\u4e00\u6b65\u7ec4\u88c5\u5f62\u6210\u4e09\u7ef4\u8d85\u539f\u5b50\u6676\u4f53\u3002\u7814\u7a76\u663e\u793a\uff0c\u901a\u8fc7\u5728\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\u6539\u53d8\u53cd\u79bb\u5b50\u7684\u53c2\u6570\u53ef\u4ee5\u8c03\u63a7\u6750\u6599\u7535\u5bfc\u6027\uff0c\u4f7f\u5f97\u7535\u5bfc\u6027\u589e\u52a0\u4e24\u4e2a\u6570\u91cf\u7ea7\u4ee5\u4e0a\u3002\u901a\u8fc7\u5728\u8d85\u539f\u5b50\u5185\u6838\u4e0a\u4fee\u9970\u529f\u80fd\u5316\u7684\u6ca1\u98df\u5b50\u9178\u884d\u751f\u914d\u4f53\uff0c\u8fd8\u80fd\u5f62\u6210\u5177\u6709\u7ea2\u5149-\u8fd1\u7ea2\u5916\u5149\u81f4\u53d1\u5149\u7684\u6db2\u6676\u76f8\u3002<\/p>\n<ul>\n<li>\u8d85\u539f\u5b50\u805a\u5408\u7269<\/li>\n<\/ul>\n<p>\u56fe3 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\/><\/p>\n<p>\u4e0e\u8d85\u539f\u5b50\u6db2\u6676\u76f8\u4f3c\uff0c\u542b\u6709\u8d85\u539f\u5b50\u5185\u6838\u7684\u805a\u5408\u7269\u4e5f\u53ef\u4ee5\u901a\u8fc7\u652f\u94fe\u914d\u4f4d\u3001\u79bb\u5b50\/\u8d85\u5206\u5b50\u4f5c\u7528\u5408\u6210\u800c\u6765\u3002\u8fd9\u7c7b\u542b\u8d85\u539f\u5b50\u7684\u805a\u5408\u7269\u5728\u4fdd\u7559\u8d85\u539f\u5b50\u6027\u8d28\u7684\u540c\u65f6\uff0c\u8fd8\u80fd\u8d4b\u4e88\u5927\u5206\u5b50\u9aa8\u67b6\u53ef\u52a0\u5de5\u6027\u80fd\u3002\u8d85\u539f\u5b50\u7c07\u7528\u7532\u57fa\u4e19\u70ef\u9178\u7b49\u8fdb\u884c\u5904\u7406\u53ef\u4ee5\u5f97\u5230\u53ef\u805a\u5408\u7684\u8d85\u539f\u5b50\uff0c\u8fd9\u4e9b\u8d85\u539f\u5b50\u5355\u5143\u4e0e\u8fc7\u91cf\u7684\u6709\u673a\u5355\u4f53\u7ecf\u8fc7\u81ea\u7531\u57fa\u805a\u5408\u53ef\u4ee5\u5f62\u6210\u542b\u8d85\u539f\u5b50\u7ed3\u6784\u7684\u5076\u8054\u805a\u5408\u7269\u7f51\u7edc\u3002\u5229\u7528\u8fd9\u4e00\u7b56\u7565\uff0c\u4eba\u4eec\u53d1\u660e\u4e86\u4e00\u7cfb\u5217\u542b\u6709\u8d85\u539f\u5b50\u7684\u5d4c\u6bb5\u5171\u805a\u7269\uff08\u5982\u56fe3\u6240\u793a<sup>[7]<\/sup>\uff09\u3002\u4f8b\u5982\u964d\u51b0\u7247\u70ef\u57fa\u5355\u4f53\u9996\u5148\u901a\u8fc7\u5149\u4e0d\u7a33\u5b9a\u7fb0\u57fa\u914d\u4f53\u53d6\u4ee3\u53cd\u5e94\u88ab\u88c5\u8f7d\u5728Co<sub>6<\/sub>Se<sub>8<\/sub>\u8d85\u539f\u5b50\u7c07\u4e0a\uff0c\u968f\u540e\u5728\u5f00\u73af\u53cd\u5e94\u4e2d\u4e0e\u53e6\u4e00\u5d4c\u6bb5\u8fdb\u884c\u805a\u5408\u521b\u9020\u51fa\u542b\u8d85\u539f\u5b50\u7684\u65b0\u578b\u5d4c\u6bb5\u5171\u805a\u7269\u3002\u8fd9\u4e00\u7c7b\u5d4c\u6bb5\u5171\u805a\u7269\u540c\u65f6\u542b\u6709\u4eb2\u6c34\u9633\u79bb\u5b50\u8d85\u539f\u5b50\u7247\u6bb5\u548c\u53ef\u5171\u4ef7\u5076\u8054\u7684\u758f\u6c34\u7247\u6bb5\uff0c\u5728\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u53ef\u4ee5\u81ea\u7ec4\u88c5\u5f62\u6210\u5fae\u5c3a\u5ea6\u56ca\u6ce1\u3002\u5176\u4e2d\uff0c\u9633\u79bb\u5b50\u8d85\u539f\u5b50\u5f62\u6210\u56ca\u6ce1\u58c1\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u901a\u8fc7\u5149\u6d3b\u6027\u7247\u6bb5\u8fdb\u884c\u8fdb\u4e00\u6b65\u5076\u8054\uff0c\u8fd8\u80fd\u7528\u4e8e\u88c5\u8f7d\u7532\u57fa\u84dd\u7b49\u5206\u5b50\u8d27\u7269\u3002<\/p>\n<ul>\n<li>\u7535\u8377\u8f6c\u79fb\u7ec4\u88c5<\/li>\n<\/ul>\n<p>\u6709\u673a\u65e0\u673a\u6742\u5316\u6750\u6599\u7684\u51fa\u73b0\u4e3a\u8d85\u539f\u5b50\u6676\u4f53\u7684\u7ec4\u88c5\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u4f8b\u5982\u8d85\u539f\u5b50\u7684\u7535\u7ed3\u6676\uff0c\u53ef\u4ee5\u5229\u7528\u8d85\u539f\u5b50\u7c07\u4f5c\u4e3a\u6784\u5efa\u6a21\u5757\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u6676\u683c\u7684\u6676\u72b6\u56fa\u4f53\uff0c\u5176\u4e2d\u8d85\u539f\u5b50\u4e0a\u7684\u6c30\u5316\u7269\u914d\u4f53\u80fd\u591f\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u5f15\u5bfc\u6676\u683c\u7684\u5f62\u6210\u3002\u56e0\u6b64\u5229\u7528\u6709\u673a\u7535\u6d3b\u6027\u5206\u5b50\u7ed3\u5408\u5bcc\u7535\u8d85\u539f\u5b50\u7c07\u53ef\u4ee5\u7ec4\u88c5\u5f62\u6210\u65b0\u578b\u7684\u4e8c\u5143\u8d85\u539f\u5b50\u6676\u4f53\u3002\u5728\u8fd9\u7c7b\u6676\u4f53\u4e2d\uff0c\u7535\u8377\u5411\u7535\u5b50\u53d7\u4f53\u5355\u5143\uff08\u4f8b\u5982C<sub>60<\/sub>\uff09\u8f6c\u79fb\uff0c\u901a\u8fc7\u7535\u8377\u8f6c\u79fb\u9a71\u52a8\u4f5c\u7528\u805a\u96c6\u7ec4\u88c5\u4ea7\u751f\u4e8c\u5143\u79bb\u5b50\u7ec4\u5206\u3002\u56e0\u6b64\uff0c\u7535\u5b50\u53d7\u4f53\u5355\u5143\u5982C<sub>60<\/sub>\u3001C<sub>70<\/sub>\u4ee5\u53ca\u5bcc\u52d2\u70ef\u7b49\u4e5f\u53ef\u4ee5\u7ec4\u88c5\u5f62\u6210\u78b3\u57fa\u8d85\u539f\u5b50\u6676\u4f53\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u7535\u4e92\u8865\u6027\u8f83\u5f3a\u7684\u65e0\u673a\u6784\u5efa\u6a21\u5757\uff0c\u5982\u91d1\u5c5e\u786b\u5316\u7269\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u8005\u91d1\u5c5e\u5364\u5316\u7269\u5747\u53ef\u4ee5\u7ec4\u88c5\u5f62\u6210\u8d85\u539f\u5b50\u6676\u4f53\u3002<\/p>\n<ul>\n<li>\u5206\u5b50\u8bc6\u522b\u7ec4\u88c5<\/li>\n<\/ul>\n<p>\u56fe4 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\/><\/p>\n<p>\u9664\u4e86\u8d85\u539f\u5b50\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u5bfc\u81f4\u7684\u9759\u7535\u4f5c\u7528\u5916\uff0c\u8d85\u539f\u5b50\u6676\u4f53\u8fd8\u80fd\u591f\u901a\u8fc7\u5206\u5b50\u8bc6\u522b\u7247\u6bb5\u8fdb\u884c\u7ec4\u88c5\u800c\u6210\u3002\u4f8b\u5982\uff0c\u6709\u7814\u7a76<sup>[8]<\/sup>\u5229\u7528\u4fee\u9970\u6709\u83f2\u7c7b\uff08phenanthrene\uff09\u57fa\u56e2\u7684\u8d85\u539f\u5b50\u4f5c\u4e3a\u7eb3\u7c73\u5c3a\u5ea6\u5bfc\u5411\u5242\u5f62\u6210\u5c42\u72b6\u8303\u5fb7\u74e6\u5c14\u65af\u56fa\u4f53\u3002\u5982\u56fe4\u6240\u793a\uff0c\u83f2\u7c7b\u914d\u4f53\u5728Co<sub>6<\/sub>Se<sub>8<\/sub>(PEt<sub>2<\/sub>phen)<sub>6<\/sub>\u00a0(PEt<sub>2<\/sub>phen = diethyl(9-ethynylphenanthrene)\u00a0phosphine\u4e0a\u901a\u8fc7\u5ef6\u4f38\u3001\u65cb\u8f6c\u3001\u7ec4\u7ec7\u7b49\u4e0eC<sub>60<\/sub>\u8fdb\u884c\u76f8\u4e92\u4f5c\u7528\uff0c\u5f62\u6210\u54d1\u94c3\u5355\u5143\u4f5c\u4e3a\u6269\u5c55\u5c42\u72b6\u7ed3\u6784\u7684\u6a21\u677f\u3002\u901a\u8fc7\u8fd9\u4e00\u65b9\u6cd5\u5f62\u6210\u7684\u5757\u4f53\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u901a\u8fc7\u5265\u79bb\u7684\u65b9\u5f0f\u8fd8\u80fd\u4ea7\u751f\u4e8c\u7ef4\u8d85\u539f\u5b50\u6750\u6599\u3002<\/p>\n<p><strong>\u591a\u5ba4\u8d85\u539f\u5b50\u6750\u6599<\/strong><\/p>\n<p>\u56fe5 \u7535\u7ed3\u6676\u8d85\u539f\u5b50\u7ec7\u7269\u6750\u6599\u7684\u7ebf\u6846\u5f0f\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-200185 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/04\/\u56fe\u72475-12.png\" alt=\"\" width=\"565\" height=\"268\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/04\/\u56fe\u72475-12.png 565w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2020\/04\/\u56fe\u72475-12-300x142.png 300w\" sizes=\"(max-width: 565px) 100vw, 565px\" 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Atomic clusters: buildingblocks for a class of solids. Phys. Rev. B 51,\u00a013705\u201313716 (1995).<\/p>\n<p>2. Metal chalcogenide clusterchemistry. Prog. Inorg. Chem. 41, 637\u2013803 (1994).<\/p>\n<p>3. Nonmolecular metalchalcogenide\/halide solids and their molecular clusteranalogues. Angew. Chem. Int. Ed. 29, 840\u2013856\u00a0(1990).<\/p>\n<p>4. Building diatomic andtriatomic superatom molecules. Nano Lett. 16,5273\u20135277 (2016).<\/p>\n<p>5. Superatom fusionand the nature of quantum confinement. Nano Lett.18, 4564\u20134569 (2018).<\/p>\n<p>6. Modulating the hierarchical fibrousassembly of Au nanoparticles with atomic precision.Nat. Commun. 9, 3871 (2018).<\/p>\n<p>7. Multifunctionalvesicles from a self-assembled cluster-containingdiblock copolymer. J. Am. Chem. Soc. 140,\u00a05607\u20135611 (2018).<\/p>\n<p>8. Choi, B. et al. van der Waals solids fromself-assembled nanoscale building blocks. Nano Lett.16, 1445\u20131449 (2016).<\/p>\n<p>9. Champsaur, A. M. et al. Weaving nanoscale cloththrough electrostatic templating. J. Am. Chem. 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